chemistry packet: chemical bonding - east … · web viewchemical bonding involves the valence...

46
Chemical Bonding Chemical Bonding Name__________________________________Period:______Date:____________ CHEMICAL BONDS & VALENCE ELECTRONS 1) __________________________= an interaction between atoms that holds them together by reducing the potential energy of their electrons 2) ____________________________= a shorthand representation of the composition of a substance using atomic symbols and numeric subscripts (Ex: NaCl, MgCl 2 , H 2 O, C 6 H 12 O 6 ) 3) Chemical bonding involves the valence electrons of the atoms involved in a___________________________. 4) _____________________________= the electrons available to be lost, gained, or shared in the formation of chemical bonds For atoms of main group elements, valance electrons are electrons in the _______________________ main energy level. Use of the periodic table to determine the number of valence electrons for atoms of the main group elements: Group Number of Valence Electrons 1 2 13 14 15 16 17 18 1

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Page 1: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

Chemical BondingChemical BondingName__________________________________Period:______Date:____________

CHEMICAL BONDS & VALENCE ELECTRONS1) __________________________= an interaction between atoms that holds them together

by reducing the potential energy of their electrons

2) ____________________________= a shorthand representation of the composition of a substance using atomic symbols and numeric subscripts (Ex: NaCl, MgCl2, H2O, C6H12O6)

3) Chemical bonding involves the valence electrons of the atoms involved in a___________________________.

4) _____________________________= the electrons available to be lost, gained, or shared in the formation of chemical bonds For atoms of main group elements, valance electrons are electrons in the

_______________________ main energy level. Use of the periodic table to determine the number of valence electrons for atoms

of the main group elements:

GroupNumber of Valence

Electrons12131415161718

______________________= a helium atom has ________valence electrons

Electron Configuration of oxygen:

1

Page 2: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

5) In the Lewis electron-dot formulas for atoms of main group elements, valence electrons are represented by _________that surround an element’s symbol.

6) Examples of Lewis electron-dot formulas for atoms of the main group elements:

DETERMINING BOND TYPE

2

Page 3: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

+ -

1) __________________= a chemical bond resulting from ________________________________between positive and negative ions

a) In a purely ionic bond, one or more electrons are transferred from one atom to another

2) _______________________= a chemical bond resulting from the___________ of electrons between two atoms

a) ___________________= a covalent bond in which the bonding electrons are ______________________ by the bonded atoms

b) ______________________= a covalent bond in which the bonding electrons are ___________________ by the bonded atoms

3) Chemical bonds between two unlike atoms are NEVER completely ionic and RARELY completely covalent. Bonds can be anywhere in the range between these two extremes, depending upon how strongly the bonded atoms attract electrons.

4) _______________________= a measure of the ability of an atom in a chemical compound to attract electrons

3

Page 4: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

5) The degree to which bonds are ionic or covalent can be ___________________ by comparing the electronegativities of the bonded atoms.

6) The electronegativity difference of two atoms can be used to determine the ionic character of a bond.

Only ___________________values are used for the final electronegativity

7) The scale below can be used to classify the probable bond type between two atoms.

a) If the electronegativity difference between two atoms is: _________________the probable bond type is usually classified

as___________________________.

______________________the probable bond type is usually classified as_______________________.

_____________________the probable bond type is usually classified as __________________.

8) Polar covalent bonds, a closer look: a) In a polar covalent bond electrons are________________________.

b) Shared electrons spend MORE of their time near the atom with the _____________________ electronegativity.

c) __________________________ (+ or -) result.

A - is assigned to the atom with the ________________electronegativity

A + is assigned to the atom with the ________________electronegativity

d) Ex: An H atom and a Cl atom form a polar-covalent bond resulting in partial charges.

9) Determine the electronegativity difference and probable bond type with respect to bonds formed between the following pairs of atoms. Assign partial charges if the probable bond type is polar-covalent.

Pair of Atoms

Electronegativity Difference

Probable Bond Type Partial Charges

4

Page 5: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

S and H

S and Cs

I and I

Cl and Br

S and Cl

Br and F

IONIC BONDING AND IONIC COMPOUNDS1) Characteristics of ionic compounds:

a) Ionic compounds are held together by____________________________.

b) Ionic compounds usually involve__________________________________.

c) Ionic compounds are _____________under normal conditions.

d) Ionic compounds consist of a very large number of positive and negative ions (anions and cations) that are combined so that the numbers of positive and negative charges are________________.

e) The chemical formula for an ionic compound represents a formula unit, NOT a____________________________.

