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In\' CIIEMTROII;ICS MSIIS #0609
SECTION I: CIIE\'lICAL 1'1100H:cr ANIl COMI'AII;Y III;FOIIM,\T1011;Com pan)' Address:8125 Cobb Cenler Dri\cKennesaw. GA 30152
Product Information: 800.TECH-401Customer Service: 800-645.5244
Product Idenfificatioll
Emergency :Revision Date:
(Chcmtrcc) 800-424.9300November I, 2012
FI{EE7..•..IT Al\TISTAT(Formerl~' FreeL-II :2000 Anlistaf)
WI. % Hange94.0-99.0%0.1-1.5
CAS#811-97-267-56-1
I'roduet Code: ESI051, ES1251, ESI551, ES1051C, ESI551C
SECTION 2: COMI'OSITION/III;FORMATlOII; ON INGREilIENTSChemical NallleTetrafluorocthancMethanolSECTIO~ J: IIAURDS IDENTIFICATIOII;Emergenc" Overview: Clear, colorless liquclied gas. This product is nonflammable. Exposure to liquid rnay caus~ frostbite.~ Conlact with liquid is irritating and nuy cause frostbite.Skin: Contact causes frostbite; prolonged CCnlac! elm cause skin IrritationIngestion: Unlikely due 10 volatile nalUrt.:ofprodJct. Contact •.••.ith liquid may cause frostbite to mouth and throat lissuesInhalation: Hamlful if inhaled. High concentrati)ns of vapors in immediate area can displace oxygen and can cause dizziness, unconsciousness, and even death ••••.lthlonger exposure, Keep people away from such \:Ilpors without scltcontllined breathing apparatusPre-Existir.g Medical Conditions Aggravated by EXQosurc He-art.lung. skin. eye.
(HilER(IIUI'ONT) AEL1,000 ppm
IIMISIo1B
SECTION 6: ACCIIlEII;'IAL IlELMSE MEASI;IIESLarge Spills' Shut 00" leak if possible and safe to do so. \Vear self-contained breathing apparatus ami appropriate personal protective equipment. Absorb spill withinert malenal (e.g. dry sand or earth). then place i1 a chemical waste container for proper disposal. Do nOll1ush to sewer, A\'oid runotT ir.to slOrm sewers and dItcheswhich lead to waterways.Small SpillS' Absorb spill with inert material (e,g. dry sand or earth), then place in a chemical wasle container fOl proper disposal.SECTIOII; 7: IIANIlI.ING ,1'10111STORAGEAvoid prolonged or repeated contact with eyes, shin. and clothing. \Vash hands before ealing. Usc with adequate ventilation, Avoid breathing product vapor or mist.Do not reU$e this container. Store in a cool dry place a••••.ay from heat. sparks and Ilamc Keep coniiner closed when not in usc, Do not store in direct sunlight.KEEl' OUT OF IIEACIi OF ClIllllREI\.
