SafetyDatasheet
Silicate Resin 3P W1
Express (Comp. B)
according to Regulation (EC) No. 1907/2006 and Regulation (EU) 2015/830
1/12
1. Identificationofthesubstance/mixtureandofthecompany/undertaking
1.1 Productidentifier
FluviusSilicateResin-3PTypeW1Express(Comp.B)
1.2 Relevantidentifiedusesofthesubstanceormixtureandusesadvisedagainst
“B”componentforwaterglass–polyisocyanatebasedtwo-com-
ponentsyntheticresin.Thesyntheticresin(components“A”+“B”)
isusedfortheliningofsewerpipesandmanholes.Theapplication
hastobecarriedoutunderprofessional,industrialconditionsby
personshavingproperprevioustraining.
1.3 Detailsofthesupplierofthesafetydatasheet
Company FluviusGmbH
Street/POB Schiessstrasse56
Postcode/City/Country D-40549Düsseldorf
Phone +49(0)211-691682-0
Telefax +49(0)211-691682-19
E-mail [email protected]
1.4 Emergencytelephonenumber
Medical emergency information in case of intoxication
Giftinformationszentrum(GIZ)Mainz
Emergency +49(0)613119240
telephonenumber (AdviceinGermanorEnglish)
2. Hazardsidentification
2.1 Classificationofthesubstanceormixture
2.1.1 ClassificationaccordingtoRegulation(EC)No1272/2008(CLP)
Hazard classes Hazard statements
AcuteTox.4. H302Harmfulifswallowed.
SkinIrrit.2 H315Causesskinirritation.
SkinSens.1B H317Maycauseanallergicskinreaction.
EyeIrrit.2 H319Causesseriouseyeirritation.
AcuteTox.4. H332Harmfulifinhaled.
Resp.Sens.1 H334Maycauseallergyorasthmasym-
ptomsofbreathingdifficultiesifinhaled.
STOTSE3 H335Maycauserespiratoryirritation.
Carc.2 H351Suspectedofcausingcancer.
STOTRE2 H373Maycausedamagetoorgans
throughprolongedorrepeated
exposure:respiratorysystem,inhalation.
2.2 Labelelements
2.2.1 LabelingaccordingtoRegulation(EC)No1272/2008(CLP)
Hazard pictograms
Signal word Danger
Hazard statements
H302 Harmfulifswallowed.
H315 Causesskinirritation.
H317 Maycauseanallergicskinreaction.
H319 Causesseriouseyeirritation.
H332 Harmfulifinhaled.
H334 Maycauseallergyorasthmasymptoms
ofbreathingdifficultiesifinhaled.
H335 Maycauserespiratoryirritation.
H351 Suspectedofcausingcancer.
H373 Maycausedamagetoorgansthrough
prolongedorrepeatedexposure:
respiratorysystem,inhalation.
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SafetyDatasheet
Silicate Resin 3P W1
Express (Comp. B)
according to Regulation (EC) No. 1907/2006 and Regulation (EU) 2015/830
2/12
Precautionary statements
P260 Donotbreathedust/fume/gas/mist/
vapours/spray.
P280 Wearprotectivegloves/protective
clothing/eyeprotection/faceprotection.
P285 Incaseofinadequateventilationwear
respiratoryprotection.
P302+P352 IFONSKIN:Washwithplentyofsoap
andwater.
P304+P340 IFINHALED:Removevictimtofresh
airandkeepatrestinaposition
comfortableforbreathing.
P309+P311 IFexposedorifyoufeelunwell:Calla
POISONCENTERordoctor/physician.
Hazarddeterminingcomponent(s)forlabelling
Diphenylmethandiisocyanate,isomersandhomologes(CAS:9016-
87-9);Tris(2-chloro-1-methylethyl)phosphate(CAS:13674-84-5).
2.3 Otherhazards
Themixturedoesnotmeetpersistent(P)andbioaccumulation(B)
criteria,butitmeetsthecriteriafortoxicity(T).Themixtureisnot
PBTorvPvB.
Name EC-No. CAS-No. REACH-No. Content(%) ClassificationaccordingtoRegulation
(EG)No.1272/2008(CLP)
Hazardcategories1 H-phrase(s)1
Isocyanicacid,polymethylen-
epolyphenyleneester
(PolymericMDI)2
(polymer) 9016-87-9 (polymer) >60 AcuteTox.4
SkinIrrit.2
EyeIrrit.2
Resp.Sens.1
SkinSens.1B
Carc.2
STOTSE3
STOTRE2
H332
H315
H319
H334
H317
H351
H335
H373
Tris(2-chloro-1-methyl-ethyl)
phosphate(TCPP)
237-158-7 13674-84-5 3 >10 AcuteTox.4 H302
4,4'-Methylenediphenyldiiso-
cyanate,oligomericreaction
productswith2,4'-diisocyana-
to-diphenylmethane,2,2'-me-
thylenediphenyldiisocyanate
andα-hydro-α-hydroxypoly
[oxy(methyl-1,2-ethanediyl)]4
500-410-4 158885-25-7 5 ≤5 AcuteTox.4
SkinIrrit.2
EyeIrrit.2
Resp.Sens.1
SkinSens.1B
Carc.2
STOTSE3
STOTRE2
H332
H315
H319
H334
H317
H351
H335
H373
3. Composition/informationoningredients
Mixtures / Chemical characterization
1SeeSection16forthefulltextoftheabbreviationsdeclaredabove.2Contains<25%4,4’-MDI(4,4'-methylenediphenyldiisocyanate)
(CAS:101-68-8).301-2119486772-26-XXXX
4Containscca.10%4,4’-MDI(4,4'-methylenediphenyldiisocyanate)
(CAS:101-68-8).5Nodata.
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SafetyDatasheet
Silicate Resin 3P W1
Express (Comp. B)
according to Regulation (EC) No. 1907/2006 and Regulation (EU) 2015/830
3/12
4. Firstaidmeasures
4.1 Descriptionoffirstaidmeasures
Generaladvice Soiled,fairlysoakedclothingandshoes
mustbeimmediatelyremoved.
Incaseofinhalation Ifinhaled,removetofreshair.Ifnot
breathing,giveartificialrespiration.
Getmedicalattentionimmediately.
Incaseofskincontact Intheeventofcontactwiththeskin,
preferablywashalternatelywitha
cleanserbasedonpolyethyleneglycol
andwithplentyofwarmwaterandsoap.
Consultadoctorintheeventofaskin
reaction.Washthelessclothingbefore
reuse.Cleanshoesthoroughlybefore
reuse.
Incaseofeyecontact Holdtheeyesopenandrinsewithwater
forasufficientlylongperiodoftime(at
least10minutes).Getmedicalattention
immediately.
Incaseofingestion DONOTinducethepatienttovomit,
medicaladviceisrequired.Nevergive
anythingbymouthtoanunconscious
person.Providedthepatientiscon-
scious,washoutmouthwithwater.
Informationtophysician Theproductirritatestherespiratory
tractandmaytriggersensitisationof
theskinandrespiratorytract.Treatment
ofacuteirritationorbronchialconstric-
tionisprimarilysymptomatic.Following
severeexposurethepatientshouldbe
keptundermedicalreviewforatleast
48hours.
4.2 Mostimportantsymptomsandeffects,bothacuteanddelayed
Headache,nausea,shortnessofbreath,sorethroat,rednessonthe
skin.Repeatedorprolongedcontactmaycauseskinsensitization.
Repeatedorprolongedinhalationexposuremaycauseasthma.
4.3 Indicationofanyimmediatemedicalattentionandspe-cialtreatmentneeded
Dependingonthedegreeofexposure,periodicmedicalexaminati-
onissuggested.
5. Firefightingmeasures
5.1 Extinguishingmedia
Suitable Foam,CO2ordrypowder.Waterspray
extinguishingmedia maybeusedifnootheravailableand
thenincopiousquantities.
Unsuitable Highvolumewaterjet.
extinguishingmedia
5.2 Specialhazardsarisingfromthesubstanceormixture
Carbondioxide,carbonmonoxide,hydrogencyanide,nitrogenoxi-
des,isocyanate.Thesubstances/groupsofsubstancesmentioned
canbereleasedincaseoffire.
5.3 Adviceforfirefighter
Reactionbetweenwaterandhotisocyanatemaybevigorous.
Preventwashingsfromenteringwatercourses,keepfireexposed
containerscoolbysprayingwithwater.
Specialprotective Fire-fightersshouldwearappropriate
equipment protectiveequipmentandself-contained
breathingapparatus(SCBA)withafull
face-pieceoperatedinpositivepressure
mode.Safetyboots,gloves,safetyhel-
metandprotectiveclothingshouldbe
worn.
Furtherinformation Intheeventoffireand/orexplosiondo
notbreathefumes.Fireinvicinityposes
riskofpressurebuild-upandrupture.
Containersatriskfromfireshould
becooledwithwaterand,ifpossible,
removedfromthedangerarea.Dueto
reactionwithwaterproducingCO2gas,
ahazardousbuild-upofpressurecould
resultifcontaminatedcontainersare
re-sealed.Containersmayburstifover-
heated.
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SafetyDatasheet
Silicate Resin 3P W1
Express (Comp. B)
according to Regulation (EC) No. 1907/2006 and Regulation (EU) 2015/830
4/12
6. Accidentalreleasemeasures
6.1 Personalprecautions,protectiveequipmentandemergencyprocedures
Immediatelycontactemergencypersonnel.Evacuatethearea.