2) An ionic compound is __________composed of independent, neutral units that can be isolated and examined.

3) ____________________= a compound of positive and negative ions (anions and cations) that are combined so that the numbers of positive and negative charges are equal

4) The chemical formula of an ionic compound shows the _______of ions present in a sample of any size.

5

Page 6: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

a) Ex: magnesium chloride has the following chemical formula: MgCl2 For every one Mg+2 ion present, two Cl ions are present. If 13 mol Mg+2 ions are present in a sample, then 26 mol Cl ions are present in

the sample.

5) The chemical formula for an ionic compound represents a formula unit, NOT a molecule.

6) __________________= the simplest collection of ions from which an ionic compound’s formula can be established

7) __________________= chemical compounds tend to form so that each atom (by gaining, losing, or sharing electrons) contains eight electrons in its outermost occupied main energy level (valence electrons)

8) Electron-dot formulas can be used to illustrate the formation of_________________.

a) Use electron-dot formulas to illustrate the formation of ionic bonds involving Na and Cl.

Ionic Formula = ________________

b) Use electron-dot formulas to illustrate the formation of ionic bonds involving Ca and F.

Ionic Formula = ________________

c) Use electron-dot formulas to illustrate the formation of ionic bonds involving K and O.

Ionic Formula = ________________6

Page 7: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

COVALENT BONDING & MOLECULAR SUBSTANCES

1) Characteristics of molecular substances:

a) Molecular substances are held together by___________________________.

b) Molecular substances usually involve ONLY ____________________.

c) Molecular substances may be ______________________________under normal conditions.

d) Molecular substances consist of_______________________. The_________ of different molecules varies greatly.

2) _______________________= a chemical compound whose simplest units are molecules

3) __________________= a neutral group of atoms held to together by ______________________________

a) A single molecule is an individual unit capable of existing on its own.

4) The chemical formula for a molecular compound is called a_________________.

5) _______________________________= a shorthand representation showing the types and numbers of atoms combined in a single molecule

a) Ex: hydrogen peroxide; H2O2;________ atoms of hydrogen and _______ atoms of oxygen are held together by covalent bonds

b) Ex: glucose; C6H12O6; 6 atoms of carbon, 12 atoms of hydrogen, and 6 atoms of oxygen are held together by __________________

6) _______________________= a molecule containing only two atomsa) Ex: HCl, O2

7) Certain elements occur naturally as diatomic molecules (you need to know these elements!!)

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Page 8: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

a) They are: H2, O2, N2, Cl2, Br2, I2, and F2

INTERMOLECULAR FORCES (IM FORCES)1) __________________________________________(IM Forces) = forces of attraction between

adjacent particles (molecules, atoms, or ions)

a) Generally much _________________ than ionic or covalent bonds

b) The example below shows two HCl molecules. The force of attraction that exists between the two molecules is an intermolecular force.

c) IM forces are ____________significant in solids and liquids than in gases because the particles are much closer together in solids and liquids.

d) IM _______________are responsible for many properties of compounds such as melting point and boiling point, surface tension, and viscosity.

Strong IM forces = ___________melting points & boiling pointsoEx: ______________compoundsoRequires_______________energy (higher temp.) to break strong IM

forces between particles

Weaker IM forces = __________melting points & boiling points

oEx: ____________________compounds

oRequires ________________energy (lower temp.) to break weak IM forces between particles

LEWIS ELECTRON-DOT FORMULAS AND LEWIS STRUCTURAL FORMULAS

1) Lewis electron-dot formulas illustrate the sharing of ________________________ between atoms.

2) Electron pairs:

a) _________________= an electron pair NOT involved in bonding

b) ______________= an electron pair shared between two atoms

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Page 9: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

3) Types of covalent bonds:a) ________________________= a covalent bond produced by the sharing of one pair of

electrons between two atoms Ex: H—H or H : H

b) ________________________= a covalent bond produced by the sharing of two pairs of electrons between two atoms

Ex: O2

c) ____________________= a covalent bond produced by the sharing of three pairs of electrons between two atoms Ex: N2

d) In general, _________________are _________________and ____________than single bonds.

e) In general, __________________are shorter and stronger than___________________.

