COURSES OF STUDIES FOR THEM.Sc. EXAMINATION IN CHEMISTRY

SEMESTER-I and IISEMESTER-III and IV

The two year course in M.Sc chemistry shall comprise four semesters. There shall besixteen theory papers, four practical papers and one dissertation. Each theory paper shallcarry 15+60 marks. Each practical paper shall carry 100 marks. The dissertation carries 200marks. The dissertation is expected to carry out under the supervision of a facultymember of the department.

Each theory paper shall carry four units. Questions will be set unit wise.

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PAPER-I (CH.l~.l)INORGANIC CHEMISTRY

Marks-lBEiiIt /5+f,O

UNIT-I Stereochemistry and Bonding in main group compoundsVSEPR, Walsh diagram (tri molecules), dz-Pn bonds, Bent rule and energetics of hybridization,some simple reactions of covalently bonded molecules.

UNIT-II Symmetry and Group TheorySymmetry elements ,and Symmetry operation, Groups and Subgroups, Symmetry point group.

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UNIT-III Chemistry of Main Group elements AGeneral characteristics, Allotropes, Structure and Reactions of simple and industriallyimportant compounds: Boranes, Carboranes, Silicones, Silicates, Boron nitride, Borazines andPhosphazenes.

UNIT-IV Chemistry of Main Group elements BGeneral characteristics, Structure and Reactions of simple and industrially important

compounds: Hydrides, Oxides and Oxoacids ofpnictogens (N, P), chalcogens (S, Se &Te) andhalogens, Xenon compounds, Pseudo halogens and Interhalogen compounds.

Books and References:~ChemicalApplicationofGroup Theory: F. A. Cotton, JohnWiley.

2. Symmetry in Chemistry: Orchin and Jaffe."~Group theory: K. V. Raman, Tata McGraw Hill.'ii. Advanced Inorganic Chemistry: F. A. Cotton and G. Wilkinson, John Wiley.'5. Inorganic Chemistry: I.E. HOOeey, E. A. Keiter, R. L. Keiter, Pearson Education.6. Chemistry ofthe Elements: N. N. B. Greenwood and A. Eamshow, Pergamon.7. Comprehensive Coordination Chemistry eds.,- G. Wilkinson, R. D. Gillars and I. A.

McCleverty, Pergamon.

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SEMESTER-IPAPER-IT (CHl(l.2)

ORGANIC CHEMISTRYMarks-~ t$N f)

UNIT-I Reaction Mechanism: Structure and Reactivity: (a) Types of mechanism, types ofreactions, thermodynamic and kinetic requirements, kinetic and thermodynamic control,Hammond's postulate, Curtin - Hanunett principle. Potential energy diagrams, transition statesand intermediates, methods of determining mechanisms, isotope effects. Hard and soft acidsand bases. (b) Generation; structure, stability and reactivity of carbocations, carbanions, freeradicals. Carbenes and nitrenes. Effect of structure on reactivity: resonance and field effect,steric effect, quantitative treatment. The Hammett equation and linear free energy relationships,

UNIT-IT (a) Aliphatic Nucleophilic substitution:The SN2, SNI, mixed SNI and SN2 and SETmechanisms. The neighbouring group mechanism, neighbouring group participation by cr and 1t

bonds, anchimeric assistance. Classical and nonclassical carbocations, phenonium ions,norbomyl system, common carbocation rearrangements. .

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The SNI mechanism: Nucleophilic substitution at an allylic, aliphatic trigonal and a vinyliccarbon. Reactivity effects of substrate structure, attacking nucleophile, leaving group and,reaction medium, phase transfer catalysis and ultrasound, ambident nucleophile,regioselectivity.

(b) Selective organic name reactions: Favorski reaction, stock .enaIJ:!ine reaction, Mannichreaction,~' • __.,Bae~~r-Villiger

reaction, Chichibabin reaction, Claisen condensation, Claisen reduction, Curtius\.,-.~"-,,. __~"'~T_'"

Rearrangeml?nt, Demjanov rearrangement, Diec.~.£.QD.densation, Favorskii rearrangement,, -. Wittig olefination, Wolff-kishner reduction,-- -- ~--

'~" . .', Friu rearrangement, ;: . : . .'W"t'lK" .,.M.«¥'tVf'J:v r;Li.~, .

UNIT-ITI (a) Aromatic Nucleophilic Substitution: The SNAr, SN' benzyne and SRNI"mechanisms. Reactivity-effect of substrate structure, leaving group and attacking nucleophile.,;'The von Richter, Sommelet-Hauser, and Smiles rearrangements.(b) Aromatic Electrophilic Substitution: The areniun ion mechanism, orientation andreactivity, energy profile diagrams. The ortho/para ratio, Ipso attack, orientation in other ring,systems. Quantitative treatment of reactivity in substrates and electrophiles. Diazonium'coupling, Vilsmeier reaction, Gattermann- Koch reaction.

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Books and References:1. Orfianic chemistry: J. Clayden, N. Greeves, S. Warren and P. Wothers, Oxford University

Press.

2. Advanced Organic Chemistry Reactions, Mechanism and Structure: Jerry March. JohnWiley and Sons.

3. Advanced Organic Chemistry: F. A. Carey and R. J. Sundberg. Plenum.4. A Guide Book to Mechanism in Organic Chemistry: Peter Sykes, LongmanlPearson

Education.5. Structure and Mechanism in Organic Chemistry: C. K Ingold. Cornell University Press.6. Organic Chemistry: R. T. Morrison and R. N. Boyd Prentice HalllPearson Education.7. Modem Synthetic Reactions: Second Edition, H. O. House, Benjamin, Menlo Park, 1972.8. Principles of Organic Synthesis: R. O. C. Norman and J. M. Coxon. Blackie Academic and

Professional! CBS Publishers.

9. A logical Approach to Modem Organic Chemistry: Dr. Jagdamba Singh and Dr. S.Anandvardhan. Pragati Prakasan.

10. Reaction Mechanism in Organic Chemistry: S. Mukherji and S. P. Singh, Macmillan.11. Advanced Organic Chemistry: Reactions and Mechanism: B. Miller and R. Prasad.

Pearson-Education.12. Stereochemistry ofOrganic Compounds: D. Nasipuri, New Age International.13. Stereochemistry ofOrganic Compounds: P. S. Kalsi, New Age International.14. Stereochemistry ofOrganic Compounds: E. L. Eliel and S. H. Wilen. John Wiley.15. Stereochemistry, Conformation and Mechanism: P. S. Kalsi, New Age International.

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SEMESTER-IPAPER-ill (CH-l.(l.3)

PHYSICAL CHEMISTRY

Marks·_ l/fif~ 0

III

UNIT-I Quantum Chemistry: The Schrodinger equation and the postulates of quantummechanics. Discussion of solutions of the Schrodinger equation to some model systems viz.particle in a box, the hannonic oscillator, the rigid rotor, the hydrogen atom

UNIT-ll Approximation Methods: The Helium atom The variation theorem, linear variationprinciple, Perturbation theory (first order and non-degenerate). Applications of variationmethod and perturbation theory to the Helium atom.

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UNIT-ill Electronic Structure of Atoms: Multielectron atom.Russell-Saunders terms and coupling schemes, magnetic effects:Zeeman splitting.

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spin-orbit coupling and

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UNIT-IV Molecular Orbital Theory: H2+ and H2 molecules: Valance bond theory (VBT) andmolecular orbital theory (MOT) approaches. Homonuclear and Heteronuclear diatoms. Huckeltheory of conjugated systems, bond order and charge density calculation. Applications toethylene, butadiene, cyclopropenyl radical, and cyclobutadiene.

Books and References:,)Y,'"Atkin's Physical Chemistry: P. W. Atkins, J. D. Paula, Oxford University Press

vr.'1ntroductory to Quantum Chemistry: 4th Ed., A. K. Chandra, TataMc Graw Hill.~) Quantum Chemistry: Ira N. Levine, Prentice Hall.

4. D. A. McQuarrie and J. D. Simon, Molecular Thermodynamics, University Science Books,California 2004.

'Voo R S. Berry, S. A. Rice and J. Ross, Physical Chemistry, 2nd Edition, Oxford University\7Press, Oxford 2007.

\.,6:"" D. A. McQuarrie, Statistical Mechanics, University Science Books, California (2OOS).7. B. Widom, Statistical Mechanics - A Concise Introduction for Chemists, Cambridge

University Press 2002.

JY' D. Chandler, Introduction to Modern Statistical Mechanics, Oxford University Press 1987.'. Physical Chemistry Vol-II: .K. L. Kapoor, Mcmillan Publication.O. Statistical Thermodynamics: M. C. Gupta, New Age Pvt Publication..

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SEMESTER-IPAPER-IV (CH-1£l'.4)

PHYSICAL CHEMISTRY

UNIT-I Classical Thermodynamics: Brief resume of concepts of laws of thermodynamics,entropy and free energy. The concept of chemical potenilaI and partial molar properties; partialmolar free energy, partial molar volume and partial molar heat content and their significance.Determination of these quantities. Concept of fugacity and determination of fugacity. Activity,activity coefficient, Debye-Hu,ckel theory for activity coefficient of electrolytic solutions;determination of activity and \ty coefficients, ionic strength.

• ~,. havior of one and two component systems (solid-solid,

solid-liquid, solid-vapor, liquid-liquid, liquid-vapor equilibrium). Ehrenfest classification ofphase transitions.

-JJNIT-ill Statistical Thermodynamics: Concept of distribution, thermodynamic probabilityand most probable distribution. Ensemble averaging, postulates of ensemble averaging,Canonical, grand canonical and microcanonical ensembles, corresponding distribution laws(using Lagrange's method of undetermined multipliers)Partition functions-translational, rotational, vibrational and electronic partition functions,.calculation of thermodynamic properties in terms of partition function. Fermi-Dirac statistics,distribution law and application to metal. Bose-Einstein statistics - distribution law andapplication to helium.

UNIT-IV Chemical Dynamics: Potential energy surfaces. Collision theory of reaction rates,Conventional transition state theory (CTST); CTST as applied to ionic reactions, kinetic salteffects. steady state kinetics. Kinetic and thermadynamic control of reactions. Treatment ofunimolecular reactians. dYl1amics of unimolecular reactions (Lindemann- Hinshelwood andRice Rampsberger - Kassel Marcus (RRKM) theories of unimolecular reactions).

Dynamics chain (hydrogen-bromine reaction, pyrolysis of acetaldehyde, decompositionof ethane), photochemical (hydrogen -bromine and hydrogen - chlorine reactions) andoscillatory reactions (Belousov- Zhabotinski reaction), homogeneous catalysis, kinetics ofenzyme reactions. General features of fast reactions, study of fast reactions by flow methods,relaxation methods, Flash photolysis. Dynamics of barrier less chemical reactions in solution.

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SEMESTER-IPAPER-V (CH·l~.5)

INORGANIC CHEMISTRY PRACTICAL·M~20+80 .¥Qualitative analysis of mixtures containing not more than eight radicals [less common metal

ions Mo, W, Ti, V, Zr, U (two metal ions in cationic I anionic forms), insoluble-oxides,A 3.?'

sUlphates and halides may be included].2. Separation and determination of two metal ions Cu-Ni, Ni-Zn, Cu-Fe etc. involving

volumetric and gravimetric methods.3. Synthesis of bulky Schiff base (Ketiminel diketiminel phenolate) transition metal complexes.4. Preparation of some selected inorganic compounds and their study. Handling of air and

moisture sensitive compounds.a) Mn(acac)3

b) K3[Fe(C20 4)3. Ic) [Ni (NH3)6] C12d) [Ni(dimgh.V"Au (NH3)4]. s04.H20

f) Cis - and Trans [Co (enhlCh.5. A. Synthesis of Wilkinson's catalyst

B. Reaction of Wilkinson's catalyst with CyclohexeneC. Reaction of Wilkinson's catalyst with Hydrogen.

Books and References: .~1. Inorganic Experiments: J. Derek Woollins, VCH.2. Microscale Inorganic-chemistry; Z.Szafran, RM. Pike and M. Singh. Wiley.3. Practical Inorganic Chemistry: G.Marr and B.W. Rockett, van,Nbstrand.4. Vogel'-s Qualitative Inorganic Analysis (revised) : G. Svehla, Longman.'l ~-,~)

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SEMESTER-llPAPER - VI (CH-l~ ctv -20 I

ff' INORGANIC CHEMISTRYr Marks-10+40

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UNIT-I: Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states,Orgel diagrams for d1_d9 states in Oh and Td symmetry, Tanabe-Sugano diagrams for d2

configuration in Oh and Td symmetry. Calculations of Dq, B and pparameters.

UNIT-ll Metal-Ligand Bonding: Crystal-Field Theories: Limitation of Crystal Field Theory,Molecular orbital theory for Octahedral, Tetrahedral and Square Planar Complexes, a andnbonding in Molecular Orbital Theory. Application of MOT to Correlation diagrams.

UNIT-ill: Chemistry of Transition Transition Elements: Coordination chemistry ofTransition Metal ions, Stabilization of Unusual oxidation states, Stereochemistry ofcoordination compounds, Splitting of d-orbitals in Low symmetry environment, Jahn-Tellereffect, Interpretation of Electronic Spectra including Charge Transfer Spectra, Spectrochemicalseries, Nephelauxetic series, Fluxional molecules, Iso and Hetero Poly acids. Structures ofMixed Metal Oxides: Spinel & Inverse Spinel, lleminite and Perovskite structure, ColouredMinerals and Gem quality crystals.

UNIT-IV: Chemistry of Inner Transition Elements: Chemistry of Lanthanides andActinides: Lanthanide Contraction, Separation of Lanthanide elements, Oxidation state,Spectral and Magnetic Properties, Stereochemistry, Use of Lanthanide Compounds as Shiftreagents, Actinide contraction, Oxidation states, Comparisons between Lanthanides andActinides.

Books and References:1. Advanced Inorganic Chemistry: A Comprehensive Text: F. A. Cotton and G. Wilkinson,

John Wiley.2. Inorganic Chemistry: Principles of Structure and Reactivity: J. E. Huheey, E. A. Keiter and

R. L. Keiter, Addition Wisley Publishing Company.3. Comprehensive Coordination Chemistry eds.: G. Wilkinson, R. D. Gillars and J. A.

McCleverty, Pergamon.4. Inorganic chemistry: Gary L. Miessler, Donald A. Tarr, Pearson

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SEMESTER-IIPAPER -Vll (CH-l:U:J a /ZO 2­

ORGANIC CHEMISTRY

Marks-10+40

UNIT-I (a) Nature of Bonding in Organic Molecules:Delocalized chemical bonding:conjugation, cross conjugation, resonance, hyperconjugation, tautomerism. Arornaticity inbenzenoid and nonbenzenoid compounds, altemant and non-altemant hydrocarbons. Hucker srule, energy level of n-molecular orbitals, annulenes, antiarornaticity, 'l'-arornaticity,homoarornaticity, Fullerene (C60)

(b) Stereochemistry: Conformational analysis of cycloalkanes, decalins, effect ofconformation on reactivity, conformation of sugars, steric strain due to unavoidable crowding.

molecules with more than one chiral center, threo anderythro isomers, methods of resolution, optical purity, enantiotropic and diastereotropic atoms,

groups and faces, stereospecifjc and, steroselective synthesis. Asymmetric synthesis. Opticalactivity in the absence of chiral carbon (biphenyls, allenes and spiranes), chirality due to helicalshape. Stereochemistry of the compounds containing nitrogen, sulphur and phosphorus.

UNIT-II (a) Addition to Carbon-Carbon Multiple Bonds: Mechanistic and stereochemicalaspects of addition reactions involving electrophiles, nucleophiles and free radicals, selectivity,orientation and reactivity, Electrophilic cyclization, Baldwin's rule. Hydrogenation of double

and triple bonds, hydrogenation of aromatic rings. Hydroboration, Michael reaction. Sharplessasymmetric epoxidation.(b) Addition to Carbon-Hetero Multiple Bonds: Mechanism of metal hydride reduction ofsaturated and unsaturated carbonyl compounds, acids, esters and nitriles. Addition of Grignardreagents, organozinc and organolithium reagents to carbonyl and unsaturated carbonylcompounds. Wittig reaction.

Mechanism of condensation reactions involving enolates, Aldol, Knoevenagel, Claisen,Mannich, Benzoin, Perkin and Stobbe reactions.

UNIT-ill Pericyclic Reactions: Molecular orbital symmetry, Frontier orbitals of ethylene, 1,3­butadiene, 1, 3, 5 - hexatriene and allyl system. Classification of pericyclic reactions.WoodWard -Hoffmann correlation diagrams. FMO and PMO approach. Electrocyclic

reactions, conrotator and disrotatory motions; 4n, 4n+2 and allyl systems. Cycloadditions,antarafacial and suprafacial additions; 4n and 4n+2 systems, 2+2 addition of ketenes. 1, 3 ­dipolar cycloadditon and cheletropic reactions. Sigrnatropic rearrangements - suprafacial andantarafacial shifts of H, sigmatropic shifts involving carbon moieties, 3, 3 - and 5, 5 -

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UNIT-IV (a) Disconnection approach: An introduction to synthons and synthetic equivalents,disconnection approach, functional group interconversions, the importance of the order ofevents in organic synthesis, one group C-X and two groups CoX disconnections,chemoselectivity, reversal of pOlarity (umpolung reaction), cyclisation reactions, aminesynthesis.(h) Protecting groups: Principle of protection of alcohol, amine, carbonyl, carboxyl groups

.', and Umpolung ReactionI, (c) One group C-C disconnection: Alcohols and carbonyl compounds, regioselectivity.. Alkene synthesis, use of acetylenes and aliphatic nitro compounds in organic synthesis.

ized compoundsalpha, beta- unsaturated carbonyl compounds, control in carbonyl condensations, 1,5 ­difunctionalized compounds, Michael addition and Robinson annelation.(e) Chemistry of Natural Products: Application of Disconnection approach in theconstruction of biomolecules like Synthesis of Camphor, Longifoline & Juvabione.

Books and References:1. Organic chemistry: J. Clayden, N. Greeves, S. Warren and P. Wothers, Oxford University

Press.2. Advanced Organic Chemistry Reactions, Mechanism and Structure: Jerry March. John

Wiley and Sons.3. Advanced Organic Chemistry: FA Carey and RJ. Sundberg. Plenum.4. Photo Chemistry and Pericyclic Reactians: Jagdamba Singh and Jaya Singh, New Age

Intematianal.

SEMESTER-ITPAPER VITI (CH-I.2.S) cJ, - ~CJ3

PHYSICAL CHEMISTRYMarks-IO+40p/UNIT-I sJrace Chemistry: (a) Adsorption: Surface tension, capillary action, pressuredifference across curved surface (Laplace equation), vapour pressure of droplets (Kelvinequation). Gibbs adsorption isotherm, estimation of surface area (BET equation), surface filmson liquids (Electrokinetic phenomenon), catalytic activity at surfaces.

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(b) MiCell~Surface active agents, classification of surface active agents, micellization,hydrophobic interaction, critical micellar concentraion (CMC), factors affecting the CMC ofsurfactants counter ion binding to micelles, thermodynamics of micellization, phase separationand mass action models, solubilization, micro emulsion, reverse micelles.

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UNIT-II Electrochemistry: (a) Ion-Solvent interactions: Nonstructural treatment of ion- ../solvent interaction, quantitative measure of ion solvent interactions. The Born model,Electrostatic potential at the surface of a charged sphere. The electrostatics of charging anddischarging spheres. The Born expression for the free energy of ion-solvent interactions, theinteraction of a single ionic species with the solvents. Experimental evaluation of the heat ofinteraction of a salt and solvent, limitation of Born theory.

Structural treatment of the ion"solvent interactions, structure of water near an ion, Ion-

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,I: of ion-dipole theory of salvation, water molecule as electrical quadrupole, ion-quadrupole" model of ion-solvent interaction, Ion-induced dipole interactions in the primary salvation

sheath, Limitation of ion-quadrupole theory of salvation.(b) Ion-Ion interactions: Debye-Huckel-Onsager treatment and its extension. Debye-Huckel­Jerrum model.

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UNIT-ill Electrodics: Thermodynamics of electrified interface equations. Derivation ofelectrocapiliarity; Lippmann equations (surface excess), methods of determination, Structure ofelectrified interfaces. Overpotentials, exchange current density, derivation of Butler-Volmerequation, Tafel plot, interfaces-theory of double layer at semiconductor-electrolyte solutioninterfaces. Effect of light at semiconductor solution interface. Electrocatalysis-influence ofvarious parameters. Diffusion layer. The limiting current density and its practical application.Corrosion, Battery and Fuel cell.

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UNIT-IV Error Analysis: Statistical methods in chemical analysis: Theory of error andtreatment of quantitative data, accuracy and precision, ways of expressing accuracy andprecision, Normal error curve and its equation. Useful statistical tests with equation, test ofsignificance, the F-test, the students t-test, the Chi-test, the correlation coefficient, confidencelimit of the mean, comparison of two standard values, comparison of two standard values,comparison of standard deviation with average deviation, comparison of mean with true values,regression analysis (least square method for linear plots).

Books and References:1. Physical Chemistry: P. W. Atkins, J. D. Paula, Oxford III University Press.2. Introduction to Quantum Chemistry: A. K. Chandra, Tata Me Graw Hill.

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~v?Cr-3. Quantum-Chemistry: Ira N. Levine, Prentice Hall.4. Coulson's Valence: R Mc Weeny, ELBS.5. Chemical Kinetics: K. J. Laidler, McGraw-Hill.6. Kinetics and Mechanism of Chemical Transformation: J. Rajaraman and J. Kuriacose, Mc

millan.7. Micelles, Theoretical and Applied Aspects, V. Morui, Plenum.8. Modern Electrochemistry: Vol.-I and Vol. IT, J. O. M. Bockris and A. K. N. Reddy, Plenum.9. An Introduction to electrochemistry: S. GIasstone, Affiliated East-West Press Pvt. Ltd.10. Principles of instrumental analysis: D. A. Skoog, 5th eOO, Sauns College Publishing

Philadelphia (London).11. Basic concepts ofanalytical chemistry: S. M. Khopkar, Wiley Eastern

SEMESTER -IIPAPER-IX (CH-Je9)

ORGANIC SPECTROSCOPYMarks- 10 + 40

UNIT-I ~Ultraviolet and Visible Spectroscopy: Various electronic transitions, Beer~Lambert law, effect of solvent on electronic transitions, ultraviolet bands for carbonylcompounds, unsaturated carbonyl compounds, dienes, conjugated polyenes, Fieser-Woodwardrules for conjugated dienes and carbonyl compounds, ultraviolet spectra of aromatic and

. heterocyclic compounds, steric effect in biphenyls. \II,$J-(j) Infrared spectroscopy: Instrumentation and sample handling, characteristics vibrational

frequencies of alkanes, alkenes, alkynes, aromatic compounds, alcohols, ethers, phenols andamines, Detail study of vibrational frequencies of carbonyl compounds (ketones, aldehydes,esters, arnides, acids, arnides, acids, anhydrides, lactones, lactams, and conjugated carbonylcompounds), Effect of hydrogen bonding and solvent effect on vibrational frequencies,overtones, combination bands and Fermi resonance, FfIR, IR of gaseous, solid and polymericmaterials.

UNITID: Nuclear Magnetic Resonance Spectroscopy (NMR): General introduction anddefmition, chemical shift, spin-spin interaction, shielding mechanism, mechanism of

measurement, chemical shift values and correlation for protons bonded to carbon (aliphatic,olefmic, aldehydic, and aromatic compounds) and other nuclei (alcohols, phenols, enols,carboxylic acids, arnines, arnides, and mercapto), chemical exchange, effect of deuterium,complex spin-spin interaction between two, three, four and five nuclei (first order spectra),virtual coupling, stereochemistry, hindered rotation, karplus curve-variation of couplingconstant with dihedral angle, simplification of complex spectra, nuclear magnetic double

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resonance, NMR shift reagents, solvent effects, Fourier transform .technique, nuclear

overhauser (NOE). Resonance of other materials.

UNIT'" Carbon-13 NMR spectroscopy: General considerations, chemical shift (aliphatic,olefinic, alkyne, aromatic, heteroaromatic and carbonyl carbon), coupling constants. Two

dimension NMR spectroscopy -COSY, NOESY, DEPT, APT and INADEQUATE techniques.

UNITt.\'Mass spectrometry: Introduction, ion production - EI, CI and FAB factors affectingfragmentation, ion-analysis, ion analysis, ion abundance, mass spectral fragmentation oforganic compounds, common functional groups, molecular ion peak, metastable peak,McLafferty rearrangement, nitrogen rule, high resolution mass spectrometry, examples of massspectral fragmentation of organic compounds with respect to their structure determination.

