chemistry in power plant-p
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Chemistry in Power PlantTRANSCRIPT
April 22, 2023 1
WATER CHEMISTRY IN POWER PLANT
BY P. SRIVASTAVA SR. MANAGER(CHEM.)
April 22, 2023 2
WATER CHEMISTRY IN POWER PLANT
WATER CHEMISTRY IS A VERY IMPORTANT
DISCIPLINE IN POWER SECTOR. TO ACHIEVE HIGHER OPERATION
EFFICIENCY AND TO REDUCE PLANT DOWNTIME, HIGH WATER QUALITY STANDARDS ARE TO BE MAINTAINED
April 22, 2023 3
WATER CHEMISTRY IN POWER PLANT
PRODUCTION OF : - --- D.M. WATER FOR BOILER MAKE-UP. --- FILTER WATER FOR SOFTENING PLANT, D.M. PLANT, DRINKING WATER AND A.C. COOLING SYSTEM. MONITORING OF STEAM/ WATER PARAMETERS H.P./L.P. DOSING. TESTING OF COAL. TESTING OF LUB OIL.
April 22, 2023 4
WATER CHEMISTRY IN POWER PLANT
CIRCULATING WATER TREATMENT POLLUTION MONITORING
– STACK MONITORING– AMBIENT AIR– WATER EFFLUENT
EFFLUENT TREATMENT PLANT COMMISSIONING ACTIVITES
April 22, 2023 5
WATER FLOW DIAGRAM
CLARIFLOCCULATOR
GRAVITY FILTER
D.M. PLANT
SOFTENING PLANT
COOLING WATER
U/G STORAGE TANK
RAW WATER
DRINKING WATER
BOILER MAKEUP
C.W. MAKEUP
April 22, 2023 6
D.M. PLANT
WEAKACIDCATION
STRONG ACID CATION
ACF
WEAKBASE ANION
STRONGBASE ANION
MIXED BED
DEGASSER
D.M. WATERSTORAGETANK
April 22, 2023 7
D.M. WATER QUALITY
pH - 7.0 ± 0.2 CONDUCTIVITY < 0.2 mho TDS - NIL SiO2 < 20 ppb
April 22, 2023 8
WATER STEAM CYCLE (GAS PROJECT)
D.M. WATER RFT CONDENSER D/A
LP TURBINE LP STEAM LP BOILER
HP TURBINE HP STEAM HP BOILER
L.P. DOSING
H.P. DOSING
HP BFP
LP BFP
April 22, 2023 9
WATER STEAM CYCLE (THERMAL PROJECT)
D.M. WATER CST CONDENSER D/A
TURBINE STEAM BOILER
T.S.P. DOSING
HYDRAZINE DOSING
BFP
AMMONIA DOSING
CEP
April 22, 2023 10
WATER/STEAM CHEMISTRY
PARAMETERS MONITORED– pH– Silica– Conductivity– After Cation Conductivity– Dissolved Oxygen– Sodium– Copper– Iron
April 22, 2023 11
WATER QUALITY
FEED WATER– ACC <0.2 uS/cm– pH 8.8-9.2– Total Iron+Copper <0.02 ppm– Silica <0.02 ppm– Dissolved Oxygen <7 ppb
April 22, 2023 12
WATER QUALITY
CONDENSATE WATER– ACC <0.2 uS/cm
– pH 8.8-9.2
– Silica <0.02 ppm
– Dissolved Oxygen <40 ppb
April 22, 2023 13
WATER QUALITY
BOILER WATER– Conductivity <30 uS/cm
– pH 9.2-9.6
– Silica <0.300 ppm
– Phosphate 2-4 ppm
April 22, 2023 14
WATER QUALITY
STEAM– ACC <0.2 uS/cm– pH 8.8-9.2– Total Iron+Copper <0.02 ppm– Silica <0.02 ppm– Sodium <10 ppb
April 22, 2023 15
DISTRIBUTION RATIO BETWEEN STEAM & BOILER WATER AT pH 9.5
Drum Pressure Silica in Boiler Water 194 Kg/Cm2 130 ppb176 Kg/Cm2 220 ppb159 Kg/Cm2 290 ppb 134 Kg/Cm2 500 ppb117 Kg/Cm2 1000 ppb100 Kg/Cm2 2220 ppb 65 Kg/Cm2 4000 ppb -- Boiller Drum Pressure is to be maintined as such,Silica value in Main Steam maintain bellow 20 ppb.
April 22, 2023 16
100
10-1
10-2
10-3
10-4
10-5
10-6
10-7
226 220 200 180 160 140 120 100 50 40 30
PRESSURE ( BAR)
PAR
TIT I
ON
CO
EFFI
CIE
NT
Kp
SiO2
NaOH
NaCl
PARTITION COEFFICIENT AT DIFFERENT PRESSURES
April 22, 2023 17
SOURCES OF IMPURITIES IN STEAM
By evaporation from the boiler drum By entrainment of boiler water droplets in
saturated steam. As impurity present in feed water used in
desuper heater spray.
April 22, 2023 18
EFFECTS OF SILICA
Silica has high partition coefficient, so it has tendency to deposit from steam onto turbine.
Silica can deposit on turbine blades specially on LP turbine, which can lead to significant loss of output.
April 22, 2023 19
H.P. DOSING
COORDINATED PHOSPHATE CONTROL
Na3PO4+H2O Na2HPO4 + NaOH
Na2HPO4+H2O NaH2PO4 + NaOH
NaOH + HCl (As Impurity) NaCl + H2O
April 22, 2023 20
L.P.DOSING
AMMONIA & HYDRAZINE HYDRATE DOSING
AMMONIA IS USED TO INCREASE THE pH OF THE SYSTEM AND HYDRAZINE IS USED TO REMOVE THE OXYGENN2H4 + O2 N2 + H2O3N2H4 4NH3 + N2
April 22, 2023 21
CHEMICAL CONTROL OF GENERATOR STATOR WATER COOLING CIRCUITS
GENERATOR STATOR COOLANT --- D.M. WATERSTATOR WATER PARAMETER TO BE MAINTAINED - pH 6.8 + .2 - K < 1.0 µs/cm - Copper < 50 PPb - D.O. < 10 PPb in low D.O. regime
2.0 to 5.0 PPM in high D.O. regime
April 22, 2023 22
CORROSION OF COPPER
There are two methods where the copper is
best passivated and minimum corrosion is found.
1. Low dissolved oxygen regime. 2. High dissolved oxygen regime.
April 22, 2023 23
LOW D.O. REGIME
- Limits below 10 PPb With low D.O. concentration, copper
corrosion is inhibited by a passive film of Cuprous Oxide(Cu2O).
April 22, 2023 24
HIGH D.O. REGIME
- Limits 2 to 5 PPM With high D.O. concentration, copper
corrosion is inhibited by a passive film of Cupric Oxide(CuO).
April 22, 2023 25