Kit components27.11.2020
Product code Description
PT-CN-CFULL CONTEST Group C Full
Components:
PT-CN-C03C 3C - Group C Soil
PT-CN-C05 5 - Group C PAHs
PT-CN-C07A 7a - Group C Phenol
PT-CN-C07B 7b - Group C Phenol
PT-CN-C11 11 - Group C PCBs
PT-CN-C14A 14a - Group C TPH
PT-CN-C14B 14b - Group C TPH
PT-CN-C15 15 - Group C BTEX
PT-CN-C19 19 - Group C Chlorinated Hydrocarbons
PT-CN-C20 20 - Group C SVOCs
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Safety data sheetaccording to 1907/2006/EC, Article 31
Printing date 27.11.2020 Revision: 27.11.2020Version number 1
49.2.0
SECTION 1: Identification of the substance/mixture and of the company/undertaking
· 1.1 Product identifier
· Product name: 3C - Group C Soil
· Part number: PT-CN-C03C
· 1.2 Relevant identified uses of the substance or mixture and uses advised againstNo further relevant information available.
· Application of the substance / the mixture Reference material for laboratory use only
· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:
LGC Limited Tel :+44 (0) 20 8943 7000
Queens Road Fax :+44 (0) 20 8943 2767
Teddington eMail : [email protected]
Middlesex TW11 0LY Web : www.lgcstandards.com
UNITED KINGDOM
· Further information obtainable from:Product safety department
eMail : [email protected]
· 1.4 Emergency telephone number:For Hazardous Materials or Dangerous Goods Incident
Spill, Leak, Fire Exposure, or Accident
Call CHEMTREC:
USA & Canada 1-800-424-9300
Rest of the world +1 703-741-5970
SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008
GHS08 health hazard
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS08
· Signal word Warning
· Hazard-determining components of labelling:Quartz (SiO2)
(Contd. on page 2)
GB
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(Contd. from page 1)
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· Hazard statementsH373 May cause damage to organs through prolonged or repeated exposure.
· Precautionary statementsP260 Do not breathe dust/fume/gas/mist/vapours/spray.
P314 Get medical advice/attention if you feel unwell.
P501 Dispose of contents/container in accordance with local/regional/national/international regulations.
· 2.3 Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
· 3.2 Chemical characterisation: Mixtures· Description: Also contains substances at levels not considered to be hazardous.
· Dangerous components:
CAS: 14808-60-7
EINECS: 238-878-4
RTECS: VV 7330000
Quartz (SiO2) STOT RE 2, H373; Acute Tox. 4, H332 >95%
· Additional information: For the wording of the listed hazard phrases refer to section 16.
SECTION 4: First aid measures
· 4.1 Description of first aid measures· General information:
Symptoms of poisoning may occur even after several hours; therefore medical observation for at least 48
hours after the accident is recommended.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: Rinse mouth. Do not induce vomiting.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment neededNo further relevant information available.
SECTION 5: Firefighting measures
· 5.1 Extinguishing media· Suitable extinguishing agents: Use fire extinguishing methods suitable for surrounding conditions.
· 5.2 Special hazards arising from the substance or mixtureDuring heating or in case of fire poisonous gases are produced.
· 5.3 Advice for firefighters· Protective equipment:
Mouth respiratory protective device.(Contd. on page 3)
GB
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Product name: 3C - Group C Soil
(Contd. from page 2)
49.2.0
Wear self-contained respiratory protective device.
SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency proceduresMount respiratory protective device.
· 6.2 Environmental precautions: Do not allow product to reach sewage system or any water course.
· 6.3 Methods and material for containment and cleaning up:Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sectionsSee Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
· 7.1 Precautions for safe handlingEnsure good ventilation/extraction at the workplace.
Store in cool, dry place in tightly closed receptacles.
· Information about fire - and explosion protection: Keep respiratory protective device available.
· 7.2 Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:
Please refer to the manufacturer's certificate for specific storage and transport temperature conditions.
Store only in the original receptacle unless other advice is given on the CoA.
Keep container in a well-ventilated place. Keep away from sources of ignition and heat.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions: None.
· 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
· Additional information: Lists used were valid at the time of SDS preparation.
· 8.2 Exposure controls· Personal protective equipment:· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.(Contd. on page 4)
GB
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Product name: 3C - Group C Soil
(Contd. from page 3)
49.2.0
Store protective clothing separately.
· Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
· Protection of hands:The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the
related standard EN374
Protective gloves
· Material of gloves Fluorocarbon rubber (Viton)
· Penetration time of glove materialThe exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
Tightly sealed goggles
SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties· General Information· Appearance:
Form: Solid
Colour: Brown
· Odour: Odourless
· Odour threshold: Not determined.
· pH-value: Not applicable.
· Change in conditionMelting point/freezing point: 1,713 °C
Initial boiling point and boiling range: 2,230 °C
· Flash point: Not applicable.
· Flammability (solid, gas): Not determined.
· Ignition temperature: Not determined
· Decomposition temperature: Not determined.
(Contd. on page 5)
GB
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(Contd. from page 4)
49.2.0
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Not determined.
· Explosion limits:Lower: Not determined.
Upper: Not determined.
· Vapour pressure at 1732 °C: 13.5 hPa
· Density at 20 °C: 2.2-2.6 g/cm³
· Bulk density: 1,400 kg/m³
· Relative density Not determined.
· Vapour density Not applicable.
· Evaporation rate Not applicable.
· Solubility in / Miscibility withwater: Insoluble.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:Dynamic: Not applicable.
Kinematic: Not applicable.
· 9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity
· 10.1 ReactivityStable under normal conditions.
No further relevant information available.
· 10.2 Chemical stability Stable under normal conditions.
· Thermal decomposition / conditions to be avoided:Formation of toxic gases is possible during heating or in case of fire.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid Heat.
· 10.5 Incompatible materials: Strong oxidizing agents.
· 10.6 Hazardous decomposition products:Formation of toxic gases is possible during heating or in case of fire.
SECTION 11: Toxicological information
· 11.1 Information on toxicological effects· Acute toxicity Based on available data, the classification criteria are not met.
· Primary irritant effect:· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.(Contd. on page 6)
GB
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(Contd. from page 5)
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· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposureMay cause damage to organs through prolonged or repeated exposure.
· Aspiration hazard Based on available data, the classification criteria are not met.
SECTION 12: Ecological information
· 12.1 Toxicity· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:· General notes: Not hazardous for water.
· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
· 13.1 Waste treatment methods· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· European waste catalogueWaste disposal key numbers from EWC have to be assigned depending on origin and processing.
· Uncleaned packaging:· Recommendation: Dispose of in accordance with national regulations.
SECTION 14: Transport information
· 14.1 UN-Number· ADR, IMDG, IATA Not applicable
· ADR, IMDG, IATA Not applicable
· 14.3 Transport hazard class(es)
· ADR, ADN, IMDG, IATA· Class Not applicable
(Contd. on page 7)
GB
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(Contd. from page 6)
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· 14.4 Packing group· ADR, IMDG, IATA Not applicable
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Not applicable.
· 14.7 Transport in bulk according to Annex II ofMarpol and the IBC Code Not applicable.
· UN "Model Regulation": Not applicable
SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
The information in this safety data sheet (SDS) has been prepared with due care and is true and accurate to
the best of our knowledge. The user must determine the suitability of the information for its particular
purpose, ensure compliance with existing laws and regulations, and be aware that other or additional safety
or performance considerations may arise when using, handling and/ or storing the material. The information
in this SDS does not purport to be all inclusive or a guarantee as to the properties of the material supplied,
and should be used only as a guide. LGC makes no warranties or representations as to the accuracy and
completeness of the information contained herein, shall not be held responsible for the suitability of this
information for the user's intended purposes or the consequences of such use, and shall not be liable for any
damage or loss, howsoever arising, direct or otherwise.
· Abbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Acute Tox. 4: Acute toxicity – Category 4
STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
· SourcesTables 3.1 and 3.2 from Annex 6 of EC 1272/2008, EC 1907/2006, EH40/2005 as amended 2011, Registry of
Toxic Effects of Chemical Substances (RTECS), The Dictionary of Substances and their Effects, 1st Edition,
IUCLID.
· Data compared to the previous version altered. All sections have been updated. GB
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49.2.0
SECTION 1: Identification of the substance/mixture and of the company/undertaking
· 1.1 Product identifier
· Product name: 5 - Group C PAHs
· Part number: PT-CN-C05
· 1.2 Relevant identified uses of the substance or mixture and uses advised againstNo further relevant information available.
· Application of the substance / the mixture Reference material for laboratory use only
· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:
LGC Limited Tel :+44 (0) 20 8943 7000
Queens Road Fax :+44 (0) 20 8943 2767
Teddington eMail : [email protected]
Middlesex TW11 0LY Web : www.lgcstandards.com
UNITED KINGDOM
· Further information obtainable from:Product safety department
eMail : [email protected]
· 1.4 Emergency telephone number:For Hazardous Materials or Dangerous Goods Incident
Spill, Leak, Fire Exposure, or Accident
Call CHEMTREC:
USA & Canada 1-800-424-9300
Rest of the world +1 703-741-5970
SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 2 H225 Highly flammable liquid and vapour.
GHS08 health hazard
Repr. 2 H361f Suspected of damaging fertility.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
GHS09 environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.(Contd. on page 2)
GB
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(Contd. from page 1)
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GHS07
Skin Irrit. 2 H315 Causes skin irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS02 GHS07 GHS08 GHS09
· Signal word Danger
· Hazard-determining components of labelling:n-Hexane
· Hazard statementsH225 Highly flammable liquid and vapour.
H315 Causes skin irritation.
H361f Suspected of damaging fertility.
H336 May cause drowsiness or dizziness.
H373 May cause damage to organs through prolonged or repeated exposure.
H304 May be fatal if swallowed and enters airways.
H411 Toxic to aquatic life with long lasting effects.
· Precautionary statementsP210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water [or shower].
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable. GB
(Contd. on page 3)
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(Contd. from page 2)
49.2.0
SECTION 3: Composition/information on ingredients
· 3.2 Chemical characterisation: Mixtures· Description: Also contains substances at levels not considered to be hazardous.
· Dangerous components:
CAS: 110-54-3
EINECS: 203-777-6
RTECS: MN 9275000
n-Hexane
Flam. Liq. 2, H225; Repr. 2, H361f; STOT RE 2, H373; Asp. Tox. 1,H304; Aquatic Chronic 2, H411; Skin Irrit. 2, H315; STOT SE 3, H336
>95%
· Additional information: For the wording of the listed hazard phrases refer to section 16.
SECTION 4: First aid measures
· 4.1 Description of first aid measures· General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may occur even after several hours; therefore medical observation for at least 48
hours after the accident is recommended.
· After inhalation: In case of unconsciousness place patient in recovery position for transport.
· After skin contact:Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing:Rinse mouth. Do not induce vomiting.
Call for a doctor immediately.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment neededNo further relevant information available.
SECTION 5: Firefighting measures
· 5.1 Extinguishing media· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· 5.2 Special hazards arising from the substance or mixtureDuring heating or in case of fire poisonous gases are produced.
· 5.3 Advice for firefighters· Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device. GB
(Contd. on page 4)
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(Contd. from page 3)
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SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency proceduresMount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions:Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sectionsSee Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
· 7.1 Precautions for safe handlingEnsure good ventilation/extraction at the workplace.
Store in cool, dry place in tightly closed receptacles.
Open and handle receptacle with care.
Prevent formation of aerosols.
· Information about fire - and explosion protection:Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
· 7.2 Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:
Please refer to the manufacturer's certificate for specific storage and transport temperature conditions.
Store only in the original receptacle unless other advice is given on the CoA.
Keep container in a well-ventilated place. Keep away from sources of ignition and heat.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions:Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
· 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.(Contd. on page 5)
GB
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· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
CAS: 110-54-3 n-Hexane
WEL Long-term value: 72 mg/m³, 20 ppm
· Additional information: Lists used were valid at the time of SDS preparation.
· 8.2 Exposure controls· Personal protective equipment:· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
· Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced
· Protection of hands:The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the
related standard EN374
Protective gloves
· Material of gloves Nitrile rubber, NBR
· Penetration time of glove materialThe exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
Tightly sealed goggles
GB
(Contd. on page 6)
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(Contd. from page 5)
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SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties· General Information· Appearance:
Form: Liquid
Colour: Colourless
· Odour: Petrol-like
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in conditionMelting point/freezing point: -95 °C
Initial boiling point and boiling range: 69 °C
· Flash point: -26 °C
· Flammability (solid, gas): Not determined.
· Ignition temperature: 240 °C
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product is not explosive. However, formation of explosive air/
vapour mixtures is possible.
· Explosion limits:Lower: 1.2 Vol %
Upper: 7.4 Vol %
· Vapour pressure at 20 °C: 160 hPa
· Density at 20 °C: 0.66 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility withwater at 20 °C: 0.1 g/l
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:Dynamic: Not determined.
Kinematic: Not determined.
· 9.2 Other information No further relevant information available.
GB
(Contd. on page 7)
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SECTION 10: Stability and reactivity
· 10.1 ReactivityStable under normal conditions.
No further relevant information available.
· 10.2 Chemical stability Stable under normal conditions.
· Thermal decomposition / conditions to be avoided:Formation of toxic gases is possible during heating or in case of fire.
· 10.3 Possibility of hazardous reactions May form flammable/explosive vapour-air mixture.
· 10.4 Conditions to avoidSources of ignition
Heat.
· 10.5 Incompatible materials: Strong oxidizing agents.
· 10.6 Hazardous decomposition products:Formation of toxic gases is possible during heating or in case of fire.
SECTION 11: Toxicological information
· 11.1 Information on toxicological effects· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
CAS: 110-54-3 n-Hexane
Oral LD50 5,000 mg/kg (rat)
Dermal LD50 3,000 mg/kg (rat)
· Primary irritant effect:· Skin corrosion/irritation
Causes skin irritation.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)Repr. 2
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicitySuspected of damaging fertility.
· STOT-single exposureMay cause drowsiness or dizziness.
· STOT-repeated exposureMay cause damage to organs through prolonged or repeated exposure.
· Aspiration hazardMay be fatal if swallowed and enters airways.
GB
(Contd. on page 8)
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(Contd. from page 7)
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SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
CAS: 110-54-3 n-Hexane
EC50/48 h 2.1 mg/l (daphnia)
LC50/96 h 2.5 mg/l (fish)
CAS: 191-24-2 Benzo[ghi]perylene
EC50/48 h 0.000587 mg/l (crustacean)
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Ecotoxicological effects:· Remark: Toxic for fish
· Additional ecological information:· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
· 13.1 Waste treatment methods· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· European waste catalogueWaste disposal key numbers from EWC have to be assigned depending on origin and processing.
· Uncleaned packaging:· Recommendation: Dispose of in accordance with national regulations.
SECTION 14: Transport information
· 14.1 UN-Number· ADR, IMDG, IATA UN1208
· ADR 1208 HEXANES, ENVIRONMENTALLY HAZARDOUS
· IMDG HEXANES, MARINE POLLUTANT
(Contd. on page 9)
GB
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· IATA HEXANES
· 14.3 Transport hazard class(es)
· ADR, IMDG
· Class 3 Flammable liquids.
· Label 3
· IATA
· Class 3 Flammable liquids.
· Label 3
· 14.4 Packing group· ADR, IMDG, IATA II
· 14.5 Environmental hazards: Product contains environmentally hazardous substances:
Naphthalene, n-Hexane
· Marine pollutant: Symbol (fish and tree)
· Special marking (ADR): Symbol (fish and tree)
· 14.6 Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 33
· EMS Number: F-E,S-E
· Stowage Category E
· 14.7 Transport in bulk according to Annex II ofMarpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· Transport category 2
· Tunnel restriction code D/E
· UN "Model Regulation": UN 1208 HEXANES, 3, II , ENVIRONMENTALLY
HAZARDOUS
GB
(Contd. on page 10)
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(Contd. from page 9)
49.2.0
SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso categoryE2 Hazardous to the Aquatic Environment
P5c FLAMMABLE LIQUIDS
· Qualifying quantity (tonnes) for the application of lower-tier requirements 200 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
The information in this safety data sheet (SDS) has been prepared with due care and is true and accurate to
the best of our knowledge. The user must determine the suitability of the information for its particular
purpose, ensure compliance with existing laws and regulations, and be aware that other or additional safety
or performance considerations may arise when using, handling and/ or storing the material. The information
in this SDS does not purport to be all inclusive or a guarantee as to the properties of the material supplied,
and should be used only as a guide. LGC makes no warranties or representations as to the accuracy and
completeness of the information contained herein, shall not be held responsible for the suitability of this
information for the user's intended purposes or the consequences of such use, and shall not be liable for any
damage or loss, howsoever arising, direct or otherwise.
· Abbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids – Category 2
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Repr. 2: Reproductive toxicity – Category 2
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
Asp. Tox. 1: Aspiration hazard – Category 1
Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
· SourcesTables 3.1 and 3.2 from Annex 6 of EC 1272/2008, EC 1907/2006, EH40/2005 as amended 2011, Registry of
Toxic Effects of Chemical Substances (RTECS), The Dictionary of Substances and their Effects, 1st Edition,
IUCLID.
· Data compared to the previous version altered. All sections have been updated. GB
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SECTION 1: Identification of the substance/mixture and of the company/undertaking
· 1.1 Product identifier
· Product name: 7a - Group C Phenol
· Part number: PT-CN-C07A
· 1.2 Relevant identified uses of the substance or mixture and uses advised againstNo further relevant information available.
· Application of the substance / the mixture Reference material for laboratory use only
· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:
LGC Limited Tel :+44 (0) 20 8943 7000
Queens Road Fax :+44 (0) 20 8943 2767
Teddington eMail : [email protected]
Middlesex TW11 0LY Web : www.lgcstandards.com
UNITED KINGDOM
· Further information obtainable from:Product safety department
eMail : [email protected]
· 1.4 Emergency telephone number:For Hazardous Materials or Dangerous Goods Incident
Spill, Leak, Fire Exposure, or Accident
Call CHEMTREC:
USA & Canada 1-800-424-9300
Rest of the world +1 703-741-5970
SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008
GHS05 corrosion
Skin Corr. 1B H314 Causes severe skin burns and eye damage.
Eye Dam. 1 H318 Causes serious eye damage.
· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS05
· Signal word Danger(Contd. on page 2)
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(Contd. from page 1)
49.2.0
· Hazard-determining components of labelling:Sodium hydroxide
· Hazard statementsH314 Causes severe skin burns and eye damage.
· Precautionary statementsP280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water [or shower].
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
· 3.2 Chemical characterisation: Mixtures· Description: Also contains substances at levels not considered to be hazardous.
· Dangerous components:
CAS: 1310-73-2
EINECS: 215-185-5
RTECS: WB4900000
Sodium hydroxide Skin Corr. 1A, H314; Acute Tox. 4, H302 <5%
· Additional information: For the wording of the listed hazard phrases refer to section 16.
SECTION 4: First aid measures
· 4.1 Description of first aid measures· General information: Immediately remove any clothing soiled by the product.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing: Rinse mouth. Do not induce vomiting.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment neededNo further relevant information available.
GB
(Contd. on page 3)
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(Contd. from page 2)
49.2.0
SECTION 5: Firefighting measures
· 5.1 Extinguishing media· Suitable extinguishing agents: Use fire extinguishing methods suitable for surrounding conditions.
· 5.2 Special hazards arising from the substance or mixtureDuring heating or in case of fire poisonous gases are produced.
· 5.3 Advice for firefighters· Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency proceduresMount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions:Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Use neutralising agent.
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sectionsSee Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
· 7.1 Precautions for safe handlingEnsure good ventilation/extraction at the workplace.
Store in cool, dry place in tightly closed receptacles.
Prevent formation of aerosols.
· Information about fire - and explosion protection: Keep respiratory protective device available.
· 7.2 Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:
Please refer to the manufacturer's certificate for specific storage and transport temperature conditions.
Store only in the original receptacle unless other advice is given on the CoA.
Keep container in a well-ventilated place. Keep away from sources of ignition and heat.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions: Keep container tightly sealed.(Contd. on page 4)
GB
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(Contd. from page 3)
49.2.0
· 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
CAS: 1310-73-2 Sodium hydroxide
WEL Short-term value: 2 mg/m³
· Additional information: Lists used were valid at the time of SDS preparation.
· 8.2 Exposure controls· Personal protective equipment:· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
· Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
· Protection of hands:The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the
related standard EN374
Protective gloves
· Material of gloves Nitrile rubber, NBR
· Penetration time of glove materialThe exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
Tightly sealed goggles
GB
(Contd. on page 5)
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(Contd. from page 4)
49.2.0
SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties· General Information· Appearance:
Form: Liquid
Colour: Colourless
· Odour: Odourless
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in conditionMelting point/freezing point: Not determined.
Not determined.
Initial boiling point and boiling range: 100 °C
· Flash point: Not applicable.
· Flammability (solid, gas): Not determined.
· Ignition temperature: Not determined
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Not determined.
· Explosion limits:Lower: Not determined.
Upper: Not determined.
· Vapour pressure at 20 °C: 23 hPa
· Density at 20 °C: 1.00452 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility withwater: Fully miscible.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:Dynamic: Not determined.
Kinematic: Not determined.
· 9.2 Other information No further relevant information available.
GB
(Contd. on page 6)
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(Contd. from page 5)
49.2.0
SECTION 10: Stability and reactivity
· 10.1 ReactivityStable under normal conditions.
No further relevant information available.
· 10.2 Chemical stability Stable under normal conditions.
· Thermal decomposition / conditions to be avoided:Formation of toxic gases is possible during heating or in case of fire.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid Heat.