4) Guide for Writing Lewis Electron-Dot Formulas for Molecules:

a) Count the ___________number of valence electrons in the molecule. THESE ARE ALL THE ELECTRONS YOU MAY USE!

b) Identify the central atom and terminal atoms:

H is always a terminal atom C, if present is usually the _____________atom Molecules tend to be somewhat symmetrical (if one atom is different than the

others it is usually the central atom)

c) Place _____________of electrons between each pair of bonded atoms to form a____________________.

With six valence electrons each, two oxygen atoms can use twelve electrons to satisfy both octets. By sharing one electron from each oxygen, we can't have more than one oxygen's octet satisfied. We'll need to try a different sharing pattern; a double bond will work.

With five valence electrons each, two nitrogen atoms can use ten electrons to satisfy both octets. By sharing one electron from each nitrogen, we can't have either nitrogen's octet satisfied. We'll need to try a different sharing pattern; a triple bond will work.

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Page 10: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

d) Add electron pairs around the _____________________to satisfy the octet rule for the terminal atoms. THERE ARE EXCEPTIONS TO THE OCTET RULE! (see below)

e) Assign left over electron pairs to the ___________________________.

f) Orient atoms so there is _______________ electron pair repulsions around the central atom. (arrange electron pairs as far apart as you can)

g) If the central atom has LESS than an octet of electrons, then move one or more lone pairs from the _________________atoms to form multiple bonds (double and triple bonds). oxygen, nitrogen and carbon CAN form ___________________.

h) DO THE FOLLOWING FINAL CHECKS: Check that the total number of valence electrons in the molecule is correct. Check that the octet rule is satisfied for all atoms. DON’T FORGET ABOUT

THE EXCEPTIONS.5) EXCEPTIONS to the octet rule:

a) _____________________is an exception to the octet rule. In a molecule, hydrogen contains ________electrons in its outermost occupied main energy level. HYDROGEN CAN FORM ONLY A SINGLE BOND AND WILL CONTAIN NO LONE PAIRS!

b) ________________and _______________are SOMETIMES exceptions to the octet rule. These atoms sometimes contain less than eight electrons in their outermost occupied main energy level. Remembering that these atoms DO NOT form double and triple bonds will be helpful when determining if they break the octet rule.

6) Guide for Writing Lewis Structural Formulas for Molecules and Polyatomic Ions:

a) Follow all guides from above except write a __________to indicate every bond pair.

b) __________are still used to represent_________________.

7) Guide for Writing Lewis Electron-Dot Formulas for Polyatomic Ions:

a) Follow the guide from above except:

Add a ____________and _______________to the electron-dot and structural formulas

Account for ______________when counting valence electrons A POSITIVE CHARGE indicates you have to _____________electron(s)

o Ex: H3O +1 has ____ valence electrons:

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Page 11: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

___________________________________________________

O= _______________

H3 = _____________

So now there is _______ and you subtract ______since the ion has a _____charge to get the final total of ___ valence electrons

o Ex: NH4 +1

A NEGATIVE CHARGE indicates you have to _________electron(s)o Ex: CO3-2 has _____valence electrons

C= ________________________

O3 = ________________________

So now there is ________and you add _____since the ion has a _____charge to get the final total of _____valence electrons

THE VALENCE SHELL ELECTRON PAIR REPULSION (VSEPR) MODEL

1) The _____________________has proven useful in predicting molecular geometry and bond angles.

2) The VSEPR model assumes that atoms will orient themselves so as to ___________electron pair repulsions around the central atom.

3) Steps to determine molecular geometry and bond angles:

a) Draw an electron-dot formula.

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Page 12: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

b) Arrange the electron pairs around the central atom in a way that minimizes repulsion. In other words, put the electron pairs as far apart as possible.

c) Determine molecular geometry:

d) Predict the bond angles from the molecular geometry.

Molecular Geometry

Atoms Bonded

to Central Atom

Lone Pairs

Around the

Central Atom

Predicted Bond

AnglesExample

2 0BeF2

3 0

BeF3

3 1

NH3

2 1

SnCl2

2 2 H2O12

Page 13: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

4 0

CH4

e) Notice the bond angle distortion for molecules with a molecular geometry of _____________________and ___________(with_____________________).

Ex: O3 is considered bent with a predicted bond angle of 120º since there is only 1 lone pair of electrons

Ex: H2O is considered bent with a predicted bond angle of 105 since there is 2 lone pairs of electrons

VSEPR model assumes that _______________require more room than bond pairs and tend to compress the angles between bond pairs.

