cheminform abstract: titanocene(iii) chloride mediated radical induced allylation of aldimines:...
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C-C bond formationO 0282 DOI: 10.1002/chin.201201035
Titanocene(III) Chloride Mediated Radical Induced Allylation of Aldimines: For-mal Synthesis of C-Linked 4'-Deoxy Aza-disaccharide. — The reaction allows a mild and convenient access to homoallyl amines as useful synthons. The sugar deriva-tive (IX) can be smoothly and stereoselectively converted into the C-linked deoxy aza-disaccharide (XIII). — (SAHA, S.; ROY*, S. C.; J. Org. Chem. 76 (2011) 17, 7229-7234, http://dx.doi.org/10.1021/jo200908b ; Dep. Org. Chem., Indian Assoc. Cultiv. Sci., Kolkata 700 032, India; Eng.) — Jannicke
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ChemInform 2012, 43, issue 01 © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim