May 15, 2017May 17, 2017
Cairo, Egypt Alexandria, Egypt
Take the Profitable Path to Olefins using
UOP TechnologiesMike Banach
Sr. Business Leader, Olefins &
Detergents2017 Honeywell Oil & Gas Technologies Symposium
Tremendous Opportunities in Light Olefins
Population growth continues to drive demand for products
derived from light olefins
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World demand for ethylene and propylene growing (about 4%/yr)
More than 50 MMTA of additional capacity will be needed by 2020
Driven primarily by growing middle class in developing regions
Source: IHS Chemical
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0
50
100
150
200
250
300
350
400
2000 2005 2010 2015 2020 2025
Millio
n M
TA
Light Olefin Demand
Propylene
Ethylene
Tremendous Opportunities in Light Olefins
2
Growing share from “other” sources other than steam cracking and refineries
Propylene gap continuing to grow
Options for on-purpose olefin production include MTO, OCP, and Oleflex
Source: IHS Chemical
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UOP has the technologies to meet your light olefin demands
80
130
180
230
280
330
2000 2005 2010 2015 2020 2025
Millio
n M
TA
Light Olefin Supply
Propylene - Other
Ethylene - Other
Propylene - Refinery
Propylene - Steam Cracking
Ethylene - Steam Cracking
Pathways to Maximize Profitability …
3
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Feedstocks Processes Products
PropaneButane
Propylene
ButyleneUOP OleflexTM
Process
MethaneCoal
Ethylene
Propylene
UOP Advanced MTO Process
MTO: Value Chain from Gas or Coal
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Coal to Olefins (CTO)
Ethylene & Propylene
Synthesis Gas
Production
Methanol Synthesis
Coal
Gas to Olefins (GTO)
Natural Gas
MTO
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MTO Connects Natural Gas and Coal to the Largest Commodity
Petrochemicals – Ethylene and Propylene
UOP Advanced MTO Technology
All processes licensed by UOP
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Highest Olefin Yield
Wide P/E Flexibility Range
Maximum Single Train Capacity
Opportunity to Produce Butadiene
Regen Gas
Air
Methanol
Water
Ethylene
C4+
Propylene
By-product
MTO Process Integrated withOlefin Cracking Process (OCP)
Sep Section
OCP
MTOLight
Olefin
Recovery
n-Butenes(optional)
TPC/UOP OXO-D™Process
Butadiene(optional)
DMERecovery
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Yield Benefits from OCP Integration
6
0
10
20
30
40
50
60
70
80
90
100
Naphtha MTP MTO Advanced
MTO
Carb
on
Yie
ld %
Other high value products
Ethylene
Propylene
70
80
90
100
1.0 1.2 1.4 1.6 1.8 2.0
Lig
ht
Ole
fin
Ca
rbo
n Y
ield
s,
Wt-
%Propylene/Ethylene (P/E) Product Ratio, Wt.
2.6 tons of Methanol consumed per ton of light olefin produced
OCP integration increases light olefin yields by >15%
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Commercialization Status
Strong global interest continues – On stream unit operating successes
# Owner Location Scopekmta LO Capacity Status
1Wison (Nanjing) Clean
Energy Company, Ltd.
Nanjing, Jiangsu
MTO / OCP 300 On stream 2013
2Jiutai Energy (Zhungeer)
Company, Ltd.
Ordos, Inner
MongoliaMTO 600 SU 2018
3Shandong Yangmei Hengtong
Chemicals Company, Ltd.
Linyi, Shandong
MTO / OCP 300 On stream 2015
4 Jiangsu-SailboatLianyungang, Jiangsu
MTO / OCP 830On stream Dec.
2016
5 Shandong Better Energy Dongying, Shandong
MTO / OCP 300 Awarded
6 Undisclosed China MTO / OCP 300 Awarded
7 Undisclosed China MTO / OCP 300 SU 2019
8 LUXI Chemical Group Co. Ltd.Liaocheng, Shandong
MTO / OCP 300 SU 2018
9Connell Chemical Industrial Co.
Ltd.Jilin City,
JilinMTO / OCP 300 SU 2017
The following projects in China have selected the UOP/INOVYN MTO™ Process:
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MTO Summary
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• Strong demand growth for ethylene and propylene
• MTO opens a new path to ethylene and propylene starting from cost advantaged gas and coal
– Low cost of production
– High yield of ethylene and propylene (> 89%)
– Flexible product ratio (P/E range 0.9 to 1.8, depending on configuration)
– Byproduct C4 olefins available for B1, B2, and BD production
• Single train capacity up to 1.8 million MTA of light olefin
• Commercialized in 2013 by Wison Clean Energy,
3 units on stream in 2016, 3 more by 2018
• Best technology available – UOP will help you
evaluate MTO for your situation
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Pathways to Maximize Profitability …
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Feedstocks Processes Products
PropaneButane
Propylene
ButyleneUOP OleflexTM
Process
MethaneCoal
Ethylene
Propylene
UOP Advanced MTO Process
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LPG to High Value Olefins with Oleflex Process
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Propane
Butane
Propylene
ContainedButylene
Feedstocks Products Uses
Gasoline Blending Components
MTBE
Iso-Octane
ETBE
Synthetic Rubbers & Acrylics
Propane
Butane+
Propylene
+ContainedButylene
Dedicated and Mixed Unit Applications
H2
UOP Oleflex Process
High performance plastic
Fiber
Packaging
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C3 Oleflex Complex
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OleflexUnit
C3 LPG
C4+
Byproduct H2C2-
Propylene
SHP
P-P Splitter
Deethanizer
Depropanizer
UOP Oleflex Process used in 18 of the 28 operating PDH Units operating in the world today
(Two C3 Oleflex at 750 KMTA – world’s largest PDH Units)
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UOP 7864B-12
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UOP Leads the Way in Dehydrogenation
Chosen in every engagement in 2015
6 wins out of 7 in 2016
Why Customers Choose UOP Oleflex - I
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• Lowest Overall Cost of Production:
– Low feed consumption design available <1.15
– Lowest gross / net energy usage
– Lowest coke → Flexible byproduct disposition
• Smaller Investment Required
– Fewest reactors on most compact plot space
– Efficient regeneration requires smaller equipment
– Constant equipment count → Best economy of scale
You can have both! Get lowest CAPEX and OPEX in one design
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Why Customers Choose UOP Oleflex - II
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• High Reliability / On-Stream Availability
– Constant process conditions
– CCR technology well proven across the industry
• Smallest Environmental Footprint:
– Lowest energy leads to lowest CO2
– Low NOx & VOC emissions
– Proven non-toxic compliant catalyst system
Most environmentally friendly technology
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Take the Profitable Path with UOP Technologies
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• Fundamentals remain strong for on-purpose olefin investments
– Traditional sources will not meet demand
– Low-cost coal or methane and propane
– Now is the right time to invest in on-purpose technologies
• UOP’s Advanced MTO Process– Highest Olefin Yields with Flexible P:E Ratio
– Leverage cost advantaged coal or gas to produce high value light olefins
• UOP’s Oleflex Dehydrogenation Technology:
– Lowest Capital Cost & Energy Usage results in
Lowest Operating Cost (CCOP) and
Highest Return on Investment (ROI)
– Selected in 35 of last 41 projects since 2011
– Process your LPG into profitable propylene or butenes
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Q u e s t i o n a n d A n s w e r
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