![Page 1: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/1.jpg)
Materials in Nanotechnology
Introduction to Nanoparticle
Synthesis and Applications
Terence Kuzma
![Page 2: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/2.jpg)
Outline
• Nanomaterial Synthesis Approaches
– General overview (Lecture 1)
• Nanoparticle Synthesis
– Chemical Reduction Methods
– Attrition
– Pyrolysis (Lecture 2)
– RF Plasma (Lecture 3)
– Thermal decomposition
– Pulsed Laser Method
• Some Nanoparticle Applications
![Page 3: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/3.jpg)
Nanomaterial Synthesis
Approaches• Top down approach starts with a bulk material and then
breaks it into smaller pieces using mechanical, chemical,
or any other form of energy. In some applications, it
could be described as relative large amounts of energy
to force materials into specific configurations. Examples
PVD such as sputtering or e-gun evaporation.
• The bottom up approach synthesizes the nanomaterials
from atomic or molecular species via chemical reactions
or self assembly. This allows the precursor particles to
grow in size or gradually assembling the atomic or
molecular precursors until the desired structure is
achieved.
![Page 4: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/4.jpg)
Nanomaterials Synthesis
ApproachesThe bottom up approach examples that we will explore in
the section include pyrolysis, colloidal chemical methods,
attrition, RF plasma, and pulsed laser method.
These approaches feature advantages, and
disadvantages. There are trades off factors such as cost.
Cost factors could include raw material, environmental
factors, process system maintenance, particle filtration.
Again the specific approach will dictate size distribution,
environmental concerns, and material type. So selecting
an approach has many considerations.
Examples that we will explore in the section include
pyrolysis, colloidal chemical methods, attrition, pyrolysis,
RF plasma, and pulsed laser method.
![Page 5: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/5.jpg)
Nanomaterials Synthesis
Approaches• Both top down and bottom up can be performed in the
gas or liquid phases, supercritical fluids, the solid state,
or in a partial vacuum.
• Key to both processes is the ability to be repeatable and
predictable in manufacturing the nanoscale product. The
process must control the particle size, particle shape,
size distribution, particle composition, and degree of
agglomeration.
• Another important consideration is assuring a desired
level of stability. Intuitively nanomaterials usually have
reactive surface energy, but this potential must be
enabled at the appropriate time. So often nanomaterials
are stabilized until the desired reaction is enabled.
![Page 6: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/6.jpg)
Outline
• Nanomaterial Synthesis Approaches
– General overview
• Nanoparticle Synthesis
– Chemical Reduction Methods
– Attrition
– Pyrolysis
– RF Plasma
– Thermal decomposition
– Pulsed Laser Method
• Some Nanoparticle Applications
![Page 7: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/7.jpg)
Chemical Reduction Method
• Chemical reduction methods has the potential to be
scaled up even at room temperature. The chemical
reduction of meyal salts is the most common method for
the synthesis of nanoparticles. Generally, this approach
is very useful because it easy, and initially inexpensive.
Naturally liquid byproducts may be costly to dispose, and
this method is applicable to a limited number of
materials.
• Chemical reduction methods may utilize both organic
and inorganic reactants.
• Typically, a metal salt is reduced leaving nanoparticles
evenly dispersed in a liquid.
![Page 8: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/8.jpg)
Typical nanoparticle for bio-application
Metal nano colloid
Reducing agents
Sodium citrate
NaBH4
Ascorbic acid
Capping agents
Thiols
Citrate
Polymers, PVA, PVP
![Page 9: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/9.jpg)
Chemical Reduction Method
• Aggregation is prevented by electrostatic repulsion or the
introduction of a stabilizing reagent that coats the particle
surfaces.
• Several reducing agents such as ascorbic acid, citric
acid, and their salts; alkali hydrides namely NaBH4,
NaB(C2H5)3H, and LIB(C2H5)3H along with various
capping agents such as polymers. These polymers
could include polyvinylpyrrolidone, organic ligands such
as quaternary amines, thiols, and surfactants help to
stabilize metal nanoparticles.