Keepupwindtoavoidinhalationofvapours.Clean-upshouldonly
beperformedbytrainedpersonnel.Keepunauthorizedpersons
away.
Fornon-emergency Removenotaffectedpeople.Informthe
personnel relevantemergencyservicesandautho-
rities.
Foremergency Peopledealingwithmajorspillages
responders shouldwearfullprotectiveclothing
includingrespiratoryprotection.Use
suitableprotectiveequipment.
6.2 Environmentalprecautions
Donotallowcontaminatedextinguishingwatertoenterthesoil,
ground-waterorsurfacewaters.Avoiddispersalofspiltmaterial
andrunoffandcontactwithdrainsandsewers.
6.3 Methodsandmaterialforcontainmentandcleaningup
Absorbspillagesontosand,earthoranysuitableadsorbentma-
terial.Leavetoreactforatleast30minutes.Donotabsorbonto
sawdustorothercombustiblematerials.Contaminatedabsorbent
materialshallbedisposedaccordingtoSection13.)Washthespilla-
geareawithwater.
6.4 Referencetoothersections
Informationregardingexposurecontrols/personalprotectionand
disposalconsiderationscanbefoundinsection8and13.
7. Handlingandstorage
7.1 Precautionsforsafehandling
Protective measures
Providesufficientairexchangeand/orexhaustinworkrooms.Inall
workplacesoftheplantwherehighconcentrationsofisocyanate
aerosolsand/orvapoursmaybegenerated(e.g.duringpressure
release,mouldventingorwhencleaningmixingheadswithanair
blast),appropriatelylocatedexhaustventilationmustbeprovided
inordertopreventoccupationalexposurelimitsfrombeingexcee-
ded.Theairshouldbedrawnawayfromthepersonnelhandlingthe
product.Theefficiencyoftheventilationsystemmustbemonito-
redregularlybecauseofthepossibilityofblockage.Atmospheric
concentrationsshouldbeminimisedandkeptaslowasreasonably
practicablebelowtheoccupationalexposurelimit.
Advice on general occupational hygiene
Noeating,drinking,smokingortobaccouseattheplaceofwork.
Contactwithskinandeyesandinhalationofvapoursmustbe
avoidedunderallcircumstances.Keepequipmentclean.Abasic
essentialinsampling,handlingandstorageisthepreventionof
contactwithwater.Keepstocksofdecontaminantreadilyavailable.
7.2 Conditionsforsafestorage,includinganyincompatibilities
Storeinaccordancewithlocalregulations.Storeinoriginal
containerprotectedfromdirectsunlightinadry,cooland
well-ventilatedarea,awayfromincompatiblematerialsandfood
anddrink.Keepcontainertightlyclosedandsealeduntilreadyfor
use.Containersthathavebeenopenedmustbecarefullyresealed
andkeptuprighttopreventleakage.Donotstoreinunlabelled
containers.Useappropriatecontainmenttoavoidenvironmental
contamination.Suitablecontainers:steel,stainlesssteel.Unsuitab-
lecontainers:copper,copperalloyandgalvanisedsurfaces.
7.3 Specificenduse(s)
Fortherelevantidentifieduse(s)listedinSection1theadvicementi-
onedinthissection7istobeobserved.
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SafetyDatasheet
Silicate Resin 3P W1
Express (Comp. B)
according to Regulation (EC) No. 1907/2006 and Regulation (EU) 2015/830
5/12
8. Exposurecontrols/personalprotection
8.1 Controlparameters
Aworkplaceexposurelevel(WEL)of0.02mg/m3fortotalisocya-
nates(asNCO)asan8hourTWA,andashorttermWEL(15min)
of0.07mg/m3havebeenassignedintheUnitedKingdom.ABMGV
forisocyanates,basedonthemeasurementofurinarydiamines,
hasbeensetat1 µmoldiamine/molcreatinine.
(http://www.hse.gov.uk/foi/internalops/sectors/manuf/03-10-07.htm)
8.2 DNEL/PNEC-values
The risk characterization of MDI (CAS: 9016-87-9) is the following
Workers
Acute/short-term exposure
systemiceffects(dermal) DNEL=50mg/kgbw/day
Acute/short-term exposure
systemiceffects(inhalation)DNEL=0,1mg/m3
Acute/short-term exposure
localeffects(dermal) DNEL=28,7mg/cm2
Acute/short-term exposure
localeffects(inhalation) DNEL=0,1mg/m3
Long-term exposure
systemiceffects(inhalation)DNEL=0,05mg/m3
Long-term exposure
systemiceffects(dermal) Notapplicable.
Long-term exposure
localeffects(inhalation) DNEL=0,05mg/m3
Long-term exposure
localeffects(dermal) Notapplicable.