In general, bond angles of at least _______________provide enough room for lone pairs that significant bond angle distortion does NOT occur.

Using The Modeling Kits: Easily shows molecular geometry

A wooden peg represents a single bond (one bond pair of electrons)

Use longer pegs first, then if needed use smaller pegs

A spring represents a multiple bond

A colored wooden ball represents various atoms

When writing dot formulas and structural formulas you still will have to account for lone pair(s) of electrons since models do not account for lone pair(s)

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Page 14: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

Does the molecule have any polar covalent bonds?

2. Is the electronegativity of all terminal atoms the same?NO

The molecule is NONPOLAR

YES

The molecule is POLAR

3. Is the molecule “symmetrical”?(Lone pairs on central atom means molecule is NOT symmetrical)

YESNO

NOThe molecule is POLAR

The molecule is NONPOLAR

YES

POLAR vs. NONPOLAR MOLECULES1) Use the following chart to determine if a molecule is polar or

nonpolar.

Note: if the molecule only contains 2 atoms,

stop after the first question.

Modeling Kit Color Code:PurplePurple = iodine or fluorine = iodine or fluorine BlackBlack = carbon = carbonRedRed = oxygen = oxygen GreenGreen = chlorine = chlorineOrangeOrange = bromine = bromine YellowYellow = = hydrogenhydrogenLight BlueLight Blue = nitrogen = nitrogen

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Page 15: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

Complete the following tables on pg 16-18 as a class.

BF3

BeF2

CH3 I

ICl

Formula

# of Valence

ElectronsLewis Electron-Dot Form

ulaLewis Structural Form

ulaM

olecular Geom

etry

NA

Predicted Bond Angles

15

Page 16: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

Polar or Nonpolar?

H2 O

NH

3

H2 CO

CO2

Formula

# of Valence

ElectronsLewis Electron-Dot Form

ulaLewis Structural Form

ulaM

olecular Geom

etryPredicted Bond Angles

16

Page 17: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

Polar or Nonpolar?

N2

NH

4 +

SO4

2

SO2

Formula

# of ValenceElectron

sLewis Electron-Dot Form

ulaLewis Structural Form

ulaM

olecular Geom

etry

NA

Predicted Bond Angles

17

Page 18: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

NA NA

Polar or Nonpolar

?

Valence Electrons & Lewis Electron-Dot Notation Worksheet

1) Where are valance electrons located?______________________________2) Why are valence electrons important?

3) Determine the number of valence electrons in one atom of each of the following elements. Then write the electron-dot notation for each element.

a) Na

b) F

c) Rb

d) Ba

e) I

f) Se

g) Al

h) C

i) Mg

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Page 19: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

j) HeElectronegativity & Probable Bond Type Worksheet

1) When predicting probable bond types, list the ranges for the following:

a. Non-polar covalent =______________________________b. Polar-covalent = __________________________________c. Ionic = __________________________________________

2) Define ionic bond.

3) What is the difference between polar-covalent and non-polar covalent bond types?

4) A - is assigned to the atom with the (higher or lower) electronegativity.5) Determine the electronegativity difference and probable bond type with respect to bonds

formed between the following pairs of atoms. Assign partial charges if the probable bond type is polar-covalent.

Pair of Atoms Electronegativity Difference Probable Bond

TypePartial Charges (if

polar-covalent)H and H

S and O

H and I

K and Br

Si and Cl

H and F

Se and S

C and H

Na and Cl

O and H

N and N

19

Page 20: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

I and Cl

Ionic Bonding & Ionic Compounds Worksheet1) Ionic compounds usually have what type of elements present?

2) Ionic compounds are ___________________________ under normal conditions.3) Molecular compounds usually have what type of elements present?

4) Molecular compounds are ________________________under normal conditions.5) Use electron-dot formulas to illustrate the formation of ionic bonds involving Li

and Cl.Ionic Formula = ________________

6) Use electron-dot formulas to illustrate the formation of ionic bonds involving Ca and I.

Ionic Formula = ________________

7) Use electron-dot formulas to illustrate the formation of ionic bonds involving K and F.

Ionic Formula = ________________

8) Use electron-dot formulas to illustrate the formation of ionic bonds involving Mg and Br.

Ionic Formula = ________________

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Page 21: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

9) Use electron-dot formulas to illustrate the formation of ionic bonds involving Al and I.

