78.608655.161347.546946.150145.994341.649141.060240.309540.100039.890839.682039.474939.252338.689338.379736.963733.850033.079132.647032.414730.639428.099327.650527.085725.845823.564623.296422.961218.280216.998415.641215.2690

JH/1

6 (D

M/0

16) i

n C

DC

13 4

00 M

HZ

Oct

. 19-

2009

- FS-

Jam

es 1

1 1/

opt/t

opsp

in F

S

[ppm

]

0 5 10 15 [*1e6]

200

150

100

80

0

[ppm]

Oct

. 19-

2006

-FS-

Jam

es 1

3 1/

opt/t

opeo

m F

S

Oct

. Sca

ie: 2

.00

Oct

. 19-

2006

-FS-

Jam

es 1

2 1/

opt/t

opeo

m F

S

Oct

. Sca

ie: 2

.00

Oct

. 19-

2006

-FS-

Jam

es 1

1 1/

opt/t

opeo

m F

S

Oct

. Sca

ie: 2

.00

Oct

. 19-

2006

-FS-

Jam

es 1

1 1/

opt/t

opeo

m F

S

200

150

100

50

0

[ppm

]

0 10 20 30 40

[*1e6]

Analysis name: JHB.D Instrument: LC-MSD-Trap-VL Print date: 11/11/2009 10:57:17 AMMethod: FIA.M Operator: Administrator Acq. Date: 11/11/2009 10:52:17 AMSample name: JHBAnalysis info: JHB

2.50

2.25

2.00

1.75

150

1.25

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 Time [min]

300 320 340 360 380 400 420 440 460 480 m/z

800

600

400

200

0

Intens

304.9 339.0 363.9391.0

412.9

433.0

441.0

455.1

479.2+MS, 0.1 min#9

MSD trap report v5.2 (A4-Opt1) Page 1 of 1 Agilent techonologies

Intens×104

107.3106

104

102

100

98

96

94

92

90

88

86

84

82

80

78

76

74

72

70

67.3

4000.0 3000 2000 1500 1000 500 380.0

C:/pel_data/spectra/james 11.002-JH16

(%) T

2937.76

3384.90

1686.30

1460.76

1364.83

1386.56

1269.821182.29

1303.78

825.28

761.90655.20

567.54

402.25

80.938677.337277.019676.702055.283747.545646.542245.828241.535640.900539.272738.052837.690036.985433.780233.056032.509732.437730.664728.035027.660325.904723.576223.516423.385522.860221.307318.165017.173516.653415.3790

Oct

31-

2009

-FS-

Jam

es 1

1 1/

opt/t

opsi

n FS

JH/2

3 (D

M/0

23) i

n C

DC

13

400

MH

z

-184.1032

-171.0673

-143.6051

-122.5458

200

150

100

50

0

[ppm]

200150

50[ppm

]

Oct 31-2009-FS-Jam

es 11 1 /opt/topspin FS

Oct 31-2009-FS-Jam

es 11 1 /opt/topspin FS

Oct 31-2009-FS-Jam

es 12 1 /opt/topspin FS

Oct 31-2009-FS-Jam

es 13 1 /opt/topspin FS

1000

Analysis name: JHB.D Instrument: LC-MSD-Trap-VL Print date: 11/11/2009 10:57:17 AMMethod: FIA.M Operator: Administrator Acq. Date: 11/11/2009 10:52:17 AMSample name: JHBAnalysis info: JHB

0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 Time [min]

100 200 300 400 500 600 m/z

MSD trap report v5.2 (A4-Opt1) Page 1 of 1 Agilent techonologies

Intens×10−4

4

3

2

Intens2500

2000

1500

1000

500

0

TIC+All MS

+MS, 0.2 min#11521.2

441.0

413.1

393.1364.9

104.55

104.0

103.5

103.0

102.5

102.0

101.5

101.0

100.5

100.0

99.5

99.0

98.5

98.0

97.5

97.0

96.5

96.0

95.5

95.12

4000.0 3000 2000 1500 1000 500 380.0

cm−1

(%) T

3562.79

2921.05

1767.22

1729.82

1630.20

1453.17 1238.01

1026.10

1006.33