chemistry session plan
TRANSCRIPT
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Session 1Session Name:pH-Metry in Chemical
AnalysisAuthor Name: Z. D. Sande
Department: General EngineeringSubject/Course: Engineering Chemistry
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Session Objectives
At the end of this session, the learner will be able to:
List the advantages and disadvantages of instrumental methods ofchemical analysis.
Explain the importance of pH-metry in engineering applications.
Draw the Glass electrode for measurement of pH of any kind of solution.
Explain the construction and working of glass electrode.
Describe equation of pH using glass electrode.
Teaching Learning Material
White Board and Markers
Presentation
LCD Projector
Instrumental Methods of Chemical AnalysisPage 2 Ver : 1.01 Mr. Z. D. Sande Annasaheb Dange College of Engg. & Tech., Ashta
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Session Plan
Time
(in min) Content
Learning Aid and
Methodology
Faculty
Approach
Typical Student
Activity
Learning Outcomes
(Blooms +Gardeners)
10
Introduction toinstrumental methodsof chemical analysis,its advantages anddisadvantages
Questions andAnswers,
ExplainsFacilitates
ListensParticipates
Remembering
IntrapersonalVerbalLinguistic
10Importance of pH-metry in engineeringapplications
Brainstorming ExplainsFacilitates
ListensParticipates
Understanding
IntrapersonalLinguistic
10
Glass electrode, itsprinciple andconstruction withdiagram
PPT/ Charts Explains,Questions,Facilitates
Listens,Answers,Participates
Understand
Visual, Linguistic
05
Working of glasselectrode
Group Task ExplainsFacilitates
ListensParticipates
Apply
Visual, Linguistic
10Derivation ofequation of pH usingglass electrode
Board Activity Questions,Explains
Answers,Listens
UnderstandingVisualLogical
15 Conclusion
CrosswordPuzzle(using notes-stickers)
ExplainsFacilitates
ListensParticipatesAnswers
AnalyzingInterpersonalVerbal LinguisticKinesthetic
Please maintain the flow of the session by explaining the contentin such a way that one topic should be followed by the other topic.Give proper explanation of why the current topic is explained afterthe previous topic throughout the session.
Session Inputs
Instrumental Methods of Chemical AnalysisPage 3 Ver : 1.01 Mr. Z. D. Sande Annasaheb Dange College of Engg. & Tech., Ashta
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Introduction to Instrumental Methods Of ChemicalAnalysis
Learners would have some basic knowledge about chemical analysis and itstypes. Therefore, we can conduct a question-answer activity to bring outthe advantages and disadvantages of instrumental methods.
Suggested Activity: Questioning
We can ask the following simple questions to the learners.1. What do you mean by chemical analysis?2. What do you mean by instrumental methods?3. Which is the best method of chemical analysis?4. Why instrumental methods are more advantageous than non-instrumental methods?5. Tell advantageous and disadvantages of instrumental methods?
Learners may give various answers. We can write these on the board, and discuss andanalyze the answers with the help of suitable examples.
Answers to these questions are like this:1. Chemical analysis deals with finding composition of a material.2. Chemical analysis in which instruments are used.
3. Instrumental methods4. Due to their accuracy, reliability, sensitivity, faster, use for complex
materials or mixtures, etc.5. Advantages: accuracy, sensitivity, reliability, faster, use for
complex materials or mixtures,not affected by oxidation-reductionpotential of solution, etc.
Disadvantages: Require skill/training, standardize/ calibrate,much costly, sensitivity/ accuracy depends on instrument.
Dear students, it is now clear that instrumental methods of
chemical analysis are more advantageous than non-instrumental or regular methods. Now, let us learn one of themost important and best methods of analyzing, which is pH-Metry.
