distillation and molecular sieves: a … of distillation.pdf · l viewpointl viewpoint. cincinnati,...
TRANSCRIPT
ALCOHOL
DISTILLATDISTILLATMOLECULAMOLECULA
A PRACTICAA PRACTICAA PRACTICAA PRACTICA
L SCHOOL
ATION ANDATION ANDAR SIEVES:AR SIEVES:
L VIEWPOINTL VIEWPOINTL VIEWPOINTL VIEWPOINT
FUNDAMFUNDAMFUNDAMFUNDAMFUNDAMFUNDAMOO
FUNDAMFUNDAMOOOO
DISTILLDISTILLOO
DISTILLDISTILLDISTILLDISTILLDISTILLDISTILL
MENTALSMENTALSMENTALSMENTALSMENTALSMENTALSOFOFMENTALSMENTALSOFOFOFOFLATIONLATION
OFOFLATIONLATIONLATIONLATIONLATIONLATION
TYPICAL DITYPICAL DIRELATIORELATIO
TYPICAL DITYPICAL DIRELATIORELATIORELATIORELATIORELATIORELATIOVAPOURVAPOUR
LOWERTEMPERATURE
FEEDFEEDFEEDFEED`
THERMALTHERMALENERGYENERGY BOILING
VAPOUR
ENERGYENERGYHIGHER
TEMPERATURE
BOILINGLIQUID
BOTTOMS PRODBOTTOMS PROD
ISTILLATIONISTILLATIONONSHIPSONSHIPSISTILLATIONISTILLATIONONSHIPSONSHIPSONSHIPSONSHIPSONSHIPSONSHIPS
CONDENSERCONDENSER
REFLUXREFLUX OVERHEADOVERHEAD
COOLING WATERCOOLING WATER
REFLUXREFLUXLIQUIDLIQUID
OVERHEADOVERHEADPRODUCTPRODUCT
TRAYSTRAYS(CONTACTING DEVICES)(CONTACTING DEVICES)
DUCTDUCT
VAPOURVAPOUR--LIQUIDLIQUIDVAPOURVAPOUR--LIQUIDLIQUIDETHANOLETHANOLETHANOLETHANOL
D EQUILIBRIUMD EQUILIBRIUMD EQUILIBRIUMD EQUILIBRIUMLL--WATERWATERLL--WATERWATER
100
90
80
70
MOLE %ETHANOL
60
50ETHANOL
IN VAPOUR 40
30
20
10
0 10 20 30 40
MOLE % ET40 50 60 70 80 90 100
THANOL IN LIQUID
100
90
80
70
MOLE %ETHANOL
60
50ETHANOL
IN VAPOUR 40
30
20
10
0 10 20 30 40
(10 VOLUM(10 VOLUM
MOLE % ET40 50 60 70 80 90 100
ME % FEED)ME % FEED)
THANOL IN LIQUID
100
90
80
70
MOLE %ETHANOL
60
50ETHANOL
IN VAPOUR 40
30
20
10
0 10 20 30 40
(10 VOLUM(10 VOLUM
MOLE % ET40 50 60 70 80 90 100
ME % FEED)ME % FEED)
THANOL IN LIQUID
100
90
80
70
MOLE %ETHANOL
60
50ETHANOL
IN VAPOUR 40
30
20
10
0 10 20 30 40
(10 VOLUM(10 VOLUM
MOLE % ET40 50 60 70 80 90 100
ME % FEED)ME % FEED)
THANOL IN LIQUID
100
90
80
70
MOLE %ETHANOL
60
50ETHANOL
IN VAPOUR 40
30
20
10
0 10 20 30 40
(10 VOLUM(10 VOLUM
MOLE % ET40 50 60 70 80 90 100
ME % FEED)ME % FEED)
THANOL IN LIQUID
100
90
80
70
MOLE %ETHANOL
60
50ETHANOL
IN VAPOUR 40
30
20
10
0 10 20 30 40
(10 VOLUM(10 VOLUM
MOLE % ET40 50 60 70 80 90 100
ME % FEED)ME % FEED)
THANOL IN LIQUID
100
90
80
70
MOLE %ETHANOL
60
50ETHANOL
IN VAPOUR 40
30
20
10
0 10 20 30 40
(10 VOLUM(10 VOLUM
MOLE % ET
AZEOTROPE 194.4AZEOTROPE 194.4PROOFPROOF
40 50 60 70 80 90 100
ME % FEED)ME % FEED)
THANOL IN LIQUID
100
90
80
70EQUILIBRIUM CURVEEQUILIBRIUM CURVE
MOLE %ETHANOL
60
50ETHANOL
IN VAPOUR 40
30
20
10
0 10 20 30 40
(10 VOLUM(10 VOLUM
MOLE % ET
AZEOTROPE 194.4AZEOTROPE 194.4PROOFPROOF
40 50 60 70 80 90 100
ME % FEED)ME % FEED)
THANOL IN LIQUID
STRUCTURING THSTRUCTURING THSTRUCTURING THSTRUCTURING THSYSTEM SSYSTEM SSYSTEM SSYSTEM S
