dr alex bevan 1, dr david book 1, professor andreas z ü ttel 2 and professor rex harris 1 1...

1
Dr Alex Bevan 1 , Dr David Book 1 , Professor Andreas Züttel 2 and Professor Rex Harris 1 1 University of Birmingham UK. 2 EMPA Zürich, Switzerland Performance 0.00 2.00 4.00 6.00 8.00 10.00 12.00 14.00 0 1 2 3 4 5 6 7 Speed (kph) M otorpow er (kW ) 0 50 100 150 200 250 300 350 1.5 2.5 3.5 4.5 5.5 6.5 7.5 Speed (kph) B oatrange (km ) B attery pow er B attery pow er+ H ydrogen store Key Objectives Energy performance of the boat was monitored, with speed data being provided through GPS measurements. The motor power requirements vs. speed (fig 9) shows an exponential relationship (fitted line). The theoretical range of the boat (fig 10) has been calculated based on the energy/ speed requirement. Utilizing a fully charged battery stack with 47kWhrs of energy and 2.5kg of hydrogen. The metal hydride/ fuel cell combination increases the boat range by 66% Provide vital practical data on the on-board use of hydrogen as an energy store. Develop the necessary local scale hydrogen infrastructure which could provide a model and a catalyst for a much larger scale operation throughout the entire inland waterway network, with Birmingham as the hub. Develop technical innovations which will lead to wider exploitation of the energy storage and propulsion systems. Demonstrate an early, practical and economic alternative to diesel canal boats. Figure 9 Power requirement vs. Speed Figure 10 Theoretical boat range vs. Speed Key features •Hydride store has a significantly faster charging rate than the batteries •The craft will have a longer range of operation in the hybrid form before needing access to electric charging facilities •Batteries can be “trickle-charged” using solar panels, wind and water generators. PM electric motor can also serve as a generator •Fuel cell would prefer to operate at a constant load and any variability can be taken up by the battery stack •Hot water (80°C) supplied by fuel cell can be used to heat store and living space •Unlike batteries, hydride stores will not discharge on standing idle, even for prolonged periods •Other advantages (and disadvantages) will be revealed by operational experience Potential Advantages of a Hybrid System Solid state metal hydride store 1kW ReliOn PEM fuel cell (fig 2) Computer monitoring and control (fig 3) 10kW NdFeB-based drive motor (Fig 4) 47kWhr lead acid battery stack Display area with LCD screen Project contact: Prof Rex Harris (e-mail: [email protected] Tel: +44-(0)121-4145165 web: www.hydrogen.bham.ac.uk) Hydrogen also plays a crucial role in the manufacture of the NdFeB sintered magnets employed in the electric motor. The Hydrogen Store Based on 26kg of Laves-phase composition Ti 0.93 Zr 0.05 (Mn 0.73 V 0.22 Fe 0.04 ) 2 powder. Each of the 5 storage modules (fig 5) contains 7 connected stainless steel tubes which are each surrounded by a water cooling jacket. This provides 28m 3 of pure hydrogen at STP (fig 6). Based on the hydrogen consumption of the ReliOn fuel cell, this is equivalent to 31kWhrs of stored energy. Thermal management of the storage units is accomplished by heat exchanging with canal water (fig 7), and the charging characteristics of one hydride module are shown in figure 8. Hydride modu le Hydride modu le Hydride modu le Hydride module Hydride module Fuel cell Gas distribu tion Motor Heat exchanger Canal water in Water pump (1) Filter Water pump (2) Expansion tank Canal water out Hydrid e module s Antifreeze 0 1000 2000 3000 4000 5000 6000 0 1 2 3 4 5 6 7 Tim e (Hours) H ydrogen Flow ed (Ltrs) S tatic w ater W ith w atercooling flow 0 10 20 30 40 50 60 70 0 1 2 3 4 5 6 7 Tim e (Hours) W atertem perature (C elsius) S tatic w ater W ith w atercooling flow Figure 5 Stainless steel storage modules Figure 6 PCT diagram Figure 7 Thermal management Figure 8 Charging characteristics of one hydride module, showing (a) accumulated flow of hydrogen with and without controlling the (b) water jacket temperature (a) (b) Boat Conversion • 5 cylinders, each containing 26 kg of metal hydride power. • Gives about 2.5 kg of hydrogen. • Operating pressure is < 10 bar PEM Fuel Cell Batteries & Motor Start Finish Figure 2 PEM Fuel cell PEM 1kW FUEL CELL Figure 1 Energy flow diagram Figure 3 Computer monitoring systems Drive belt Moto r Propel ler shaft Figure 4 NdFeB Motor HYDROGEN SOLID STATE STORE 2.5kg H2 Throughout the world there is a huge effort to develop an effective, solid state, reversible, lightweight hydrogen store for road transport applications. There are, however, much less demanding transport applications which can employ established intermetallic metal hydrides as hydrogen stores. Development of these systems would allow solid state storage technologies to gain a “toe-hold” and hence accumulate invaluable operating experience. At Birmingham (and in collaboration with EMPA Switzerland) we have been developing a hybrid electric canal boat using a combination of a NdFeB-type permanent magnet electric motor, a lead acid battery stack and a PEM fuel cell supplied by a (TiV)(FeMn) 2 - metal hydride store (fig 1) The boat weighs 12 tonnes and the volume and weight (350 kg; metal frame, tank and metal hydrides) of the hydrogen storage system can readily be accommodated on the vessel, replacing the existing ballast.

