Download - LONGHORN ARMY AMMUNITION PLANT KARNACK ...longhorn-engage.s3.amazonaws.com/static/2011 Volume 4 of...LONGHORN ARMY AMMUNITION PLANT KARNACK, TEXAS ADMINISTRATIVE RECORD – CHRONOLOGICAL

LONGHORN ARMY AMMUNITION PLANT

KARNACK, TEXAS

ADMINISTRATIVE RECORD

Volume 4 of 16

2011

Bate Stamp Numbers 00101493 – 00102505

Prepared for

Department of the Army Longhorn Army Ammunition Plant

1976 – 2011

LONGHORN ARMY AMMUNITION PLANT KARNACK, TEXAS

ADMINISTRATIVE RECORD – CHRONOLOGICAL INDEX

VOLUME 4 of 16 2011 A. Title: Report (continued) – Final Feasibility Study LHAAP-47, Plant 3 Area, Group 4, Longhorn Army Ammunition Plant, Karnack, Texas Author(s): Shaw Environmental, Inc., Houston, Texas Recipient: All Stakeholders Date: July 27, 2011 Bate Stamp: 00101493 - 00102505

156 Starlite Drive, Marietta, OH 45750 • TEL 740-373-4071 • FAX 740-373-4835 • http://www.kemron.com

Laboratory Report Number: L0710596

Please find enclosed the analytical results for the samples you submitted to KEMRON Environmental Services.

Review and compilation of your report was completed by KEMRON’s Sales and Service Team. If you have questions,comments or require further assistance regarding this report, please contact your team member noted in the reviewedbox bleow at 800-373-4071. Team member e-mail addresses also appear here for your convenience.

Debra Elliott - Team Leader Amanda Fickiesen - Client Services [email protected] [email protected]

Kathy Albertson - Team Chemist/Data Specialist Annie Brown - Client Services [email protected] [email protected]

Stephanie Mossburg - Team Chemist/Data Specialist Katie Barnes - Team [email protected] [email protected]

Brenda Gregory - Client Services Specialist Jacqueline Parsons - Team [email protected] [email protected]

This report was reviewed on November 02, 2007.

STEPHANIE MOSSBURG - Team Chemist/Data Specialist

I certify that all test results meet all of the requirements of the NELAP standards and other applicable contract termsand conditions. All results for soil samples are reported on a ’dry-weight’ basis unless specified otherwise. Analyticalresults for water and wastes are reported on a ’as received’ basis unless specified otherwise. A statement of uncertaintyfor each analysis is available upon request. This laboratory report shall not be reproduced, except in full, without thewritten approval of KEMRON Environmental Services.

This report was certified on November 02, 2007.

David Vandenberg - Vice President

FL DOH NELAP ID: E8755This report contains a total of 321 pages.

Protecting Our Environmental Future

Page 1

00101493

KEMRON REPORT L0710596PREPARED FOR Shaw E I, Inc.WORK ID: LONGHORN AAP KARNACK TX

1.0 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 32.1 Volatiles Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39

2.1.1 Volatiles GCMS Data (8260) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 402.1.1.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 412.1.1.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 67

2.2 Metals Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1442.2.1 Metals I C P Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .145

2.2.1.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1462.2.1.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 151

2.2.2 Metals ICP-MS Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .1942.2.2.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1952.2.2.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200

2.2.3 Metals CVAA Data (Mercury) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2352.2.3.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2362.2.3.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 240

2.3 General Chemistry Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2622.3.1 Perchlorate Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 263

2.3.1.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2642.3.1.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 271

2.3.2 Total Dissolved Solids Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2812.3.2.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2822.3.2.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2862.3.2.3 Raw Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 293

2.3.3 Total Suspended Solids Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2962.3.3.1 Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2972.3.3.2 QC Summary Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3012.3.3.3 Raw Data . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 308

3.0 Attachments . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 311

Page 2

00101494

1.0 Introduction

Page 3

00101495

ID: 63618

KEMRON ENVIRONMENTAL SERVICESREPORT NARRATIVE

KEMRON Login No.: L0710596

CHAIN OF CUSTODY: The chain of custody number was 10305.

SHIPMENT CONDITIONS: The chain of custody forms were received sealed in a cooler. The cooler temperaturewas 4 degrees C.

SAMPLE MANAGEMENT: All samples received were intact.

I certify that this data package is in compliance with the terms and conditions agreed to by the client and KEMRONEnvironmental Services, both technically and for completeness, except for the conditions noted above. Release of thedata contained in this hardcopy data package has been authorized by the Laboratory Manager or designated person,as verified by the following signature.

Approved: 25-OCT-07

Page 4

00101496

Laboratory Data Package Cover Page

This data Package consists of:This signature page, the laboratory review checklists, and the following reportable data:R1 Field chain-of-custody documentation;R2 sample identification cross-reference;R3 Test reports (analytical data sheets) for each enviornmental sample that includes:

a) Items consistant with NELAC 5.13 or ISO/IEC 17025 Section 5.10b) dilution factors,c) preparation methods,d) Cleanup methods, ande) If required for the project, tentatively identified compounds (TICs)

R4 Surrogate recovery data including:a) Calculated recovery (%R) for each analyte, andb) The laboratory’s surrogate QC limits.

