cheminform abstract: ultrasonic irradiation and the homo- and hetero-diels—alder reaction

2001 microwave chemistry, sonochemistry, mechanochemistry microwave chemistry, sonochemistry, mechanochemistry O 0170 51 - 058 Ultrasonic Irradiation and the Homo- and Hetero-Diels–Alder Re- action. — The eﬀects of ultrasound on the hetero- and homo-Diels–Alder reactions have been investigated varying ultrasonic source and solvent. Irra- diation enhances both reactions minimally; however, while this appears to be due to cavitation in the homo-Diels–Alder reaction, mechanical mixing appears to be the cause in the hetero-Diels–Alder reaction. — (ALFARO, RAUL; MCCLUSKY, JOHN V.; Synth. Commun. 31 (2001) 16, 2513-2522; Div. Earth Phys. Sci., Univ. Tex., San Antonio, TX 78249, USA; EN) 1

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Page 1: ChemInform Abstract: Ultrasonic Irradiation and the Homo- and Hetero-Diels—Alder Reaction

2001 microwave chemistry, sonochemistry, mechanochemistry

microwave chemistry, sonochemistry, mechanochemistryO 0170

51 - 058Ultrasonic Irradiation and the Homo- and Hetero-Diels–Alder Re-action. — The effects of ultrasound on the hetero- and homo-Diels–Alderreactions have been investigated varying ultrasonic source and solvent. Irra-diation enhances both reactions minimally; however, while this appears to bedue to cavitation in the homo-Diels–Alder reaction, mechanical mixing appearsto be the cause in the hetero-Diels–Alder reaction. — (ALFARO, RAUL;MCCLUSKY, JOHN V.; Synth. Commun. 31 (2001) 16, 2513-2522; Div. EarthPhys. Sci., Univ. Tex., San Antonio, TX 78249, USA; EN)

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