comparison of partial discharges in sf6 and … properties • high dielectric strength (2 x air)...

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Comparison of Partial Discharges in SF 6 and Fluoronitrile/CO2 Gas Mixtures Boya ZHANG, Yang CAO University of Connecticut, USA Nenad UZELAC G&W Electric Company, USA 1

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Page 1: Comparison of Partial Discharges in SF6 and … properties • High dielectric strength (2 x air) • Nontoxic, nonflammable, noncorrosive • Excellent arc extinction • Excellent

Comparison of Partial Discharges in SF6 and Fluoronitrile/CO2 Gas

Mixtures

Boya ZHANG, Yang CAOUniversity of Connecticut, USA

Nenad UZELACG&W Electric Company, USA

1

Page 2: Comparison of Partial Discharges in SF6 and … properties • High dielectric strength (2 x air) • Nontoxic, nonflammable, noncorrosive • Excellent arc extinction • Excellent

Agenda

1. Background2. Fluoronitrile gas3. Setup and test procedure4. Results and analysis5. Summary

2

Page 3: Comparison of Partial Discharges in SF6 and … properties • High dielectric strength (2 x air) • Nontoxic, nonflammable, noncorrosive • Excellent arc extinction • Excellent

1. Background

3

• SF6 has been used successfullyfor decades in the power industry.

• One big shortcoming – has ahigh global warming potential(23,500)

• Included in Kyoto Protocol (1997)on the list to be limited.

Global annual SF6 emissions from electrical equipmentare reported by ECOFYS: 1,600 t to 2,800 t SF6. Thatequals to 37,600 kt to 65,800 kt CO2!

Page 4: Comparison of Partial Discharges in SF6 and … properties • High dielectric strength (2 x air) • Nontoxic, nonflammable, noncorrosive • Excellent arc extinction • Excellent

1. Background

4

Failures in the switchgear due to long-term PDs.

• Since 1997, lots of effort to find alternative to SF6

• Proved to be hard task due to unique SF6 properties

• High dielectric strength (2 x air)

• Nontoxic, nonflammable, noncorrosive

• Excellent arc extinction

• Excellent thermal conductivity

• Chemically stable (good material compatibility)

Page 5: Comparison of Partial Discharges in SF6 and … properties • High dielectric strength (2 x air) • Nontoxic, nonflammable, noncorrosive • Excellent arc extinction • Excellent

2. Fluoronitriles

5

Molecular structure of the NovecTM 4710

• One of the promising options is NovecTM 4710 fluid.

• 2x better dielectric than SF6• High boiling temp. (-4.7C)

need to be diluted into buffer gas

• CO2 selected over N2 and air due to reported better arc quenching capability

• In this paper we’ve compared the PD between SF6 and fluoronitrile/CO2 mixture

Page 6: Comparison of Partial Discharges in SF6 and … properties • High dielectric strength (2 x air) • Nontoxic, nonflammable, noncorrosive • Excellent arc extinction • Excellent

2. Fluoronitriles

6

0 10 20 30 40 50 60 70 80 90 1000.2

0.4

0.6

0.8

1.0

1.2

1.4

1.6

1.8

2.0

2.2

2.4

100kPa (14.5 psi) 120kPa (17.4 psi) 140kPa (20.3 psi) 160kPa (23.2 psi) 180kPa (26.1 psi) 200kPa (29.0 psi)D

iele

ctric

stre

ngth

of t

he g

as m

ixtu

re/S

F 6

NovecTM 4710 mixing ratio (%)

• The EB of pure Novecis more than twotimes that of SF6.

• EB of pure CO2 isfound only 32-37% ofSF6, while it isdoubled by addingonly 5% of Novec4710 into CO2.

• For 15% Novec 4710/CO2 mixture, the EBis equivalent to SF6.

Dielectric strength for NovecTM 4710 fluid in mixture with CO2 compared with SF6.

Page 7: Comparison of Partial Discharges in SF6 and … properties • High dielectric strength (2 x air) • Nontoxic, nonflammable, noncorrosive • Excellent arc extinction • Excellent

3. Setup & procedures

7

R 25mmH.V.

δ=2mm0mm

r 20μmθ=30̊

ToPC

Configuration of PD defect model

PD measuring system

First vacuumed for 30 min.

Then filled with CO2 to 150 kPa andvacuumed again. Repeated three .

Novec and CO2 were filled to thedesigned ratio according to theirpartial pressures.

To determine the PDIV, the appliedvoltage was increased graduallyfrom 0 until the detection of PD.

10 pC was chosen as threshold ofPDIV.

To obtain PRPD pattern, the PDsignal was recorded for 120 s.