· 10.5 Incompatible materials: Strong oxidizing agents.
· 10.6 Hazardous decomposition products:Formation of toxic gases is possible during heating or in case of fire.
SECTION 11: Toxicological information
· 11.1 Information on toxicological effects· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
CAS: 1310-73-2 Sodium hydroxide
Oral LD50 2,000 mg/kg (rat)
LD 50 (Intraperitoneal) 40 mg/kg (rat)
· Primary irritant effect:· Skin corrosion/irritation
Causes severe skin burns and eye damage.
· Serious eye damage/irritationCauses serious eye damage.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
SECTION 12: Ecological information
· 12.1 Toxicity· Aquatic toxicity: No further relevant information available.
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.(Contd. on page 7)
GB
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(Contd. from page 6)
49.2.0
· Additional ecological information:· General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product to reach ground water, water course or sewage system.
Must not reach sewage water or drainage ditch undiluted or unneutralised.
· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
· 13.1 Waste treatment methods· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· European waste catalogueWaste disposal key numbers from EWC have to be assigned depending on origin and processing.
· Uncleaned packaging:· Recommendation: Dispose of in accordance with national regulations.
· Recommended cleansing agents: Water, if necessary together with cleansing agents.
SECTION 14: Transport information
· 14.1 UN-Number· ADR, IMDG, IATA UN1824
· ADR 1824 SODIUM HYDROXIDE SOLUTION
· IMDG, IATA SODIUM HYDROXIDE SOLUTION
· 14.3 Transport hazard class(es)
· ADR, IMDG, IATA
· Class 8 Corrosive substances.
· Label 8
· 14.4 Packing group· ADR, IMDG, IATA III
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Warning: Corrosive substances.
· Danger code (Kemler): 80
· EMS Number: F-A,S-B
· Segregation groups Alkalis
(Contd. on page 8)
GB
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(Contd. from page 7)
49.2.0
· Stowage Category A
· Segregation Code SG35 Stow "separated from" SGG1-acids
· 14.7 Transport in bulk according to Annex II ofMarpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
· Transport category 3
· Tunnel restriction code E
· UN "Model Regulation": UN 1824 SODIUM HYDROXIDE SOLUTION, 8, III
SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
The information in this safety data sheet (SDS) has been prepared with due care and is true and accurate to
the best of our knowledge. The user must determine the suitability of the information for its particular
purpose, ensure compliance with existing laws and regulations, and be aware that other or additional safety
or performance considerations may arise when using, handling and/ or storing the material. The information
in this SDS does not purport to be all inclusive or a guarantee as to the properties of the material supplied,
and should be used only as a guide. LGC makes no warranties or representations as to the accuracy and
completeness of the information contained herein, shall not be held responsible for the suitability of this
information for the user's intended purposes or the consequences of such use, and shall not be liable for any
damage or loss, howsoever arising, direct or otherwise.
· Abbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
(Contd. on page 9)
GB
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(Contd. from page 8)
49.2.0
vPvB: very Persistent and very Bioaccumulative
Acute Tox. 4: Acute toxicity – Category 4
Skin Corr. 1A: Skin corrosion/irritation – Category 1A
Skin Corr. 1B: Skin corrosion/irritation – Category 1B
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
· SourcesTables 3.1 and 3.2 from Annex 6 of EC 1272/2008, EC 1907/2006, EH40/2005 as amended 2011, Registry of
Toxic Effects of Chemical Substances (RTECS), The Dictionary of Substances and their Effects, 1st Edition,
IUCLID.
· Data compared to the previous version altered. All sections have been updated. GB
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SECTION 1: Identification of the substance/mixture and of the company/undertaking
· 1.1 Product identifier
· Product name: 7b - Group C Phenol
· Part number: PT-CN-C07B
· 1.2 Relevant identified uses of the substance or mixture and uses advised againstNo further relevant information available.
· Application of the substance / the mixture Reference material for laboratory use only
· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:
LGC Limited Tel :+44 (0) 20 8943 7000
Queens Road Fax :+44 (0) 20 8943 2767
Teddington eMail : [email protected]
Middlesex TW11 0LY Web : www.lgcstandards.com
UNITED KINGDOM
· Further information obtainable from:Product safety department
eMail : [email protected]
· 1.4 Emergency telephone number:For Hazardous Materials or Dangerous Goods Incident
Spill, Leak, Fire Exposure, or Accident
Call CHEMTREC:
USA & Canada 1-800-424-9300
Rest of the world +1 703-741-5970
SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 2 H225 Highly flammable liquid and vapour.
GHS06 skull and crossbones
Acute Tox. 3 H301 Toxic if swallowed.
Acute Tox. 3 H311 Toxic in contact with skin.
Acute Tox. 3 H331 Toxic if inhaled.
GHS08 health hazard
STOT SE 1 H370 Causes damage to organs.(Contd. on page 2)
GB
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(Contd. from page 1)
49.2.0
· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS02 GHS06 GHS08
· Signal word Danger
· Hazard-determining components of labelling:Methanol
· Hazard statementsH225 Highly flammable liquid and vapour.
H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled.
H370 Causes damage to organs.
· Precautionary statementsP210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water [or shower].
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
· 3.2 Chemical characterisation: Mixtures· Description: Also contains substances at levels not considered to be hazardous.
· Dangerous components:
CAS: 67-56-1
EINECS: 200-659-6
RTECS: PC1400000
Methanol
Flam. Liq. 2, H225; Acute Tox. 3, H301; Acute Tox. 3, H311; AcuteTox. 3, H331; STOT SE 1, H370
>95%
· Additional information: For the wording of the listed hazard phrases refer to section 16. GB
(Contd. on page 3)
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(Contd. from page 2)
49.2.0
SECTION 4: First aid measures
· 4.1 Description of first aid measures· General information:
Immediately remove any clothing soiled by the product.
Remove breathing equipment only after contaminated clothing has been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
· After inhalation:Supply fresh air or oxygen; call for doctor.
In case of unconsciousness place patient in recovery position for transport.
Seek immediate medical advice.
· After skin contact:Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:Rinse mouth. Do not induce vomiting.
Call for a doctor immediately.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment neededNo further relevant information available.
SECTION 5: Firefighting measures
· 5.1 Extinguishing media· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· 5.2 Special hazards arising from the substance or mixtureDuring heating or in case of fire poisonous gases are produced.
· 5.3 Advice for firefighters· Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency proceduresMount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions:Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.(Contd. on page 4)
GB
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(Contd. from page 3)
49.2.0
· 6.4 Reference to other sectionsSee Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
· 7.1 Precautions for safe handlingEnsure good ventilation/extraction at the workplace.
Store in cool, dry place in tightly closed receptacles.
Open and handle receptacle with care.
Prevent formation of aerosols.
· Information about fire - and explosion protection:Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
· 7.2 Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:
Please refer to the manufacturer's certificate for specific storage and transport temperature conditions.
Store only in the original receptacle unless other advice is given on the CoA.
Keep container in a well-ventilated place. Keep away from sources of ignition and heat.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions:Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
· 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
CAS: 67-56-1 Methanol
WEL Short-term value: 333 mg/m³, 250 ppm
Long-term value: 266 mg/m³, 200 ppm
Sk
· Additional information: Lists used were valid at the time of SDS preparation.
· 8.2 Exposure controls· Personal protective equipment:· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.(Contd. on page 5)
GB
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49.2.0
Store protective clothing separately.
Avoid contact with the eyes and skin.
· Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced
· Protection of hands:The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the
related standard EN374
Protective gloves
· Material of gloves Butyl rubber, BR
· Penetration time of glove materialThe exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
Tightly sealed goggles
SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties· General Information· Appearance:
Form: Liquid
Colour: Colourless
· Odour: Alcohol-like
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in conditionMelting point/freezing point: -98 °C
Initial boiling point and boiling range: 65 °C
· Flash point: 12 °C
(Contd. on page 6)
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49.2.0
· Flammability (solid, gas): Not determined.
· Ignition temperature: Not determined
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product is not explosive. However, formation of explosive air/
vapour mixtures is possible.
· Explosion limits:Lower: 6 Vol %
Upper: 50 Vol %
· Vapour pressure: Not determined.
· Density at 20 °C: 0.80001 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility withwater: Fully miscible.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:Dynamic: Not determined.
Kinematic: Not determined.
· 9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity
· 10.1 ReactivityStable under normal conditions.
No further relevant information available.
· 10.2 Chemical stability Stable under normal conditions.
· Thermal decomposition / conditions to be avoided:Formation of toxic gases is possible during heating or in case of fire.
· 10.3 Possibility of hazardous reactions May form flammable/explosive vapour-air mixture.
· 10.4 Conditions to avoidSources of ignition
Heat.
· 10.5 Incompatible materials:Strong oxidizing agents.
Strong acids.
Reducing agents.
Alkali metals.(Contd. on page 7)
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· 10.6 Hazardous decomposition products:Formation of toxic gases is possible during heating or in case of fire.
SECTION 11: Toxicological information
· 11.1 Information on toxicological effects· Acute toxicity
Toxic if swallowed, in contact with skin or if inhaled.
· LD/LC50 values relevant for classification:
CAS: 67-56-1 Methanol
Oral (LD50) 5,630 mg/kg (rat)
Dermal (LD50) 15,800 mg/kg (rabbit)
Inhalative (LC50/4h) 83.9 mg/l (rat)
· Primary irritant effect:· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposureCauses damage to organs.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
CAS: 67-56-1 Methanol
LC50/96 h 24,000 mg/l (fish)
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.(Contd. on page 8)
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· 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
· 13.1 Waste treatment methods· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· European waste catalogueWaste disposal key numbers from EWC have to be assigned depending on origin and processing.
· Uncleaned packaging:· Recommendation: Dispose of in accordance with national regulations.
· Recommended cleansing agents: Water, if necessary together with cleansing agents.
SECTION 14: Transport information
· 14.1 UN-Number· ADR, IMDG, IATA UN1230
· ADR 1230 METHANOL mixture
· IMDG, IATA METHANOL mixture
· 14.3 Transport hazard class(es)
· ADR
· Class 3 Flammable liquids.
· Label 3+6.1
· IMDG
· Class 3 Flammable liquids.
· Label 3/6.1
· IATA
· Class 3 Flammable liquids.
(Contd. on page 9)
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· Label 3 (6.1)
· 14.4 Packing group· ADR, IMDG, IATA II
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 336
· EMS Number: F-E,S-D
· Stowage Category B
· Stowage Code SW2 Clear of living quarters.
· 14.7 Transport in bulk according to Annex II ofMarpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· Transport category 2
· Tunnel restriction code D/E
· UN "Model Regulation": UN 1230 METHANOL MIXTURE, 3 (6.1), II
SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso categoryH2 ACUTE TOXIC
P5c FLAMMABLE LIQUIDS
· Qualifying quantity (tonnes) for the application of lower-tier requirements 50 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3, 69
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
The information in this safety data sheet (SDS) has been prepared with due care and is true and accurate to
the best of our knowledge. The user must determine the suitability of the information for its particular
purpose, ensure compliance with existing laws and regulations, and be aware that other or additional safety
or performance considerations may arise when using, handling and/ or storing the material. The information
in this SDS does not purport to be all inclusive or a guarantee as to the properties of the material supplied,
and should be used only as a guide. LGC makes no warranties or representations as to the accuracy and(Contd. on page 10)
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completeness of the information contained herein, shall not be held responsible for the suitability of this
information for the user's intended purposes or the consequences of such use, and shall not be liable for any
damage or loss, howsoever arising, direct or otherwise.
· Abbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids – Category 2
Acute Tox. 3: Acute toxicity – Category 3
STOT SE 1: Specific target organ toxicity (single exposure) – Category 1
· SourcesTables 3.1 and 3.2 from Annex 6 of EC 1272/2008, EC 1907/2006, EH40/2005 as amended 2011, Registry of
Toxic Effects of Chemical Substances (RTECS), The Dictionary of Substances and their Effects, 1st Edition,
IUCLID.
· Data compared to the previous version altered. All sections have been updated. GB
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SECTION 1: Identification of the substance/mixture and of the company/undertaking
· 1.1 Product identifier
· Product name: 11 - Group C PCBs
· Part number: PT-CN-C11
· 1.2 Relevant identified uses of the substance or mixture and uses advised againstNo further relevant information available.
· Application of the substance / the mixture Reference material for laboratory use only
· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:
LGC Limited Tel :+44 (0) 20 8943 7000
Queens Road Fax :+44 (0) 20 8943 2767
Teddington eMail : [email protected]
Middlesex TW11 0LY Web : www.lgcstandards.com
UNITED KINGDOM
· Further information obtainable from:Product safety department
eMail : [email protected]
· 1.4 Emergency telephone number:For Hazardous Materials or Dangerous Goods Incident
Spill, Leak, Fire Exposure, or Accident
Call CHEMTREC:
USA & Canada 1-800-424-9300
Rest of the world +1 703-741-5970
SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 2 H225 Highly flammable liquid and vapour.
GHS08 health hazard
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
GHS09 environment
Aquatic Acute 1 H400 Very toxic to aquatic life.
Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.(Contd. on page 2)
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GHS07
Skin Irrit. 2 H315 Causes skin irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS02 GHS07 GHS08 GHS09
· Signal word Danger
· Hazard-determining components of labelling:2,2,4-Trimethylpentane
n-Hexane
· Hazard statementsH225 Highly flammable liquid and vapour.
H315 Causes skin irritation.
H336 May cause drowsiness or dizziness.
H304 May be fatal if swallowed and enters airways.
H410 Very toxic to aquatic life with long lasting effects.
· Precautionary statementsP210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water [or shower].
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
· 3.2 Chemical characterisation: Mixtures· Description: Also contains substances at levels not considered to be hazardous.
(Contd. on page 3)
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· Dangerous components:
CAS: 540-84-1
EINECS: 208-759-1
RTECS: SA 3320000
2,2,4-Trimethylpentane
Flam. Liq. 2, H225; Asp. Tox. 1, H304; Aquatic Acute 1, H400;Aquatic Chronic 1, H410; Skin Irrit. 2, H315; STOT SE 3, H336
>95%
· Additional information: For the wording of the listed hazard phrases refer to section 16.
SECTION 4: First aid measures
· 4.1 Description of first aid measures· General information: Immediately remove any clothing soiled by the product.
· After inhalation: In case of unconsciousness place patient in recovery position for transport.
· After skin contact:Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing:Rinse mouth. Do not induce vomiting.
Call for a doctor immediately.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment neededNo further relevant information available.
SECTION 5: Firefighting measures
· 5.1 Extinguishing media· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· 5.2 Special hazards arising from the substance or mixtureFormation of toxic gases is possible during heating or in case of fire.
· 5.3 Advice for firefighters· Protective equipment: Wear self-contained respiratory protective device.
SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency proceduresWear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions:Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.(Contd. on page 4)
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· 6.4 Reference to other sectionsSee Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
· 7.1 Precautions for safe handlingEnsure good ventilation/extraction at the workplace.
Store in cool, dry place in tightly closed receptacles.
Prevent formation of aerosols.
· Information about fire - and explosion protection:Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
· 7.2 Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:
Please refer to the manufacturer's certificate for specific storage and transport temperature conditions.
Store only in the original receptacle unless other advice is given on the CoA.
Keep container in a well-ventilated place. Keep away from sources of ignition and heat.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions:Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
· 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters· Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be
monitored at the workplace.
· Additional information: Lists used were valid at the time of SDS preparation.
· 8.2 Exposure controls· Personal protective equipment:· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the skin.
Avoid contact with the eyes and skin.(Contd. on page 5)
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· Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced
· Protection of hands:The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the
related standard EN374
Protective gloves
· Material of gloves Nitrile rubber, NBR
· Penetration time of glove materialThe exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
Tightly sealed goggles
SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties· General Information· Appearance:
Form: Liquid
Colour: Colourless
· Odour: Petrol-like
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in conditionMelting point/freezing point: -107 °C
Initial boiling point and boiling range: 99 °C
· Flash point: -12 °C
· Flammability (solid, gas): Not determined.
· Ignition temperature: 410 °C
(Contd. on page 6)
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· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product is not explosive. However, formation of explosive air/
vapour mixtures is possible.
· Explosion limits:Lower: 1.1 Vol %
Upper: 6 Vol %
· Vapour pressure at 20 °C: 15 hPa
· Density at 20 °C: 0.69 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility withwater: Not miscible or difficult to mix.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:Dynamic: Not determined.
Kinematic: Not determined.
· 9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity
· 10.1 ReactivityStable under normal conditions.
No further relevant information available.
· 10.2 Chemical stability Stable under normal conditions.
· Thermal decomposition / conditions to be avoided:Formation of toxic gases is possible during heating or in case of fire.
· 10.3 Possibility of hazardous reactions May form flammable/explosive vapour-air mixture.
· 10.4 Conditions to avoidSources of ignition
Heat.
· 10.5 Incompatible materials: Strong oxidizing agents.
· 10.6 Hazardous decomposition products:Formation of toxic gases is possible during heating or in case of fire.
SECTION 11: Toxicological information
· 11.1 Information on toxicological effects· Acute toxicity Based on available data, the classification criteria are not met.
(Contd. on page 7)
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· Primary irritant effect:· Skin corrosion/irritation
Causes skin irritation.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposureMay cause drowsiness or dizziness.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazardMay be fatal if swallowed and enters airways.
SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
CAS: 540-84-1 2,2,4-Trimethylpentane
EC50/48 h 0.38 mg/l (daphnia)
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Ecotoxicological effects:· Remark: Very toxic for fish
· Additional ecological information:· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms
· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
· 13.1 Waste treatment methods· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· European waste catalogueWaste disposal key numbers from EWC have to be assigned depending on origin and processing.
(Contd. on page 8)
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· Uncleaned packaging:· Recommendation: Dispose of in accordance with national regulations.
SECTION 14: Transport information
· 14.1 UN-Number· ADR, IMDG, IATA UN1262
· ADR 1262 OCTANES mix ture , ENVIRONMENTALLY
HAZARDOUS
· IMDG OCTANES mixture, MARINE POLLUTANT
· IATA OCTANES mixture
· 14.3 Transport hazard class(es)
· ADR, IMDG
· Class 3 Flammable liquids.
· Label 3
· IATA
· Class 3 Flammable liquids.
· Label 3
· 14.4 Packing group· ADR, IMDG, IATA II
· 14.5 Environmental hazards: Product contains environmentally hazardous substances:
2,2,4-Trimethylpentane
· Marine pollutant: Symbol (fish and tree)
· Special marking (ADR): Symbol (fish and tree)
· 14.6 Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 33
· EMS Number: F-E,S-E
· Stowage Category B
· 14.7 Transport in bulk according to Annex II ofMarpol and the IBC Code Not applicable.
(Contd. on page 9)
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· Transport/Additional information:
· ADR· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· Transport category 2
· Tunnel restriction code D/E
· UN "Model Regulation": U N 1 2 6 2 O C T A N E S M I X T U R E , 3 , I I ,
ENVIRONMENTALLY HAZARDOUS
SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso categoryE1 Hazardous to the Aquatic Environment
P5c FLAMMABLE LIQUIDS
· Qualifying quantity (tonnes) for the application of lower-tier requirements 100 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
The information in this safety data sheet (SDS) has been prepared with due care and is true and accurate to
the best of our knowledge. The user must determine the suitability of the information for its particular
purpose, ensure compliance with existing laws and regulations, and be aware that other or additional safety
or performance considerations may arise when using, handling and/ or storing the material. The information
in this SDS does not purport to be all inclusive or a guarantee as to the properties of the material supplied,
and should be used only as a guide. LGC makes no warranties or representations as to the accuracy and
completeness of the information contained herein, shall not be held responsible for the suitability of this
information for the user's intended purposes or the consequences of such use, and shall not be liable for any
damage or loss, howsoever arising, direct or otherwise.
· Abbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
PBT: Persistent, Bioaccumulative and Toxic
(Contd. on page 10)
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vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids – Category 2
Skin Irrit. 2: Skin corrosion/irritation – Category 2
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
Asp. Tox. 1: Aspiration hazard – Category 1
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
· SourcesTables 3.1 and 3.2 from Annex 6 of EC 1272/2008, EC 1907/2006, EH40/2005 as amended 2011, Registry of
Toxic Effects of Chemical Substances (RTECS), The Dictionary of Substances and their Effects, 1st Edition,
IUCLID.
· Data compared to the previous version altered. All sections have been updated. GB
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SECTION 1: Identification of the substance/mixture and of the company/undertaking
· 1.1 Product identifier
· Product name: 14a - Group C TPH
· Part number: PT-CN-C14A
· 1.2 Relevant identified uses of the substance or mixture and uses advised againstNo further relevant information available.
· Application of the substance / the mixture Reference material for laboratory use only
· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:
LGC Limited Tel :+44 (0) 20 8943 7000
Queens Road Fax :+44 (0) 20 8943 2767
Teddington eMail : [email protected]
Middlesex TW11 0LY Web : www.lgcstandards.com
UNITED KINGDOM
· Further information obtainable from:Product safety department
eMail : [email protected]
· 1.4 Emergency telephone number:For Hazardous Materials or Dangerous Goods Incident
Spill, Leak, Fire Exposure, or Accident
Call CHEMTREC:
USA & Canada 1-800-424-9300
Rest of the world +1 703-741-5970
SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 2 H225 Highly flammable liquid and vapour.
GHS08 health hazard
Carc. 2 H351 Suspected of causing cancer.
Repr. 2 H361f Suspected of damaging fertility.
STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
GHS09 environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.(Contd. on page 2)
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GHS07
Skin Irrit. 2 H315 Causes skin irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS02 GHS07 GHS08 GHS09
· Signal word Danger
· Hazard-determining components of labelling:n-Hexane
Gasoil : fuels, diesel
· Hazard statementsH225 Highly flammable liquid and vapour.