HE DISTILLATIONHE DISTILLATIONHE DISTILLATIONHE DISTILLATIONSTRATEGYSTRATEGYSTRATEGYSTRATEGY
STRIPPING SYSTSTRIPPING SYST
100
RECTIFYINGRECTIFYING
90
80EQUILIBRIUM CURVEEQUILIBRIUM CURVE
MOLE %
70
60
EQUILIBRIUM CURVEEQUILIBRIUM CURVE
MOLE %ETHANOL
IN VAPOUR
50
40
30
20
(10 VOLUM(10 VOLUM
0 10 20 30 40
10
0STILLAGESTILLAGE
MOLE % ETHSTILLAGESTILLAGE
TEMTEM DEHYDRATIONDEHYDRATION
G SYSTEMG SYSTEMANHYDROUS ANHYDROUS PRODUCTPRODUCT
SYSTEMSYSTEM
AZEOTROPE 194.4AZEOTROPE 194.4PROOFPROOF
PRODUCTPRODUCT
PROOFPROOF
SPIRITSPIRIT
E % FEED)E % FEED)
50 60 70 80 90 100
HANOL IN LIQUID
OPERATIOPERATIOPERATIOPERATIOPERATIOPERATIOPERATIOPERATILocus of possible coLocus of possible coliquid and vapour pliquid and vapour pa given energy inpua given energy inpua given energy inpua given energy inpu
ING LINEING LINEING LINEING LINEING LINEING LINEING LINEING LINEoncentrations of oncentrations of
passing in tower for passing in tower for utututut
100
90EQUILIBRIUM CURVEEQUILIBRIUM CURVE
80
70
EQUILIBRIUM CURVEEQUILIBRIUM CURVE
MOLE %ETHANOL
60
50ETHANOL
IN VAPOUR 40
30 OPOPSTST20
10
STSTTYPICALTYPICAL
MOLE % E0 10 20 30 40
0STILLAGESTILLAGE
(0.02 WT. %)(0.02 WT. %)BEER FEEDBEER FEED MOLE % EBEER FEEDBEER FEED
(10 VOLUME %)(10 VOLUME %)
AZEOTROPEAZEOTROPE190 PROOF190 PROOFSPIRITSPIRIT
AZEOTROPEAZEOTROPE
PERATING LINEPERATING LINETRIPPINGTRIPPINGTRIPPINGTRIPPINGL L/V = 5.0L L/V = 5.0
THANOL IN LIQUID50 60 70 80 90 100
THANOL IN LIQUID
100
90EQUILIBRIUM CURVEEQUILIBRIUM CURVE
80
70
EQUILIBRIUM CURVEEQUILIBRIUM CURVE
MOLE %ETHANOL
60
50ETHANOL
IN VAPOUR 40
30
20
10
MOLE % E0 10 20 30 40
0STILLAGESTILLAGE
(0.02 WT. %)(0.02 WT. %)BEER FEEDBEER FEED MOLE % EBEER FEEDBEER FEED
(10 VOLUME %)(10 VOLUME %)
AZEOTROPEAZEOTROPE190 PROOF190 PROOFSPIRITSPIRIT
AZEOTROPEAZEOTROPE
OPERATING LINEOPERATING LINERECTIFYINGRECTIFYINGRECTIFYINGRECTIFYING
THANOL IN LIQUID50 60 70 80 90 100
THANOL IN LIQUID
100
90EQUILIBRIUM CURVEEQUILIBRIUM CURVE
80
70
EQUILIBRIUM CURVEEQUILIBRIUM CURVE
MOLE %ETHANOL
60
50ETHANOL
IN VAPOUR 40
30 OPOPSTST20
10
STSTTYPICALTYPICAL
MOLE % E0 10 20 30 40
0STILLAGESTILLAGE
(0.02 WT. %)(0.02 WT. %)BEER FEEDBEER FEED MOLE % EBEER FEEDBEER FEED
(10 VOLUME %)(10 VOLUME %)
AZEOTROPEAZEOTROPE190 PROOF190 PROOFSPIRITSPIRIT
AZEOTROPEAZEOTROPE
OPERATING LINEOPERATING LINERECTIFYINGRECTIFYING
PERATING LINEPERATING LINETRIPPINGTRIPPING
RECTIFYINGRECTIFYING
TRIPPINGTRIPPINGL L/V = 5.0L L/V = 5.0
THANOL IN LIQUID50 60 70 80 90 100
THANOL IN LIQUID
VAPOURVAPOUR--LIQUIDLIQUIDVAPOURVAPOUR--LIQUIDLIQUIDSTAGE ASTAGE ASTAGE ASTAGE A
D EQUILIBRIUMD EQUILIBRIUMD EQUILIBRIUMD EQUILIBRIUMANALYSISANALYSISANALYSISANALYSIS
TYPICAL - 14 REC- 8 STR
100
90EQUILIBRIUM CURVEEQUILIBRIUM CURVE
- 8 STR
80
7033
EQUILIBRIUM CURVEEQUILIBRIUM CURVE
MOLE %ETHANOL
60
50 22
33
ETHANOLIN VAPOUR 40
30 1 OPOPSTST20
10
STSTTYPICALTYPICAL
MOLE % E0 10 20 30 40
0STILLAGESTILLAGE
(0.02 WT. %)(0.02 WT. %)BEER FEEDBEER FEED MOLE % EBEER FEEDBEER FEED
(10 VOLUME %)(10 VOLUME %)
CTIFYING STAGES RIPPING STAGES
88 99 1010 1111 121213131414
RIPPING STAGES
AZEOTROPEAZEOTROPE190 PROOF190 PROOFSPIRITSPIRIT44
55 66 77
AZEOTROPEAZEOTROPE
OPERATING LINEOPERATING LINERECTIFYINGRECTIFYING
PERATING LINEPERATING LINETRIPPINGTRIPPING
RECTIFYINGRECTIFYING
TRIPPINGTRIPPINGL L/V = 5.0L L/V = 5.0
THANOL IN LIQUID50 60 70 80 90 100
THANOL IN LIQUID
VAPOURVAPOUR--LIQUIDLIQUIDSTAGE ASTAGE A
VAPOURVAPOUR--LIQUIDLIQUIDSTAGE ASTAGE ASTAGE ASTAGE ASTAGE ASTAGE A
100
90
80MOLE %ETHANOL
70
60
IN VAPOUR33
44
60
50
100
90
80
70
60
50
40
190 PROOFSPIRIT
2
34
5 6
8 9 10 11121314
7EQUILIBRIUM CURVE
TYPICAL - 14 RECTIFYING STAGES - 8 STRIPPING STAGES
OPERATING LINERECTIFICATION
40 50MOLE % ETHANOL IN LIQUID
0 10 20 30 40 50 60 70 80 90 100
30
20
10
0
1
STILLAGE(0.02 WT. %)
BEER FEED(10 VOLUME %)
OPERATING LINESTRIPPING
TYPICAL L/V = 5.0
MOLE %
D EQUILIBRIUMD EQUILIBRIUMANALYSISANALYSISD EQUILIBRIUMD EQUILIBRIUMANALYSISANALYSISANALYSISANALYSISANALYSISANALYSIS
88 99 1010 1111 1212 1313 1414
55 66 77 190 PROOF190 PROOFSPIRITSPIRIT
44SPIRITSPIRIT
OPERATING LINEOPERATING LINERECTIFYINGRECTIFYING
60 70 80 90 100
% ETHANOL IN LIQUID
VAPOURVAPOUR--LIQUIDLIQUIDVAPOURVAPOUR--LIQUIDLIQUIDSTAGE ASTAGE ASTAGE ASTAGE A
30
MOLE %ETHANOL 20ETHANOL
IN VAPOUR
20
10
1
2210
100
90
80
70
60
50
40
190 PROOFSPIRIT
2
34
5 6
8 9 10 11121314
7EQUILIBRIUM CURVE
TYPICAL - 14 RECTIFYING STAGES - 8 STRIPPING STAGES
OPERATING LINERECTIFICATION
3344
5566
7788
0
0STILLAGESTILLAGE
(0.02 WT. %)(0.02 WT. %)MOLE % ETHANOL IN LIQUID
0 10 20 30 40 50 60 70 80 90 100
30
20
10
0
1
STILLAGE(0.02 WT. %)
BEER FEED(10 VOLUME %)
OPERATING LINESTRIPPING
TYPICAL L/V = 5.088
M
D EQUILIBRIUMD EQUILIBRIUMD EQUILIBRIUMD EQUILIBRIUMANALYSISANALYSISANALYSISANALYSIS
OPERATING LINEOPERATING LINESTRIPPINGSTRIPPING
TYPICAL L/V = 5.0TYPICAL L/V = 5.0
BEER FEEDBEER FEED(10 VOLUME %)(10 VOLUME %)
10 20 30 40
MOLE % ETHANOL IN LIQUID
DISTILLATIODISTILLATIODISTILLATIODISTILLATIODISTILLATIODISTILLATIOCONSUMCONSUM
DISTILLATIODISTILLATIOCONSUMCONSUMCONSUMCONSUMCONSUMCONSUM
ON ENERGYON ENERGYON ENERGYON ENERGYON ENERGYON ENERGYMPTIONMPTION
ON ENERGYON ENERGYMPTIONMPTIONMPTIONMPTIONMPTIONMPTION
STEAM REQSTEAM REQSTEAM REQSTEAM REQETHANOL STRIPETHANOL STRIPETHANOL STRIPETHANOL STRIP
QUIREMENTSQUIREMENTSQUIREMENTSQUIREMENTSPPERPPER--RECTIFIERRECTIFIERPPERPPER--RECTIFIERRECTIFIER
50
40
45
BTU (In 1000’s) PER GALLON 30
35
ETHANOL (ANHYDROUS
BASIS)20
25
BASIS)
10
15
0
5
BEER CONC(VOLU
0 5
(VOLUCENTRATIONUME %)
CONSTRAINTS:• 190 PROOF PRODUCT
10 15
UME %) • 0.02% (WT.) BOTTOMS• SATURATED FEED
1112
91011
MJPER LITER 7
89
ETHANOL (ANHYDROUS
BASIS) 456
BASIS)
234
012
BEER CONC(VOLU
0 5
(VOLUCENTRATIONUME %)
CONSTRAINTS:• 190 PROOF PRODUCT
5 10 15
UME %) • 0.02% (WT.) BOTTOMS• SATURATED FEED
ENEENEENEENEENEENEENEENEEFFICIEFFICIEFFICIEFFICIEFFICIEFFICIEFFICIEFFICI
ERGYERGYERGYERGYERGYERGYERGYERGYIENCYIENCYIENCYIENCYIENCYIENCYIENCYIENCY
TRADITTRADITTRADITTRADIT
VAPOURVAPOUR CWCW
REFLUXREFLUX CONDENSECONDENSE
OVERHEADOVERHEADPRODUCTPRODUCTFEEDFEED FEEFEEFEEDFEED
TOWERTOWER
FEEFEE
STEAMSTEAM(ENERGY)(ENERGY)
TOWERTOWER11 STESTE
(EN(EN
BOTTOMSBOTTOMSPRODUCTPRODUCTPRODUCTPRODUCT
Energy InefficEnergy Ineffic
TIONALTIONALTIONALTIONAL
VAPOURVAPOUR CWCW
RR REFLUXREFLUX CONDENSERCONDENSER
OVERHEADOVERHEADPRODUCTPRODUCTEDEDEDED
TOWERTOWEREAMEAM
NERGY)NERGY)
TOWERTOWER22
BOTTOMSBOTTOMSPRODUCTPRODUCTPRODUCTPRODUCT
cientcient
ENERGY TRENERGY TRENERGY TRENERGY TRENERGY TRENERGY TRFORCEDFORCED -- CICIENERGY TRENERGY TRFORCEDFORCED -- CICIFORCED FORCED -- CICI
REBOREBOFORCED FORCED -- CICI
REBOREBOREBOREBOREBOREBO
RANSFER BYRANSFER BYRANSFER BYRANSFER BYRANSFER BYRANSFER BYIRCULATIONIRCULATION
RANSFER BYRANSFER BYIRCULATIONIRCULATIONIRCULATIONIRCULATION
OILEROILERIRCULATIONIRCULATION
OILEROILEROILEROILEROILEROILER
VAPOURVAPOURVAPOURVAPOUR
NGEC
TIFY
IN
FEEDFEEDMIXTUREMIXTURE
RENG
STEAM (ENERGY)STEAM (ENERGY)
STRI
PPIN
REBOILERREBOILERS
CONDENSATECONDENSATERETURNRETURN
TO BOILERTO BOILERTO BOILERTO BOILER
COOLING WATERCOOLING WATERCONDENSERCONDENSER
REFLUXREFLUX
COOLING WATERCOOLING WATER
LOWLOW-- BOILINGBOILINGPRODUCTPRODUCT
HIGH HIGH -- BOILING PRODUCTBOILING PRODUCT
ONE ONE --ONE ONE --ENEENEENEENEENEENEENEENE
CASCCASCCASCCASC
LEVELLEVELLEVELLEVELRGYRGYRGYRGYRGYRGYRGYRGY
CADECADECADECADE
ENERGY ENERGY ENERGY ENERGY
VAPOURVAPOUR
REFLUXREFLUX
FEEDFEEDFEEDFEED
RERETOWERTOWER
STEAMSTEAM(ENERGY)(ENERGY)
RERE11
BOTTOMSBOTTOMSPRODUCTPRODUCT OVERHEADOVERHEAD
PRODUCTPRODUCTPRODUCTPRODUCT
CASCADECASCADECASCADECASCADE
VAPOURVAPOURCONDENSERCONDENSER
REFLUXREFLUX
OVERHEADOVERHEADPRODUCTPRODUCTFEEDFEEDFEEDFEED
ECOVEREDECOVEREDTOWERTOWER
ECOVEREDECOVEREDENERGYENERGY 22
REBOILERREBOILER
BOTTOMSBOTTOMSBOTTOMSBOTTOMSPRODUCTPRODUCT
ENERGY CASCADEENERGY CASCADEENERGY CASCADEENERGY CASCADE
VAPOURVAPOUR
REFLUXREFLUXREFLUXREFLUX
HOTHOTFEEDFEEDFEEDFEED
RERETOWERTOWER
STEAMSTEAM(ENERGY)(ENERGY)
RERE11
BOTTOMSBOTTOMSPRODUCTPRODUCT OVERHEADOVERHEAD
PRODUCTPRODUCTPRODUCTPRODUCT
E E -- FEED PREHEATFEED PREHEATE E -- FEED PREHEATFEED PREHEAT
VAPOURVAPOUR FEEDFEED
REFLUXREFLUX CONDENSERCONDENSER
OVERHEADOVERHEADPRODUCTPRODUCTFEEDFEEDFEEDFEED
ECOVEREDECOVEREDTOWERTOWER
ECOVEREDECOVEREDENERGYENERGY 22
REBOILERREBOILER
BOTTOMSBOTTOMSBOTTOMSBOTTOMSPRODUCTPRODUCT
TWOTWO --TWOTWO --TWO TWO ENEENE
TWO TWO ENEENEENEENEENEENE
CASCCASCCASCCASC(3(3 –– TOTO(3(3 –– TOTO(3 (3 –– TOTO(3 (3 –– TOTO
LEVELLEVELLEVELLEVELLEVELLEVELRGYRGYLEVELLEVELRGYRGYRGYRGYRGYRGY
CADECADECADECADEOWER)OWER)OWER)OWER)OWER)OWER)OWER)OWER)
50
40
45
BTU (In 1000’s) PER GALLON 30
35
ETHANOL (ANHYDROUS
BASIS)20
25
BASIS)
10
15
0
5
BEER CONC(VOLU
0 5
(VOLUCENTRATIONUME %)
CONSTRAINTS:• 190 PROOF PRODUCT
10 15
UME %) • 0.02% (WT.) BOTTOMS• SATURATED FEED
1112
91011
MJPER LITER 7
89
ETHANOL (ANHYDROUS
BASIS) 456
BASIS)
234
012
BEER CONC(VOLU
0 5
(VOLUCENTRATIONUME %)
CONSTRAINTS:• 190 PROOF PRODUCT
5 10 15
UME %) • 0.02% (WT.) BOTTOMS• SATURATED FEED
ENEENEENEENEENEENEREQUIREREQUIRE
ENEENEREQUIREREQUIREREQUIREREQUIREREQUIREREQUIRE
BA
StrippingStripping--CoCopp gpp g14 lb STEAM per U.S14 lb STEAM per U.S
o1.7 Kg STEAM
o1.7 Kg STEAMgg
ERGYERGYERGYERGYERGYERGYEMENTSEMENTS
ERGYERGYEMENTSEMENTSEMENTSEMENTSEMENTSEMENTSSIC
oncentratingoncentratingggS. GALLON (absolute)S. GALLON (absolute)orM per LITER orM per LITER
ENEENEENEENEENEENEREQUIREREQUIRE
ENEENEREQUIREREQUIREREQUIREREQUIREREQUIREREQUIRE
ADVANCED-I
StrippingStripping--CoCopp gpp g9 lb STEAM per U.S.9 lb STEAM per U.S.
o1.1 Kg STEAM
o1.1 Kg STEAMgg
ERGYERGYERGYERGYERGYERGYEMENTSEMENTS
ERGYERGYEMENTSEMENTSEMENTSEMENTSEMENTSEMENTSNTEGRATED
oncentratingoncentratinggg. GALLON (absolute). GALLON (absolute)
orM per LITER orM per LITER
CONTACTINCONTACTINCONTACTINCONTACTIN(TRA(TRA(TRA(TRA((((
NG DEVICESNG DEVICESNG DEVICESNG DEVICESAYS)AYS)AYS)AYS)))))
DISTILLATION TRDISTILLATION TRDISTILLATION TRDISTILLATION TR• MIX RISING VAPOUR WITH FA• ALLOW FOR SEPARATION AFT• ALLOW FOR SEPARATION AFT• PROVIDE PATH FOR LIQUID T• PROVIDE PATH FOR VAPOUR PROVIDE PATH FOR VAPOUR
ENRICHEENRICHE
VV--LL
STRIPPEDSTRIPPEDLIQUIDLIQUID
RAY FUNCTIONSRAY FUNCTIONSRAY FUNCTIONSRAY FUNCTIONSALLING LIQUIDTER MIXINGTER MIXINGTO PROCEED DOWN THE TOWERTO PROCEED UP THE TOWERTO PROCEED UP THE TOWER
ED VAPOURED VAPOUR LIQUIDLIQUID
L MIXINGL MIXING
VAPOURVAPOUR
PERFORAPERFORAPERFORAPERFORA
OUTLET WEIROUTLET WEIR II
DOWNCOMERDOWNCOMERAREAAREA
ATED TRAYSATED TRAYSATED TRAYSATED TRAYS
NLET WEIRNLET WEIR
ENRICHEDENRICHED
DOWNCOMINGDOWNCOMINGLIQUIDLIQUID
ENRICHEDENRICHEDVAPOURVAPOUR
VV--L SEPARATIONL SEPARATION
VV--L MIXINGL MIXING
VV L SEPARATIONL SEPARATION
VAPOURVAPOUR STRIPPEDSTRIPPEDLIQUIDLIQUID
PERFORATED TPERFORATED TPERFORATED TPERFORATED T
ININOUTLET WEIROUTLET WEIR ININOUTLET WEIROUTLET WEIR
DOWNCOMERDOWNCOMERAREAAREA
FROFROFROFRO
TRAY FROTHINGTRAY FROTHINGTRAY FROTHINGTRAY FROTHING
NLET WEIRNLET WEIRNLET WEIRNLET WEIRENRICHEDENRICHEDVAPOURVAPOUR
DOWNCOMINGDOWNCOMINGLIQUIDLIQUID