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Page 1: Dr Alex Bevan 1, Dr David Book 1, Professor Andreas Z ü ttel 2 and Professor Rex Harris 1 1 University of Birmingham UK. 2 EMPA Z ü rich, Switzerland Performance

Dr Alex Bevan1, Dr David Book1, Professor Andreas Züttel2 and Professor Rex Harris1

1University of Birmingham UK.2 EMPA Zürich, Switzerland

Performance

0.00

2.00

4.00

6.00

8.00

10.00

12.00

14.00

0 1 2 3 4 5 6 7

Speed (kph)

Mo

tor

po

wer

(kW

)

0

50

100

150

200

250

300

350

1.5 2.5 3.5 4.5 5.5 6.5 7.5

Speed (kph)

Bo

at r

ang

e (k

m)

Battery power

Battery power + Hydrogen store

Key Objectives

Energy performance of the boat was monitored, with speed data being provided through GPS measurements. The motor power requirements vs. speed (fig 9) shows an exponential relationship (fitted line).

The theoretical range of the boat (fig 10) has been calculated based on the energy/ speed requirement. Utilizing a fully charged battery stack with 47kWhrs of energy and 2.5kg of hydrogen.

The metal hydride/ fuel cell combination increases the boat range by 66%

Provide vital practical data on the on-board use of hydrogen as an energy store.

Develop the necessary local scale hydrogen infrastructure which could provide a model and a catalyst for a much larger scale operation throughout the entire inland waterway network, with Birmingham as the hub.

Develop technical innovations which will lead to wider exploitation of the energy storage and propulsion systems.

Demonstrate an early, practical and economic alternative to diesel canal boats.

Figure 9 Power requirement vs. Speed

Figure 10 Theoretical boat range vs. Speed

Key features

•Hydride store has a significantly faster charging rate than the batteries•The craft will have a longer range of operation in the hybrid form before needing access to electric charging facilities•Batteries can be “trickle-charged” using solar panels, wind and water generators. PM electric motor can also serve as a generator•Fuel cell would prefer to operate at a constant load and any variability can be taken up by the battery stack•Hot water (80°C) supplied by fuel cell can be used to heat store and living space•Unlike batteries, hydride stores will not discharge on standing idle, even for prolonged periods•Other advantages (and disadvantages) will be revealed by operational experience

Potential Advantages of a Hybrid System

Solid state metal hydride store

1kW ReliOn PEM fuel cell (fig 2)

Computer monitoring and control (fig 3)

10kW NdFeB-based drive motor (Fig 4)

47kWhr lead acid battery stack

Display area with LCD screen

Project contact: Prof Rex Harris(e-mail: [email protected] Tel: +44-(0)121-4145165 web: www.hydrogen.bham.ac.uk)

Hydrogen also plays a crucial role in the manufacture of the NdFeB sintered magnets employed in the electric motor.

The Hydrogen StoreBased on 26kg of Laves-phase composition Ti0.93Zr0.05(Mn0.73V0.22Fe0.04)2 powder. Each of the 5 storage modules (fig 5) contains 7 connected stainless steel tubes which are each surrounded by a water cooling jacket. This provides 28m3 of pure hydrogen at STP (fig 6). Based on the hydrogen consumption of the ReliOn fuel cell, this is equivalent to 31kWhrs of stored energy. Thermal management of the storage units is accomplished by heat exchanging with canal water (fig 7), and the charging characteristics of one hydride module are shown in figure 8.

Hydride module

Hydride module

Hydride module

Hydride module

Hydride module

FuelcellGas

distribution

Mot

or

Heat exchanger

Canal water in

Water pump (1) Filter

Water pump (2)

Expansion tank

Canal water out

Hydride modules

Antifreeze

Hydrogen charging vs. time0

1000

2000

3000

4000

5000

6000

0 1 2 3 4 5 6 7

Time (Hours)

Hyd

rog

en

Flo

we

d (

Ltr

s)

Static water With water cooling flow

0

10

20

30

40

50

60

70

0 1 2 3 4 5 6 7

Time (Hours)

Wat

er t

emp

erat

ure

(C

elsi

us)

Static water With water cooling flow

Figure 5 Stainless steel storage modules

Figure 6 PCT diagram

Figure 7 Thermal management

Figure 8 Charging characteristics of one hydride module, showing (a) accumulated flow of hydrogen with and without controlling the (b) water jacket temperature

(a) (b)

Boat Conversion

• 5 cylinders, each containing 26 kg of metal hydride power.• Gives about 2.5 kg of hydrogen.• Operating pressure is < 10 bar

PEM Fuel Cell Batteries & Motor

Start

Finish

Figure 2 PEM Fuel cell

PEM 1kWFUEL CELL

Figure 1 Energy flow diagramFigure 3 Computer monitoring systems

Drive belt

Motor

Propeller shaft

Figure 4 NdFeB Motor

HYDROGEN SOLID STATE

STORE2.5kg H2

Throughout the world there is a huge effort to develop an effective, solid state, reversible, lightweight hydrogen store for road transport applications.

There are, however, much less demanding transport applications which can employ established intermetallic metal hydrides as hydrogen stores.

Development of these systems would allow solid state storage technologies to gain a “toe-hold” and hence accumulate invaluable operating experience.

At Birmingham (and in collaboration with EMPA Switzerland) we have been developing a hybrid electric canal boat using a combination of a NdFeB-type permanent magnet electric motor, a lead acid battery stack and a PEM fuel cell supplied by a (TiV)(FeMn)2 - metal hydride store (fig 1)

The boat weighs 12 tonnes and the volume and weight (350 kg; metal frame, tank and metal hydrides) of the hydrogen storage system can readily be accommodated on the vessel, replacing the existing ballast.