H315 Causes skin irritation.
H351 Suspected of causing cancer.
H361f Suspected of damaging fertility.
H336 May cause drowsiness or dizziness.
H373 May cause damage to organs through prolonged or repeated exposure.
H304 May be fatal if swallowed and enters airways.
H411 Toxic to aquatic life with long lasting effects.
· Precautionary statementsP210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water [or shower].
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable. GB
(Contd. on page 3)
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SECTION 3: Composition/information on ingredients
· 3.2 Chemical characterisation: Mixtures· Description: Mixture: consisting of the following components.
· Dangerous components:
CAS: 110-54-3
EINECS: 203-777-6
RTECS: MN 9275000
n-Hexane
Flam. Liq. 2, H225; Repr. 2, H361f; STOT RE 2, H373; Asp. Tox. 1,H304; Aquatic Chronic 2, H411; Skin Irrit. 2, H315; STOT SE 3, H336
>95%
CAS: 68334-30-5
EINECS: 269-822-7
RTECS: -
Gasoil : fuels, diesel
Carc. 2, H351
<2%
· Additional information: For the wording of the listed hazard phrases refer to section 16.
SECTION 4: First aid measures
· 4.1 Description of first aid measures· General information:
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may occur even after several hours; therefore medical observation for at least 48
hours after the accident is recommended.
· After inhalation: In case of unconsciousness place patient in recovery position for transport.
· After skin contact:Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing:Rinse mouth. Do not induce vomiting.
Call for a doctor immediately.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment neededNo further relevant information available.
SECTION 5: Firefighting measures
· 5.1 Extinguishing media· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· 5.2 Special hazards arising from the substance or mixtureDuring heating or in case of fire poisonous gases are produced.
· 5.3 Advice for firefighters· Protective equipment:
Mouth respiratory protective device.(Contd. on page 4)
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Wear self-contained respiratory protective device.
SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency proceduresMount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions:Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
· 6.4 Reference to other sectionsSee Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
· 7.1 Precautions for safe handlingEnsure good ventilation/extraction at the workplace.
Store in cool, dry place in tightly closed receptacles.
Open and handle receptacle with care.
Prevent formation of aerosols.
· Information about fire - and explosion protection:Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
· 7.2 Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:
Please refer to the manufacturer's certificate for specific storage and transport temperature conditions.
Store only in the original receptacle unless other advice is given on the CoA.
Keep container in a well-ventilated place. Keep away from sources of ignition and heat.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions:Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
· 7.3 Specific end use(s) No further relevant information available. GB
(Contd. on page 5)
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SECTION 8: Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
CAS: 110-54-3 n-Hexane
WEL Long-term value: 72 mg/m³, 20 ppm
· Additional information: Lists used were valid at the time of SDS preparation.
· 8.2 Exposure controls· Personal protective equipment:· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
· Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced
· Protection of hands:The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the
related standard EN374
Protective gloves
· Material of gloves Nitrile rubber, NBR
· Penetration time of glove materialThe exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.(Contd. on page 6)
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· Eye protection:
Tightly sealed goggles
SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties· General Information· Appearance:
Form: Liquid
Colour: Colourless
· Odour: Petrol-like
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in conditionMelting point/freezing point: -95 °C
Initial boiling point and boiling range: 69 °C
· Flash point: -26 °C
· Flammability (solid, gas): Not determined.
· Ignition temperature: 240 °C
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product is not explosive. However, formation of explosive air/
vapour mixtures is possible.
· Explosion limits:Lower: 1.2 Vol %
Upper: 7.4 Vol %
· Vapour pressure at 20 °C: 160 hPa
· Density at 20 °C: 0.66 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility withwater at 20 °C: 0.1 g/l
· Partition coefficient: n-octanol/water: Not determined.
(Contd. on page 7)
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· Viscosity:Dynamic: Not determined.
Kinematic: Not determined.
· 9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity
· 10.1 ReactivityStable under normal conditions.
No further relevant information available.
· 10.2 Chemical stability Stable under normal conditions.
· Thermal decomposition / conditions to be avoided:Formation of toxic gases is possible during heating or in case of fire.
· 10.3 Possibility of hazardous reactions May form flammable/explosive vapour-air mixture.
· 10.4 Conditions to avoidSources of ignition
Heat.
· 10.5 Incompatible materials: Strong oxidizing agents.
· 10.6 Hazardous decomposition products:Formation of toxic gases is possible during heating or in case of fire.
SECTION 11: Toxicological information
· 11.1 Information on toxicological effects· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
CAS: 110-54-3 n-Hexane
Oral LD50 5,000 mg/kg (rat)
Dermal LD50 3,000 mg/kg (rat)
· Primary irritant effect:· Skin corrosion/irritation
Causes skin irritation.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)Carc. 2, Repr. 2
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· CarcinogenicitySuspected of causing cancer.
· Reproductive toxicitySuspected of damaging fertility.
· STOT-single exposureMay cause drowsiness or dizziness.
(Contd. on page 8)
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· STOT-repeated exposureMay cause damage to organs through prolonged or repeated exposure.
· Aspiration hazardMay be fatal if swallowed and enters airways.
SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
CAS: 110-54-3 n-Hexane
EC50/48 h 2.1 mg/l (daphnia)
LC50/96 h 2.5 mg/l (fish)
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Ecotoxicological effects:· Remark: Toxic for fish
· Additional ecological information:· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
· 13.1 Waste treatment methods· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· European waste catalogueWaste disposal key numbers from EWC have to be assigned depending on origin and processing.
· Uncleaned packaging:· Recommendation: Dispose of in accordance with national regulations.
GB
(Contd. on page 9)
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SECTION 14: Transport information
· 14.1 UN-Number· ADR, IMDG, IATA UN1208
· ADR 1208 HEXANES mix ture , ENVIRONMENTALLY
HAZARDOUS
· IMDG HEXANES mixture, MARINE POLLUTANT
· IATA HEXANES mixture
· 14.3 Transport hazard class(es)
· ADR, IMDG
· Class 3 Flammable liquids.
· Label 3
· IATA
· Class 3 Flammable liquids.
· Label 3
· 14.4 Packing group· ADR, IMDG, IATA II
· 14.5 Environmental hazards: Product contains environmentally hazardous substances:
n-Hexane
· Marine pollutant: Symbol (fish and tree)
· Special marking (ADR): Symbol (fish and tree)
· 14.6 Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 33
· EMS Number: F-E,S-D
· Stowage Category E
· 14.7 Transport in bulk according to Annex II ofMarpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· Transport category 2
(Contd. on page 10)
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· Tunnel restriction code D/E
· UN "Model Regulation": U N 1 2 0 8 H E X A N E S M I X T U R E , 3 , I I ,
ENVIRONMENTALLY HAZARDOUS
SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso categoryE2 Hazardous to the Aquatic Environment
P5c FLAMMABLE LIQUIDS
· Qualifying quantity (tonnes) for the application of lower-tier requirements 200 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 500 t
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
The information in this safety data sheet (SDS) has been prepared with due care and is true and accurate to
the best of our knowledge. The user must determine the suitability of the information for its particular
purpose, ensure compliance with existing laws and regulations, and be aware that other or additional safety
or performance considerations may arise when using, handling and/ or storing the material. The information
in this SDS does not purport to be all inclusive or a guarantee as to the properties of the material supplied,
and should be used only as a guide. LGC makes no warranties or representations as to the accuracy and
completeness of the information contained herein, shall not be held responsible for the suitability of this
information for the user's intended purposes or the consequences of such use, and shall not be liable for any
damage or loss, howsoever arising, direct or otherwise.
· Abbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids – Category 2
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Carc. 2: Carcinogenicity – Category 2
Repr. 2: Reproductive toxicity – Category 2
STOT SE 3: Specific target organ toxicity (single exposure) – Category 3
STOT RE 2: Specific target organ toxicity (repeated exposure) – Category 2
Asp. Tox. 1: Aspiration hazard – Category 1
(Contd. on page 11)
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Aquatic Chronic 2: Hazardous to the aquatic environment - long-term aquatic hazard – Category 2
· SourcesTables 3.1 and 3.2 from Annex 6 of EC 1272/2008, EC 1907/2006, EH40/2005 as amended 2011, Registry of
Toxic Effects of Chemical Substances (RTECS), The Dictionary of Substances and their Effects, 1st Edition,
IUCLID.
· Data compared to the previous version altered. All sections have been updated. GB
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SECTION 1: Identification of the substance/mixture and of the company/undertaking
· 1.1 Product identifier
· Product name: 14b - Group C TPH
· Part number: PT-CN-C14B
· 1.2 Relevant identified uses of the substance or mixture and uses advised againstNo further relevant information available.
· Application of the substance / the mixture Reference material for laboratory use only
· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:
LGC Limited Tel :+44 (0) 20 8943 7000
Queens Road Fax :+44 (0) 20 8943 2767
Teddington eMail : [email protected]
Middlesex TW11 0LY Web : www.lgcstandards.com
UNITED KINGDOM
· Further information obtainable from:Product safety department
eMail : [email protected]
· 1.4 Emergency telephone number:For Hazardous Materials or Dangerous Goods Incident
Spill, Leak, Fire Exposure, or Accident
Call CHEMTREC:
USA & Canada 1-800-424-9300
Rest of the world +1 703-741-5970
SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 2 H225 Highly flammable liquid and vapour.
GHS06 skull and crossbones
Acute Tox. 3 H301 Toxic if swallowed.
Acute Tox. 3 H311 Toxic in contact with skin.
Acute Tox. 3 H331 Toxic if inhaled.
GHS08 health hazard
STOT SE 1 H370 Causes damage to organs.(Contd. on page 2)
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· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS02 GHS06 GHS08
· Signal word Danger
· Hazard-determining components of labelling:Methanol
· Hazard statementsH225 Highly flammable liquid and vapour.
H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled.
H370 Causes damage to organs.
· Precautionary statementsP210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water [or shower].
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
· 3.2 Chemical characterisation: Mixtures· Description: Also contains substances at levels not considered to be hazardous.
· Dangerous components:
CAS: 67-56-1
EINECS: 200-659-6
RTECS: PC1400000
Methanol
Flam. Liq. 2, H225; Acute Tox. 3, H301; Acute Tox. 3, H311; AcuteTox. 3, H331; STOT SE 1, H370
>95%
· Additional information: For the wording of the listed hazard phrases refer to section 16. GB
(Contd. on page 3)
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SECTION 4: First aid measures
· 4.1 Description of first aid measures· General information:
Immediately remove any clothing soiled by the product.
Remove breathing equipment only after contaminated clothing has been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
· After inhalation:Supply fresh air or oxygen; call for doctor.
In case of unconsciousness place patient in recovery position for transport.
Seek immediate medical advice.
· After skin contact:Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:Rinse mouth. Do not induce vomiting.
Call for a doctor immediately.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment neededNo further relevant information available.