Instrumental Methods of Chemical AnalysisPage 4 Ver : 1.01 Mr. Z. D. Sande Annasaheb Dange College of Engg. & Tech., Ashta
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Importance of pH-metry in engineering applications:
Suggested Activity: BrainstormingAs the students have some basic knowledge about this topic, the classcan be divided into 4-5 groups, and each group needs to brainstorm theother group. One representative from each group can share their findings,and the answers can be written on the board in short. The incorrectanswers can be cancelled out, and the faculty can explain the correctanswers in detail.
PH metry is technic used to analyze materials by measuring pHwith the help of instrument pH meter.pH metry is useful in various engineering applications, such as:
i) Effluent treatmentii) Water testingiii) Corrosion monitoringiv) Quality Controlv) City water supplyvi) Scale formation in boilers
Glass electrode, its principle, construction and working
Please explain the principle, construction and working
Suggested Activity: Observe and Answer
Faculty can show the slides or charts containing such diagrams one byone. After each slide he can ask the names of different parts of the
diagram with their definitions, which they know.
Instrumental Methods of Chemical AnalysisPage 5 Ver : 1.01 Mr. Z. D. Sande Annasaheb Dange College of Engg. & Tech., Ashta
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fig.(a)
fig.(b)
Instrumental Methods of Chemical AnalysisPage 6 Ver : 1.01 Mr. Z. D. Sande Annasaheb Dange College of Engg. & Tech., Ashta
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fig.(c)
fig.(d)
Please explain all the block diagrams in detail for betterunderstanding.
Instrumental Methods of Chemical AnalysisPage 7 Ver : 1.01 Mr. Z. D. Sande Annasaheb Dange College of Engg. & Tech., Ashta
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Derivation of equation of pH using glass electrode
Suggested Activity: QuestioningFaculty can ask questions to the students at each step on the basis of
their previous knowledge.
The formula for emf of a cell is:Ecell =ER EL
For given cell this formula is:
= ESCE - EGWhere, EG is emf of Glass Electrode. Now,using Nernst equationfor glass electrode,
= ESCE - {EG0- 2.303RT/nF log [H+]}
At 298 K eqn becomes as,= ESCE - {E
0- 0.0591 log [H+]}But, -log [H+]= pH, Hence,
= ESCE - {E0 + 0.0591 pH}
Ecell = ESCE - EG0 - 0.0591 pH
But ESCE = 0.2422 V & EG0 is known for glass
electrode.
Ecell = 0.2422 - EG0
- 0.0591 pH
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Conclusion
Faculty is supposed to write questions on different stickers with numbers 1 to
8 and stick on white board.Selected students at the end of session can be called one by one and asked totake any one sticker and find the answer and write on big card sheetcontaining cross-word puzzle.
Suggested Activity: Crossword Puzzle
Faculty can writequestions related to following answers on card sheets:
1. ELECTRODE2. CALOMEL
3. PLATINUM4. ETHANOL5. OPERATE6. EFFLUENTS7. BUFFER8. TWO
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2 6 8
1
3
5
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SummaryIn this session, we learnt to:
List advantages and disadvantages of Instrumental Methods of ChemicalAnalysis
Compare Instrumental Methods with Non-instrumental methods
Draw glass electrode for measurement of pH of any kind of solution
Explain construction and working of glass electrode
Derive equation of pH using glass electrode
Instrumental Methods of Chemical AnalysisPage 10 Ver : 1.01 Mr. Z. D. Sande Annasaheb Dange College of Engg. & Tech., Ashta
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Assignment
1. Draw the diagram of glass electrode used in pH-metry.
2. Explain construction and working of glass electrode.3. How will you derive equation of pH using glass electrode.
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References
Instrumental methods Chatwal and Anand
http://en.wikipedia.org/wiki/Glass_electrode
http://www.google.co.in/images
Instrumental Methods of Chemical AnalysisPage 12 Ver : 1.01 Mr. Z. D. Sande Annasaheb Dange College of Engg. & Tech., Ashta
http://en.wikipedia.org/wiki/Glass_electrodehttp://www.google.co.in/imageshttp://en.wikipedia.org/wiki/Glass_electrodehttp://www.google.co.in/images