SECTION 8: EXI'OSURE CO~TROLS, I't:IlSO~,\L 1'1l0HCTlO~Exposure Guidelines:CIIEMICAL I\AMI; ACGIII TI.\' OSIIA I'EL ,1'0;111 SHLTetratluoroeth<llle NA NA NAMethanol 200 ppm 200 ppm 250 ppmWorkIHygienic I)ractices: Good gcneral ventilation should be sufficient to control airborne levels Local exhaust ventilation may be necessary to control any aircontaminants to within their TL Vs during Ihe use of this product. If\'apor concentration cxceeds TLV, lise NIOSH appro ••..ed organic vapor cartridge respirator. Wearsafely glasses with side shields (or goggles) and rubber or other chemically resistant gloves when handling this material.NFPA and HMIS Codes: NFPi\~Iealth IFlammability 0Reactivily IPersonal Protection
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Solubility in Water: 67mg/l @ 77FSpecific Gravity: (Water = I) 1.21Vapor Pressure: 4730 mmHg @ 77°FPercent Volatile: 100%Boiling Pomt: .15.7F (.27C)
Ql)
ITW CIIEMTRO:-lICS
SECTION 9: PIIYSICAL A:-Ill CIIE'IICAL 1'llOl'ERTIESPhysical State: Clear, colorless liquefied gasOdor: Slight ethereal odorEvaporation Rale: >1 (Butyl acetate=l)Vapor Density" 3.18@77F(Air: I)
SECTION 10: STABILITY ANIl REACTIVITYStability ~This product is stahle. Conditions to AVQid: Do 110\spmy ncar open names. red hot slirfacesor other sources of ignition.Incompatibility: Do nut mix with powdered alkali and nlkaline earth metals or strong oxidil.ing agents.Products of Decomposition: Thermal decomposition may release hydrotluoflc acid vapor.Hazardous Polymerization: Will nol occurConditions to Avoid: NA
MSIlS #0609
Methanol LD50 ral<; 5,628 mglkgIngestion:
SECTION II: TOXICOLOGICAL I:'IFORMATIO:'lInhalation:Tetralluorocthallc. Rats ALe 567,000 ppm/4hrsMethanol LC50 rats 64,000 ppm/4hrs• Information from Dupont.Cancer Infomlation: No ingredients listed as human carcinogens by NT!' or IARCReproductive effects: nonc Teratogenic effects: none
SECTION 12: ECOLOGICAL INFORMATIO:-li<:nvironmcntallmpHct InformationAvoid runolf into storm sewers and ditches which lead 10waterways Water runolT can cause environmental dmnagc.
Mutagenic effects: none
IU':PORTII\'GUS regulations require reporting spills orlhis material that could reach any surface wa:crs, The toll free number for LheUS Coast Guard National Response Center is:1-800-424-8802
Max.Quantity
Pkg.Instr.
HazardLabel
Pkg.Group
Sub.RiskClass
SECTION 13: IlISPOSAL CONSIIlERATIO:-lSDispose of in accordance with all federal, slate md local regulations. '''later runolf can cause environmcntaklarrage.SECTION 14: TI{ANSI'ORTATION INFORMATION
ProperShipping Name UN Number
75 kg; 150 kg200
Pkg. Auth. 173.306DOT-E-10232
WI. % Range0.1-1.0
NontlammableGasORM-IlNA
NANANA
2.2
ORM-D
UN 3 159
NA(1,1, I ,2wTctralluorocthar.e)
Ground: Consumer CommodityORM-D
SECTIO:'l15: REGULATORY IN.-ORMATIO:'lSECTION 313 SUPPLIER NOTIFICATIONThis product contains the following toxic chemicals subject to the reporting requirements of Section 313 of the ::mergency Planning and Community Right-To-KnowAct of 1986 (40 CFR 372)Chemical Name CAS#Methanol 67-56-1This information should be included on all MSDSs copied nnd distributed lor this materialTOXIC SUBSTANCES CONTROL ACT !TSCAl.All ingredients of this product are listed all the TSCA Im:entor}'.WI-IMIS: Class A; Class D2BThis product has been classified according to the hazard criterin of the CPR and the MSDS contains aliaI' the information rCqJiredby the CPR.SECTION 16: OTHER I:-IFOllMATIONProduct is a Level I aerosol. Do not puncture (.r incinerate containers. Normal ventilation for standnrd manufucturing prnctices is usually adequate. Local exhaustshould be used when large amounts are released.To the best of our knowledge, the information contained herein is accurate. However. all materials may present unknown hazards and should be used with caution. Inparticular, improper u~e of our products and their inappropriate combination with olher products and substances may produce harmful results which cannot beanticipated. Final determination of the suitabil ty of any material is the sole respon~ibility of the user. Although certain hazards are described herein, we cannotguarantee that these are the only hazards that may exist.
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