SECTION 5: Firefighting measures
· 5.1 Extinguishing media· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· For safety reasons unsuitable extinguishing agents: Water with full jet
· 5.2 Special hazards arising from the substance or mixtureDuring heating or in case of fire poisonous gases are produced.
· 5.3 Advice for firefighters· Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency proceduresMount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.(Contd. on page 4)
GB
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· 6.4 Reference to other sectionsSee Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
· 7.1 Precautions for safe handlingEnsure good ventilation/extraction at the workplace.
Store in cool, dry place in tightly closed receptacles.
Open and handle receptacle with care.
Prevent formation of aerosols.
· Information about fire - and explosion protection:Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
· 7.2 Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:
Please refer to the manufacturer's certificate for specific storage and transport temperature conditions.
Store only in the original receptacle unless other advice is given on the CoA.
Keep container in a well-ventilated place. Keep away from sources of ignition and heat.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions:Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
· 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
CAS: 67-56-1 Methanol
WEL Short-term value: 333 mg/m³, 250 ppm
Long-term value: 266 mg/m³, 200 ppm
Sk
· Additional information: Lists used were valid at the time of SDS preparation.
· 8.2 Exposure controls· Personal protective equipment:· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.(Contd. on page 5)
GB
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Store protective clothing separately.
Avoid contact with the eyes and skin.
· Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced
· Protection of hands:The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the
related standard EN374
Protective gloves
· Material of gloves Butyl rubber, BR
· Penetration time of glove materialThe exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
Tightly sealed goggles
SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties· General Information· Appearance:
Form: Liquid
Colour: Colourless
· Odour: Alcohol-like
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in conditionMelting point/freezing point: -98 °C
Initial boiling point and boiling range: 65 °C
· Flash point: 12 °C
(Contd. on page 6)
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· Flammability (solid, gas): Not determined.
· Ignition temperature: Not determined
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product is not explosive. However, formation of explosive air/
vapour mixtures is possible.
· Explosion limits:Lower: 6 Vol %
Upper: 50 Vol %
· Vapour pressure: Not determined.
· Density at 20 °C: 0.8 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility withwater: Not miscible or difficult to mix.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:Dynamic: Not determined.
Kinematic: Not determined.
· 9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity
· 10.1 ReactivityStable under normal conditions.
No further relevant information available.
· 10.2 Chemical stability Stable under normal conditions.
· Thermal decomposition / conditions to be avoided:Formation of toxic gases is possible during heating or in case of fire.
· 10.3 Possibility of hazardous reactions May form flammable/explosive vapour-air mixture.
· 10.4 Conditions to avoidSources of ignition
Heat.
· 10.5 Incompatible materials:Strong oxidizing agents.
Strong acids.
Reducing agents.
Alkali metals.(Contd. on page 7)
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(Contd. from page 6)
49.2.0
· 10.6 Hazardous decomposition products:Formation of toxic gases is possible during heating or in case of fire.
SECTION 11: Toxicological information
· 11.1 Information on toxicological effects· Acute toxicity
Toxic if swallowed, in contact with skin or if inhaled.
· LD/LC50 values relevant for classification:
CAS: 67-56-1 Methanol
Oral (LD50) 5,630 mg/kg (rat)
Dermal (LD50) 15,800 mg/kg (rabbit)
Inhalative (LC50/4h) 83.9 mg/l (rat)
· Primary irritant effect:· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposureCauses damage to organs.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
CAS: 67-56-1 Methanol
LC50/96 h 24,000 mg/l (fish)
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.(Contd. on page 8)
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· 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
· 13.1 Waste treatment methods· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· European waste catalogueWaste disposal key numbers from EWC have to be assigned depending on origin and processing.
· Uncleaned packaging:· Recommendation: Dispose of in accordance with national regulations.
SECTION 14: Transport information
· 14.1 UN-Number· ADR, IMDG, IATA UN1230
· ADR 1230 METHANOL mixture
· IMDG, IATA METHANOL mixture
· 14.3 Transport hazard class(es)
· ADR
· Class 3 Flammable liquids.
· Label 3+6.1
· IMDG
· Class 3 Flammable liquids.
· Label 3/6.1
· IATA
· Class 3 Flammable liquids.
· Label 3 (6.1)
(Contd. on page 9)
GB
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· 14.4 Packing group· ADR, IMDG, IATA II
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 336
· EMS Number: F-E,S-D
· Stowage Category B
· Stowage Code SW2 Clear of living quarters.
· 14.7 Transport in bulk according to Annex II ofMarpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· Transport category 2
· Tunnel restriction code D/E
· UN "Model Regulation": UN 1230 METHANOL MIXTURE, 3 (6.1), II
SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso categoryH2 ACUTE TOXIC
P5c FLAMMABLE LIQUIDS
· Qualifying quantity (tonnes) for the application of lower-tier requirements 50 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3, 69
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
The information in this safety data sheet (SDS) has been prepared with due care and is true and accurate to
the best of our knowledge. The user must determine the suitability of the information for its particular
purpose, ensure compliance with existing laws and regulations, and be aware that other or additional safety
or performance considerations may arise when using, handling and/ or storing the material. The information
in this SDS does not purport to be all inclusive or a guarantee as to the properties of the material supplied,
and should be used only as a guide. LGC makes no warranties or representations as to the accuracy and
completeness of the information contained herein, shall not be held responsible for the suitability of this(Contd. on page 10)
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49.2.0
information for the user's intended purposes or the consequences of such use, and shall not be liable for any
damage or loss, howsoever arising, direct or otherwise.
· Abbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids – Category 2
Acute Tox. 3: Acute toxicity – Category 3
STOT SE 1: Specific target organ toxicity (single exposure) – Category 1
· SourcesTables 3.1 and 3.2 from Annex 6 of EC 1272/2008, EC 1907/2006, EH40/2005 as amended 2011, Registry of
Toxic Effects of Chemical Substances (RTECS), The Dictionary of Substances and their Effects, 1st Edition,
IUCLID.
· Data compared to the previous version altered. All sections have been updated. GB
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SECTION 1: Identification of the substance/mixture and of the company/undertaking
· 1.1 Product identifier
· Product name: 15 - Group C BTEX
· Part number: PT-CN-C15
· 1.2 Relevant identified uses of the substance or mixture and uses advised againstNo further relevant information available.
· Application of the substance / the mixture Reference material for laboratory use only
· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:
LGC Limited Tel :+44 (0) 20 8943 7000
Queens Road Fax :+44 (0) 20 8943 2767
Teddington eMail : [email protected]
Middlesex TW11 0LY Web : www.lgcstandards.com
UNITED KINGDOM
· Further information obtainable from:Product safety department
eMail : [email protected]
· 1.4 Emergency telephone number:For Hazardous Materials or Dangerous Goods Incident
Spill, Leak, Fire Exposure, or Accident
Call CHEMTREC:
USA & Canada 1-800-424-9300
Rest of the world +1 703-741-5970
SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 2 H225 Highly flammable liquid and vapour.
GHS06 skull and crossbones
Acute Tox. 3 H301 Toxic if swallowed.
Acute Tox. 3 H311 Toxic in contact with skin.
Acute Tox. 3 H331 Toxic if inhaled.
GHS08 health hazard
STOT SE 1 H370 Causes damage to organs.(Contd. on page 2)
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· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS02 GHS06 GHS08
· Signal word Danger
· Hazard-determining components of labelling:Methanol
· Hazard statementsH225 Highly flammable liquid and vapour.
H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled.
H370 Causes damage to organs.
· Precautionary statementsP210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water [or shower].
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
· 3.2 Chemical characterisation: Mixtures· Description: Also contains substances at levels not considered to be hazardous.
· Dangerous components:
CAS: 67-56-1
EINECS: 200-659-6
RTECS: PC1400000
Methanol
Flam. Liq. 2, H225; Acute Tox. 3, H301; Acute Tox. 3, H311; AcuteTox. 3, H331; STOT SE 1, H370
>95%
· Additional information: For the wording of the listed hazard phrases refer to section 16. GB
(Contd. on page 3)
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SECTION 4: First aid measures
· 4.1 Description of first aid measures· General information:
Immediately remove any clothing soiled by the product.
Remove breathing equipment only after contaminated clothing has been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
· After inhalation:Supply fresh air or oxygen; call for doctor.
In case of unconsciousness place patient in recovery position for transport.
Seek immediate medical advice.
· After skin contact:Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:Rinse mouth. Do not induce vomiting.
Call for a doctor immediately.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment neededNo further relevant information available.
SECTION 5: Firefighting measures
· 5.1 Extinguishing media· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· 5.2 Special hazards arising from the substance or mixtureDuring heating or in case of fire poisonous gases are produced.
· 5.3 Advice for firefighters· Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency proceduresMount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions:Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.(Contd. on page 4)
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· 6.4 Reference to other sectionsSee Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
· 7.1 Precautions for safe handlingEnsure good ventilation/extraction at the workplace.
Store in cool, dry place in tightly closed receptacles.
Open and handle receptacle with care.
Prevent formation of aerosols.
· Information about fire - and explosion protection:Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
· 7.2 Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:
Please refer to the manufacturer's certificate for specific storage and transport temperature conditions.
Store only in the original receptacle unless other advice is given on the CoA.
Keep container in a well-ventilated place. Keep away from sources of ignition and heat.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions:Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
· 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
CAS: 67-56-1 Methanol
WEL Short-term value: 333 mg/m³, 250 ppm
Long-term value: 266 mg/m³, 200 ppm
Sk
· Additional information: Lists used were valid at the time of SDS preparation.
· 8.2 Exposure controls· Personal protective equipment:· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.(Contd. on page 5)
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Store protective clothing separately.
Avoid contact with the eyes and skin.
· Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced
· Protection of hands:The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the
related standard EN374
Protective gloves
· Material of gloves Butyl rubber, BR
· Penetration time of glove materialThe exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
Tightly sealed goggles
SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties· General Information· Appearance:
Form: Liquid
Colour: Colourless
· Odour: Alcohol-like
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in conditionMelting point/freezing point: -98 °C
Initial boiling point and boiling range: 65 °C
· Flash point: 12 °C
(Contd. on page 6)
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· Flammability (solid, gas): Not determined.
· Ignition temperature: Not determined
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product is not explosive. However, formation of explosive air/
vapour mixtures is possible.
· Explosion limits:Lower: 6 Vol %
Upper: 50 Vol %
· Vapour pressure: Not determined.
· Density at 20 °C: 0.79948 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility withwater: Fully miscible.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:Dynamic: Not determined.
Kinematic: Not determined.
· 9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity
· 10.1 ReactivityStable under normal conditions.
No further relevant information available.
· 10.2 Chemical stability Stable under normal conditions.
· Thermal decomposition / conditions to be avoided:Formation of toxic gases is possible during heating or in case of fire.
· 10.3 Possibility of hazardous reactions May form flammable/explosive vapour-air mixture.
· 10.4 Conditions to avoidSources of ignition
Heat.
· 10.5 Incompatible materials:Strong oxidizing agents.
Strong acids.
Reducing agents.
