cheminform abstract: broensted acid-promoted aziridination of electron-deficient olefins
TRANSCRIPT
www.cheminform.wiley-vch.de
Aziridine derivativesR 0040 Broensted Acid-Promoted Aziridination of Electron-Deficient Olefins. — The re-
action mechanism is systematically studied using a combined theoretical and experi-mental approach. The efficiency of this reaction is shown to strongly depend on the ba-sicity of the olefins used. Accordingly, TfOH readily promotes the aziridination of var-ious acrylamides (I), while less basic acrylates and acrylonitrile are significantly less reactive. — (LI, J.; FU*, Y.; GUO, Q.-X.; Tetrahedron 64 (2008) 49, 11167-11174; Dep. Chem., Univ. Sci. Technol. China, Hefei 230026, Anhui, Peop. Rep. China; Eng.) — Mischke
16- 097
ChemInform 2009, 40, issue 16 © 2009 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim