cheminform abstract: carbohydrate-based pseudo-dipeptides: new ligands for the highly...

ChemInform 2012, 43, issue 13 © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim Alcohols Q 0230 DOI: 10.1002/chin.201213077 Carbohydrate-Based Pseudo-Dipeptides: New Ligands for the Highly Enantiose- lective Ru-Catalyzed Transfer Hydrogenation Reaction. — Ruthenium-complexes of novel carbohydrate based pseudo-dipeptide ligands selectively catalyze the reduc- tion of aryl-alkyl ketones (I) under transfer-hydrogenation conditions. Excellent enan- tioselectivities are obtained using aminosugars as the sole source of chirality. — (COLL, M.; PAMIES, O.; ADOLFSSON, H.; DIEGUEZ*, M.; Chem. Commun. (Cambridge) 47 (2011) 44, 12188-12190, http://dx.doi.org/10.1039/c1cc15024c ; Dep. Quim. Fis. Inorg., Univ. Rovira Virgili, E-43007 Tarragona, Spain; Eng.) — M. Paetzel 13- 077

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Page 1: ChemInform Abstract: Carbohydrate-Based Pseudo-Dipeptides: New Ligands for the Highly Enantioselective Ru-Catalyzed Transfer Hydrogenation Reaction

AlcoholsQ 0230 DOI: 10.1002/chin.201213077

Carbohydrate-Based Pseudo-Dipeptides: New Ligands for the Highly Enantiose-lective Ru-Catalyzed Transfer Hydrogenation Reaction. — Ruthenium-complexes of novel carbohydrate based pseudo-dipeptide ligands selectively catalyze the reduc-tion of aryl-alkyl ketones (I) under transfer-hydrogenation conditions. Excellent enan-tioselectivities are obtained using aminosugars as the sole source of chirality. — (COLL, M.; PAMIES, O.; ADOLFSSON, H.; DIEGUEZ*, M.; Chem. Commun. (Cambridge) 47 (2011) 44, 12188-12190, http://dx.doi.org/10.1039/c1cc15024c ; Dep. Quim. Fis. Inorg., Univ. Rovira Virgili, E-43007 Tarragona, Spain; Eng.) —M. Paetzel

13- 077

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