R5 Test reports/summary forms for blank samples;R6 Test reports/summary forms FOR laboratory control samples (LCSs) including:

a) LCS spiking amount,b) Calculated %R for each analyte, andc) The laboratory”s LCS QC limits.

R7 Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:a) Samples associated with the MS/MSD clearly identified,b) MS/MSD spiking amounts,c) Concentration of each MS/MSD analyte measured in the parent and spiked samples,d) Calculated %R and relative percent differences (RPDs), ande) The laboratory’s MS/MSD QC limits

R8 Laboratory analytical duplicate (if applicable) revocery and precision:a) the amount of analyte measured in the duplicate,b) the calculated RPD, andc) the laboratory’s QC limits for anlytical duplicates.

R9 List of method quantitation limits (MQLs) for each analyte for each method and matrix;R10 Other problems or anomalies.The exception Report for every ”No” or ”Not Reviewed (NR)” item in laboratory review checklist.

Release statement: I am responsible for the release of this laboratory data package. This data package has been reviewed by thelaboratory and is complete and technically compliant with the requirements of the methods used, except where noted by the laboratoryin the attached exceptions reports. By my signature below, I affirm to the best of my knowledge, all problems/anomalies, observed bythe laboratory as having the potential to affect the quality of the data, have been identified by the laboratoy in the Laboratory ReviewChecklist, and no information or data have been knowingly withheld that would affect the quality of the data.

Check, If applicable: [] This laboratory is an in-house laboratory controlled by the person repsonding to rule. The official signing thecover page of the rule-required report (for example, the APAR) in which these data are used is responsible for releasing this datapackage and is by signature affirming the above release statement is trus.

SHERI L. PFALZGRAF Chemist II November 2, 2007

Name (Printed) Signature Official Title (printed) DATE

RG-366/TRRP-13 December 2002 A1

Page 5

00101497

Checklist ID: 22886

KEMRON Environmental ServicesLaboratory Review Checklist

Laboratory Name: KEMRONLaboratory Log Number: L0710596Project Name: 798-LONGHORNMethod: 6020Prep Batch Number(s): WG253712Reviewer Name: SHERI L. PFALZGRAFLRC Date: November 02, 2007

Description Yes No NA(1) NR(2) ER(3)

Chain-Of-Custody (C-O-C)Did samples meet the laboratory’s standard conditions of sample acceptability uponreceipt?

X

Were all departures from standard conditions described in an exception report? XSample and quality control (QC) identificationAre all field sample ID numbers cross-referenced to the laboratory ID numbers? XAre all laboratory ID numbers cross-referenced to the corresponding QC data? XTest reportsWere all samples prepared and analyzed within holding times? XOther than those results


Were MS/MSD RPDs within laboratory QC limits? XAnalytical duplicate dataWere appropriate analytical duplicates analyzed for each matrix? XWere analytical duplicates analyzed at the appropriate frequency? XWere RPDs or relative standard deviations within the laboratory QC limits? XMethod quantitation limits (MQLs):Are the MQLs for each method analyte included in the laboratory data package? XDo the MQLs correspond to the concentration of the lowest non-zero calibration standard? XAre unadjusted MQLs included in the laboratory data package? X 1Other problems/anomaliesAre all known problems/anomalies/special conditions noted in this LRC and ER? XWere all necessary corrective actions performed for the reported data? XWas applicable and available technology used to lower the SQL minimize the matrixinterference affects on the sample results?

X

ICALWere response factors and/or relative response factors for each analyte within QC limits? XWere percent RSDs or correlation coefficient criteria met? XWas the number of standards recommended in the method used for all analytes? XWere all points generated between the lowest and highest standard used to calculate thecurve?

X

Are ICAL data available for all instruments used? XHas the initial calibration curve been verified using an appropriate second source standard? XInitial and continuing calibration verification (ICV and CCV) and continuingcalibration blank (CCB):Was the CCV analyzed at the method-required frequency? XWere percent differences for each analyte within the method-required QC limits? XWas the ICAL curve verified for each analyte? XWas the absolute value of the analyte concentration in the inorganic CCB


Standards documentationAre all standards used in the analyses NIST-traceable or obtained from other appropriatesources?

X

Compound/analyte identification proceduresAre the procedures for compound/analyte identification documented? XDemonstration of analyst competency (DOC)Was DOC conducted consistent with NELAC Chapter 5C or ISO/IEC 4? XIs documentation of the analyst’s competency up-to-date and on file? XVerification/validation documentation for methods (NELAC Chap 5 or ISO/IEC17025 Section 5)Are all the methods used to generate the data documented, verified, and validated, whereapplicable?

X

Laboratory standard operating procedures (SOPs):Are laboratory SOPs current and on file for each method performed? X

Page 8

00101500

Checklist ID: 22886


Laboratory Name: KEMRONLaboratory Log Number: L0710596Project Name: 798-LONGHORNMethod: 6020Prep Batch Number(s): WG253712Reviewer Name: SHERI L. PFALZGRAFLRC Date: November 02, 2007

EXCEPTIONS REPORTER1 - Due to a result that exceeded the linear range on initial analysis, client sample 12 was reported from a dilution analysisfor sodium. Due to a result that was noncompliant on the negative side on initial analysis, sample 12 was reported from adilution analysis for vanadium. Due to a result that exceeded the linear range of the instrument in the reference sample to theMS/MSD, the reference, MS, and MSD were reported from dilution analyses for sodium. Due to results that were noncomplianton the negative side in the reference sample to the MS/MSD, the reference, MS, and MSD were reported from dilution analysesfor aluminum and vanadium.Footnotes:(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number

Page 9

00101501












MAREN M. BEERY Metals Supervisor November 1, 2007



Page 10

00101502

Checklist ID: 22866


Laboratory Name: KEMRONLaboratory Log Number: L0710596Project Name: 798-LONGHORNMethod: 6010Prep Batch Number(s): WG253902Reviewer Name: MAREN M. BEERYLRC Date: November 01, 2007



X



Were MS/MSD RPDs within laboratory QC limits? XAnalytical duplicate dataWere appropriate analytical duplicates analyzed for each matrix? XWere analytical duplicates analyzed at the appropriate frequency? XWere RPDs or relative standard deviations within the laboratory QC limits? XMethod quantitation limits (MQLs):Are the MQLs for each method analyte included in the laboratory data package? XDo the MQLs correspond to the concentration of the lowest non-zero calibration standard? XAre unadjusted MQLs included in the laboratory data package? XOther problems/anomaliesAre all known problems/anomalies/special conditions noted in this LRC and ER? XWere all necessary corrective actions performed for the reported data? XWas applicable and available technology used to lower the SQL minimize the matrixinterference affects on the sample results?

X ER2


X




X


X


Page 13

00101505

Checklist ID: 22866


Laboratory Name: KEMRONLaboratory Log Number: L0710596Project Name: 798-LONGHORNMethod: 6010Prep Batch Number(s): WG253902Reviewer Name: MAREN M. BEERYLRC Date: November 01, 2007

EXCEPTIONS REPORTER#1 - Due to a result that exceeded the linear range on initial analysis, client sample 12 was reported from a dilution analysisfor sodium.ER2 - Due to a result that was noncompliant on the negative side on initial analysis, sample 12 was reported from a dilutionanalysis for vanadium.Footnotes:(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number

Page 14

00101506












MAREN M. BEERY Metals Supervisor October 25, 2007



Page 15

00101507

Checklist ID: 22650


Laboratory Name: KEMRONLaboratory Log Number: L0710596Project Name: 798-LONGHORNMethod: 7471Prep Batch Number(s): WG253689Reviewer Name: MAREN M. BEERYLRC Date: October 25, 2007



X




X


X




X


X


Page 18

00101510

Checklist ID: 22650


Laboratory Name: KEMRONLaboratory Log Number: L0710596Project Name: 798-LONGHORNMethod: 7471Prep Batch Number(s): WG253689Reviewer Name: MAREN M. BEERYLRC Date: October 25, 2007

EXCEPTIONS REPORTER# - DescriptionFootnotes:(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number

Page 19

00101511





XR5 Test reports/summary forms for blank samples;XR6 Test reports/summary forms for laboratory control samples (LCSs) including:







DEANNA I. HESSON Conventional Lab Supervisor October 29, 2007



Page 20

00101512

Checklist ID: 22738


Laboratory Name: KEMRONLaboratory Log Number: L0710596Project Name: 798-LONGHORNMethod: TDSPrep Batch Number(s): WG253612Reviewer Name: DEANNA I. HESSONLRC Date: October 29, 2007



X




X

Were response factors and/or relative response factors for each analyte within QC limits? XWere percent RSDs or correlation coefficient criteria met? XWas the number of standards recommended in the method used for all analytes? XWere all points generated between the lowest and highest standard used to calculate thecurve?

X




X


X


Page 23

00101515

Checklist ID: 22738


Laboratory Name: KEMRONLaboratory Log Number: L0710596Project Name: 798-LONGHORNMethod: TDSPrep Batch Number(s): WG253612Reviewer Name: DEANNA I. HESSONLRC Date: October 29, 2007


Page 24

00101516












DEANNA I. HESSON Conventional Lab Supervisor October 29, 2007



Page 25

00101517

Checklist ID: 22739


Laboratory Name: KEMRONLaboratory Log Number: L0710596Project Name: 798-LONGHORNMethod: TSSPrep Batch Number(s): WG253700Reviewer Name: DEANNA I. HESSONLRC Date: October 29, 2007



X




X


X




X


X


Page 28

00101520

Checklist ID: 22739


Laboratory Name: KEMRONLaboratory Log Number: L0710596Project Name: 798-LONGHORNMethod: TSSPrep Batch Number(s): WG253700Reviewer Name: DEANNA I. HESSONLRC Date: October 29, 2007


Page 29

00101521








XR8 Laboratory analytical duplicate (if applicable) revocery and precision:a) the amount of analyte measured in the duplicate,b) the calculated RPD, andc) the laboratory’s QC limits for anlytical duplicates.