Books and References~erstein,R. M.; Webster, F. X. Spectrometric identification oforganic compounds; 6th I

ed.; Wiley: New York, 1998.2. Lambert, J. B; Shurvell, H. F, Organic structural spectroscopy, Prentice Hall, 1998.~mp, W. Organic spectrospopy; 3rd ed.; Macmillan Education: Houndmills, Basingstoke,

Hampshire, 1991.4. Levitt, Malcolm H.; Spin Dynamics-Basics of Nuclear Magnetic Resonance, Second

edition; John Willey & Sons Ltd. . 0 ,t; . M~(I-R.A,.v0.P-Y U.t,c.hvkC JJt"'> :t: r fVVvev, r SIiMi'STER -II

PAPER-X (CH-l=t&) 2-fJ5'ORGANIC CHEMISTRY PRACTICAL

Marks. - 20+ 801. Separation, purification and identification of compounds of binary mixtures (solid-solid,

solid-liquid, liquid-liquid) using TLC and column chromatography, Chemical tests.2. Quantitative Analysis:

(a) Determination of amino group by acetylation method.(b) Detennination of hydroxyl group by acetylation method.(c) Estimation of Keto group.

(d) Determination of iodine value and saponification value of an oil sample.3. Organic Synthesis: Preparation of adipic acid, p-chlorotoluene, p-nitroaniline, p­

bromoaniline, triphenylmethanol.Preparation of PDC (Pyridinium dichromate) & PCC(Pyridinium chloro chromate) reagentsand it's application on benzyl alcoholGrignard reagent preparation and reactions on aldehyde.

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Books and References:1. The Systematic Identification of Organic Compounds: RL. Shriner, C. K. F. Hannann, T.e.

Morrill, D.Y. Curtin, RC. Fusion, John Wiley and Sons.2. Organic Analytical Chemistry (Theory and Practice): Jagmohan, Narosa Publishing House.3. A Text Book ofPractical Organic Chemistry: Arthur 1 Vogel, .E.L.B.S. and Longman.4. Experiments and Techniques in Organic Chemistry: D. Pasto, e. Johnson.5. Laboratory Mannual of Organic Chemistry: B.B. Dey and M.V.Siaram (Revised)­

:T.RGovindachari, Allied Publishers.6. Systematic Qualitative Organic Analysis: H. Middleton, Orient Longman.

and Ouantitative): H.T. Clarke, Revised, B.Haynes, Arnold Publishers.

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PG-IISEMESTER-ill

PAPER-XI (CH-~) jlo IINORGANIC CHEMISTRY ill

Marks: 10+40

UNIT -I (a) Metal2t -Complex: Metal Carbonyls, Structure and Bonding, Important reactionsof metal carbonyls; Preparation, Bonding, Structure and· Important Reactions of TransitionMetal Nitrosyl, Dinitrogen and Dioxygen Complexes ligands.(b) Metal clusters: Metalloboranes, Metallocarboranes, Metal carbonyls and Metal halideclusters.

UNIT -II Metal -Lil!and Equilibria in Solution: Stepwise and Overall formation constantsand their interaction, trends in stepwise constants. Factors affecting the Stability of metalcomplexes with reference to the nature of metal ion and ligand. Chelate effect, Macrocycliceffect and its thennodynamic origin. Determination of Binary Formation Constants by pH­metry and Spectrophotometry.

UNIT-ill Reaction Mechanism of Transition Metal Complexes (Part-A): Energy profile ofa reaction, Reactivity of metal complexes, Inert and Labile complexes, Kinetic application ofValence Bond and Crystal field theories, Kinetics of Octahedral substitution, Acid hydrolysis,Factors affecting acid hydrolysis and base hydrolysis, Conjugate base mechanism, direct andindirect evidences in favour of conjugate base mechanism.

UNIT-IV Reaction Mechanism of Transition Metal Complexes (Part-B): Anation reactions,k-exchange, reaction without metal ligand bond cleavage. Substitution reactions in squareplanar complexes. The trans effect, mechanism of one electron transfer reactions, Outer spherereactions, Marcus-Hush Theory, Inner sphere type reactions.

Books and References:1. Advanced Inorganic Chemistry: A Comprehensive Text: F. A. Cotton and G. Wilkinson,

John Wiley.

2. Inorganic Chemistry: Principles ofStructure and Reactivity: J. E. Huheey, E. A. Keiter andR. L. Keiter, Addition Wisley Publishing Company.

3. Comprehensive Coordination Chemistry eds.: G. Wilkinson, R. D. Gillars and J AMcCleverty, Pergamon.

4. Advanced Inorganic Chemistry: F. A. Cotton, G. Wilkinson, C. A. Murillo and M.Bochmann, John Wiley and Sons.

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INORGANIC CHEMISTRY IVMarks: 10+40

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unsaturated compounds,Fischer-Tropsch synthesis,

Oxygen transfer from Peroxo and Oxo Species, ReductIve & HvOD£JeDisplacement and Isomerization reaction.

Hydrogenation, Hydrosilation and Hydrocyrlation ofHydroformylation, Wacker (Smidt) Process, ,Olefin Metathesis,Zeigler-Natta polymerization, Water gas reacti6n.

UNIT -IV Magneto Chemistry & EPR: (a) Induction and susceptibility. Lande interval rule,calculation of g-values, Van Vleck's equation and its use. Effect of spin orbit coupling.

,I Magnetic properties of AE.T terms with reference to Co(I) and Ni(II) complexes.(b) Electron Paramagnetic Resonance Spectroscopy: Hyperfine splitting, Spin orbit coupling,Significance of g-tensor, Zero field splitting, Kramer's degeneracy, Application to inorganicsystems

Ii

UNIT -III Nuclear Chemistry: Radioactive Decay, Radioactive Equilibria, NuclearReactions, Q-Value, Reaction Cross- sections, Nuclear Fission, Fission Yield, Nuclear Fusion,Pinch Effect, Tracer Techniques, Neutron Activation Analysis (NAA), Counting Techniques,Ionization Counter, GM Counter, Proportional Counter.

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I UNIT-I Organometallic Chemistry: 18-Electron Rule, Ligands in Organomettallics,'i Synthesis, bonding and reactions of Alkyl, Aryl, Alkylidenes, Alkylidynes, Allyl, Dienyl,

Arene & Trienyl complexes, Cyclic 1t systems (3 to 8 membered rings) and Fullerenecomplexes. Spectral analysis of Organometallic Complexes.

Books and References:J' 1. Advanced Inorganic Chemistry: F. A. Cotton and G. Wilkinson, John Wiley.

; i 3. Inorganic Electronic Spectroscopy: A B. P. Lever, Elsevier.. " 4. Magnetochemistry, R. L. Carlin, Springer Verlag.

,', 5. Comprehensive Coordination Chemistry eds.,-G. Wilkinson, R. D. Gillars and 1. A,,: McCleverty, Pergamon.

iii UNIT -IT Homogenous and Heterogenous catalysis: Stiochiometric reactions for! Or,,~nometallic catalvsts: Dissociation & Substitution, Oxidative addition & carbonylation,

.•;'

SEMESTER-illPAPER-XIII (CH.j 1)3D.yORGANIC CHEMISTRY

arks: 10+40

'UNIT- I (a) Oxidation: Introduction, different oxidative processes, hydroborations alkanes,alkenes, aromatic rings, saturated C-H groups (active and unactivated), alcohols, diols,aldehydes, ketones, ketals, and carboxylic. Amines, hydrazines and sulphides, Oxidation withruthenium tetraoxide, iodobenzene diacetate and thallium Ill) nitrate, oxidation with mx,Dess"martin periodinane, PDC (Pyridinium Dichromate), PCC (Pyridinium Chlorocmomate).Swem oxidation. (b) Reduction: 'Introduction: Different reductive processes, hydrocarbons-alkanes, alkenes, alkynes and aromatic nng, Carbonyl cWllpoullds: aldehydes, ketones, acidsand their derivatives. Epoxides, Nitro, nitroso, azo, oxime groups, hyrogenolysis,Clemmenson's reduction,Wolff kishner reduction & Luche reduction.

UNIT- n (a) Photo-chemistry: Cis-Tran Isonrensation, Patemo-Buchi Reaction, Norish type I& II reactions, Photo reductions of ketones, Di-1t methane rearrangement, Photochemistry ofArenes. (b) Asymmetric synthesis: Chiral auxiliaries, methods of asymmetric induction ­substrate, reagent and catalyst controlled reactions; detennination of enantiomeric anddiastereomeric excess; enantio-discrimination.Resolution- optical and kinetic.

'-

UNIT-ill (a) Heterocyclic Chemistry Principles of heteroclic synthesis involving cyclisationreactions and cycloadditions. (i) Three-membered and four-membered heterocycles:Synthesis and reactions of Aziridines, Oxiranes, thiranes, azetidines, Oxetanes and thietanes.(ii) Benzo fused Five-Membered Heterocycles: Synthesis and reactions including medicinalapplications of benzopyrroles, benzofurans and benzothiophenes. (iii) Nitrogen Containingheterocyclic: Synthesis and reactivity of pyridine, quinoline, Isoqunoline and Indole. SkraupSynthesis, Fisher Indole Synthesis.(b) Carbohydrate: Chemistry of life, Primary metabolisim, Glycosides, Synthesis Compounds(Vitamin C and Inositols) derived from sugar, Hydrolysis of Polysaccharide, Amino Sugars.

UNIT- IV (a) Organometalic reagents: Principle, Preparations, properties and application ofthe following in organic Synthesis with mechanistic details. (i) Group I and n Metals: Li,

" Mg, Hg, Cd, Zn, (li) Transition metals: Cu, Pd, Ni, Co (iii) Group I and n metal OrganicCompounds: Li, Mg, Hg, Cd, Zn(b) Organo main group chemistry-Boron, Silicon and Tin

17

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); Books and References:Ii 1. Advanced Organic Chemistry; Reactians Mechanism and Structure: Jerry March,

"j, John.Wiley." ~dvanced Organic Chemistry: F. A. Carey and R. 1. Sundberg, Part-B.

"i. 3. Principles of Organic Synthesis: R. O. C. Nonnan and J. M. Coxon, Blackie Academic &

Professianall C.B .S. Publishers.4. Reactian Mechanism in Organic Chemistry: S. M. Mukherjee and S. P. Singh, Macmillian.

India. Ltd.5. Organic Chemistry: J. Clayden, N. Greeves, S. Warren and P. Wothers, Oxfard University

Press.6. Organic Reactians and Orbital Symmetry: T. L. Gilchrist and R. C. Storr, Cambridge at the

University Press.7. Photo Chemistry and Pericyclic Reactians : Jagaa

Intematianal.8. Mechanism and Theory in Organic Chemistry: Thomas H. Lowry, Additian Wesley.

9. Named reaction by Jie Jack Lie.

SEMESTER-illPAPER-XIV (CH4;3#4) C'/n,/ -30 '1)

(pHYSICAL CHEMISTRY-III, INTERDISCIPLINARY-I)

Marks: 10+40

UNIT-I Spectroscopy: (a) Rotational Spectroscopy The rigid diatomic rotor, selection rules,intensity of rotational transitions, the role of rotational level degeneracy, the role of nuclearspin in detennining allowed rotational energy levels. Classification of polyatomic rotors and thenon-rigid rotor. (b) Vibrational Spectroscopy: Review of linear harmonic oscillator,vibrational energies of diatomic molecules, zero point energy, force constant and bond strength;anhannonicity, Morse potential energy diagram, vibration-rotation spectroscopy. Breakdown of

Oppenheimer approximation, vibrations of polyatomic molecules, Selection rules, normalmodes of vibration, group frequencies, overtones, hot bands, factors affecting the bandpositions and intensities; metal-ligand vibrations.

UNIT-II (a) Electronic Spectroscopy: Electronic transitions, Franck-Condon principle.Vertical transitions. Selection rules, parity, symmetry and spin selection rules. Polarization oftransitions. Fluorescence and phosphorescence.(b) Raman Spectroscopy: Classical andquantum theories of Raman effect Pure rotational, vibrational and vibrational-rotational Ramanspectra, selection rules, Mutual exclusion principle.

18

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-ill Electron Spin Resonance (ESR) spectroscopy: g-factor, electron-nuclear coupling,,Ie resonance in ESR electron-electron coupling. Techniques of ESR spectroscopybauer Spectroscopy: Basic principles, instrumentation, spectral parameter and displays,

·cations. Mossbauer parameters- isomer shift, qUadropole splitting, Magnetic hyperfine.ction, Doppler effect. Applications of Mossbauer spectroscopy.

lIT-IV Instrumental Method of Analysis: X-ray diffraction: Crystals and the diffractionsX-ray, Bragg's law concept of symmetry in crystals, lattice planes and Miller indices,:ematic absence of reflections, multiplicities, the x-ray diffraction experiment, powderod, single crystal method, x-ray intensities, structure factor, particle size measurement by

"y diffraction. Polarography: Current-voltage relationship, theory of polarographic waves,entation, qualitative and quantitative applications. Thermal analysis: Theory,

odology, instruments and applications of theromogravlmemcerential scanning calorimetry (DSC).

