dbt-ict technology platforms for advanced biofuels · 2018. 3. 19. · the dbt-ict rapid-ad...
TRANSCRIPT
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DBT-ICT Technology PlatformsFor Advanced Biofuels
Arvind LaliDBT-ICT Centre for Energy Biosciences
Institute of Chemical TechnologyMumbai, India
EU-India Conference on Advanced BiofuelsMarch 6-8 2018
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DBT-ICT Centre for Energy BiosciencesInstitute of Chemical Technology
Matunga, Mumbai
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DBT-ICT Centre of Energy Biosciences(Sanctioned Dec 2007; Functional May 2009)
- India’s first National Bioenergy Research CentreThe Department of Biotechnology, Ministry of S&T, India
- Set up at a cumulative cost of about 15 million USD
- Multidisciplinary State-of-the-Art facility for developing andtranslating cutting-edge technologies
- Networked with Institutions & Industry in India and abroad
>60 PhD scholars; >10 Senior Research Scientistsin different disciplines of modern biological sciences and chemicalengineering/technology
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DBT-ICT Centre of Energy BiosciencesA State-of-the-Art Laboratories
Modern Biology
ChemicalEngineering
Chemistry
TECHNOLOGY
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BioDiesel Ethanol BioGas
The three ‘inadequate’ alternatives
Vegetable Oil Cane Molasses Bio-Waste
No non-edibleOils
InadequateFeedstock &
The FvF-debate
TechnologyLimitationsToo Slow !!Low yields!!
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BioDiesel Ethanol BioGas
Development of Energy Oil Crops/Algae
Use of agriculturalResidues/Waste
Use of agri-wasteand MSW
Aimed at >5% diesel
blending
Aimed at>5% Petrolblending
Aimed at>5% replacement
of LPG/CNG
The three alternatives andThe DBT-ICT Solutions
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Simple Sugars; Lignin monomers; CHO-Molecules
Carbon Sources: Solid; Liquid; GasAgri-residues; Municipal Wastes; Industrial Wastes
The three alternatives andThe DBT-ICT Solutions
Fuel Molecules and Materials/Chemicals
The Platform
Ethanol; Methane; Methanol; ‘Green’ Diesel; Hydrogen
Green PET; PLA; Acrylate; Butadiene; Solvents;
Organic acids/Chemicals
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Waste to Fuel InnovationsThe DBT-ICT Technology Platforms
(1) Lignocellulosic Sugars(2) Catalytically Thermo-Liquefied CTL-Oil
(3) Lignin Hydrolysate
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PLATFORM 1DBT-ICT 2G-Alcohol/Sugars/Lignin Technology
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Lignocellulosic Biomass
Pre-Treatment Step
Saccharification
Separation
Fermentation/Purification Sugars/Lignin/Alcohol
PRO
CESS
OU
TLIN
E STEP 1
STEP 2
STEP 3
STEP 4
Fractionation to Sugars/LigninRapid & Efficient Process
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March 2016
The DBT-ICT 2G-Sugars/Ethanol Technology
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BIRAC SUPPORTED10 ton biomass/day
Lignocellulosic Ethanol Demonstration PlantIndia Glycols Limited, Kashipur
World’s First Multi-feedstock Continuous 2G-Ethanol Plant
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DBT-ICT 2G-Alcohol TechnologySix Novel Processing Segments
1. Biomass Fractionation2. Enzyme Hydrolysis3. HCD Fermentation4. Silica Recovery (Rice straw)5. Water/Reagent Recovery6. Recovery of inorganic Fertilizer
Four Established Supporting SegmentsAdded as established Plug-in Modules from known vendors
7. Alcohol Purification8. Lignin concentration (similar to pulping mills)9. Steam Production (similar to pulping mills)10. Power Production (similar to any cogen plants)
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Technology being scaled up to commercial scale 2G-Ethanol plants by
Hindustan Petroleum Corp. and Bharat Petroleum Corp.Engineering Partners: L&T Hydrocarbon Engineering
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SugarsLignin
ProteinsLipids AlcoholsOrganic AcidsFatty AcidsAmino AcidsTerpenoidsHydrocarbons
E. Coli
S. Cereviseae
Corynebacteria
Clostridia sp.
Yarrowia sp.
Pseudomonas sp.
Cyanobacteria
Algae
Methanotrophs
Synthetic Biology & FermentationBiotechnology at the DBT-ICT Centre
BiomassTerrestrialMarine/Aquatic
Designed Microorganisms
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SugarsLignin
ProteinsLipids AlcoholsOrganic AcidsFatty AcidsAmino AcidsTerpenoidsHydrocarbons
E. Coli
S. Cereviseae
Corynebacteria
Clostridia sp.