• Particle sizes range from 1-200nm and are controlled by
the initial concentrations of the reactants and the action
of the stabilizing reagent.
![Page 10: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/10.jpg)
Chemical Reduction Method
• Examples: Gold
– A common method for preparing colloidal gold
nanoparticles involves combining hydrogen
tetrachloroaurate (HAuCl4) and sodium citrate
(Na3C6H5O7) in a dilute solution.
– Upon dissociation, the citrate ions (C6H5O73-) reduce
Au3+ to yield 30-40 nm gold particles.
Half reaction equations:
• Au3+(aq) + 3e- Au(s)
• C6H5O73-(aq) +H2O(l) C5H4O4
2-(aq) + CO2(g) + H3O(aq) +
2e-
![Page 11: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/11.jpg)
Example: Formation of Gold Nanoparticles
HAuCl4Gold
NPHAuCl4
Sodium
Citrate
Heat
http://mrsec.wisc.edu/Edetc/nanolab/gold/index.html
J. Chem. Ed. 2004, 81, 544A.
1. Heat a solution of chloroauric acid (HAuCl4) up to reflux (boiling). HAuCl4 is
a water soluble gold salt.
2. Add trisodium citrate, which is a reducing agent.
3. Continue stirring and heating for about 10 minutes.
• During this time, the sodium citrate reduces the gold salt (Au3+) to
metallic gold (Au0).
• The neutral gold atoms aggregate into seed crystals.
• The seed crystals continue to grow and eventually form gold
nanoparticles.
Red Color = Gold NP
![Page 12: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/12.jpg)
Example: Formation of Gold Nanoparticles
Reduction of gold ions: Au(III) + 3e- → Au(0)
Nucleation of Au(0) seed crystals:Seed Crystal
10’s to 100’s of Atoms
Nanorods
Spherical
Nanoparticles
Isotropic
Growth
Anisotropic
Growth
Surface capped
with citrate anions
Adding surfactant to growth solution
caps certain crystal faces and promotes
growth only in selected directions.
Growth of nanoparticles:
Seed
![Page 13: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/13.jpg)
Chemical Reduction Method
• Examples: Molybdenum
– 1-5 nm molybdenum nanoparticles can be
created at room temperature by reducing
MoCl3 in a toluene solution in the presence of
sodium triethylborohydride (NaBEt3H).
– Reaction equation:
MoCl3 + 3NaBEt3H Mo + 3NaCl + 3BEt3 +
(3/2)H2
![Page 14: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/14.jpg)
Chemical Reduction Method
• Examples: Iron– The TEM image to the right shows
3nm Fe nanoparticles produced by
reducing FeCl2 with sodium
borohydride (NaBH4) in xylene.
– Trioctylphosphine oxide (TOPO) was
introduced as a capping agent to
prevent oxidation and aggregation
Phys. Chem. Chem. Phys., 2001, 3, 1661È1665
TEM image of Fe nanoparticles
![Page 15: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/15.jpg)
Chemical Reduction Method
• Examples: Silver– The reduction of AgNO3 by NaBH4 in
aqueous solution can produce small
diameter (<5nm) silver nanoparticles
– In one reported method, the reduction
takes place between layers of kaolinite, a
layered silicate clay material that functions
to limit particle growth.
– Dimethyl sulfoxide (DMSO) is used as a
capping agent to prevent corrosion and
aggregation of the Ag particles.
R. Patakfalvi et al. / Colloids and Surfaces A: Physicochem. Eng. Aspects 220 (2003) 45/54
![Page 16: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/16.jpg)
Outline
• Nanomaterial Synthesis Approaches
– General overview
• Nanoparticle Synthesis
– Chemical Reduction Methods
– Attrition (Mechanical Milling)
– Pyrolysis
– RF Plasma
– Thermal decomposition
– Pulsed Laser Method
• Some Nanoparticle Applications
![Page 17: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/17.jpg)
Attrition (Mechanical Milling)
• Attrition known as mechanical milling is routinely used in powder metallurgy and mineral processing industries. In this method mixtures of elemental or prealloyed powders are subjected to grinding under protective atmosphere in systems that are capable of high energy compressive impact forces.
• Macro or micro scale particles are ground in a ball mill, a planetary ball mill, or other size reducing mechanism.
• The resulting particles are separated by filters and recovered.
• Particle sizes range from tens to hundreds of nm.
• Broad size distribution and varied particle geometry.
• May contain defects and impurities from the milling process.
• Generally considered to be very energy intensive.
Cao, Guozhong. Nanostructures and Nanomaterials: Synthesis, Properties &
Applications. Imperial College Press. 2004
![Page 18: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/18.jpg)
Attrition • For single-phase elemental powder or intermetalic
compound powder is milled the grain size of the powder continues to decrease until it reaches a desired level of 3-25nm.
• Some intermetallic compounds of the powder becomes amorphous beyond this point.
• Because the processes are low temperature newly formed grains grow very slowly.
• Mechanical attrition processes allow allow the preparation of alloys and composites that could be precluded by other manufacturing methods.
• High energy mechanical milling is a very effective process for synthesizing metal ceramic composites.
![Page 19: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/19.jpg)
Attrition: Rotary Ball Mill
• A hollow steel cylinder containing tungsten balls and a solid precursor rotates about its central axis.
• Particle size is reduced by brittle fracturing resulting from ball-ball and ball-wall collisions.
• Milling takes place in an inert gas atmosphere to reduce contamination.
http://www.ktf-split.hr/glossary/image/ball_mill.gif
![Page 20: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/20.jpg)
Attrition: Rotary Ball Mill• Rotary mills are likely to introduce impurities to the particle
surface. This could be to serve as a sintering aid, and may force eutectic liquid so as to introduce liquid phase sintering.
• Surface defects from milling may also increase surface defects that increase surface energy which may be favorable for densification in a nanocomposite.
• This is a popular method of making powdered metals with each particle having a predictable alloy ratio. This allows products that have consistent uniformity in the bulk. An example is CPM-3V steel. This steel is used for
cutting tools such as specially
knives. These knives have
outstanding edge retention
due to their homogeneity.
![Page 21: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/21.jpg)
Attrition
Claudio L. De Castro, Brian S. Mitchell. Nanoparticles from Mechanical Attrition.
Department of Chemical Engineering, Tulane University, New Orleans, Louisiana, USA
• Attrition Examples
![Page 22: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/22.jpg)
Materials in Nanotechnology
Introduction to Nanoparticle
Synthesis and Applications
Part 2
Terence Kuzma
![Page 23: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/23.jpg)
Outline
• Nanomaterial Synthesis Approaches
– General overview
• Nanoparticle Synthesis
– Chemical Reduction Methods
– Attrition
– Pyrolysis
– RF Plasma
– Thermal decomposition
– Pulsed Laser Method
• Some Nanoparticle Applications
![Page 24: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/24.jpg)
Pyrolysis
• Pyrolysis is a popular method for creating
nanoparticles, especially oxides. A
precursor (liquid or gas) is forced through
an orifice at high pressure and burned.
• The resulting ash is collected to recover
the nanoparticles.
• Large volume of gas leads to high rate of
material synthesis
![Page 25: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/25.jpg)
Pyrolysis: Material Applications
Images clockwise from top left:
1. Tire <www.Safercar.gov>
2. Paint cans <http://www.ndhealth.gov/wm/PollutionPreventionAndRecyclingProgram/
MercuryContainingDevicesProducts.htm>
3. Optical Fibers <https://lasers.llnl.gov/publications/photons_fusion/2009/january
_february.php>
4. Vitamans <www.fda.gov/AboutFDA/WhatWeDo/History/ThisWeek/ucm117726.htm>
5. Makeup <https://pa-online.pa.gov.sg/NASApp/sdsol/sdsol/common
/Bring_Out_Best_In_You.htm>
6. Ink Quil < http://www.orovalleyaz.gov/Town_Government/Town_Clerk/notary_services.htm>
Carbon Black
TiO2
SiO2
Tires
Inks
Paints
Makeup Flowing aid
Optical
fibers
![Page 26: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/26.jpg)
Annual Production of
Flame made materials
• Carbon black – 8 million tons $8 billion
• TiO2 - 2.5 million tons, $5 billion
• SiO2 2.0 million tons, $2 billion
![Page 27: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/27.jpg)
Pratsinis, Sotiris E., Functional Nanoparticles and Films Made in the Gas-
phase. Nano Science and Technology Institute, Cambridge. 2008
![Page 28: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/28.jpg)
Pratsinis, Sotiris E., Functional Nanoparticles and Films Made in the Gas-
phase. Nano Science and Technology Institute, Cambridge. 2008
![Page 29: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/29.jpg)
Flame Spray Pyrolysis (FSP)
• Versatile
• Large Variety
of precursors
• Controllable
• Scalable
Aggregation
Condensation
Coagulation
Nucleation
Droplet evaporation
![Page 30: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/30.jpg)
Pyrolysis: System Overview
Xiao Q., Yiguang J., Stefan B. and Nan Y. Synthesis of Y2O3:Eu Phosphor Nanoparticles by
Flame Spray Pyrolysis. Princeton University, Princeton, NJ
![Page 31: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/31.jpg)
Pyrolysis
Aggregates and Agglomerates:• Aggregate – An assemblage of particles rigidly joined together by chemical
or sinter-forces.
• Agglomerate – A loosely coherent assembly of particles and/or aggregates
held together by weak interactions
• Current aerosol instruments cannot distinguish between them.
Aggregates Agglomerates
![Page 32: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/32.jpg)
Pyrolysis
Agglomerate Formation Sequence
Residence time
TiO2
Monomers
Transient Hard
Agglomerates
Spherical
Particles Hard Agglomerates Soft Agglomerates
![Page 33: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/33.jpg)
Pyrolysis
Degree of agglomeration matters:
• Agglomerated
- Fillers
- Catalysts
- Lightguide preforms
- Particles for CMP
• Non-agglomerated
- Pigments
- Composites
- Electronics
• Distinction between hard and soft agglomerates is largely empirical.
• Controlled agglomeration can minimize post-grinding and other
costly separation techniques.
Pratsinis, Sotiris E., Functional Nanoparticles and Films Made in the Gas-
phase. Nano Science and Technology Institute, Cambridge. 2008
![Page 34: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/34.jpg)
Pyrolysis
Regions of AgglomerationNon-Agglomerates
Hard Agglomerates
Soft Agglomerates
Pratsinis, Sotiris E., Functional Nanoparticles and Films Made in the Gas-
phase. Nano Science and Technology Institute, Cambridge. 2008
![Page 35: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/35.jpg)
Pyrolysis
![Page 36: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/36.jpg)
Impact of oxygen
• Aids in combustion
• Provides chemistry in the reaction
• Acts as a dilutent, cools the flame,
prevents agglomeration
• All of these variables can be decoupled by
burner design. Which is cheaper than
increasing oxygen flow.
Pyrolysis
![Page 37: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/37.jpg)
Pyrolysis
Particle Size Controlled by O2 Flow
• Excess oxygen
makes the flame
burn cooler
resulting in
smaller diameter
particles
![Page 38: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/38.jpg)
Pyrolysis
Particle Formation and Growth by Gas Phase Chemical
Reaction, Coagulation, Sintering and Surface Growth:
O2
TTIP
Molecules
TiO2
Molecules
TiO2
Particles
Ti
C3H7O
C3H7O
OC3H7
OC3H7
Titanium-Tetra-Iso-Propoxide
TiO2
Aggregates
Decreasing Temperature
Pratsinis, Sotiris E., Functional Nanoparticles and Films Made in the Gas-
phase. Nano Science and Technology Institute, Cambridge. 2008
![Page 39: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/39.jpg)
Pyrolysis: Jet Design
CH4 CH4
CH4Air
AirAir
TiCl4 TiCl4TiCl4 TiCl4
Air Air
![Page 40: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/40.jpg)
Pyrolysis: Jet DesignEffect of Oxidant Composition on TiO2 Morphology:
CH4
CH4
Oxidant
Oxidant
TiCl4TiCl4
Flame mixing B Flame mixing C
![Page 41: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/41.jpg)
Pyrolysis: Nozzle Quenching
Pratsinis, Sotiris E., Functional Nanoparticles and Films Made in the Gas-
phase. Nano Science and Technology Institute, Cambridge. 2008
Vapor
• Flame length is controlled by
rapid quenching
• Prevents agglomeration by
inhibiting growth processes in the
early stages of growth.
• Provides precise control of
particle size
Desired
![Page 42: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/42.jpg)
Pyrolysis: Nozzle QuenchingNozzle Quenching controls flame length and particle
size.
![Page 43: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/43.jpg)
Pyrolysis: Nozzle QuenchingTiO2 Particle Size Control by Nozzle Quenching
Pratsinis, Sotiris E., Functional Nanoparticles and Films Made in the Gas-
phase. Nano Science and Technology Institute, Cambridge. 2008
![Page 44: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/44.jpg)
Pyrolysis: Electrostatic Charging
• Particle size can also be controlled by generating an
electric field across the flame.
• A large electric field (hundreds of kV/m) is generated
between two plate electrodes situated on opposite sides
of the flame.
• Similar to nozzle quenching, the electric field limits
particle growth by reducing the residence time in the
high temperature region of the flame.
• In addition, the electric field charges the particles. This
results in electrostatic repulsion between newly formed
particles, preventing coagulation.
S. Vemury, S.E. Pratsinis, L. Kibbey, Electrically-controlled flame synthesis of nanophase TiO2, SiO2, and
SnO2 powders. JMR, Vol. 12, 1031-1042. 1997.
![Page 45: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/45.jpg)
Pyrolysis: Electrostatic Charging
![Page 46: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/46.jpg)
• Pyrolysis is a high yield method that can
fulfill the strong demand for nanoparticles.
• Can be customized to produce unique
nanoparticles.
• Broad distribution of particle sizes and
morphology, needs filtration/separation.
Pyrolysis: Advantages &
Disadvantages
![Page 47: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/47.jpg)
Materials in Nanotechnology
Introduction to Nanoparticle
Synthesis and Applications
Part 3
Terence Kuzma
![Page 48: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/48.jpg)
Outline
• Nanoparticle Synthesis
– Colloidal Chemical Methods
– Attrition
– Pyrolysis
– RF Plasma
– Thermal Decomposition
– Pulsed Laser Method
• Nanoparticle Applications
![Page 49: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/49.jpg)
RF Plasma Synthesis • The starting material is placed in a pestle and heated under vacuum
by RF heating coils.
• A high temperature plasma is created by flowing a gas, such as He,
through the system in the vicinity of the coils.
• When the material is heated beyond its evaporation point, the vapor
nucleates on the gas atoms which diffuse up to a cooler collector rod
and form nanoparticles.
• The particles can be passivated by introducing another gas such as
O2.
• In the case of Al nanoparticles the O2 forms a thin layer of AlO3
around the outside of the particle inhibiting aggregation and
agglomeration.
• RF plasma synthesis is very popular method for creating ceramic
nanoparticles and powders
• Low mass yield.
Poole, C., Owens, F. Introduction to Nanotechnology. Wiley, New Jersey. 2003
![Page 50: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/50.jpg)
RF Plasma Apparatus
Poole, C., Owens, F. Introduction to Nanotechnology. Wiley, New Jersey. 2003
![Page 51: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/51.jpg)
Outline
• Nanoparticle Synthesis
– Colloidal Chemical Methods
– Attrition
– Pyrolysis
– RF Plasma
– Thermal Decomposition
– Pulsed Laser Method
• Nanoparticle Applications
![Page 52: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/52.jpg)
Thermal Decomposition
• Thermal decomposition is the chemical decomposition of a substance into ins constituents by heating.
• A solid bulk material is heated beyond its decomposition temperature in an evacuated furnace tube.
• The precursor material may contain metal cations and molecular anions, or metal organic solids.
• Example: 2LiN3(s) 2Li(s) +3N2(g)
– Lithium particles can be synthesized by heating LiN3 in a quartz tube under vacuum.
– When heated to 375oC the nitrogen outgases from the bulk material and the Li atoms coalesce to form metal nanoparticles.
Poole, C., Owens, F. Introduction to Nanotechnology. Wiley, New Jersey. 2003
![Page 53: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/53.jpg)
Thermal Decomposition Apparatus
Sample in Ta foil
Furnace
Evacuated
Quartz Tube
Turbo Molecular
Pump
Mechanical Pump
![Page 54: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/54.jpg)
Outline
• Nanoparticle Synthesis
– Colloidal Chemical Methods
– Attrition
– Pyrolysis
– RF Plasma
– Thermal Decomposition
– Pulsed Laser Methods
• Nanoparticle Applications
![Page 55: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/55.jpg)
Pulsed Laser Methods
• Pulsed Lasers have been employed in the
synthesis silver nanoparticles from silver nitrate
solutions.
• A disc rotates in this solution while a laser beam
is pulsed onto the disc creating hot spots.
• Silver nitrate is reduced, forming silver
nanoparticles.
• The size of the particle is controlled by the
energy in the laser and the speed of the rotating
disc.
Poole, C., Owens, F. Introduction to Nanotechnology. Wiley, New Jersey. 2003
![Page 56: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/56.jpg)
Pulsed Laser Methods
• Pulsed Lasers have also been employed to
aqueous media at room temperature without
reducing agents or organic ligands.
• As you recall capping agents are required for
gold particles, and the capping agents and
ligands can interfere with subsequent
processes. The un-encapsulated exposed gold
high catalytic activity, exclusion of toxic effects in
biomedical applications or an improved
sensitivity in analytical applications
Monophasic ligand-free alloy nanoparticle synthesis determinants during
pulsed laser ablation of bulk alloy and consolidated microparticles in water
Anne Neumeister , Jurij Jakobi , Christoph Rehbock , Janine Moysig and
Stephan Barcikowski
![Page 57: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/57.jpg)
Pulsed Laser Methods• Pulsed lasers can also create homogeneous
particles without temperature segregation that
are typical of high temperature processes.
• Alloy nanoparticles (NPs) are of increasing
interest due to their beneficial properties in
contrast to their monometallic constituents.
• Alloy NPs benefit from the fact that their optical,
catalytic as well as magnetic properties are
tunable based on the elemental compositions of
the particles
Monophasic ligand-free alloy nanoparticle synthesis determinants during
pulsed laser ablation of bulk alloy and consolidated microparticles in water
Anne Neumeister , Jurij Jakobi , Christoph Rehbock , Janine Moysig and
Stephan Barcikowski
![Page 58: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/58.jpg)
Pulsed Laser Methods• A well-studied bimetallic system is the
combination of Ag and Au which possess similar
lattice constants while the two elements are
completely miscible over the entire composition
range
• Both metals display intense and well-defined
surface plasmon resonance (SPR) bands in the
visible range and the optical absorption spectra
of Ag–Au alloy NPs generally exhibit one SPR
band whose maximum depends on the alloy
compositionMonophasic ligand-free alloy nanoparticle synthesis determinants during
pulsed laser ablation of bulk alloy and consolidated microparticles in water
Anne Neumeister , Jurij Jakobi , Christoph Rehbock , Janine Moysig and
Stephan Barcikowski
![Page 59: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/59.jpg)
Pulsed Laser Methods
Phys. Chem. Chem. Phys., 2014, 16, 23671-23678
![Page 60: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/60.jpg)
Pulsed Laser Methods• Incoming laser pulse is adsorbed by the bulk
material forming a plasma (C2).