OTH ZONEOTH ZONE VV--LLOTH ZONEOTH ZONE SEPARATIONSEPARATION
VV--L MIXINGL MIXING
VAPOURVAPOURSTRIPPEDSTRIPPEDSTRIPPEDSTRIPPED
LIQUIDLIQUID
DISCDISC--DONUDONUDISCDISC--DONUDONU
DONDONDONDON
DISCDISC
UT TRAYSUT TRAYSUT TRAYSUT TRAYS
NUTSNUTSNUTSNUTSDESCENDINGDESCENDING
LIQUIDLIQUIDDESCENDINGDESCENDING
LIQUIDLIQUIDENRICHEDENRICHEDVAPOURVAPOUR
VAPOURVAPOUR
STRIPPED STILLAGESTRIPPED STILLAGE
DISCDISC--DONUDONUDISCDISC--DONUDONU
DONDONDONDON
DISCDISC
FOUFOU
UT TRAYSUT TRAYSUT TRAYSUT TRAYS
NUTSNUTSNUTSNUTSDESCENDINGDESCENDING
LIQUIDLIQUIDDESCENDINGDESCENDING
LIQUIDLIQUIDENRICHEDENRICHEDVAPOURVAPOUR
VAPOURVAPOURLINGLING
STRIPPED STILLAGESTRIPPED STILLAGE
PERFORAPERFORAPERFORAPERFORA
OUTLET WEIROUTLET WEIR II
DOWNCOMERDOWNCOMERAREAAREA
FOULINFOULIN
ATED TRAYSATED TRAYSATED TRAYSATED TRAYS
NLET WEIRNLET WEIR
ENRICHEDENRICHED
DOWNCOMINGDOWNCOMINGLIQUIDLIQUID
ENRICHEDENRICHEDVAPOURVAPOUR
VAPOURVAPOUR STRIPPEDSTRIPPEDNGNG
LIQUIDLIQUID
BAFFLEBAFFLE -- TRAYTRAYBAFFLEBAFFLE -- TRAYTRAYBAFFLE BAFFLE -- TRAYTRAYBAFFLE BAFFLE -- TRAYTRAY
• 39 COMMERCIAL SCOMMERCIAL S• 39 COMMERCIAL SCOMMERCIAL SSULFITE PULPING LIQUOSULFITE PULPING LIQUO-- SULFITE PULPING LIQUOSULFITE PULPING LIQUO
-- FERMENTED SULFITE LIFERMENTED SULFITE LIFERMENTED IGNOFERMENTED IGNO CECE-- FERMENTED LIGNOFERMENTED LIGNO--CELCEL
-- FERMENTED WHOLE GRFERMENTED WHOLE GR-- ALCELLALCELL PULPING LIQUOPULPING LIQUO-- FERMENTED CHEESE WFERMENTED CHEESE W-- FERMENTED CANE MOLFERMENTED CANE MOL
Y EXPERIENCEY EXPERIENCEY EXPERIENCEY EXPERIENCEY EXPERIENCEY EXPERIENCEY EXPERIENCEY EXPERIENCE
SYSTEMSSYSTEMSSYSTEMSSYSTEMSORORORORIQUORIQUOR
U OSE HYDRO YZATEU OSE HYDRO YZATELLULOSE HYDROLYZATELLULOSE HYDROLYZATERAINRAINOROR
WHEYWHEYLASSESLASSES
BAFFLE BAFFLE -- TRAYTRAYBAFFLE BAFFLE -- TRAYTRAY•• 5 YEAR CLEAN5 YEAR CLEAN
FERMENTED GFERMENTED G1 YEAR CLEAN1 YEAR CLEAN•• 1 YEAR CLEAN1 YEAR CLEANFERMENTED CFERMENTED C
•• ELIMINATED AELIMINATED ASCALANTSCALANTSCALANTSCALANT
•• 66--12 MONTH C12 MONTH CFERMENTED “FERMENTED “
Y EXPERIENCEY EXPERIENCEY EXPERIENCEY EXPERIENCENING CYCLE NING CYCLE GRAINGRAINNING CYCLENING CYCLENING CYCLE NING CYCLE CHEESE WHEYCHEESE WHEYANTIANTI--FOAM AND ANTIFOAM AND ANTI--
CLEANING CYCLE CLEANING CYCLE “C” MOLASSES“C” MOLASSES
RECOMMENDEDRECOMMENDEDRECOMMENDEDRECOMMENDEDRECOMMENDED RECOMMENDED RECOMMENDED RECOMMENDED
BEERSTILLS (ALL FOULING FEEDBEERSTILLS (ALL FOULING FEEDBEERSTILLS (ALL FOULING FEEDBEERSTILLS (ALL FOULING FEED
RECTIFIERSRECTIFIERS
EXTRACTIVE TOWERSEXTRACTIVE TOWERS
TECHNICAL ALCOHOL TOWERSTECHNICAL ALCOHOL TOWERS
TRAY DESIGNSTRAY DESIGNSTRAY DESIGNSTRAY DESIGNS TRAY DESIGNS TRAY DESIGNS TRAY DESIGNS TRAY DESIGNS
DSTOCKS)DSTOCKS) BAFFLE TRAYBAFFLE TRAYDSTOCKS)DSTOCKS) -- BAFFLE TRAYBAFFLE TRAY