R9 List of method quantitation limits (MQLs) for each analyte for each method and matrix;R10 Other problems or anomalies.XThe exception Report for every ”No” or ”Not Reviewed (NR)” item IN laboratory review checklist.



MICHAEL D. COCHRAN Semivolatiles Lab Supervisor October 30, 2007



Page 30

00101522

Checklist ID: 22757


Laboratory Name: KEMRONLaboratory Log Number: L0710596Project Name: 798-LONGHORNMethod: 314Prep Batch Number(s): WG254202Reviewer Name: MICHAEL D. COCHRANLRC Date: October 30, 2007



X




X 2


X




X


X


Page 33

00101525

Checklist ID: 22757


Laboratory Name: KEMRONLaboratory Log Number: L0710596Project Name: 798-LONGHORNMethod: 314Prep Batch Number(s): WG254202Reviewer Name: MICHAEL D. COCHRANLRC Date: October 30, 2007

EXCEPTIONS REPORTER# - Description1. The MS/MSD results were not associated with this sample delivery group.2. Samples -01, -03 and -04 were analyzed at a dilution only due to high conductivity readings.

(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number

Page 34

00101526


This data Package consists of:This signature page, the laboratory review checklists, and the following reportable data:XR1 Field chain-of-custody documentation;XR2 sample identification cross-reference;R3 Test reports (analytical data sheets) for each enviornmental sample that includes:


XR4 Surrogate recovery data including:a) Calculated recovery (%R) for each analyte, andb) The laboratory’s surrogate QC limits.



XR7 Test reports for project matrix spike/matrix spike duplicates (MS/MSDs) including:a) Samples associated with the MS/MSD clearly identified,b) MS/MSD spiking amounts,c) Concentration of each MS/MSD analyte measured in the parent and spiked samples,d) Calculated %R and relative percent differences (RPDs), ande) The laboratory’s MS/MSD QC limits

XR8 Laboratory analytical duplicate (if applicable) revocery and precision:a) the amount of analyte measured in the duplicate,b) the calculated RPD, andc) the laboratory’s QC limits for anlytical duplicates.

XR9 List of method quantitation limits (MQLs) for each analyte for each method and matrix;XR10 Other problems or anomalies.XThe exception Report for every ”No” or ”Not Reviewed (NR)” item IN laboratory review checklist.


Check, if applicable: [X] This laboratory is an in-house laboratory controlled by the person repsonding to rule. The official signingthe cover page of the rule-required report (for example, the APAR) in which these data are used is responsible for releasing this datapackage and is by signature affirming the above release statement is true.

MIKE D. ALBERTSON Volatiles Lab Supervisor October 30, 2007



Page 35

00101527

Checklist ID: 22781


Laboratory Name: KEMRONLaboratory Log Number: L0710596Project Name: 798-LONGHORNMethod: 8260BPrep Batch Number(s): 253794, 254006, 253678Reviewer Name: MIKE D. ALBERTSONLRC Date: October 30, 2007



X




X


X

Are ICAL data available for all instruments used? XHas the initial calibration curve been verified using an appropriate second source standard? XInitial and continuing calibration verification (ICV and CCV) and continuingcalibration blank (CCB):Was the CCV analyzed at the method-required frequency? XWere percent differences for each analyte within the method-required QC limits? XWas the ICAL curve verified for each analyte? X 4Was the absolute value of the analyte concentration in the inorganic CCB



X


X


EXCEPTIONS REPORTER# - Description#1: Toluene-d8 was below the lower control limit in the analyses of samples 01 and 09.#2: Surrogate toluene-d8 was below the lower control limit in the method blank analyzed 10/24/07 on HPMS-11.#3: MTBE exceeded the upper advisory limit in the LCS/LCSD analyzed 10/25/07 on HPMS-10.Methyl acetate and MTBE exceeded the upper advisory limits in the LCS/LCSD analyzed 10/24/07 on HPMS-11.#4: Methyl acetate exceeded the upper control limit in the alternate source analyzed 10/01/07 on HPMS-11.