• At point C1, the generation of an expanding
cavitation bubble, while crystalline NPs are
formed inside the cavitation bubble by
nucleation and coalescence
• At point B, coalescence and reaction of the
generated species with colloidal particles
• At point C, ablation and cavitation bubble
formation
Monophasic ligand-free alloy nanoparticle synthesis determinants during
pulsed laser ablation of bulk alloy and consolidated microparticles in water
Anne Neumeister , Jurij Jakobi , Christoph Rehbock , Janine Moysig and
Stephan Barcikowski
![Page 61: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/61.jpg)
Pulsed Laser Apparatus for Ag
Nanoparticles
Poole, C., Owens, F. Introduction to Nanotechnology. Wiley, New Jersey. 2003
![Page 62: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/62.jpg)
Outline
• Nanoparticle Synthesis
– Colloidal Chemical Methods
– Attrition
– Pyrolysis
– RF Plasma
– Thermal Decomposition
– Pulsed Laser Methods
• Nanoparticle Applications
![Page 63: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/63.jpg)
Nanoparticle Applications: ZnO
• Zinc Oxide has opaque and antifungal
properties.
• Used as UV blocking pigments in sunscreens,
cosmetics, varnishes, and fabrics
• Incorporated in foot powders and garden
supplies as an antifungal.
• ZnO nanowires can improve the elastic
toughness of bulk materials
![Page 64: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/64.jpg)
Nanoparticle Applications: TiO2
• Titanium Dioxide is used as an inorganic white
pigment for paper, paints, plastics, and whitening
agents.
• TiO2 nanoparticles are used as UV blocking
pigments in sunscreens, cosmetics, varnishes, and
fabrics.
• TiO2 has unique photocatalytic properties that make
it suitable for a number of advanced applications:
– Self-cleaning glass and antifogging coatings
– Photoelectrochemical cells (PECs)
– Detoxification of waste water
– Hydrolysis
![Page 65: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/65.jpg)
Nanoparticle Applications: Fe
• 50-100nm Iron nanoparticles are used in
magnetic recording devices for both digital
and analog data.
• Decreasing the diameter to 30-40nm
increases the magnetic recording capacity
by 5-10 times per unit.
![Page 66: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/66.jpg)
Nanoparticle Applications:
Iron Oxide• Iron Oxide nanoparticles have unique
magnetic and optical properties.
• Iron oxide nanoparticles can be
translucent to visible light while being
opaque to UV light.
• Applications include UV protective
coatings, various electromagnetic uses,
electro-optic uses, and data storage.
![Page 67: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/67.jpg)
Nanoparticle Applications:
Iron Alloys• Iron-platinum nanoparticles have
increased magnetism and it is predicted
that 3nm particle can increase the data
storage capacity by 10 times per unit area.
• Iron-palladium nanoparticles 100-200nm in
diameter have been shown to reduce toxic
chlorinated hydrocarbons to nontoxic
hydrocarbon and chloride compounds.
SCIENCE VOL 287 17 MARCH 2000
![Page 68: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/68.jpg)
Nanoparticle Applications:
Alumina• Alumina (Aluminum Oxide) is used in
Chemical Mechanical Polishing (CMP)
slurries, as well as ceramic filters.
• Nano-alumina is used in light bulb and
fluorescent tube coatings because it emits
light more uniformly and allows for better
flow of fluorescent materials.
![Page 69: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/69.jpg)
Nanoparticle Applications: Ag
• Silver has excellent conductivity and has
been used as an antimicrobial material for
thousands of years.
• Silver’s anti-microbial potential increase
with increased surface area.
• Applications include biocides, transparent
conductive inks, and antimicrobial plastics,
and bandages.
![Page 70: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/70.jpg)
Nanoparticle Applications: Gold
• Gold nanoparticles are relatively easy to produce compared to other types of nanoparticles due to its high chemical stability.
