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Developing Grease Technology to Meet Key Performance Requirements with Specifc Focus on Mining 2 nd Asian Industrial Lubricants Conference | November 13, 2019 | Singapore | Anuj Mistry

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Page 1: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Developing Grease Technology to Meet

Key Performance Requirements with

Specifc Focus on Mining

2nd Asian Industrial Lubricants Conference

| November 13, 2019 | Singapore | Anuj Mistry

Page 2: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Agenda

l 2

| Lubricating Grease Chemistry and Market Overview1

| Grease Components - Optimized Lubrication 2

| Lubrication Requirements for General End-User Applications 3

| Mining Application Grease Requirements, Challenges & Solutions 4

| Grease Technology Evolution and Opportunities in Mining 5

| Summary – Effective Mining Equipment Lubrication 6

Page 3: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Lubricating Grease Chemistry and Market Overview01

Page 4: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Grease Market 2018 & Evolution since 2014by Chemistry

l 4

51%

21%

8%

6%

5%4%

4%

1% 0%

Lithium

Lithium Complex

Calcium

Polyurea

Others*

Aluminium Complex

Calcium Sulfonate

Calcium Complex

Aluminium

1,17 Mn

mt

Market Volume

-2,0%

2.8%

4.3% 3.9%

-0.6%

4.9%

9.4%

1.9%

8.7%

-5%

0%

5%

10%

*Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners – All non-soap thickeners except Clay

Source: NLGI Grease Production Survey Report 2018

CAGR 2014 - 2018

Page 5: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

l 5

-2,4%

4.2%

-1.8%

7.6%

1.4%0.7%

5.9%

-2.5%

-5%

0%

5%

10%

Grease Market 2018 & Evolution Since 2014by Region

Market Volume*

51%

20%8%

9%

7%

4%

4% 3%

China

Europe

North America

India / IndiaSubcontinent

Japan

Pacific / Southeast Asia

Africa & Middle East

Caribbean, Central &South America

1,17 Mn

mt

Market Volume

Source: NLGI Grease Production Survey Report 2018

CAGR 2014 - 2018

Page 6: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Grease Components - Optimized Lubrication 02

Page 7: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Grease Components - Optimized Lubrication

l 7

Thickener Types Base Oils Additives

Lithium 12-hydroxy stearate Mineral Anti-oxidants

Lithium-calcium mixed soap Polyalphaolefin (PAO) Rust inhibitors

Calcium soap Alkylated Aromatics Extreme Pressure

Lithium complex Diester & Polyol Ester Anti-Wear

PolyureaPolyalkylene Glycol (PAG) Corrosion inhibitors

Calcium sulfonate Perfluoroalkyl Ethers (PFPE) Tackifiers

Calcium sulfonate complex Dimethyl & Phenyl Methyl SiliconeSolid lubricants (MoS2, graphite, zinc oxide,

PTFE, PE, dyes)

Bentones, silica Vegetable Oils

Aluminum Complex

The choice of thickener, base oil type, base

oil viscosity, and additives is important

Page 8: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Grease Components - Optimized Lubrication

l 8

Application Expectation Core Grease Requirements

Wide operating temperature rangeOxidation resistance, good rust protection, good pumpability,

good low temperature torque, high temperature thickener

Low operating temperature Low NLGI grade, low thickener content, low base oil viscosity,

base oil of low pour point, good rust protection

High operating temperature

Oxidation resistance, high temperature thickener, high NLGI

grade, high base oil viscosity

Water ingressTackiness, low washout and spray-off, appreciable

consistency, good rust protection

Extreme pressure at critical points Consider solid additives, high base oil viscosity, high EP and

low wear characteristics

Multipurpose Good oxidation resistance, good rust protection, water

resistance, Antiwear and EP characteristics

Page 9: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Lubrication Requirements for General End-User

Applications

03

Page 10: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

10

Lubrication Requirements for General End-User Applications – Steel Mills

Caster Bearings, Roll Stands, Coilers, Hot Mill Rolling

Heat, Load, Water, Pumpability, Reversibility, Shear Stability

Lithium Complex, Aluminium Complex, Calcium Sulfonate Complex, Bentone

Mineral oil synthetic base, Typically NLGI 1, 1.5

High base oil viscosity

Page 11: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Lubrication Requirements for General End-User Applications – Industrial

11

Lawn and Garden

Mechanical Stability

Lithium Complex, Bentone

Mineral oil synthetic base

Typically NLGI 2

Post Tensioning

Corrosion Protection

Calcium

Mineral Oil

Typically NLGI 2

Forge PressHeat, Mechanical

Stability, Pumpability

Lithium

Mineral Oil

Typically NLGI 1, 1.5

Garage DoorsCorrosion Protection,

Mechanical Stability

Lithium

Synthetic Oil

Typically NLGI 2

Page 12: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

12

Agriculture

Chemical Resistance

Corrosion Protection

Mechanical Stability, Wet Environment

Shock Loads

Grease Pumpability

Calcium Sulfonate Complex, Lithium Complex, Polyurea

Mineral Oil

Typically NLGI 2, NLGI 0/00

Construction

Corrosion Protection, Mechanical Stability

Shock Loads

Lithium, Lithium Complex, Calcium ComplexSulfonate

Mineral Oil, Semi-Synthetic

Typically NLGI 2

Lubrication Requirements for General End-User Applications – Construction

& Agriculture

Page 13: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Mining Application Grease Requirements, Challenges

