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Chemistry 6.0 Name________________________________Chapter 8 – Chemical Equations
Chemical Equations Introduction:
Write complete equations for the following:
1. Two moles of solid sodium chloride decompose when exposed to an electric current into two moles of sodium metal and 1 mole of chlorine gas.
2. One mole of barium chloride in solution reacts with one mole of sodium sulfate in solution to produce 1 mole of solid barium sulfate and 2 moles of sodium chloride in solution.
3. Two mole of solid potassium chlorate, when heated, decompose into two moles of solid potassium chloride and 3 moles of oxygen gas.
4. One mole of solid calcium carbonate decomposes when heated into one mole of solid calcium oxide and 1 mole of carbon dioxide gas.
5. Two moles of solid aluminum hydroxide decomposes when heated into one mole of solid aluminum oxide and three moles of water vapor.
6. One mole of zinc metal when mixed with two moles of a hydrochloric acid solution react and produce one mole of zinc chloride in solution and one mole of hydrogen gas.
7. Eight moles of fluorine gas are bubbled through a solution containing eight moles of potassium sulfide and react to produce sixteen moles of potassium fluoride in solution and one mole of solid sulfur.
2Balancing Equations: Balance the following reactions. Place a “B” at the beginning of any that are
balanced as written.
8. _____ Zn + _____O2 → _____ZnO
9. _____HI → _____H2 + _____I2
10. _____B + _____F2 → _____BF3
11. _____N2 + _____H2 → _____NH3
12. _____Fe + _____H2O → _____Fe3O4 + _____H2
13. _____BaCl2 + _____H2SO4 → _____BaSO4 + _____HCl
14. _____P4 + _____O2 → _____P4O10
15. _____KClO3 → _____KCl + _____O2
16. _____C3H8 + _____O2 → _____CO2 + _____H2O
17. _____Cu + _____AgNO3 → _____Cu(NO3)2 + _____Ag
18. _____Te + _____H2O → _____TeO + _____H2
19. _____La(NO3)3 + _____NaOH → _____La(OH)3 + _____NaNO3
20. _____RhO3 → _____RhO + _____O2
21. _____Hf + _____N2 → _____Hf3N4
22. _____Ga + _____H2SO4 → _____Ga2(SO4)3 + _____H2
23. _____PdCl2 + _____HNO3 → _____Pd(NO3)2 + _____HCl
24. _____RbBr + _____AgCl → _____AgBr + _____RbCl
25. _____PaI5 → _____Pa + _____I2
326. Na + O2 → Na2O
27. H2 + O2 → H2O
28. Na2SO4 + CaCl2 → CaSO4 + NaCl
29. Al2O3 → Al + O2
30. C2H6 + O2 → CO2 + H2O
31. SO3 + H2O → H2SO4
32. SiCl4 → Si + Cl2
33. C + H2 → CH4
34. Br2 + NaI → NaBr + I2
35. Zn + HCl → ZnCl2 + H2
36. H2S + O2 → H2O + SO2
37. Ba(NO3)2 + Na2SO4 → BaSO4 + NaNO3
38. C5H12 + O2 → CO2 + H2O
39. HgO → Hg + O2
40. H2SO4 + Pb + PbO2 → PbSO4 + H2O
41. C6H12O6 + O2 → CO2 + H2O
42. Ca + H2O → Ca(OH)2 + H2
43. C6H12O6 → C2H5OH + CO2
44. HC2H3O2 + NaHCO3 → CO2 + NaC2H3O2 + H2O
45. NaCl + SO2 + H2O + O2 → Na2SO4 + HCl
46. Fe2O3 + CO → CO2 + Fe
47. Ca3(PO4)2 + C + SiO2 → CaSiO3 + CO + P4
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48. aluminum + hydrochloric acid aluminum chloride + hydrogen
49. chromium(III) hydroxide + nitric acid water + chromium(III) nitrate
50. chromium + hydrobromic acid chromium (III) bromide + hydrogen
51. krypton difluoride + water krypton + oxygen + hydrofluoric acid
52. chlorine + water hydrochloric acid + oxygen
53. CH3OH + O2 CO2 + H2O
54. Si2H6 + O2 SiO2 + H2O
55. CH3NH2 + O2 CO2 + H2O + N2
56. Na2SiO3 + HF H2SiF6 + NaF + H2O
57. NH3 + O2 NO + H2O
58. Sb2S3 + HCl H3SbCl6 + H2S
59. Al + NaOH + H2O NaAl(OH)4 + H2
60. C2H5Cl+ NaPb (C2H5)4Pb + NaCl + Pb
5Types of Reactions: Balance the following equations and indicate the type of reaction on the line
provided.