PNECsediment AsPMDIisareactantwithwater,access
ofwatertoPMDIandviceversaisstrictly
controlled.Furthermore,PMDIpolyme-
rizesinthepresenceofwaterandthus
exposureofPMDItosedimentishighly
likelytobenegligible.Therefore,PNEC
sedimentcannotbederivedforPMDI.
PNECsoil 1mg/kgsoildw(dryweight)
PNECoral TherearenodataoneffectsoforalPMDI
tobirds.Exposuretobirdsisnotexpected
anddatafromexperimentalanimals
showPMDItobeofloworaltoxicity.
8.3 Exposurecontrols
Respiratoryprotection Respiratoryprotectionincaseofvapour/
aerosolrelease.Combinationfilterfor
gases/vapoursoforganic,inorganic,acid
inorganicparticles(f.e.EN14387Type
ABEK)shallbeused.
Handprotection Chemicalresistantprotectivegloves
(EN374).
Suitable materials also with prolonged, direct contact
(Recommended: Protective index 6, corresponding > 480 minutes
of permeation time according to EN 374)
butylrubber(butyl) 0,7mmcoatingthickness
nitrilerubber(NBR) 0,4mmcoatingthickness
chloroprenerubber(CR) 0,5mmcoatingthickness
Unsuitable materials
polyvinylchloride(PVC) 0,7mmcoatingthickness
Polyethylene-Laminate ca.0,1mmcoatingthickness
(PE-laminate)
Eyeprotection Safetyglasseswithside-shields
(framegoggles)(e.g.EN166)
Bodyprotection safetyshoes
(e.g.accordingtoEN20346)
Generalsafetyand
hygienemeasures
Donotbreathevapour/spray.Withproducts
freshlymanufacturedfromisocyanates
bodyprotectionandchemicalresistant
protectiveglovesisrecommended.Wearing
ofclosedworkclothingisrequired
additionallytothestatedpersonal
protectionequipment.Noeating,drinking,
smokingortobaccouseattheplaceofwork.
Takeoffimmediatelyallcontaminated
clothing.Handsand/orfaceshouldbe
washedbeforebreaksandattheendofthe
shift.Attheendoftheshifttheskinshould
becleanedandskin-careagentsapplied.
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SafetyDatasheet
Silicate Resin 3P W1
Express (Comp. B)
according to Regulation (EC) No. 1907/2006 and Regulation (EU) 2015/830
6/12
9. Physicalandchemicalproperties
9.1 Informationonbasicphysicalandchemicalproperties
Appearance liquid,dark-brown
Odour damp
Odourthreshold nodata
pH-value notapplicable
Meltingpoint/
freezingpoint nodata
Boilingrange nodata
Flashpoint >200°CMDI
Evaporationrate nodata
Flammability nodata
(solid,gaseous)
Ignitable,explosiverangenodata
Vapourpressure <0,00001mbar(at20°C)
Vapourdensity nodata
Density 124±0,02g/cm3(at25°C)
Solubility Reactswithwaterattheborderarea
withslowCO2appearanceintonon
soluble,highmeltingpointornot
meltingpolyurea.
Partitioncoefficient notapplicable
(n-octanol/water)
Self-ignitiontemperature nodata
Decomposition
temperature nodata
Viscosity 310-370mPa·s(at20°C)
Explosiveproperties non-explosive
Oxidisingproperties nodata
9.2 Otherinformation
Notapplicable.
10. Stabilityandreactivity
10.1 Reactivity
Reactswithwater,acids,alcohols,amines,basesandoxidants.
10.2Chemicalstability
ThemainremovalmechanismofMDIsintheenvironmentis
hydrolysis.MDIreactsquicklywithwatertoformpredominantly
solid,insolublepolyureas.Underconditionstypicalofmanytypes
ofenvironmentalcontact,i.e.withrelativelypoordispersionofthe
isocyanate,theinterfacialreactionleadstotheformationofasolid
crustencasingpartiallyreactedproduct.Thiscrustrestrictsin-
gressofwaterandegressofamine,andhenceslowsandmodifies
hydrolysis.
Stability in organic solvents
AllMDIisomersandformsarehighlyunstableindimethylsulhpoxi-
desolvent,watercontentoftheDMSOisincreasingbreakdown.
MDIismorestableinEGDE(ethyleneglycoldimethylether)as
solvent.
(Read-acrossbasedon4,4’-methylenediphenyldiisocyanate-CAS
101-68-8.)
10.3Possibilityofhazardousreactions
Reactionisslowwithcoldorwarmwater(<50°C),withhotwater
orsteamthereactionisfaster,producingcarbon-dioxidecausing
pressureincrease.Acids,alcohols,amines,basesandoxidants
causefireandexplosionhazard.
10.4Conditionstoavoid
Hightemperature,moisture,stronglight.
10.5Incompatiblematerials
Substancestoavoid acids,alcohols,amines,water,alkalines.