-- PERFORATED TRAYPERFORATED TRAY
-- PERFORATED TRAYPERFORATED TRAY
-- PERFORATED TRAYPERFORATED TRAY-- PACKED ( < 24” )PACKED ( < 24” )
COCOCOCOCONTCONTCONTCONTSTRATSTRATSTRATSTRATSTRATSTRATSTRATSTRAT
OOOOTROLTROLTROLTROLTEGIESTEGIESTEGIESTEGIESTEGIESTEGIESTEGIESTEGIES
TEMPERATURE ANDTEMPERATURE ANDTEMPERATURE ANDTEMPERATURE AND
REFLUXREFLUX
CONDENSERCONDENSER
TOP TRAY
PRODUCTPRODUCT(190 PROOF SPIRITS)(190 PROOF SPIRITS)
TOP TRAY
RECTIFIER
TEMPERATURETEMPERATURETEMPERATURETEMPERATURE
BEER FEEDBEER FEED
STRIPPERSTRIPPER
BOTTOM TRAYSTILLAGESTILLAGE TRAY
D PROOF PROFILED PROOF PROFILED PROOF PROFILED PROOF PROFILE
TEMP. (°C)77
°GL95
77777878
94.59493
91 578798084
91.5898475
PROOFPROOF
84859398
75696040
ZONE OFZONE OFCONTROLCONTROL
98
102106
40
205106
106107107
51.50.5
0.005STEAMSTEAM 107 0.00005STEAMSTEAM
TEMPERATURE ANDTEMPERATURE ANDTEMPERATURE ANDTEMPERATURE AND
REFLUXREFLUX
CONDENSERCONDENSER
TOP TRAY
PRODUCTPRODUCT(190 PROOF SPIRITS)(190 PROOF SPIRITS)
TOP TRAY
RECTIFIER
TEMPERATURETEMPERATURETEMPERATURETEMPERATURE
BEER FEEDBEER FEED
STRIPPERSTRIPPER
BOTTOM TRAYSTILLAGESTILLAGE TRAY
D PROOF PROFILED PROOF PROFILED PROOF PROFILED PROOF PROFILE
TEMP. (°F)170
°PR. (U.S.)190
170171172173
189188186183
PROOFPROOF173174176184
183178168150
ZONE OFZONE OFCONTROLCONTROL
184191199208
15013812080208
216222
80
4010222
223224225
1031
0.01STEAMSTEAM 225 0.0001STEAMSTEAM
190 PROOF190 PROOFSPIRITSSPIRITS
FC
TCBEERBEERFEEDFEED FC
TC
FCSTEAMSTEAM
FC
STRIPPESTRIPPESTILLAGESTILLAGE
STRIPPESTRIPPERECTIFIRECTIFI
CONDENSERCONDENSER
REFLUXREFLUXREFLUXREFLUXDRUMDRUM
LC LC
ERERERER--IERIER
VAPOURVAPOUR--LIQUIDLIQUIDVAPOURVAPOUR--LIQUIDLIQUIDETHANOLETHANOLETHANOLETHANOL
D EQUILIBRIUMD EQUILIBRIUMD EQUILIBRIUMD EQUILIBRIUMLL--WATERWATERLL--WATERWATER
100
90
80
70EQUILIBRIUM CURVEEQUILIBRIUM CURVE
MOLE %ETHANOL
60
50ETHANOL
IN VAPOUR 40
30
20
10
0 10 20 30 40
(10 VOLUM(10 VOLUM
MOLE % ET
AZEOTROPE 194.4AZEOTROPE 194.4PROOFPROOF
40 50 60 70 80 90 100
ME % FEED)ME % FEED)
THANOL IN LIQUID
STRUCTURING THSTRUCTURING THSTRUCTURING THSTRUCTURING THSYSTEM SSYSTEM SSYSTEM SSYSTEM S
HE DISTILLATIONHE DISTILLATIONHE DISTILLATIONHE DISTILLATIONSTRATEGYSTRATEGYSTRATEGYSTRATEGY
STRIPPING SYSTSTRIPPING SYST
100
RECTIFYINGRECTIFYING
90
80EQUILIBRIUM CURVEEQUILIBRIUM CURVE
MOLE %
70
60
EQUILIBRIUM CURVEEQUILIBRIUM CURVE
MOLE %ETHANOL
IN VAPOUR
50
40
30
20
(10 VOLUM(10 VOLUM
0 10 20 30 40
10
0STILLAGESTILLAGE
MOLE % ETHSTILLAGESTILLAGE
TEMTEM DEHYDRATIONDEHYDRATION
G SYSTEMG SYSTEMANHYDROUS ANHYDROUS PRODUCTPRODUCT
SYSTEMSYSTEM
AZEOTROPE 194.4AZEOTROPE 194.4PROOFPROOF
PRODUCTPRODUCT
PROOFPROOF
SPIRITSPIRIT
E % FEED)E % FEED)
50 60 70 80 90 100
HANOL IN LIQUID
TERNTERNTERNTERNAZEOTAZEOTAZEOTAZEOTAZEOTAZEOTAZEOTAZEOT