61. NaCl → Na + Cl2 _____________________
62. Na + Cl2 → NaCl _____________________
63. C2H4 + O2 → CO2 + H2O _____________________
64. H2O → H2 + O2 _____________________
65. H2 + O2 → H2O _____________________
66. C8H18 + O2 → CO2 + H2O _____________________
67. NaOH + HCl → H2O + NaCl _____________________
68. Na + HCl → H2 + NaCl _____________________
69. K + Cl2 → KCl _____________________
70. K + AgCl → Ag + KCl _____________________
71. C6H12 + O2 → CO2 + H2O _____________________
72. Ca + S8 → CaS _____________________
73. KOH + HNO3 → H2O + KNO3 _____________________
74. Al + O2 → Al2O3 _____________________
75. HgO → Hg + O2 _____________________
76. NaOH + H2SO4 → Na2SO4 + H2O _____________________
77. Fe + O2 → Fe2O3 _____________________
78. C6H8 + O2 → CO2 + H2O _____________________
79. Pb(NO3)2 + K2CrO4 → PbCrO4 + KNO3 _____________________
80. H2 + N2 → NH3 _____________________
81. C3H5(NO3)3 → CO2 + N2 + H2O + O2 _____________________
6Decomposition, Synthesis, and Combustion
82. Pt2O
83. Mg(ClO3)2
84. P2O5
85. SrO + H2O →
86. BaCO3
87. HNO3(aq)
88. C4H10 + O2 →
89. Al + O2
90. Cl2O3 + H2O →
91. Al(OH)3
92. iron(III) chlorate is heated
93. zinc oxide powder is added to water
94. pentane (C5H12) is ignited in air
95. phosphorous acid is heated
96. magnesium phosphide is exposed to an electric current
97. lithium hydroxide is heated
98. hydrogen gas is ignited in air
799. magnesium ribbon is heated in the presence of sulfur
100. scandium carbonate is heated
101. dinitrogen pentoxide gas is bubbled through water
Single Replacement
102. Zn + CuSO4 →
103. Pb + Mg(NO3)2 →
104. AgC2H3O2 + Li →
105. Cl2 + KBr →
106. HF(aq) + Ca →
107. magnesium + nitric acid →
108. sodium chloride + aluminum →
109. barium + calcium sulfate →
110. nickel(II) sulfate + lithium →
111. potassium + water →
112. silver + strontium chloride →
113. sodium fluoride + iodine →
114. rubidium + iron(III) sulfate →
115. sodium + water →
8116. fluorine + aluminum bromide →
117. phosphoric acid + calcium →
118. copper + water →
Double Replacement
119. AgCH3COO + CaSO4 →
120. Pb(NO3)2 + Na2S →
121. AgNO3 + FeCl3 →
122. H2SO4 + Ba(OH)2 →
123. Al(OH)3 + NH4Cl →
124. A solution of lead(II) chlorate is mixed with a solution of chromium(III) iodide.
125. A solution of nitric acid is added to a solution of magnesium hydroxide.
126. Solutions of copper(II) chloride and potassium carbonate are mixed.
127. Solid sodium carbonate is sprinkled on a hydrochloric acid spill.
128. Perchloric acid is neutralized by the addition of ammonium hydroxide.
Energy and Change of Enthalpy
129. Indicate the following as either exothermic or endothermic.
a) CH4 + 74.4 kJ → C + 2H2 a) ___________________
b) 1/8 S8 + O2 → SO2 b) ___________________
c) 3 C + 4 H2 → C3H8 + 104 kJ c) ___________________
d) butane + oxygen → carbon dioxide + water d) ___________________
e) CO2 → CO + ½ O2 ΔH = +238kJ e) ___________________
9130. The energy term of an exothermic reaction is added to the (right / left) side of chemical
equation because energy is (absorbed / released).
131. The ∆H of an endothermic reaction is indicated as a (+ / −) value because the enthalpy (potential energy) of the reactants is ( > / < ) than the enthalpy of the products.