Alkali metals.(Contd. on page 7)
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· 10.6 Hazardous decomposition products:Formation of toxic gases is possible during heating or in case of fire.
SECTION 11: Toxicological information
· 11.1 Information on toxicological effects· Acute toxicity
Toxic if swallowed, in contact with skin or if inhaled.
· LD/LC50 values relevant for classification:
CAS: 67-56-1 Methanol
Oral (LD50) 5,630 mg/kg (rat)
Dermal (LD50) 15,800 mg/kg (rabbit)
Inhalative (LC50/4h) 83.9 mg/l (rat)
· Primary irritant effect:· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposureCauses damage to organs.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
CAS: 67-56-1 Methanol
LC50/96 h 24,000 mg/l (fish)
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.(Contd. on page 8)
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· 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
· 13.1 Waste treatment methods· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· European waste catalogueWaste disposal key numbers from EWC have to be assigned depending on origin and processing.
· Uncleaned packaging:· Recommendation: Dispose of in accordance with national regulations.
· Recommended cleansing agents: Water, if necessary together with cleansing agents.
SECTION 14: Transport information
· 14.1 UN-Number· ADR, IMDG, IATA UN1230
· ADR 1230 METHANOL mixture
· IMDG, IATA METHANOL mixture
· 14.3 Transport hazard class(es)
· ADR
· Class 3 Flammable liquids.
· Label 3+6.1
· IMDG
· Class 3 Flammable liquids.
· Label 3/6.1
· IATA
· Class 3 Flammable liquids.
(Contd. on page 9)
GB
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· Label 3 (6.1)
· 14.4 Packing group· ADR, IMDG, IATA II
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 336
· EMS Number: F-E,S-D
· Stowage Category B
· Stowage Code SW2 Clear of living quarters.
· 14.7 Transport in bulk according to Annex II ofMarpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· Transport category 2
· Tunnel restriction code D/E
· UN "Model Regulation": UN 1230 METHANOL MIXTURE, 3 (6.1), II
SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso categoryH2 ACUTE TOXIC
P5c FLAMMABLE LIQUIDS
· Qualifying quantity (tonnes) for the application of lower-tier requirements 50 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3, 69
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
The information in this safety data sheet (SDS) has been prepared with due care and is true and accurate to
the best of our knowledge. The user must determine the suitability of the information for its particular
purpose, ensure compliance with existing laws and regulations, and be aware that other or additional safety
or performance considerations may arise when using, handling and/ or storing the material. The information
in this SDS does not purport to be all inclusive or a guarantee as to the properties of the material supplied,
and should be used only as a guide. LGC makes no warranties or representations as to the accuracy and(Contd. on page 10)
GB
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completeness of the information contained herein, shall not be held responsible for the suitability of this
information for the user's intended purposes or the consequences of such use, and shall not be liable for any
damage or loss, howsoever arising, direct or otherwise.
· Abbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids – Category 2
Acute Tox. 3: Acute toxicity – Category 3
STOT SE 1: Specific target organ toxicity (single exposure) – Category 1
· SourcesTables 3.1 and 3.2 from Annex 6 of EC 1272/2008, EC 1907/2006, EH40/2005 as amended 2011, Registry of
Toxic Effects of Chemical Substances (RTECS), The Dictionary of Substances and their Effects, 1st Edition,
IUCLID.
· Data compared to the previous version altered. All sections have been updated. GB
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SECTION 1: Identification of the substance/mixture and of the company/undertaking
· 1.1 Product identifier
· Product name: 19 - Group C Chlorinated Hydrocarbons
· Part number: PT-CN-C19
· 1.2 Relevant identified uses of the substance or mixture and uses advised againstNo further relevant information available.
· Application of the substance / the mixture Reference material for laboratory use only
· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:
LGC Limited Tel :+44 (0) 20 8943 7000
Queens Road Fax :+44 (0) 20 8943 2767
Teddington eMail : [email protected]
Middlesex TW11 0LY Web : www.lgcstandards.com
UNITED KINGDOM
· Further information obtainable from:Product safety department
eMail : [email protected]
· 1.4 Emergency telephone number:For Hazardous Materials or Dangerous Goods Incident
Spill, Leak, Fire Exposure, or Accident
Call CHEMTREC:
USA & Canada 1-800-424-9300
Rest of the world +1 703-741-5970
SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Liq. 2 H225 Highly flammable liquid and vapour.
GHS06 skull and crossbones
Acute Tox. 3 H301 Toxic if swallowed.
Acute Tox. 3 H311 Toxic in contact with skin.
Acute Tox. 3 H331 Toxic if inhaled.
GHS08 health hazard
STOT SE 1 H370 Causes damage to organs.(Contd. on page 2)
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· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS02 GHS06 GHS08
· Signal word Danger
· Hazard-determining components of labelling:Methanol
· Hazard statementsH225 Highly flammable liquid and vapour.
H301+H311+H331 Toxic if swallowed, in contact with skin or if inhaled.
H370 Causes damage to organs.
· Precautionary statementsP210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/ doctor.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with
water [or shower].
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
· 3.2 Chemical characterisation: Mixtures· Description: Also contains substances at levels not considered to be hazardous.
· Dangerous components:
CAS: 67-56-1
EINECS: 200-659-6
RTECS: PC1400000
Methanol
Flam. Liq. 2, H225; Acute Tox. 3, H301; Acute Tox. 3, H311; AcuteTox. 3, H331; STOT SE 1, H370
>95%
· Additional information: For the wording of the listed hazard phrases refer to section 16. GB
(Contd. on page 3)
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SECTION 4: First aid measures
· 4.1 Description of first aid measures· General information:
Immediately remove any clothing soiled by the product.
Remove breathing equipment only after contaminated clothing has been completely removed.
In case of irregular breathing or respiratory arrest provide artificial respiration.
· After inhalation:Supply fresh air or oxygen; call for doctor.
In case of unconsciousness place patient in recovery position for transport.
Seek immediate medical advice.
· After skin contact:Immediately wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
· After swallowing:Rinse mouth. Do not induce vomiting.
Call for a doctor immediately.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment neededNo further relevant information available.
SECTION 5: Firefighting measures
· 5.1 Extinguishing media· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
· 5.2 Special hazards arising from the substance or mixtureDuring heating or in case of fire poisonous gases are produced.
· 5.3 Advice for firefighters· Protective equipment:
Mouth respiratory protective device.
Wear self-contained respiratory protective device.
SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency proceduresMount respiratory protective device.
Wear protective equipment. Keep unprotected persons away.
· 6.2 Environmental precautions:Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.(Contd. on page 4)
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· 6.4 Reference to other sectionsSee Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
· 7.1 Precautions for safe handlingEnsure good ventilation/extraction at the workplace.
Store in cool, dry place in tightly closed receptacles.
Open and handle receptacle with care.
Prevent formation of aerosols.
· Information about fire - and explosion protection:Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Keep respiratory protective device available.
· 7.2 Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:
Please refer to the manufacturer's certificate for specific storage and transport temperature conditions.
Store only in the original receptacle unless other advice is given on the CoA.
Keep container in a well-ventilated place. Keep away from sources of ignition and heat.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions:Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
· 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
CAS: 67-56-1 Methanol
WEL Short-term value: 333 mg/m³, 250 ppm
Long-term value: 266 mg/m³, 200 ppm
Sk
· Additional information: Lists used were valid at the time of SDS preparation.
· 8.2 Exposure controls· Personal protective equipment:· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.(Contd. on page 5)
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Store protective clothing separately.
Avoid contact with the eyes and skin.
· Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced
· Protection of hands:The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the
related standard EN374
Protective gloves
· Material of gloves Butyl rubber, BR
· Penetration time of glove materialThe exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection:
Tightly sealed goggles
SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties· General Information· Appearance:
Form: Liquid
Colour: Colourless
· Odour: Alcohol-like
· Odour threshold: Not determined.
· pH-value: Not determined.
· Change in conditionMelting point/freezing point: -98 °C
Initial boiling point and boiling range: 65 °C
· Flash point: 12 °C
(Contd. on page 6)
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· Flammability (solid, gas): Not determined.
· Ignition temperature: Not determined
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Product is not explosive. However, formation of explosive air/
vapour mixtures is possible.
· Explosion limits:Lower: 6 Vol %
Upper: 50 Vol %
· Vapour pressure: Not determined.
· Density at 20 °C: 0.8 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility withwater: Fully miscible.
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:Dynamic: Not determined.
Kinematic: Not determined.
· 9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity
· 10.1 ReactivityStable under normal conditions.
No further relevant information available.
· 10.2 Chemical stability Stable under normal conditions.
· Thermal decomposition / conditions to be avoided:Formation of toxic gases is possible during heating or in case of fire.
· 10.3 Possibility of hazardous reactions May form flammable/explosive vapour-air mixture.
· 10.4 Conditions to avoidSources of ignition
Heat.
· 10.5 Incompatible materials:Strong oxidizing agents.
Strong acids.
Reducing agents.
Alkali metals.(Contd. on page 7)
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· 10.6 Hazardous decomposition products:Formation of toxic gases is possible during heating or in case of fire.
SECTION 11: Toxicological information
· 11.1 Information on toxicological effects· Acute toxicity
Toxic if swallowed, in contact with skin or if inhaled.
· LD/LC50 values relevant for classification:
CAS: 67-56-1 Methanol
Oral (LD50) 5,630 mg/kg (rat)
Dermal (LD50) 15,800 mg/kg (rabbit)
Inhalative (LC50/4h) 83.9 mg/l (rat)
· Primary irritant effect:· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· Carcinogenicity Based on available data, the classification criteria are not met.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposureCauses damage to organs.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
CAS: 67-56-1 Methanol
LC50/96 h 24,000 mg/l (fish)
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.(Contd. on page 8)
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· 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
· 13.1 Waste treatment methods· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· European waste catalogueWaste disposal key numbers from EWC have to be assigned depending on origin and processing.
· Uncleaned packaging:· Recommendation: Dispose of in accordance with national regulations.
· Recommended cleansing agents: Water, if necessary together with cleansing agents.
SECTION 14: Transport information
· 14.1 UN-Number· ADR, IMDG, IATA UN1230
· ADR 1230 METHANOL mixture
· IMDG, IATA METHANOL mixture
· 14.3 Transport hazard class(es)
· ADR
· Class 3 Flammable liquids.
· Label 3+6.1
· IMDG
· Class 3 Flammable liquids.
· Label 3/6.1
· IATA
· Class 3 Flammable liquids.
(Contd. on page 9)
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· Label 3 (6.1)
· 14.4 Packing group· ADR, IMDG, IATA II
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Warning: Flammable liquids.
· Danger code (Kemler): 336
· EMS Number: F-E,S-D
· Stowage Category B
· Stowage Code SW2 Clear of living quarters.
· 14.7 Transport in bulk according to Annex II ofMarpol and the IBC Code Not applicable.
· Transport/Additional information:
· ADR· Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· Transport category 2
· Tunnel restriction code D/E
· UN "Model Regulation": UN 1230 METHANOL MIXTURE, 3 (6.1), II
SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.