Ionic Formula = ________________

10) Use electron-dot formulas to illustrate the formation of ionic bonds involving Ca and O.

Ionic Formula = ________________

11) Use electron-dot formulas to illustrate the formation of ionic bonds involving Na and S.

Ionic Formula = ________________

12) Use electron-dot formulas to illustrate the formation of ionic bonds involving Al and S.

Ionic Formula = ________________

Complete the following table.

21

Page 22: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

H2 BF

BF4

O3

NO

2 +

Formula

Number

of ValenceElectron

s

Lewis Electron-Dot Formula

Lewis Structural Formula

Molecular

Geometry

Predicted Bond Angles

NA NA

Polar or Nonpolar?

22

Page 23: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

HCl

NO

2

CH4

BeCl2

Formula

Number

of ValenceElectron

s

Lewis Electron-Dot Formula

Lewis Structural Formula

Molecular

Geometry

NA

Predicted Bond Angles

NA

Polar or Nonpolar

?

23

Page 24: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

CCl4

NF

3

CHCl3

Cl2 CO

Formula

Number

of ValenceElectron

s

Lewis Electron-Dot Formula

Lewis Structural Formula

Molecular

Geometry

Predicted Bond Angles

Polar or Nonpolar

?

24

Page 25: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

SiO2

H2 Te

CHI3

H2

Formula

Number

of ValenceElectron

s

Lewis Electron-Dot Formula

Lewis Structural Formula

Molecular

Geometry

NA

Predicted Bond Angles

Polar or Nonpolar

?

25

Page 26: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

PH3

ClO

HCN

H2 S

Formula

Number

of ValenceElectron

s

Lewis Electron-Dot Formula

Lewis Structural Formula

Molecular

Geometry

NA

Predicted Bond Angles

NA

Polar or Nonpolar

?

26

Page 27: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

OF

2

PCl3

HClO

ClO2

Formula

Number

of ValenceElectron

s

Lewis Electron-Dot Formula

Lewis Structural Formula

Molecular

Geometry

Predicted Bond Angles

NA

Polar or Nonpolar

?

27

Page 28: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

SCl2

CF4

I2

H3 O

+

Formula

Number

of ValenceElectron

s

Lewis Electron-Dot Formula

Lewis Structural Formula

Molecular

Geometry

NA

Predicted Bond Angles

NA

Polar or Nonpolar

?

28

Page 29: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

SiCl3 Br

NH

2 Cl

Cl2 O

NCl3

Formula

Number

of ValenceElectron

s

Lewis Electron-Dot Formula

Lewis Structural Formula

Molecular

Geometry

Predicted Bond Angles

Polar or Nonpolar

?

29

Page 30: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

SCN

SO4

2

NO

3

ON

Cl

Formula

Number

of ValenceElectron

s

Lewis Electron-Dot Formula

Lewis Structural Formula

Molecular

Geometry

Predicted Bond Angles

NA NA NA

Polar or Nonpolar

?

30

Page 31: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

6. Describe the IM forces.

5. Describe the melting points

and boiling points.

4. What type of bond is holding

the atoms together? Explain

how atom

s are held together by this type of bonding?

3. This type of compound can be

described as a collection of ________?

2. Under ordinary conditions, in

what state of m

atter w

ould you find this com

pound?

1. What type(s) of elem

ents are usually contained in this type of

compound?

Ionic Compounds vs. M

olecular Compounds

Ionic Compounds vs. M

olecular Compounds

ION

IC COM

POU

ND

SIO

NIC CO

MPO

UN

DS

MO

LECULAR

MO

LECULAR

31

Page 32: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

Bonding Basics WorksheetBonding Basics WorksheetVocabulary: Use your notes to help you identify the following vocabulary.

1) A __________________________________is a covalent bond produced by the sharing of two pairs of electrons between two atoms

2) ____________________________is a measure of the ability of an atom in a chemical compound to attract electrons

3) _________________________ is a chemical bond resulting from electrostatic attraction between positive & negative ions

4) A _________________ is a neutral group of atoms held to together by covalent bonds

5) __________________________ is a chemical bond resulting from the sharing of electrons between two atoms

6) A _____________________________ is a covalent bond produced by the sharing of three pairs of electrons between two atoms

7) ___________________________ is a covalent bond in which the bonding electrons are shared unequally by the bonded atoms

