cheminform abstract: non-aqueous synthesis and structure of a novel monodimensional zirconium...
TRANSCRIPT
2002 structure
structure (solids and liquids)D 2000
27 - 006Non-aqueous Synthesis and Structure of a Novel Monodimen-sional Zirconium Phosphate: [NH4]3 [Zr(OH)2(PO4)(HPO4)]. —The novel, one-dimensional title compound is synthesized from a mixture ofZrOCl2·8H2O, H3PO4, en, NH4F, and (HOCH2CH2)2O in a ratio of 1:1.2:1:4:30(autoclave, 180 ◦C, 6 d). As revealed by single crystal XRD, the compoundcrystallizes in the triclinic space group P1 with Z = 2. The structure consists ofmacroanionic chains of [ZrP2O10H3]3− separated by NH4
+ cations. The titlecompound might probably have some ion-exchange properties. — (WANG,DAN; YU, RANBO; TAKEI, TAKAHIRO; KUMADA, NOBUHIRO; KINO-MURA, NOBUKAZU; ONDA, AYUMU; KAJIYOSHI, KOJI; YANAGISAWA,KAZUMICHI; Chem. Lett. (2002) 3, 398-399; Catal. Sci. Lab., Res. Inst.Innovative Technol. Earth, Soraku, Kyoto 619-02, Japan; EN)
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