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Page 1: ChemInform Abstract: Regioselective Synthesis of Pyrroloquinolines — Approaches to Martinelline

1999 fused pyridine derivatives

fused pyridine derivativesR 0450

22 - 147Regioselective Synthesis of Pyrroloquinolines – Approaches to Mar-tinelline. — Diels–Alder reaction of imines with cyclic enamides catalyzedby indium trichloride affords cis-fused pyrroloquinolines which form the corestructure of martinelline. The mixtures of endo and exo isomers are readilyseparated by chromatography. — (HADDEN, MARK; STEVENSON, PAULJ.; Tetrahedron Lett. 40 (1999) 6, 1215-1218; Sch. Chem., Queen’s Univ.,Belfast BT9 5AG, UK; EN)

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