DEHYDRDEHYDRDEHYDRDEHYDR
NARYNARYNARYNARYTROPETROPETROPETROPETROPETROPE
OOTROPETROPE
OORATIONRATIONRATIONRATION
ANHYDROUS ETHANHYDROUS ETHANHYDROUS ETHANHYDROUS ETHANHYDROUS ETHANHYDROUS ETHANHYDROUS ETHANHYDROUS ETH
190 PROOF 190 PROOF ETHANOL FEEDETHANOL FEED
STEAMSTEAMSTEAMSTEAM
DDCONDENSATECONDENSATE
DEHYDRATIONDEHYDRATIONTOWERTOWERTOWERTOWER
HANOL SYSTEMHANOL SYSTEMHANOL SYSTEMHANOL SYSTEMHANOL SYSTEM HANOL SYSTEM HANOL SYSTEM HANOL SYSTEM
ANHYDROUSANHYDROUSANHYDROUSANHYDROUSETHANOLETHANOL
WASTEWASTEWATERWATER
DECANTERDECANTER
ENTRAINERENTRAINERTOWERTOWER
WATERWATER
TOWERTOWER
MOLECULMOLECULMOLECULMOLECULMOLECULMOLECULDEHYDRDEHYDR
MOLECULMOLECULDEHYDRDEHYDRDEHYDRDEHYDRDEHYDRDEHYDR
VAPOUR PHAVAPOUR PHA
NO ENTRAINENO ENTRAINE
LOW ENERGYLOW ENERGYLOW ENERGYLOW ENERGY
LAR SIEVELAR SIEVELAR SIEVELAR SIEVELAR SIEVELAR SIEVERATIONRATION
LAR SIEVELAR SIEVERATIONRATIONRATIONRATIONRATIONRATION
SE ADSORPTIONSE ADSORPTION
ERER
YYYY
MOLECULAMOLECULAMOLECULAMOLECULATYPETYPETYPETYPE
CHEMICAL CHEMICAL (K2O • Na2O) • Al2(K2O • Na2O) • Al2
AR SIEVEAR SIEVEAR SIEVEAR SIEVEE 3AE 3AE 3AE 3A
FORMULA:FORMULA:O3 • 2SiO2 • XH2OO3 • 2SiO2 • XH2O
MOLECULARMOLECULARMOLECULARMOLECULAR SIEVE BED SIEVE BED SIEVE BED SIEVE BED
INTERMEDIATE SUPPORTINTERMEDIATE SUPPORT
ADSORBENT BEDADSORBENT BED
INTERMEDIATE SUPPORTINTERMEDIATE SUPPORTINTERMEDIATE SUPPORTINTERMEDIATE SUPPORT
SUPPORT MEDIUMSUPPORT MEDIUM
MFGE DISTILLATIONMFGE DISTILLATIONPSA MOLECPSA MOLEC
MFGE DISTILLATIONMFGE DISTILLATIONPSA MOLECPSA MOLECPSA MOLECPSA MOLECPSA MOLECPSA MOLEC
BEERBEERFEEDFEED
STEAMSTEAM
RECTIFIERRECTIFIER
BEERBEER
STEAMSTEAM
FUSFUS
BEERBEERSTRIPPERSTRIPPER
REBOILERREBOILERREBOILERREBOILER FUSFUSDECDEC
STSTSTM.STM.
REBOILERREBOILERREBOILERREBOILER
CC
STILLAGESTILLAGE
REBOILERREBOILERWATERWATER
COND.COND.
N & DEHYDRATIONN & DEHYDRATIONULAR SIEVEULAR SIEVEN & DEHYDRATIONN & DEHYDRATIONULAR SIEVEULAR SIEVEULAR SIEVEULAR SIEVEULAR SIEVEULAR SIEVE
MFGEMFGEPRODUCTPRODUCT
WATERWATER
SEL OILSEL OIL
WATERWATER
BADEHYDRATIONDEHYDRATION
BEDSBEDS
VACUUMVACUUMPUMPPUMP
SEL OILSEL OILCANTERCANTERTEAMTEAMOND.OND. PUMPPUMP
DISTILLATIONDISTILLATION--DISTILLATIONDISTILLATION--DISTILLATIONDISTILLATIONTECHNTECHN
DISTILLATIONDISTILLATIONTECHNTECHN
TYPETYPEDEHYDDEHYDTECHNTECHNTYPETYPE TECHNTECHN
1970’s STANDALONE AZEO
1980’s INTEGRATEDCOMPLEX
AZEO
1990’s INTEGRATEDUSER FRIENDLY
MOLESIEVE
2000’s ADDITIONALINTEGRATIONINTEGRATION
DEHYDRATIONDEHYDRATIONDEHYDRATIONDEHYDRATIONDEHYDRATIONDEHYDRATIONOLOGYOLOGYDEHYDRATIONDEHYDRATIONOLOGYOLOGY
DRATIONDRATIONNOLOGYNOLOGY
ENERGYENERGY(MJ/L) (BTU/G l)(MJ/L) (BTU/G l)NOLOGYNOLOGY (MJ/L) (BTU/Gal)(MJ/L) (BTU/Gal)
OTROPIC 9.5 34,000
OTROPIC 4.7 17,000
ECULARE
3.9 14,000