Footnotes:(1) NA = Not applicable to method or project(2) NR = Not reviewed(3) ER# = Exception report number

Page 38

00101530

2.1 Volatiles Data

Page 39

00101531

2.1.1 Volatiles GCMS Data(8260)

Page 40

00101532

2.1.1.1 Summary Data

Page 41

00101533

LABORATORY REPORT

11/02/07 10:41

L0710596

1 OFKEMRON FORMS - Modified 11/30/2005

11/02/2007 10:41Version 1.5Report generated

924245PDF File ID:1

L0710596-01

L0710596-01

L0710596-02

L0710596-02

L0710596-05

L0710596-07

L0710596-08

L0710596-09

L0710596-09

L0710596-10

L0710596-11

L0710596-15

LHSMW56-102007

LHSMW56-102007

47WW05-102007

47WW05-102007

47WW23-101907

47WW21-101807

47WW21-101807-QC

47WW01-101807

47WW01-101807

47WW04-101807

47WWZZ-101807

TRIP BLANK

Client ID Lab ID Dilution

1

100

1

10

1

1

1

1

20

1

1

1

Sample Analysis Summary

Date Received

23-OCT-07

23-OCT-07

23-OCT-07

23-OCT-07

23-OCT-07

23-OCT-07

23-OCT-07

23-OCT-07

23-OCT-07

23-OCT-07

23-OCT-07

23-OCT-07

Attention: Larry Duty

Account Name: Shaw E & I, Inc.ABB Lummus Biulding3010 Briarpark Drive Suite 4NHouston, TX 77042

Account Number:Work ID:

2773LHAAD

P.O. Number: 322255 OP

Submitted By

For

KEMRON Environmental Services

156 Starlite Drive

Marietta OH 45750,

740 373 4071)( -

Method

8260B

8260B

8260B

8260B

8260B

8260B

8260B

8260B

8260B

8260B

8260B

8260B

Page 42

00101534

KEMRON ENVIRONMENTAL SERVICESL0710596

November 2, 2007

Report Number:

Report Date :

1 of 24

L0710596-01Sample Number: HPMS11Instrument:

11M46864File ID:10/24/2007Run Date:Analyst:10/01/2007 15:48Cal Date:

16:23Workgroup Number:Matrix: Analytical Method:Water

LHSMW56-102007Client ID:

Sample Tag:01Dilution:

Units:

WG2536788260BMES1ug/L

Collect Date:10/20/2007 08:10

Prep Method:5030B 10/24/2007 16:23Prep Date:

1,1,1-Trichloroethane

1,1,2,2-Tetrachloroethane

1,1,2-Trichloro-1,2,2-Trifluoroethane


1,1-Dichloroethane

1,1-Dichloroethene

1,2,4-Trichlorobenzene

1,2-Dibromo-3-chloropropane

1,2-Dibromoethane

1,2-Dichlorobenzene

1,2-Dichloroethane

cis-1,2-Dichloroethene

trans-1,2-Dichloroethene

1,2-Dichloropropane

1,3-Dichlorobenzene

1,4-Dichlorobenzene

2-Butanone

2-Hexanone

4-Methyl-2-pentanone

Acetone

Benzene

Bromodichloromethane

Bromoform

Bromomethane

Carbon disulfide

Carbon tetrachloride

Chlorobenzene

Chloroethane

Chloroform

Chloromethane

cis-1,3-Dichloropropene

Cyclohexane

Dibromochloromethane

Dichlorodifluoromethane

Ethyl benzene

Isopropylbenzene

Methyl acetate

Methyl tert-butyl ether

Methylcyclohexane

Methylene chloride

Styrene

Tetrachloroethene

Toluene

trans-1,3-Dichloropropene

Trichloroethene

Trichlorofluoromethane

Vinyl chloride

Xylenes, Total

U

U

U

J

U

U

U

U

U

I

U

U

U

U

U

U

U

J

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

J

U

U

I

U

U

0.250

0.125

0.250

0.250

0.125

0.500

0.200

1.00

0.250

0.125

0.250

0.250

0.250

0.200

0.250

0.125

2.50

2.50

2.50

2.50

0.125

0.250

0.500

0.500

0.500

0.250

0.125

0.500

0.125

0.250

0.250

0.250

0.250

0.250

0.250

0.250

0.250

0.500

0.250

0.250

0.125

0.250

0.250

0.500

0.250

0.250

0.250

0.500

1.00

1.00

5.00

1.00

1.00

1.00

1.00

5.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

10.0

10.0

10.0

10.0

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

5.00

1.00

1.00

1.00

1.00

10.0

5.00

10.0

2.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

0.835

46.2

184

219

2.47

0.543

0.746

3560

33.6

71-55-6

79-34-5

76-13-1

79-00-5

75-34-3

75-35-4

120-82-1

96-12-8

106-93-4

95-50-1

107-06-2

156-59-2

156-60-5

78-87-5

541-73-1

106-46-7

78-93-3

591-78-6

108-10-1

67-64-1

71-43-2

75-27-4

75-25-2

74-83-9

75-15-0

56-23-5

108-90-7

75-00-3

67-66-3

74-87-3

10061-01-5

110-82-7

124-48-1

75-71-8

100-41-4

98-82-8

79-20-9

1634-04-4

108-87-2

75-09-2

100-42-5

127-18-4

108-88-3

10061-02-6

79-01-6

75-69-4

75-01-4

1330-20-7

Analyte QualResultCAS. Number PQL SDL

NONEPrePrep Method:

Page 43

00101535


November 2, 2007

Report Number:

Report Date :

2 of 24






Units:


Collect Date:10/20/2007 08:10


U Not detected at or above adjusted sample detection limitJ The analyte was positively identified, but the quantitation was below the RL* Surrogate or spike compound out of rangeI Semiquantitative result (out of instrument calibration range)

80

86

86

88

120

118

115

110

91.6

92.5

89.2

86.2 *

1,2-Dichloroethane-d4

Dibromofluoromethane

p-Bromofluorobenzene

Toluene-d8

Surrogate Lower Upper% Recovery Qual

NONEPrePrep Method:

Page 44

00101536


November 2, 2007

Report Number:

Report Date :

3 of 24





Sample Tag:DL01Dilution:

Units:

WG2540068260BMES100ug/L

Collect Date:10/20/2007 08:10






1,1-Dichloroethane

1,1-Dichloroethene



1,2-Dibromoethane

1,2-Dichlorobenzene

1,2-Dichloroethane



1,2-Dichloropropane

1,3-Dichlorobenzene

1,4-Dichlorobenzene

2-Butanone

2-Hexanone


Acetone

Benzene


Bromoform

Bromomethane

Carbon disulfide


Chlorobenzene

Chloroethane

Chloroform

Chloromethane


Cyclohexane



Ethyl benzene

Isopropylbenzene

Methyl acetate


Methylcyclohexane

Methylene chloride

Styrene

Tetrachloroethene

Toluene


Trichloroethene


Vinyl chloride

Xylenes, Total

U

U

U

U

J

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

J

U

25.0

12.5

25.0

25.0

12.5

50.0

20.0

100

25.0

12.5

25.0

25.0

25.0

20.0

25.0

12.5

250

250

250

250

12.5

25.0

50.0

50.0

50.0

25.0

12.5

50.0

12.5

25.0

25.0

25.0

25.0

25.0

25.0

25.0

25.0

50.0

25.0

25.0

12.5

25.0

25.0

50.0

25.0

25.0

25.0

50.0

100

100

500

100

100

100

100

500

100

100

100

100

100

100

100

100

1000

1000

1000

1000

100

100

100

100

100

100

100

100

100

100

100

500

100

100

100

100

1000

500

1000

200

100

100

100

100

100

100

100

100

44.2

188

171

8740

35.6

71-55-6

79-34-5

76-13-1

79-00-5

75-34-3

75-35-4

120-82-1

96-12-8

106-93-4

95-50-1

107-06-2

156-59-2

156-60-5

78-87-5

541-73-1

106-46-7

78-93-3

591-78-6

108-10-1

67-64-1

71-43-2

75-27-4

75-25-2

74-83-9

75-15-0

56-23-5

108-90-7

75-00-3

67-66-3

74-87-3

10061-01-5

110-82-7

124-48-1

75-71-8

100-41-4

98-82-8

79-20-9

1634-04-4

108-87-2

75-09-2

100-42-5

127-18-4

108-88-3

10061-02-6

79-01-6

75-69-4

75-01-4

1330-20-7


NONEPrePrep Method:

Page 45

00101537


November 2, 2007

Report Number:

Report Date :

4 of 24






Units:

WG2540068260BMES100ug/L

Collect Date:10/20/2007 08:10


U Not detected at or above adjusted sample detection limitJ The analyte was positively identified, but the quantitation was below the RL

80

86

86

88

120

118

115

110

96.8

99.5

102

98.2




Toluene-d8


NONEPrePrep Method:

Page 46

00101538


November 2, 2007

Report Number:

Report Date :

5 of 24




47WW05-102007Client ID:


Units:


Collect Date:10/20/2007 08:50






1,1-Dichloroethane

1,1-Dichloroethene



1,2-Dibromoethane

1,2-Dichlorobenzene

1,2-Dichloroethane



1,2-Dichloropropane

1,3-Dichlorobenzene

1,4-Dichlorobenzene

2-Butanone

2-Hexanone


Acetone

Benzene


Bromoform

Bromomethane

Carbon disulfide


Chlorobenzene

Chloroethane

Chloroform

Chloromethane


Cyclohexane



Ethyl benzene

Isopropylbenzene

Methyl acetate


Methylcyclohexane

Methylene chloride

Styrene

Tetrachloroethene

Toluene


Trichloroethene


Vinyl chloride

Xylenes, Total

U

U

J

U

U

J

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

J

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

I

U

U

U

0.250

0.125

0.250

0.250

0.125

0.500

0.200

1.00

0.250

0.125

0.250

0.250

0.250

0.200

0.250

0.125

2.50

2.50

2.50

2.50

0.125

0.250

0.500

0.500

0.500

0.250

0.125

0.500

0.125

0.250

0.250

0.250

0.250

0.250

0.250

0.250

0.250

0.500

0.250

0.250

0.125

0.250

0.250

0.500

0.250

0.250

0.250

0.500

1.00

1.00

5.00

1.00

1.00

1.00

1.00

5.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

10.0

10.0

10.0

10.0

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

5.00

1.00

1.00

1.00

1.00

10.0

5.00

10.0

2.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

3.16

0.702

6.44

0.277

677

71-55-6

79-34-5

76-13-1

79-00-5

75-34-3

75-35-4

120-82-1

96-12-8

106-93-4

95-50-1

107-06-2

156-59-2

156-60-5

78-87-5

541-73-1

106-46-7

78-93-3

591-78-6

108-10-1

67-64-1

71-43-2

75-27-4

75-25-2

74-83-9

75-15-0

56-23-5

108-90-7

75-00-3

67-66-3

74-87-3

10061-01-5

110-82-7

124-48-1

75-71-8

100-41-4

98-82-8

79-20-9

1634-04-4

108-87-2

75-09-2

100-42-5

127-18-4

108-88-3

10061-02-6

79-01-6

75-69-4

75-01-4

1330-20-7


NONEPrePrep Method:

Page 47

00101539


November 2, 2007

Report Number:

Report Date :

6 of 24






Units:


Collect Date:10/20/2007 08:50


U Not detected at or above adjusted sample detection limitJ The analyte was positively identified, but the quantitation was below the RLI Semiquantitative result (out of instrument calibration range)

80

86

86

88

120

118

115

110

94.8

93.3

90.0

88.6




Toluene-d8


NONEPrePrep Method:

Page 48

00101540


November 2, 2007

Report Number:

Report Date :

7 of 24






Units:


Collect Date:10/20/2007 08:50






1,1-Dichloroethane

1,1-Dichloroethene



1,2-Dibromoethane

1,2-Dichlorobenzene

1,2-Dichloroethane



1,2-Dichloropropane

1,3-Dichlorobenzene

1,4-Dichlorobenzene

2-Butanone

2-Hexanone


Acetone

Benzene


Bromoform

Bromomethane

Carbon disulfide


Chlorobenzene

Chloroethane

Chloroform

Chloromethane


Cyclohexane



Ethyl benzene

Isopropylbenzene

Methyl acetate


Methylcyclohexane

Methylene chloride

Styrene

Tetrachloroethene

Toluene


Trichloroethene


Vinyl chloride

Xylenes, Total

U

U

J

U

U

U

U

U

U

U

U

J

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

2.50

1.25

2.50

2.50

1.25

5.00

2.00

10.0

2.50

1.25

2.50

2.50

2.50

2.00

2.50

1.25

25.0

25.0

25.0

25.0

1.25

2.50

5.00

5.00

5.00

2.50

1.25

5.00

1.25

2.50

2.50

2.50

2.50

2.50

2.50

2.50

2.50

5.00

2.50

2.50

1.25

2.50

2.50

5.00

2.50

2.50

2.50

5.00

10.0

10.0

50.0

10.0

10.0

10.0

10.0

50.0

10.0

10.0

10.0

10.0

10.0

10.0

10.0

10.0

100

100

100

100

10.0

10.0

10.0

10.0

10.0

10.0

10.0

10.0

10.0

10.0

10.0

50.0

10.0

10.0

10.0

10.0

100

50.0

100

20.0

10.0

10.0

10.0

10.0

10.0

10.0

10.0

10.0

2.53

6.02

759

71-55-6

79-34-5

76-13-1

79-00-5

75-34-3

75-35-4

120-82-1

96-12-8

106-93-4

95-50-1

107-06-2

156-59-2

156-60-5

78-87-5

541-73-1

106-46-7

78-93-3

591-78-6

108-10-1

67-64-1

71-43-2

75-27-4

75-25-2

74-83-9

75-15-0

56-23-5

108-90-7

75-00-3

67-66-3

74-87-3

10061-01-5

110-82-7

124-48-1

75-71-8

100-41-4

98-82-8

79-20-9

1634-04-4

108-87-2

75-09-2

100-42-5

127-18-4

108-88-3

10061-02-6

79-01-6

75-69-4

75-01-4

1330-20-7


NONEPrePrep Method:

Page 49

00101541


November 2, 2007

Report Number:

Report Date :

8 of 24






Units:


Collect Date:10/20/2007 08:50



80

86

86

88

120

118

115

110

99.1

101

98.9

96.5




Toluene-d8


NONEPrePrep Method:

Page 50

00101542


November 2, 2007

Report Number:

Report Date :

9 of 24






Units:


Collect Date:10/19/2007 09:45






1,1-Dichloroethane

1,1-Dichloroethene



1,2-Dibromoethane

1,2-Dichlorobenzene

1,2-Dichloroethane



1,2-Dichloropropane

1,3-Dichlorobenzene

1,4-Dichlorobenzene

2-Butanone

2-Hexanone


Acetone

Benzene


Bromoform

Bromomethane

Carbon disulfide


Chlorobenzene

Chloroethane

Chloroform

Chloromethane


Cyclohexane



Ethyl benzene

Isopropylbenzene

Methyl acetate


Methylcyclohexane

Methylene chloride

Styrene

Tetrachloroethene

Toluene


Trichloroethene


Vinyl chloride

Xylenes, Total

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

0.250

0.125

0.250

0.250

0.125

0.500

0.200

1.00

0.250

0.125

0.250

0.250

0.250

0.200

0.250

0.125

2.50

2.50

2.50

2.50

0.125

0.250

0.500

0.500

0.500

0.250

0.125

0.500

0.125

0.250

0.250

0.250

0.250

0.250

0.250

0.250

0.250

0.500

0.250

0.250

0.125

0.250

0.250

0.500

0.250

0.250

0.250

0.500

1.00

1.00

5.00

1.00

1.00

1.00

1.00

5.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

10.0

10.0

10.0

10.0

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

5.00

1.00

1.00

1.00

1.00

10.0

5.00

10.0

2.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

71-55-6

79-34-5

76-13-1

79-00-5

75-34-3

75-35-4

120-82-1

96-12-8

106-93-4

95-50-1

107-06-2

156-59-2

156-60-5

78-87-5

541-73-1

106-46-7

78-93-3

591-78-6

108-10-1

67-64-1

71-43-2

75-27-4

75-25-2

74-83-9

75-15-0

56-23-5

108-90-7

75-00-3

67-66-3

74-87-3

10061-01-5

110-82-7

124-48-1

75-71-8

100-41-4

98-82-8

79-20-9

1634-04-4

108-87-2

75-09-2

100-42-5

127-18-4

108-88-3

10061-02-6

79-01-6

75-69-4

75-01-4

1330-20-7


NONEPrePrep Method:

Page 51

00101543


November 2, 2007

Report Number:

Report Date :

10 of 24






Units:


Collect Date:10/19/2007 09:45


U Not detected at or above adjusted sample detection limit

80

86

86

88

120

118

115

110

102

103

99.2

97.6




Toluene-d8


NONEPrePrep Method:

Page 52

00101544


November 2, 2007

Report Number:

Report Date :

11 of 24






Units:


Collect Date:10/18/2007 14:20






1,1-Dichloroethane

1,1-Dichloroethene



1,2-Dibromoethane

1,2-Dichlorobenzene

1,2-Dichloroethane



1,2-Dichloropropane

1,3-Dichlorobenzene

1,4-Dichlorobenzene

2-Butanone

2-Hexanone


Acetone

Benzene


Bromoform

Bromomethane

Carbon disulfide


Chlorobenzene

Chloroethane

Chloroform

Chloromethane


Cyclohexane



Ethyl benzene

Isopropylbenzene

Methyl acetate


Methylcyclohexane

Methylene chloride

Styrene

Tetrachloroethene

Toluene


Trichloroethene


Vinyl chloride

Xylenes, Total

U

U

U

U

J

J

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

0.250

0.125

0.250

0.250

0.125

0.500

0.200

1.00

0.250

0.125

0.250

0.250

0.250

0.200

0.250

0.125

2.50

2.50

2.50

2.50

0.125

0.250

0.500

0.500

0.500

0.250

0.125

0.500

0.125

0.250

0.250

0.250

0.250

0.250

0.250

0.250

0.250

0.500

0.250

0.250

0.125

0.250

0.250

0.500

0.250

0.250

0.250

0.500

1.00

1.00

5.00

1.00

1.00

1.00

1.00

5.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

10.0

10.0

10.0

10.0

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

5.00

1.00

1.00

1.00

1.00

10.0

5.00

10.0

2.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

0.161

0.566

1.99

2.61

71-55-6

79-34-5

76-13-1

79-00-5

75-34-3

75-35-4

120-82-1

96-12-8

106-93-4

95-50-1

107-06-2

156-59-2

156-60-5

78-87-5

541-73-1

106-46-7

78-93-3

591-78-6

108-10-1

67-64-1

71-43-2

75-27-4

75-25-2

74-83-9

75-15-0

56-23-5

108-90-7

75-00-3

67-66-3

74-87-3

10061-01-5

110-82-7

124-48-1

75-71-8

100-41-4

98-82-8

79-20-9

1634-04-4

108-87-2

75-09-2

100-42-5

127-18-4

108-88-3

10061-02-6

79-01-6

75-69-4

75-01-4

1330-20-7


NONEPrePrep Method:

Page 53

00101545


November 2, 2007

Report Number:

Report Date :

12 of 24






Units:


Collect Date:10/18/2007 14:20



80

86

86

88

120

118

115

110

100

102

96.6

93.9




Toluene-d8


NONEPrePrep Method:

Page 54

00101546


November 2, 2007

Report Number:

Report Date :

13 of 24




47WW21-101807-QCClient ID:


Units:


Collect Date:10/18/2007 14:20






1,1-Dichloroethane

1,1-Dichloroethene


1,2-Dibromo-3-chloropro

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