10.6Hazardousdecompositionproducts
Nohazardousdecompositionproductsifstoredandhandledas
prescribed/indicated.
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SafetyDatasheet
Silicate Resin 3P W1
Express (Comp. B)
according to Regulation (EC) No. 1907/2006 and Regulation (EU) 2015/830
7/12
11. Toxicologicalinformation
Informationisrelatedto4,4-Methylenediphenyldiisocyanateifno
otherismentioned.
11.1 Informationontoxicologicaleffects
Acutetoxicity– Harmful
oral Rats(female)
LD50
=632mg/kg
Tris(2-chlor-1-methylethyl)phosphate
(CAS-Number:13674-84-5)
Acutetoxicity– Harmful
inhalation Rats
LC50
>2,24mg/lair(1h)
OECDGuideline403
Rats
LC50
>7mg/lair(4h)
dustsandmists
OECD403AcuteInhalationToxicity/
433AcuteInhalationToxicity-FixedDose
ProcedureTris(2-chloro-1-methylethyl)
phosphate(CAS-Number:13674-84-5)
Acutetoxicity– Notclassified.Basedonavailabledata,
dermal theclassificationcriteriaarenotmet.
Rabbit
LD50
>9400mg/kg
bw(24h)
OECDGuideline402
11.2 Irritation/Corrosion
Summarizedtheresultsofthestudiestogetherwithhumanoccup-
ationalcasereportssupporttheofficialclassification.
Skincorrosion/ Irritating
Skinirritation Irritatinginrabbits.(4h/14days)
OECDGuideline404
Eyedamage/ Notirritatinginrabbits
Irritation (24h/21days)
OECDGuideline405
(Read-acrossbasedonmethylenediphe-
nyldiisocyanate-CAS26447-40-5.)
Summarizedtheavailableanimaldatawouldnotsupportclassifica-
tionofMDIasaneyeirritant.Buttogetherwithhumanoccupatio-
nalcasereportsinwhichsymptomsofeyeirritationwerereported
thelegalclassificationaseyeirritantshouldbeapplied.
11.3 Sensitisation
Animaldataaswellasstudiesinhumansprovideevidenceof
possibleskinsensitisation,andofrespiratorysensitisationdueto
MDI.AnimalstudiesindicatethatMDIisastrongallergen.Human
casereportsdescribetheoccurrenceofallergiccontactdermatitis
duetoMDIexposure.
Skinsensitisation MiceSensitizing.
OECDGuideline429(LLNA)
Respiratorysensitisation GuineapigSensitizing.
11.4 Mutagenicity
Notclassified.Basedonavailabledata,theclassificationcriteria
arenotmet.
11.5 Carcinogenity
Carc.Cat.2 Rats(inhalation)
NOAEC=0,2mg/m3air(Toxicity)
(2years;6h/day,5days/week)
NOAEC=1mg/m3air(Carcinogenicity)
(2years;6h/day,5days/week)
LOAEC=6mg/m3air(Carcinogenicity)
(2years;6h/day,5days/week)
OECDGuideline414
11.6 Reproductivetoxicity
Notclassified.Basedonavailabledata,theclassificationcriteria
arenotmet.
Effectsonfertility Nofertilitynormultigenerationstudies
areavailableforMDI.
Rats(inhalation)
NOAEL=4mg/m3air(developmental
toxicity)(10days;1/day,6h)
NOAEL=4mg/m3(maternaltoxicity)
(10days;1/day,6h)
OECDGuideline453
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SafetyDatasheet
Silicate Resin 3P W1
Express (Comp. B)
according to Regulation (EC) No. 1907/2006 and Regulation (EU) 2015/830
8/12
11.7 STOT-singleexposure
MDIsareirritanttotherespiratorytract.
11.8 STOT-repeatedexposure
Harmful Rats(inhalation)
LOAEC=1mg/m3air
(2years;6h/day,5days/week)
Targetorgans:respiratory–lung
OECDGuideline453
11.9 Aspirationhazard
Notclassifiedduetolackofdata.
12. Ecologicalinformation
Informationisrelatedto4,4-Methylenediphenyldiisocyanateifno
otherismentioned.
12.1 Toxicity
12.1.1 Aquatictoxicity
Short-termtoxicitytofish
Freshwaterfish LC50
>1000mg/l(96h)
(Brachydaniorerio) OECDGuideline203
Fisch LC50
=56,2mg/l(96h)
Tris(2-chlor-1-methylethyl)phosphate
(CAS-Number:13674-84-5)
Long-termtoxicitytofish
Datawaiving.Inaccordancewithcolumn2ofREACHAnnexIXthe
long-termtoxicitytestingonfishshallbeproposedifthechemical
safetyassessmentaccordingtoAnnexIindicatestheneedto
investigatefurthertheeffectsonaquaticorganisms.Thecorrespon-
dingPEC/PNECratioswouldbelessthan1.Takingintoaccountthe
scientificandexposurearguments,itappearsappropriatetowaiver
thelong-termfish/plant/soilandsedimenttoxicitystudies.
