Maine Department of Environmental Protection | 11.05.2018 | 10193.050
November 5, 2018
Mr. Richard Currie
Maine Department of Environmental Protection
17 State House Station
Augusta, Maine 04330
Re: Phase II Environmental Site Assessment | Steamship Navigation |
2287 Camden Road | Warren, Maine
Dear Mr. Currie:
Enclosed please find a copy of the Final Phase II Environmental Site Assessment (ESA) Report
for the Steamship Navigation property located at 2287 Camden Road in Warren, Maine (Site).
This Phase II ESA has been completed by CES, Inc. (CES) in accordance with our proposal dated
July 27, 2018.
The enclosed report describes the Phase II ESA investigation completed at the Site in August
and September of 2018 and the associated findings and recommendations.
If you have any questions regarding this investigation, please feel free to contact either of the
undersigned at (207) 765-6009.
Sincerely,
CES, Inc.
Suzanne Yerina, C.G. Christopher Buckman, P.G.
Project Geologist Project Manager
SLY/CFB/jna
Enc.
DRAFT PHASE II ENVIRONMENTAL SITE ASSESSMENT
STEAMSHIP NAVIGATION 2287 CAMDEN ROAD
WARREN, MAINE
Report Prepared for: MAINE DEPARTMENT OF ENVIRONMENTAL PROTECTION
17 State House Station Augusta, Maine 04330
NOVEMBER 5, 2018 JN: 10193.050
Report Prepared By: CES, Inc.
640 Main Street Lewiston, Maine 04240
207.795.6009
JN: 10193.050 Phase II ESA – 2287 Camden Road Warren, Maine
TABLE OF CONTENTS SECTION 1 | EXECUTIVE SUMMARY ................................................................................... 1 SECTION 2 | SCOPE OF WORK............................................................................................ 2 SECTION 3 | LOCATION AND BACKGROUND INFORMATION .......................................... 3
3.1 General Description ............................................................................................... 3 3.2 Environmental Setting, Geology, and Hydrogeology .............................................. 3 3.3 Site History ............................................................................................................ 4 3.4 Previous Investigations .......................................................................................... 4 SECTION 4 | FIELD SAMPLING PROGRAM ......................................................................... 8 4.1 Utility Clearance and Geophysical Survey ............................................................. 8 4.2 Direct Push Soil Borings ........................................................................................ 8 4.3 Monitoring Well Installation and Sampling ............................................................. 9 4.4 Multi-Increment Soil Sampling ............................................................................... 9 4.5 Surface Soil XRF Screening and Sampling ............................................................ 11 SECTION 5 | QUALITY ASSURANCE / QUALITY CONTROL .............................................. 12 5.1 Sub-Surface Soil Borings ....................................................................................... 12 5.2 Groundwater .......................................................................................................... 12 5.3 Multi-Increment Soil Sampling ............................................................................... 12 5.4 Surface Soil ........................................................................................................... 12 SECTION 6 | EVALUATION AND PRESENTATION OF RESULTS ...................................... 12 6.1 Subsurface Soils .................................................................................................... 12 6.2 Groundwater .......................................................................................................... 13 6.3 Multi-Increment Samples ....................................................................................... 14 6.4 Surface Soil ........................................................................................................... 14 SECTION 7 | CONCLUSIONS ................................................................................................ 15 SECTION 8 | REFERENCES .................................................................................................. 16
JN: 10193.050 Phase II ESA – 2287 Camden Road Warren, Maine
FIGURES
Figure 1 Site Location and Direct Push Soil Boring Location Map Figure 2 Baled Material Surface Soil Sampling Locations Figure 3 Short Paper Fiber Surface Soil Sampling Locations Figure 4 Covered Material Surface Soil Sampling Locations Figure 5 XRF Screening Locations – Indoor Firing Range Figure 6 XRF Screening Locations – Former Photoprocessing Trailer Figure 7 XRF Screening Locations – Spent Ammunition Lead Pile
TABLES
Table 1 Ground-Penetrating Radar Interpreted Depth to Bedrock Table 2 Surface Soil Screening and Lead in Soil Results Table 3 Direct Push Subsurface Soil PFAS Analytical Results Table 4 Multi-Increment Surface Soil PFAS Analytical Results Table 5 Multi-Increment Surface Soil PFAS Quality Control Analytical Results
APPENDICES
Appendix A – Soil Boring Logs Appendix B – Laboratory Analysis Reports
JN: 10193.050 1 Phase II ESA – 2287 Camden Road Warren, Maine
PHASE II
ENVIRONMENTAL SITE ASSESSMENT
STEAMSHIP NAVIGATION
2287 CAMDEN ROAD
WARREN, MAINE
SECTION 1 | EXECUTIVE SUMMARY
CES, Inc. (CES) completed a Phase II Environmental Site Assessment (ESA) at the Steamship Navigation property located at 2287 Camden Road in Warren, Maine (Site). Based on the results of soil and porewater sampling performed by the Maine Department of Environmental Protection (MDEP) in May 2018, it was determined that further investigation of the Site was necessary for the assessment of per- and polyfluoroalkyl substances (PFAS). In August and September 2018, CES performed the following work on behalf of the MDEP as part of the Phase II ESA for the Site:
◆ Performed ground-penetrating radar (GPR) surveying to determine depths to bedrock in areas of interest within the Site.
◆ Advanced 10 soil borings via direct push technology (DPT) at 10 locations.
◆ Collected a total of 16 soil samples, and one duplicate, from soil borings advanced at the Site.
◆ Installed and developed temporary monitoring wells at two DPT locations.
◆ Sampled overburden groundwater at one temporary microwell location to characterize groundwater quality.
◆ Completed multi-increment sampling (MIS) in the vicinity of the three waste types at the Site, including baled fiber material, papermill short paper fiber, and covered polyester fiber material.
◆ Performed x-ray fluorescence (XRF) scanning for lead at locations adjacent to Site buildings; and,
◆ Collected seven soil samples for RCRA 8 metals analysis in areas screened using the XRF.
GPR data collection did not result in any anomalous conditions within surveyed portions of the Site, with bedrock ranging between 0 and 2.5 ft below ground surface (BGS) (Table 1). Depth to bedrock, as interpreted in the field, generally correlated with encountered depths to bedrock from DPT soil boring locations; however, borings located to the southwest of the Site (DPT-01 and DPT-02) varied in depths to bedrock from those interpreted from GPR records. This is believed to be due to variations in bedrock depths along the west and southwest of the Site and visual evidence for the use of baled waste material under access roads. Exposed bedrock was located to the east of the roadway along GPR Transect No. 2 with encountered depths to bedrock in DPT-01 and DPT-02 (located west of GPR Transect No. 2) being 8 ft BGS and 13.9 ft BGS, respectively.
JN: 10193.050 2 Phase II ESA – 2287 Camden Road Warren, Maine
A total of 10 soil borings were completed using DPT resulting in a total of 16 soil samples being submitted for PFAS analysis. Each boring was completed to refusal, which was encountered at depths ranging from ground surface (DPT-04) to 14 feet BGS (DPT-02). Detected concentrations of perfluorooctane sulfonate (PFOS), perfluorooctanoic acid (PFOA), and perfluorobutanesulfonic acid (PFBS) were below the leaching to groundwater criteria (Table 2) as contained in the MDEP Maine Remedial Action Guidelines (RAGs) for Sites Contaminated with Hazardous Substances (MDEP, 2018). Two temporary microwells were installed within DPT borings where water was encountered; however, only one microwell (TW-2) contained sufficient water for sampling following development. A groundwater sample from TW-2 was submitted to Vista Analytical Laboratory (Vista) for analysis of PFAS. Analytical results indicate that PFOS and PFOA were detected at concentrations above the Maine Center for Disease Control (MeCDC) Maximum Exposure Guideline (MEG) of 70 nanograms per liter (ng/L). PFOS and PFOA were reported at a concentration of 88.0 ng/L and 88.6 ng/L, respectively. These results are consistent with the results obtained by MDEP in a porewater sample (PW-1) collected 600 feet south of TW-2 in May 2018. Composite soil samples from MIS activities were submitted for analysis of PFAS and included a sample and associated replicate from a 0-10 ft distance from the base of waste (Zone A) and a sample located 10-20 ft from the base of waste material (Zone B) as illustrated in Figure 2 through Figure 7. Samples from Zone A (primary and/or replicate sample) and Zone B associated with baled material and short paper fiber detected PFOS at a concentration above the RAG; however, detected concentrations of PFOA and PFBS were below applicable RAGs. PFAS concentrations in Covered Waste (CW) samples were reported as below the detection limit (DL) for the three PFAS compounds with applicable soil RAGs (PFOA, PFOS, and PFBS). Soil samples collected from the indoor firing range (IFR) included a sample from each of the four openings to the exterior, as illustrated on Figure 5. Three of the four analytical samples collected near the IFR were above the construction worker RAG for lead (450 mg/kg). A total of 36 locations were field-screened via XRF near the mobile home trailer, having been previously used in processing of photographic film, with two soil samples subsequently submitted to Alpha for lead analysis. Neither sample collected from the areas surrounding the trailer exceeded the RAG for lead. Screening locations in the vicinity of the spent ammunition lead pile were positioned, due to exposed bedrock, to account for the flow of precipitation as surface water towards and across the visible spent lead fragments. Lead was reported in this area at a concentration of 9,760 mg/kg, which is approximately 20 times the current construction worker RAG. SECTION 2 | SCOPE OF WORK CES performed the following Scope of Work as outlined in the MDEP Request for Bids #90 and CES’ bid submittal dated July 27, 2018. The Phase II ESA activities included:
◆ Site clearance for underground utilities;
◆ A survey of accessible portions of the Site using Ground Penetrating Radar (GPR);
◆ Clearance of soil boring locations of waste using an excavator;
◆ Advancing 10 soil borings beneath waste piles at locations identified by MDEP using direct push technology;
◆ Collection of 16 soil samples from the 10 direct push soil borings;
JN: 10193.050 3 Phase II ESA – 2287 Camden Road Warren, Maine
◆ Completion of two soil boring locations as temporary microwells and subsequent groundwater sampling;
◆ Collection of nine composite surface samples using Multi-Increment Sampling Methodology;
◆ X-Ray Fluoroscope (XRF) screening of surficial soils in the vicinity of the Indoor Firing Range, former photo processing trailer, and pile of spend lead ammunition; and
◆ Collection of seven surface soil samples based on XRF screening results and submittal for RCRA 8 Metals analysis.
Results of these activities are presented below with details provided on Site background and history, methodology used during the investigation, and discussion of results for analyzed soil and groundwater samples. SECTION 3 | LOCATION AND BACKGROUND INFORMATION 3.1 General Description
The Steamship Navigation property consists of approximately 71.40 acres located at 2287 Camden Road in Warren, Maine and is developed with three buildings (Figure 1). The Warren Tax Assessor’s Office currently identifies the Site as Lot 38 on Town of Warren Tax Map R-11 with the Knox County Registry of Deeds containing a legal description of the Site recorded in Book 2189 Page 156. The Site is currently developed with three structures, including a single-story wood-framed building with offices and indoor firing range on a concrete slab, a single-story concrete block garage on a concrete slab, and a metal-sided mobile home trailer. The ground surface at the Site slopes gently to the southwest with several areas having been regraded to construct and maintain gravel roadways. Most areas have not been maintained since the facility ceased operations; however, based on spent ammunition casings and presence of vehicles entering and exiting the Site during the investigation, some areas to the south and east appear to be currently used as a firing range. Groundcover consists primarily of landscaped green areas, gravel roadways, bales of formed fiber, exposed bedrock outcrops, and sparsely vegetated soil. The subject property is accessed from the north via an entrance from Camden Road with gravel roadways extending to the southeast and southwest portions of the Site as illustrated on Figure 1.
3.2 Environmental Setting, Geology, and Hydrogeology The Bedrock Geology Map of Maine (Osberg et al, 1985) describes bedrock underlying the Site as calcareous sandstone; interbedded sandstone, and impure limestone. CES observed bedrock outcroppings at several locations on the Site during investigation activities with the depth to bedrock, as determined through direct push sampling, varying between 0 and 14 feet BGS. The Surficial Geologic Map of Maine (Thompson et al, 1997) indicates that glaciomarine deposits (silt, clay, sand and minor amounts of gravel) underlie the Site and according to the Significant Sand and Gravel Aquifer Map of the West Rockport Quadrangle, Maine (Weddle, 2009), the Site is not underlain by a mapped significant sand or gravel aquifer. Based upon the USGS topographical map for the Site and surrounding area, groundwater flow is inferred to be generally south toward the Oyster River.
JN: 10193.050 4 Phase II ESA – 2287 Camden Road Warren, Maine
3.3 Site History Based upon observations made during the Site visit and information supplied by the MDEP from previously completed investigations, it has been determined that within the last 30 years, the Site has been occupied by a retail firearms store. This facility included both an indoor firing range (IFR) and outdoor firing range (OFR). In addition, a photographic laboratory was in operation for a short period of time on the Site during this time period. According to the results of previous Phase I Environmental Site Assessments (ESAs) conducted at the Site, the firing ranges began operation sometime during the 1970s. As a portion of its use as a firearm sales business (RD Outfitters), two firing ranges were developed on the Site. The IFR was located within the main building. The OFR was located east of the main building within a raised berm area and was originally designed as a 600-meter shooting range but was later converted to a shorter (approximately 100-meter) range. A small room within the main building appears to have been used for the manufacture of small quantities of ammunition, based upon the presence of tools and supplies associated with this practice, including several lead ingots. To lessen the sound of the shooting range and to absorb ammunition fragments, the current owner began accepting waste material from Gates Formed-Fiber in Auburn, Maine in 1997 to create berms with this material. The MDEP approved the use of fiber material in a Solid Waste Beneficial Reuse Permit issued in 1997. The material consists of a non-woven fabric used to manufacture automobile trunk liners. Currently, approximately 25% of the Site is covered by berms of this waste fiber material. A Phase I ESA completed by Summit Environmental Consultants, Inc. (Summit) in 2007 estimated that approximately 254,000 square feet (SF) of fiber is present at the Site. The berms are in various stages of completion, ranging from uncovered to completely covered and vegetated. It is unknown if the berms, used as bullet stops, were ever cleaned to remove spent bullets and associated fragments. The MDEP did require that spent bullets and associated fragments be collected annually as a condition of the 1997 MDEP Solid Waste Beneficial Reuse Permit. According to previous Site investigations, a small room within the main building, which was used to make ammunition, was also used, at one time, as a photographic laboratory for the development of school photographs. MDEP records indicate that approximately 20 rolls of black and white film were processed in this laboratory on a yearly basis with silver recovery done on the property. Documentation of this and the removal of the actual silver recovery units at the end of the laboratory’s usage could not be verified during the previous investigations.
3.4 Previous Investigations Summit Environmental Phase I ESA: Summit completed a Phase I ESA for the Site dated July 27, 2007. The following Recognized Environmental Conditions (RECs), Historical Recognized Environmental Conditions and/or De Minimis Conditions were identified at the Site:
◆ Fiber materials from Gates Formed Fiber were brought to Site for use in the construction of sound reduction and bullet stop berms. Approximately 254,000 square feet of fiber was present on the property. The presence of this material was currently in violation with the conditions of the MDEP’s Solid Waste License #S-21758-WL-A-N.
JN: 10193.050 5 Phase II ESA – 2287 Camden Road Warren, Maine
◆ Photographic chemicals were disposed to the on-Site septic tank during the operation of a photographic laboratory on the Site.
◆ An IFR was operated inside of the Office Building. Contamination associated with this usage, including lead dust and bullet fragments may be present within the IFR.
◆ The operation of OFRs operated on-Site may have resulted in the presence of lead contaminated soils and bullet fragments within the range area and in the bullet stop berms.
◆ Ammunition manufacturing within the room of the Office Building may have resulted in the presence of lead contamination, associated with the melting of lead ingots, on the surfaces within this room.
Summit made the following recommendations based on the results of the Phase I ESA:
◆ Perform a Phase II ESA, including a subsurface investigation of soil including areas within the OFR at the Site as well as laboratory analysis of groundwater samples collected from on-site monitoring wells to determine if former Site activities (firing range and photo lab) have impacted Site soil and groundwater.
◆ Due to on-site usage of photochemicals, lead, and solvent-based cleaners, a water sample should be collected from the water supply well at the Site for laboratory analysis of volatile organic compounds (VOCs), semivolatile organic compounds (SVOCs), total Resource Conservation and Recovery Act (RCRA) metals.
◆ Prior to reuse of the Office Building, lead sampling should be performed to determine if it is suitable for habitation.
◆ Submit a plan for the finalization of the Gates fiber berms to the MEDEP’s Solid Waste Bureau to address the violations incurred by Steamship Navigation.
◆ Summit recommends that the future property owner apply to the MEDEP Voluntary Response Action Program (VRAP).
Summit Environmental Phase II ESA: Summit completed a Phase II ESA for the Site dated October 29, 2007. The purpose of the Phase II ESA was to characterize surface and subsurface soil at the Site to determine if these soils have been impacted by historical use of the Site as a firing range and photographic laboratory. Summit performed the following investigations as part of the Phase II ESA: ◆ Advancement of soil borings in 12 locations and installation and development of two
monitoring wells to characterize groundwater at the Site.
◆ Collection of groundwater samples from each of the two temporary monitoring wells installed at the Site.
◆ Collection of a sample from the on-Site drinking water well.
◆ Collection of seventeen lead wipe samples to determine whether impacts were present within the Office Building.
◆ Collection of one soil sample from one of the twelve soil borings advanced at the Site.
◆ Collection of six surficial soil samples at the Site.
◆ Screening of soil samples collected on-Site with an X-Ray Fluorescence (XRF) device to determine total metals levels.
JN: 10193.050 6 Phase II ESA – 2287 Camden Road Warren, Maine
Elevated concentrations of lead, above the MDEP RAGs for the Outdoor/Construction Worker, were identified in four of the seven soil samples submitted for laboratory analysis. Soil samples with elevated lead concentrations were all collected from the area surrounding the IFR. In addition, arsenic concentrations above the Outdoor/Construction Worker RAG were identified in three of the seven soil samples submitted for analysis. Groundwater analytical results from the two temporary monitoring wells and the on-site water supply well did not report concentrations of any metals, Volatile Organic Compounds (VOCs) or Semi-Volatile Organic Compounds (SVOCs) at concentrations above the MEGs. Summit made the following recommendations based on the results of the Phase II ESA:
◆ Apply to the MDEP Voluntary Response Action Program (VRAP) to obtain a release of liability for the property.
◆ If the main building is to be reused, a thorough cleaning/decontamination will be required for the entire building to remove lead debris and lead dust to allow for occupancy.
◆ If the main building is to be demolished, lead fragments should be removed from the backstop and a sample of the concrete backstop within the indoor firing range should be collected to determine if leachable lead exists within it.
◆ Encapsulate or remove and properly dispose of lead-impacted soils above the MDEP RAGs for Adult Workers.
◆ Prior to renovation/demolition of the buildings, an asbestos-containing materials (ACM) survey should be performed.
◆ Hazardous materials (paints, lead ingot, spent shells, live shells), Universal Waste, and petroleum products should be removed from the Site and disposed of properly.
◆ Although the fiber bales do not present a contaminant risk, they present a
regulatory challenge, as well as a potential fire hazard. Therefore, the bales should
be removed or covered as initially permitted by the MDEP Solid Waste Division.
Beacon Environmental Consultants Phase I ESA: Beacon Environmental Consultants, LLC (Beacon) completed a Phase I ESA for the Site dated June 5, 2018. The following RECs were identified during completion of the Phase I ESA:
◆ The property was listed in 2007 as a Solid Waste Facility with licenses held by Steamship Navigation and Cascade Fiber;
◆ Past usage of the property as a firing range, photographic lab, and solid waste dumping of fiber bales;
◆ Past environmental reports indicated environmental issues with the property;
◆ Lead dust and small quantities of hazardous substances are present within the Site structure;
◆ Significant lead dust and bullet fragments are present within the Site structure based on past sampling and analysis. Additional sampling should be performed to determine disposal options.
◆ A sump is located within the IFR. No pump was present, and the discharge of this sump is not known;
JN: 10193.050 7 Phase II ESA – 2287 Camden Road Warren, Maine
◆ Significant solid waste dumping of fiber bales has occurred on the property. Additionally, a landfill of these bales was established to the northeast of the Site structures in the late 1990’s; and
◆ Distressed vegetation was observed in areas of bales of fiber. The following data gaps were identified by Beacon during completion of the Phase I ESA:
◆ Location/presence of a septic leach field associated with the septic tank is unknown;
◆ Due to the unsafe nature of the roof of the garage, this structure was not entered; and
◆ Dates of the photographic laboratory's operations on the Site could not be specifically identified.
Beacon made the following recommendations based on the results of the Phase I ESA: ◆ A Phase II ESA should be completed on the property to determine the presence of
ACM, LBP, lead concentrations within the firing (including the backstop), identification of the location/presence of a septic leach field and whether impacts are present within it, and additional soil samples to determine potential impacts from past usage of the property.
◆ A plan should be developed to complete the covering of the fiber bales or their removal to comply with past MDEP Notices of Violations (NOVs).
Maine Department of Environmental Protection PFAS Investigation On May 10 and 11, 2018, the MDEP collected soil, pore water, and drinking water samples at the Site for Per- and Polyfluoroalkyl Substances (PFAS) analysis as part of ongoing department investigation of potential PFAS Sites in the State of Maine. The investigation included the collection of 13 soil samples, six pore water samples, and one water sample from the on-site drinking water well. Results of the investigation identified four soil samples and four pore water samples containing PFAS in exceedance of the 2018 MDEP RAGs. In addition to the collection of analytical samples, a borehole geophysical survey was performed in the on-site well by Northeast Geophysical Services, Inc. (NGS) on May 10, 2018. The well is located immediately adjacent to the west side of the former retail business structure and was found to be 102 ft in depth with approximately 20 ft of overburden casing installed. The depth to water was measured at 5.36 ft below the top of casing (TOC) at the time of the survey. The well was logged for fluid temperature, fluid resistivity, borehole caliper, optical and acoustic televiewer, and heat pulse flowmeter. Results indicated a likely transmissive zone from 33 to 35 ft below TOC with a possible transmissive zone from 91 to 94 ft below TOC. Information from the borehole caliper and heat pulse data under pumping conditions indicated that the shallow interval (33 to 35 ft below TOC) was most likely the interval with the greatest contribution of water to the well.
JN: 10193.050 8 Phase II ESA – 2287 Camden Road Warren, Maine
SECTION 4 | FIELD SAMPLING PROGRAM 4.1 Utility Clearance and Surface Geophysical Survey
CES completed a DigSafe non-member utility notification and utility marking for proposed drilling locations as selected by MDEP on August 16, 2018 during a Site meeting between Chris Buckman of CES and Richard Currie and Sean Dougherty of the MDEP. Locations were selected based on waste type (e.g. baled material, short paper fiber, covered material), access, and location relative to previously collected soil, groundwater, and porewater samples. In addition to DigSafe notification and utility markout, CES performed ground-penetrating radar (GPR) surveying over accessible portions of the Site to determine the approximate depth to bedrock. Due to the requirements of the GPR antenna to remain in contact with the ground surface to ensure accurate profile information, CES defined “accessible” as areas of existing roadways and driveways that did not require preparation prior to data collection. These areas included a total of approximately 3,360 lineal feet of profile and are identified accordingly on Figure 1. Depths to bedrock were interpreted from collected profile data with corresponding coordinates and depths below ground surface (bgs) located in Table 1.
Based on tests performed in the field between a 270 MHz and a 400 MHz antenna, it was determined that a 400 MHz GPR antenna provided the requisite depth of signal penetration and desired resolution to meet the objective. The test was performed in an area of exposed bedrock located east of the Site buildings and within the center of the outdoor firing range berm. It was interpreted that the depth to bedrock varied between 0 feet BGS and 5 ft BGS, with depths confirmed with depths to refusal encountered during the direct push sampling investigation.
4.2 Direct Push Soil Borings
On August 20, 2018, Michael Deyling with CES mobilized to the Site to clear boring locations of waste material using an excavator under the supervision of Richard Currie with the MDEP. MDEP personnel directed Mr. Deyling to clear waste from 10 predetermined locations at the Site, as shown on the Site Plan (Figure 1), to allow access by the direct push rig to underlying soil. These locations were selected to include each type of waste material present at the Site. On August 23, 2018, CES mobilized to the Site to perform direct push soil sampling activities. CES advanced a total of ten soil borings utilizing Geoprobe® direct-push equipment. Soil borings were advanced at the following locations:
◆ Five borings below exposed baled material (BM) in two areas (DPT-01, DPT-02, DPT-03, DPT-04, and DPT-07);
◆ Two borings below covered Short Paper Fiber (SPF) material (DPT-05 and DPT-06); and
◆ Three borings below the covered material (CM) area (DPT-08, DPT-09, and DPT-10).
JN: 10193.050 9 Phase II ESA – 2287 Camden Road Warren, Maine
Each boring was completed to refusal, which was encountered at depths ranging from ground surface (DPT-04) to 14 feet BGS (DPT-02). Soil samples were collected in acetate sleeves in four-foot intervals and characterized in the field. Typical subsurface soils encountered were classified as sandy to rocky fill in each of the soil boring locations with several locations terminating on waste that included short paper fiber or formed fiber upholstery material. Boring locations are illustrated on the Site Plan (Figure 1) with completed soil boring logs included as Appendix A. Soil samples were visually inspected for the presence of waste material, staining or other evidence of potential environmental impacts. A total of 16 soil samples from the 10 soil borings were selected for laboratory analysis based on field observations and/or location with an additional two duplicate samples collected for submittal to Vista. All collected samples were submitted to Vista for laboratory analysis for the presence of PFAS compounds using USEPA method 537M by isotope dilution. Results of the laboratory analysis are discussed in Section 6.2.
4.3 Monitoring Well Installation and Sampling On August 23, 2018, CES completed two of the direct push sample locations (DPT-02 and DPT-09) as one-inch temporary microwells TW-1 and TW-2, respectively. TW-1 was installed to a depth of approximately 12 ft BGS and was constructed with 10 feet of 0.010-inch slotted PVC well screen and five feet of PVC riser. A fine silica sand filter was installed to a depth of one ft BGS followed by a bentonite seal to ground surface. TW-2 was installed to a depth of approximately 7.9 feet BGS and was constructed with five feet of 0.010-inch slotted PVC well screen and five feet of PVC riser. A fine sand filter was installed to a depth of two feet BGS followed by a bentonite seal to ground surface. After installation, each temporary well was developed utilizing a peristaltic pump until purge water was visually clear. Following the initial development, groundwater did not appear to recharge at TW-1. CES returned to the Site on August 28, 2018 to sample the newly installed monitoring wells. Groundwater was not present in TW-1; therefore, the well was not sampled. Temporary well TW-2 was pumped dry after approximately 10 minutes of purging. The pump was stopped, and the well was allowed to recharge for approximately 20 minutes. CES collected a groundwater sample from TW-2 and submitted the sample to Vista for analysis of PFAS.
4.4 Multi-Increment Soil Sampling
On September 28 and 30, 2018, CES conducted surface soil sampling around three types of identified waste material, as selected by MDEP, using Incremental Sampling Methodology (ISM) in accordance with MDEP standard operating procedure (SOP) RWM-DR-015 Incremental Sample Methodology for Site Investigation and Risk Assessment. The three areas selected by MDEP were designated as Covered Waste (CW), Short Paper Fiber (SPF) and Baled Material (BM) based on the material within the pile being sampled.
JN: 10193.050 10 Phase II ESA – 2287 Camden Road Warren, Maine
Prior to mobilization, GIS software was used to divide the surface soil sampling areas into two zones, one from zero to 10 feet (inner zone) of the edge of the designated pile (Zone A) and the second between 10 and 20 feet (outer zone) from the edge of the designated pile (Zone B). Each zone was divided into a 30-cell grid and further divided into nine cells of equivalent area, which were assigned a number 1-9. A random number generator was used to select one of the nine sub-cells for sampling with a surface soil aliquot to be collected from the center of each designated cell. The GPS coordinates of each aliquot location were then stored in the GPS for use by field personnel. Replicate aliquots were collected six inches from the primary sample in Zone A. Replicate aliquots were not collected in Zone B. Figures 2 through 4 depict the locations of the sample aliquots collected by CES during this investigation. In total, approximately 80 percent of locations were able to be sampled within the baled material, 57 percent within the short paper fiber, and 100 percent within the covered material investigation areas. Upon field inspection, several of the pre-selected GPS locations were not able to be sampled due to waste material or other obstruction present in the location. Efforts were made to relocate the sample; however, there were several site-specific conditions that prevented repositioning. These conditions included, but were not limited to exposed bedrock, location in an area of comingled waste containing more than one type, and extensive limits of waste outside areas of sampling. The following changes were made to the aliquot locations based on conditions at the time of sampling: Baled Material:
◆ Samples BM-I-1, -02, and -30 were not collected as they were located on the gravel road. Movement of the samples to a representative area off the gravel drive would have resulted in a location within another sampling grid.
◆ Samples BM-I-27, -28 and -29 were located in areas of short paper fiber. BM-I-27 was moved to a location approximately five feet from the edge of the pile where waste material as not present. Locations BM-I-28 and -29 were not collected due to amount of SPF waste material present.
◆ Sample BM-I-08 was not collected as the location was determined to be under baled material.
◆ BM-O-28 and BM-O-29 were located in areas where SPF was present. BM-O-28 was moved to a location approximately 15 feet from the edge of the baled material where SPF was not present. Aliquot BM-O-29 was not collected as moving the location would put it in the road and outside of an area believed to be representative of the requisite conditions for sampling.
◆ BM-O-02 and BM-O-08 were not collected as they were located under waste material.
◆ Sample BM-O-11 was located on top of a bedrock outcrop and was not collected. Movement of the sample to a representative area off the bedrock outcrop would have resulted in a location within another sampling grid.
Short Paper Fiber:
◆ SPF-I-09 and -10 were moved approximately five feet from the edge of the waste pile into a location within Zone A.
◆ SPF-I-25, -27 through -30 and -1 through -8 were located within waste material and could not be relocated due to extensive waste present in the area.
◆ SPF-O-01 through -09, -20, -24, -29, and -30 were located in waste material and could not be moved due to extensive waste present in the area.
JN: 10193.050 11 Phase II ESA – 2287 Camden Road Warren, Maine
◆ SPF-O-10 was originally located in waste material and was moved approximately 15 ft from the interpreted edge of the waste pile into Zone B.
Covered Waste: ◆ CW-I-15, -16, -19, -20, -21. -22, -27, -28, and -29: Original locations were on a
slope of covered waste material. Locations were adjusted 5 feet beyond the toe of the slope into Zone A.
◆ CW-O-17, -18, -20. -21, and -22: Original locations were on a slope of covered waste material. Locations were adjusted 15 feet beyond the toe of the slope into Zone B.
Each sample aliquot was collected from zero to four inches (0-10 cm) BGS using a stainless-steel increment soil sampler which was decontaminated between sampling areas in accordance with MDEP RWM-DR-017 Equipment Decontamination Protocol, with provisions made to avoid use of any potential PFAS-containing materials. Collected aliquots were placed in a stainless-steel bowl and mixed until homogenous. A total of nine composite soil samples, comprised of six primary samples and three replicates, were submitted to Vista for analysis of PFAS by USEPA Method 537M and in accordance with MDEP SOP DR-012 Chain of Custody Protocol. In addition, field blanks were collected from the decontaminated stainless-steel samplers and bowls for PFAS analysis after the completion of surface soil sampling activities using laboratory-supplied PFAS-free water.
4.5 Surface Soil XRF Screening
On August 29, 2018, CES performed soil screening at the Site for metals using an Olympus Delta 4000 X-Ray Fluoroscope (XRF). Soil was screened in three areas including the Indoor Firing Range (IFR), a spent ammunition lead pile located to the west of the IFR between the building and wooded area, and a mobile home-style trailer believed to have been formerly used as a photography studio based on Phase I ESAs completed by others. The IFR screening locations were comprised of four individual openings to the structure and included two doors, a window, and wall-mounted exhaust fan. Surface soil samples (0-4”) were collected in Ziploc bags using a stainless-steel hand auger; however, efforts were made in the area surrounding the lead pile to sample at a depth of up to 8 inches, but shallow surface soils limited sampling depths. Following collection, each bag was screened using the XRF. Concentrations of lead and silver (Table 2) were recorded for samples around the trailer with remaining locations screened for lead only. A summary of the XRF screening data is included on Table 2 with sample location figures with screening values for lead presented in Figure 5 through Figure 7. After the completion of XRF screening, CES collected and submitted seven confirmation soil samples based on the highest screening levels observed. The collected samples included four from the IFR, two from the trailer, and one from the “lead pile”. Soil samples were sent to Alpha Analytical (Alpha) for laboratory analysis of eight Resource Conservation and Recovery Act (RCRA) metals. Surface soil analytical results are summarized in Section 6.3.
JN: 10193.050 12 Phase II ESA – 2287 Camden Road Warren, Maine
SECTION 5 | QUALITY ASSURANCE / QUALITY CONTROL Quality assurance and quality control (QA/QC) samples were collected in accordance with the July 27, 2018 proposal to MDEP. A total of one duplicate (DUP) per 10 samples and one matrix spike/matrix spike duplicate (MS/MSD) per 20 samples were proposed for sub-surface soil samples. There were no duplicates collected or submitted for groundwater or surface soil samples; however, replicate samples were collected as part of the multi-increment sampling effort as detailed below. All data, as qualified and presented in Table 3 through Table 5, are acceptable for use based on supplied laboratory case narratives (Appendix B). 5.1 Sub-Surface Soil
Based on the number of soil samples collected (16), a total of two duplicate samples were submitted for QA/QC purposes with reported concentrations between samples being within acceptable limits. An MS/MSD was performed on sample DPT-05 (5-6). As stated by Vista in their analysis of data for the submitted samples, the MS/MSD recoveries and relative percent differences (RPDs) were within the method acceptance criteria. A Method Blank and Ongoing Precision and Recovery (OPR) sample were extracted by Vista and analyzed with the preparation batch for the original samples and one for the re-extractables. There were no analytes detected in either Method Blank above one half the Limit of Quantification (LOQ). Recoveries for the OPR samples were within the method acceptance criteria for both OPRs.
5.2 Groundwater
Only one groundwater sample was collected, therefore no QA/QC samples were submitted for analysis, as per stated QA/QC sampling criteria. Dedicated equipment was used in the collection of the groundwater sample and did not require the collection of an equipment rinsate blank.
5.3 Multi-Increment Samples
A replicate sample was submitted for each inner zone (Zone A) sample collected (a total of 3 samples) with no replicate samples collected for the outer zone (Zone B), as dictated in the CES scope of work. In addition to replicate samples, equipment blank samples were submitted for the decontaminated stainless-steel sampler and bowl (two total) following the completion of surface soil sampling activities.
5.4 Surface Soil
As only seven surface soil samples were submitted for analysis, no QA/QC samples were collected as part of this investigation task. All samples were received by the laboratory in accordance with the chain of custody and no significant deviations were encountered during sample preparation or analysis.
SECTION 6 | EVALUATION AND PRESENTATION OF RESULTS 6.1 Subsurface Soils
A total of 16 subsurface soil samples were collected and submitted for laboratory analysis from 10 direct push subsurface locations as illustrated on Figure 1 with reported results for 26 PFAS compounds presented on Table 3. Samples were identified based on DPT boring location (DPT-XX) and depth interval in feet BGS (X-X). Subsurface soils were collected from each of the three waste material areas and included baled material (BM), short paper fiber (SPF), and covered material (CM). Soil results were compared to the MDEP RAGs for Sites Contaminated with Hazardous Substances (MDEP, 2018) for
JN: 10193.050 13 Phase II ESA – 2287 Camden Road Warren, Maine
PFOS, PFOA, and PFBS leaching to groundwater criteria. RAGs for PFOS, PFOA, and PFBS are 21 ng/g, 9.5 ng/g, and 7,100 ng/g respectively. Direct push sampling locations for the characterization of BM impacts to soil included DPT-01, -02, -03, -04, and -07. Locations DPT-01 and -02 were located adjacent to BM within the west/southwest portions of the Site with DPT-03 and -04 located near BM in the southeast. Location DPT-07 was in the center of the Site and positioned between CW material to the north and SPF to the south. Temporary microwell TW-01 was installed at DPT-02; however, did not contain enough water following development to obtain a groundwater sample. No samples were submitted from DPT-04 due to the presence of bedrock immediately below the ground surface. Analytical results for soil samples submitted for analysis of PFAS in the characterization of the BM area did not detect concentrations of PFOA, PFOS, or PFBS above applicable RAGs. Most samples resulted in remaining PFAS compounds at concentrations of not detected (ND) with values representative of being less than their respective detection limit (DL). DPT-01 (3-4), DPT-01 (7-8), DPT-01 (7-8) DUP, DPT-03 (3-4), and DPT-07 (0-1) contained levels of PFOS ranging from 2.66 ng/g at DPT-01 (7-8) DUP to 12.1 ng/g at DPT-07 (0-1). Detections of PFOS at DPT-01 were similar to those reported by the MDEP at soil borings SS-11 and SS-12 completed during their May 2018 investigation. PFOA was only detected in DPT-07 (0-1) with PFBS at ND levels within all samples submitted for soil characterization at BM locations. In general, analytical results for PFOS near BW locations were similar to those reported by the MDEP at nearby locations. For example, detections of PFOS at DPT-03 and DPT-07 were similar to MDEP results at locations SS-4 and SS-7, respectively.
Soil underlying CW material were sampled at direct push locations DPT-08, -09, and -10. A temporary microwell (TW-2) was installed in DPT-09 following advancement to refusal. A total of six samples were submitted for laboratory analysis from these three locations with results of ND for all PFAS compounds analyzed. Though DPT locations completed near CW piles were below detection limits, results as reported by the MDEP at SS-1 (May 2018) were at 1.9 ng/g combined for PFOS and PFOA. DPT-05 and DPT-06 were advanced along the northeast edge of the SPF waste material. A total of three samples (two primary and one duplicate) were submitted for analysis; however, these samples were from DPT-05 only due to the presence of subsurface SPF waste material at DPT-06. No detections of PFAS were present at DPT-05 (5-6) or DPT-05 (5-6) DUP; however, soil collected at DPT-05 (8-9) detected of both PFOS and PFOA. Though not above the applicable RAG, PFOS was detected at a level of 13.1 ng/g with PFOA at 1.04 ng/g, slightly above the DL at DPT-05 (8-9). In general, there was consistency between the values for PFOS and PFOA reported during this Phase II ESA and those reported by the MDEP during their May 2018 sampling investigation. Though some sampling locations were not identical between the two investigations, similarity in concentrations were present.
6.2 Groundwater
Following the installation and development of temporary microwells TW-1 and TW-2, an overburden groundwater sample was collected only from TW-2 due to insufficient water volume in TW-1 following development. The groundwater sample from TW-2 detected PFOS and PFOA at concentrations above the MeCDC MEG. The MEG is 70 ng/L for each compound or 70 ng/L combined when both PFOS and PFOA are found together.
JN: 10193.050 14 Phase II ESA – 2287 Camden Road Warren, Maine
PFOS and PFOA were reported at 88.0 ng/L and 88.6 ng/L, respectively. These results are consistent with those obtained by MDEP in a shallow porewater sample (PW-1) collected 600 feet south and downgradient of TW-2 during the May 2018 investigation. There were no additional groundwater samples collected as part of this Phase II ESA; however, groundwater was sampled by the MDEP from the on-site drinking water supply well located 380 feet west of TW-2 during the May 2018 investigation. Though PFOS (3.6 ng/L) and PFOA (13.4 ng/l) were both detected in the sample submitted to Vista, concentrations were below the MEG. Concentrations in the supply well are believed to be lower due to the source of water (overburden versus bedrock) and location up and cross gradient relative to stockpiled source material.
6.3 Multi-Increment Samples Multi-increment sampling (MIS) was completed at each of the three waste types (BM, SPF, and CW) within two zones (Zones A and B). Each inner zone (Zone A), located 0-10 ft from base of waste material, was comprised of a primary sample with a replicate. The outer zone (Zone B) was located 10-20 ft from base of waste material and did not include a corresponding replicate sample. This resulted in a total of nine samples being collected and submitted for analysis of PFAS. Results were compared to the MDEP Maine Remedial Action Guidelines (RAGs) for Sites Contaminated with Hazardous Substances (MDEP, 2018) for PFOS, PFOA, and perfluorobutanesulfonic acid (PFBS) leaching to groundwater criteria. The RAGs for PFOS, PFOA, and PFBS are 21 nanograms/grams (ng/g), 9.5 ng/g, and 7,100 ng/g, respectively. Baled material (BM) samples detected PFOS within both the inner Zone A (23.6 ng/g) and outer Zone B (21.5 ng/g) samples at concentrations above the RAG, with the Zone A replicate (17.7 ng/g) being slightly below the RAG. Of the three waste types investigated, SPF had the highest concentrations of PFAS, specifically PFOS and PFOA. The primary and replicate samples from Zone A of the SPF investigation area had concentrations above the RAG for PFOS at 61.9 ng/g and 67.6 ng/g, respectively, with the Zone B sample having a reported PFOS concentration of 42.4 ng/g, approximately twice the RAG of 21 ng/g. PFOA concentrations were below the applicable RAG within Zone A and Zone B with concentrations of PFBS being reported below the DL. No samples collected within Zone A or Zone B from the CW investigation area resulted in PFOA and PFBS at results above the DL. Detections of PFOS were reported at between 0.851 ng/g (Zone B) and 1.16 ng/g (Zone A). These results are believed to be typical with higher concentrations nearer the waste material and decreasing with increasing distance away from identified waste. Results for equipment blanks were below the detection limit for all PFAS compounds reported by Vista.
6.4 Surface Soil
A total of seven surface soil samples were submitted to Alpha for analysis of RCRA 8 metals based on XRF screening results performed on August 29, 2018. The samples consisted of four from the IFR, two from the former photo-processing trailer (TR), and one from the spent ammunition “lead pile” (LP). As the Site may be redeveloped in the future, the construction worker MDEP RAG of 450 milligrams per kilogram (mg/kg) was used in
JN: 10193.050 15 Phase II ESA – 2287 Camden Road Warren, Maine
the evaluation of exceedances. Soil samples collected near the IFR included one from each of four openings to the exterior as illustrated on Figure 5. Analytical samples collected along the east side of the IFR included IFR-17 (adjacent to existing doorway that entered the IFR) and IFR-27 (adjacent to the doorway that accesses the storage room located behind and south of the IFR) where XRF screening values for lead were 4,376 mg/kg and 4,044 mg/kg, respectively. Confirmatory laboratory results for these samples, as reported by Alpha, were 2,850 mg/kg and 5,290 mg/kg, respectively. Lead concentration in both samples exceeded the construction worker RAG of 450 mg/kg. Soil samples collected along the west side of the IFR were collected adjacent to a wall-mounted exhaust fan for the IFR (IFR-4) and window to the storage room (IFR-5). Sample IFR-4 detected lead at a concentration of 542 mg/kg, above the MDEP RAG. Alternatively, sample IFR-5 detected lead at a concentration of 315 mg/kg, below the applicable RAG. These results are consistent with anticipated exposure to lead dust from the IFR relative to the size of opening and proximity/connection to the former IFR. Wipe samples, as collected by Summit during the 2007 Phase II ESA, detected the highest lead concentrations at the IFR floor and on exhaust fan blades.
A total of 36 locations were field-screened with an XRF for lead and silver around the trailer (Figure 6) believed to have been a location where photo-processing was performed. Two soil samples were submitted to Alpha for RCRA 8 metals analysis. Screening locations TR-5 and TR-15 contained the highest XRF screening values of 40 mg/kg and 80 mg/kg for lead, respectively, with field screening for silver reported as not detected (ND). Confirmatory soil samples submitted to the laboratory for these two locations detected lead at concentrations of 6.96 mg/kg (TR-5) and 17.6 mg/kg (TR-15), respectively, below the applicable RAG. Silver concentrations being reported as ND, or below the DL for both locations. Screening locations around the spent ammunition waste lead pile were positioned, due to exposed bedrock, to account for the flow of precipitation as surface water towards and across the visible spent lead fragments. A total of 18 XRF screening locations were completed with a confirmatory soil sample submitted to the laboratory for analysis of lead from LP-13B (Figure 7). Location LP-13 was screened via XRF twice (LP-13 and LP-13B) due to the high amount of lead recorded by the instrumentation (1.66% and 5,160 mg/kg). Analytical results detected lead at a concentration of 9,760 mg/kg, approximately 20 times the current construction worker RAG.
SECTION 7 | CONCLUSIONS Soil and groundwater samples collected as part of this Phase II ESA were intended to identify and evaluate the potential risk to receptors within the area of investigation. Based on the observations made during field activities, field screening, and laboratory analysis of submitted soil and groundwater samples, evidence of PFAS impacts above applicable remediation action guidelines were identified at several areas within the Site. These results correlate with the findings of the investigation completed by MDEP in May 2018. Subsurface soil samples collected for PFAS analysis from DPT borings did not result in concentrations above applicable leaching to groundwater RAGs and would indicate that limited risk exists within shallow subsurface soils. Despite there being limited evidence to suggest a significant risk within subsurface soils, concentrations of PFOS above applicable RAGs within surface soils around baled waste material and short paper fiber suggests that some risk may be
JN: 10193.050 16 Phase II ESA – 2287 Camden Road Warren, Maine
present within these areas for leaching to groundwater. Data collected from shallow groundwater during this investigation and from porewater samples collected by the MDEP during their May 2018 sampling indicates that PFAS compounds have impacted overburden groundwater. However, based on limited information available for PFAS compounds in existing drinking water wells adjacent to the Site, it is unknown if risk to receptors are present. Lead in soil was found to be above the applicable RAG for a construction worker to soils sampled around the former IFR and the spent ammunition waste lead pile located west of the office building. These levels represent an elevated risk to the applied RAG; however, final Site remediation alternatives and objectives were not known at the time of this report.
SECTION 8 | REFERENCES
The following sources of information and published references were relied upon in preparing this
Phase II ESA:
Maine Remedial Action Guidelines for Sites Contaminated with Hazardous Substances (MDEP,
October 19, 2018).
Phase I Environmental Site Assessment, Steamship Navigation, 2287 Camden Road, Warren,
Maine (Beacon Environmental Consultants, June 5, 2018)
Phase I Environmental Site Assessment, RD Outfitters, 2287 Camden Road, Warren, Maine
(Summit Environmental Consultants, Inc., July 31, 2007)
Phase II Environmental Site Assessment, RD Outfitters, 2287 Camden Road, Warren, Maine
(Summit Environmental Consultants, Inc., September 7, 2007)
SURFACE SOIL SAMPLINGLOCATION GRID
ZONE A SURFACE SOILSAMPLING LOCATION
ZONE B SURFACE SOILSAMPLING LOCATION
0 FT 100 FT
STEAMSHIP NAVIGATION2287 CAMDEN ROAD, WARREN, MAINE
SHORT PAPER FIBERSURFACE SOIL SAMPLING LOCATIONS
FIGURE 3
0 100
1 INCH = 50 FEET
SURFACE SOIL SAMPLINGLOCATION GRID
ZONE A SURFACE SOILSAMPLING LOCATION
ZONE B SURFACE SOILSAMPLING LOCATION
LP-1(613)
LEAD PILE
LP-2(993)LP-7
(120)
LP-8(273)
LP-3(2513)
LP-4(362)
LP-9(847)
LP-11(179)
LP-5(648)
LP-6(809) LP-14
(846)
LP-13(1.66%)
LP-16(133)
LP-17(1935)
LP-18(409)
LP-12(3808)
LP-15(316)
BUILDING
LP-13B(5160) [9670]
LP-10(149)
XRF SCREENING LOCATION
LEGEND
TOTAL LEAD IN mg/kg VIAXRF SCREENING(273)
TOTAL LEAD IN mg/kg VIAMETHOD 6010D[9670]
(LP-2)
DATE:
BY:
REV DATE:
REV:
SCALE:
DWG:
JN:
Engineers Environmental Scientists Surveyors
STEAMSHIP NAVIGATION SITE
WARREN MAINE
XRF SCREENING LOCATIONS
LEAD PILE
FIGURE 710193.050
1"=10'
BLQ
2018-10-09
TRAILER
TR-1(19)
TR-2(21)
TR-3(12)
TR-4(20)
TR-5(40) [6.96]
TR-6(23)
TR-7(22)
TR-8(19)
TR-9(21)
TR-10(19)
TR-11(12)
TR-12(19)
TR-13(13)
TR-14(20)
TR-15(80) [17.6]
TR-16(38)
TR-17(14)
TR-18(69)
TR-19(17)
TR-20(12)
TR-21(16)
TR-22(11)
TR-23(12)
TR-24(12)
TR-25(19)
TR-26(22)
TR-27(ND)
TR-28(11)
TR-29(ND)
TR-30(22)
TR-31(14)
TR-32(15)
TR-33(11)
TR-34(16)
TR-35(14)
TR-36(9)
XRF SCREENING LOCATION
LEGEND
TOTAL LEAD IN mg/kg VIAXRF SCREENING(21)
TOTAL LEAD IN mg/kg VIAMETHOD 6010D[40]
(TR-2)
DATE:
BY:
REV DATE:
REV:
SCALE:
DWG:
JN:
Engineers Environmental Scientists Surveyors
STEAMSHIP NAVIGATION SITE
WARREN MAINE
XRF SCREENING LOCATIONS
TRAILER
FIGURE 610193.050
1"=10'
BLQ
2018-10-09
INDOOR FIRING RANGE
IFR-1(307)
GR
AVEL DR
IVEIFR-2(15)
IFR-4(650) [542]
IFR-11(647)
IFR-6(240)
IFR-5(488) [315]
IFR-8(92)
IFR-7(55)
IFR-9(194)
IFR-3(543)
IFR-10(145)
IFR-16(280)
IFR-13(1823)
IFR-11(12)
IFR-14(3020)
IFR-19(42)
IFR-25(1147)
IFR-22(701)
IFR-17(4376) [2850]
IFR-12(1819)
IFR-20(3159)
IFR-29(304)
IFR-26(2628)
IFR-23(233)
IFR-30(180)
IFR-24(446)
IFR-28(1893)
IFR-27(4044) [5290]
IFR-21(466)
IFR-15(575)
IFR-18(180)
XRF SCREENING LOCATION
LEGEND
TOTAL LEAD IN mg/kg VIAXRF SCREENING(15)
TOTAL LEAD IN mg/kg VIAMETHOD 6010D[315]
(IFR-2)
DATE:
BY:
REV DATE:
REV:
SCALE:
DWG:
JN:
Engineers Environmental Scientists Surveyors
STEAMSHIP NAVIGATION SITE
WARREN MAINE
XRF SCREENING LOCATIONS
INDOOR FIRING RANGE
FIGURE 510193.050
1"=10'
BLQ
2018-10-09
TABLE 1
GROUND PENETRATING RADAR DEPTH TO BEDROCK
GPR Transect No. Easting Northing Interpreted Depth to Bedrock (ft)
1 802782.42 176716.99 0.821 802800.23 176688.88 0.821 802818.04 176660.77 1.151 802835.85 176633.24 1.481 802853.66 176605.70 1.671 802889.85 176547.76 1.641 802931.21 176482.37 1.711 802972.57 176419.84 1.641 803016.23 176351.01 1.381 803060.47 176289.63 1.571 803108.60 176223.79 1.481 803154.55 176163.87 1.311 803208.17 176103.32 1.151 803261.79 176041.50 0.981 803328.81 175975.21 0.921 803407.32 175920.40 1.021 803399.02 175835.62 0.891 803382.43 175768.70 0.821 803390.73 175690.94 0.661 803460.94 175621.47 0.621 803507.54 175546.26 0.491 803587.32 175497.18 0.161 803691.37 175530.32 0.151 803759.67 175578.12 0.101 803770.52 175638.04 0.122 802685.97 176562.67 0.982 802672.96 176447.14 1.482 802702.87 176335.49 1.052 802748.37 176225.15 1.712 802780.87 176101.82 2.072 802771.77 175973.31 2.122 802696.37 175870.75 1.622 802630.06 175759.11 1.312 802500.06 175651.36 1.323 802902.87 176681.06 0.233 802988.99 176663.11 0.213 803078.21 176650.74 0.183 803155.66 176602.48 0.133 803223.82 176551.75 0.103 803286.40 176503.49 0.12
TABLE 2
SURFACE SOIL SCREENING AND LEAD IN SOIL RESULTS
SAMPLE ID / DEPTH TR-SS-5 TR-SS-15 IFR-SS-04 IFR-SS-05 IFR-SS-17 IFR-SS-27 LP-SS-13BSoil RAG -
Construction
Worker
UNITS mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg
COLLECTION DATE 8/29/2018 8/29/2018 8/29/2018 8/29/2018 8/29/2018 8/29/2018 8/29/2018
Lead XRF 40 80 650 488 4376 4044 5160 950
Lead 6.96 17.6 542 315 2850 5290 9670 450
Arsenic 6.28 7.63 10.3 12.5 10.8 9.95 20.0 54
Barium 37.7 49.8 34.6 30.1 67.0 38.5 87.2 20,000
Cadmium <0.409 <0.441 <0.436 0.496 0.469 <0.463 2.74 42
Chromium 18.4 28.9 18.9 22.4 23.0 19.3 11.3 46
Silver <0.409 <0.441 <0.436 <0.460 <0.451 0.496 1.02 1,700
Notes:
mg/kg = milligrams per kilogram
XRF = X-Ray Fluoroscope
SURFACE SOILS - METALS ANALYSIS
RAG = Remedial Action Guidelines a presented on Table 1 in the Maine Remedial Action Guidelines for Sites Contaminated by
Hazardous Substances (MDEP, October 19, 2018)
TABLE 3
DIRECT PUSH SUBSURFACE SOIL
PFAS ANALYTICAL RESULTS
MATRIX GROUNDWATER SOIL
SAMPLE ID / DEPTH DPT-08 (cover) DPT-08 (1-2) DPT-08 (4.1-5.1) DPT-09 (0-1.2) DPT-09 (6.9-7.9) TW-2 DPT-10 (1.5-2.2) DPT-01 (3-4) DPT-01 (7-8) DPT-01 (7-8) DUP DPT-02 (1-2) DPT-02 (9-10) DPT-02 (13-14) DPT-03 (0-1) DPT-03 (3-4) DPT-07 (0-1) DPT-05 (5-6) DPT-05 (5-6) DUP DPT-05 (8-9)Leaching to
Groundwater
Commercial
Worker
Park User Construction
Worker
UNITS ng/g ng/g ng/g ng/g ng/g ng/L ng/g ng/g ng/g ng/g ng/g ng/g ng/g ng/g ng/g ng/g ng/g ng/g ng/g
COLLECTION DATE 8/23/2018 8/23/2018 8/23/2018 8/23/2018 8/23/2018 8/28/2018 8/23/2018 8/23/2018 8/23/2018 8/23/2018 8/23/2018 8/23/2018 8/23/2018 8/23/2018 8/23/2018 8/23/2018 8/23/2018 8/23/2018 8/23/2018
PFBA <0.997 <0.993 <0.954 <0.974 <0.982 11.4 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
PFPeA <0.997 <0.993 <0.954 <0.974 <0.982 16.9 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
PFBS <0.997 <0.993 <0.954 <0.974 <0.982 5.62 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 7,100 22,000 4,900 51,000
PFHxA <0.997 <0.993 <0.954 <0.974 <0.982 22.9 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
PFHpA <0.997 <0.993 <0.954 <0.974 <0.982 23.3 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
PFHxS <0.997 <0.993 <0.954 <0.974 <0.982 17.1 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
6:2 FTS <0.997 <0.993 <0.954 <0.974 <0.982 <1.95 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
PFOA <0.997 <0.993 <0.954 <0.974 <0.982 88.6 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 1.17 J <0.973 <0.995 1.04 J 9.5 22 4.9 5.1
PFHpS <0.997 <0.993 <0.954 <0.974 <0.982 3.43 J <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
PFNA <0.997 <0.993 <0.954 <0.974 <0.982 8.23 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
PFOSA <0.997 <0.993 <0.954 <0.974 <0.982 <1.95 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 0.924 J NA NA NA NA
PFOS <0.997 <0.993 <0.954 <0.974 <0.982 88 <0.980 3.55 3.37 2.66 <0.991 <1.00 <0.985 <0.986 4.03 12.1 <0.973 <0.995 13.1 21 22 4.9 5.1
PFDA <0.997 <0.993 <0.954 <0.974 <0.982 5.58 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
8:2 FTS <0.997 <0.993 <0.954 <0.974 <0.982 <1.95 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
MeFOSAA <0.997 <0.993 <0.954 <0.974 <0.982 <1.95 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
EtFOSAA <0.997 <0.993 <0.954 <0.974 <0.982 <1.95 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 4.97 NA NA NA NA
PFUnA <0.997 <0.993 <0.954 <0.974 <0.982 <1.95 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
PFDS <0.997 <0.993 <0.954 <0.974 <0.982 <1.95 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
PFDoA <0.997 <0.993 <0.954 <0.974 <0.982 <1.95 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
MeFOSA <4.98 <4.96 <4.77 <4.87 <4.91 <9.77 <4.90 <4.93 <4.94 <4.96 <4.95 <5.01 <4.92 <4.93 <4.87 <4.83 <4.87 <4.97 <4.93 NA NA NA NA
PFTrDA <0.997 <0.993 <0.954 <0.974 <0.982 <1.95 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
PFTeDA <0.997 <0.993 <0.954 <0.974 <0.982 <1.95 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
EtFOSA <4.98 <4.96 <4.77 <4.87 <4.91 <9.77 <4.90 <4.93 <4.94 <4.96 <4.95 <5.01 <4.92 <4.93 <4.87 <4.83 <4.87 <4.97 <4.93 NA NA NA NA
PFHxDA <0.997 <0.993 <0.954 <0.974 <0.982 <1.95 <0.980 <0.986 <0.988 <0.991 <0.991 <1.00 <0.985 <0.986 <0.974 <0.967 <0.973 <0.995 <0.986 NA NA NA NA
MeFOSE <4.98 <4.96 <4.77 <4.87 <4.91 <9.77 <4.90 <4.93 <4.94 <4.96 <4.95 <5.01 <4.92 <4.93 <4.87 <4.83 <4.87 <4.97 <4.93 NA NA NA NA EtFOSE <4.98 <4.96 <4.77 <4.87 <4.91 <9.77 <4.90 <4.93 <4.94 <4.96 <4.95 <5.01 <4.92 <4.93 <4.87 <4.83 <4.87 <4.97 <4.93 NA NA NA NA
Notes:
ng/g = nanogram per gram
mg/kg - milligrams per kilogram
ng/L = nanograms per liter
RAG = Remedial Action Guidelines a presented on Table 1 in the Maine Remedial Action Guidelines for Sites Contaminated by Hazardous Substances (MDEP, October 19, 2018)
RAG units for leaching to groundwater are listed in ng/g to coincide with reported concentrations with remaining RAG guidelines listed in mg/kg.
ng/g mg/kg mg/kg mg/kg
SHORT PAPER FIBER
SOIL
REMEDIAL ACTION GUIDELINE (RAG)
SOIL
DIRECT PUSH DATA TABLE
COVERED MATERIAL
SOIL
BALED MATERIAL
SOILSOIL
TABLE 4
MULTI-INCREMENT SURFACE SOIL
PFAS ANALYTICAL RESULTS
MATRIX
SAMPLE ID / DEPTH CW - Inner CW - Replicate CW - Outer BM - Inner BM - Replicate BM - Outer SPF - Inner SPF - Replicate SPF - Outer
UNITS ng/g ng/g ng/g ng/g ng/g ng/g ng/g ng/g ng/g
COLLECTION DATE 8/30/2018 8/30/2018 8/28/2018 8/30/2018 8/30/2018 8/28/2018 8/30/2018 8/30/2018 8/28/2018
PFBA <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
PFPeA <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
PFBS <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 7,100 22,000 4,900 51,000
PFHxA <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
PFHpA <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
PFHxS <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
6:2 FTS <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
PFOA <0.985 <0.974 <0.978 1.38 J 1.40 J 1.80 J 3.83 3.73 3.11 9.5 22 4.9 5.1
PFHpS <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
PFNA <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
PFOSA <0.985 <0.974 <0.978 1.00 J 0.858 J 1.05 J 3.54 4.18 2.55 NA NA NA NA
PFOS 1.16 J 0.935 J 0.851 J 23.6 17.7 21.5 61.9 67.6 42.4 21 22 4.9 5.1
PFDA <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
8:2 FTS <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
MeFOSAA <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
EtFOSAA <0.985 <0.974 <0.978 1.59 J <0.995 1.42 J 8.37 12.6 7.16 NA NA NA NA
PFUnA <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
PFDS <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
PFDoA <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
MeFOSA <4.93 <4.87 <4.89 <4.92 <4.97 <4.89 <4.85 <4.91 <4.97 NA NA NA NA
PFTrDA <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
PFTeDA <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
EtFOSA <4.93 <4.87 <4.89 <4.92 <4.97 <4.89 <4.85 <4.91 <4.97 NA NA NA NA
PFHxDA <0.985 <0.974 <0.978 <0.985 <0.995 <0.979 <0.969 <0.983 <0.993 NA NA NA NA
MeFOSE <4.93 <4.87 <4.89 1.94 J <4.97 <4.89 8.36 J 6.45 J 5.49 J NA NA NA NA
EtFOSE <4.93 <4.87 <4.89 <4.92 <4.97 <4.89 2.31 J 2.26 J <4.97 NA NA NA NA
Notes:
ng/g = nanogram per gram
mg/kg = milligrams per kilogram
J = Concentration detected is below the Reorting Limit (RL)/Limits of Quantitation (LOQ)
RAG = Remedial Action Guidelines a presented on Table 1 in the Maine Remedial Action Guidelines for Sites Contaminated by Hazardous Substances (MDEP, October 19, 2018)
ng/g
Park UserConstruction
Worker
Leaching to
Groundwater
SOIL RAG
Commercial
Worker
mg/kg mg/kg mg/kg
MULTIINCREMENT DATA TABLE
SHORT PAPER FIBER
SOIL
COVERED MATERIAL
SOIL
BALED MATERIAL
SOIL
TABLE 5
MULTI-INCREMENT SURFACE SOIL PFAS QUALITY CONTROL
ANALYTICAL RESULTS
MATRIX
SAMPLE ID EQ-1 EQ-2
UNITS ng/g ng/g
COLLECTION DATE 8/30/2018 8/30/2018
PFBA <1.89 <1.96
PFPeA <1.89 <1.96
PFBS <1.89 <1.96
PFHxA <1.89 <1.96
PFHpA <1.89 <1.96
PFHxS <1.89 <1.96
6:2 FTS <1.89 <1.96
PFOA <1.89 <1.96
PFHpS <1.89 <1.96
PFNA <1.89 <1.96
PFOSA <1.89 <1.96
PFOS <1.89 <1.96
PFDA <1.89 <1.96
8:2 FTS <1.89 <1.96
MeFOSAA <1.89 <1.96
EtFOSAA <1.89 <1.96
PFUnA <1.89 <1.96
PFDS <1.89 <1.96
PFDoA <1.89 <1.96
MeFOSA <9.47 <9.80
PFTrDA <1.89 <1.96
PFTeDA <1.89 <1.96
EtFOSA <9.47 <9.80
PFHxDA <1.89 <1.96
MeFOSE <9.47 <9.80
EtFOSE <9.47 <9.80
Notes:
ng/g = nanogram per gram
MULTI-INCREMENT DATA TABLE
EQUIPMENT BLANK
SOIL
SOIL BORING LOG Boring #: DPT-01Project: Steamship Navigation Project #: 10193.050
640 Main Street Location: 2287 Camden Road Sheet: 1Lewiston, Maine 04240 Warren, Maine Chkd by:
Drilling Co: CES, Inc. Boring Location: Baled MaterialPersonnel: Jason Patterson Elevation: CES Staff: Wesley Harden Date started: 8/23/2018 Date Completed: 8/23/2018
DRILLING METHOD SAMPLER ESTIMATED GROUND WATER DEPTHVehicle: Geoprobe Type: Date Depth Reference Groundwater ElevationModel: 5410 Hammer: Ex. Grade Method: DPT Fall: Top of PVC
Depth SAMPLE(ft.) No. Pen/Rec (in) Depth (ft) Blows/6 in. DESCRIPTION Stratum Notes
1 48/20 0-4
2
42 48/42 4-8
6
8Refusal @ 8' BGS
10
12
14
16
18
20
Granular Soils Cohesive Soils % Composition
Blows/ft. Density Blows/ft. Consistency
0-4 V. Loose <2 V. soft
4-10 Loose 2-4 Soft <5% trace
10-30 Compact 4-8 Firm 5-15 little
30-50 Dense 8-15 Stiff 15-25 some
>50 V. Dense 15-30 V. Stiff >25 and
>30 Hard
0"-9": FILL. Coarse-grained sand with short paper fiber. Light gray. Polyester upholstery at 9".
9"- 20": FILL. Fine-grained sand. Brown to dark brown. Trace clay with small to medium gravel. Damp.
0"- 42": FILL. Fine- to medium-grained sand. Brown with trace to few fine to medium gravel. Damp.
collect sample 3-4' at 14:15
collect sample 7-8' and DUP2 at 14:20
SOIL BORING LOG Boring #: DPT-02Project: Steamship Navigation Project #: 10193.050
640 Main Street Location: 2287 Camden Road Sheet: 1Lewiston, Maine 04240 Warren, Maine Chkd by:
Drilling Co: CES, Inc. Boring Location: Baled MaterialPersonnel: Jason Patterson Elevation: CES Staff: Wesley Harden Date started: 8/23/2018 Date Completed: 8/23/2018
DRILLING METHOD SAMPLER ESTIMATED GROUND WATER DEPTHVehicle: Geoprobe Type: Date Depth Reference Groundwater ElevationModel: 5410 Hammer: Ex. Grade Method: DPT Fall: Top of PVC
Depth SAMPLE(ft.) No. Pen/Rec (in) Depth (ft) Blows/6 in. DESCRIPTION Stratum Notes
1 36.1/20 0-3.1
2
2 48/42 3.1-7.14
6
3 48/48 7.1-11.18
10
4 34.8/20 11.1-1412
14Refusal @ 13.9' BGS
16
18
20
Granular Soils Cohesive Soils % Composition
Blows/ft. Density Blows/ft. Consistency
0-4 V. Loose <2 V. soft
4-10 Loose 2-4 Soft <5% trace
10-30 Compact 4-8 Firm 5-15 little
30-50 Dense 8-15 Stiff 15-25 some
>50 V. Dense 15-30 V. Stiff >25 and
>30 Hard
0"-20": CLAY (CL). Gray. Trace fine to medium gravel. Dense. Damp.
0-30": SAND (SW). Fine-grained. Light brown. Cobble at 15".
20"-48": SILTY SAND (SM). Fine-grained. Light brown to gray. Trace clay with few fine to medium gravel. Saturated.
0"-8": SAND (SW). Fine-grained. Dark brown with trace medium gravel. Loose. Dry. Cobble at 9-10".
10"-20": SAND (SW). Fine grained. Light brown with trace silt. Few fine to medium gravel. Damp.
30"-40": SAND (SW). Fine-grained. Light brown. Trace to few fine to medium gravel. Wet.
0-12": SAND (SW). Fine-grained. Light brown. Trace to few fine to medium gravel. Wet.
12"-20": SAND (SW). Medium-grained. Brown. Trace fine to medium gravel. Saturated.
SOIL BORING LOG Boring #: DPT-03Project: Steamship Navigation Project #: 10193.050
640 Main Street Location: 2287 Camden Road Sheet: 1Lewiston, Maine 04240 Warren, Maine Chkd by:
Drilling Co: CES, Inc. Boring Location: Baled MaterialPersonnel: Jason Patterson Elevation: CES Staff: Wesley Harden Date started: 8/23/2018 Date Completed: 8/23/2018
DRILLING METHOD SAMPLER ESTIMATED GROUND WATER DEPTHVehicle: Geoprobe Type: Date Depth Reference Groundwater ElevationModel: 5410 Hammer: Ex. Grade Method: DPT Fall: Top of PVC
Depth SAMPLE(ft.) No. Pen/Rec (in) Depth (ft) Blows/6 in. DESCRIPTION Stratum Notes
1 48/30 0-4 samples taken0-1" @ 13:103-4" @ 13:15
2Polyester formed fiber at 30".
4Refusal @ 4' BGS
6
8
10
12
14
16
18
20
Granular Soils Cohesive Soils % Composition
Blows/ft. Density Blows/ft. Consistency
0-4 V. Loose <2 V. soft
4-10 Loose 2-4 Soft <5% trace
10-30 Compact 4-8 Firm 5-15 little
30-50 Dense 8-15 Stiff 15-25 some
>50 V. Dense 15-30 V. Stiff >25 and
>30 Hard
0-30": SAND (SP). Fine-grained. Brown with trace clay and few fine to medium gravel. Loose. Dry.
SOIL BORING LOG Boring #: DPT-04Project: Steamship Navigation Project #: 10193.050
640 Main Street Location: 2287 Camden Road Sheet: 1Lewiston, Maine 04240 Warren, Maine Chkd by:
Drilling Co: CES, Inc. Boring Location: Baled MaterialPersonnel: Jason Patterson Elevation: CES Staff: Wesley Harden Date started: 8/23/2018 Date Completed: 8/23/2018
DRILLING METHOD SAMPLER ESTIMATED GROUND WATER DEPTHVehicle: Geoprobe Type: Date Depth Reference Groundwater ElevationModel: 5410 Hammer: Ex. Grade Method: DPT Fall: Top of PVC
Depth SAMPLE(ft.) No. Pen/Rec (in) Depth (ft) Blows/6 in. DESCRIPTION Stratum Notes
1 Short paper fiber on top of bedrock.
2
4
6
8
10
12
14
16
18
20
Granular Soils Cohesive Soils % Composition
Blows/ft. Density Blows/ft. Consistency
0-4 V. Loose <2 V. soft
4-10 Loose 2-4 Soft <5% trace
10-30 Compact 4-8 Firm 5-15 little
30-50 Dense 8-15 Stiff 15-25 some
>50 V. Dense 15-30 V. Stiff >25 and
>30 Hard
SOIL BORING LOG Boring #: DPT-05Project: Steamship Navigation Project #: 10193.050
640 Main Street Location: 2287 Camden Road Sheet: 1Lewiston, Maine 04240 Warren, Maine Chkd by:
Drilling Co: CES, Inc. Boring Location: Short Paper FiberPersonnel: Jason Patterson Elevation: CES Staff: Wesley Harden Date started: 8/23/2018 Date Completed: 8/23/2018
DRILLING METHOD SAMPLER ESTIMATED GROUND WATER DEPTHVehicle: Geoprobe Type: Date Depth Reference Groundwater ElevationModel: 5410 Hammer: Ex. Grade Method: DPT Fall: Top of PVC
Depth SAMPLE(ft.) No. Pen/Rec (in) Depth (ft) Blows/6 in. DESCRIPTION Stratum Notes
1 48/12 0-4 0" - 12": FILL. Short Paper Fiber.
2
42 48/30 4-8 0" - 6": FILL. Short Paper Fiber. Sample @ 5-6"
Collected DUP1
6"-12": CLAY (CL). Dark gray with sand. Dense. Dry.
6
28"-30": SAND (SM). Fine-grained with silt. Gray. Wet.
83 12.4/6 8-9.4 0"-6": SAND (SM). Fine-grained with silt. Gray. Wet. As above. Sample 8-9" @12:30
10 Refusal @ 9.4' BGS
12
14
16
18
20
Granular Soils Cohesive Soils % Composition
Blows/ft. Density Blows/ft. Consistency
0-4 V. Loose <2 V. soft
4-10 Loose 2-4 Soft <5% trace
10-30 Compact 4-8 Firm 5-15 little
30-50 Dense 8-15 Stiff 15-25 some
>50 V. Dense 15-30 V. Stiff >25 and
>30 Hard
12"-28": CLAY (CL). Dark gray with trace sand. Less dense. Trace gravel.
SOIL BORING LOG Boring #: DPT-06Project: Steamship Navigation Project #: 10193.050
640 Main Street Location: 2287 Camden Road Sheet: 1Lewiston, Maine 04240 Warren, Maine Chkd by:
Drilling Co: CES, Inc. Boring Location: Short Paper FiberPersonnel: Jason Patterson Elevation: CES Staff: Wesley Harden Date started: 8/23/2018 Date Completed: 8/23/2018
DRILLING METHOD SAMPLER ESTIMATED GROUND WATER DEPTHVehicle: Geoprobe Type: Date Depth Reference Groundwater ElevationModel: 5410 Hammer: Ex. Grade Method: DPT Fall: Top of PVC
Depth SAMPLE(ft.) No. Pen/Rec (in) Depth (ft) Blows/6 in. DESCRIPTION Stratum Notes
1 48/24 0-4 0-24": FILL. Short paper fiber with soil.
2
42 12.7/24 4-5.7 0-24": FILL. Short paper fiber with soil and wood chips.
6Refusal @ 5.7' BGS
8
10
12
14
16
18
20
Granular Soils Cohesive Soils % Composition
Blows/ft. Density Blows/ft. Consistency
0-4 V. Loose <2 V. soft
4-10 Loose 2-4 Soft <5% trace
10-30 Compact 4-8 Firm 5-15 little
30-50 Dense 8-15 Stiff 15-25 some
>50 V. Dense 15-30 V. Stiff >25 and
>30 Hard
SOIL BORING LOG Boring #: DPT-07Project: Steamship Navigation Project #: 10193.050
640 Main Street Location: 2287 Camden Road Sheet: 1Lewiston, Maine 04240 Warren, Maine Chkd by:
Drilling Co: CES, Inc. Boring Location: Baled MaterialPersonnel: Jason Patterson Elevation: CES Staff: Wesley Harden Date started: 8/23/2018 Date Completed: 8/23/2018
DRILLING METHOD SAMPLER ESTIMATED GROUND WATER DEPTHVehicle: Geoprobe Type: Date Depth Reference Groundwater ElevationModel: 5410 Hammer: Ex. Grade Method: DPT Fall: Top of PVC
Depth SAMPLE(ft.) No. Pen/Rec (in) Depth (ft) Blows/6 in. DESCRIPTION Stratum Notes
12.4/10 0-1.4 0-10": SAND. Fine-grained. Brown. Dry.
Sample 0-1" @ 11:002 Refusal @ 1.4' BGS
4
6
8
10
12
14
16
18
20
Granular Soils Cohesive Soils % Composition
Blows/ft. Density Blows/ft. Consistency
0-4 V. Loose <2 V. soft
4-10 Loose 2-4 Soft <5% trace
10-30 Compact 4-8 Firm 5-15 little
30-50 Dense 8-15 Stiff 15-25 some
>50 V. Dense 15-30 V. Stiff >25 and
>30 Hard
Rock in drive shoe @ 1.4 ft BGS
SOIL BORING LOG Boring #: DPT-08Project: Steamship Navigation Project #: 10193.050
640 Main Street Location: 2287 Camden Road Sheet: 1Lewiston, Maine 04240 Warren, Maine Chkd by:
Drilling Co: CES, Inc. Boring Location: Covered WastePersonnel: Jason Patterson Elevation: CES Staff: Wesley Harden Date started: 8/23/2018 Date Completed: 8/23/2018
DRILLING METHOD SAMPLER ESTIMATED GROUND WATER DEPTHVehicle: Geoprobe Type: Date Depth Reference Groundwater ElevationModel: 5410 Hammer: Ex. Grade Method: DPT Fall: Top of PVC
Depth SAMPLE(ft.) No. Pen/Rec (in) Depth (ft) Blows/6 in. DESCRIPTION Stratum Notes
48/24 0-4 0-6": FILL. Brown. Dry.
212"-14": GRAVEL (GP). Well rounded.
14"-24": CLAY (CL) till. Gray. Damp.4
12.1/12 4-5.1
6
8
10
12
14
16
18
20
Granular Soils Cohesive Soils % Composition
Blows/ft. Density Blows/ft. Consistency
0-4 V. Loose <2 V. soft
4-10 Loose 2-4 Soft <5% trace
10-30 Compact 4-8 Firm 5-15 little
30-50 Dense 8-15 Stiff 15-25 some
>50 V. Dense 15-30 V. Stiff >25 and
>30 Hard
Collected sample 1-2' BGS below carpet waste @ 10:30
Collected sample @ 4.1-5.1" @ 10:35
6"-12": SAND (SP). Fine-grained. Dark brown with fine to medium gravel. Polyester carpet waste at 6.1"-6.2".