8) A _________________________is a molecule containing only two atoms

9) _______________________________ is an electron pair shared between two atoms

10) _____________________________________________ is an interaction between atoms that holds them together by reducing the potential energy of their electrons

11) __________________________________________________is the simplest collection of ions from which an ionic compound’s formula can be established

12) ___________________________________________is a shorthand representation of the composition of a substance using atomic symbols and numeric subscripts (Ex: NaCl, MgCl2, H2O, C6H12O6)

13) _________________________________________ is the tendency of compounds to form so that each atom (by gaining, losing, or sharing electrons) contains eight electrons in its outermost occupied main energy level (valence electrons)

14) A __________________________________is a chemical compound whose simplest units are molecules

15) _____________________________ is the outermost electrons available to be lost, gained, or shared in the formation of chemical bonds

16) __________________________________________ is an electron pair NOT involved in bonding

17) ___________________________________ is a covalent bond in which the bonding electrons are shared equally by the bonded atoms

18) ____________________________________________ are forces of attraction between adjacent particles (molecules, atoms, or ions)

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Page 33: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

Concepts: Answer the following questions.

1. When predicting probable bond types, list the ranges for the following:

d. Non-polar covalent =______________________________

e. Polar-covalent = __________________________________

f. Ionic = __________________________________________

2. Which atom is assigned the partial negative charge when a polar covalent bond is established?

3. Ionic compounds contain what type of elements?_____________________________________

4. What phase(s) of matter would you most likely find ionic compounds? _______________________

5. Molecular substances usually involve only what type of elements? __________________________

6. What phase(s) of matter would you most likely find molecular compounds? _____________________

7. List the naturally occurring diatomic molecules.

________________________________________________________________

8. In terms of IM forces, describe melting points and boiling points of ionic and molecular compounds?

9. Use electron dot formulas to illustrate the formation of ionic bonds involving Li and N.

Ionic Formula = ________________

10. Use electron dot formulas to illustrate the formation of ionic bonds involving Na and O.

Ionic Formula = ________________

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Page 34: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

Dot & Structural Formulas: For each of the following formulas determine the number of valence electrons and draw the electron dot formula and structural formula.

Formula

Number of

Valence Electrons

Lewis Electron Dot Formula

Lewis Structural Formula

CO

SeF2

NCl3

BeCl2

HCN

34

Page 35: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

Dot & Structural Formulas: For each of the following formulas determine the number of valence electrons and draw the electron dot formula and structural formula.

Formula

Number of

Valence Electrons

Lewis Electron Dot Formula

Lewis Structural Formula

PH3

SO3

CS2

CH2O

SiCl4

(silicon

tetrachloride)

35

Page 36: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

BONDING REVIEW WORKSHEET1) What are valance electrons?

a. Where are valance electrons found?

2) What is an ionic bond?

3) What is the difference between a non-polar covalent bond and a polar-covalent bond?

4) What is electronegativity?

5) When predicting probable bond types, list the ranges for the following:

a. Non-polar covalent =______________________________

b. Polar-covalent = __________________________________

c. Ionic = __________________________________________

6) Which atom is assigned the partial negative charge?

7) Ionic compounds contain what type of elements? _________________________________

8) What phase(s) of matter would you most likely find ionic compounds?___________________

9) What is the octet rule?

10) Molecular substances usually involve only what type of elements?__________________

11) What phase(s) of matter would you most likely find molecular compounds?

12) What are diatomic molecules? List the naturally occurring diatomic molecules.36

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13) What is the difference between lone pair electrons and bond pair electrons?

14) What are the exceptions to the octet rule when constructing electron dot formulas?

15) What needs to be added to the electron dot and structural formulas for polyatomic ions? __________________________ & ______________________________

16) List the 6 types of molecular geometry that a compound may exhibit and the predicted bond angle.

17) Use electron dot formulas to illustrate the formation of ionic bonds involving Ca and Cl.

Ionic Formula = ________________

18) Use electron dot formulas to illustrate the formation of ionic bonds involving K and O.

Ionic Formula = ________________

19) What is the difference between the melting and boiling points of ionic and molecular compounds?

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Unit Learning Map (10 days): Bonding Mrs. Hostetter

Class: Academic Chemistry A - Grade 11

Unit Essential Question(s): OptionalInstructional Tools:

Guided NotesLab Materials:

Ionic vs. Molecular Compound Lab

Modeling Lab

Why is one atom rarely found by itself in nature?