• Uses for gold nanoparticles are typically catalytic and include DNA detection and the oxidation of carbon monoxide.
• Gold has superior conductivity allowing gold nanoparticles to be used in various probes, sensors, and optical applications.
![Page 71: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/71.jpg)
Nanoparticle Applications: Gold
• The First Response® home pregnancy test uses 1µm polystyrene sphere and 50nm gold particles coated with an antibody to human chorionic gonadotropin (hCG), a hormone produced during pregnancy.
• When urine containing hCG comes in contact with the polystyrene-gold-antibody complex, the nanoparticles coagulate into red clumps. Fluids pass through a filter where the clumps are caught yielding a pink filter.
• Suspended (un-coagulated) nanoparticles pass through the filter and no color change occurs.
Bangs, L. B. New Developments in Particle-based
Immunoassays. Pure & Appl. Chem. Vol. 68, No 10 p
1873-1879. 1996
![Page 72: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/72.jpg)
Nanoparticle Applications: Gold
Bangs, L. B. New Developments in Particle-based
Immunoassays. Pure & Appl. Chem. Vol. 68, No 10 p
1873-1879. 1996
![Page 73: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/73.jpg)
Nanoparticle Applications: ZrO
• Zirconium Dioxide nanoparticles can
increase the tensile strength of materials
when applied as a coating.
• This has many possible applications in
wear coatings, ceramics, dies, cutting
edges, as well as piezoelectric
components, and dielectrics.
![Page 74: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/74.jpg)
Sintering
• Sintering is the process of compacting and
forming a solid mass of material by heat and/or
pressure without melting it to the point of
liquefaction
• Sintering is possible with metals, ceramics,
plastics
• Atoms in the materials diffuse across the
boundaries of the particles, fusing the particles
together and creating one solid piece
![Page 75: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/75.jpg)
Sintering
• Because the sintering temperature does not
have to reach the melting point of the material,
sintering is often chosen as the shaping process
for materials with extremely high melting points
such as tungsten and molybdenum
![Page 76: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/76.jpg)
Sintering• Sintering occurs by diffusion of atoms through
the microstructure, this diffusion is caused by a
gradient of chemical potential
http://www.intechopen.com/books/sintering-applications/pulse-current-auxiliary-sintering
![Page 77: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/77.jpg)
Sintering• The six common mechanisms are:
– Surface diffusion – Diffusion of atoms along the
surface of a particle
– Vapor transport – Evaporation of atoms which
condense on a different surface
– Lattice diffusion from surface – atoms from surface
diffuse through lattice
– Lattice diffusion from grain boundary – atom from
grain boundary diffuses through lattice
– Grain boundary diffusion – atoms diffuse along grain
boundary
– Plastic deformation – dislocation motion causes flow
of matter
![Page 78: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/78.jpg)
Sintering
Synthesis and Thermoluminescent Characterization of Ceramics Materials,
Teodoro Rivera
![Page 79: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/79.jpg)
Structural and Dielectric Properties of Glass – Ceramic Substrate With Varied Sintering Temperatures
Rosidah Alias
![Page 80: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/80.jpg)
Sintering• Zirconium dental sintering
![Page 81: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/81.jpg)
Sintering
https://3dprint.com/165438/sdm-employee-jay-lenos-garage/
![Page 82: Materials in Nanotechnology - UNESCO...Outline • Nanomaterial Synthesis Approaches –General overview (Lecture 1) • Nanoparticle Synthesis –Chemical Reduction Methods –Attrition](https://reader034.vdocuments.net/reader034/viewer/2022042709/5f3ebfee1efbbf30eb65b4e4/html5/thumbnails/82.jpg)
Outline
• Nanomaterial Synthesis Approaches
– General overview
• Nanoparticle Synthesis
– Chemical Reduction Methods
– Attrition
– Pyrolysis
– RF Plasma
– Thermal decomposition
– Pulsed Laser Method
• Some Nanoparticle Applications
– END