· Seveso categoryH2 ACUTE TOXIC
P5c FLAMMABLE LIQUIDS
· Qualifying quantity (tonnes) for the application of lower-tier requirements 50 t
· Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3, 69
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
The information in this safety data sheet (SDS) has been prepared with due care and is true and accurate to
the best of our knowledge. The user must determine the suitability of the information for its particular
purpose, ensure compliance with existing laws and regulations, and be aware that other or additional safety
or performance considerations may arise when using, handling and/ or storing the material. The information
in this SDS does not purport to be all inclusive or a guarantee as to the properties of the material supplied,
and should be used only as a guide. LGC makes no warranties or representations as to the accuracy and(Contd. on page 10)
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completeness of the information contained herein, shall not be held responsible for the suitability of this
information for the user's intended purposes or the consequences of such use, and shall not be liable for any
damage or loss, howsoever arising, direct or otherwise.
· Abbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Liq. 2: Flammable liquids – Category 2
Acute Tox. 3: Acute toxicity – Category 3
STOT SE 1: Specific target organ toxicity (single exposure) – Category 1
· SourcesTables 3.1 and 3.2 from Annex 6 of EC 1272/2008, EC 1907/2006, EH40/2005 as amended 2011, Registry of
Toxic Effects of Chemical Substances (RTECS), The Dictionary of Substances and their Effects, 1st Edition,
IUCLID.
· Data compared to the previous version altered. All sections have been updated. GB
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SECTION 1: Identification of the substance/mixture and of the company/undertaking
· 1.1 Product identifier
· Product name: 20 - Group C SVOCs
· Part number: PT-CN-C20
· 1.2 Relevant identified uses of the substance or mixture and uses advised againstNo further relevant information available.
· Application of the substance / the mixture Reference material for laboratory use only
· 1.3 Details of the supplier of the safety data sheet· Manufacturer/Supplier:
LGC Limited Tel :+44 (0) 20 8943 7000
Queens Road Fax :+44 (0) 20 8943 2767
Teddington eMail : [email protected]
Middlesex TW11 0LY Web : www.lgcstandards.com
UNITED KINGDOM
· Further information obtainable from:Product safety department
eMail : [email protected]
· 1.4 Emergency telephone number:For Hazardous Materials or Dangerous Goods Incident
Spill, Leak, Fire Exposure, or Accident
Call CHEMTREC:
USA & Canada 1-800-424-9300
Rest of the world +1 703-741-5970
SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture· Classification according to Regulation (EC) No 1272/2008
GHS08 health hazard
Carc. 2 H351 Suspected of causing cancer.
· 2.2 Label elements· Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS08
· Signal word Warning
· Hazard-determining components of labelling:Methylene chloride
(Contd. on page 2)
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· Hazard statementsH351 Suspected of causing cancer.
· Precautionary statementsP201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
· 2.3 Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.
SECTION 3: Composition/information on ingredients
· 3.2 Chemical characterisation: Mixtures· Description: Mixture: consisting of the following components.
· Dangerous components:
CAS: 75-09-2
EINECS: 200-838-9
RTECS: PA8050000
Methylene chloride Carc. 2, H351 >95%
· Additional information: For the wording of the listed hazard phrases refer to section 16.
SECTION 4: First aid measures
· 4.1 Description of first aid measures· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Immediately wash with water and soap and rinse thoroughly.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: Rinse mouth. Do not induce vomiting.
· 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment neededNo further relevant information available.
SECTION 5: Firefighting measures
· 5.1 Extinguishing media· Suitable extinguishing agents: Use fire extinguishing methods suitable for surrounding conditions.
· 5.2 Special hazards arising from the substance or mixtureFormation of toxic gases is possible during heating or in case of fire.
(Contd. on page 3)
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· 5.3 Advice for firefighters· Protective equipment: Wear self-contained respiratory protective device.
SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency procedures Wear protective clothing.
· 6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
· 6.3 Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item 13.
· 6.4 Reference to other sectionsSee Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
· 7.1 Precautions for safe handlingStore in cool, dry place in tightly closed receptacles.
Open and handle receptacle with care.
· Information about fire - and explosion protection: Keep respiratory protective device available.
· 7.2 Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:
Please refer to the manufacturer's certificate for specific storage and transport temperature conditions.
Store only in the original receptacle unless other advice is given on the CoA.
Keep container in a well-ventilated place. Keep away from sources of ignition and heat.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions: Keep container tightly sealed.
· 7.3 Specific end use(s) No further relevant information available.
SECTION 8: Exposure controls/personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· 8.1 Control parameters
· Ingredients with limit values that require monitoring at the workplace:
CAS: 75-09-2 Methylene chloride
WEL Short-term value: 706 mg/m³, 200 ppm
Long-term value: 353 mg/m³, 100 ppm
BMGV, Sk
(Contd. on page 4)
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· Ingredients with biological limit values:
CAS: 75-09-2 Methylene chloride
BMGV 30 ppm
Medium: end-tidal breath
Sampling time: post shift
Parameter: carbon monoxide
· Additional information: Lists used were valid at the time of SDS preparation.
· 8.2 Exposure controls· Personal protective equipment:· General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Store protective clothing separately.
· Respiratory protection:Not required.
Use suitable respiratory protective device in case of insufficient ventilation.
· Protection of hands:The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the
related standard EN374
Protective gloves
· Material of gloves Fluorocarbon rubber (Viton)
· Penetration time of glove materialThe exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
· Eye protection: Safety glasses
SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties· General Information· Appearance:
Form: Liquid
Colour: Colourless
· Odour: Aromatic
· Odour threshold: Not determined.
· pH-value: Not determined.
(Contd. on page 5)
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· Change in conditionMelting point/freezing point: -95.1 °C
Initial boiling point and boiling range: 40 °C
· Flash point: Not applicable.
· Flammability (solid, gas): Not determined.
· Ignition temperature: 605 °C
· Decomposition temperature: Not determined.
· Auto-ignition temperature: Product is not selfigniting.
· Explosive properties: Not determined.
· Explosion limits:Lower: 13 Vol %
Upper: 22 Vol %
· Vapour pressure at 20 °C: 453 hPa
· Density at 20 °C: 1.32987 g/cm³
· Relative density Not determined.
· Vapour density Not determined.
· Evaporation rate Not determined.
· Solubility in / Miscibility withwater at 20 °C: 20 g/l
· Partition coefficient: n-octanol/water: Not determined.
· Viscosity:Dynamic: Not determined.
Kinematic: Not determined.
· 9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity
· 10.1 ReactivityStable under normal conditions.
No further relevant information available.
· 10.2 Chemical stability Stable under normal conditions.
· Thermal decomposition / conditions to be avoided:Formation of toxic gases is possible during heating or in case of fire.
· 10.3 Possibility of hazardous reactions No dangerous reactions known.
· 10.4 Conditions to avoid Heat.
· 10.5 Incompatible materials: Strong oxidizing agents.(Contd. on page 6)
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· 10.6 Hazardous decomposition products:Formation of toxic gases is possible during heating or in case of fire.
SECTION 11: Toxicological information
· 11.1 Information on toxicological effects· Acute toxicity Based on available data, the classification criteria are not met.
· LD/LC50 values relevant for classification:
CAS: 75-09-2 Methylene chloride
Oral (LD50) 1,600 mg/kg (rat)
LD 50 (Intraperitoneal) 916 mg/kg (rat)
· Primary irritant effect:· Skin corrosion/irritation Based on available data, the classification criteria are not met.
· Serious eye damage/irritation Based on available data, the classification criteria are not met.
· Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)Carc. 2
· Germ cell mutagenicity Based on available data, the classification criteria are not met.
· CarcinogenicitySuspected of causing cancer.
· Reproductive toxicity Based on available data, the classification criteria are not met.
· STOT-single exposure Based on available data, the classification criteria are not met.
· STOT-repeated exposure Based on available data, the classification criteria are not met.
· Aspiration hazard Based on available data, the classification criteria are not met.
SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
CAS: 75-09-2 Methylene chloride
EC50/48 h 1,470 mg/l (crustacean)
LC50/96 h 310 mg/l (fish)
· 12.2 Persistence and degradability No further relevant information available.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
· 12.5 Results of PBT and vPvB assessment· PBT: Not applicable.
· vPvB: Not applicable.(Contd. on page 7)
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· 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
· 13.1 Waste treatment methods· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
· European waste catalogueWaste disposal key numbers from EWC have to be assigned depending on origin and processing.
· Uncleaned packaging:· Recommendation: Dispose of in accordance with national regulations.
SECTION 14: Transport information
· 14.1 UN-Number· ADR, IMDG, IATA UN1593
· ADR 1593 DICHLOROMETHANE
· IMDG, IATA DICHLOROMETHANE
· 14.3 Transport hazard class(es)
· ADR, IMDG, IATA
· Class 6.1 Toxic substances.
· Label 6.1
· 14.4 Packing group· ADR, IMDG, IATA III
· 14.5 Environmental hazards: Not applicable.
· 14.6 Special precautions for user Warning: Toxic substances.
· Danger code (Kemler): 60
· EMS Number: F-A,S-A
· Segregation groups Liquid halogenated hydrocarbons
· Stowage Category A
· 14.7 Transport in bulk according to Annex II ofMarpol and the IBC Code Not applicable.
(Contd. on page 8)
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· Transport/Additional information:
· ADR· Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml
· Transport category 2
· Tunnel restriction code E
· UN "Model Regulation": UN 1593 DICHLOROMETHANE, 6.1, III
SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.
· REGULATION (EC) No 1907/2006 ANNEX XVII Conditions of restriction: 3, 59
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
The information in this safety data sheet (SDS) has been prepared with due care and is true and accurate to
the best of our knowledge. The user must determine the suitability of the information for its particular
purpose, ensure compliance with existing laws and regulations, and be aware that other or additional safety
or performance considerations may arise when using, handling and/ or storing the material. The information
in this SDS does not purport to be all inclusive or a guarantee as to the properties of the material supplied,
and should be used only as a guide. LGC makes no warranties or representations as to the accuracy and
completeness of the information contained herein, shall not be held responsible for the suitability of this
information for the user's intended purposes or the consequences of such use, and shall not be liable for any
damage or loss, howsoever arising, direct or otherwise.
· Abbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Carc. 2: Carcinogenicity – Category 2
(Contd. on page 9)
GB
Page 9/9
Safety data sheetaccording to 1907/2006/EC, Article 31
Printing date 27.11.2020 Revision: 03.08.2020Version number 2
Product name: 20 - Group C SVOCs
(Contd. from page 8)
49.2.0
· SourcesTables 3.1 and 3.2 from Annex 6 of EC 1272/2008, EC 1907/2006, EH40/2005 as amended 2011, Registry of
Toxic Effects of Chemical Substances (RTECS), The Dictionary of Substances and their Effects, 1st Edition,
IUCLID.
· Data compared to the previous version altered. All sections have been updated. GB