& Solutions

04

Page 14: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Mining Application Grease Requirements, Challenges & Solutions

14

Equipment

Excavators

Shovels

Draglines

Loaders

Graders

Haul Trucks

Conveyer Belts

Longwall

Processing Plants

Applications

Pins & Bushings

Hoist Bearings

Slew Bearings

Electric Motor Bearings

Ball Joints

Centralized Lube System

Airlock

Open Gears

Challenges

Heavy Loads

Shock Loads

Wet Environments

High Temperature

Corrosion

Low Temperature Pumpability

THERE IS NO TIME FOR EQUIPMENT DOWNTIME

Page 15: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Mining Application Grease Requirements, Challenges & Solutions

15

CHALLENGES THICKENER CONSIDERATIONBASE OIL

VISCOSITYADDITIVATION

NLGI

GRADE

Heavy LoadsCalcium Sulfonate Complex, Lithium Complex,

Aluminum ComplexHigh MoS2, other solids 1.5, 2

Shock LoadsCalcium Sulfonate Complex, Lithium Complex,

Aluminum ComplexHigh MoS2, other solids 1.5, 2

Wet Environments Calcium Sulfonate Complex, Aluminum Complex Medium to High Polymers 1.5, 2

High Temperatures Calcium Sulfonate Complex, Polyurea High MoS2, other solids 1, 1.5, 2

Low Temperature

Pumpability

Calcium Sulfonate Complex, Aluminum ComplexLow to Medium - 1, 1.5

CorrosionCalcium Sulfonate Complex, Lithium Complex,

Aluminum Complex

Medium to HighAnticorrosion 1, 1.5, 2

High Speeds Polyurea, Calcium Sulfonate Complex Low to Medium Anti-Oxidants 2

Page 16: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Grease Technology Evolution and Opportunities in

Mining

05

Page 17: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Grease Technology Evolution and Opportunities in Mining

l 17

Grease Performance

ASTM D1264 – Water Washout

ASTM D 1831 Modified Roll Stability - Ability of grease to withstand water environment under severe

mechanical shear; grease consistency change is measured.

0

1

2

3

4

5

6

7

Calcium

Sulfonate

Complex

Aluminum

Complex

Lithium Complex

3.5

4.2

6.5

% Water Washout as a Function of Lubricating Grease

Thickener Type

Type of Grease

Thickener

Modified Shell Roll Stability %

Change

Calcium Sulfonate

Complex-10 (hardened)

Aluminum Complex -2.7 (hardened)

Lithium Complex + 7.7 (softened)

Page 18: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Grease Technology Evolution and Opportunities in Mining

l 18

Grease Performance

ASTM D2596 – Weld Load & Load Wear Index

DIN 51819-2 FE-8 Bearing Wear Test

Grease Type Weld Point (kgf) LWI (kgf)

Unadditized Lithium Complex Grease 160 20

Unadditized Aluminum Complex Grease 160 25

Unadditized Calcium Sulfonate Complex Grease 500 60

EP Additized Lithium Complex Grease 500 65

EP Additized Aluminum Complex Grease 400 50

EP Additized Calcium Sulfonate Complex Grease >800 160

CALCIUM SULFONATE COMPLEX NLGI 1 WITH 10% WATER

Tapered roller bearing, of type 31312 @ 1500 RPM, 10 KN Load

PASS – 524 HRS, 0.003% WEAR, NO BLEED, LOW TORQUE

Page 19: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Grease Technology Evolution and Opportunities in Mining

l 19

Lithium Complex - require additivities for sustained load carrying, heat, mechanical stability and water

handling

Aluminum complex -exhibit reversibility, require additivities for sustained load carrying, heat,

mechanical stability and water handling

Polyurea - exhibit exceptional thermal stability, low oil bleed behavior, oxidation stability and

mechanical stability

Calcium Sulfonate Complex -Provides holistic solutions

High soap content – high mechanical stability and high load carrying capacity

Inherent corrosion protection and extremely tolerant to wet environments

Excellent for handling water, heat and load

Page 20: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Summary – Effective Mining Equipment Lubrication 06

Page 21: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Summary – Effective Mining Equipment Lubrication

l 21

Mining Industry Today

Very demanding

Associated equipment is much larger and faster

Equipment availability at all times is key to success……no time for equipment downtime!

Grease Technology

Lithium and aluminum based greases will continue to play a key role.

Sustainable solutions through Calcium Sulfonate Complex and polyurea will continue to grow

Effective use of solid lubricant additives will make a difference

Page 22: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Acknowledgements

l 22

My sincere thank you to the

FUCHS PETROLUB SE

team for their suppport.....

Christopher Liebig

(Head of Global Product

Management Greases)

Jörg Wehrle

(Vice President Global

Product Management

Strategy)

Page 23: Developing Grease Technology to Meet Key Performance ... · *Others: Sodium Soap, other Metallic Soap, Organophilic Clay Thickeners, other Non-soap Thickeners –All non-soap thickeners

Thank you very much for your attention.