132. All chemical fuels produce an (endothermic / exothermic) reaction upon ordinary combustion.
133. Baking a potato is an example of an (exothermic / endothermic ) reaction.
134. Copper and oxygen react according to the following: Cu + ½ O2 → CuO ∆H = −155kJ Rewrite this equation for 1 mole of O2 and include energy in the equation.
135. Carbon and sulfur react according to the following equation: 4C + S8 + 3511 kJ → 4CS2 Rewrite the equation for one mole of C, using the ∆H notation.
136. Draw an energy diagram for the equation given in the previous problem. Be sure to label all parts. (progress of the reaction, enthalpy or energy, ∆H, reactants, and products.
137. Using the graph below, determine:
a. The activation energy needed for the forward reaction?___________________
b. The activation energy needed for the reverse reaction? ___________________
c. ∆H for the forward reaction? Endothermic or exothermic? ___________________
d. ∆H for the reverse reaction? Endothermic or exothermic? ___________________
e. Label the activated complex on the curve.
f. Sketch what the curve might look like if a catalyst was added.
10138. Draw a potential energy diagram with the following criteria:
a. ∆Hrev = −30 kJb. Ea (forward reaction) = 70 kJc. Activated Complex = 90 kJ
139. Based on your diagram, determine:
a. ∆Hfor _____________________
b. Ea (reverse) _________________
c. Enthalpy of reactants__________________
d. Enthalpy of products_________________
Bond Energy
140. Given:
a. Identify the type and number of bonds broken in this reaction and determine the total amount of energy required to break them.
b. Identify the type and number of bonds formed in this reaction and determine the total amount of energy released when they are formed.
c. Calculate the enthalpy change for the entire reaction.
d. Is this reaction endothermic or exothermic?
e. Write a thermochemical equation for the reaction.
f. Draw and label a potential energy diagram for the reaction.
11141. Using bond energies, calculate the enthalpy change for the following reactions:
a.
b.
c.
d.
12Ionic Equations and Dissociation Reactions
1. Write appropriate ionization equations or dissociation equations to represent what happens when each of the following chemicals are mixed with water:
a. HNO3(aq)
b. H2SO4(aq)
c. LiOH
d. Ba(OH)2
e. Na2SO4
2. Write molecular, ionic and net ionic equations for each of the following:
a. Solutions of potassium hydroxide and nitric acid are mixed.
b. Solutions of barium chloride and sodium sulfate are mixed.
c. Solid calcium oxide is added to a hydrochloric acid solution
d. Solutions of lithium acetate and copper(II) nitrate are mixed.
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e. Solutions of iron(III) bromide and ammonium carbonate are mixed
f. A piece of zinc metal is added to a solution of copper(II) sulfate.
g. Solid lead(II) nitrate crystals are sprinkled into a solution of rubidium iodide.
h. A piece of aluminum metal is added to a solution of silver nitrate.
14Review (Identify reaction type before writing the equation)
142. calcium metal is added to a solution of nitric acid.
143. solutions of copper(II) nitrate and sodium hydroxide are mixed.