Chemical Bonds Bond Types Electron Dot and Structural Formulas

VSEPR Model

Why do chemical bonds form?

How do you determine probably bond type?

How can molecules and polyatomic ions be represented using electron dot and structural formulas?

How can the VSEPR model be used to predict molecular geometry and bond angles?

Chemical bondChemical formulaValence electrons

Ionic bondsCovalent bondNonpolar-covalent bondPolar-covalent bondElectronegativityIonic compoundFormula unitOctet ruleMolecular compoundMoleculeMolecular formulaDiatomic moleculeIntermolecular Forces

Lone pair electronsBond pair electronsSingle bondDouble bondTriple bondCentral atomDot formulaStructural formula

VSEPR ModelMolecular geometryBond anglesLinear Trigonal planarBentTetrahedralTrigonal PyramidalIsomer

Vocabulary: Vocabulary: Vocabulary: Vocabulary:

Lesson Essential Questions: Lesson Essential Questions: Lesson Essential Questions: Lesson Essential Questions:

Concept Concept Concept Concept

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Page 39: Chemistry Packet: Chemical Bonding - East … · Web viewChemical bonding involves the valence electrons of the atoms involved in a_____. _____ = the electrons available to be lost,

Bonding Vocabulary:1) Chemical bond - an interaction between atoms that holds them together by reducing the potential energy of

their electrons2) Chemical formula - a shorthand representation of the composition of a substance using atomic symbols and

numeric subscripts (Ex: NaCl, MgCl2, H2O, C6H12O6)3) Valence electrons - the outermost electrons available to be lost, gained, or shared in the formation of

chemical bonds4) Ionic bonds - a chemical bond resulting from electrostatic attraction between positive & negative ions5) Covalent bonds - a chemical bond resulting from the sharing of electrons between two atoms6) Nonpolar-covalent bond - a covalent bond in which the bonding electrons are shared equally by the bonded

atoms7) Polar-covalent bond - a covalent bond in which the bonding electrons are shared unequally by the bonded

atoms8) Electronegativity - a measure of the ability of an atom in a chemical compound to attract electrons9) Ionic compound - a compound of positive and negative ions (anions and cations) that are combined so that

the numbers of positive and negative charges are equal10) Formula unit - the simplest collection of ions from which an ionic compound’s formula can be established11) Octet rule - chemical compounds tend to form so that each atom (by gaining, losing, or sharing electrons)

contains eight electrons in its outermost occupied main energy level (valence electrons)12) Molecular compound - a chemical compound whose simplest units are molecules13) Molecule - a neutral group of atoms held to together by covalent bonds14) Molecular formula - a shorthand representation showing the types and numbers of atoms combined in a

single molecule15) Diatomic molecule - a molecule containing only two atoms (Natural = H2,O2, N2, Cl2, Br2, I2, F2)16) Intermolecular forces (IM Forces) = forces of attraction between adjacent particles (molecules, atoms, or

ions)17) Lone pair electrons - an electron pair NOT involved in bonding18) Bond pair electrons - an electron pair shared between two atoms19) Single bond - a covalent bond produced by the sharing of one pair of electrons between two atoms20) Double bond - a covalent bond produced by the sharing of two pairs of electrons between two atoms21) Triple bond- a covalent bond produced by the sharing of three pairs of electrons between two atoms22) Central atom - atom in the center of the compound, often carbon23) Dot formula - when dots are used to show bond pairs and lone pairs 24) VSEPR Model- ( Valence Shell Electron Pair Repulsion Model) has proven useful in predicting molecular

geometry and bond angles25) Molecular geometry- Linear, Trigonal planer, Bent, Tetrahedral, Trigonal pyramidal, and Bent26) Bond angles - angle at which the bond takes place27) Linear - 2 atoms bonded to central angle and predicted bond angles is 180°28) Trigonal planar - 3 atoms bonded to central angle and predicted bond angles is 120°29) Bent -2 atoms bonded to central angle,1 lone pair around the central atom;predicted bond angle is 120°30) Bent - 2 atoms bonded to central angle, 2 lone pairs around central atom; predicted bond angle is 105°31) Tetrahedral - 4 atoms bonded to central angle; predicted bond angle is 109.5°32) Trigonal Pyramidal - 3 atoms bonded to central angle, 1 lone pair around central atom; predicted bond

angle is 107°33) Isomer = Compounds that have the same molecular formula, but different structural formula.

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