Page 8: Comparison of Partial Discharges in SF6 and … properties • High dielectric strength (2 x air) • Nontoxic, nonflammable, noncorrosive • Excellent arc extinction • Excellent

4. Results & Analysis

8

10 20 30 40 50 60 70 80 90 100 110 120 130

1.5 2.9 4.3 5.8 7.2 8.7 10.1 11.6 13.0 14.5 15.9 17.4 18.8

0

10

20

30

40

50

60

PD inception voltage

5% Novec + 95% CO2

10% Novec + 90% CO2

15% Novec + 85% CO2

20% Novec + 80% CO2

SF6

Volta

ge (k

V)rm

s

Pressure

d=10mmδ=2mm

breakdown voltage

(psi)

(kPa)

PDIV and breakdown voltage

PDIV and breakdown voltage of the NovecTM 4710/CO2 mixture and SF6 at different pressures

Page 9: Comparison of Partial Discharges in SF6 and … properties • High dielectric strength (2 x air) • Nontoxic, nonflammable, noncorrosive • Excellent arc extinction • Excellent

4. Results & Analysis

9

phase-resolved partial discharge (PRPD) pattern

PRPD pattern of 20%Novec/80%CO2 mixture and SF6 under different voltages.

P=100kPa (14.5 psi)

Page 10: Comparison of Partial Discharges in SF6 and … properties • High dielectric strength (2 x air) • Nontoxic, nonflammable, noncorrosive • Excellent arc extinction • Excellent

4. Results & Analysis

10PRPD pattern of 20%Novec/80%CO2 mixture and SF6 under different voltages.

P=100kPa (14.5 psi)

Page 11: Comparison of Partial Discharges in SF6 and … properties • High dielectric strength (2 x air) • Nontoxic, nonflammable, noncorrosive • Excellent arc extinction • Excellent

4. Results & Analysis

11

phase-resolved partial discharge (PRPD) pattern

14 16 18 20 22 24 26 280.1

1

10

100

1000

10000 SF6 20% Novec+20%CO2 SF6 20% Novec+20%CO2

Applied voltage (kV)

Cou

nts

per s

econ

d

5

10

15

20

25

30

Ave

rage

cha

rge

mag

nitu

de (p

C)

Comparison of the PD number and PD magnitude for the NovecTM 4710/CO2 mixture and SF6 under different voltages.

Page 12: Comparison of Partial Discharges in SF6 and … properties • High dielectric strength (2 x air) • Nontoxic, nonflammable, noncorrosive • Excellent arc extinction • Excellent

4. Results & Analysis

12

PRPD pattern of fluoronitrile/CO2 mixtures with different ratios. (V=22.5 kV)

• A better PD suppressionwith the increase ofmixing ratio, especiallyin the positive half cycle.

Page 13: Comparison of Partial Discharges in SF6 and … properties • High dielectric strength (2 x air) • Nontoxic, nonflammable, noncorrosive • Excellent arc extinction • Excellent

4. Results & Analysis

13

Comparison of PD levels through PRPD statistics

Even 15% mixture has a lowerPD level in the positive halfcycle compared with SF6.

the comparison of their PD amplitudes at different phases.

Page 14: Comparison of Partial Discharges in SF6 and … properties • High dielectric strength (2 x air) • Nontoxic, nonflammable, noncorrosive • Excellent arc extinction • Excellent

4. Results & Analysis

14

Comparison of PD levels through PRPD statistic

0 10 20 30 40 50 60 70 80 90 100 1100

2000

4000

6000

8000

10000

12000

14000

16000

18000

Cum

ulat

ive

Cou

nt

PD charge (pC)

5% Novec + 95% CO2 10% Novec + 90% CO2

15% Novec + 85% CO2 20% Novec + 80% CO2 SF6

(a)

trigg

er le

vel

0 10 20 30 40 50 60 70 80 90 100

0

1000

2000

3000

4000

trigg

er le

vel

5% Novec + 95% CO2 10% Novec + 90% CO2

15% Novec + 85% CO2 20% Novec + 80% CO2 SF6

(b)

Cou

ntPD charge (pC)

• PD number of SF6 is in between 15% mixture and 20% mixture.• In SF6, there are much more PDs with low magnitude compared

with the 20% fluoronitrile/CO2 mixture.

Page 15: Comparison of Partial Discharges in SF6 and … properties • High dielectric strength (2 x air) • Nontoxic, nonflammable, noncorrosive • Excellent arc extinction • Excellent

5. SUMMARY

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• 15% Fluoronitrile/CO2 mixture shows equivalent dielectric strength compared with SF6 under uniform field

• 15% Fluoronitrile/CO2 mixture and SF6 have almost the same PDIV under 11.6psi, 14.5 psi and 17.4psi. Both slightly lower than 20% mixture.

• PD counts in SF6 are in-between 15% and 20% mixture.

• SF6 has much more PDs with low magnitude and the 20% fluoronitrile/CO2 mixture has less PDs but with higher magnitude.

Page 16: Comparison of Partial Discharges in SF6 and … properties • High dielectric strength (2 x air) • Nontoxic, nonflammable, noncorrosive • Excellent arc extinction • Excellent

16

Thank you!

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