Short-termtoxicitytoaquaticinvertebrates
Freshwaterinvertebrates EC50
>1000mg/l(24h)
(Daphniamagna) OECDGuideline202
Freshwaterinvertebrates EC50
=131mg/l(48h)
(Daphniamagna) Tris(2-chlor-1-methylethyl)phosphate
(CAS-Number:13674-84-5)
Long-termtoxicitytoaquaticinvertebrates
Freshwaterinvertebrates NOEC>=10mg/l(21h)
(Daphniamagna) OECDGuideline211
Toxicitytoaquaticalgaeandcyanobacteria
Freshwateralgae EC50
>1640mg/l(72h)
(Desmodesmus OECDGuideline201
subspicatus)
Freshwateralgae EC50
=82mg/l(72h)
(Desmodesmus Tris(2-chlor-1-methylethyl)phosphate
subspicatus) (CAS-Number:13674-84-5)
Toxicitytoaquaticplantsotherthanalgae
Datawaiving.NotrequiredbyREACHannexes.However,a
mesocosmstudywithPMDIexistsinwhichthetoxicitytowards
macrophytes(PotamogetoncrispusandZannichelliapalustris)was
assessed.Notoxicitywasobservedataloadingof1000and10,000
mg/l,approximately100%ofthesubstancewasfoundinthesedi-
mentashardenedmaterial.
Toxicitytomicroorganisms
Microorganisms EC50
>100mg/l(3h)
(activatedsludge) OECDGuideline209
Toxicitytootheraquaticorganisms
Thisinformationisnotavailable,butnotrequiredunderREACH.
12.1.2Sedimenttoxicity
Datawaiving.AnnexXstatesthatthisstudyneednotbeconducted
ifthechemicalsafetyassessmentdoesnotindicateaneedto
furtherinvestigatetheeffectsonsedimentorganisms.
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Silicate Resin 3P W1
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according to Regulation (EC) No. 1907/2006 and Regulation (EU) 2015/830
9/12
12.1.3Terrestrialtoxicity
Toxicitytosoilmacroorganismsexceptarthropods
Eiseniafetida EC50
>1000mg/kgsoil
dw(14days)
OECDGuideline207
Toxicitytoterrestrialarthropods
Datawaiving.Basedonthechemicalsafetyassessmentand
theriskassessment,thereisnoneedtofurtherinvestigatethe
terrestrialarthropodstoxicityasthereisnoriskfortheterrestrial
environmentasindicatedbythePEC/PNECratiobeing<0.239.
Direct/indirectexposuretosoilisunlikely.
Toxicitytoterrestrialplants
Avenasativa EC50
>1000mg/kgsoil
dw(14days)
Lactucasativa EC50
>1000mg/kgsoil
dw(14days)
OECDGuideline208
Toxicitytosoilmicroorganisms
Datawaiving.AnnexXstatesthatthisstudyneednotbeconduc-
tedifthechemicalsafetyassessmentdoesnotindicateaneedto
furtherinvestigatetheeffectsonsedimentorganisms.
Toxicitytootherabove-groundorganisms
Datawaiving.NotrequiredbyREACHannexes.
12.1.4Conclusiononclassification
Hazardoustotheaquaticenvironment(acute)
Basedonavailabledata,theclassificationcriteriaarenotmet.
(EC/LC50
forfish,invertebratesandalgae>1000mg/l)
Hazardoustotheaquaticenvironment(chronic)
Basedonavailabledata,theclassificationcriteriaarenotmet.
(NOECforalgae>1640mg/L;NOECforinvertebrates>10mg/l).
12.2Persistenceanddegradability
Phototransformationinair
Half-life(DT50
) 1day
Hydrolysis
MDIreactswithwatertoformpredominantlyinertpolyurea.
Half-life(DT50
) 20h(at25°C)
Reactionratehydrolysis 0.5-1h
(Read-acrossbasedonOligomerMDI–CAS32055-14-4)
Phototransformationinwaterandsoil
Therearenophototransformationdatainwaterandsoilforthe
testsubstance.
Biodegradationinwater
Undertestconditionsnobiodegradationobserved.
(28days)OECDGuideline302C
Biodegradationinwaterandsediment
Datawaiving.InaccordancewithAnnexXI,simulationbiodegrada-
tiontestsaretechnicallynotfeasibleasthetestsubstancereacts
quicklywithwater.ThecorrespondingPEC/PNECratioswouldbe
lessthan1.Takingintoaccountthescientificandexposureargu-
ments,itappearsappropriatetowaiverthelong-termfish/plant/soil
andsedimenttoxicitystudies.
Biodegradationinsoil
Datawaiving.SeeatBiodegradationinwaterandsediment.