,ks and References:Fundamentals ofMolecular Spectroscopy: C. N. Banwell, McGraw-Hill.Basic Principles ofSpectroscopy: R. Chang, Mc Graw HillApplication ofspectroscopy oforganic compounds, J. R. Dyer, Prentice hallSpectroscopic methods in organic chemistry, D. H. Williams, 1. Fleming, Tata McGrawHill.Organic spectroscopy, W. Kemp, ELBSSpectroscopy oforganic compounds, P. S. Kalsi, New Age International.

i Mossbauer Spectroscopy and Transition Metal Chemistry, P. Glitlich, R. Link, A.. Trautwien, Springer-Verlag (1978).

MOssbauerSTJectroscojJy,}J..N: Greenwood, T. C. Gibb, Chapman and Hall Ltd. (1971).

F.M.I00

SEMESTER -IIIPAPER-301i'

(GENERAL CHEMISTRY-IV: PRACTICAL)Time: 6 hr

Chemical Kinetics:I. Saponification of ethylacetate with sodium hydroxide by chemical method.

2. Comparison of strength of acids by ester hydrolysis

3. Determination of energy of activation of acid catalyzed hydrolysis ofmethyl acetate.

4. Detennination of velocity constant of hydrolysis of an ester/ionic reaction inmicellar media.

Adsol plio,,:I. Adsorption of acetic acid and oxalic acid on animal charcoal and verification of

Freundlich isotherm.

2. Study of the surface tension - concentration relationship for solutions (Gibb' sequation)

Books and References:

I. Experimental physical chemistry: R. C. Das and B. Behera, Tata McGraw Hill.

2. Findlay'spractical chemistry (revised): B. P. Levitt, Longman.3. Advancedpractical physical chemistry: J. B. Yadav, Goel publishing house, Meerut.

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SEMESTER - IVPAl'ER-401

MODERN ORGANIC & MATERIALS CHEMISTRY

Marks-15+60

UNIT-I (a) Organic compounds in Medicine and their mode of action (i) Synthesisof antipyretics, analgesics (Aspirin, Paracetamol, Ibuprofen) (ii) Antimalarial drugs(Chloroquine and Artesunate) (b) Natural Products (i) Steroids: Cholesterol andProgesterone (ii) Alkaloids: Morphine aud Nicotine (iii) Terpenoids and Carotcueids:Menthol, Citral, Lycopene and Carotene (Biosyrlthetic aspects should be addressed)UNIT-11 Modern Asymmetric Syuthesis: (a) Principles of asyrrunetric reaction ands)11thesis; Kinetic resolution, Dynamic kinetic resolution (DKR) and autocatalyticreactions; Chemo-, regio-, diastereo- and enantio-controlled approaches; Chirality transferand relay; Asyrrunetric inductions; Chiral pools, auxiliaries and templates. (b) Asymmetricoxidations and Reductions: Sharpless asyrrunetric epoxidation, dihydroxylation, Reduction ofketones, imines and olefins.UNIT-III Materials Synthesis: Solid state synthesis, preparation ofthin films, Growhl. ofsingle crystals, synthesis ofuanomaterials (Top-down and bottom-up approach).

UNIT-IV Characterization and Properties: X-ray diffraction, Scanning prubemicroscopy, Electron microscopy. Electrical, Magnetic and Optical properties of Materials.

Books and References1. J. Claydell, N. Greeves, S. Warren and P. Wothers; Organic chemistry: Oxford UniversityPress.:

-2. Jerry March; Advanced Organic Chemistry Reactions, Mechanism and Structure:JohnWiley and Sons.

3. A. R. West, Solid State Chemistry and;'ts Applications, John Wiley & Sons, 1984.4. EmestL. Eliel; Asymmetric Reactions and Processes in Chemistr)'.5. K. Chakrabarty, Solid State Chemistry, New Age Publishers. 1996.6. Bud,1y D.Ratner, Allan S. Hoftil1an, Hiomaterials Science, S.xond Edition: Wiley S<.:ience2004.

'1, JOOrJ Park, R. s. Lakes~ Blcm,ateriais AJV InlYuduction, Spring;':T; 2010.

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SEMESTER - IVPAPER-XVII(CH-~ '102-)

BIOCHEMISTRY /

Marks-10+40

UNIT-I Biophysical Chemistry 1: Introduction, chemical and biological catalysis, remarkableproperties of enzymes like catalytic power, specificity and regulation. Nomenclature andclassification. Fishers lock and key and koshland's induced fit hypothesis, concept andidentification of active site by the use of inhibitors, affinity, labeling and enzyme modit'ication

by site directed mutagenesis.

:lismenten and lineweaver-burkplots, reversible and irreversible inhibition. Transition-state theory, orientation and steric effect,acid base catalysis, covalent catalysis, strain or distortion.

UNIT-III Bioorganic Chemistry 1: Example of some typical enzyme mechanism:

chymotrypsin, ribonuclease, lysozyme, carboxypeptidase A. Cofactor.s as derived from /vitamins, coenzymes, prosthetic groups, ap6enzymes. Structure and biological functions ofcoenzyme A, Thiamine pyrophosphate, pyridoxal phosphate, NAD+, NaDP+, FMN, FAD,

lipoic acid, 'vitamin B12. • • • ••, •

•

,UNIT-IV Bioorganic Chemistry 2: Mechanism. of reactions catalyzed by cofactors.Nucleophilic displ~ement on a phosphorous atom, multiple displaq:ment reaction and. ,coupling of ATP cleavage to endergonic processes, transfer of sulphate, addition andelimination reactions, enolic intermediates in the isomerization reactions, ~ cleavage andcondensation, isomerization, rearrangement, carboxylation, decarboxylation.

Books and References1. Bioorganic Chemistry: A chemical approach to enzyme action-Hermann Dugas, C. Penny,

Springer Verlag.

2. Biochemistry (The Chemical reactions ofliving cells): D. E. Metzler, (Academic Press)3. Enzyme chemistry Impact and applications, Ed. Collin J. Sucklins, chapman and Hall

.4. Enzyme reaction mechanisim: C. Walsh and W. H. Freeman.5. Enzyme structure and mechanisim: A. Fersht and W. H. Freerpan.6. Fundamentals ofBiochemistry: A. C. Daeb, New Central Book Agency, pvt. Ltd.7. Biochemistry: C. B. Powar and G. R. Chatwal, Himalaya publishing House.