0-10": SAND (SP). Fine to medium-grained. Orange. Trace to few fine gravel. Dry.
10"-12": SAND (SP/SW). Fine-grained. Gray to brown. Trace to few fine to medium gravel. Dry.
Refusal @ 5.1' BGS
SOIL BORING LOG Boring #: DPT-09Project: Steamship Navigation Project #: 10193.050
640 Main Street Location: 2287 Camden Road Sheet: 1Lewiston, Maine 04240 Warren, Maine Chkd by:
Drilling Co: CES, Inc. Boring Location: Covered WastePersonnel: Jason Patterson Elevation: CES Staff: Wesley Harden Date started: 8/23/2018 Date Completed: 8/23/2018
DRILLING METHOD SAMPLER ESTIMATED GROUND WATER DEPTHVehicle: Geoprobe Type: Date Depth Reference Groundwater ElevationModel: 5410 Hammer: Ex. Grade Method: DPT Fall: Top of PVC
Depth SAMPLE(ft.) No. Pen/Rec (in) Depth (ft) Blows/6 in. DESCRIPTION Stratum Notes
48/35 0-4
2
448/48 4-7.9
15"-28": SAND (SP). Fine-grained. Brown. Saturated.6
8
10
12
14
16
18
20
Granular Soils Cohesive Soils % Composition
Blows/ft. Density Blows/ft. Consistency
0-4 V. Loose <2 V. soft
4-10 Loose 2-4 Soft <5% trace
10-30 Compact 4-8 Firm 5-15 little
30-50 Dense 8-15 Stiff 15-25 some
>50 V. Dense 15-30 V. Stiff >25 and
>30 Hard
Refusal @ 7.9' BGS
0-10": SAND (SP/SW). Fine-grained. Trace to few fine to medium gravel. Damp.
10"-25": SAND (SW). Fine to medium-grained. Brown to gray. Trace clay with trace fine gravel. Dry.
Sample 6.9-7.9' for PFAS at 09:53
25"-35": SAND (SP). Fine-grained. Brown. Trace to few fine gravel. Dry.
0-15": SAND (SP/SW). Fine-grained with trace clay. Brown. Damp.
28"-31": SAND (SW). Fine to medium-grained with trace to few fine gravel. Saturated.
Moisture decreases with depth.
31"-48": SAND (SP/SW). Fine-grained with trace carse sand to fine gravel. Brown. Damp.
SOIL BORING LOG Boring #: DPT-10Project: Steamship Navigation Project #: 10193.050
640 Main Street Location: 2287 Camden Road Sheet: 1Lewiston, Maine 04240 Warren, Maine Chkd by:
Drilling Co: CES, Inc. Boring Location: Covered WastePersonnel: Jason Patterson Elevation: CES Staff: Wesley Harden Date started: 8/23/2018 Date Completed: 8/23/2018
DRILLING METHOD SAMPLER ESTIMATED GROUND WATER DEPTHVehicle: Geoprobe Type: Date Depth Reference Groundwater ElevationModel: 5410 Hammer: Ex. Grade Method: DPT Fall: Top of PVC
Depth SAMPLE(ft.) No. Pen/Rec (in) Depth (ft) Blows/6 in. DESCRIPTION Stratum Notes
26.4/1.5 0-2.2
2Refusal @ 2.2' BGS
4
6
8
10
12
14
16
18
20
Granular Soils Cohesive Soils % Composition
Blows/ft. Density Blows/ft. Consistency
0-4 V. Loose <2 V. soft
4-10 Loose 2-4 Soft <5% trace
10-30 Compact 4-8 Firm 5-15 little
30-50 Dense 8-15 Stiff 15-25 some
>50 V. Dense 15-30 V. Stiff >25 and
>30 Hard
Sample 1.7-2.2' for PFAS @ 09:15
0-0.25": SAND (SP). Fine-grained. Brown. Trace roots. Damp. Polyester carpet waste at 0.25".
0.25"-1.5": SAND (SP/SM). Fine-grained. Brown. Trace silt. Damp.
JN: 10193.050 Phase II ESA – 2287 Camden Road Warren, Maine
APPENDIX B
LABORATORY ANALYTICAL RESULTS
L1834592
CES, Inc
10193.050
STEAMSHIP
Client:
Project Name:
Project Number:
09/12/18
Eight Walkup Drive, Westborough, MA 01581-1019
Lab Number:
Report Date:
508-898-9220 (Fax) 508-898-9193 800-624-9220 - www.alphalab.com
640 Main St
Lewiston, ME 04240
David ChapmanATTN:
ANALYTICAL REPORT
Certifications & Approvals: MA (M-MA086), NH NELAP (2064), CT (PH-0574), IL (200077), ME (MA00086), MD (348), NJ (MA935), NY (11148), NC (25700/666), PA (68-03671), RI (LAO00065), TX (T104704476), VT (VT-0935), VA (460195), USDA (Permit #P330-17-00196).
(207) 989-4824Phone:
The original project report/data package is held by Alpha Analytical. This report/data package is paginated and should be reproduced only in itsentirety. Alpha Analytical holds no responsibility for results and/or data that are not consistent with the original.
Serial_No:09121814:51
Page 1 of 28
L1834592-01
L1834592-02
L1834592-03
L1834592-04
L1834592-05
L1834592-06
L1834592-07
L1834592-08
Alpha Sample ID
TR-SS-5
IFR-SS-05
IFR-SS-17
IFR-SS-27
IFR-SS-04
TR-SS-15
LP-SS-13B
CANCEL
Client ID
WARREN, ME
WARREN, ME
WARREN, ME
WARREN, ME
WARREN, ME
WARREN, ME
WARREN, ME
WARREN, ME
Sample Location
STEAMSHIP
10193.050
Project Name:Project Number:
Lab Number: Report Date:
L183459209/12/18
08/29/18 11:35
08/29/18 12:35
08/29/18 15:05
08/29/18 15:30
08/29/18 12:30
08/29/18 11:40
08/29/18 14:00
08/29/18 00:00
Collection Date/TimeMatrix Receive Date
SOIL
SOIL
SOIL
SOIL
SOIL
SOIL
SOIL
SOIL
08/31/18
08/31/18
08/31/18
08/31/18
08/31/18
08/31/18
08/31/18
08/31/18
Serial_No:09121814:51
Page 2 of 28
STEAMSHIP
10193.050
Project Name:
Project Number:
Lab Number:
Report Date:L1834592
09/12/18
Case Narrative
The samples were received in accordance with the Chain of Custody and no significant deviations were encountered during the preparation
or analysis unless otherwise noted. Sample Receipt, Container Information, and the Chain of Custody are located at the back of the report.
Results contained within this report relate only to the samples submitted under this Alpha Lab Number and meet NELAP requirements for all
NELAP accredited parameters unless otherwise noted in the following narrative. The data presented in this report is organized by parameter
(i.e. VOC, SVOC, etc.). Sample specific Quality Control data (i.e. Surrogate Spike Recovery) is reported at the end of the target analyte list
for each individual sample, followed by the Laboratory Batch Quality Control at the end of each parameter. Tentatively Identified Compounds
(TICs), if requested, are reported for compounds identified to be present and are not part of the method/program Target Compound List,
even if only a subset of the TCL are being reported. If a sample was re-analyzed or re-extracted due to a required quality control corrective
action and if both sets of data are reported, the Laboratory ID of the re-analysis or re-extraction is designated with an "R" or "RE",
respectively. When multiple Batch Quality Control elements are reported (e.g. more than one LCS), the associated samples for each element
are noted in the grey shaded header line of each data table. Any Laboratory Batch, Sample Specific % recovery or RPD value that is outside
the listed Acceptance Criteria is bolded in the report. All specific QC information is also incorporated in the Data Usability format of our Data
Merger tool where it can be reviewed along with any associated usability implications. Soil/sediments, solids and tissues are reported on a
dry weight basis unless otherwise noted. Definitions of all data qualifiers and acronyms used in this report are provided in the Glossary
located at the back of the report.
In reference to questions H (CAM) or 4 (RCP) when "NO" is checked, the performance criteria for CAM and RCP methods allow for some
quality control failures to occur and still be within method compliance. In these instances the specific failure is not narrated but noted in the
associated QC table. The information is also incorporated in the Data Usability format of our Data Merger tool where it can be reviewed
along with any associated usability implications.
Please see the associated ADEx data file for a comparison of laboratory reporting limits that were achieved with the regulatory Numerical
Standards requested on the Chain of Custody.
HOLD POLICY
For samples submitted on hold, Alpha's policy is to hold samples (with the exception of Air canisters) free of charge for 21 calendar days
from the date the project is completed. After 21 calendar days, we will dispose of all samples submitted including those put on hold unless
you have contacted your Client Service Representative and made arrangements for Alpha to continue to hold the samples. Air canisters will
be disposed after 3 business days from the date the project is completed.
Please contact Client Services at 800-624-9220 with any questions.
I, the undersigned, attest under the pains and penalties of perjury that, to the best of my knowledge and belief and based upon my personal inquiry of those responsible for providing the information contained in this analytical report, such information is accurate and complete. This certificate of analysis is not complete unless this page accompanies any and all pages of this report.
Authorized Signature:
Title: Technical Director/Representative Date: 09/12/18
Serial_No:09121814:51
Page 3 of 28
FF
Project Name:
Project Number:
Lab Number:
Report Date:
STEAMSHIP
10193.050
L1834592
09/12/18
SAMPLE RESULTS
TR-SS-5Client ID:08/29/18 11:35Date Collected:08/31/18Date Received:
Matrix: Soil
WARREN, MESample Location:
L1834592-01Lab ID:
Field Prep: Not Specified
Parameter ResultDilution FactorQualifier Units RL
DateAnalyzed
AnalyticalMethod Analyst
Date Prepared
Total Metals - Mansfield Lab
Arsenic, Total
Barium, Total
Cadmium, Total
Chromium, Total
Lead, Total
Mercury, Total
Selenium, Total
Silver, Total
6.28
37.7
ND
18.4
6.96
ND
ND
ND
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
1
1
1
1
1
1
1
1
0.409
0.409
0.409
0.409
2.04
0.067
0.817
0.409
09/11/18 15:58
09/11/18 15:58
09/11/18 15:58
09/11/18 15:58
09/11/18 15:58
09/11/18 16:32
09/11/18 15:58
09/11/18 15:58
1,6010D
1,6010D
1,6010D
1,6010D
1,6010D
1,7471B
1,6010D
1,6010D
LC
LC
LC
LC
LC
MG
LC
LC
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 08:30
09/11/18 11:41
09/11/18 11:41
EPA 3050B
EPA 3050B
EPA 3050B
EPA 3050B
EPA 3050B
EPA 7471B
EPA 3050B
EPA 3050B
PrepMethod
Percent Solids: 94%
MDL
--
--
--
--
--
--
--
--
Sample Depth:
Serial_No:09121814:51
Page 5 of 28
Project Name:
Project Number:
Lab Number:
Report Date:
STEAMSHIP
10193.050
L1834592
09/12/18
SAMPLE RESULTS
IFR-SS-05Client ID:08/29/18 12:35Date Collected:08/31/18Date Received:
Matrix: Soil
WARREN, MESample Location:
L1834592-02Lab ID:
Field Prep: Not Specified
Parameter ResultDilution FactorQualifier Units RL
DateAnalyzed
AnalyticalMethod Analyst
Date Prepared
Total Metals - Mansfield Lab
Arsenic, Total
Barium, Total
Cadmium, Total
Chromium, Total
Lead, Total
Mercury, Total
Selenium, Total
Silver, Total
12.5
30.1
0.496
22.4
315
ND
ND
ND
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
1
1
1
1
1
1
1
1
0.450
0.450
0.450
0.450
2.25
0.075
0.901
0.450
09/11/18 16:02
09/11/18 16:02
09/11/18 16:02
09/11/18 16:02
09/11/18 16:02
09/11/18 16:34
09/11/18 16:02
09/11/18 16:02
1,6010D
1,6010D
1,6010D
1,6010D
1,6010D
1,7471B
1,6010D
1,6010D
LC
LC
LC
LC
LC
MG
LC
LC
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 08:30
09/11/18 11:41
09/11/18 11:41
EPA 3050B
EPA 3050B
EPA 3050B
EPA 3050B
EPA 3050B
EPA 7471B
EPA 3050B
EPA 3050B
PrepMethod
Percent Solids: 85%
MDL
--
--
--
--
--
--
--
--
Sample Depth:
Serial_No:09121814:51
Page 6 of 28
Project Name:
Project Number:
Lab Number:
Report Date:
STEAMSHIP
10193.050
L1834592
09/12/18
SAMPLE RESULTS
IFR-SS-17Client ID:08/29/18 15:05Date Collected:08/31/18Date Received:
Matrix: Soil
WARREN, MESample Location:
L1834592-03Lab ID:
Field Prep: Not Specified
Parameter ResultDilution FactorQualifier Units RL
DateAnalyzed
AnalyticalMethod Analyst
Date Prepared
Total Metals - Mansfield Lab
Arsenic, Total
Barium, Total
Cadmium, Total
Chromium, Total
Lead, Total
Mercury, Total
Selenium, Total
Silver, Total
10.8
67.0
0.469
23.0
2850
ND
ND
ND
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
1
1
1
1
1
1
1
1
0.451
0.451
0.451
0.451
2.25
0.072
0.902
0.451
09/11/18 16:07
09/11/18 16:07
09/11/18 16:07
09/11/18 16:07
09/11/18 16:07
09/11/18 16:36
09/11/18 16:07
09/11/18 16:07
1,6010D
1,6010D
1,6010D
1,6010D
1,6010D
1,7471B
1,6010D
1,6010D
LC
LC
LC
LC
LC
MG
LC
LC
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 08:30
09/11/18 11:41
09/11/18 11:41
EPA 3050B
EPA 3050B
EPA 3050B
EPA 3050B
EPA 3050B
EPA 7471B
EPA 3050B
EPA 3050B
PrepMethod
Percent Solids: 87%
MDL
--
--
--
--
--
--
--
--
Sample Depth:
Serial_No:09121814:51
Page 7 of 28
Project Name:
Project Number:
Lab Number:
Report Date:
STEAMSHIP
10193.050
L1834592
09/12/18
SAMPLE RESULTS
IFR-SS-27Client ID:08/29/18 15:30Date Collected:08/31/18Date Received:
Matrix: Soil
WARREN, MESample Location:
L1834592-04Lab ID:
Field Prep: Not Specified
Parameter ResultDilution FactorQualifier Units RL
DateAnalyzed
AnalyticalMethod Analyst
Date Prepared
Total Metals - Mansfield Lab
Arsenic, Total
Barium, Total
Cadmium, Total
Chromium, Total
Lead, Total
Mercury, Total
Selenium, Total
Silver, Total
9.95
38.5
ND
19.3
5290
ND
ND
0.496
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
1
1
1
1
1
1
1
1
0.463
0.463
0.463
0.463
2.32
0.073
0.927
0.463
09/11/18 16:25
09/11/18 16:25
09/11/18 16:25
09/11/18 16:25
09/11/18 16:25
09/11/18 16:38
09/11/18 16:25
09/11/18 16:25
1,6010D
1,6010D
1,6010D
1,6010D
1,6010D
1,7471B
1,6010D
1,6010D
LC
LC
LC
LC
LC
MG
LC
LC
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 08:30
09/11/18 11:41
09/11/18 11:41
EPA 3050B
EPA 3050B
EPA 3050B
EPA 3050B
EPA 3050B
EPA 7471B
EPA 3050B
EPA 3050B
PrepMethod
Percent Solids: 85%
MDL
--
--
--
--
--
--
--
--
Sample Depth:
Serial_No:09121814:51
Page 8 of 28
Project Name:
Project Number:
Lab Number:
Report Date:
STEAMSHIP
10193.050
L1834592
09/12/18
SAMPLE RESULTS
IFR-SS-04Client ID:08/29/18 12:30Date Collected:08/31/18Date Received:
Matrix: Soil
WARREN, MESample Location:
L1834592-05Lab ID:
Field Prep: Not Specified
Parameter ResultDilution FactorQualifier Units RL
DateAnalyzed
AnalyticalMethod Analyst
Date Prepared
Total Metals - Mansfield Lab
Arsenic, Total
Barium, Total
Cadmium, Total
Chromium, Total
Lead, Total
Mercury, Total
Selenium, Total
Silver, Total
10.3
34.6
ND
18.9
542
ND
ND
ND
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
1
1
1
1
1
1
1
1
0.436
0.436
0.436
0.436
2.18
0.072
0.872
0.436
09/11/18 16:29
09/11/18 16:29
09/11/18 16:29
09/11/18 16:29
09/11/18 16:29
09/11/18 16:40
09/11/18 16:29
09/11/18 16:29
1,6010D
1,6010D
1,6010D
1,6010D
1,6010D
1,7471B
1,6010D
1,6010D
AB
AB
AB
AB
AB
MG
AB
AB
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 08:30
09/11/18 11:41
09/11/18 11:41
EPA 3050B
EPA 3050B
EPA 3050B
EPA 3050B
EPA 3050B
EPA 7471B
EPA 3050B
EPA 3050B
PrepMethod
Percent Solids: 87%
MDL
--
--
--
--
--
--
--
--
Sample Depth:
Serial_No:09121814:51
Page 9 of 28
Project Name:
Project Number:
Lab Number:
Report Date:
STEAMSHIP
10193.050
L1834592
09/12/18
SAMPLE RESULTS
TR-SS-15Client ID:08/29/18 11:40Date Collected:08/31/18Date Received:
Matrix: Soil
WARREN, MESample Location:
L1834592-06Lab ID:
Field Prep: Not Specified
Parameter ResultDilution FactorQualifier Units RL
DateAnalyzed
AnalyticalMethod Analyst
Date Prepared
Total Metals - Mansfield Lab
Arsenic, Total
Barium, Total
Cadmium, Total
Chromium, Total
Lead, Total
Mercury, Total
Selenium, Total
Silver, Total
7.63
49.8
ND
28.9
17.6
ND
ND
ND
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
1
1
1
1
1
1
1
1
0.441
0.441
0.441
0.441
2.20
0.070
0.882
0.441
09/11/18 16:33
09/11/18 16:33
09/11/18 16:33
09/11/18 16:33
09/11/18 16:33
09/11/18 16:42
09/11/18 16:33
09/11/18 16:33
1,6010D
1,6010D
1,6010D
1,6010D
1,6010D
1,7471B
1,6010D
1,6010D
AB
AB
AB
AB
AB
MG
AB
AB
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 08:30
09/11/18 11:41
09/11/18 11:41
EPA 3050B
EPA 3050B
EPA 3050B
EPA 3050B
EPA 3050B
EPA 7471B
EPA 3050B
EPA 3050B
PrepMethod
Percent Solids: 90%
MDL
--
--
--
--
--
--
--
--
Sample Depth:
Serial_No:09121814:51
Page 10 of 28
Project Name:
Project Number:
Lab Number:
Report Date:
STEAMSHIP
10193.050
L1834592
09/12/18
SAMPLE RESULTS
LP-SS-13BClient ID:08/29/18 14:00Date Collected:08/31/18Date Received:
Matrix: Soil
WARREN, MESample Location:
L1834592-07Lab ID:
Field Prep: Not Specified
Parameter ResultDilution FactorQualifier Units RL
DateAnalyzed
AnalyticalMethod Analyst
Date Prepared
Total Metals - Mansfield Lab
Arsenic, Total
Barium, Total
Cadmium, Total
Chromium, Total
Lead, Total
Mercury, Total
Selenium, Total
Silver, Total
20.0
87.2
2.74
11.3
9670
ND
ND
1.02
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
1
1
1
1
1
1
1
1
0.553
0.553
0.553
0.553
2.76
0.089
1.11
0.553
09/11/18 16:38
09/11/18 16:38
09/11/18 16:38
09/11/18 16:38
09/11/18 16:38
09/11/18 16:44
09/11/18 16:38
09/11/18 16:38
1,6010D
1,6010D
1,6010D
1,6010D
1,6010D
1,7471B
1,6010D
1,6010D
AB
AB
AB
AB
AB
MG
AB
AB
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 08:30
09/11/18 11:41
09/11/18 11:41
EPA 3050B
EPA 3050B
EPA 3050B
EPA 3050B
EPA 3050B
EPA 7471B
EPA 3050B
EPA 3050B
PrepMethod
Percent Solids: 72%
MDL
--
--
--
--
--
--
--
--
Sample Depth:
Serial_No:09121814:51
Page 11 of 28
FF
Parameter
Parameter
Result
Result
Dilution Factor
Dilution Factor
Qualifier
Qualifier
Units
Units
RL
RL
Method Blank AnalysisBatch Quality Control
Project Name:
Project Number:
Lab Number:
Report Date:
STEAMSHIP
10193.050
L1834592
DateAnalyzed
DateAnalyzed
AnalyticalMethod
AnalyticalMethod
Analyst
Analyst
Date Prepared
Date Prepared
09/12/18
Mercury, Total
Arsenic, Total
Barium, Total
Cadmium, Total
Chromium, Total
Lead, Total
Selenium, Total
Silver, Total
ND
ND
ND
ND
ND
ND
ND
ND
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
1
1
1
1
1
1
1
1
0.083
0.400
0.400
0.400
0.400
2.00
0.800
0.400
09/11/18 15:57
09/11/18 15:30
09/11/18 15:30
09/11/18 15:30
09/11/18 15:30
09/11/18 15:30
09/11/18 15:30
09/11/18 15:30
1,7471B
1,6010D
1,6010D
1,6010D
1,6010D
1,6010D
1,6010D
1,6010D
MG
LC
LC
LC
LC
LC
LC
LC
09/11/18 08:30
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
09/11/18 11:41
Total Metals - Mansfield Lab for sample(s): 01-07 Batch: WG1155478-1
Total Metals - Mansfield Lab for sample(s): 01-07 Batch: WG1155600-1
EPA 7471B
EPA 3050B
Digestion Method:
Digestion Method:
Prep Information
Prep Information
MDL
MDL
--
--
--
--
--
--
--
--
Serial_No:09121814:51
Page 12 of 28
Mercury, Total
Arsenic, Total
Barium, Total
Cadmium, Total
Chromium, Total
Lead, Total
Selenium, Total
Silver, Total
110
93
87
92
89
87
95
91
-
-
-
-
-
-
-
-
65-134
83-117
83-118
83-118
83-117
82-118
79-121
80-120
-
-
-
-
-
-
-
-
ParameterLCS
%RecoveryLCSD
%Recovery%Recovery
Limits RPD RPD Limits
Total Metals - Mansfield Lab Associated sample(s): 01-07 Batch: WG1155478-2 SRM Lot Number: D102-540
Total Metals - Mansfield Lab Associated sample(s): 01-07 Batch: WG1155600-2 SRM Lot Number: D102-540
Lab Control Sample AnalysisBatch Quality Control
Project Name:
Project Number:
Lab Number:
Report Date:
STEAMSHIP
10193.050
L1834592
09/12/18
Qual Qual Qual
Serial_No:09121814:51
Page 13 of 28
FF
TR-SS-5Client ID:08/29/18 11:35Date Collected:08/31/18Date Received:
Parameter ResultDilution Factor
Matrix: Soil
WARREN, MESample Location:
L1834592-01Lab ID:
Qualifier Units RL
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
STEAMSHIP
10193.050
L1834592
Field Prep:
DateAnalyzed
AnalyticalMethod Analyst
Not Specified
General Chemistry - Westborough LabSolids, Total 94.4 % 10.100 09/01/18 11:52 121,2540G RI
Date Prepared
-
09/12/18
MDL
NA
Sample Depth:
Serial_No:09121814:51
Page 15 of 28
FF
IFR-SS-05Client ID:08/29/18 12:35Date Collected:08/31/18Date Received:
Parameter ResultDilution Factor
Matrix: Soil
WARREN, MESample Location:
L1834592-02Lab ID:
Qualifier Units RL
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
STEAMSHIP
10193.050
L1834592
Field Prep:
DateAnalyzed
AnalyticalMethod Analyst
Not Specified
General Chemistry - Westborough LabSolids, Total 85.1 % 10.100 09/01/18 11:52 121,2540G RI
Date Prepared
-
09/12/18
MDL
NA
Sample Depth:
Serial_No:09121814:51
Page 16 of 28
FF
IFR-SS-17Client ID:08/29/18 15:05Date Collected:08/31/18Date Received:
Parameter ResultDilution Factor
Matrix: Soil
WARREN, MESample Location:
L1834592-03Lab ID:
Qualifier Units RL
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
STEAMSHIP
10193.050
L1834592
Field Prep:
DateAnalyzed
AnalyticalMethod Analyst
Not Specified
General Chemistry - Westborough LabSolids, Total 87.4 % 10.100 09/01/18 11:52 121,2540G RI
Date Prepared
-
09/12/18
MDL
NA
Sample Depth:
Serial_No:09121814:51
Page 17 of 28
FF
IFR-SS-27Client ID:08/29/18 15:30Date Collected:08/31/18Date Received:
Parameter ResultDilution Factor
Matrix: Soil
WARREN, MESample Location:
L1834592-04Lab ID:
Qualifier Units RL
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
STEAMSHIP
10193.050
L1834592
Field Prep:
DateAnalyzed
AnalyticalMethod Analyst
Not Specified
General Chemistry - Westborough LabSolids, Total 85.3 % 10.100 09/01/18 11:52 121,2540G RI
Date Prepared
-
09/12/18
MDL
NA
Sample Depth:
Serial_No:09121814:51
Page 18 of 28
FF
IFR-SS-04Client ID:08/29/18 12:30Date Collected:08/31/18Date Received:
Parameter ResultDilution Factor
Matrix: Soil
WARREN, MESample Location:
L1834592-05Lab ID:
Qualifier Units RL
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
STEAMSHIP
10193.050
L1834592
Field Prep:
DateAnalyzed
AnalyticalMethod Analyst
Not Specified
General Chemistry - Westborough LabSolids, Total 87.2 % 10.100 09/01/18 11:52 121,2540G RI
Date Prepared
-
09/12/18
MDL
NA
Sample Depth:
Serial_No:09121814:51
Page 19 of 28
FF
TR-SS-15Client ID:08/29/18 11:40Date Collected:08/31/18Date Received:
Parameter ResultDilution Factor
Matrix: Soil
WARREN, MESample Location:
L1834592-06Lab ID:
Qualifier Units RL
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
STEAMSHIP
10193.050
L1834592
Field Prep:
DateAnalyzed
AnalyticalMethod Analyst
Not Specified
General Chemistry - Westborough LabSolids, Total 90.1 % 10.100 09/01/18 11:52 121,2540G RI
Date Prepared
-
09/12/18
MDL
NA
Sample Depth:
Serial_No:09121814:51
Page 20 of 28
FF
LP-SS-13BClient ID:08/29/18 14:00Date Collected:08/31/18Date Received:
Parameter ResultDilution Factor
Matrix: Soil
WARREN, MESample Location:
L1834592-07Lab ID:
Qualifier Units RL
SAMPLE RESULTS
Project Name:
Project Number:
Lab Number:
Report Date:
STEAMSHIP
10193.050
L1834592
Field Prep:
DateAnalyzed
AnalyticalMethod Analyst
Not Specified
General Chemistry - Westborough LabSolids, Total 72.2 % 10.100 09/01/18 11:52 121,2540G RI
Date Prepared
-
09/12/18
MDL
NA
Sample Depth:
Serial_No:09121814:51
Page 21 of 28
*Values in parentheses indicate holding time in days
L1834592-01A
L1834592-01B
L1834592-02A
L1834592-02B
L1834592-03A
L1834592-03B
L1834592-04A
L1834592-04B
L1834592-05A
L1834592-05B
L1834592-06A
L1834592-06B
L1834592-07A
L1834592-07B
L1834592-08A
L1834592-08B
Plastic 2oz unpreserved for TS
Metals Only-Glass 60mL/2oz unpreserved
Plastic 2oz unpreserved for TS
Metals Only-Glass 60mL/2oz unpreserved
Plastic 2oz unpreserved for TS
Metals Only-Glass 60mL/2oz unpreserved
Plastic 2oz unpreserved for TS
Metals Only-Glass 60mL/2oz unpreserved
Plastic 2oz unpreserved for TS
Metals Only-Glass 60mL/2oz unpreserved
Plastic 2oz unpreserved for TS
Metals Only-Glass 60mL/2oz unpreserved
Plastic 2oz unpreserved for TS
Metals Only-Glass 60mL/2oz unpreserved
Plastic 2oz unpreserved for TS
Glass 60mL/2oz unpreserved
A
A
A
A
A
A
A
A
A
A
A
A
A
A
N/A
N/A
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
2.2
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
Absent
A
N/A
Absent
Absent
Cooler Custody SealCooler Information
STEAMSHIP
10193.050
ME-TS-2540(7)
AS-TI(180),BA-TI(180),AG-TI(180),CR-TI(180),PB-TI(180),SE-TI(180),HG-T(28),CD-TI(180)
ME-TS-2540(7)
AS-TI(180),BA-TI(180),AG-TI(180),CR-TI(180),PB-TI(180),SE-TI(180),HG-T(28),CD-TI(180)
ME-TS-2540(7)
AS-TI(180),BA-TI(180),AG-TI(180),CR-TI(180),PB-TI(180),SE-TI(180),HG-T(28),CD-TI(180)
ME-TS-2540(7)
AS-TI(180),BA-TI(180),AG-TI(180),CR-TI(180),PB-TI(180),SE-TI(180),HG-T(28),CD-TI(180)
ME-TS-2540(7)
AS-TI(180),BA-TI(180),AG-TI(180),CR-TI(180),PB-TI(180),SE-TI(180),HG-T(28),CD-TI(180)
ME-TS-2540(7)
AS-TI(180),BA-TI(180),AG-TI(180),CR-TI(180),PB-TI(180),SE-TI(180),HG-T(28),CD-TI(180)
ME-TS-2540(7)
AS-TI(180),BA-TI(180),AG-TI(180),CR-TI(180),PB-TI(180),SE-TI(180),HG-T(28),CD-TI(180)
HOLD()
HOLD()
Project Name:
Project Number:
L1834592Lab Number:
Report Date:
Sample Receipt and Container Information
Container ID Container Type CoolerTempdeg C Pres Seal
Container Information
Analysis(*)
09/12/18
Were project specific reporting limits specified? YES
FrozenDate/Time
FinalpH
Initial pH
Serial_No:09121814:51
Page 22 of 28
*Values in parentheses indicate holding time in days
STEAMSHIP
10193.050
Project Name:
Project Number:
L1834592Lab Number:
Report Date:
Container ID Container Type CoolerTempdeg C Pres Seal
Container Information
Analysis(*)
09/12/18
FrozenDate/Time
FinalpH
Initial pH
Serial_No:09121814:51
Page 23 of 28
Report Format: Data Usability Report
GLOSSARY
Project Name:
Project Number:
Lab Number:
Report Date:
L1834592STEAMSHIP
10193.050 09/12/18
Acronyms
EDL
EMPC
EPA
LCS
LCSD
LFB
MDL
MS
MSD
NA
NC
NDPA/DPA
NI
NP
RL
RPD
SRM
STLP
TEF
TEQ
TIC
Estimated Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated values, when those target analyte concentrations are quantified below the reporting limit (RL). The EDL includes any adjustments from dilutions, concentrations or moisture content, where applicable. The use of EDLs is specific to the analysis of PAHs using Solid-Phase Microextraction (SPME).Estimated Maximum Possible Concentration: The concentration that results from the signal present at the retention time of an analyte when the ions meet all of the identification criteria except the ion abundance ratio criteria. An EMPC is a worst-case estimate of the concentration.Environmental Protection Agency.
Laboratory Control Sample: A sample matrix, free from the analytes of interest, spiked with verified known amounts of analytes or a material containing known and verified amounts of analytes.Laboratory Control Sample Duplicate: Refer to LCS.
Laboratory Fortified Blank: A sample matrix, free from the analytes of interest, spiked with verified known amounts of analytes or a material containing known and verified amounts of analytes.Method Detection Limit: This value represents the level to which target analyte concentrations are reported as estimated values, when those target analyte concentrations are quantified below the reporting limit (RL). The MDL includes any adjustments from dilutions, concentrations or moisture content, where applicable.Matrix Spike Sample: A sample prepared by adding a known mass of target analyte to a specified amount of matrix sample forwhich an independent estimate of target analyte concentration is available. Matrix Spike Sample Duplicate: Refer to MS.
Not Applicable.
Not Calculated: Term is utilized when one or more of the results utilized in the calculation are non-detect at the parameter's reporting unit.N-Nitrosodiphenylamine/Diphenylamine.
Not Ignitable.
Non-Plastic: Term is utilized for the analysis of Atterberg Limits in soil.
Reporting Limit: The value at which an instrument can accurately measure an analyte at a specific concentration. The RL includes any adjustments from dilutions, concentrations or moisture content, where applicable.Relative Percent Difference: The results from matrix and/or matrix spike duplicates are primarily designed to assess the precision of analytical results in a given matrix and are expressed as relative percent difference (RPD). Values which are less than five times the reporting limit for any individual parameter are evaluated by utilizing the absolute difference between the values; although the RPD value will be provided in the report.Standard Reference Material: A reference sample of a known or certified value that is of the same or similar matrix as the associated field samples.Semi-dynamic Tank Leaching Procedure per EPA Method 1315.
Toxic Equivalency Factors: The values assigned to each dioxin and furan to evaluate their toxicity relative to 2,3,7,8-TCDD.
Toxic Equivalent: The measure of a sample¿s toxicity derived by multiplying each dioxin and furan by its corresponding TEF and then summing the resulting values.Tentatively Identified Compound: A compound that has been identified to be present and is not part of the target compound list (TCL) for the method and/or program. All TICs are qualitatively identified and reported as estimated concentrations.
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
Terms
Analytical Method: Both the document from which the method originates and the analytical reference method. (Example: EPA 8260B is shown as 1,8260B.) The codes for the reference method documents are provided in the References section of the Addendum.Final pH: As it pertains to Sample Receipt & Container Information section of the report, Final pH reflects pH of container determined after adjustment at the laboratory, if applicable. If no adjustment required, value reflects Initial pH.Frozen Date/Time: With respect to Volatile Organics in soil, Frozen Date/Time reflects the date/time at which associated Reagent Water-preserved vials were initially frozen. Note: If frozen date/time is beyond 48 hours from sample collection, value will be reflected in 'bold'.Initial pH: As it pertains to Sample Receipt & Container Information section of the report, Initial pH reflects pH of container determined uponreceipt, if applicable.Total: With respect to Organic analyses, a 'Total' result is defined as the summation of results for individual isomers or Aroclors. If a 'Total' result is requested, the results of its individual components will also be reported. This is applicable to 'Total' results for methods 8260, 8081 and 8082.
1 The reference for this analyte should be considered modified since this analyte is absent from the target analyte list of the original method.
-
Footnotes
Serial_No:09121814:51
Page 24 of 28
Report Format: Data Usability Report
Project Name:
Project Number:
Lab Number:
Report Date:
L1834592STEAMSHIP
10193.050 09/12/18
Data Qualifiers
A
B
C
D
E
G
H
I
M
NJ
P
Q
R
RE
S
-
-
-
-
-
-
-
-
-
-
-
-
-
-
-
Spectra identified as "Aldol Condensation Product".
The analyte was detected above the reporting limit in the associated method blank. Flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank. For MCP-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank. For DOD-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte at less than ten times (10x) the concentration found in the blank AND the analyte was detected above one-half the reporting limit (or above the reporting limit for common lab contaminants) in the associated method blank. For NJ-Air-related projects, flag only applies to associated field samples that have detectable concentrations of the analyte above the reporting limit. For NJ-related projects (excluding Air), flag only applies to associated field samples that have detectable concentrations of the analyte, which was detected above the reporting limit in the associated method blank or above five times the reporting limit for common lab contaminants (Phthalates, Acetone, Methylene Chloride, 2-Butanone). Co-elution: The target analyte co-elutes with a known lab standard (i.e. surrogate, internal standards, etc.) for co-extracted analyses.Concentration of analyte was quantified from diluted analysis. Flag only applies to field samples that have detectable concentrations of the analyte.Concentration of analyte exceeds the range of the calibration curve and/or linear range of the instrument.
The concentration may be biased high due to matrix interferences (i.e, co-elution) with non-target compound(s). The result should be considered estimated.The analysis of pH was performed beyond the regulatory-required holding time of 15 minutes from the time of sample collection.
The lower value for the two columns has been reported due to obvious interference.
Reporting Limit (RL) exceeds the MCP CAM Reporting Limit for this analyte.
Presumptive evidence of compound. This represents an estimated concentration for Tentatively Identified Compounds (TICs), where the identification is based on a mass spectral library search.The RPD between the results for the two columns exceeds the method-specified criteria.
The quality control sample exceeds the associated acceptance criteria. For DOD-related projects, LCS and/or Continuing CalibrationStandard exceedences are also qualified on all associated sample results. Note: This flag is not applicable for matrix spike recoverieswhen the sample concentration is greater than 4x the spike added or for batch duplicate RPD when the sample concentrations are lessthan 5x the RL. (Metals only.)Analytical results are from sample re-analysis.
Analytical results are from sample re-extraction.
Analytical results are from modified screening analysis.
J
ND
-
-
Estimated value. This represents an estimated concentration for Tentatively Identified Compounds (TICs).
Not detected at the reporting limit (RL) for the sample.
Serial_No:09121814:51
Page 25 of 28
Alpha Analytical performs services with reasonable care and diligence normal to the analytical testinglaboratory industry. In the event of an error, the sole and exclusive responsibility of Alpha Analyticalshall be to re-perform the work at it's own expense. In no event shall Alpha Analytical be held liablefor any incidental, consequential or special damages, including but not limited to, damages in any wayconnected with the use of, interpretation of, information or analysis provided by Alpha Analytical.
We strongly urge our clients to comply with EPA protocol regarding sample volume, preservation, cooling,containers, sampling procedures, holding time and splitting of samples in the field.
LIMITATION OF LIABILITIES
1
121
Test Methods for Evaluating Solid Waste: Physical/Chemical Methods. EPA SW-846. Third Edition. Updates I - IV, 2007.
Standard Methods for the Examination of Water and Wastewater. APHA-AWWA-WEF. Standard Methods Online.
Project Name:
Project Number:
Lab Number:
Report Date:
L1834592STEAMSHIP
10193.050
REFERENCES
09/12/18
Serial_No:09121814:51
Page 26 of 28
Alpha Analytical, Inc. ID No.:17873 Facility: Company-wide Revision 11 Department: Quality Assurance Published Date: 1/8/2018 4:15:49 PM Title: Certificate/Approval Program Summary Page 1 of 1
Document Type: Form Pre-Qualtrax Document ID: 08-113
Certification Information
The following analytes are not included in our Primary NELAP Scope of Accreditation:
Westborough Facility EPA 624: m/p-xylene, o-xylene EPA 8260C: NPW: 1,2,4,5-Tetramethylbenzene; 4-Ethyltoluene, Azobenzene; SCM: Iodomethane (methyl iodide), Methyl methacrylate, 1,2,4,5-Tetramethylbenzene; 4-Ethyltoluene. EPA 8270D: NPW: Dimethylnaphthalene,1,4-Diphenylhydrazine; SCM: Dimethylnaphthalene,1,4-Diphenylhydrazine. EPA 300: DW: Bromide EPA 6860: SCM: Perchlorate EPA 9010: NPW and SCM: Amenable Cyanide Distillation SM4500: NPW: Amenable Cyanide, Dissolved Oxygen; SCM: Total Phosphorus, TKN, NO2, NO3. Mansfield Facility SM 2540D: TSS EPA 8082A: NPW: PCB: 1, 5, 31, 87,101, 110, 141, 151, 153, 180, 183, 187. EPA TO-15: Halothane, 2,4,4-Trimethyl-2-pentene, 2,4,4-Trimethyl-1-pentene, Thiophene, 2-Methylthiophene, 3-Methylthiophene, 2-Ethylthiophene, 1,2,3-Trimethylbenzene, Indan, Indene, 1,2,4,5-Tetramethylbenzene, Benzothiophene, 1-Methylnaphthalene. Biological Tissue Matrix: EPA 3050B
The following analytes are included in our Massachusetts DEP Scope of Accreditation
Westborough Facility:
Drinking Water EPA 300.0: Chloride, Nitrate-N, Fluoride, Sulfate; EPA 353.2: Nitrate-N, Nitrite-N; SM4500NO3-F: Nitrate-N, Nitrite-N; SM4500F-C, SM4500CN-CE, EPA 180.1, SM2130B, SM4500Cl-D, SM2320B, SM2540C, SM4500H-B EPA 332: Perchlorate; EPA 524.2: THMs and VOCs; EPA 504.1: EDB, DBCP. Microbiology: SM9215B; SM9223-P/A, SM9223B-Colilert-QT,SM9222D. Non-Potable Water SM4500H,B, EPA 120.1, SM2510B, SM2540C, SM2320B, SM4500CL-E, SM4500F-BC, SM4500NH3-BH: Ammonia-N and Kjeldahl-N, EPA 350.1: Ammonia-N, LACHAT 10-107-06-1-B: Ammonia-N, EPA 351.1, SM4500NO3-F, EPA 353.2: Nitrate-N, EPA 351.1, SM4500P-E, SM4500P-B, E, SM4500SO4-E, SM5220D, EPA 410.4, SM5210B, SM5310C, SM4500CL-D, EPA 1664, EPA 420.1, SM4500-CN-CE, SM2540D. EPA 624: Volatile Halocarbons & Aromatics, EPA 608: Chlordane, Toxaphene, Aldrin, alpha-BHC, beta-BHC, gamma-BHC, delta-BHC, Dieldrin, DDD, DDE, DDT, Endosulfan I, Endosulfan II, Endosulfan sulfate, Endrin, Endrin Aldehyde, Heptachlor, Heptachlor Epoxide, PCBs EPA 625: SVOC (Acid/Base/Neutral Extractables), EPA 600/4-81-045: PCB-Oil. Microbiology: SM9223B-Colilert-QT; Enterolert-QT, SM9221E, SM9222D. Mansfield Facility: Drinking Water EPA 200.7: Al, Ba, Be, Cd, Cr, Cu, Mn, Ni, Na, Ag, Ca, Zn. EPA 200.8: Al, Sb, As, Ba, Be, Cd, Cr, Cu, Pb, Mn, Ni, Se, Ag, TL, Zn. EPA 245.1 Hg. EPA 522. Non-Potable Water EPA 200.7: Al, Sb, As, Be, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Ag, Na, Sr, TL, Ti, V, Zn. EPA 200.8: Al, Sb, As, Be, Cd, Cr, Cu, Pb, Mn, Ni, Se, Ag, TL, Zn. EPA 245.1 Hg. SM2340B
For a complete listing of analytes and methods, please contact your Alpha Project Manager.
Serial_No:09121814:51
Page 27 of 28
Alpha Analytical, Inc. ID No.:17873 Facility: Company-wide Revision 11 Department: Quality Assurance Published Date: 1/8/2018 4:15:49 PM Title: Certificate/Approval Program Summary Page 1 of 1
Document Type: Form Pre-Qualtrax Document ID: 08-113
Certification Information
The following analytes are not included in our Primary NELAP Scope of Accreditation:
Westborough Facility EPA 624: m/p-xylene, o-xylene EPA 8260C: NPW: 1,2,4,5-Tetramethylbenzene; 4-Ethyltoluene, Azobenzene; SCM: Iodomethane (methyl iodide), Methyl methacrylate, 1,2,4,5-Tetramethylbenzene; 4-Ethyltoluene. EPA 8270D: NPW: Dimethylnaphthalene,1,4-Diphenylhydrazine; SCM: Dimethylnaphthalene,1,4-Diphenylhydrazine. EPA 300: DW: Bromide EPA 6860: SCM: Perchlorate EPA 9010: NPW and SCM: Amenable Cyanide Distillation SM4500: NPW: Amenable Cyanide, Dissolved Oxygen; SCM: Total Phosphorus, TKN, NO2, NO3. Mansfield Facility SM 2540D: TSS EPA 8082A: NPW: PCB: 1, 5, 31, 87,101, 110, 141, 151, 153, 180, 183, 187. EPA TO-15: Halothane, 2,4,4-Trimethyl-2-pentene, 2,4,4-Trimethyl-1-pentene, Thiophene, 2-Methylthiophene, 3-Methylthiophene, 2-Ethylthiophene, 1,2,3-Trimethylbenzene, Indan, Indene, 1,2,4,5-Tetramethylbenzene, Benzothiophene, 1-Methylnaphthalene. Biological Tissue Matrix: EPA 3050B
The following analytes are included in our Massachusetts DEP Scope of Accreditation
Westborough Facility:
Drinking Water EPA 300.0: Chloride, Nitrate-N, Fluoride, Sulfate; EPA 353.2: Nitrate-N, Nitrite-N; SM4500NO3-F: Nitrate-N, Nitrite-N; SM4500F-C, SM4500CN-CE, EPA 180.1, SM2130B, SM4500Cl-D, SM2320B, SM2540C, SM4500H-B EPA 332: Perchlorate; EPA 524.2: THMs and VOCs; EPA 504.1: EDB, DBCP. Microbiology: SM9215B; SM9223-P/A, SM9223B-Colilert-QT,SM9222D. Non-Potable Water SM4500H,B, EPA 120.1, SM2510B, SM2540C, SM2320B, SM4500CL-E, SM4500F-BC, SM4500NH3-BH: Ammonia-N and Kjeldahl-N, EPA 350.1: Ammonia-N, LACHAT 10-107-06-1-B: Ammonia-N, EPA 351.1, SM4500NO3-F, EPA 353.2: Nitrate-N, EPA 351.1, SM4500P-E, SM4500P-B, E, SM4500SO4-E, SM5220D, EPA 410.4, SM5210B, SM5310C, SM4500CL-D, EPA 1664, EPA 420.1, SM4500-CN-CE, SM2540D. EPA 624: Volatile Halocarbons & Aromatics, EPA 608: Chlordane, Toxaphene, Aldrin, alpha-BHC, beta-BHC, gamma-BHC, delta-BHC, Dieldrin, DDD, DDE, DDT, Endosulfan I, Endosulfan II, Endosulfan sulfate, Endrin, Endrin Aldehyde, Heptachlor, Heptachlor Epoxide, PCBs EPA 625: SVOC (Acid/Base/Neutral Extractables), EPA 600/4-81-045: PCB-Oil. Microbiology: SM9223B-Colilert-QT; Enterolert-QT, SM9221E, SM9222D. Mansfield Facility: Drinking Water EPA 200.7: Al, Ba, Be, Cd, Cr, Cu, Mn, Ni, Na, Ag, Ca, Zn. EPA 200.8: Al, Sb, As, Ba, Be, Cd, Cr, Cu, Pb, Mn, Ni, Se, Ag, TL, Zn. EPA 245.1 Hg. EPA 522. Non-Potable Water EPA 200.7: Al, Sb, As, Be, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Ag, Na, Sr, TL, Ti, V, Zn. EPA 200.8: Al, Sb, As, Be, Cd, Cr, Cu, Pb, Mn, Ni, Se, Ag, TL, Zn. EPA 245.1 Hg. SM2340B
For a complete listing of analytes and methods, please contact your Alpha Project Manager.
Serial_No:09121814:51
Page 27 of 28
Alpha Analytical, Inc. ID No.:17873 Facility: Company-wide Revision 11 Department: Quality Assurance Published Date: 1/8/2018 4:15:49 PM Title: Certificate/Approval Program Summary Page 1 of 1
Document Type: Form Pre-Qualtrax Document ID: 08-113
Certification Information
The following analytes are not included in our Primary NELAP Scope of Accreditation:
Westborough Facility EPA 624: m/p-xylene, o-xylene EPA 8260C: NPW: 1,2,4,5-Tetramethylbenzene; 4-Ethyltoluene, Azobenzene; SCM: Iodomethane (methyl iodide), Methyl methacrylate, 1,2,4,5-Tetramethylbenzene; 4-Ethyltoluene. EPA 8270D: NPW: Dimethylnaphthalene,1,4-Diphenylhydrazine; SCM: Dimethylnaphthalene,1,4-Diphenylhydrazine. EPA 300: DW: Bromide EPA 6860: SCM: Perchlorate EPA 9010: NPW and SCM: Amenable Cyanide Distillation SM4500: NPW: Amenable Cyanide, Dissolved Oxygen; SCM: Total Phosphorus, TKN, NO2, NO3. Mansfield Facility SM 2540D: TSS EPA 8082A: NPW: PCB: 1, 5, 31, 87,101, 110, 141, 151, 153, 180, 183, 187. EPA TO-15: Halothane, 2,4,4-Trimethyl-2-pentene, 2,4,4-Trimethyl-1-pentene, Thiophene, 2-Methylthiophene, 3-Methylthiophene, 2-Ethylthiophene, 1,2,3-Trimethylbenzene, Indan, Indene, 1,2,4,5-Tetramethylbenzene, Benzothiophene, 1-Methylnaphthalene. Biological Tissue Matrix: EPA 3050B
The following analytes are included in our Massachusetts DEP Scope of Accreditation
Westborough Facility:
Drinking Water EPA 300.0: Chloride, Nitrate-N, Fluoride, Sulfate; EPA 353.2: Nitrate-N, Nitrite-N; SM4500NO3-F: Nitrate-N, Nitrite-N; SM4500F-C, SM4500CN-CE, EPA 180.1, SM2130B, SM4500Cl-D, SM2320B, SM2540C, SM4500H-B EPA 332: Perchlorate; EPA 524.2: THMs and VOCs; EPA 504.1: EDB, DBCP. Microbiology: SM9215B; SM9223-P/A, SM9223B-Colilert-QT,SM9222D. Non-Potable Water SM4500H,B, EPA 120.1, SM2510B, SM2540C, SM2320B, SM4500CL-E, SM4500F-BC, SM4500NH3-BH: Ammonia-N and Kjeldahl-N, EPA 350.1: Ammonia-N, LACHAT 10-107-06-1-B: Ammonia-N, EPA 351.1, SM4500NO3-F, EPA 353.2: Nitrate-N, EPA 351.1, SM4500P-E, SM4500P-B, E, SM4500SO4-E, SM5220D, EPA 410.4, SM5210B, SM5310C, SM4500CL-D, EPA 1664, EPA 420.1, SM4500-CN-CE, SM2540D. EPA 624: Volatile Halocarbons & Aromatics, EPA 608: Chlordane, Toxaphene, Aldrin, alpha-BHC, beta-BHC, gamma-BHC, delta-BHC, Dieldrin, DDD, DDE, DDT, Endosulfan I, Endosulfan II, Endosulfan sulfate, Endrin, Endrin Aldehyde, Heptachlor, Heptachlor Epoxide, PCBs EPA 625: SVOC (Acid/Base/Neutral Extractables), EPA 600/4-81-045: PCB-Oil. Microbiology: SM9223B-Colilert-QT; Enterolert-QT, SM9221E, SM9222D. Mansfield Facility: Drinking Water EPA 200.7: Al, Ba, Be, Cd, Cr, Cu, Mn, Ni, Na, Ag, Ca, Zn. EPA 200.8: Al, Sb, As, Ba, Be, Cd, Cr, Cu, Pb, Mn, Ni, Se, Ag, TL, Zn. EPA 245.1 Hg. EPA 522. Non-Potable Water EPA 200.7: Al, Sb, As, Be, Cd, Ca, Cr, Co, Cu, Fe, Pb, Mg, Mn, Mo, Ni, K, Se, Ag, Na, Sr, TL, Ti, V, Zn. EPA 200.8: Al, Sb, As, Be, Cd, Cr, Cu, Pb, Mn, Ni, Se, Ag, TL, Zn. EPA 245.1 Hg. SM2340B
For a complete listing of analytes and methods, please contact your Alpha Project Manager.
Serial_No:09121814:51
Page 27 of 28
Enclosed are the results for the sample set received at Vista Analytical Laboratory on August 28, 2018 under your
Project Name 'Steamship Navigation'.
Vista Analytical Laboratory is committed to serving you effectively. If you require additional information, please
contact me at 916-673-1520 or by email at [email protected].
Thank you for choosing Vista as part of your analytical support team.
Sincerely,
Martha Maier
Laboratory Director
October 01, 2018
Vista Work Order No. 1802726
CES Inc.
640 Main Street
Lewiston, ME 0240
Dear Mr. Buckman,
Mr. Chris Buckman
Vista Analytical Laboratory certifies that the report herein meets all the requirements set forth by NELAP for those applicable test
methods. Results relate only to the samples as received by the laboratory. This report should not be reproduced except in full without
the written approval of Vista.
Vista Analytical Laboratory 1104 Windfield Way El Dorado Hills, CA 95762 ph: 916-673-1520 fx: 916-673-0106 www.vista-analytical.com
Work Order 1802726 Page 1 of 62
Vista Work Order No. 1802726
Case Narrative
Sample Condition on Receipt:
Eighteen soil samples were received in good condition and within the method temperature requirements. The
samples were received and stored securely in accordance with Vista standard operating procedures and EPA
methodology.
Analytical Notes:
VAL-PFAS
The samples were extracted and analyzed for a selected list of PFAS using VAL Method PFAS. The results for
PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both linear and branched isomers. Results for all other
analytes include the linear isomers only.
Holding Times
The samples were extracted and analyzed within the hold times. All re-extractions were extracted within the
method hold times.
Quality Control
The Initial Calibration and Continuing Calibration Verifications met the method acceptance criteria.
The following samples were re-extracted because of low IS recoveries:
Laboratory ID Sample Name
1802726-01 DPT-10 (1.5-2.2)
1802726-03 DPT-09 (6.9-7.9)
1802726-05 DPT-08 (4.1-5.1)
1802726-08 DPT-05 (5-6)
1802726-09 DPT-05 (8-9)
1802726-10 DPT-03 (0-1)
1802726-13 DPT-01 (7-8)
1802726-15 DPT-02 (9-10)
1802726-16 DPT-02 (13-14)
1802726-18 DPT-DUP 2
A Method Blank and Ongoing Precision and Recovery (OPR) sample were extracted and analyzed with the
preparation batch for the original samples and for the re-extractions. No analytes were detected in the Method
Blank above 1/2 the LOQ for either Method Blank. The OPR recoveries were within the method acceptance
criteria for both OPRs.
As requested, an MS/MSD was performed on sample "DPT-05 (5-6)". The MS/MSD recoveries and RPDs were
Work Order 1802726 Page 2 of 62
within the method acceptance criteria.
The labeled standard recoveries outside the acceptance criteria are listed in the table below.
Work Order 1802726 Page 3 of 62
QC Anomalies
LabNumber SampleName Analysis Analyte Flag %Rec
1802726-01 DPT-10 (1.5-2.2) VAL - PFAS 13C8-PFOSA H 37.6
1802726-01 DPT-10 (1.5-2.2) VAL - PFAS d3-MeFOSA H 6.90
1802726-01 DPT-10 (1.5-2.2) VAL - PFAS d5-EtFOSA H 8.00
1802726-01 DPT-10 (1.5-2.2) VAL - PFAS d7-MeFOSE H 34.5
1802726-01 DPT-10 (1.5-2.2) VAL - PFAS d9-EtFOSE H 37.7
1802726-02 DPT-09 (0-1.2) VAL - PFAS d3-MeFOSA H 22.3
1802726-02 DPT-09 (0-1.2) VAL - PFAS d5-EtFOSA H 25.4
1802726-02 DPT-09 (0-1.2) VAL - PFAS d7-MeFOSE H 47.6
1802726-03 DPT-09 (6.9-7.9) VAL - PFAS 13C8-PFOSA H 39.1
1802726-03 DPT-09 (6.9-7.9) VAL - PFAS d3-MeFOSA H 8.70
1802726-03 DPT-09 (6.9-7.9) VAL - PFAS d5-EtFOSA H 8.20
1802726-03 DPT-09 (6.9-7.9) VAL - PFAS 13C2-PFHxDA H 40.2
1802726-03 DPT-09 (6.9-7.9) VAL - PFAS d7-MeFOSE H 36.2
1802726-03 DPT-09 (6.9-7.9) VAL - PFAS d9-EtFOSE H 37.2
1802726-04 DPT-08 (1-2) VAL - PFAS 13C8-PFOSA H 44.6
1802726-04 DPT-08 (1-2) VAL - PFAS d3-MeFOSA H 23.9
1802726-04 DPT-08 (1-2) VAL - PFAS d5-EtFOSA H 26.6
1802726-04 DPT-08 (1-2) VAL - PFAS d7-MeFOSE H 43.3
1802726-04 DPT-08 (1-2) VAL - PFAS d9-EtFOSE H 45.8
1802726-05 DPT-08 (4.1-5.1) VAL - PFAS 13C8-PFOSA H 43.3
1802726-05 DPT-08 (4.1-5.1) VAL - PFAS d3-MeFOSA H 4.70
1802726-05 DPT-08 (4.1-5.1) VAL - PFAS d5-EtFOSA H 4.90
1802726-05 DPT-08 (4.1-5.1) VAL - PFAS d7-MeFOSE H 36.6
1802726-05 DPT-08 (4.1-5.1) VAL - PFAS d9-EtFOSE H 39.8
1802726-06 DPT-07 (0-1) VAL - PFAS 13C8-PFOSA H 45.1
1802726-06 DPT-07 (0-1) VAL - PFAS d3-MeFOSA H 22.4
1802726-06 DPT-07 (0-1) VAL - PFAS d5-EtFOSA H 26.8
1802726-06 DPT-07 (0-1) VAL - PFAS d7-MeFOSE H 39.4
1802726-06 DPT-07 (0-1) VAL - PFAS d9-EtFOSE H 46.4
1802726-07 DPT-08 (cover) VAL - PFAS 13C8-PFOSA H 46.6
1802726-07 DPT-08 (cover) VAL - PFAS d3-MeFOSA H 22.2
1802726-07 DPT-08 (cover) VAL - PFAS d5-EtFOSA H 25.8
1802726-07 DPT-08 (cover) VAL - PFAS d7-MeFOSE H 41.4
1802726-07 DPT-08 (cover) VAL - PFAS d9-EtFOSE H 44.9
1802726-08 DPT-05 (5-6) VAL - PFAS d3-MeFOSA H 20.3
1802726-08 DPT-05 (5-6) VAL - PFAS d5-EtFOSA H 23.7
1802726-08 DPT-05 (5-6) VAL - PFAS d7-MeFOSE H 48.7
1802726-09 DPT-05 (8-9) VAL - PFAS d3-MeFOSA H 13.9
1802726-09 DPT-05 (8-9) VAL - PFAS 13C2-PFTeDA H 40.0
1802726-09 DPT-05 (8-9) VAL - PFAS d5-EtFOSA H 15.7
1802726-09 DPT-05 (8-9) VAL - PFAS 13C2-PFHxDA H 22.8
1802726-09 DPT-05 (8-9) VAL - PFAS d7-MeFOSE H 43.5
1802726-09 DPT-05 (8-9) VAL - PFAS d9-EtFOSE H 44.3
1802726-10 DPT-03 (0-1) VAL - PFAS 13C8-PFOSA H 45.6
1802726-10 DPT-03 (0-1) VAL - PFAS d3-MeFOSA H 7.50
1802726-10 DPT-03 (0-1) VAL - PFAS d5-EtFOSA H 7.80
1802726-10 DPT-03 (0-1) VAL - PFAS 13C2-PFHxDA H 34.3
1802726-10 DPT-03 (0-1) VAL - PFAS d7-MeFOSE H 37.2
1802726-10 DPT-03 (0-1) VAL - PFAS d9-EtFOSE H 39.9
1802726-11 DPT-03 (3-4) VAL - PFAS 13C8-PFOSA H 39.1
1802726-11 DPT-03 (3-4) VAL - PFAS d3-MeFOSA H 18.1
1802726-11 DPT-03 (3-4) VAL - PFAS d5-EtFOSA H 19.4
Work Order 1802726 Page 4 of 62
QC Anomalies
LabNumber SampleName Analysis Analyte Flag %Rec
1802726-11 DPT-03 (3-4) VAL - PFAS d7-MeFOSE H 37.2
1802726-11 DPT-03 (3-4) VAL - PFAS d9-EtFOSE H 40.4
1802726-12 DPT-01 (3-4) VAL - PFAS d3-MeFOSA H 25.4
1802726-12 DPT-01 (3-4) VAL - PFAS d5-EtFOSA H 27.2
1802726-12 DPT-01 (3-4) VAL - PFAS d7-MeFOSE H 48.9
1802726-13 DPT-01 (7-8) VAL - PFAS 13C8-PFOSA H 41.5
1802726-13 DPT-01 (7-8) VAL - PFAS d3-MeFOSA H 8.00
1802726-13 DPT-01 (7-8) VAL - PFAS d5-EtFOSA H 8.00
1802726-13 DPT-01 (7-8) VAL - PFAS d7-MeFOSE H 35.1
1802726-13 DPT-01 (7-8) VAL - PFAS d9-EtFOSE H 37.9
1802726-14 DPT-02 (1-2) VAL - PFAS 13C8-PFOSA H 46.2
1802726-14 DPT-02 (1-2) VAL - PFAS d3-MeFOSA H 17.8
1802726-14 DPT-02 (1-2) VAL - PFAS d5-EtFOSA H 18.9
1802726-14 DPT-02 (1-2) VAL - PFAS d7-MeFOSE H 43.9
1802726-14 DPT-02 (1-2) VAL - PFAS d9-EtFOSE H 44.3
1802726-15 DPT-02 (9-10) VAL - PFAS 13C8-PFOSA H 35.3
1802726-15 DPT-02 (9-10) VAL - PFAS 13C2-PFUnA H 49.6
1802726-15 DPT-02 (9-10) VAL - PFAS d3-MeFOSA H 8.80
1802726-15 DPT-02 (9-10) VAL - PFAS 13C2-PFTeDA H 49.2
1802726-15 DPT-02 (9-10) VAL - PFAS d5-EtFOSA H 7.90
1802726-15 DPT-02 (9-10) VAL - PFAS 13C2-PFHxDA H 37.2
1802726-15 DPT-02 (9-10) VAL - PFAS d7-MeFOSE H 17.2
1802726-15 DPT-02 (9-10) VAL - PFAS d9-EtFOSE H 13.8
1802726-16 DPT-02 (13-14) VAL - PFAS 13C8-PFOSA H 39.1
1802726-16 DPT-02 (13-14) VAL - PFAS d3-MeFOSA H 8.80
1802726-16 DPT-02 (13-14) VAL - PFAS d5-EtFOSA H 7.40
1802726-16 DPT-02 (13-14) VAL - PFAS d7-MeFOSE H 17.7
1802726-16 DPT-02 (13-14) VAL - PFAS d9-EtFOSE H 16.7
1802726-17 DPT-DUP 1 VAL - PFAS 13C8-PFOSA H 46.4
1802726-17 DPT-DUP 1 VAL - PFAS d3-MeFOSA H 28.4
1802726-17 DPT-DUP 1 VAL - PFAS d5-EtFOSA H 32.8
1802726-17 DPT-DUP 1 VAL - PFAS d7-MeFOSE H 49.8
1802726-18 DPT-DUP 2 VAL - PFAS 13C8-PFOSA H 38.8
1802726-18 DPT-DUP 2 VAL - PFAS d3-MeFOSA H 7.60
1802726-18 DPT-DUP 2 VAL - PFAS d5-EtFOSA H 7.00
1802726-18 DPT-DUP 2 VAL - PFAS d7-MeFOSE H 30.9
1802726-18 DPT-DUP 2 VAL - PFAS d9-EtFOSE H 34.2
B8H0237-BLK1 B8H0237-BLK1 VAL - PFAS 13C8-PFOSA H 29.9
B8H0237-BLK1 B8H0237-BLK1 VAL - PFAS d3-MeFOSA H 1.90
B8H0237-BLK1 B8H0237-BLK1 VAL - PFAS d5-EtFOSA H 1.50
B8H0237-BLK1 B8H0237-BLK1 VAL - PFAS d7-MeFOSE H 24.0
B8H0237-BLK1 B8H0237-BLK1 VAL - PFAS d9-EtFOSE H 20.6
B8H0237-BS1 B8H0237-BS1 VAL - PFAS 13C8-PFOSA H 34.8
B8H0237-BS1 B8H0237-BS1 VAL - PFAS d3-MeFOSA H 2.40
B8H0237-BS1 B8H0237-BS1 VAL - PFAS d5-EtFOSA H 1.90
B8H0237-BS1 B8H0237-BS1 VAL - PFAS d7-MeFOSE H 23.8
B8H0237-BS1 B8H0237-BS1 VAL - PFAS d9-EtFOSE H 21.4
B8I0165-BLK1 B8I0165-BLK1 VAL - PFAS 13C8-PFOSA H 23.7
B8I0165-BLK1 B8I0165-BLK1 VAL - PFAS 13C2-PFDoA H 48.8
B8I0165-BLK1 B8I0165-BLK1 VAL - PFAS d3-MeFOSA H 6.50
B8I0165-BLK1 B8I0165-BLK1 VAL - PFAS d5-EtFOSA H 6.30
B8I0165-BLK1 B8I0165-BLK1 VAL - PFAS d7-MeFOSE H 21.3
Work Order 1802726 Page 5 of 62
QC Anomalies
LabNumber SampleName Analysis Analyte Flag %Rec
B8I0165-BLK1 B8I0165-BLK1 VAL - PFAS d9-EtFOSE H 21.3
B8I0165-BS1 B8I0165-BS1 VAL - PFAS 13C8-PFOSA H 34.2
B8I0165-BS1 B8I0165-BS1 VAL - PFAS d3-MeFOSA H 8.60
B8I0165-BS1 B8I0165-BS1 VAL - PFAS d5-EtFOSA H 8.50
B8I0165-BS1 B8I0165-BS1 VAL - PFAS d7-MeFOSE H 30.1
B8I0165-BS1 B8I0165-BS1 VAL - PFAS d9-EtFOSE H 28.9
B8I0165-MS1 B8I0165-MS1 VAL - PFAS 13C8-PFOSA H 44.4
B8I0165-MS1 B8I0165-MS1 VAL - PFAS d3-MeFOSA H 19.8
B8I0165-MS1 B8I0165-MS1 VAL - PFAS d5-EtFOSA H 24.6
B8I0165-MS1 B8I0165-MS1 VAL - PFAS d7-MeFOSE H 43.8
B8I0165-MS1 B8I0165-MS1 VAL - PFAS d9-EtFOSE H 44.1
B8I0165-MSD1 B8I0165-MSD1 VAL - PFAS 13C8-PFOSA H 42.2
B8I0165-MSD1 B8I0165-MSD1 VAL - PFAS d3-MeFOSA H 15.4
B8I0165-MSD1 B8I0165-MSD1 VAL - PFAS d5-EtFOSA H 19.0
B8I0165-MSD1 B8I0165-MSD1 VAL - PFAS d7-MeFOSE H 41.2
B8I0165-MSD1 B8I0165-MSD1 VAL - PFAS d9-EtFOSE H 41.9
H = Recovery was outside laboratory acceptance criteria.
Work Order 1802726 Page 6 of 62
TABLE OF CONTENTS
Case Narrative................................................................................................ 1
Table of Contents........................................................................................... 7
Sample Inventory........................................................................................... 8
Analytical Results.......................................................................................... 9
Qualifiers........................................................................................................ 56
Certifications.................................................................................................. 57
Sample Receipt.............................................................................................. 60
Work Order 1802726 Page 7 of 62
Client
Sample ID
Sample Inventory Report
Vista
Sample ID Sampled Received Components/Containers
1802726-01 DPT-10 (1.5-2.2) 23-Aug-18 09:10 28-Aug-18 09:30 HDPE Jar, 6 oz
1802726-02 DPT-09 (0-1.2) 23-Aug-18 09:30 28-Aug-18 09:30 HDPE Jar, 6 oz
1802726-03 DPT-09 (6.9-7.9) 23-Aug-18 09:53 28-Aug-18 09:30 HDPE Jar, 6 oz
1802726-04 DPT-08 (1-2) 23-Aug-18 10:30 28-Aug-18 09:30 HDPE Jar, 6 oz
1802726-05 DPT-08 (4.1-5.1) 23-Aug-18 10:35 28-Aug-18 09:30 HDPE Jar, 6 oz
1802726-06 DPT-07 (0-1) 23-Aug-18 11:00 28-Aug-18 09:30 HDPE Jar, 6 oz
1802726-07 DPT-08 (cover) 23-Aug-18 13:45 28-Aug-18 09:30 HDPE Jar, 6 oz
1802726-08 DPT-05 (5-6) 23-Aug-18 12:15 28-Aug-18 09:30 HDPE Jar, 6 ozMS/MSD
HDPE Jar, 6 oz
1802726-09 DPT-05 (8-9) 23-Aug-18 12:30 28-Aug-18 09:30 HDPE Jar, 6 oz
1802726-10 DPT-03 (0-1) 23-Aug-18 13:10 28-Aug-18 09:30 HDPE Jar, 6 oz
1802726-11 DPT-03 (3-4) 23-Aug-18 13:15 28-Aug-18 09:30 HDPE Jar, 6 oz
1802726-12 DPT-01 (3-4) 23-Aug-18 14:15 28-Aug-18 09:30 HDPE Jar, 6 oz
1802726-13 DPT-01 (7-8) 23-Aug-18 14:20 28-Aug-18 09:30 HDPE Jar, 6 oz
1802726-14 DPT-02 (1-2) 23-Aug-18 16:05 28-Aug-18 09:30 HDPE Jar, 6 oz
1802726-15 DPT-02 (9-10) 23-Aug-18 16:15 28-Aug-18 09:30 HDPE Jar, 6 oz
1802726-16 DPT-02 (13-14) 23-Aug-18 16:25 28-Aug-18 09:30 HDPE Jar, 6 oz
1802726-17 DPT-DUP 1 23-Aug-18 00:00 28-Aug-18 09:30 HDPE Jar, 6 oz
1802726-18 DPT-DUP 2 23-Aug-18 00:00 28-Aug-18 09:30 HDPE Jar, 6 oz
Vista Project: 1802726 Client Project: Steamship Navigation
Work Order 1802726 Page 8 of 62
Name:
Project:
Client Data
Steamship Navigation
Sample ID: Method Blank
Matrix:
Laboratory Data
Lab Sample: B8H0237-BLK1
VAL - PFAS
CES Inc. Column: BEH C18Solid
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-18375-22-4
PFPeA 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-182706-90-3
PFBS 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-18375-73-5
PFHxA 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-18307-24-4
PFHpA 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-18375-85-9
PFHxS 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-18355-46-4
6:2 FTS 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-1827619-97-2
PFOA 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-18335-67-1
PFHpS 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-18375-92-8
PFNA 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-18375-95-1
PFOSA 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-18754-91-6
PFOS 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-181763-23-1
PFDA 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-18335-76-2
8:2 FTS 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-1839108-34-4
MeFOSAA 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-182355-31-9
EtFOSAA 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-182991-50-6
PFUnA 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-182058-94-8
PFDS 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-18335-77-3
PFDoA 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-18307-55-1
MeFOSA 1.95ND 15.00 10.0 21-Sep-18 15:16B8H0237 1.00 g05-Sep-1831506-32-8
PFTrDA 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-1872629-94-8
PFTeDA 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-18376-06-7
EtFOSA 1.95ND 15.00 10.0 21-Sep-18 15:16B8H0237 1.00 g05-Sep-184151-50-2
PFHxDA 0.845ND 11.00 2.00 21-Sep-18 15:16B8H0237 1.00 g05-Sep-1867905-19-5
MeFOSE 1.95ND 15.00 10.0 21-Sep-18 15:16B8H0237 1.00 g05-Sep-1824448-09-7
EtFOSE 1.95ND 15.00 10.0 21-Sep-18 15:16B8H0237 1.00 g05-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 93.0 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - 13C3-PFPeA 89.5 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - 13C3-PFBS 97.1 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - 13C2-PFHxA 89.8 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - 13C4-PFHpA 91.2 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - 18O2-PFHxS 86.8 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - 13C2-6:2 FTS 79.1 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - 13C2-PFOA 79.4 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
Work Order 1802726 Page 10 of 62
Name:
Project:
Client Data
Steamship Navigation
Sample ID: Method Blank
Matrix:
Laboratory Data
Lab Sample: B8H0237-BLK1
VAL - PFAS
CES Inc. Column: BEH C18Solid
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C5-PFNA 79.4 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - 13C8-PFOSA 29.9 50 150 H 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - 13C8-PFOS 88.3 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - 13C2-PFDA 69.0 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - 13C2-8:2 FTS 82.7 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - d3-MeFOSAA 64.9 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - d5-EtFOSAA 70.5 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - 13C2-PFUnA 68.6 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - 13C2-PFDoA 67.7 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - d3-MeFOSA 1.90 50 150 H 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - 13C2-PFTeDA 71.4 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - d5-EtFOSA 1.50 50 150 H 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - 13C2-PFHxDA 52.7 50 150 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - d7-MeFOSE 24.0 50 150 H 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 g
IS - d9-EtFOSE 20.6 50 150 H 121-Sep-18 15:16B8H0237 05-Sep-18 1.00 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 11 of 62
Name:Project:
Client Data
Steamship Navigation
Sample ID: OPR
Matrix:
Laboratory Data
Lab Sample: B8H0237-BS1
VAL - PFAS
CES Inc. Column: BEH C18Solid
Analyte Amt Found (ng/g ) Qualifiers Analyzed DilutionSpike Amt % Rec Limits Samp SizeExtractedBatchCAS Number
PFBA 10.7 121-Sep-18 15:2710.0 107 - 70 130 1.00 g05-Sep-18B8H0237375-22-4
PFPeA 10.7 121-Sep-18 15:2710.0 107 - 70 130 1.00 g05-Sep-18B8H02372706-90-3
PFBS 11.1 121-Sep-18 15:2710.0 111 - 70 130 1.00 g05-Sep-18B8H0237375-73-5
PFHxA 10.4 121-Sep-18 15:2710.0 104 - 70 130 1.00 g05-Sep-18B8H0237307-24-4
PFHpA 10.6 121-Sep-18 15:2710.0 106 - 70 130 1.00 g05-Sep-18B8H0237375-85-9
PFHxS 10.1 121-Sep-18 15:2710.0 101 - 70 130 1.00 g05-Sep-18B8H0237355-46-4
6:2 FTS 11.1 121-Sep-18 15:2710.0 111 - 60 130 1.00 g05-Sep-18B8H023727619-97-2
PFOA 11.1 121-Sep-18 15:2710.0 111 - 70 130 1.00 g05-Sep-18B8H0237335-67-1
PFHpS 11.3 121-Sep-18 15:2710.0 113 - 60 130 1.00 g05-Sep-18B8H0237375-92-8
PFNA 10.8 121-Sep-18 15:2710.0 108 - 70 130 1.00 g05-Sep-18B8H0237375-95-1
PFOSA 10.5 121-Sep-18 15:2710.0 105 - 70 130 1.00 g05-Sep-18B8H0237754-91-6
PFOS 11.3 121-Sep-18 15:2710.0 113 - 70 130 1.00 g05-Sep-18B8H02371763-23-1
PFDA 10.8 121-Sep-18 15:2710.0 108 - 70 130 1.00 g05-Sep-18B8H0237335-76-2
8:2 FTS 11.4 121-Sep-18 15:2710.0 114 - 60 130 1.00 g05-Sep-18B8H023739108-34-4
MeFOSAA 10.5 121-Sep-18 15:2710.0 105 - 70 130 1.00 g05-Sep-18B8H02372355-31-9
EtFOSAA 10.5 121-Sep-18 15:2710.0 105 - 70 130 1.00 g05-Sep-18B8H02372991-50-6
PFUnA 10.9 121-Sep-18 15:2710.0 109 - 70 130 1.00 g05-Sep-18B8H02372058-94-8
PFDS 9.95 121-Sep-18 15:2710.0 99.5 - 60 130 1.00 g05-Sep-18B8H0237335-77-3
PFDoA 10.7 121-Sep-18 15:2710.0 107 - 70 130 1.00 g05-Sep-18B8H0237307-55-1
MeFOSA 49.1 121-Sep-18 15:2750.0 98.1 - 70 130 1.00 g05-Sep-18B8H023731506-32-8
PFTrDA 10.5 121-Sep-18 15:2710.0 105 - 60 130 1.00 g05-Sep-18B8H023772629-94-8
PFTeDA 10.5 121-Sep-18 15:2710.0 105 - 70 130 1.00 g05-Sep-18B8H0237376-06-7
EtFOSA 44.7 121-Sep-18 15:2750.0 89.5 - 70 130 1.00 g05-Sep-18B8H02374151-50-2
PFHxDA 11.2 121-Sep-18 15:2710.0 112 - 70 130 1.00 g05-Sep-18B8H023767905-19-5
MeFOSE 49.3 121-Sep-18 15:2750.0 98.6 - 70 130 1.00 g05-Sep-18B8H023724448-09-7
EtFOSE 48.8 121-Sep-18 15:2750.0 97.6 - 70 130 1.00 g05-Sep-18B8H02371691-99-2
Labeled Standards % Rec Limits Qualifiers Analyzed DilutionType Samp SizeExtractedBatch
IS - 13C3-PFBA 93.8 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - 13C3-PFPeA 92.8 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - 13C3-PFBS 97.4 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - 13C2-PFHxA 94.3 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - 13C4-PFHpA 94.8 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - 18O2-PFHxS 100 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - 13C2-6:2 FTS 87.7 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - 13C2-PFOA 86.8 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
Work Order 1802726 Page 12 of 62
Name:Project:
Client Data
Steamship Navigation
Sample ID: OPR
Matrix:
Laboratory Data
Lab Sample: B8H0237-BS1
VAL - PFAS
CES Inc. Column: BEH C18Solid
Labeled Standards % Rec Limits Qualifiers Analyzed DilutionType Samp SizeExtractedBatch
IS - 13C5-PFNA 84.7 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - 13C8-PFOSA 34.8 50 150 H 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - 13C8-PFOS 84.2 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - 13C2-PFDA 71.5 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - 13C2-8:2 FTS 80.4 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - d3-MeFOSAA 70.1 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - d5-EtFOSAA 72.2 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - 13C2-PFUnA 72.0 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - 13C2-PFDoA 77.9 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - d3-MeFOSA 2.40 50 150 H 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - 13C2-PFTeDA 81.3 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - d5-EtFOSA 1.90 50 150 H 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - 13C2-PFHxDA 75.9 50 150 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - d7-MeFOSE 23.8 50 150 H 121-Sep-18 15:271.00 g05-Sep-18B8H0237
IS - d9-EtFOSE 21.4 50 150 H 121-Sep-18 15:271.00 g05-Sep-18B8H0237
Work Order 1802726 Page 13 of 62
Name:
Project:
Client Data
Steamship Navigation
Sample ID: Method Blank
Matrix:
Laboratory Data
Lab Sample: B8I0165-BLK1
VAL - PFAS
CES Inc. Column: BEH C18Solid
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-18375-22-4
PFPeA 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-182706-90-3
PFBS 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-18375-73-5
PFHxA 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-18307-24-4
PFHpA 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-18375-85-9
PFHxS 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-18355-46-4
6:2 FTS 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-1827619-97-2
PFOA 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-18335-67-1
PFHpS 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-18375-92-8
PFNA 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-18375-95-1
PFOSA 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-18754-91-6
PFOS 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-181763-23-1
PFDA 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-18335-76-2
8:2 FTS 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-1839108-34-4
MeFOSAA 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-182355-31-9
EtFOSAA 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-182991-50-6
PFUnA 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-182058-94-8
PFDS 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-18335-77-3
PFDoA 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-18307-55-1
MeFOSA 1.95ND 15.00 10.0 28-Sep-18 15:29B8I0165 1.00 g24-Sep-1831506-32-8
PFTrDA 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-1872629-94-8
PFTeDA 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-18376-06-7
EtFOSA 1.95ND 15.00 10.0 28-Sep-18 15:29B8I0165 1.00 g24-Sep-184151-50-2
PFHxDA 0.845ND 11.00 2.00 28-Sep-18 15:29B8I0165 1.00 g24-Sep-1867905-19-5
MeFOSE 1.95ND 15.00 10.0 28-Sep-18 15:29B8I0165 1.00 g24-Sep-1824448-09-7
EtFOSE 1.95ND 15.00 10.0 28-Sep-18 15:29B8I0165 1.00 g24-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 77.4 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - 13C3-PFPeA 69.7 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - 13C3-PFBS 84.6 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - 13C2-PFHxA 75.4 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - 13C4-PFHpA 76.5 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - 18O2-PFHxS 83.7 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - 13C2-6:2 FTS 77.1 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - 13C2-PFOA 75.4 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
Work Order 1802726 Page 14 of 62
Name:
Project:
Client Data
Steamship Navigation
Sample ID: Method Blank
Matrix:
Laboratory Data
Lab Sample: B8I0165-BLK1
VAL - PFAS
CES Inc. Column: BEH C18Solid
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C5-PFNA 71.3 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - 13C8-PFOSA 23.7 50 150 H 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - 13C8-PFOS 79.6 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - 13C2-PFDA 59.2 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - 13C2-8:2 FTS 78.7 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - d3-MeFOSAA 57.5 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - d5-EtFOSAA 57.9 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - 13C2-PFUnA 52.5 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - 13C2-PFDoA 48.8 50 150 H 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - d3-MeFOSA 6.50 50 150 H 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - 13C2-PFTeDA 51.5 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - d5-EtFOSA 6.30 50 150 H 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - 13C2-PFHxDA 59.1 50 150 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - d7-MeFOSE 21.3 50 150 H 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 g
IS - d9-EtFOSE 21.3 50 150 H 128-Sep-18 15:29B8I0165 24-Sep-18 1.00 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 15 of 62
Name:Project:
Client Data
Steamship Navigation
Sample ID: OPR
Matrix:
Laboratory Data
Lab Sample: B8I0165-BS1
VAL - PFAS
CES Inc. Column: BEH C18Solid
Analyte Amt Found (ng/g ) Qualifiers Analyzed DilutionSpike Amt % Rec Limits Samp SizeExtractedBatchCAS Number
PFBA 10.4 128-Sep-18 15:1810.0 104 - 70 130 1.00 g24-Sep-18B8I0165375-22-4
PFPeA 10.3 128-Sep-18 15:1810.0 103 - 70 130 1.00 g24-Sep-18B8I01652706-90-3
PFBS 9.78 128-Sep-18 15:1810.0 97.8 - 70 130 1.00 g24-Sep-18B8I0165375-73-5
PFHxA 10.8 128-Sep-18 15:1810.0 108 - 70 130 1.00 g24-Sep-18B8I0165307-24-4
PFHpA 10.1 128-Sep-18 15:1810.0 101 - 70 130 1.00 g24-Sep-18B8I0165375-85-9
PFHxS 10.0 128-Sep-18 15:1810.0 100 - 70 130 1.00 g24-Sep-18B8I0165355-46-4
6:2 FTS 10.9 128-Sep-18 15:1810.0 109 - 60 130 1.00 g24-Sep-18B8I016527619-97-2
PFOA 10.5 128-Sep-18 15:1810.0 105 - 70 130 1.00 g24-Sep-18B8I0165335-67-1
PFHpS 10.9 128-Sep-18 15:1810.0 109 - 60 130 1.00 g24-Sep-18B8I0165375-92-8
PFNA 9.60 128-Sep-18 15:1810.0 96.0 - 70 130 1.00 g24-Sep-18B8I0165375-95-1
PFOSA 10.4 128-Sep-18 15:1810.0 104 - 70 130 1.00 g24-Sep-18B8I0165754-91-6
PFOS 10.7 128-Sep-18 15:1810.0 107 - 70 130 1.00 g24-Sep-18B8I01651763-23-1
PFDA 9.57 128-Sep-18 15:1810.0 95.7 - 70 130 1.00 g24-Sep-18B8I0165335-76-2
8:2 FTS 10.6 128-Sep-18 15:1810.0 106 - 60 130 1.00 g24-Sep-18B8I016539108-34-4
MeFOSAA 10.0 128-Sep-18 15:1810.0 100 - 70 130 1.00 g24-Sep-18B8I01652355-31-9
EtFOSAA 9.23 128-Sep-18 15:1810.0 92.3 - 70 130 1.00 g24-Sep-18B8I01652991-50-6
PFUnA 10.5 128-Sep-18 15:1810.0 105 - 70 130 1.00 g24-Sep-18B8I01652058-94-8
PFDS 8.84 128-Sep-18 15:1810.0 88.4 - 60 130 1.00 g24-Sep-18B8I0165335-77-3
PFDoA 10.9 128-Sep-18 15:1810.0 109 - 70 130 1.00 g24-Sep-18B8I0165307-55-1
MeFOSA 55.5 128-Sep-18 15:1850.0 111 - 70 130 1.00 g24-Sep-18B8I016531506-32-8
PFTrDA 11.2 128-Sep-18 15:1810.0 112 - 60 130 1.00 g24-Sep-18B8I016572629-94-8
PFTeDA 11.6 128-Sep-18 15:1810.0 116 - 70 130 1.00 g24-Sep-18B8I0165376-06-7
EtFOSA 54.3 128-Sep-18 15:1850.0 109 - 70 130 1.00 g24-Sep-18B8I01654151-50-2
PFHxDA 9.99 128-Sep-18 15:1810.0 99.9 - 70 130 1.00 g24-Sep-18B8I016567905-19-5
MeFOSE 50.4 128-Sep-18 15:1850.0 101 - 70 130 1.00 g24-Sep-18B8I016524448-09-7
EtFOSE 49.5 128-Sep-18 15:1850.0 99.0 - 70 130 1.00 g24-Sep-18B8I01651691-99-2
Labeled Standards % Rec Limits Qualifiers Analyzed DilutionType Samp SizeExtractedBatch
IS - 13C3-PFBA 79.6 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - 13C3-PFPeA 76.8 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - 13C3-PFBS 85.2 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - 13C2-PFHxA 81.9 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - 13C4-PFHpA 83.6 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - 18O2-PFHxS 82.6 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - 13C2-6:2 FTS 85.8 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - 13C2-PFOA 73.9 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
Work Order 1802726 Page 16 of 62
Name:Project:
Client Data
Steamship Navigation
Sample ID: OPR
Matrix:
Laboratory Data
Lab Sample: B8I0165-BS1
VAL - PFAS
CES Inc. Column: BEH C18Solid
Labeled Standards % Rec Limits Qualifiers Analyzed DilutionType Samp SizeExtractedBatch
IS - 13C5-PFNA 75.8 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - 13C8-PFOSA 34.2 50 150 H 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - 13C8-PFOS 83.6 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - 13C2-PFDA 66.9 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - 13C2-8:2 FTS 83.3 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - d3-MeFOSAA 68.6 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - d5-EtFOSAA 74.1 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - 13C2-PFUnA 60.4 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - 13C2-PFDoA 57.7 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - d3-MeFOSA 8.60 50 150 H 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - 13C2-PFTeDA 58.1 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - d5-EtFOSA 8.50 50 150 H 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - 13C2-PFHxDA 58.4 50 150 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - d7-MeFOSE 30.1 50 150 H 128-Sep-18 15:181.00 g24-Sep-18B8I0165
IS - d9-EtFOSE 28.9 50 150 H 128-Sep-18 15:181.00 g24-Sep-18B8I0165
Work Order 1802726 Page 17 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-10 (1.5-2.2)
Matrix:
Laboratory Data
Lab Sample: 1802726-01
VAL - PFAS
% Solids:
CES Inc.
93.6
Column: BEH C18Soil
23-Aug-18 09:10 Date Received: 28-Aug-18 09:30
Location: covered waste
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-18375-22-4
PFPeA 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-182706-90-3
PFBS 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-18375-73-5
PFHxA 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-18307-24-4
PFHpA 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-18375-85-9
PFHxS 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-18355-46-4
6:2 FTS 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-1827619-97-2
PFOA 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-18335-67-1
PFHpS 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-18375-92-8
PFNA 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-18375-95-1
PFOSA 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-18754-91-6
PFOS 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-181763-23-1
PFDA 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-18335-76-2
8:2 FTS 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-1839108-34-4
MeFOSAA 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-182355-31-9
EtFOSAA 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-182991-50-6
PFUnA 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-182058-94-8
PFDS 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-18335-77-3
PFDoA 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-18307-55-1
MeFOSA 1.91ND 14.90 9.80 28-Sep-18 16:01B8I0165 1.09 g24-Sep-1831506-32-8
PFTrDA 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-1872629-94-8
PFTeDA 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-18376-06-7
EtFOSA 1.91ND 14.90 9.80 28-Sep-18 16:01B8I0165 1.09 g24-Sep-184151-50-2
PFHxDA 0.828ND 10.980 1.96 28-Sep-18 16:01B8I0165 1.09 g24-Sep-1867905-19-5
MeFOSE 1.91ND 14.90 9.80 28-Sep-18 16:01B8I0165 1.09 g24-Sep-1824448-09-7
EtFOSE 1.91ND 14.90 9.80 28-Sep-18 16:01B8I0165 1.09 g24-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 80.3 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - 13C3-PFPeA 75.9 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - 13C3-PFBS 81.5 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - 13C2-PFHxA 82.7 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - 13C4-PFHpA 75.4 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - 18O2-PFHxS 75.3 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
Work Order 1802726 Page 18 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-10 (1.5-2.2)
Matrix:
Laboratory Data
Lab Sample: 1802726-01
VAL - PFAS
% Solids:
CES Inc.
93.6
Column: BEH C18Soil
23-Aug-18 09:10 Date Received: 28-Aug-18 09:30
Location: covered waste
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 77.1 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - 13C2-PFOA 68.6 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - 13C5-PFNA 76.5 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - 13C8-PFOSA 37.6 50 150 H 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - 13C8-PFOS 82.2 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - 13C2-PFDA 72.2 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - 13C2-8:2 FTS 80.4 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - d3-MeFOSAA 63.1 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - d5-EtFOSAA 71.9 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - 13C2-PFUnA 69.1 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - 13C2-PFDoA 70.8 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - d3-MeFOSA 6.90 50 150 H 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - 13C2-PFTeDA 67.8 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - d5-EtFOSA 8.00 50 150 H 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - 13C2-PFHxDA 70.7 50 150 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - d7-MeFOSE 34.5 50 150 H 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 g
IS - d9-EtFOSE 37.7 50 150 H 128-Sep-18 16:01B8I0165 24-Sep-18 1.09 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 19 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-09 (0-1.2)
Matrix:
Laboratory Data
Lab Sample: 1802726-02
VAL - PFAS
% Solids:
CES Inc.
76.6
Column: BEH C18Soil
23-Aug-18 09:30 Date Received: 28-Aug-18 09:30
Location: covered waste
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-18375-22-4
PFPeA 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-182706-90-3
PFBS 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-18375-73-5
PFHxA 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-18307-24-4
PFHpA 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-18375-85-9
PFHxS 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-18355-46-4
6:2 FTS 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-1827619-97-2
PFOA 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-18335-67-1
PFHpS 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-18375-92-8
PFNA 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-18375-95-1
PFOSA 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-18754-91-6
PFOS 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-181763-23-1
PFDA 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-18335-76-2
8:2 FTS 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-1839108-34-4
MeFOSAA 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-182355-31-9
EtFOSAA 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-182991-50-6
PFUnA 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-182058-94-8
PFDS 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-18335-77-3
PFDoA 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-18307-55-1
MeFOSA 1.90ND 14.87 9.74 21-Sep-18 16:09B8H0237 1.34 g05-Sep-1831506-32-8
PFTrDA 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-1872629-94-8
PFTeDA 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-18376-06-7
EtFOSA 1.90ND 14.87 9.74 21-Sep-18 16:09B8H0237 1.34 g05-Sep-184151-50-2
PFHxDA 0.823ND 10.974 1.95 21-Sep-18 16:09B8H0237 1.34 g05-Sep-1867905-19-5
MeFOSE 1.90ND 14.87 9.74 21-Sep-18 16:09B8H0237 1.34 g05-Sep-1824448-09-7
EtFOSE 1.90ND 14.87 9.74 21-Sep-18 16:09B8H0237 1.34 g05-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 87.7 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - 13C3-PFPeA 84.5 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - 13C3-PFBS 90.5 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - 13C2-PFHxA 83.4 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - 13C4-PFHpA 86.8 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - 18O2-PFHxS 83.6 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
Work Order 1802726 Page 20 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-09 (0-1.2)
Matrix:
Laboratory Data
Lab Sample: 1802726-02
VAL - PFAS
% Solids:
CES Inc.
76.6
Column: BEH C18Soil
23-Aug-18 09:30 Date Received: 28-Aug-18 09:30
Location: covered waste
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 90.0 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - 13C2-PFOA 82.0 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - 13C5-PFNA 80.3 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - 13C8-PFOSA 53.7 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - 13C8-PFOS 83.7 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - 13C2-PFDA 76.3 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - 13C2-8:2 FTS 89.5 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - d3-MeFOSAA 65.7 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - d5-EtFOSAA 65.5 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - 13C2-PFUnA 77.2 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - 13C2-PFDoA 75.8 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - d3-MeFOSA 22.3 50 150 H 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - 13C2-PFTeDA 82.3 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - d5-EtFOSA 25.4 50 150 H 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - 13C2-PFHxDA 78.7 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - d7-MeFOSE 47.6 50 150 H 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 g
IS - d9-EtFOSE 51.1 50 150 121-Sep-18 16:09B8H0237 05-Sep-18 1.34 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 21 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-09 (6.9-7.9)
Matrix:
Laboratory Data
Lab Sample: 1802726-03
VAL - PFAS
% Solids:
CES Inc.
89.3
Column: BEH C18Soil
23-Aug-18 09:53 Date Received: 28-Aug-18 09:30
Location: covered waste
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-18375-22-4
PFPeA 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-182706-90-3
PFBS 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-18375-73-5
PFHxA 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-18307-24-4
PFHpA 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-18375-85-9
PFHxS 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-18355-46-4
6:2 FTS 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-1827619-97-2
PFOA 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-18335-67-1
PFHpS 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-18375-92-8
PFNA 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-18375-95-1
PFOSA 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-18754-91-6
PFOS 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-181763-23-1
PFDA 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-18335-76-2
8:2 FTS 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-1839108-34-4
MeFOSAA 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-182355-31-9
EtFOSAA 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-182991-50-6
PFUnA 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-182058-94-8
PFDS 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-18335-77-3
PFDoA 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-18307-55-1
MeFOSA 1.91ND 14.91 9.82 28-Sep-18 16:12B8I0165 1.14 g24-Sep-1831506-32-8
PFTrDA 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-1872629-94-8
PFTeDA 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-18376-06-7
EtFOSA 1.91ND 14.91 9.82 28-Sep-18 16:12B8I0165 1.14 g24-Sep-184151-50-2
PFHxDA 0.830ND 10.982 1.96 28-Sep-18 16:12B8I0165 1.14 g24-Sep-1867905-19-5
MeFOSE 1.91ND 14.91 9.82 28-Sep-18 16:12B8I0165 1.14 g24-Sep-1824448-09-7
EtFOSE 1.91ND 14.91 9.82 28-Sep-18 16:12B8I0165 1.14 g24-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 77.9 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - 13C3-PFPeA 70.6 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - 13C3-PFBS 77.3 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - 13C2-PFHxA 78.7 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - 13C4-PFHpA 77.5 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - 18O2-PFHxS 78.2 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
Work Order 1802726 Page 22 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-09 (6.9-7.9)
Matrix:
Laboratory Data
Lab Sample: 1802726-03
VAL - PFAS
% Solids:
CES Inc.
89.3
Column: BEH C18Soil
23-Aug-18 09:53 Date Received: 28-Aug-18 09:30
Location: covered waste
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 81.8 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - 13C2-PFOA 73.9 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - 13C5-PFNA 70.3 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - 13C8-PFOSA 39.1 50 150 H 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - 13C8-PFOS 86.3 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - 13C2-PFDA 59.2 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - 13C2-8:2 FTS 86.6 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - d3-MeFOSAA 60.1 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - d5-EtFOSAA 68.9 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - 13C2-PFUnA 66.4 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - 13C2-PFDoA 70.6 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - d3-MeFOSA 8.70 50 150 H 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - 13C2-PFTeDA 52.4 50 150 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - d5-EtFOSA 8.20 50 150 H 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - 13C2-PFHxDA 40.2 50 150 H 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - d7-MeFOSE 36.2 50 150 H 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 g
IS - d9-EtFOSE 37.2 50 150 H 128-Sep-18 16:12B8I0165 24-Sep-18 1.14 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 23 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-08 (1-2)
Matrix:
Laboratory Data
Lab Sample: 1802726-04
VAL - PFAS
% Solids:
CES Inc.
74.1
Column: BEH C18Soil
23-Aug-18 10:30 Date Received: 28-Aug-18 09:30
Location: covered waste
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-18375-22-4
PFPeA 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-182706-90-3
PFBS 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-18375-73-5
PFHxA 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-18307-24-4
PFHpA 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-18375-85-9
PFHxS 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-18355-46-4
6:2 FTS 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-1827619-97-2
PFOA 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-18335-67-1
PFHpS 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-18375-92-8
PFNA 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-18375-95-1
PFOSA 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-18754-91-6
PFOS 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-181763-23-1
PFDA 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-18335-76-2
8:2 FTS 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-1839108-34-4
MeFOSAA 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-182355-31-9
EtFOSAA 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-182991-50-6
PFUnA 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-182058-94-8
PFDS 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-18335-77-3
PFDoA 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-18307-55-1
MeFOSA 1.94ND 14.96 9.93 21-Sep-18 16:30B8H0237 1.36 g05-Sep-1831506-32-8
PFTrDA 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-1872629-94-8
PFTeDA 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-18376-06-7
EtFOSA 1.94ND 14.96 9.93 21-Sep-18 16:30B8H0237 1.36 g05-Sep-184151-50-2
PFHxDA 0.839ND 10.993 1.99 21-Sep-18 16:30B8H0237 1.36 g05-Sep-1867905-19-5
MeFOSE 1.94ND 14.96 9.93 21-Sep-18 16:30B8H0237 1.36 g05-Sep-1824448-09-7
EtFOSE 1.94ND 14.96 9.93 21-Sep-18 16:30B8H0237 1.36 g05-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 85.6 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - 13C3-PFPeA 81.7 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - 13C3-PFBS 88.8 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - 13C2-PFHxA 81.7 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - 13C4-PFHpA 87.4 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - 18O2-PFHxS 76.8 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
Work Order 1802726 Page 24 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-08 (1-2)
Matrix:
Laboratory Data
Lab Sample: 1802726-04
VAL - PFAS
% Solids:
CES Inc.
74.1
Column: BEH C18Soil
23-Aug-18 10:30 Date Received: 28-Aug-18 09:30
Location: covered waste
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 97.5 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - 13C2-PFOA 79.1 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - 13C5-PFNA 80.5 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - 13C8-PFOSA 44.6 50 150 H 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - 13C8-PFOS 76.4 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - 13C2-PFDA 71.9 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - 13C2-8:2 FTS 88.1 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - d3-MeFOSAA 69.8 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - d5-EtFOSAA 75.2 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - 13C2-PFUnA 70.7 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - 13C2-PFDoA 75.0 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - d3-MeFOSA 23.9 50 150 H 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - 13C2-PFTeDA 81.9 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - d5-EtFOSA 26.6 50 150 H 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - 13C2-PFHxDA 84.2 50 150 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - d7-MeFOSE 43.3 50 150 H 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 g
IS - d9-EtFOSE 45.8 50 150 H 121-Sep-18 16:30B8H0237 05-Sep-18 1.36 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 25 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-08 (4.1-5.1)
Matrix:
Laboratory Data
Lab Sample: 1802726-05
VAL - PFAS
% Solids:
CES Inc.
81.9
Column: BEH C18Soil
23-Aug-18 10:35 Date Received: 28-Aug-18 09:30
Location: covered waste
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-18375-22-4
PFPeA 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-182706-90-3
PFBS 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-18375-73-5
PFHxA 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-18307-24-4
PFHpA 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-18375-85-9
PFHxS 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-18355-46-4
6:2 FTS 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-1827619-97-2
PFOA 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-18335-67-1
PFHpS 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-18375-92-8
PFNA 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-18375-95-1
PFOSA 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-18754-91-6
PFOS 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-181763-23-1
PFDA 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-18335-76-2
8:2 FTS 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-1839108-34-4
MeFOSAA 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-182355-31-9
EtFOSAA 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-182991-50-6
PFUnA 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-182058-94-8
PFDS 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-18335-77-3
PFDoA 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-18307-55-1
MeFOSA 1.86ND 14.77 9.54 28-Sep-18 16:22B8I0165 1.28 g24-Sep-1831506-32-8
PFTrDA 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-1872629-94-8
PFTeDA 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-18376-06-7
EtFOSA 1.86ND 14.77 9.54 28-Sep-18 16:22B8I0165 1.28 g24-Sep-184151-50-2
PFHxDA 0.806ND 10.954 1.91 28-Sep-18 16:22B8I0165 1.28 g24-Sep-1867905-19-5
MeFOSE 1.86ND 14.77 9.54 28-Sep-18 16:22B8I0165 1.28 g24-Sep-1824448-09-7
EtFOSE 1.86ND 14.77 9.54 28-Sep-18 16:22B8I0165 1.28 g24-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 80.1 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - 13C3-PFPeA 70.3 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - 13C3-PFBS 80.3 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - 13C2-PFHxA 75.8 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - 13C4-PFHpA 76.1 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - 18O2-PFHxS 73.8 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
Work Order 1802726 Page 26 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-08 (4.1-5.1)
Matrix:
Laboratory Data
Lab Sample: 1802726-05
VAL - PFAS
% Solids:
CES Inc.
81.9
Column: BEH C18Soil
23-Aug-18 10:35 Date Received: 28-Aug-18 09:30
Location: covered waste
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 79.8 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - 13C2-PFOA 69.0 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - 13C5-PFNA 71.0 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - 13C8-PFOSA 43.3 50 150 H 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - 13C8-PFOS 82.2 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - 13C2-PFDA 67.4 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - 13C2-8:2 FTS 79.6 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - d3-MeFOSAA 63.3 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - d5-EtFOSAA 68.5 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - 13C2-PFUnA 75.3 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - 13C2-PFDoA 75.7 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - d3-MeFOSA 4.70 50 150 H 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - 13C2-PFTeDA 69.2 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - d5-EtFOSA 4.90 50 150 H 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - 13C2-PFHxDA 79.1 50 150 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - d7-MeFOSE 36.6 50 150 H 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 g
IS - d9-EtFOSE 39.8 50 150 H 128-Sep-18 16:22B8I0165 24-Sep-18 1.28 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 27 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-07 (0-1)
Matrix:
Laboratory Data
Lab Sample: 1802726-06
VAL - PFAS
% Solids:
CES Inc.
82.1
Column: BEH C18Soil
23-Aug-18 11:00 Date Received: 28-Aug-18 09:30
Location: baled material
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-18375-22-4
PFPeA 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-182706-90-3
PFBS 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-18375-73-5
PFHxA 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-18307-24-4
PFHpA 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-18375-85-9
PFHxS 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-18355-46-4
6:2 FTS 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-1827619-97-2
PFOA 0.8171.17 J 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-18335-67-1
PFHpS 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-18375-92-8
PFNA 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-18375-95-1
PFOSA 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-18754-91-6
PFOS 0.81712.1 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-181763-23-1
PFDA 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-18335-76-2
8:2 FTS 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-1839108-34-4
MeFOSAA 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-182355-31-9
EtFOSAA 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-182991-50-6
PFUnA 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-182058-94-8
PFDS 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-18335-77-3
PFDoA 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-18307-55-1
MeFOSA 1.88ND 14.83 9.67 21-Sep-18 16:52B8H0237 1.26 g05-Sep-1831506-32-8
PFTrDA 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-1872629-94-8
PFTeDA 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-18376-06-7
EtFOSA 1.88ND 14.83 9.67 21-Sep-18 16:52B8H0237 1.26 g05-Sep-184151-50-2
PFHxDA 0.817ND 10.967 1.93 21-Sep-18 16:52B8H0237 1.26 g05-Sep-1867905-19-5
MeFOSE 1.88ND 14.83 9.67 21-Sep-18 16:52B8H0237 1.26 g05-Sep-1824448-09-7
EtFOSE 1.88ND 14.83 9.67 21-Sep-18 16:52B8H0237 1.26 g05-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 91.8 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - 13C3-PFPeA 88.1 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - 13C3-PFBS 89.2 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - 13C2-PFHxA 87.1 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - 13C4-PFHpA 91.0 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - 18O2-PFHxS 80.7 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
Work Order 1802726 Page 28 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-07 (0-1)
Matrix:
Laboratory Data
Lab Sample: 1802726-06
VAL - PFAS
% Solids:
CES Inc.
82.1
Column: BEH C18Soil
23-Aug-18 11:00 Date Received: 28-Aug-18 09:30
Location: baled material
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 105 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - 13C2-PFOA 81.9 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - 13C5-PFNA 79.6 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - 13C8-PFOSA 45.1 50 150 H 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - 13C8-PFOS 89.0 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - 13C2-PFDA 76.1 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - 13C2-8:2 FTS 94.4 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - d3-MeFOSAA 62.4 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - d5-EtFOSAA 69.2 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - 13C2-PFUnA 71.0 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - 13C2-PFDoA 77.7 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - d3-MeFOSA 22.4 50 150 H 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - 13C2-PFTeDA 75.1 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - d5-EtFOSA 26.8 50 150 H 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - 13C2-PFHxDA 70.3 50 150 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - d7-MeFOSE 39.4 50 150 H 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 g
IS - d9-EtFOSE 46.4 50 150 H 121-Sep-18 16:52B8H0237 05-Sep-18 1.26 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 29 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-08 (cover)
Matrix:
Laboratory Data
Lab Sample: 1802726-07
VAL - PFAS
% Solids:
CES Inc.
86.5
Column: BEH C18Soil
23-Aug-18 13:45 Date Received: 28-Aug-18 09:30
Location: covered material
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-18375-22-4
PFPeA 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-182706-90-3
PFBS 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-18375-73-5
PFHxA 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-18307-24-4
PFHpA 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-18375-85-9
PFHxS 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-18355-46-4
6:2 FTS 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-1827619-97-2
PFOA 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-18335-67-1
PFHpS 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-18375-92-8
PFNA 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-18375-95-1
PFOSA 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-18754-91-6
PFOS 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-181763-23-1
PFDA 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-18335-76-2
8:2 FTS 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-1839108-34-4
MeFOSAA 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-182355-31-9
EtFOSAA 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-182991-50-6
PFUnA 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-182058-94-8
PFDS 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-18335-77-3
PFDoA 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-18307-55-1
MeFOSA 1.94ND 14.98 9.97 21-Sep-18 17:02B8H0237 1.16 g05-Sep-1831506-32-8
PFTrDA 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-1872629-94-8
PFTeDA 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-18376-06-7
EtFOSA 1.94ND 14.98 9.97 21-Sep-18 17:02B8H0237 1.16 g05-Sep-184151-50-2
PFHxDA 0.842ND 10.997 1.99 21-Sep-18 17:02B8H0237 1.16 g05-Sep-1867905-19-5
MeFOSE 1.94ND 14.98 9.97 21-Sep-18 17:02B8H0237 1.16 g05-Sep-1824448-09-7
EtFOSE 1.94ND 14.98 9.97 21-Sep-18 17:02B8H0237 1.16 g05-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 92.1 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - 13C3-PFPeA 92.2 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - 13C3-PFBS 95.5 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - 13C2-PFHxA 90.6 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - 13C4-PFHpA 92.1 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - 18O2-PFHxS 92.7 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
Work Order 1802726 Page 30 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-08 (cover)
Matrix:
Laboratory Data
Lab Sample: 1802726-07
VAL - PFAS
% Solids:
CES Inc.
86.5
Column: BEH C18Soil
23-Aug-18 13:45 Date Received: 28-Aug-18 09:30
Location: covered material
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 99.7 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - 13C2-PFOA 87.7 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - 13C5-PFNA 81.3 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - 13C8-PFOSA 46.6 50 150 H 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - 13C8-PFOS 83.2 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - 13C2-PFDA 75.5 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - 13C2-8:2 FTS 97.3 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - d3-MeFOSAA 66.4 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - d5-EtFOSAA 71.7 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - 13C2-PFUnA 74.6 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - 13C2-PFDoA 77.8 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - d3-MeFOSA 22.2 50 150 H 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - 13C2-PFTeDA 80.2 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - d5-EtFOSA 25.8 50 150 H 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - 13C2-PFHxDA 78.3 50 150 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - d7-MeFOSE 41.4 50 150 H 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 g
IS - d9-EtFOSE 44.9 50 150 H 121-Sep-18 17:02B8H0237 05-Sep-18 1.16 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 31 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-05 (5-6)
Matrix:
Laboratory Data
Lab Sample: 1802726-08
VAL - PFAS
% Solids:
CES Inc.
73.9
Column: BEH C18Soil
23-Aug-18 12:15 Date Received: 28-Aug-18 09:30
Location: short paper fiber
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-18375-22-4
PFPeA 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-182706-90-3
PFBS 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-18375-73-5
PFHxA 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-18307-24-4
PFHpA 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-18375-85-9
PFHxS 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-18355-46-4
6:2 FTS 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-1827619-97-2
PFOA 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-18335-67-1
PFHpS 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-18375-92-8
PFNA 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-18375-95-1
PFOSA 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-18754-91-6
PFOS 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-181763-23-1
PFDA 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-18335-76-2
8:2 FTS 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-1839108-34-4
MeFOSAA 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-182355-31-9
EtFOSAA 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-182991-50-6
PFUnA 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-182058-94-8
PFDS 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-18335-77-3
PFDoA 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-18307-55-1
MeFOSA 1.90ND 14.87 9.73 28-Sep-18 16:33B8I0165 1.39 g24-Sep-1831506-32-8
PFTrDA 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-1872629-94-8
PFTeDA 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-18376-06-7
EtFOSA 1.90ND 14.87 9.73 28-Sep-18 16:33B8I0165 1.39 g24-Sep-184151-50-2
PFHxDA 0.822ND 10.973 1.95 28-Sep-18 16:33B8I0165 1.39 g24-Sep-1867905-19-5
MeFOSE 1.90ND 14.87 9.73 28-Sep-18 16:33B8I0165 1.39 g24-Sep-1824448-09-7
EtFOSE 1.90ND 14.87 9.73 28-Sep-18 16:33B8I0165 1.39 g24-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 81.9 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - 13C3-PFPeA 75.8 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - 13C3-PFBS 76.5 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - 13C2-PFHxA 80.6 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - 13C4-PFHpA 78.7 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - 18O2-PFHxS 69.7 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
Work Order 1802726 Page 32 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-05 (5-6)
Matrix:
Laboratory Data
Lab Sample: 1802726-08
VAL - PFAS
% Solids:
CES Inc.
73.9
Column: BEH C18Soil
23-Aug-18 12:15 Date Received: 28-Aug-18 09:30
Location: short paper fiber
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 101 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - 13C2-PFOA 70.9 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - 13C5-PFNA 75.0 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - 13C8-PFOSA 58.5 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - 13C8-PFOS 85.1 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - 13C2-PFDA 71.0 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - 13C2-8:2 FTS 96.7 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - d3-MeFOSAA 60.4 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - d5-EtFOSAA 64.0 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - 13C2-PFUnA 70.4 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - 13C2-PFDoA 78.1 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - d3-MeFOSA 20.3 50 150 H 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - 13C2-PFTeDA 68.8 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - d5-EtFOSA 23.7 50 150 H 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - 13C2-PFHxDA 71.9 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - d7-MeFOSE 48.7 50 150 H 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 g
IS - d9-EtFOSE 51.6 50 150 128-Sep-18 16:33B8I0165 24-Sep-18 1.39 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 33 of 62
VAL - PFASSample ID: DPT-05 (5-6)
B8I0165
Name:
Project:
Matrix:
Lab Sample:
QC Batch: Date Extracted:CES Inc.
Column: BEH C18Solid
Source Lab Sample: 1802726-08
24-Sep-18B8I0165-MS1/B8I0165-MSD1
1.32/1.31 gSamp Size:Steamship Navigation
Analyte
MS
(ng/g )
MS
QualsMS
Spike Amt
MS
% Rec
RPD
Limits
MSD
(ng/g )MSD
Quals
MSD
Spike Amt
MSD
% Rec
%Rec
LimitsRPD
Sample
(ng/g )
MS
Analyzed
MS
DilMSD
Analyzed
MSD
DilCAS Number
PFBA 10.5 10.3 102 0.97610.210.5 28-Sep-18 15:39 1103 28-Sep-18 15:50 1ND 30375-22-4 - 70 130
PFPeA 10.4 10.3 101 0.98510.210.4 28-Sep-18 15:39 1102 28-Sep-18 15:50 1ND 302706-90-3 - 70 130
PFBS 10.3 10.3 100 0.70210.210.1 28-Sep-18 15:39 199.3 28-Sep-18 15:50 1ND 30375-73-5 - 70 130
PFHxA 10.9 10.3 105 3.8810.210.4 28-Sep-18 15:39 1101 28-Sep-18 15:50 1ND 30307-24-4 - 70 130
PFHpA 10.4 10.3 101 0.99510.210.2 28-Sep-18 15:39 1100 28-Sep-18 15:50 1ND 30375-85-9 - 70 130
PFHxS 9.11 10.3 87.9 17.710.210.8 28-Sep-18 15:39 1105 28-Sep-18 15:50 1ND 30355-46-4 - 70 130
6:2 FTS 11.5 10.3 112 6.0610.212.2 28-Sep-18 15:39 1119 28-Sep-18 15:50 1ND 3027619-97-2 - 60 130
PFOA 12.1 10.3 114 3.5710.211.5 28-Sep-18 15:39 1110 28-Sep-18 15:50 1ND 30335-67-1 - 70 130
PFHpS 10.7 10.3 104 7.2710.29.86 28-Sep-18 15:39 196.7 28-Sep-18 15:50 1ND 30375-92-8 - 60 130
PFNA 10.6 10.3 103 1.9610.210.3 28-Sep-18 15:39 1101 28-Sep-18 15:50 1ND 30375-95-1 - 70 130
PFOSA 10.6 10.3 103 1.9610.210.3 28-Sep-18 15:39 1101 28-Sep-18 15:50 1ND 30754-91-6 - 70 130
PFOS 10.4 10.3 95.2 14.410.211.9 28-Sep-18 15:39 1110 28-Sep-18 15:50 1ND 301763-23-1 - 70 130
PFDA 10.5 10.3 102 5.2310.29.87 28-Sep-18 15:39 196.8 28-Sep-18 15:50 1ND 30335-76-2 - 70 130
8:2 FTS 11.5 10.3 111 7.4810.210.5 28-Sep-18 15:39 1103 28-Sep-18 15:50 1ND 3039108-34-4 - 60 130
MeFOSAA 10.6 10.3 102 0.97610.210.6 28-Sep-18 15:39 1103 28-Sep-18 15:50 1ND 302355-31-9 - 70 130
EtFOSAA 10.5 10.3 94.6 1.2810.210.2 28-Sep-18 15:39 193.4 28-Sep-18 15:50 1ND 302991-50-6 - 70 130
PFUnA 10.7 10.3 104 0.96610.210.6 28-Sep-18 15:39 1103 28-Sep-18 15:50 1ND 302058-94-8 - 70 130
PFDS 9.41 10.3 91.3 5.0210.29.79 28-Sep-18 15:39 196.0 28-Sep-18 15:50 1ND 30335-77-3 - 60 130
PFDoA 10.9 10.3 106 7.2310.210.1 28-Sep-18 15:39 198.6 28-Sep-18 15:50 1ND 30307-55-1 - 70 130
MeFOSA 55.6 51.6 108 1.8751.254.2 28-Sep-18 15:39 1106 28-Sep-18 15:50 1ND 3031506-32-8 - 70 130
PFTrDA 11.3 10.3 110 6.5710.210.5 28-Sep-18 15:39 1103 28-Sep-18 15:50 1ND 3072629-94-8 - 60 130
PFTeDA 11.9 10.3 116 1.7110.212.0 28-Sep-18 15:39 1118 28-Sep-18 15:50 1ND 30376-06-7 - 70 130
EtFOSA 56.9 51.6 110 7.8651.261.0 28-Sep-18 15:39 1119 28-Sep-18 15:50 1ND 304151-50-2 - 70 130
PFHxDA 9.91 10.3 96.0 5.0810.210.3 28-Sep-18 15:39 1101 28-Sep-18 15:50 1ND 3067905-19-5 - 70 130
MeFOSE 50.9 51.6 98.6 0.70751.250.8 28-Sep-18 15:39 199.3 28-Sep-18 15:50 1ND 3024448-09-7 - 70 130
EtFOSE 54.5 51.6 106 2.7951.255.6 28-Sep-18 15:39 1109 28-Sep-18 15:50 1ND 301691-99-2 - 70 130
Labeled StandardsMS
% Rec LimitsMS
QualsTypeMSD
% RecMSD
Quals
MS
Analyzed
MS
Dil
MSD
Analyzed
MSD
Dil
IS - 13C3-PFBA 50 15081.2 28-Sep-18 15:39 182.4 28-Sep-18 15:50 1
IS - 13C3-PFPeA 50 15080.0 28-Sep-18 15:39 178.7 28-Sep-18 15:50 1
IS - 13C3-PFBS 50 15082.5 28-Sep-18 15:39 186.8 28-Sep-18 15:50 1
IS - 13C2-PFHxA 50 15081.3 28-Sep-18 15:39 183.1 28-Sep-18 15:50 1
IS - 13C4-PFHpA 50 15079.8 28-Sep-18 15:39 182.3 28-Sep-18 15:50 1
IS - 18O2-PFHxS 50 15082.6 28-Sep-18 15:39 179.9 28-Sep-18 15:50 1
IS - 13C2-6:2 FTS 50 15086.4 28-Sep-18 15:39 192.3 28-Sep-18 15:50 1
Work Order 1802726 Page 34 of 62
VAL - PFASSample ID: DPT-05 (5-6)
B8I0165
Name:
Project:
Matrix:
Lab Sample:
QC Batch: Date Extracted:CES Inc.
Column: BEH C18Solid
Source Lab Sample: 1802726-08
24-Sep-18B8I0165-MS1/B8I0165-MSD1
1.32/1.31 gSamp Size:Steamship Navigation
Labeled StandardsMS
% Rec LimitsMS
QualsTypeMSD
% RecMSD
Quals
MS
Analyzed
MS
Dil
MSD
Analyzed
MSD
Dil
IS - 13C2-PFOA 50 15069.5 28-Sep-18 15:39 174.6 28-Sep-18 15:50 1
IS - 13C5-PFNA 50 15072.3 28-Sep-18 15:39 173.8 28-Sep-18 15:50 1
IS - 13C8-PFOSA 50 150H42.2 28-Sep-18 15:39 144.4 28-Sep-18 15:50 1H
IS - 13C8-PFOS 50 15086.1 28-Sep-18 15:39 182.7 28-Sep-18 15:50 1
IS - 13C2-PFDA 50 15071.5 28-Sep-18 15:39 172.9 28-Sep-18 15:50 1
IS - 13C2-8:2 FTS 50 15081.9 28-Sep-18 15:39 183.9 28-Sep-18 15:50 1
IS - d3-MeFOSAA 50 15067.9 28-Sep-18 15:39 168.3 28-Sep-18 15:50 1
IS - d5-EtFOSAA 50 15076.3 28-Sep-18 15:39 175.1 28-Sep-18 15:50 1
IS - 13C2-PFUnA 50 15070.1 28-Sep-18 15:39 167.8 28-Sep-18 15:50 1
IS - 13C2-PFDoA 50 15070.3 28-Sep-18 15:39 175.5 28-Sep-18 15:50 1
IS - d3-MeFOSA 50 150H15.4 28-Sep-18 15:39 119.8 28-Sep-18 15:50 1H
IS - 13C2-PFTeDA 50 15070.6 28-Sep-18 15:39 167.9 28-Sep-18 15:50 1
IS - d5-EtFOSA 50 150H19.0 28-Sep-18 15:39 124.6 28-Sep-18 15:50 1H
IS - 13C2-PFHxDA 50 15081.1 28-Sep-18 15:39 179.1 28-Sep-18 15:50 1
IS - d7-MeFOSE 50 150H41.2 28-Sep-18 15:39 143.8 28-Sep-18 15:50 1H
IS - d9-EtFOSE 50 150H41.9 28-Sep-18 15:39 144.1 28-Sep-18 15:50 1H
Work Order 1802726 Page 35 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-05 (8-9)
Matrix:
Laboratory Data
Lab Sample: 1802726-09
VAL - PFAS
% Solids:
CES Inc.
82.4
Column: BEH C18Soil
23-Aug-18 12:30 Date Received: 28-Aug-18 09:30
Location: short paper fiber
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-18375-22-4
PFPeA 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-182706-90-3
PFBS 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-18375-73-5
PFHxA 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-18307-24-4
PFHpA 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-18375-85-9
PFHxS 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-18355-46-4
6:2 FTS 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-1827619-97-2
PFOA 0.8331.04 J 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-18335-67-1
PFHpS 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-18375-92-8
PFNA 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-18375-95-1
PFOSA 0.8330.924 J 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-18754-91-6
PFOS 0.83313.1 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-181763-23-1
PFDA 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-18335-76-2
8:2 FTS 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-1839108-34-4
MeFOSAA 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-182355-31-9
EtFOSAA 0.8334.97 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-182991-50-6
PFUnA 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-182058-94-8
PFDS 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-18335-77-3
PFDoA 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-18307-55-1
MeFOSA 1.92ND 14.93 9.86 28-Sep-18 16:43B8I0165 1.23 g24-Sep-1831506-32-8
PFTrDA 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-1872629-94-8
PFTeDA 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-18376-06-7
EtFOSA 1.92ND 14.93 9.86 28-Sep-18 16:43B8I0165 1.23 g24-Sep-184151-50-2
PFHxDA 0.833ND 10.986 1.97 28-Sep-18 16:43B8I0165 1.23 g24-Sep-1867905-19-5
MeFOSE 1.92ND 14.93 9.86 28-Sep-18 16:43B8I0165 1.23 g24-Sep-1824448-09-7
EtFOSE 1.92ND 14.93 9.86 28-Sep-18 16:43B8I0165 1.23 g24-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 82.6 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - 13C3-PFPeA 77.3 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - 13C3-PFBS 87.1 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - 13C2-PFHxA 84.2 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - 13C4-PFHpA 80.9 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - 18O2-PFHxS 78.0 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
Work Order 1802726 Page 36 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-05 (8-9)
Matrix:
Laboratory Data
Lab Sample: 1802726-09
VAL - PFAS
% Solids:
CES Inc.
82.4
Column: BEH C18Soil
23-Aug-18 12:30 Date Received: 28-Aug-18 09:30
Location: short paper fiber
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 83.9 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - 13C2-PFOA 77.6 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - 13C5-PFNA 75.4 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - 13C8-PFOSA 54.2 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - 13C8-PFOS 81.9 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - 13C2-PFDA 68.5 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - 13C2-8:2 FTS 83.0 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - d3-MeFOSAA 57.4 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - d5-EtFOSAA 60.5 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - 13C2-PFUnA 71.1 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - 13C2-PFDoA 72.4 50 150 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - d3-MeFOSA 13.9 50 150 H 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - 13C2-PFTeDA 40.0 50 150 H 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - d5-EtFOSA 15.7 50 150 H 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - 13C2-PFHxDA 22.8 50 150 H 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - d7-MeFOSE 43.5 50 150 H 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 g
IS - d9-EtFOSE 44.3 50 150 H 128-Sep-18 16:43B8I0165 24-Sep-18 1.23 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 37 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-03 (0-1)
Matrix:
Laboratory Data
Lab Sample: 1802726-10
VAL - PFAS
% Solids:
CES Inc.
91.3
Column: BEH C18Soil
23-Aug-18 13:10 Date Received: 28-Aug-18 09:30
Location: baled material
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-18375-22-4
PFPeA 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-182706-90-3
PFBS 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-18375-73-5
PFHxA 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-18307-24-4
PFHpA 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-18375-85-9
PFHxS 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-18355-46-4
6:2 FTS 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-1827619-97-2
PFOA 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-18335-67-1
PFHpS 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-18375-92-8
PFNA 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-18375-95-1
PFOSA 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-18754-91-6
PFOS 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-181763-23-1
PFDA 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-18335-76-2
8:2 FTS 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-1839108-34-4
MeFOSAA 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-182355-31-9
EtFOSAA 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-182991-50-6
PFUnA 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-182058-94-8
PFDS 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-18335-77-3
PFDoA 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-18307-55-1
MeFOSA 1.92ND 14.93 9.86 28-Sep-18 16:54B8I0165 1.11 g24-Sep-1831506-32-8
PFTrDA 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-1872629-94-8
PFTeDA 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-18376-06-7
EtFOSA 1.92ND 14.93 9.86 28-Sep-18 16:54B8I0165 1.11 g24-Sep-184151-50-2
PFHxDA 0.834ND 10.986 1.97 28-Sep-18 16:54B8I0165 1.11 g24-Sep-1867905-19-5
MeFOSE 1.92ND 14.93 9.86 28-Sep-18 16:54B8I0165 1.11 g24-Sep-1824448-09-7
EtFOSE 1.92ND 14.93 9.86 28-Sep-18 16:54B8I0165 1.11 g24-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 78.7 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - 13C3-PFPeA 78.9 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - 13C3-PFBS 75.5 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - 13C2-PFHxA 77.3 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - 13C4-PFHpA 79.9 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - 18O2-PFHxS 76.0 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
Work Order 1802726 Page 38 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-03 (0-1)
Matrix:
Laboratory Data
Lab Sample: 1802726-10
VAL - PFAS
% Solids:
CES Inc.
91.3
Column: BEH C18Soil
23-Aug-18 13:10 Date Received: 28-Aug-18 09:30
Location: baled material
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 78.0 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - 13C2-PFOA 72.8 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - 13C5-PFNA 68.0 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - 13C8-PFOSA 45.6 50 150 H 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - 13C8-PFOS 80.6 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - 13C2-PFDA 64.7 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - 13C2-8:2 FTS 78.0 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - d3-MeFOSAA 65.8 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - d5-EtFOSAA 70.1 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - 13C2-PFUnA 73.6 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - 13C2-PFDoA 73.4 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - d3-MeFOSA 7.50 50 150 H 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - 13C2-PFTeDA 57.6 50 150 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - d5-EtFOSA 7.80 50 150 H 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - 13C2-PFHxDA 34.3 50 150 H 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - d7-MeFOSE 37.2 50 150 H 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 g
IS - d9-EtFOSE 39.9 50 150 H 128-Sep-18 16:54B8I0165 24-Sep-18 1.11 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 39 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-03 (3-4)
Matrix:
Laboratory Data
Lab Sample: 1802726-11
VAL - PFAS
% Solids:
CES Inc.
79.6
Column: BEH C18Soil
23-Aug-18 13:15 Date Received: 28-Aug-18 09:30
Location: baled material
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-18375-22-4
PFPeA 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-182706-90-3
PFBS 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-18375-73-5
PFHxA 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-18307-24-4
PFHpA 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-18375-85-9
PFHxS 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-18355-46-4
6:2 FTS 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-1827619-97-2
PFOA 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-18335-67-1
PFHpS 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-18375-92-8
PFNA 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-18375-95-1
PFOSA 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-18754-91-6
PFOS 0.8234.03 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-181763-23-1
PFDA 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-18335-76-2
8:2 FTS 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-1839108-34-4
MeFOSAA 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-182355-31-9
EtFOSAA 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-182991-50-6
PFUnA 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-182058-94-8
PFDS 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-18335-77-3
PFDoA 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-18307-55-1
MeFOSA 1.90ND 14.87 9.74 21-Sep-18 18:06B8H0237 1.29 g05-Sep-1831506-32-8
PFTrDA 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-1872629-94-8
PFTeDA 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-18376-06-7
EtFOSA 1.90ND 14.87 9.74 21-Sep-18 18:06B8H0237 1.29 g05-Sep-184151-50-2
PFHxDA 0.823ND 10.974 1.95 21-Sep-18 18:06B8H0237 1.29 g05-Sep-1867905-19-5
MeFOSE 1.90ND 14.87 9.74 21-Sep-18 18:06B8H0237 1.29 g05-Sep-1824448-09-7
EtFOSE 1.90ND 14.87 9.74 21-Sep-18 18:06B8H0237 1.29 g05-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 90.3 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - 13C3-PFPeA 86.0 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - 13C3-PFBS 95.6 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - 13C2-PFHxA 87.1 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - 13C4-PFHpA 92.8 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - 18O2-PFHxS 92.8 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
Work Order 1802726 Page 40 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-03 (3-4)
Matrix:
Laboratory Data
Lab Sample: 1802726-11
VAL - PFAS
% Solids:
CES Inc.
79.6
Column: BEH C18Soil
23-Aug-18 13:15 Date Received: 28-Aug-18 09:30
Location: baled material
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 96.0 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - 13C2-PFOA 83.4 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - 13C5-PFNA 79.3 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - 13C8-PFOSA 39.1 50 150 H 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - 13C8-PFOS 89.7 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - 13C2-PFDA 73.5 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - 13C2-8:2 FTS 92.2 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - d3-MeFOSAA 62.6 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - d5-EtFOSAA 68.4 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - 13C2-PFUnA 73.2 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - 13C2-PFDoA 76.0 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - d3-MeFOSA 18.1 50 150 H 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - 13C2-PFTeDA 86.1 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - d5-EtFOSA 19.4 50 150 H 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - 13C2-PFHxDA 78.1 50 150 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - d7-MeFOSE 37.2 50 150 H 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 g
IS - d9-EtFOSE 40.4 50 150 H 121-Sep-18 18:06B8H0237 05-Sep-18 1.29 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 41 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-01 (3-4)
Matrix:
Laboratory Data
Lab Sample: 1802726-12
VAL - PFAS
% Solids:
CES Inc.
75.2
Column: BEH C18Soil
23-Aug-18 14:15 Date Received: 28-Aug-18 09:30
Location: baled material
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-18375-22-4
PFPeA 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-182706-90-3
PFBS 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-18375-73-5
PFHxA 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-18307-24-4
PFHpA 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-18375-85-9
PFHxS 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-18355-46-4
6:2 FTS 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-1827619-97-2
PFOA 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-18335-67-1
PFHpS 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-18375-92-8
PFNA 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-18375-95-1
PFOSA 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-18754-91-6
PFOS 0.8333.55 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-181763-23-1
PFDA 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-18335-76-2
8:2 FTS 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-1839108-34-4
MeFOSAA 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-182355-31-9
EtFOSAA 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-182991-50-6
PFUnA 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-182058-94-8
PFDS 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-18335-77-3
PFDoA 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-18307-55-1
MeFOSA 1.92ND 14.93 9.86 21-Sep-18 18:16B8H0237 1.35 g05-Sep-1831506-32-8
PFTrDA 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-1872629-94-8
PFTeDA 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-18376-06-7
EtFOSA 1.92ND 14.93 9.86 21-Sep-18 18:16B8H0237 1.35 g05-Sep-184151-50-2
PFHxDA 0.833ND 10.986 1.97 21-Sep-18 18:16B8H0237 1.35 g05-Sep-1867905-19-5
MeFOSE 1.92ND 14.93 9.86 21-Sep-18 18:16B8H0237 1.35 g05-Sep-1824448-09-7
EtFOSE 1.92ND 14.93 9.86 21-Sep-18 18:16B8H0237 1.35 g05-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 88.3 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - 13C3-PFPeA 84.2 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - 13C3-PFBS 91.0 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - 13C2-PFHxA 86.7 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - 13C4-PFHpA 87.1 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - 18O2-PFHxS 86.5 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
Work Order 1802726 Page 42 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-01 (3-4)
Matrix:
Laboratory Data
Lab Sample: 1802726-12
VAL - PFAS
% Solids:
CES Inc.
75.2
Column: BEH C18Soil
23-Aug-18 14:15 Date Received: 28-Aug-18 09:30
Location: baled material
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 109 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - 13C2-PFOA 82.2 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - 13C5-PFNA 76.9 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - 13C8-PFOSA 53.6 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - 13C8-PFOS 92.9 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - 13C2-PFDA 70.4 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - 13C2-8:2 FTS 93.0 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - d3-MeFOSAA 70.0 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - d5-EtFOSAA 74.4 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - 13C2-PFUnA 75.0 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - 13C2-PFDoA 72.5 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - d3-MeFOSA 25.4 50 150 H 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - 13C2-PFTeDA 84.5 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - d5-EtFOSA 27.2 50 150 H 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - 13C2-PFHxDA 80.5 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - d7-MeFOSE 48.9 50 150 H 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 g
IS - d9-EtFOSE 50.7 50 150 121-Sep-18 18:16B8H0237 05-Sep-18 1.35 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 43 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-01 (7-8)
Matrix:
Laboratory Data
Lab Sample: 1802726-13
VAL - PFAS
% Solids:
CES Inc.
75.0
Column: BEH C18Soil
23-Aug-18 14:20 Date Received: 28-Aug-18 09:30
Location: baled material
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-18375-22-4
PFPeA 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-182706-90-3
PFBS 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-18375-73-5
PFHxA 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-18307-24-4
PFHpA 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-18375-85-9
PFHxS 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-18355-46-4
6:2 FTS 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-1827619-97-2
PFOA 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-18335-67-1
PFHpS 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-18375-92-8
PFNA 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-18375-95-1
PFOSA 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-18754-91-6
PFOS 0.8353.37 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-181763-23-1
PFDA 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-18335-76-2
8:2 FTS 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-1839108-34-4
MeFOSAA 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-182355-31-9
EtFOSAA 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-182991-50-6
PFUnA 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-182058-94-8
PFDS 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-18335-77-3
PFDoA 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-18307-55-1
MeFOSA 1.93ND 14.94 9.88 28-Sep-18 17:05B8I0165 1.35 g24-Sep-1831506-32-8
PFTrDA 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-1872629-94-8
PFTeDA 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-18376-06-7
EtFOSA 1.93ND 14.94 9.88 28-Sep-18 17:05B8I0165 1.35 g24-Sep-184151-50-2
PFHxDA 0.835ND 10.988 1.98 28-Sep-18 17:05B8I0165 1.35 g24-Sep-1867905-19-5
MeFOSE 1.93ND 14.94 9.88 28-Sep-18 17:05B8I0165 1.35 g24-Sep-1824448-09-7
EtFOSE 1.93ND 14.94 9.88 28-Sep-18 17:05B8I0165 1.35 g24-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 82.1 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - 13C3-PFPeA 81.0 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - 13C3-PFBS 81.0 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - 13C2-PFHxA 78.6 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - 13C4-PFHpA 74.8 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - 18O2-PFHxS 74.7 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
Work Order 1802726 Page 44 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-01 (7-8)
Matrix:
Laboratory Data
Lab Sample: 1802726-13
VAL - PFAS
% Solids:
CES Inc.
75.0
Column: BEH C18Soil
23-Aug-18 14:20 Date Received: 28-Aug-18 09:30
Location: baled material
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 80.5 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - 13C2-PFOA 63.8 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - 13C5-PFNA 61.5 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - 13C8-PFOSA 41.5 50 150 H 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - 13C8-PFOS 82.0 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - 13C2-PFDA 61.4 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - 13C2-8:2 FTS 81.1 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - d3-MeFOSAA 60.7 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - d5-EtFOSAA 64.5 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - 13C2-PFUnA 65.7 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - 13C2-PFDoA 72.0 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - d3-MeFOSA 8.00 50 150 H 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - 13C2-PFTeDA 70.3 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - d5-EtFOSA 8.00 50 150 H 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - 13C2-PFHxDA 74.1 50 150 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - d7-MeFOSE 35.1 50 150 H 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 g
IS - d9-EtFOSE 37.9 50 150 H 128-Sep-18 17:05B8I0165 24-Sep-18 1.35 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 45 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-02 (1-2)
Matrix:
Laboratory Data
Lab Sample: 1802726-14
VAL - PFAS
% Solids:
CES Inc.
84.8
Column: BEH C18Soil
23-Aug-18 16:05 Date Received: 28-Aug-18 09:30
Location: baled material
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-18375-22-4
PFPeA 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-182706-90-3
PFBS 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-18375-73-5
PFHxA 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-18307-24-4
PFHpA 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-18375-85-9
PFHxS 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-18355-46-4
6:2 FTS 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-1827619-97-2
PFOA 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-18335-67-1
PFHpS 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-18375-92-8
PFNA 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-18375-95-1
PFOSA 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-18754-91-6
PFOS 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-181763-23-1
PFDA 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-18335-76-2
8:2 FTS 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-1839108-34-4
MeFOSAA 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-182355-31-9
EtFOSAA 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-182991-50-6
PFUnA 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-182058-94-8
PFDS 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-18335-77-3
PFDoA 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-18307-55-1
MeFOSA 1.93ND 14.95 9.91 21-Sep-18 18:37B8H0237 1.19 g05-Sep-1831506-32-8
PFTrDA 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-1872629-94-8
PFTeDA 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-18376-06-7
EtFOSA 1.93ND 14.95 9.91 21-Sep-18 18:37B8H0237 1.19 g05-Sep-184151-50-2
PFHxDA 0.837ND 10.991 1.98 21-Sep-18 18:37B8H0237 1.19 g05-Sep-1867905-19-5
MeFOSE 1.93ND 14.95 9.91 21-Sep-18 18:37B8H0237 1.19 g05-Sep-1824448-09-7
EtFOSE 1.93ND 14.95 9.91 21-Sep-18 18:37B8H0237 1.19 g05-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 93.1 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - 13C3-PFPeA 90.0 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - 13C3-PFBS 94.1 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - 13C2-PFHxA 90.8 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - 13C4-PFHpA 88.7 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - 18O2-PFHxS 87.0 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
Work Order 1802726 Page 46 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-02 (1-2)
Matrix:
Laboratory Data
Lab Sample: 1802726-14
VAL - PFAS
% Solids:
CES Inc.
84.8
Column: BEH C18Soil
23-Aug-18 16:05 Date Received: 28-Aug-18 09:30
Location: baled material
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 89.1 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - 13C2-PFOA 81.5 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - 13C5-PFNA 78.6 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - 13C8-PFOSA 46.2 50 150 H 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - 13C8-PFOS 86.2 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - 13C2-PFDA 75.5 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - 13C2-8:2 FTS 93.6 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - d3-MeFOSAA 71.9 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - d5-EtFOSAA 72.2 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - 13C2-PFUnA 73.7 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - 13C2-PFDoA 79.3 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - d3-MeFOSA 17.8 50 150 H 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - 13C2-PFTeDA 86.3 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - d5-EtFOSA 18.9 50 150 H 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - 13C2-PFHxDA 86.7 50 150 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - d7-MeFOSE 43.9 50 150 H 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 g
IS - d9-EtFOSE 44.3 50 150 H 121-Sep-18 18:37B8H0237 05-Sep-18 1.19 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 47 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-02 (9-10)
Matrix:
Laboratory Data
Lab Sample: 1802726-15
VAL - PFAS
% Solids:
CES Inc.
89.1
Column: BEH C18Soil
23-Aug-18 16:15 Date Received: 28-Aug-18 09:30
Location: baled material
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-18375-22-4
PFPeA 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-182706-90-3
PFBS 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-18375-73-5
PFHxA 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-18307-24-4
PFHpA 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-18375-85-9
PFHxS 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-18355-46-4
6:2 FTS 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-1827619-97-2
PFOA 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-18335-67-1
PFHpS 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-18375-92-8
PFNA 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-18375-95-1
PFOSA 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-18754-91-6
PFOS 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-181763-23-1
PFDA 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-18335-76-2
8:2 FTS 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-1839108-34-4
MeFOSAA 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-182355-31-9
EtFOSAA 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-182991-50-6
PFUnA 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-182058-94-8
PFDS 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-18335-77-3
PFDoA 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-18307-55-1
MeFOSA 1.95ND 15.01 10.0 28-Sep-18 17:15B8I0165 1.12 g24-Sep-1831506-32-8
PFTrDA 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-1872629-94-8
PFTeDA 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-18376-06-7
EtFOSA 1.95ND 15.01 10.0 28-Sep-18 17:15B8I0165 1.12 g24-Sep-184151-50-2
PFHxDA 0.847ND 11.00 2.00 28-Sep-18 17:15B8I0165 1.12 g24-Sep-1867905-19-5
MeFOSE 1.95ND 15.01 10.0 28-Sep-18 17:15B8I0165 1.12 g24-Sep-1824448-09-7
EtFOSE 1.95ND 15.01 10.0 28-Sep-18 17:15B8I0165 1.12 g24-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 82.1 50 150 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - 13C3-PFPeA 78.3 50 150 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - 13C3-PFBS 82.0 50 150 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - 13C2-PFHxA 77.1 50 150 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - 13C4-PFHpA 80.1 50 150 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - 18O2-PFHxS 84.8 50 150 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
Work Order 1802726 Page 48 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-02 (9-10)
Matrix:
Laboratory Data
Lab Sample: 1802726-15
VAL - PFAS
% Solids:
CES Inc.
89.1
Column: BEH C18Soil
23-Aug-18 16:15 Date Received: 28-Aug-18 09:30
Location: baled material
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 72.5 50 150 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - 13C2-PFOA 74.4 50 150 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - 13C5-PFNA 75.3 50 150 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - 13C8-PFOSA 35.3 50 150 H 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - 13C8-PFOS 79.0 50 150 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - 13C2-PFDA 59.3 50 150 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - 13C2-8:2 FTS 74.9 50 150 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - d3-MeFOSAA 51.5 50 150 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - d5-EtFOSAA 52.4 50 150 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - 13C2-PFUnA 49.6 50 150 H 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - 13C2-PFDoA 52.4 50 150 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - d3-MeFOSA 8.80 50 150 H 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - 13C2-PFTeDA 49.2 50 150 H 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - d5-EtFOSA 7.90 50 150 H 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - 13C2-PFHxDA 37.2 50 150 H 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - d7-MeFOSE 17.2 50 150 H 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 g
IS - d9-EtFOSE 13.8 50 150 H 128-Sep-18 17:15B8I0165 24-Sep-18 1.12 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 49 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-02 (13-14)
Matrix:
Laboratory Data
Lab Sample: 1802726-16
VAL - PFAS
% Solids:
CES Inc.
86.8
Column: BEH C18Soil
23-Aug-18 16:25 Date Received: 28-Aug-18 09:30
Location: baled material
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-18375-22-4
PFPeA 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-182706-90-3
PFBS 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-18375-73-5
PFHxA 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-18307-24-4
PFHpA 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-18375-85-9
PFHxS 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-18355-46-4
6:2 FTS 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-1827619-97-2
PFOA 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-18335-67-1
PFHpS 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-18375-92-8
PFNA 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-18375-95-1
PFOSA 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-18754-91-6
PFOS 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-181763-23-1
PFDA 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-18335-76-2
8:2 FTS 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-1839108-34-4
MeFOSAA 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-182355-31-9
EtFOSAA 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-182991-50-6
PFUnA 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-182058-94-8
PFDS 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-18335-77-3
PFDoA 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-18307-55-1
MeFOSA 1.92ND 14.92 9.85 28-Sep-18 17:47B8I0165 1.17 g24-Sep-1831506-32-8
PFTrDA 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-1872629-94-8
PFTeDA 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-18376-06-7
EtFOSA 1.92ND 14.92 9.85 28-Sep-18 17:47B8I0165 1.17 g24-Sep-184151-50-2
PFHxDA 0.832ND 10.985 1.97 28-Sep-18 17:47B8I0165 1.17 g24-Sep-1867905-19-5
MeFOSE 1.92ND 14.92 9.85 28-Sep-18 17:47B8I0165 1.17 g24-Sep-1824448-09-7
EtFOSE 1.92ND 14.92 9.85 28-Sep-18 17:47B8I0165 1.17 g24-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 83.6 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - 13C3-PFPeA 81.6 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - 13C3-PFBS 85.4 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - 13C2-PFHxA 83.6 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - 13C4-PFHpA 84.2 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - 18O2-PFHxS 86.3 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
Work Order 1802726 Page 50 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-02 (13-14)
Matrix:
Laboratory Data
Lab Sample: 1802726-16
VAL - PFAS
% Solids:
CES Inc.
86.8
Column: BEH C18Soil
23-Aug-18 16:25 Date Received: 28-Aug-18 09:30
Location: baled material
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 81.1 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - 13C2-PFOA 75.1 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - 13C5-PFNA 73.9 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - 13C8-PFOSA 39.1 50 150 H 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - 13C8-PFOS 79.6 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - 13C2-PFDA 59.0 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - 13C2-8:2 FTS 80.7 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - d3-MeFOSAA 57.4 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - d5-EtFOSAA 61.6 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - 13C2-PFUnA 56.1 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - 13C2-PFDoA 58.1 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - d3-MeFOSA 8.80 50 150 H 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - 13C2-PFTeDA 58.8 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - d5-EtFOSA 7.40 50 150 H 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - 13C2-PFHxDA 60.1 50 150 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - d7-MeFOSE 17.7 50 150 H 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 g
IS - d9-EtFOSE 16.7 50 150 H 128-Sep-18 17:47B8I0165 24-Sep-18 1.17 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 51 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-DUP 1
Matrix:
Laboratory Data
Lab Sample: 1802726-17
VAL - PFAS
% Solids:
CES Inc.
83.8
Column: BEH C18Soil
23-Aug-18 00:00 Date Received: 28-Aug-18 09:30
Location: duplicate
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-18375-22-4
PFPeA 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-182706-90-3
PFBS 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-18375-73-5
PFHxA 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-18307-24-4
PFHpA 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-18375-85-9
PFHxS 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-18355-46-4
6:2 FTS 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-1827619-97-2
PFOA 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-18335-67-1
PFHpS 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-18375-92-8
PFNA 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-18375-95-1
PFOSA 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-18754-91-6
PFOS 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-181763-23-1
PFDA 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-18335-76-2
8:2 FTS 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-1839108-34-4
MeFOSAA 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-182355-31-9
EtFOSAA 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-182991-50-6
PFUnA 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-182058-94-8
PFDS 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-18335-77-3
PFDoA 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-18307-55-1
MeFOSA 1.94ND 14.97 9.95 21-Sep-18 19:09B8H0237 1.20 g05-Sep-1831506-32-8
PFTrDA 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-1872629-94-8
PFTeDA 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-18376-06-7
EtFOSA 1.94ND 14.97 9.95 21-Sep-18 19:09B8H0237 1.20 g05-Sep-184151-50-2
PFHxDA 0.841ND 10.995 1.99 21-Sep-18 19:09B8H0237 1.20 g05-Sep-1867905-19-5
MeFOSE 1.94ND 14.97 9.95 21-Sep-18 19:09B8H0237 1.20 g05-Sep-1824448-09-7
EtFOSE 1.94ND 14.97 9.95 21-Sep-18 19:09B8H0237 1.20 g05-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 93.7 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - 13C3-PFPeA 92.3 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - 13C3-PFBS 97.2 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - 13C2-PFHxA 90.2 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - 13C4-PFHpA 95.4 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - 18O2-PFHxS 91.2 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
Work Order 1802726 Page 52 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-DUP 1
Matrix:
Laboratory Data
Lab Sample: 1802726-17
VAL - PFAS
% Solids:
CES Inc.
83.8
Column: BEH C18Soil
23-Aug-18 00:00 Date Received: 28-Aug-18 09:30
Location: duplicate
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 112 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - 13C2-PFOA 92.0 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - 13C5-PFNA 87.0 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - 13C8-PFOSA 46.4 50 150 H 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - 13C8-PFOS 90.9 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - 13C2-PFDA 75.8 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - 13C2-8:2 FTS 112 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - d3-MeFOSAA 77.3 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - d5-EtFOSAA 80.0 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - 13C2-PFUnA 76.4 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - 13C2-PFDoA 75.0 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - d3-MeFOSA 28.4 50 150 H 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - 13C2-PFTeDA 91.8 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - d5-EtFOSA 32.8 50 150 H 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - 13C2-PFHxDA 84.4 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - d7-MeFOSE 49.8 50 150 H 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 g
IS - d9-EtFOSE 53.4 50 150 121-Sep-18 19:09B8H0237 05-Sep-18 1.20 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 53 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-DUP 2
Matrix:
Laboratory Data
Lab Sample: 1802726-18
VAL - PFAS
% Solids:
CES Inc.
89.3
Column: BEH C18Soil
23-Aug-18 00:00 Date Received: 28-Aug-18 09:30
Location: duplicate
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-18375-22-4
PFPeA 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-182706-90-3
PFBS 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-18375-73-5
PFHxA 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-18307-24-4
PFHpA 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-18375-85-9
PFHxS 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-18355-46-4
6:2 FTS 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-1827619-97-2
PFOA 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-18335-67-1
PFHpS 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-18375-92-8
PFNA 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-18375-95-1
PFOSA 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-18754-91-6
PFOS 0.8382.66 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-181763-23-1
PFDA 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-18335-76-2
8:2 FTS 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-1839108-34-4
MeFOSAA 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-182355-31-9
EtFOSAA 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-182991-50-6
PFUnA 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-182058-94-8
PFDS 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-18335-77-3
PFDoA 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-18307-55-1
MeFOSA 1.93ND 14.96 9.91 28-Sep-18 17:58B8I0165 1.13 g24-Sep-1831506-32-8
PFTrDA 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-1872629-94-8
PFTeDA 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-18376-06-7
EtFOSA 1.93ND 14.96 9.91 28-Sep-18 17:58B8I0165 1.13 g24-Sep-184151-50-2
PFHxDA 0.838ND 10.991 1.98 28-Sep-18 17:58B8I0165 1.13 g24-Sep-1867905-19-5
MeFOSE 1.93ND 14.96 9.91 28-Sep-18 17:58B8I0165 1.13 g24-Sep-1824448-09-7
EtFOSE 1.93ND 14.96 9.91 28-Sep-18 17:58B8I0165 1.13 g24-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 81.3 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - 13C3-PFPeA 77.8 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - 13C3-PFBS 78.4 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - 13C2-PFHxA 78.6 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - 13C4-PFHpA 77.6 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - 18O2-PFHxS 78.5 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
Work Order 1802726 Page 54 of 62
Name:
Project: Date Collected:
Client Data
Steamship Navigation
Sample ID: DPT-DUP 2
Matrix:
Laboratory Data
Lab Sample: 1802726-18
VAL - PFAS
% Solids:
CES Inc.
89.3
Column: BEH C18Soil
23-Aug-18 00:00 Date Received: 28-Aug-18 09:30
Location: duplicate
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 79.7 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - 13C2-PFOA 69.7 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - 13C5-PFNA 68.5 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - 13C8-PFOSA 38.8 50 150 H 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - 13C8-PFOS 76.7 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - 13C2-PFDA 62.5 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - 13C2-8:2 FTS 81.0 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - d3-MeFOSAA 65.0 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - d5-EtFOSAA 70.4 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - 13C2-PFUnA 65.6 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - 13C2-PFDoA 71.3 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - d3-MeFOSA 7.60 50 150 H 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - 13C2-PFTeDA 65.3 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - d5-EtFOSA 7.00 50 150 H 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - 13C2-PFHxDA 70.8 50 150 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - d7-MeFOSE 30.9 50 150 H 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 g
IS - d9-EtFOSE 34.2 50 150 H 128-Sep-18 17:58B8I0165 24-Sep-18 1.13 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802726 Page 55 of 62
DATA QUALIFIERS & ABBREVIATIONS B This compound was also detected in the method blank Conc. Concentration D Dilution DL Detection limit E The associated compound concentration exceeded the calibration range of
the instrument H Recovery and/or RPD was outside laboratory acceptance limits I Chemical Interference J The amount detected is below the Reporting Limit/LOQ LOD Limits of Detection LOQ Limits of Quantitation M Estimated Maximum Possible Concentration (CA Region 2 projects only) NA Not applicable ND Not Detected Q Ion ratio outside of 70-130% of Standard Ratio. (DOD PFAS projects only) TEQ Toxic Equivalency U Not Detected (specific projects only) * See Cover Letter Unless otherwise noted, solid sample results are reported in dry weight. Tissue samples are reported in wet weight.
Work Order 1802726 Page 56 of 62
CERTIFICATIONS
Accrediting Authority Certificate Number
Alaska Department of Environmental Conservation 17-013
Arkansas Department of Environmental Quality 18-008-0
California Department of Health – ELAP 2892
DoD ELAP - A2LA Accredited - ISO/IEC 17025:2005 3091.01
Florida Department of Health E87777-18
Hawaii Department of Health N/A
Louisiana Department of Environmental Quality 01977
Maine Department of Health 2018017
Minnesota Department of Health 1322288
New Hampshire Environmental Accreditation Program 207717
New Jersey Department of Environmental Protection CA003
New York Department of Health 11411
Oregon Laboratory Accreditation Program 4042-009
Pennsylvania Department of Environmental Protection 014
Texas Commission on Environmental Quality T104704189-18-8
Virginia Department of General Services 9077
Washington Department of Ecology C584
Wisconsin Department of Natural Resources 998036160
Current certificates and lists of licensed parameters are located in the Quality Assurance office and are available upon request.
Work Order 1802726 Page 57 of 62
NELAP Accredited Test Methods
MATRIX: Air Description of Test Method Determination of Polychlorinated p-Dioxins & Polychlorinated Dibenzofurans
EPA 23
MATRIX: Biological Tissue Description of Test Method Tetra- through Octa-Chlorinated Dioxins and Furans by Isotope Dilution GC/HRMS
EPA 1613B
Brominated Diphenyl Ethers by HRGC/HRMS EPA 1614A Chlorinated Biphenyl Congeners in Water, Soil, Sediment, and Tissue by GC/HRMS
EPA 1668A/C
Pesticides in Water, Soil, Sediment, Biosolids, and Tissue by HRGC/HRMS
EPA 1699
Perfluorinated Alkyl Acids in Drinking Water by SPE and LC/MS/MS EPA 537 Polychlorinated Dibenzo-p-Dioxins and Polychlorinated Dibenzofurans by GC/HRMS
EPA 8280A/B
Polychlorinated Dibenzodioxins (PCDDs) and Polychlorinated Dibenzofurans (PCDFs) by GC/HRMS
EPA 8290/8290A
MATRIX: Drinking Water Description of Test Method 2,3,7,8-Tetrachlorodibenzo- p-dioxin (2,3,7,8-TCDD) GC/HRMS EPA 1613 Perfluorinated Alkyl Acids in Drinking Water by SPE and LC/MS/MS EPA 537
MATRIX: Non-Potable Water Description of Test Method Tetra- through Octa-Chlorinated Dioxins and Furans by Isotope Dilution GC/HRMS
EPA 1613B
Brominated Diphenyl Ethers by HRGC/HRMS EPA 1614A Chlorinated Biphenyl Congeners in Water, Soil, Sediment, and Tissue by GC/HRMS
EPA 1668A/C
Pesticides in Water, Soil, Sediment, Biosolids, and Tissue by HRGC/HRMS EPA 1699 Perfluorinated Alkyl Acids in Drinking Water by SPE and LC/MS/MS EPA 537 Dioxin by GC/HRMS EPA 613 Polychlorinated Dibenzo-p-Dioxins and Polychlorinated Dibenzofurans by GC/HRMS
EPA 8280A/B
Polychlorinated Dibenzodioxins (PCDDs) and Polychlorinated Dibenzofurans (PCDFs) by GC/HRMS
EPA 8290/8290A
Work Order 1802726 Page 58 of 62
MATRIX: Solids Description of Test Method Tetra-Octa Chlorinated Dioxins and Furans by Isotope Dilution GC/HRMS EPA 1613 Tetra- through Octa-Chlorinated Dioxins and Furans by Isotope Dilution GC/HRMS
EPA 1613B
Brominated Diphenyl Ethers by HRGC/HRMS EPA 1614A Chlorinated Biphenyl Congeners in Water, Soil, Sediment, and Tissue by GC/HRMS
EPA 1668A/C
Perfluorinated Alkyl Acids in Drinking Water by SPE and LC/MS/MS EPA 537 Polychlorinated Dibenzo-p-Dioxins and Polychlorinated Dibenzofurans by GC/HRMS
EPA 8280A/B
Polychlorinated Dibenzodioxins (PCDDs) and Polychlorinated Dibenzofurans (PCDFs) by GC/HRMS
EPA 8290/8290A
Work Order 1802726 Page 59 of 62
Enclosed are the results for the sample set received at Vista Analytical Laboratory on August 31, 2018 under your
Project Name 'Steamship Navigation PFAS'.
Vista Analytical Laboratory is committed to serving you effectively. If you require additional information, please
contact me at 916-673-1520 or by email at [email protected].
Thank you for choosing Vista as part of your analytical support team.
Sincerely,
Martha Maier
Laboratory Director
September 28, 2018
Vista Work Order No. 1802846
CES Inc.
640 Main Street
Lewiston, ME 0240
Dear Mr. Buckman,
Mr. Chris Buckman
Vista Analytical Laboratory certifies that the report herein meets all the requirements set forth by NELAP for those applicable test
methods. Results relate only to the samples as received by the laboratory. This report should not be reproduced except in full without
the written approval of Vista.
Vista Analytical Laboratory 1104 Windfield Way El Dorado Hills, CA 95762 ph: 916-673-1520 fx: 916-673-0106 www.vista-analytical.com
Work Order 1802846 Page 1 of 47
Vista Work Order No. 1802846
Case Narrative
Sample Condition on Receipt:
Nine soil samples and three aqueous samples were received in good condition and within the method temperature
requirements. The samples were received and stored securely in accordance with Vista standard operating
procedures and EPA methodology.
Analytical Notes:
PFAS Isotope Dilution Method
The aqueous samples were extracted and analyzed for a selected list of PFAS using Vista's PFAS Isotope Dilution
Method. This method is listed on Vista's NELAP certificate as Modifed EPA Method 537. The results for
PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both linear and branched isomers. Results for all
other analytes include the linear isomers only.
Samples "TW-2" contained particulate and were centrifuged prior to extraction.
Holding Times
The samples were originally extracted and analyzed within the method hold times. The samples required
re-extractions, which were performed outside of the hold time.
Quality Control
The Initial Calibration and Continuing Calibration Verifications met the method acceptance criteria.
A Method Blank and Ongoing Precision and Recovery (OPR) sample were extracted and analyzed with the
preparation batch. No analytes were detected in the Method Blank above 1/2 the LOQ. The recoveries of
MeFOSA was greater than 130% in the OPR. This analyte was not detected in the samples. The recoveries of all
other analytes were within the method acceptance criteria.
The labeled standard recoveries outside the acceptance criteria are listed in the table below.
VAL-PFAS
The soil samples were extracted and analyzed for a selected list of PFAS using VAL Method PFAS. The results
for PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both linear and branched isomers. Results for all
other analytes include the linear isomers only.
Holding Times
The samples were extracted and analyzed within the hold times.
Work Order 1802846 Page 2 of 47
Quality Control
The Initial Calibration and Continuing Calibration Verifications met the method acceptance criteria.
A Method Blank and Ongoing Precision and Recovery (OPR) sample were extracted and analyzed with the
preparation batch. No analytes were detected in the Method Blank above 1/2 the LOQ. The OPR recoveries
were within the method acceptance criteria.
The labeled standard recoveries outside the acceptance criteria are listed in the table below.
Work Order 1802846 Page 3 of 47
QC Anomalies
LabNumber SampleName Analysis Analyte Flag %Rec
1802846-01 Covered Waste-Inner VAL - PFAS d3-MeFOSA H 36.0
1802846-01 Covered Waste-Inner VAL - PFAS d5-EtFOSA H 41.8
1802846-02 Covered Waste-Replicate VAL - PFAS d3-MeFOSA H 33.2
1802846-02 Covered Waste-Replicate VAL - PFAS d5-EtFOSA H 39.4
1802846-02 Covered Waste-Replicate VAL - PFAS d7-MeFOSE H 49.9
1802846-03 SPF-Inner VAL - PFAS d3-MeFOSA H 21.9
1802846-03 SPF-Inner VAL - PFAS d5-EtFOSA H 25.3
1802846-03 SPF-Inner VAL - PFAS d7-MeFOSE H 42.7
1802846-03 SPF-Inner VAL - PFAS d9-EtFOSE H 45.3
1802846-04 SPF-Replicate VAL - PFAS d3-MeFOSA H 31.0
1802846-04 SPF-Replicate VAL - PFAS d5-EtFOSA H 35.3
1802846-04 SPF-Replicate VAL - PFAS d7-MeFOSE H 49.0
1802846-05 BM-Inner VAL - PFAS d3-MeFOSA H 23.3
1802846-05 BM-Inner VAL - PFAS d5-EtFOSA H 26.8
1802846-05 BM-Inner VAL - PFAS d7-MeFOSE H 42.5
1802846-05 BM-Inner VAL - PFAS d9-EtFOSE H 45.8
1802846-06 BM-Replicate VAL - PFAS d3-MeFOSA H 28.6
1802846-06 BM-Replicate VAL - PFAS d5-EtFOSA H 29.3
1802846-06 BM-Replicate VAL - PFAS d7-MeFOSE H 45.6
1802846-06 BM-Replicate VAL - PFAS d9-EtFOSE H 49.9
1802846-07 EQ-1 PFAS Isotope Dilution Method 13C8-PFOSA H 25.7
1802846-07 EQ-1 PFAS Isotope Dilution Method d3-MeFOSA H 2.20
1802846-07 EQ-1 PFAS Isotope Dilution Method d5-EtFOSA H 2.60
1802846-07 EQ-1 PFAS Isotope Dilution Method d7-MeFOSE H 36.8
1802846-07 EQ-1 PFAS Isotope Dilution Method d9-EtFOSE H 41.1
1802846-08 EQ-2 PFAS Isotope Dilution Method 13C8-PFOSA H 27.3
1802846-08 EQ-2 PFAS Isotope Dilution Method d3-MeFOSA H 1.30
1802846-08 EQ-2 PFAS Isotope Dilution Method d5-EtFOSA H 1.50
1802846-08 EQ-2 PFAS Isotope Dilution Method 13C2-PFHxDA H 153
1802846-08 EQ-2 PFAS Isotope Dilution Method d7-MeFOSE H 33.5
1802846-08 EQ-2 PFAS Isotope Dilution Method d9-EtFOSE H 38.0
1802846-09 TW-2 PFAS Isotope Dilution Method d3-MeFOSA H 8.50
1802846-09 TW-2 PFAS Isotope Dilution Method d5-EtFOSA H 10.0
1802846-10 CW-Outer VAL - PFAS d3-MeFOSA H 24.3
1802846-10 CW-Outer VAL - PFAS d5-EtFOSA H 26.6
1802846-10 CW-Outer VAL - PFAS d7-MeFOSE H 42.3
1802846-10 CW-Outer VAL - PFAS d9-EtFOSE H 45.4
1802846-11 BM-Outer VAL - PFAS d3-MeFOSA H 25.7
1802846-11 BM-Outer VAL - PFAS d5-EtFOSA H 28.3
1802846-11 BM-Outer VAL - PFAS d7-MeFOSE H 42.7
1802846-11 BM-Outer VAL - PFAS d9-EtFOSE H 45.1
1802846-12 SPF-Outer VAL - PFAS d3-MeFOSA H 24.5
1802846-12 SPF-Outer VAL - PFAS d5-EtFOSA H 27.1
1802846-12 SPF-Outer VAL - PFAS d7-MeFOSE H 39.3
1802846-12 SPF-Outer VAL - PFAS d9-EtFOSE H 41.4
B8I0057-BLK1 B8I0057-BLK1 VAL - PFAS 13C8-PFOSA H 44.0
B8I0057-BLK1 B8I0057-BLK1 VAL - PFAS d3-MeFOSA H 12.3
B8I0057-BLK1 B8I0057-BLK1 VAL - PFAS d5-EtFOSA H 10.3
B8I0057-BLK1 B8I0057-BLK1 VAL - PFAS d7-MeFOSE H 22.3
B8I0057-BLK1 B8I0057-BLK1 VAL - PFAS d9-EtFOSE H 21.1
B8I0057-BS1 B8I0057-BS1 VAL - PFAS 13C8-PFOSA H 46.9
B8I0057-BS1 B8I0057-BS1 VAL - PFAS d3-MeFOSA H 11.5
Work Order 1802846 Page 4 of 47
QC Anomalies
LabNumber SampleName Analysis Analyte Flag %Rec
B8I0057-BS1 B8I0057-BS1 VAL - PFAS d5-EtFOSA H 10.6
B8I0057-BS1 B8I0057-BS1 VAL - PFAS d7-MeFOSE H 32.5
B8I0057-BS1 B8I0057-BS1 VAL - PFAS d9-EtFOSE H 31.7
B8I0151-BLK1 B8I0151-BLK1 PFAS Isotope Dilution Method 13C8-PFOSA H 36.2
B8I0151-BLK1 B8I0151-BLK1 PFAS Isotope Dilution Method d3-MeFOSA H 4.40
B8I0151-BLK1 B8I0151-BLK1 PFAS Isotope Dilution Method d5-EtFOSA H 3.90
B8I0151-BLK1 B8I0151-BLK1 PFAS Isotope Dilution Method d7-MeFOSE H 33.5
B8I0151-BLK1 B8I0151-BLK1 PFAS Isotope Dilution Method d9-EtFOSE H 32.8
B8I0151-BS1 B8I0151-BS1 PFAS Isotope Dilution Method 13C8-PFOSA H 47.8
B8I0151-BS1 B8I0151-BS1 PFAS Isotope Dilution Method d3-MeFOSA H 5.10
B8I0151-BS1 B8I0151-BS1 PFAS Isotope Dilution Method d5-EtFOSA H 5.90
H = Recovery was outside laboratory acceptance criteria.
Work Order 1802846 Page 5 of 47
TABLE OF CONTENTS
Case Narrative................................................................................................ 1
Table of Contents........................................................................................... 6
Sample Inventory........................................................................................... 7
Analytical Results.......................................................................................... 8
Qualifiers........................................................................................................ 41
Certifications.................................................................................................. 42
Sample Receipt.............................................................................................. 45
Work Order 1802846 Page 6 of 47
Client
Sample ID
Sample Inventory Report
Vista
Sample ID Sampled Received Components/Containers
1802846-01 Covered Waste-Inner 30-Aug-18 11:00 31-Aug-18 09:12 HDPE Jar, 6 oz
1802846-02 Covered Waste-Replicate 30-Aug-18 11:00 31-Aug-18 09:12 HDPE Jar, 6 oz
1802846-03 SPF-Inner 30-Aug-18 12:30 31-Aug-18 09:12 HDPE Jar, 6 oz
1802846-04 SPF-Replicate 30-Aug-18 12:30 31-Aug-18 09:12 HDPE Jar, 6 oz
1802846-05 BM-Inner 30-Aug-18 14:00 31-Aug-18 09:12 HDPE Jar, 6 oz
1802846-06 BM-Replicate 30-Aug-18 14:00 31-Aug-18 09:12 HDPE Jar, 6 oz
1802846-07 EQ-1 28-Aug-18 14:10 31-Aug-18 09:12 HDPE Bottle, 250 mL
HDPE Bottle, 250 mL
1802846-08 EQ-2 28-Aug-18 14:20 31-Aug-18 09:12 HDPE Bottle, 250 mL
HDPE Bottle, 250 mL
1802846-09 TW-2 28-Aug-18 14:40 31-Aug-18 09:12 HDPE Bottle, 250 mL
HDPE Bottle, 250 mL
1802846-10 CW-Outer 28-Aug-18 10:55 31-Aug-18 09:12 HDPE Jar, 6 oz
1802846-11 BM-Outer 28-Aug-18 14:50 31-Aug-18 09:12 HDPE Jar, 6 oz
1802846-12 SPF-Outer 28-Aug-18 13:00 31-Aug-18 09:12 HDPE Jar, 6 oz
Vista Project: 1802846 Client Project: Steamship Navigation
Work Order 1802846 Page 7 of 47
Name:
Project:
Client Data
Steamship Navigation PFAS
Sample ID: Method Blank
Matrix:
Laboratory Data
Lab Sample: B8I0057-BLK1
VAL - PFAS
CES Inc. Column: BEH C18Solid
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-18375-22-4
PFPeA 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-182706-90-3
PFBS 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-18375-73-5
PFHxA 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-18307-24-4
PFHpA 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-18375-85-9
PFHxS 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-18355-46-4
6:2 FTS 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-1827619-97-2
PFOA 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-18335-67-1
PFHpS 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-18375-92-8
PFNA 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-18375-95-1
PFOSA 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-18754-91-6
PFOS 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-181763-23-1
PFDA 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-18335-76-2
8:2 FTS 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-1839108-34-4
MeFOSAA 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-182355-31-9
EtFOSAA 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-182991-50-6
PFUnA 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-182058-94-8
PFDS 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-18335-77-3
PFDoA 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-18307-55-1
MeFOSA 1.95ND 15.00 10.0 22-Sep-18 02:24B8I0057 1.00 g13-Sep-1831506-32-8
PFTrDA 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-1872629-94-8
PFTeDA 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-18376-06-7
EtFOSA 1.95ND 15.00 10.0 22-Sep-18 02:24B8I0057 1.00 g13-Sep-184151-50-2
PFHxDA 0.845ND 11.00 2.00 22-Sep-18 02:24B8I0057 1.00 g13-Sep-1867905-19-5
MeFOSE 1.95ND 15.00 10.0 22-Sep-18 02:24B8I0057 1.00 g13-Sep-1824448-09-7
EtFOSE 1.95ND 15.00 10.0 22-Sep-18 02:24B8I0057 1.00 g13-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 95.1 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - 13C3-PFPeA 94.7 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - 13C3-PFBS 94.5 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - 13C2-PFHxA 93.0 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - 13C4-PFHpA 97.5 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - 18O2-PFHxS 86.4 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - 13C2-6:2 FTS 80.4 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - 13C2-PFOA 89.2 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
Work Order 1802846 Page 9 of 47
Name:
Project:
Client Data
Steamship Navigation PFAS
Sample ID: Method Blank
Matrix:
Laboratory Data
Lab Sample: B8I0057-BLK1
VAL - PFAS
CES Inc. Column: BEH C18Solid
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C5-PFNA 76.8 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - 13C8-PFOSA 44.0 50 150 H 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - 13C8-PFOS 88.6 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - 13C2-PFDA 66.9 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - 13C2-8:2 FTS 79.0 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - d3-MeFOSAA 56.8 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - d5-EtFOSAA 62.4 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - 13C2-PFUnA 63.4 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - 13C2-PFDoA 63.0 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - d3-MeFOSA 12.3 50 150 H 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - 13C2-PFTeDA 67.3 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - d5-EtFOSA 10.3 50 150 H 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - 13C2-PFHxDA 53.3 50 150 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - d7-MeFOSE 22.3 50 150 H 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 g
IS - d9-EtFOSE 21.1 50 150 H 122-Sep-18 02:24B8I0057 13-Sep-18 1.00 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802846 Page 10 of 47
Name:Project:
Client Data
Steamship Navigation PFAS
Sample ID: OPR
Matrix:
Laboratory Data
Lab Sample: B8I0057-BS1
VAL - PFAS
CES Inc. Column: BEH C18Solid
Analyte Amt Found (ng/g ) Qualifiers Analyzed DilutionSpike Amt % Rec Limits Samp SizeExtractedBatchCAS Number
PFBA 10.8 122-Sep-18 02:3410.0 108 - 70 130 1.00 g13-Sep-18B8I0057375-22-4
PFPeA 10.9 122-Sep-18 02:3410.0 109 - 70 130 1.00 g13-Sep-18B8I00572706-90-3
PFBS 10.7 122-Sep-18 02:3410.0 107 - 70 130 1.00 g13-Sep-18B8I0057375-73-5
PFHxA 10.7 122-Sep-18 02:3410.0 107 - 70 130 1.00 g13-Sep-18B8I0057307-24-4
PFHpA 11.0 122-Sep-18 02:3410.0 110 - 70 130 1.00 g13-Sep-18B8I0057375-85-9
PFHxS 10.2 122-Sep-18 02:3410.0 102 - 70 130 1.00 g13-Sep-18B8I0057355-46-4
6:2 FTS 11.0 122-Sep-18 02:3410.0 110 - 60 130 1.00 g13-Sep-18B8I005727619-97-2
PFOA 10.7 122-Sep-18 02:3410.0 107 - 70 130 1.00 g13-Sep-18B8I0057335-67-1
PFHpS 11.6 122-Sep-18 02:3410.0 116 - 60 130 1.00 g13-Sep-18B8I0057375-92-8
PFNA 10.7 122-Sep-18 02:3410.0 107 - 70 130 1.00 g13-Sep-18B8I0057375-95-1
PFOSA 11.3 122-Sep-18 02:3410.0 113 - 70 130 1.00 g13-Sep-18B8I0057754-91-6
PFOS 11.9 122-Sep-18 02:3410.0 119 - 70 130 1.00 g13-Sep-18B8I00571763-23-1
PFDA 10.7 122-Sep-18 02:3410.0 107 - 70 130 1.00 g13-Sep-18B8I0057335-76-2
8:2 FTS 9.75 122-Sep-18 02:3410.0 97.5 - 60 130 1.00 g13-Sep-18B8I005739108-34-4
MeFOSAA 9.70 122-Sep-18 02:3410.0 97.0 - 70 130 1.00 g13-Sep-18B8I00572355-31-9
EtFOSAA 10.6 122-Sep-18 02:3410.0 106 - 70 130 1.00 g13-Sep-18B8I00572991-50-6
PFUnA 10.8 122-Sep-18 02:3410.0 108 - 70 130 1.00 g13-Sep-18B8I00572058-94-8
PFDS 10.1 122-Sep-18 02:3410.0 101 - 60 130 1.00 g13-Sep-18B8I0057335-77-3
PFDoA 10.6 122-Sep-18 02:3410.0 106 - 70 130 1.00 g13-Sep-18B8I0057307-55-1
MeFOSA 58.5 122-Sep-18 02:3450.0 117 - 70 130 1.00 g13-Sep-18B8I005731506-32-8
PFTrDA 10.6 122-Sep-18 02:3410.0 106 - 60 130 1.00 g13-Sep-18B8I005772629-94-8
PFTeDA 10.9 122-Sep-18 02:3410.0 109 - 70 130 1.00 g13-Sep-18B8I0057376-06-7
EtFOSA 62.4 122-Sep-18 02:3450.0 125 - 70 130 1.00 g13-Sep-18B8I00574151-50-2
PFHxDA 10.8 122-Sep-18 02:3410.0 108 - 70 130 1.00 g13-Sep-18B8I005767905-19-5
MeFOSE 57.6 122-Sep-18 02:3450.0 115 - 70 130 1.00 g13-Sep-18B8I005724448-09-7
EtFOSE 56.1 122-Sep-18 02:3450.0 112 - 70 130 1.00 g13-Sep-18B8I00571691-99-2
Labeled Standards % Rec Limits Qualifiers Analyzed DilutionType Samp SizeExtractedBatch
IS - 13C3-PFBA 91.0 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - 13C3-PFPeA 90.2 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - 13C3-PFBS 90.5 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - 13C2-PFHxA 90.2 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - 13C4-PFHpA 91.0 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - 18O2-PFHxS 88.0 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - 13C2-6:2 FTS 82.7 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - 13C2-PFOA 87.7 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
Work Order 1802846 Page 11 of 47
Name:Project:
Client Data
Steamship Navigation PFAS
Sample ID: OPR
Matrix:
Laboratory Data
Lab Sample: B8I0057-BS1
VAL - PFAS
CES Inc. Column: BEH C18Solid
Labeled Standards % Rec Limits Qualifiers Analyzed DilutionType Samp SizeExtractedBatch
IS - 13C5-PFNA 79.7 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - 13C8-PFOSA 46.9 50 150 H 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - 13C8-PFOS 81.3 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - 13C2-PFDA 69.7 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - 13C2-8:2 FTS 86.8 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - d3-MeFOSAA 66.6 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - d5-EtFOSAA 66.7 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - 13C2-PFUnA 68.7 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - 13C2-PFDoA 70.5 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - d3-MeFOSA 11.5 50 150 H 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - 13C2-PFTeDA 65.6 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - d5-EtFOSA 10.6 50 150 H 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - 13C2-PFHxDA 53.1 50 150 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - d7-MeFOSE 32.5 50 150 H 122-Sep-18 02:341.00 g13-Sep-18B8I0057
IS - d9-EtFOSE 31.7 50 150 H 122-Sep-18 02:341.00 g13-Sep-18B8I0057
Work Order 1802846 Page 12 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: Covered Waste-Inner
Matrix:
Laboratory Data
Lab Sample: 1802846-01
VAL - PFAS
% Solids:
CES Inc.
61.1
Column: BEH C18Soil
30-Aug-18 11:00 Date Received: 31-Aug-18 09:12
Location: Covered Waste
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-18375-22-4
PFPeA 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-182706-90-3
PFBS 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-18375-73-5
PFHxA 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-18307-24-4
PFHpA 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-18375-85-9
PFHxS 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-18355-46-4
6:2 FTS 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-1827619-97-2
PFOA 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-18335-67-1
PFHpS 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-18375-92-8
PFNA 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-18375-95-1
PFOSA 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-18754-91-6
PFOS 0.8321.16 J 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-181763-23-1
PFDA 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-18335-76-2
8:2 FTS 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-1839108-34-4
MeFOSAA 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-182355-31-9
EtFOSAA 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-182991-50-6
PFUnA 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-182058-94-8
PFDS 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-18335-77-3
PFDoA 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-18307-55-1
MeFOSA 1.92ND 14.93 9.85 22-Sep-18 03:06B8I0057 1.66 g13-Sep-1831506-32-8
PFTrDA 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-1872629-94-8
PFTeDA 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-18376-06-7
EtFOSA 1.92ND 14.93 9.85 22-Sep-18 03:06B8I0057 1.66 g13-Sep-184151-50-2
PFHxDA 0.832ND 10.985 1.97 22-Sep-18 03:06B8I0057 1.66 g13-Sep-1867905-19-5
MeFOSE 1.92ND 14.93 9.85 22-Sep-18 03:06B8I0057 1.66 g13-Sep-1824448-09-7
EtFOSE 1.92ND 14.93 9.85 22-Sep-18 03:06B8I0057 1.66 g13-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 93.6 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - 13C3-PFPeA 96.9 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - 13C3-PFBS 92.5 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - 13C2-PFHxA 93.3 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - 13C4-PFHpA 98.3 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - 18O2-PFHxS 91.2 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
Work Order 1802846 Page 13 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: Covered Waste-Inner
Matrix:
Laboratory Data
Lab Sample: 1802846-01
VAL - PFAS
% Solids:
CES Inc.
61.1
Column: BEH C18Soil
30-Aug-18 11:00 Date Received: 31-Aug-18 09:12
Location: Covered Waste
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 99.1 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - 13C2-PFOA 92.1 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - 13C5-PFNA 89.7 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - 13C8-PFOSA 66.9 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - 13C8-PFOS 92.9 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - 13C2-PFDA 77.9 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - 13C2-8:2 FTS 96.9 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - d3-MeFOSAA 70.1 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - d5-EtFOSAA 76.7 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - 13C2-PFUnA 80.7 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - 13C2-PFDoA 80.3 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - d3-MeFOSA 36.0 50 150 H 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - 13C2-PFTeDA 85.3 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - d5-EtFOSA 41.8 50 150 H 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - 13C2-PFHxDA 90.1 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - d7-MeFOSE 55.3 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 g
IS - d9-EtFOSE 58.4 50 150 122-Sep-18 03:06B8I0057 13-Sep-18 1.66 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802846 Page 14 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: Covered Waste-Replicate
Matrix:
Laboratory Data
Lab Sample: 1802846-02
VAL - PFAS
% Solids:
CES Inc.
90.1
Column: BEH C18Soil
30-Aug-18 11:00 Date Received: 31-Aug-18 09:12
Location: Covered Waste
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-18375-22-4
PFPeA 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-182706-90-3
PFBS 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-18375-73-5
PFHxA 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-18307-24-4
PFHpA 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-18375-85-9
PFHxS 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-18355-46-4
6:2 FTS 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-1827619-97-2
PFOA 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-18335-67-1
PFHpS 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-18375-92-8
PFNA 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-18375-95-1
PFOSA 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-18754-91-6
PFOS 0.8230.935 J 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-181763-23-1
PFDA 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-18335-76-2
8:2 FTS 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-1839108-34-4
MeFOSAA 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-182355-31-9
EtFOSAA 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-182991-50-6
PFUnA 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-182058-94-8
PFDS 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-18335-77-3
PFDoA 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-18307-55-1
MeFOSA 1.90ND 14.87 9.74 22-Sep-18 03:17B8I0057 1.14 g13-Sep-1831506-32-8
PFTrDA 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-1872629-94-8
PFTeDA 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-18376-06-7
EtFOSA 1.90ND 14.87 9.74 22-Sep-18 03:17B8I0057 1.14 g13-Sep-184151-50-2
PFHxDA 0.823ND 10.974 1.95 22-Sep-18 03:17B8I0057 1.14 g13-Sep-1867905-19-5
MeFOSE 1.90ND 14.87 9.74 22-Sep-18 03:17B8I0057 1.14 g13-Sep-1824448-09-7
EtFOSE 1.90ND 14.87 9.74 22-Sep-18 03:17B8I0057 1.14 g13-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 80.0 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - 13C3-PFPeA 80.6 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - 13C3-PFBS 74.8 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - 13C2-PFHxA 77.4 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - 13C4-PFHpA 80.2 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - 18O2-PFHxS 74.2 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
Work Order 1802846 Page 15 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: Covered Waste-Replicate
Matrix:
Laboratory Data
Lab Sample: 1802846-02
VAL - PFAS
% Solids:
CES Inc.
90.1
Column: BEH C18Soil
30-Aug-18 11:00 Date Received: 31-Aug-18 09:12
Location: Covered Waste
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 91.3 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - 13C2-PFOA 78.1 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - 13C5-PFNA 77.0 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - 13C8-PFOSA 56.5 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - 13C8-PFOS 76.5 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - 13C2-PFDA 66.8 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - 13C2-8:2 FTS 97.6 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - d3-MeFOSAA 64.0 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - d5-EtFOSAA 72.1 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - 13C2-PFUnA 69.6 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - 13C2-PFDoA 72.3 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - d3-MeFOSA 33.2 50 150 H 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - 13C2-PFTeDA 82.1 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - d5-EtFOSA 39.4 50 150 H 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - 13C2-PFHxDA 75.7 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - d7-MeFOSE 49.9 50 150 H 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 g
IS - d9-EtFOSE 54.2 50 150 122-Sep-18 03:17B8I0057 13-Sep-18 1.14 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802846 Page 16 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: SPF-Inner
Matrix:
Laboratory Data
Lab Sample: 1802846-03
VAL - PFAS
% Solids:
CES Inc.
70.2
Column: BEH C18Soil
30-Aug-18 12:30 Date Received: 31-Aug-18 09:12
Location: Short Paper Fiber
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-18375-22-4
PFPeA 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-182706-90-3
PFBS 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-18375-73-5
PFHxA 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-18307-24-4
PFHpA 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-18375-85-9
PFHxS 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-18355-46-4
6:2 FTS 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-1827619-97-2
PFOA 0.8193.83 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-18335-67-1
PFHpS 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-18375-92-8
PFNA 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-18375-95-1
PFOSA 0.8193.54 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-18754-91-6
PFOS 0.81961.9 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-181763-23-1
PFDA 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-18335-76-2
8:2 FTS 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-1839108-34-4
MeFOSAA 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-182355-31-9
EtFOSAA 0.8198.37 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-182991-50-6
PFUnA 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-182058-94-8
PFDS 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-18335-77-3
PFDoA 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-18307-55-1
MeFOSA 1.89ND 14.85 9.69 22-Sep-18 03:27B8I0057 1.47 g13-Sep-1831506-32-8
PFTrDA 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-1872629-94-8
PFTeDA 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-18376-06-7
EtFOSA 1.89ND 14.85 9.69 22-Sep-18 03:27B8I0057 1.47 g13-Sep-184151-50-2
PFHxDA 0.819ND 10.969 1.94 22-Sep-18 03:27B8I0057 1.47 g13-Sep-1867905-19-5
MeFOSE 1.898.36 J 14.85 9.69 22-Sep-18 03:27B8I0057 1.47 g13-Sep-1824448-09-7
EtFOSE 1.892.31 J 14.85 9.69 22-Sep-18 03:27B8I0057 1.47 g13-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 90.0 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - 13C3-PFPeA 92.5 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - 13C3-PFBS 94.4 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - 13C2-PFHxA 90.7 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - 13C4-PFHpA 95.5 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - 18O2-PFHxS 90.8 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
Work Order 1802846 Page 17 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: SPF-Inner
Matrix:
Laboratory Data
Lab Sample: 1802846-03
VAL - PFAS
% Solids:
CES Inc.
70.2
Column: BEH C18Soil
30-Aug-18 12:30 Date Received: 31-Aug-18 09:12
Location: Short Paper Fiber
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 94.1 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - 13C2-PFOA 89.4 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - 13C5-PFNA 84.1 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - 13C8-PFOSA 53.1 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - 13C8-PFOS 80.9 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - 13C2-PFDA 81.7 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - 13C2-8:2 FTS 89.1 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - d3-MeFOSAA 67.5 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - d5-EtFOSAA 72.3 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - 13C2-PFUnA 78.3 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - 13C2-PFDoA 75.0 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - d3-MeFOSA 21.9 50 150 H 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - 13C2-PFTeDA 77.1 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - d5-EtFOSA 25.3 50 150 H 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - 13C2-PFHxDA 77.1 50 150 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - d7-MeFOSE 42.7 50 150 H 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 g
IS - d9-EtFOSE 45.3 50 150 H 122-Sep-18 03:27B8I0057 13-Sep-18 1.47 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802846 Page 18 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: SPF-Replicate
Matrix:
Laboratory Data
Lab Sample: 1802846-04
VAL - PFAS
% Solids:
CES Inc.
61.3
Column: BEH C18Soil
30-Aug-18 12:30 Date Received: 31-Aug-18 09:12
Location: Short Paper Fiber
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-18375-22-4
PFPeA 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-182706-90-3
PFBS 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-18375-73-5
PFHxA 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-18307-24-4
PFHpA 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-18375-85-9
PFHxS 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-18355-46-4
6:2 FTS 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-1827619-97-2
PFOA 0.8303.73 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-18335-67-1
PFHpS 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-18375-92-8
PFNA 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-18375-95-1
PFOSA 0.8304.18 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-18754-91-6
PFOS 0.83067.6 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-181763-23-1
PFDA 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-18335-76-2
8:2 FTS 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-1839108-34-4
MeFOSAA 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-182355-31-9
EtFOSAA 0.83012.6 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-182991-50-6
PFUnA 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-182058-94-8
PFDS 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-18335-77-3
PFDoA 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-18307-55-1
MeFOSA 1.92ND 14.91 9.83 22-Sep-18 03:38B8I0057 1.66 g13-Sep-1831506-32-8
PFTrDA 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-1872629-94-8
PFTeDA 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-18376-06-7
EtFOSA 1.92ND 14.91 9.83 22-Sep-18 03:38B8I0057 1.66 g13-Sep-184151-50-2
PFHxDA 0.830ND 10.983 1.97 22-Sep-18 03:38B8I0057 1.66 g13-Sep-1867905-19-5
MeFOSE 1.926.45 J 14.91 9.83 22-Sep-18 03:38B8I0057 1.66 g13-Sep-1824448-09-7
EtFOSE 1.922.26 J 14.91 9.83 22-Sep-18 03:38B8I0057 1.66 g13-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 92.1 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - 13C3-PFPeA 91.7 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - 13C3-PFBS 96.3 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - 13C2-PFHxA 86.7 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - 13C4-PFHpA 92.5 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - 18O2-PFHxS 92.6 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
Work Order 1802846 Page 19 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: SPF-Replicate
Matrix:
Laboratory Data
Lab Sample: 1802846-04
VAL - PFAS
% Solids:
CES Inc.
61.3
Column: BEH C18Soil
30-Aug-18 12:30 Date Received: 31-Aug-18 09:12
Location: Short Paper Fiber
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 89.5 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - 13C2-PFOA 89.7 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - 13C5-PFNA 88.7 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - 13C8-PFOSA 63.3 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - 13C8-PFOS 86.9 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - 13C2-PFDA 82.3 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - 13C2-8:2 FTS 90.5 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - d3-MeFOSAA 76.1 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - d5-EtFOSAA 75.8 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - 13C2-PFUnA 81.0 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - 13C2-PFDoA 76.0 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - d3-MeFOSA 31.0 50 150 H 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - 13C2-PFTeDA 80.9 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - d5-EtFOSA 35.3 50 150 H 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - 13C2-PFHxDA 76.9 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - d7-MeFOSE 49.0 50 150 H 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 g
IS - d9-EtFOSE 51.9 50 150 122-Sep-18 03:38B8I0057 13-Sep-18 1.66 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802846 Page 20 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: BM-Inner
Matrix:
Laboratory Data
Lab Sample: 1802846-05
VAL - PFAS
% Solids:
CES Inc.
85.4
Column: BEH C18Soil
30-Aug-18 14:00 Date Received: 31-Aug-18 09:12
Location: Baled Material
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-18375-22-4
PFPeA 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-182706-90-3
PFBS 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-18375-73-5
PFHxA 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-18307-24-4
PFHpA 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-18375-85-9
PFHxS 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-18355-46-4
6:2 FTS 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-1827619-97-2
PFOA 0.8321.38 J 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-18335-67-1
PFHpS 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-18375-92-8
PFNA 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-18375-95-1
PFOSA 0.8321.00 J 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-18754-91-6
PFOS 0.83223.6 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-181763-23-1
PFDA 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-18335-76-2
8:2 FTS 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-1839108-34-4
MeFOSAA 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-182355-31-9
EtFOSAA 0.8321.59 J 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-182991-50-6
PFUnA 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-182058-94-8
PFDS 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-18335-77-3
PFDoA 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-18307-55-1
MeFOSA 1.92ND 14.92 9.85 22-Sep-18 03:49B8I0057 1.19 g13-Sep-1831506-32-8
PFTrDA 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-1872629-94-8
PFTeDA 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-18376-06-7
EtFOSA 1.92ND 14.92 9.85 22-Sep-18 03:49B8I0057 1.19 g13-Sep-184151-50-2
PFHxDA 0.832ND 10.985 1.97 22-Sep-18 03:49B8I0057 1.19 g13-Sep-1867905-19-5
MeFOSE 1.921.94 J 14.92 9.85 22-Sep-18 03:49B8I0057 1.19 g13-Sep-1824448-09-7
EtFOSE 1.92ND 14.92 9.85 22-Sep-18 03:49B8I0057 1.19 g13-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 86.3 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - 13C3-PFPeA 86.2 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - 13C3-PFBS 84.7 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - 13C2-PFHxA 83.4 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - 13C4-PFHpA 92.0 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - 18O2-PFHxS 72.9 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
Work Order 1802846 Page 21 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: BM-Inner
Matrix:
Laboratory Data
Lab Sample: 1802846-05
VAL - PFAS
% Solids:
CES Inc.