12.3Bioaccumulativepotential
Bioaccumulation-aquatic/sediment:Duetothehighreactivityof
thesubstancesoftheMDIcategorywithwater,bioaccumulation
testscaninprinciplenotbeperformedwiththesesubstances.
However,onebioaccumulationtestwith4,4'MDIandamesocosm
studywithPMDIwithanindicationofbioaccumulationpotential
havebeenperformed.Asnoanalyticalmeasurementsweredone,
itcannotbedeterminedifthevaluesaretrulyrelatedtoMDI.
However,basedontheavailableinformationandthereactivityof
MDIsubstancesofthecategoryapproach,nonewbioaccumulation
studyisdeemednecessary.
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SafetyDatasheet
Silicate Resin 3P W1
Express (Comp. B)
according to Regulation (EC) No. 1907/2006 and Regulation (EU) 2015/830
10/12
12.4Mobilityinsoil
Adsorption/desorption Datawaiving.AccordingtoAnnexVIII
thestudyneednotbedoneifthetest
substancedegradesrapidly.Thecorres-
pondingPEC/PNECratioswouldbeless
than1.Takingintoaccountthescientific
andexposurearguments,itappears
appropriatetowaiverthelong-termfish/
plant/soilandsedimenttoxicitystudies.
Volatilisation TheestimatedHenry’sLawConstant,
calculatedfromthemeasuredvapour
pressureandthecalculatedwater
solubility,is2.263x10-7atm-m3/mole.
Hence,volatilizationisunlikelytobea
significantremovalmechanismforMDI
substancesofthecategoryapproach.
BCF(Cyprinuscarpio) 200(28days)
OECDGuideline305E
Terrestrialbioaccumulation
Nodataisavailableonterrestrialbioaccumulation,butitisnot
requiredunderREACH.
12.5ResultsofPBTandvPvBassessment
ConclusionforthePcriterion
TheresultsfromthebiodegradationtestindicatethatPMDIis
notbiodegradable.Basedonexperimentalhydrolysisandindirect
photolysishalf-lives,PMDIisnotconsideredtobepersistentinthe
environmentandisidentifiedasnotP.Basedonthejustification
inthecategoryapproach,itisassumedthatallMDIanalogues
includedinthecategoryarenotP.
ConclusionfortheBcriterion
AlthoughMDIhasahighmeasuredlogPowvalue(4.51),afull
bioaccumulationtestwith4,4’-MDIindicatedthatthebioaccumu-
lationpotentialislow.Duetothefasthydrolysis,exposureofthe
environmenttothesubstanceisunlikelyorverylow,thereisno
potentialforsignificantbioaccumulationpossible.Hence,4,4’-MDI
doesnotfulfiltherequirementsfortheBcriterionandisnotiden-
tifiedasB.Basedonthejustificationinthecategoryapproach,itis
assumedthatallMDIanaloguesincludedinthecategoryarenotB.
13. Disposalconsiderations
13.1 Wastetreatmentmethods
Theproductsbecominguselessandthecontaminatedcontainers
notsuitableforproductstoragemustbehandledashazardous
wasteinaccordancewithEUandregionalhazardouswasteregu-
lations.
EuropeanWasteCataloguecode
080501
13.1.1 Product/Packagingdisposal
Contaminatedpackagingshouldbeemptiedasfaraspossible;than
itcanbepassedonforrecyclingafterbeingthoroughlycleaned.
Wrappingscleanedfromcontaminationwithsuitablecleaning
process(e.g.bysteaming,treatingwithwashingfluid,etc.)mustbe
consideredasnonhazardouswaste.
13.1.2Wastetreatmentoptions
Incinerateinsuitableincinerationplant,observinglocalauthority
regulations.
ConclusionfortheTcriterion
Theconcentrationstestedwerefarabovethewatersolubilityof
theMDIsubstances(7.5mg/l).However,thewatersolubilitylimitof
MDIisfarabovethecriteriaforTandonthebasisofaquatic
toxicitytestsMDIisidentifiedasnotT.However,accordingto
AnnexIof67/548/EECMDIisclassifiedasXn,R48,which
automaticallytriggersaT.BasedonthisclassificationMDIis
identifiedasT.
12.6Otheradverseeffects
Itisnotexpectedthatsubstancehasaneffectonglobalwarming,
ozonedepletioninthestratosphereorozoneformationinthe
troposphere.
Secondarypoisoning:Basedontheavailableinformation,thereis
noindicationofabioaccumulationpotentialand,hence,secondary
poisoningisnotconsideredrelevant.
Exposuretobirdsisnotexpectedanddatafromexperimentalani-
malsshowMDItobeofloworaltoxicity.