22

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8. Pricipleof Biochemistry (Lehninger): D. L. Nelson and M. M. Cox, W. H. Freeman andcompany, New York.

9. Fundamentals ofBiochemistry: D. Voet, J. G. Voet and C. W. Pratt; John wiley and sons.10. Inorganic Chemistry ofBiological process- M. Huges.11. Bio Inorganic Chemistry - E. Ochiai

SEMESTER ~ IV

. PAPER-XVIII (CH-~4~J)BIOINORGANIC AND SUPRAMOLECULAR CHEMISTRY

UNIT -I Biological roles of metal ions, Calcium Biochemistry, Oxygen Transport and storage:Hemoglobin, Myoglobin, Cobalt containing models of oxygen binding, Iron containing modelsof oxygen carrier, Hemocyanin; Iron storage and transport: Ferritin, Transferrin, Siderophores.

t 'UNIT-II Enzymes exploiting acid catalysis: Carbonic anhydrase, Carboxypeptidases,Superoxide dismutase, Xanthine oxidase. Redox catalysis: Iron-sulfur proteins: FerredoJUv.s and

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• Rubbredoxins, N0ll-heme iron, Cytochromes,. Cy\ochrome P-450 en~mes, Blue CopperProteins, Coenzyme B12 Nitrogen Fixation, Photosynthesis.

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UNIT-III Metals in medicine: Ionophores, !Jpportance of Na and K, Metal deficiency and ,.

diseases, Toxic effects of metals, Metals used for diagnosis and chemotherapy, Anticancerdrugs.

UNlT-IV Supramolecular Chemistry: Host guest chemistry, chiral recognition and catalysis,liJ.olecular recognition, biomimetic chemistry, crown ethers, cryptates. Cyclodextrine,cyclodcxtrinbased enzyme models, calixarenes, Ionophores.

Books lind References:

1. Priciph! of Biochemistry (Lehninger): D. L Nelson and ¥. M Cox, W. H. Freeman andcompany, New York.

Fundamentals ofBiochemistry: D. Voet, J. G. Voet and C. W,.Pratt; John wiley and sons.Inorganic; Chemistry ofBiological process- M. Huges.Bio Inorganic Chemistry - E. Ochiai

23

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SEMESTER- IV

PAPER- 404

COMPUTER APPLICATION IN CHEMISTRY

Marks: - 15+60

UNIT-I: Introduction to Computers

Basic structure of a computer: The CPU, the I/O devices, the internal memory,commonly used secondary storage media. Data representation: Overview of binary,octal and hexadecimal number system. The software: Concept oflow level and highlevel languages, Compiler interpreter, editor, operating system concepts, salientfeatures ofMS-DOS. Windows operating systems.

UNIT-II: Programme Development Process

Algorithm, Flowchart, Decision-table, elements of high level programminglanguages. Input-output statements, conditional statements, control structure,concept of data file, file operations like searching, storing, with reference to CProgramming.

UNIT-III: Computer Programming in C

Elements of the computer language. Constants and variables. Operations andsymbols. Expressions. Arithmetic assignment statement. Input and Output. Formatstatement. Termination statements. Branching statements such as IF or GO TOstatement. LOGICAL variables. Double precision variables. Subscripted variablesand Dimension. DO statement. FUNCTION and SUBROUTINE. COMMON andDATA statements. (Students learn the programming logic and these languagefeatures by 'hands on' experience on a personal computer from the very beginningof this topic).

UNIT-IV: Programme in Chemistry

Development ofsmall computer codes involving simple formulae in chemistry, suchas van cler Waals equation, pH titration, kinetics, radioactive decay.

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SEMESTER -IVPAPER-405

(GENERAL CHEMISTRY:PRACTICAL)F.M.I00 Time: 6 hr

, Phase equilibria: '-I. Determination of critical solution temperature ofphenol-water system.

2. Construction of phase diagram for a three component system (chloroform­acetic acid -

water).

Electrochemistry:1. D~ermiBatiGB ef stHlIlgth ef StroBg aeia aHa Wllak aeia iB glVoo

mixture conductometrically.

2. Determination of solubility and solubility product of a sparingly soluble salt (i.e.,PbS04, BaS04) conductometrically.

3. Determination of strength ofhalides in a mixture potentiometrically.

4. Determination of the formation constant of silver amine complex and stochiometry

of the complex potentiometrically.

5. Estimation of ferrous iron in ferrous ammonium sulphate potentiometrically.

6. Potentiometric titration of a strong acid with strong base using quinhydroneelectrode.

7. Determination ofpartial molar volume of solute (e.g. KCI) and solvent in binarymixture.

8. Determination of stoichiometry and stability constant of inorganic (e.g. ferrlc-

salicylic acid) and organic (amine-iodine) complex.

9. Verification of Beer's law.

10. Determination of first and second ionization constants ofphosphoric acid by pHmeter.

II. Determination ofhydrolysis constant of aniline hydrochloride by pH meter.

12. Verification of Debye-Huckel-Onsagar equation of conductance.

13. Determination ofhydrolysis constant of aniline hydrochloride conductometrica1ly.

Books and References:I. Experimental physical chemistry: R. C. Das and B. Behera, Tata McGraw Hill.

2. Findlay'spractical chemistry (revised): B. P. Levitt, Longman.3. Advancedpractical physical chemistry: 1. B. Yadav, Goel publishing house, Meerut.

•

SEMESTER -IVPAPER-406Dissertation

Marks-200

The dissertation shall comprise of conducting a small project under facultymembers of the department. The title and execution of the project work shall bedecided in consultation with the faculty members ofthe dept by a committee constitutingHOD and other senior faculty members. The committee may also extend the provision ofco-opting the external guide as-pe!' the provision pliOvided by tb fiai erOOmy J lpi"€r~" I.. /p v

In general, the student is expected to do literature survey in the assigned topic, and to do Urv'V-fvYJsome kind of experimental investigation, and result analysis. However, final decisionregarding the execution ofproject work rests with the supervisor/co-supervisor and thecommittee on mutual discussion to the best benefit of the student for academic career. Theguideline provided by

UGC shall be also taken into account in this regard.

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