Yarrowia sp.
Pseudomonas sp.
Cyanobacteria
Algae
Methanotrophs
Synthetic Biology & FermentationBiotechnology at the DBT-ICT Centre
BiomassTerrestrialMarine/Aquatic
Designed Microorganisms
3 Demonstration/Pilot Scale High Value-Multiproduct Biorefineries
to be Operational in 2018
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PLATFORM 2DBT-ICT Catalytic Thermo-Liquefaction Technology
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Industrial Waste
DBT-ICT CTL-Technology
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CTLCatalytic Liquefaction
150°C, 15 Bar Pressure
Wet/Dry BiomassCTL-Oil
DBT-ICT CTL-Technology
Features- NOVEL LIQUID catalyst- Temperature ~150°C- Oil yield >90% ; near 100% C-efficient- Recoverable and Reusable Catalyst
Catalytic Thermo-Liquefaction (CTL)
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Sr .N o En try Re s u lts 1 Co lo r D a rk b ro w n
2 D e n sity 0 .9 5 -1 .0 4 g m /m L
3 Ca lo rific V a lu e 2 2 -2 5 M J/Kg 4 pH 5 -6
5 Ele m e n ta l com po sit io n (C ,H ,N ,S an d O )
C arb o n : 5 5 % , H y d rog e n : 6 % , N itro ge n : 0 .8 % S u lfur:0 .2 2 % O x yge n : 3 8 %
6 A sh co nte nt (b y grav im e tric an aly sis ) 0 .5 -1 %
7 S tab ilit y S ta b le a t n o rm a l sto ra ge co nd itio n s
8 Ch e m ical co m p o sit io n (by G C -M S)
A ro m a tics, h yd ro ca rb o n s(C 5-C 2 2) , e ste rs , a lco h o ls, p h e n ols , a ld e h yd e s, k e to n e s, carb ox ylic ac ids (C 5 -C 1 8) e tc.
9 F lash Po in t 6 6 -7 0 °C 1 0 Po u r p o in t 1 0 -1 5 °C 1 1 V isco sity 16 5-250 c P
1 2 P icto r ia l im ag e o f O il sa m p le
Fuel Oil OrCTL-Oil
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CTL/Fuel Oil
CatalyticUpgradation
(dehydration/hydrotreating)
Cracking/Distillation
Gasoline/Diesel
Anaerobic Digestion
Cleaning/Purification
Biogas
Methane (Bio-CNG)
Furnace OilShipping Fuel
Boiler Oil(Power)
Direct Use
Pathways for using CTL-Oil produced
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BioWaste
Hydrolysis
Acidogenesis/Acetogenesis
Methanogenesis
TRAD
ITIO
NAL
BIO
GAS
PRO
CESS
OU
TLIN
E
Biogas
The AnaerobicDigesterProcess Envelope
Organic acids
The Utilizable Carbon forms
Sugars and Phenolics20
-40
days
< 50% Yield of MethaneWaste
(fertilizer)
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Technology for Improved Production of Biogas and Bio-CNG from WasteThe DBT-ICT Rapid-AD Technology
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The DBT-ICT Rapid-AD Technology
Salient features of the Rapid-AD Technology- Can handle any bio-waste (incl. agri-waste) dry or wet- Generates biogas within 24 hours - Gives >90% methane yields - Zero waste generation technology- Waste-to-Profit technology for private enterprise
Being scaled up to - 1 ton MSW/day Demonstration Plant- 200 ton Bio-waste/day Commercial Scale Plant
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BioDiesel Ethanol BioGas
Development of Energy Oil Crops
Use of agriculturalResidues/Waste
Use of agri-wasteand MSW
Aimed at >5% diesel
blending
Aimed at>5% Petrolblending
Aimed at>5% replacement
of LPG/CNG
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The three alternatives: Next Steps
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Algae Science and TechnologyAlternative Feedstock for Biofuel & Bioproducts
DBT-ICT Centre for Energy BiosciencesInstitute of Chemical Technology
Mumbai
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Development of Rapid Growing and High Oil YieldingMicro-Algae and Micro-organisms
Conversion to Bio-Oil/Bio- crude As Feedstock for Energy
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Energy
Fuel and Chemicals
The Final Frontier
ICT-HarvardCatalytic/Solar Water Splitting Technology
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Collaboration with Harvard University, USA
H2O + Sunlight Hydrogen Fuels/Chemicals
CO2
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Thank you