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Silicate Resin 3P W1
Express (Comp. B)
according to Regulation (EC) No. 1907/2006 and Regulation (EU) 2015/830
11/12
14. Transportinformation
Landtransport(ADR/RID/GGVSE)
Seatransport(IMDG-Code/GGVSee)
Airtransport(ICAO-IATA/DGR)
14.1 UNnumber
Notdangerousgoods.
14.2UNpropershippingname
Notdangerousgoods.
14.3Transporthazardclass(es)
Notdangerousgoods.
14.4Packaginggroup
Notdangerousgoods.
14.5Environmentalhazards
Marinepollutant no
14.6Specialprecautionsforusers
EmSnumber Notdangerousgoods.
14.7TransportinbulkaccordingtoAnnexIIofMARPOL73/78andtheIBCCode
Notrelevant.
15. Regulatoryinformation
15.1 Safety,healthandenvironmentalregulations/legisla-tionsspecificforthesubstanceormixture
Information regarding relevant Community safety, health and
environmental provisions
ISOPA,theEuropeanDiisocyanate&PolyolProducersAssociation
haselaboratedaGuidelinedocumentforthesafetreatmentofMDI
containingproducts.TheGuidelineshavebeenbuiltintothisdata
sheet.
15.2ChemicalSafetyAssessment
InaccordancewithREACHChemicalSafetyAssessmenthasnot
beencarriedoutfortheproduct.However,theresultsfromthe
CSAfor4,4’-MDIweretransposedintothisSDS.
16. Otherinformation
Theinformationgivencorrespondswithouractualknowledgeand
experience.Thisinformationismeanttodescribeourproductin
viewofpossiblesafetyrequirements.Classificationofthemixture
isbasedontheclassificationofcomponents.
16.1 Indicationofchanges
DuetothetransitiontotheclassificationaccordingtoCLP,the
safetydatasheetshallberegardedasfullynew.
16.2Abbreviationsandacronyms
bw bodyweight
CASnumber ChemicalAbstractsServicenumber.
CLP Regulationonclassification,labelling
andpackaging.
DNEL Derivednoeffectlevel.
dw dryweight
ECnumber EINECSandELINCSnumber.
EC50
Halfmaximaleffectiveconcentration.
EINECS EuropeanInventoryofExistingCommer-
cialChemicalSubstances.
ELINCS EuropeanListofNotifiedChemical
Substances.
LC50
Lethalconcentration,50%.
LD50
MedianLethaldose.
LOAEC LowestObservedAdverseEffect
Concentration.
NOAEC NoObservedAdverseEffect
Concentration.
NOAEL NoObservedAdverseEffectLevel.
NOEC NoObservedEffectConcentration.
OECD OrganisationforEconomicCooperation
andDevelopment.
PBT Persistent,BioaccumulativeandToxic.
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SafetyDatasheet
Silicate Resin 3P W1
Express (Comp. B)
according to Regulation (EC) No. 1907/2006 and Regulation (EU) 2015/830
12/12
PolymericMDI Polymethylenepolyphenyl
poliisocyanate.
PEC PredictedEnvironmentalConcentration.
PNEC PredictedNoEffectConcentration.
REACH TheRegistration,Evaluation,Authorisa-
tionandRestrictionofChemicals.
vPvB VeryPersistentandVery
Bioaccumulative.
16.3Keyliteraturereferencesandsourcesfordata
safetydatasheets,receivedfromtherawmaterialssuppliers.
16.4Fulltextofabbreviations
H- Phrases
H302 Harmfulifswallowed.
H315 Causesskinirritation.
H317 Maycauseanallergicskinreaction.
H319 Causesseriouseyeirritation.
H332 Harmfulifinhaled.
H334 Maycauseallergyorasthmasymptoms
orbreathingdifficultiesifinhaled.
H335 Maycauserespiratoryirritation.
H351 Suspectedofcausingcancer.
H373 Maycausedamagetoorgansthrough
prolongedorrepeatedexposure:
respiratorysystem,inhalation.
P- Phrases
P260 Donotbreathedust/fume/gas/mist/
vapours/spray.
P280 Wearprotectivegloves/protective
clothing/eyeprotection/faceprotection.
P285 Incaseofinadequateventilationwear
respiratoryprotection.
P302+P352 IFONSKIN:Washwithplentyofsoap
andwater.
P304+P340 IFINHALED:Removevictimtofresh
airandkeepatrestinaposition
comfortableforbreathing.
P309+P311 IFexposedorifyoufeelunwell:Calla
POISONCENTERordoctor/physician.
Hazard classes
AcuteTox. AcuteToxicity
Carc. Carcinogenity
EyeIrrit. Seriouseyeirritation
Resp.Sens. Respiratorysensitization
SkinIrrit. Skinirritation
SkinSens. Skinsensitization
STOTRE Specifictargetorgantoxicity–
repeatedexposure
STOTSE Specifictargetorgantoxicity–
singleexposure
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