85.4
Column: BEH C18Soil
30-Aug-18 14:00 Date Received: 31-Aug-18 09:12
Location: Baled Material
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 88.9 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - 13C2-PFOA 83.7 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - 13C5-PFNA 73.7 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - 13C8-PFOSA 51.7 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - 13C8-PFOS 75.4 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - 13C2-PFDA 64.2 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - 13C2-8:2 FTS 84.5 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - d3-MeFOSAA 67.9 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - d5-EtFOSAA 66.7 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - 13C2-PFUnA 67.8 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - 13C2-PFDoA 69.7 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - d3-MeFOSA 23.3 50 150 H 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - 13C2-PFTeDA 79.8 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - d5-EtFOSA 26.8 50 150 H 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - 13C2-PFHxDA 77.8 50 150 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - d7-MeFOSE 42.5 50 150 H 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 g
IS - d9-EtFOSE 45.8 50 150 H 122-Sep-18 03:49B8I0057 13-Sep-18 1.19 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802846 Page 22 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: BM-Replicate
Matrix:
Laboratory Data
Lab Sample: 1802846-06
VAL - PFAS
% Solids:
CES Inc.
87.4
Column: BEH C18Soil
30-Aug-18 14:00 Date Received: 31-Aug-18 09:12
Location: Baled Material
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-18375-22-4
PFPeA 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-182706-90-3
PFBS 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-18375-73-5
PFHxA 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-18307-24-4
PFHpA 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-18375-85-9
PFHxS 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-18355-46-4
6:2 FTS 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-1827619-97-2
PFOA 0.8411.40 J 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-18335-67-1
PFHpS 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-18375-92-8
PFNA 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-18375-95-1
PFOSA 0.8410.858 J 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-18754-91-6
PFOS 0.84117.7 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-181763-23-1
PFDA 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-18335-76-2
8:2 FTS 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-1839108-34-4
MeFOSAA 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-182355-31-9
EtFOSAA 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-182991-50-6
PFUnA 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-182058-94-8
PFDS 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-18335-77-3
PFDoA 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-18307-55-1
MeFOSA 1.94ND 14.97 9.95 22-Sep-18 03:59B8I0057 1.15 g13-Sep-1831506-32-8
PFTrDA 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-1872629-94-8
PFTeDA 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-18376-06-7
EtFOSA 1.94ND 14.97 9.95 22-Sep-18 03:59B8I0057 1.15 g13-Sep-184151-50-2
PFHxDA 0.841ND 10.995 1.99 22-Sep-18 03:59B8I0057 1.15 g13-Sep-1867905-19-5
MeFOSE 1.94ND 14.97 9.95 22-Sep-18 03:59B8I0057 1.15 g13-Sep-1824448-09-7
EtFOSE 1.94ND 14.97 9.95 22-Sep-18 03:59B8I0057 1.15 g13-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 87.8 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - 13C3-PFPeA 90.3 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - 13C3-PFBS 86.6 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - 13C2-PFHxA 88.4 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - 13C4-PFHpA 90.3 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - 18O2-PFHxS 84.6 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
Work Order 1802846 Page 23 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: BM-Replicate
Matrix:
Laboratory Data
Lab Sample: 1802846-06
VAL - PFAS
% Solids:
CES Inc.
87.4
Column: BEH C18Soil
30-Aug-18 14:00 Date Received: 31-Aug-18 09:12
Location: Baled Material
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 90.0 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - 13C2-PFOA 82.2 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - 13C5-PFNA 74.9 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - 13C8-PFOSA 56.9 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - 13C8-PFOS 79.1 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - 13C2-PFDA 69.7 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - 13C2-8:2 FTS 84.1 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - d3-MeFOSAA 64.4 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - d5-EtFOSAA 73.5 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - 13C2-PFUnA 71.2 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - 13C2-PFDoA 73.9 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - d3-MeFOSA 28.6 50 150 H 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - 13C2-PFTeDA 82.0 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - d5-EtFOSA 29.3 50 150 H 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - 13C2-PFHxDA 81.1 50 150 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - d7-MeFOSE 45.6 50 150 H 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 g
IS - d9-EtFOSE 49.9 50 150 H 122-Sep-18 03:59B8I0057 13-Sep-18 1.15 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802846 Page 24 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: CW-Outer
Matrix:
Laboratory Data
Lab Sample: 1802846-10
VAL - PFAS
% Solids:
CES Inc.
90.4
Column: BEH C18Soil
28-Aug-18 10:55 Date Received: 31-Aug-18 09:12
Location: Covered Waste
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-18375-22-4
PFPeA 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-182706-90-3
PFBS 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-18375-73-5
PFHxA 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-18307-24-4
PFHpA 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-18375-85-9
PFHxS 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-18355-46-4
6:2 FTS 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-1827619-97-2
PFOA 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-18335-67-1
PFHpS 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-18375-92-8
PFNA 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-18375-95-1
PFOSA 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-18754-91-6
PFOS 0.8270.851 J 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-181763-23-1
PFDA 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-18335-76-2
8:2 FTS 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-1839108-34-4
MeFOSAA 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-182355-31-9
EtFOSAA 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-182991-50-6
PFUnA 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-182058-94-8
PFDS 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-18335-77-3
PFDoA 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-18307-55-1
MeFOSA 1.91ND 14.89 9.78 22-Sep-18 04:10B8I0057 1.13 g13-Sep-1831506-32-8
PFTrDA 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-1872629-94-8
PFTeDA 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-18376-06-7
EtFOSA 1.91ND 14.89 9.78 22-Sep-18 04:10B8I0057 1.13 g13-Sep-184151-50-2
PFHxDA 0.827ND 10.978 1.96 22-Sep-18 04:10B8I0057 1.13 g13-Sep-1867905-19-5
MeFOSE 1.91ND 14.89 9.78 22-Sep-18 04:10B8I0057 1.13 g13-Sep-1824448-09-7
EtFOSE 1.91ND 14.89 9.78 22-Sep-18 04:10B8I0057 1.13 g13-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 86.9 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - 13C3-PFPeA 86.2 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - 13C3-PFBS 88.3 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - 13C2-PFHxA 82.6 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - 13C4-PFHpA 87.8 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - 18O2-PFHxS 90.4 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
Work Order 1802846 Page 25 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: CW-Outer
Matrix:
Laboratory Data
Lab Sample: 1802846-10
VAL - PFAS
% Solids:
CES Inc.
90.4
Column: BEH C18Soil
28-Aug-18 10:55 Date Received: 31-Aug-18 09:12
Location: Covered Waste
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 98.7 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - 13C2-PFOA 81.4 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - 13C5-PFNA 75.8 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - 13C8-PFOSA 59.8 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - 13C8-PFOS 78.6 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - 13C2-PFDA 70.1 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - 13C2-8:2 FTS 98.7 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - d3-MeFOSAA 68.9 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - d5-EtFOSAA 73.7 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - 13C2-PFUnA 70.3 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - 13C2-PFDoA 70.9 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - d3-MeFOSA 24.3 50 150 H 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - 13C2-PFTeDA 75.3 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - d5-EtFOSA 26.6 50 150 H 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - 13C2-PFHxDA 74.1 50 150 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - d7-MeFOSE 42.3 50 150 H 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 g
IS - d9-EtFOSE 45.4 50 150 H 122-Sep-18 04:10B8I0057 13-Sep-18 1.13 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802846 Page 26 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: BM-Outer
Matrix:
Laboratory Data
Lab Sample: 1802846-11
VAL - PFAS
% Solids:
CES Inc.
54.9
Column: BEH C18Soil
28-Aug-18 14:50 Date Received: 31-Aug-18 09:12
Location: Bailed Material
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-18375-22-4
PFPeA 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-182706-90-3
PFBS 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-18375-73-5
PFHxA 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-18307-24-4
PFHpA 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-18375-85-9
PFHxS 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-18355-46-4
6:2 FTS 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-1827619-97-2
PFOA 0.8271.80 J 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-18335-67-1
PFHpS 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-18375-92-8
PFNA 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-18375-95-1
PFOSA 0.8271.05 J 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-18754-91-6
PFOS 0.82721.5 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-181763-23-1
PFDA 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-18335-76-2
8:2 FTS 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-1839108-34-4
MeFOSAA 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-182355-31-9
EtFOSAA 0.8271.42 J 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-182991-50-6
PFUnA 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-182058-94-8
PFDS 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-18335-77-3
PFDoA 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-18307-55-1
MeFOSA 1.91ND 14.89 9.79 22-Sep-18 04:20B8I0057 1.86 g13-Sep-1831506-32-8
PFTrDA 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-1872629-94-8
PFTeDA 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-18376-06-7
EtFOSA 1.91ND 14.89 9.79 22-Sep-18 04:20B8I0057 1.86 g13-Sep-184151-50-2
PFHxDA 0.827ND 10.979 1.96 22-Sep-18 04:20B8I0057 1.86 g13-Sep-1867905-19-5
MeFOSE 1.91ND 14.89 9.79 22-Sep-18 04:20B8I0057 1.86 g13-Sep-1824448-09-7
EtFOSE 1.91ND 14.89 9.79 22-Sep-18 04:20B8I0057 1.86 g13-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 82.7 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - 13C3-PFPeA 84.1 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - 13C3-PFBS 79.4 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - 13C2-PFHxA 83.5 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - 13C4-PFHpA 84.1 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - 18O2-PFHxS 83.8 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
Work Order 1802846 Page 27 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: BM-Outer
Matrix:
Laboratory Data
Lab Sample: 1802846-11
VAL - PFAS
% Solids:
CES Inc.
54.9
Column: BEH C18Soil
28-Aug-18 14:50 Date Received: 31-Aug-18 09:12
Location: Bailed Material
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 83.1 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - 13C2-PFOA 82.8 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - 13C5-PFNA 76.1 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - 13C8-PFOSA 55.4 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - 13C8-PFOS 75.6 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - 13C2-PFDA 70.1 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - 13C2-8:2 FTS 85.5 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - d3-MeFOSAA 55.6 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - d5-EtFOSAA 63.9 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - 13C2-PFUnA 68.7 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - 13C2-PFDoA 72.4 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - d3-MeFOSA 25.7 50 150 H 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - 13C2-PFTeDA 75.3 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - d5-EtFOSA 28.3 50 150 H 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - 13C2-PFHxDA 74.9 50 150 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - d7-MeFOSE 42.7 50 150 H 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 g
IS - d9-EtFOSE 45.1 50 150 H 122-Sep-18 04:20B8I0057 13-Sep-18 1.86 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802846 Page 28 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: SPF-Outer
Matrix:
Laboratory Data
Lab Sample: 1802846-12
VAL - PFAS
% Solids:
CES Inc.
49.1
Column: BEH C18Soil
28-Aug-18 13:00 Date Received: 31-Aug-18 09:12
Location: Short Paper Fiber
Analyte Conc. (ng/g ) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-18375-22-4
PFPeA 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-182706-90-3
PFBS 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-18375-73-5
PFHxA 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-18307-24-4
PFHpA 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-18375-85-9
PFHxS 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-18355-46-4
6:2 FTS 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-1827619-97-2
PFOA 0.8393.11 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-18335-67-1
PFHpS 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-18375-92-8
PFNA 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-18375-95-1
PFOSA 0.8392.55 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-18754-91-6
PFOS 0.83942.4 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-181763-23-1
PFDA 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-18335-76-2
8:2 FTS 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-1839108-34-4
MeFOSAA 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-182355-31-9
EtFOSAA 0.8397.16 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-182991-50-6
PFUnA 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-182058-94-8
PFDS 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-18335-77-3
PFDoA 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-18307-55-1
MeFOSA 1.94ND 14.97 9.93 22-Sep-18 04:31B8I0057 2.05 g13-Sep-1831506-32-8
PFTrDA 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-1872629-94-8
PFTeDA 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-18376-06-7
EtFOSA 1.94ND 14.97 9.93 22-Sep-18 04:31B8I0057 2.05 g13-Sep-184151-50-2
PFHxDA 0.839ND 10.993 1.99 22-Sep-18 04:31B8I0057 2.05 g13-Sep-1867905-19-5
MeFOSE 1.945.49 J 14.97 9.93 22-Sep-18 04:31B8I0057 2.05 g13-Sep-1824448-09-7
EtFOSE 1.94ND 14.97 9.93 22-Sep-18 04:31B8I0057 2.05 g13-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 85.3 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - 13C3-PFPeA 93.9 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - 13C3-PFBS 95.1 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - 13C2-PFHxA 91.9 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - 13C4-PFHpA 97.9 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - 18O2-PFHxS 101 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
Work Order 1802846 Page 29 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: SPF-Outer
Matrix:
Laboratory Data
Lab Sample: 1802846-12
VAL - PFAS
% Solids:
CES Inc.
49.1
Column: BEH C18Soil
28-Aug-18 13:00 Date Received: 31-Aug-18 09:12
Location: Short Paper Fiber
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 98.8 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - 13C2-PFOA 91.4 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - 13C5-PFNA 92.7 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - 13C8-PFOSA 58.0 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - 13C8-PFOS 90.6 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - 13C2-PFDA 85.9 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - 13C2-8:2 FTS 102 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - d3-MeFOSAA 75.9 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - d5-EtFOSAA 75.6 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - 13C2-PFUnA 84.6 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - 13C2-PFDoA 78.5 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - d3-MeFOSA 24.5 50 150 H 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - 13C2-PFTeDA 76.9 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - d5-EtFOSA 27.1 50 150 H 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - 13C2-PFHxDA 75.3 50 150 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - d7-MeFOSE 39.3 50 150 H 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 g
IS - d9-EtFOSE 41.4 50 150 H 122-Sep-18 04:31B8I0057 13-Sep-18 2.05 gThe results are reported in dry weight.
The sample size is reported in wet weight.
Results reported to the DL.
DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802846 Page 30 of 47
Name:
Project:
Client Data
Steamship Navigation PFAS
Sample ID: Method Blank
Matrix:
Laboratory Data
Lab Sample: B8I0151-BLK1
PFAS Isotope Dilution Method
CES Inc. Column: BEH C18Aqueous
Analyte Conc. (ng/L) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-18375-22-4
PFPeA 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-182706-90-3
PFBS 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-18375-73-5
PFHxA 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-18307-24-4
PFHpA 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-18375-85-9
PFHxS 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-18355-46-4
6:2 FTS 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-1827619-97-2
PFOA 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-18335-67-1
PFHpS 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-18375-92-8
PFNA 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-18375-95-1
PFOSA 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-18754-91-6
PFOS 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-181763-23-1
PFDA 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-18335-76-2
8:2 FTS 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-1839108-34-4
MeFOSAA 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-182355-31-9
EtFOSAA 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-182991-50-6
PFUnA 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-182058-94-8
PFDS 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-18335-77-3
PFDoA 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-18307-55-1
MeFOSA 4.41ND 110.0 20.0 26-Sep-18 23:30B8I0151 0.250 L21-Sep-1831506-32-8
PFTrDA 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-1872629-94-8
PFTeDA 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-18376-06-7
EtFOSA 4.41ND 110.0 20.0 26-Sep-18 23:30B8I0151 0.250 L21-Sep-184151-50-2
PFHxDA 1.37ND 12.00 4.00 26-Sep-18 23:30B8I0151 0.250 L21-Sep-1867905-19-5
MeFOSE 4.41ND 110.0 20.0 26-Sep-18 23:30B8I0151 0.250 L21-Sep-1824448-09-7
EtFOSE 4.41ND 110.0 20.0 26-Sep-18 23:30B8I0151 0.250 L21-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 104 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - 13C3-PFPeA 108 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - 13C3-PFBS 105 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - 13C2-PFHxA 104 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - 13C4-PFHpA 103 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - 18O2-PFHxS 95.2 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - 13C2-6:2 FTS 101 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - 13C2-PFOA 115 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
Work Order 1802846 Page 31 of 47
Name:
Project:
Client Data
Steamship Navigation PFAS
Sample ID: Method Blank
Matrix:
Laboratory Data
Lab Sample: B8I0151-BLK1
PFAS Isotope Dilution Method
CES Inc. Column: BEH C18Aqueous
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C5-PFNA 75.5 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - 13C8-PFOSA 36.2 50 150 H 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - 13C8-PFOS 97.2 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - 13C2-PFDA 59.7 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - 13C2-8:2 FTS 89.2 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - d3-MeFOSAA 87.0 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - d5-EtFOSAA 88.3 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - 13C2-PFUnA 63.6 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - 13C2-PFDoA 83.8 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - d3-MeFOSA 4.40 50 150 H 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - 13C2-PFTeDA 96.9 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - d5-EtFOSA 3.90 50 150 H 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - 13C2-PFHxDA 99.6 50 150 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - d7-MeFOSE 33.5 50 150 H 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 L
IS - d9-EtFOSE 32.8 50 150 H 126-Sep-18 23:30B8I0151 21-Sep-18 0.250 LResults reported to the DL. DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802846 Page 32 of 47
Name:Project:
Client Data
Steamship Navigation PFAS
Sample ID: OPR
Matrix:
Laboratory Data
Lab Sample: B8I0151-BS1
PFAS Isotope Dilution Method
CES Inc. Column: BEH C18Aqueous
Analyte Amt Found (ng/L) Qualifiers Analyzed DilutionSpike Amt % Rec Limits Samp SizeExtractedBatchCAS Number
PFBA 38.3 126-Sep-18 23:1940.0 95.9 - 70 130 0.250 L21-Sep-18B8I0151375-22-4
PFPeA 36.3 126-Sep-18 23:1940.0 90.9 - 70 130 0.250 L21-Sep-18B8I01512706-90-3
PFBS 35.8 126-Sep-18 23:1940.0 89.5 - 70 130 0.250 L21-Sep-18B8I0151375-73-5
PFHxA 34.8 126-Sep-18 23:1940.0 86.9 - 70 130 0.250 L21-Sep-18B8I0151307-24-4
PFHpA 41.7 126-Sep-18 23:1940.0 104 - 70 130 0.250 L21-Sep-18B8I0151375-85-9
PFHxS 39.5 126-Sep-18 23:1940.0 98.8 - 70 130 0.250 L21-Sep-18B8I0151355-46-4
6:2 FTS 32.7 126-Sep-18 23:1940.0 81.8 - 60 130 0.250 L21-Sep-18B8I015127619-97-2
PFOA 30.6 126-Sep-18 23:1940.0 76.5 - 70 130 0.250 L21-Sep-18B8I0151335-67-1
PFHpS 41.9 126-Sep-18 23:1940.0 105 - 60 130 0.250 L21-Sep-18B8I0151375-92-8
PFNA 41.1 126-Sep-18 23:1940.0 103 - 70 130 0.250 L21-Sep-18B8I0151375-95-1
PFOSA 40.8 126-Sep-18 23:1940.0 102 - 70 130 0.250 L21-Sep-18B8I0151754-91-6
PFOS 41.5 126-Sep-18 23:1940.0 104 - 70 130 0.250 L21-Sep-18B8I01511763-23-1
PFDA 37.9 126-Sep-18 23:1940.0 94.8 - 70 130 0.250 L21-Sep-18B8I0151335-76-2
8:2 FTS 34.6 126-Sep-18 23:1940.0 86.5 - 60 130 0.250 L21-Sep-18B8I015139108-34-4
MeFOSAA 36.7 126-Sep-18 23:1940.0 91.9 - 70 130 0.250 L21-Sep-18B8I01512355-31-9
EtFOSAA 35.8 126-Sep-18 23:1940.0 89.4 - 70 130 0.250 L21-Sep-18B8I01512991-50-6
PFUnA 38.4 126-Sep-18 23:1940.0 96.0 - 70 130 0.250 L21-Sep-18B8I01512058-94-8
PFDS 33.6 126-Sep-18 23:1940.0 84.0 - 60 130 0.250 L21-Sep-18B8I0151335-77-3
PFDoA 33.7 126-Sep-18 23:1940.0 84.3 - 70 130 0.250 L21-Sep-18B8I0151307-55-1
MeFOSA 262 H 126-Sep-18 23:19200 131 - 70 130 0.250 L21-Sep-18B8I015131506-32-8
PFTrDA 40.6 126-Sep-18 23:1940.0 101 - 60 130 0.250 L21-Sep-18B8I015172629-94-8
PFTeDA 33.4 126-Sep-18 23:1940.0 83.5 - 70 130 0.250 L21-Sep-18B8I0151376-06-7
EtFOSA 181 126-Sep-18 23:19200 90.5 - 70 130 0.250 L21-Sep-18B8I01514151-50-2
PFHxDA 38.5 126-Sep-18 23:1940.0 96.2 - 70 130 0.250 L21-Sep-18B8I015167905-19-5
MeFOSE 208 126-Sep-18 23:19200 104 - 70 130 0.250 L21-Sep-18B8I015124448-09-7
EtFOSE 217 126-Sep-18 23:19200 109 - 70 130 0.250 L21-Sep-18B8I01511691-99-2
Labeled Standards % Rec Limits Qualifiers Analyzed DilutionType Samp SizeExtractedBatch
IS - 13C3-PFBA 105 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - 13C3-PFPeA 107 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - 13C3-PFBS 101 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - 13C2-PFHxA 107 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - 13C4-PFHpA 96.5 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - 18O2-PFHxS 93.4 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - 13C2-6:2 FTS 101 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - 13C2-PFOA 117 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
Work Order 1802846 Page 33 of 47
Name:Project:
Client Data
Steamship Navigation PFAS
Sample ID: OPR
Matrix:
Laboratory Data
Lab Sample: B8I0151-BS1
PFAS Isotope Dilution Method
CES Inc. Column: BEH C18Aqueous
Labeled Standards % Rec Limits Qualifiers Analyzed DilutionType Samp SizeExtractedBatch
IS - 13C5-PFNA 81.9 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - 13C8-PFOSA 47.8 50 150 H 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - 13C8-PFOS 98.6 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - 13C2-PFDA 57.7 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - 13C2-8:2 FTS 110 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - d3-MeFOSAA 81.4 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - d5-EtFOSAA 82.8 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - 13C2-PFUnA 64.4 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - 13C2-PFDoA 77.7 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - d3-MeFOSA 5.10 50 150 H 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - 13C2-PFTeDA 100 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - d5-EtFOSA 5.90 50 150 H 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - 13C2-PFHxDA 102 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - d7-MeFOSE 53.2 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
IS - d9-EtFOSE 55.1 50 150 126-Sep-18 23:190.250 L21-Sep-18B8I0151
Work Order 1802846 Page 34 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: EQ-1
Matrix:
Laboratory Data
Lab Sample: 1802846-07
PFAS Isotope Dilution Method
CES Inc. Column: BEH C18Aqueous
28-Aug-18 14:10 Date Received: 31-Aug-18 09:12
Location: Equipment Blank
Analyte Conc. (ng/L) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-18375-22-4
PFPeA 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-182706-90-3
PFBS 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-18375-73-5
PFHxA 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-18307-24-4
PFHpA 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-18375-85-9
PFHxS 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-18355-46-4
6:2 FTS 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-1827619-97-2
PFOA 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-18335-67-1
PFHpS 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-18375-92-8
PFNA 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-18375-95-1
PFOSA 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-18754-91-6
PFOS 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-181763-23-1
PFDA 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-18335-76-2
8:2 FTS 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-1839108-34-4
MeFOSAA 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-182355-31-9
EtFOSAA 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-182991-50-6
PFUnA 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-182058-94-8
PFDS 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-18335-77-3
PFDoA 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-18307-55-1
MeFOSA 4.17ND 19.47 19.0 26-Sep-18 23:40B8I0151 0.264 L21-Sep-1831506-32-8
PFTrDA 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-1872629-94-8
PFTeDA 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-18376-06-7
EtFOSA 4.17ND 19.47 19.0 26-Sep-18 23:40B8I0151 0.264 L21-Sep-184151-50-2
PFHxDA 1.30ND 11.89 3.79 26-Sep-18 23:40B8I0151 0.264 L21-Sep-1867905-19-5
MeFOSE 4.17ND 19.47 19.0 26-Sep-18 23:40B8I0151 0.264 L21-Sep-1824448-09-7
EtFOSE 4.17ND 19.47 19.0 26-Sep-18 23:40B8I0151 0.264 L21-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 102 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - 13C3-PFPeA 109 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - 13C3-PFBS 102 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - 13C2-PFHxA 103 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - 13C4-PFHpA 105 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - 18O2-PFHxS 93.1 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
Work Order 1802846 Page 35 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: EQ-1
Matrix:
Laboratory Data
Lab Sample: 1802846-07
PFAS Isotope Dilution Method
CES Inc. Column: BEH C18Aqueous
28-Aug-18 14:10 Date Received: 31-Aug-18 09:12
Location: Equipment Blank
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 101 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - 13C2-PFOA 110 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - 13C5-PFNA 76.6 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - 13C8-PFOSA 25.7 50 150 H 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - 13C8-PFOS 98.3 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - 13C2-PFDA 56.3 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - 13C2-8:2 FTS 94.9 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - d3-MeFOSAA 92.6 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - d5-EtFOSAA 93.8 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - 13C2-PFUnA 60.4 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - 13C2-PFDoA 87.3 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - d3-MeFOSA 2.20 50 150 H 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - 13C2-PFTeDA 119 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - d5-EtFOSA 2.60 50 150 H 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - 13C2-PFHxDA 141 50 150 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - d7-MeFOSE 36.8 50 150 H 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 L
IS - d9-EtFOSE 41.1 50 150 H 126-Sep-18 23:40B8I0151 21-Sep-18 0.264 LResults reported to the DL. DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802846 Page 36 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: EQ-2
Matrix:
Laboratory Data
Lab Sample: 1802846-08
PFAS Isotope Dilution Method
CES Inc. Column: BEH C18Aqueous
28-Aug-18 14:20 Date Received: 31-Aug-18 09:12
Location: Equipment Blank
Analyte Conc. (ng/L) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-18375-22-4
PFPeA 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-182706-90-3
PFBS 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-18375-73-5
PFHxA 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-18307-24-4
PFHpA 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-18375-85-9
PFHxS 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-18355-46-4
6:2 FTS 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-1827619-97-2
PFOA 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-18335-67-1
PFHpS 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-18375-92-8
PFNA 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-18375-95-1
PFOSA 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-18754-91-6
PFOS 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-181763-23-1
PFDA 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-18335-76-2
8:2 FTS 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-1839108-34-4
MeFOSAA 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-182355-31-9
EtFOSAA 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-182991-50-6
PFUnA 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-182058-94-8
PFDS 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-18335-77-3
PFDoA 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-18307-55-1
MeFOSA 4.31ND 19.80 19.6 27-Sep-18 00:12B8I0151 0.255 L21-Sep-1831506-32-8
PFTrDA 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-1872629-94-8
PFTeDA 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-18376-06-7
EtFOSA 4.31ND 19.80 19.6 27-Sep-18 00:12B8I0151 0.255 L21-Sep-184151-50-2
PFHxDA 1.34ND 11.96 3.92 27-Sep-18 00:12B8I0151 0.255 L21-Sep-1867905-19-5
MeFOSE 4.31ND 19.80 19.6 27-Sep-18 00:12B8I0151 0.255 L21-Sep-1824448-09-7
EtFOSE 4.31ND 19.80 19.6 27-Sep-18 00:12B8I0151 0.255 L21-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 100 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - 13C3-PFPeA 119 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - 13C3-PFBS 102 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - 13C2-PFHxA 106 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - 13C4-PFHpA 112 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - 18O2-PFHxS 98.9 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
Work Order 1802846 Page 37 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: EQ-2
Matrix:
Laboratory Data
Lab Sample: 1802846-08
PFAS Isotope Dilution Method
CES Inc. Column: BEH C18Aqueous
28-Aug-18 14:20 Date Received: 31-Aug-18 09:12
Location: Equipment Blank
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 93.5 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - 13C2-PFOA 117 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - 13C5-PFNA 77.4 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - 13C8-PFOSA 27.3 50 150 H 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - 13C8-PFOS 98.6 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - 13C2-PFDA 59.4 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - 13C2-8:2 FTS 90.5 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - d3-MeFOSAA 97.2 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - d5-EtFOSAA 94.3 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - 13C2-PFUnA 64.4 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - 13C2-PFDoA 74.2 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - d3-MeFOSA 1.30 50 150 H 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - 13C2-PFTeDA 126 50 150 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - d5-EtFOSA 1.50 50 150 H 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - 13C2-PFHxDA 153 50 150 H 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - d7-MeFOSE 33.5 50 150 H 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 L
IS - d9-EtFOSE 38.0 50 150 H 127-Sep-18 00:12B8I0151 21-Sep-18 0.255 LResults reported to the DL. DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802846 Page 38 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: TW-2
Matrix:
Laboratory Data
Lab Sample: 1802846-09
PFAS Isotope Dilution Method
CES Inc. Column: BEH C18Aqueous
28-Aug-18 14:40 Date Received: 31-Aug-18 09:12
Location: Covered Waste
Analyte Conc. (ng/L) Qualifiers Analyzed DilutionLOD LOQDL Batch Extracted Samp SizeCAS Number
PFBA 1.3411.4 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-18375-22-4
PFPeA 1.3416.9 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-182706-90-3
PFBS 1.345.62 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-18375-73-5
PFHxA 1.3422.9 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-18307-24-4
PFHpA 1.3423.3 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-18375-85-9
PFHxS 1.3417.1 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-18355-46-4
6:2 FTS 1.34ND 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-1827619-97-2
PFOA 1.3488.6 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-18335-67-1
PFHpS 1.343.43 J 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-18375-92-8
PFNA 1.348.23 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-18375-95-1
PFOSA 1.34ND 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-18754-91-6
PFOS 1.3488.0 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-181763-23-1
PFDA 1.345.58 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-18335-76-2
8:2 FTS 1.34ND 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-1839108-34-4
MeFOSAA 1.34ND 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-182355-31-9
EtFOSAA 1.34ND 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-182991-50-6
PFUnA 1.34ND 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-182058-94-8
PFDS 1.34ND 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-18335-77-3
PFDoA 1.34ND 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-18307-55-1
MeFOSA 4.30ND 19.77 19.5 27-Sep-18 00:23B8I0151 0.256 L21-Sep-1831506-32-8
PFTrDA 1.34ND 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-1872629-94-8
PFTeDA 1.34ND 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-18376-06-7
EtFOSA 4.30ND 19.77 19.5 27-Sep-18 00:23B8I0151 0.256 L21-Sep-184151-50-2
PFHxDA 1.34ND 11.95 3.90 27-Sep-18 00:23B8I0151 0.256 L21-Sep-1867905-19-5
MeFOSE 4.30ND 19.77 19.5 27-Sep-18 00:23B8I0151 0.256 L21-Sep-1824448-09-7
EtFOSE 4.30ND 19.77 19.5 27-Sep-18 00:23B8I0151 0.256 L21-Sep-181691-99-2
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C3-PFBA 104 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - 13C3-PFPeA 106 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - 13C3-PFBS 105 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - 13C2-PFHxA 104 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - 13C4-PFHpA 104 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - 18O2-PFHxS 98.4 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
Work Order 1802846 Page 39 of 47
Name:
Project: Date Collected:
Client Data
Steamship Navigation PFAS
Sample ID: TW-2
Matrix:
Laboratory Data
Lab Sample: 1802846-09
PFAS Isotope Dilution Method
CES Inc. Column: BEH C18Aqueous
28-Aug-18 14:40 Date Received: 31-Aug-18 09:12
Location: Covered Waste
Labeled Standards % Recovery Limits Qualifiers Analyzed DilutionType Batch Extracted Samp Size
IS - 13C2-6:2 FTS 99.5 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - 13C2-PFOA 121 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - 13C5-PFNA 90.5 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - 13C8-PFOSA 54.4 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - 13C8-PFOS 99.8 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - 13C2-PFDA 66.7 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - 13C2-8:2 FTS 106 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - d3-MeFOSAA 111 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - d5-EtFOSAA 110 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - 13C2-PFUnA 79.0 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - 13C2-PFDoA 90.7 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - d3-MeFOSA 8.50 50 150 H 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - 13C2-PFTeDA 125 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - d5-EtFOSA 10.0 50 150 H 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - 13C2-PFHxDA 138 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - d7-MeFOSE 72.8 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 L
IS - d9-EtFOSE 74.3 50 150 127-Sep-18 00:23B8I0151 21-Sep-18 0.256 LResults reported to the DL. DL - Detection Limit When reported, PFHxS, PFOA, PFOS, MeFOSAA and EtFOSAA include both
linear and branched isomers. Only the linear isomer is reported for all other
analytes.
LOD - Limit of Detection
LOQ - Limit of quantitation
Work Order 1802846 Page 40 of 47
DATA QUALIFIERS & ABBREVIATIONS B This compound was also detected in the method blank Conc. Concentration D Dilution DL Detection limit E The associated compound concentration exceeded the calibration range of
the instrument H Recovery and/or RPD was outside laboratory acceptance limits I Chemical Interference J The amount detected is below the Reporting Limit/LOQ LOD Limits of Detection LOQ Limits of Quantitation M Estimated Maximum Possible Concentration (CA Region 2 projects only) NA Not applicable ND Not Detected Q Ion ratio outside of 70-130% of Standard Ratio. (DOD PFAS projects only) TEQ Toxic Equivalency U Not Detected (specific projects only) * See Cover Letter Unless otherwise noted, solid sample results are reported in dry weight. Tissue samples are reported in wet weight.
Work Order 1802846 Page 41 of 47
CERTIFICATIONS
Accrediting Authority Certificate Number
Alaska Department of Environmental Conservation 17-013
Arkansas Department of Environmental Quality 18-008-0
California Department of Health – ELAP 2892
DoD ELAP - A2LA Accredited - ISO/IEC 17025:2005 3091.01
Florida Department of Health E87777-18
Hawaii Department of Health N/A
Louisiana Department of Environmental Quality 01977
Maine Department of Health 2018017
Minnesota Department of Health 1322288
New Hampshire Environmental Accreditation Program 207717
New Jersey Department of Environmental Protection CA003
New York Department of Health 11411
Oregon Laboratory Accreditation Program 4042-009
Pennsylvania Department of Environmental Protection 014
Texas Commission on Environmental Quality T104704189-18-8
Virginia Department of General Services 9077
Washington Department of Ecology C584
Wisconsin Department of Natural Resources 998036160
Current certificates and lists of licensed parameters are located in the Quality Assurance office and are available upon request.
Work Order 1802846 Page 42 of 47
NELAP Accredited Test Methods
MATRIX: Air Description of Test Method Determination of Polychlorinated p-Dioxins & Polychlorinated Dibenzofurans
EPA 23
MATRIX: Biological Tissue Description of Test Method Tetra- through Octa-Chlorinated Dioxins and Furans by Isotope Dilution GC/HRMS
EPA 1613B
Brominated Diphenyl Ethers by HRGC/HRMS EPA 1614A Chlorinated Biphenyl Congeners in Water, Soil, Sediment, and Tissue by GC/HRMS
EPA 1668A/C
Pesticides in Water, Soil, Sediment, Biosolids, and Tissue by HRGC/HRMS
EPA 1699
Perfluorinated Alkyl Acids in Drinking Water by SPE and LC/MS/MS EPA 537 Polychlorinated Dibenzo-p-Dioxins and Polychlorinated Dibenzofurans by GC/HRMS
EPA 8280A/B
Polychlorinated Dibenzodioxins (PCDDs) and Polychlorinated Dibenzofurans (PCDFs) by GC/HRMS
EPA 8290/8290A
MATRIX: Drinking Water Description of Test Method 2,3,7,8-Tetrachlorodibenzo- p-dioxin (2,3,7,8-TCDD) GC/HRMS EPA 1613 Perfluorinated Alkyl Acids in Drinking Water by SPE and LC/MS/MS EPA 537
MATRIX: Non-Potable Water Description of Test Method Tetra- through Octa-Chlorinated Dioxins and Furans by Isotope Dilution GC/HRMS
EPA 1613B
Brominated Diphenyl Ethers by HRGC/HRMS EPA 1614A Chlorinated Biphenyl Congeners in Water, Soil, Sediment, and Tissue by GC/HRMS
EPA 1668A/C
Pesticides in Water, Soil, Sediment, Biosolids, and Tissue by HRGC/HRMS EPA 1699 Perfluorinated Alkyl Acids in Drinking Water by SPE and LC/MS/MS EPA 537 Dioxin by GC/HRMS EPA 613 Polychlorinated Dibenzo-p-Dioxins and Polychlorinated Dibenzofurans by GC/HRMS
EPA 8280A/B
Polychlorinated Dibenzodioxins (PCDDs) and Polychlorinated Dibenzofurans (PCDFs) by GC/HRMS
EPA 8290/8290A
Work Order 1802846 Page 43 of 47
MATRIX: Solids Description of Test Method Tetra-Octa Chlorinated Dioxins and Furans by Isotope Dilution GC/HRMS EPA 1613 Tetra- through Octa-Chlorinated Dioxins and Furans by Isotope Dilution GC/HRMS
EPA 1613B
Brominated Diphenyl Ethers by HRGC/HRMS EPA 1614A Chlorinated Biphenyl Congeners in Water, Soil, Sediment, and Tissue by GC/HRMS
EPA 1668A/C
Perfluorinated Alkyl Acids in Drinking Water by SPE and LC/MS/MS EPA 537 Polychlorinated Dibenzo-p-Dioxins and Polychlorinated Dibenzofurans by GC/HRMS
EPA 8280A/B
Polychlorinated Dibenzodioxins (PCDDs) and Polychlorinated Dibenzofurans (PCDFs) by GC/HRMS
EPA 8290/8290A
Work Order 1802846 Page 44 of 47