144. scandium carbonate is heated
145. nitrous acid is heated
146. zinc + magnesium carbonate →
147. dichlorine monoxide + water →
148. calcium carbonate + perchloric acid →
149. strontium chlorate is heated
150. lead(IV) sulfide is exposed to an electric current
151. the combustion of octane (C8H18)
152. silver oxide + water →
153. dichromic acid + ammonium hydroxide →
154. barium metal is dropped in water
155. copper(II) hydroxide is heated
156. lithium + sulfur →
157. bromine + iron(III) iodide →
158. solutions of sodium phosphate and calcium bromide are mixed.
159. barium metal is added to a solution of chlorous acid.
15160. chloric acid is heated
161. aluminum metal is added to a solution of sodium chlorate
162. dinitrogen pentoxide gas is bubbled through water
163. lithium carbonate is heated
164. ammonium carbonate powder is sprinkled on a hydrochloric acid spill
165. iron(III) phosphide is exposed to an electric current
166. hexane (C6H14) is ignited
167. tin(II) oxide is added to water
168. strontium hydroxide is combined with acetic acid
169. tin(IV) hydroxide is heated
170. a piece of silver metal is held in a Bunsen burner flame
171. lead(II) sulfide is heated in a fluorine environment
172. calcium hydroxide powder is added to an ammonium nitrate solution
173. A hydrocarbon compound is found to be 85.71% carbon and 14.29% hydrogen by mass. When vaporized at 35ºC, 0.136 g of the compound occupies a volume of 45.0 mL and exerts a pressure of 691 torr. Write a balanced equation for the combustion of this compound.
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174. Given:
a. Write a balanced molecular equation in ΔH notation.
b. Is the reaction endothermic or exothermic?
c. Which has a higher enthalpy, the reactants or the products?
d. Would the temperature of the surroundings increase or decrease?
175. For each of the following, write complete and balanced molecular, ionic and net ionic equations.
a. Solutions of lead(II) nitrate and potassium iodide are mixed.
b. Solutions of hydrochloric acid and silver nitrate are mixed.
c. Solutions of sodium hydroxide and iron (III) nitrate are mixed.
17Cumulative Review Questions
176. For 2607000 give the following:a) Number written in scientific notation _________________________
b) Significant figures _________________________
c) Rounded to 3 significant figures _________________________
177. Convert 23.6 hectograms to milligrams
178. A copper cube with a mass of 58.60 g is placed into a water-filled graduated cylinder. The water in the cylinder rises from 26.5 mL to 33.1 mL. Determine the density of the copper?
179. List 3 physical properties and 3 chemical properties of water.
180. Complete the following chart
Homogeneous or Heterogeneous
Element, Compound, Mixture, Solution
rubbing alcohol
calcium oxide
gasoline
181. Write nuclear equations for:
a) Alpha emission of radon-222
b) Electron capture by nitrogen-15
c) Neutron bombardment of oxygen-16
182. What is the mass and charge of 5.26 x 1024 electrons?
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183. A 2.65 gram sample of cobalt-55, with a half-life of 17.5 hours undergoes decay for 6.56 days. What mass of cobalt-55 remains at this point?
184. An element consists of 1.40% of an isotope with mass 203.973 amu, 24.10% of an isotope with mass 205.9745 amu, 22.10% of an isotope with mass 206.9759 amu, and 52.40% of an isotope with mass 207.9766 amu. Calculate the average atomic mass and identify the element.
185. Where appropriate, write formulas or names for each of the following:
a. ammonium sulfate ___________ f) H3AsO4(aq)_________________________
b. dinitrogen monoxide ___________ g) FeSO3 _________________________
c. phosphorous acid ___________ h) CuSO4•5H2O ______________________
d. lead(IV) oxalate ___________ i) BF3 _________________________
e. aluminum nitrite ___________ j) Cr(OH)3 _________________________
186. Determine the mass, in grams, of 4.22 x 1024 formula units of copper(I) sulfide.
187. What is the total number of electrons in 0.915 moles of nitrogen atoms?