eknath m. gayakwad, vilas v. patil and ganapati s ... · new journal of chemistry...
TRANSCRIPT
![Page 1: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/1.jpg)
New Journal of Chemistry
Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide
Eknath M. Gayakwad, Vilas V. Patil and Ganapati S. Shankarling*
Address: Department of Dyestuff Technology, Institute of Chemical Technology, N. P. Marg, Matunga,
Mumbai - 400019, India;
Tel.: 91-22-33612708; Fax: 91-22-33611020E; mail- [email protected]
Supporting information
Sr. no. Content Page no.
1 FTIR Spectra 2-17
2 GC-MS and MS Spectra 18-33
3 1H NMR Spectra 34-49
Electronic Supplementary Material (ESI) for New Journal of Chemistry.This journal is © The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2015
![Page 2: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/2.jpg)
New Journal of Chemistry
2) FTIR Spectra,GC-MS and MS Spectra,1H NMR Spectra
FTIR Spectra
1) (methylsulfinyl)benzene (2a)
![Page 3: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/3.jpg)
New Journal of Chemistry
2) (methylsulfonyl)benzene (3a)
![Page 4: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/4.jpg)
New Journal of Chemistry
3) Sulfinyldibenzene (2b):
![Page 5: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/5.jpg)
New Journal of Chemistry
4) 2-(benzylsulfinyl) aceticacid(2c)
![Page 6: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/6.jpg)
New Journal of Chemistry
5) (benzylsulfonyl)acetic acid (3c):
![Page 7: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/7.jpg)
New Journal of Chemistry
6) Ethyl 2-benzylsulfonyl)acetate (3d)
![Page 8: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/8.jpg)
New Journal of Chemistry
7) 2-(benzylsulfinyl) ethanol (2e):
![Page 9: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/9.jpg)
New Journal of Chemistry
8) 2-(benzylsulfonyl) ethanol (3e):
![Page 10: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/10.jpg)
New Journal of Chemistry
9) 10-butyl-10H-phenothiazine 5-oxide (2f):
![Page 11: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/11.jpg)
New Journal of Chemistry
10)10-butyl-10H-phenothiazine 5,5-dioxide (3f):
![Page 12: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/12.jpg)
New Journal of Chemistry
11) 10-hexyl-10H-phenothiazine-3-carbaldehyde 5-oxide(2g)
![Page 13: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/13.jpg)
New Journal of Chemistry
12) 10-hexyl-10H-phenothiazine-3-carbaldehyde 5, 5-dioxide (3g)
![Page 14: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/14.jpg)
New Journal of Chemistry
13) 1-methoxy-4-(methylsulfinyl)benzene (2h)
![Page 15: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/15.jpg)
New Journal of Chemistry
14) 1-methoxy-4-(methylsulfonyl)benzene (3h):
![Page 16: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/16.jpg)
New Journal of Chemistry
15) 1-(methylsulfinyl)-4-nitrobenzene(2i)
![Page 17: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/17.jpg)
New Journal of Chemistry
16) 1-(methylsulfonyl)-4-nitrobenzene(3i)
![Page 18: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/18.jpg)
New Journal of Chemistry
EIMS/GCMS Spectra
1) (methylsulfinyl)benzene (2a)
![Page 19: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/19.jpg)
New Journal of Chemistry
2) (methylsulfonyl)benzene (3a)
![Page 20: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/20.jpg)
New Journal of Chemistry
3) Sulfinyldibenzene (2b)
![Page 21: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/21.jpg)
New Journal of Chemistry
4) 2-(benzylsulfinyl)acetic acid(2c)
![Page 22: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/22.jpg)
New Journal of Chemistry
5) 2-(benzylsulfonyl)acetic acid (3c)
![Page 23: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/23.jpg)
New Journal of Chemistry
6) Ethyl 2-benzylsulfonyl)acetate(3d)
![Page 24: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/24.jpg)
New Journal of Chemistry
7) 2-(benzylsulfinyl) ethanol (2e)
![Page 25: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/25.jpg)
New Journal of Chemistry
8) 2-(benzylsulfonyl) ethanol (3e)
![Page 26: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/26.jpg)
New Journal of Chemistry
9) 10-butyl-10H-phenothiazine 5-oxide (2f)
![Page 27: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/27.jpg)
New Journal of Chemistry
10) 10-butyl-10H-phenothiazine 5,5-dioxide (3f
![Page 28: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/28.jpg)
New Journal of Chemistry
11) 10-hexyl-10H-phenothiazine-3-carbaldehyde 5-oxide(2g)
20 MIN FOL_140731152018 #17 RT: 0.17 AV: 1 NL: 9.72E2T: + c ESI Full ms [ 300.00-400.00]
300 310 320 330 340 350 360 370 380 390 400
m/z
0
50
100
150
200
250
300
350
400
450
500
550
600
650
700
750
800
850
900
950
Inte
nsi
ty
312.42
311.29
328.02
370.91
314.00
![Page 29: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/29.jpg)
New Journal of Chemistry
12) 10-hexyl-10H-phenothiazine-3-carbaldehyde 5, 5-dioxide (3g)
![Page 30: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/30.jpg)
New Journal of Chemistry
13) 1-methoxy-4-(methylsulfinyl)benzene (2h)
![Page 31: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/31.jpg)
New Journal of Chemistry
14) 1-methoxy-4-(methylsulfonyl)benzene (3h)
![Page 32: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/32.jpg)
New Journal of Chemistry
15) 1-(methylsulfinyl)-4-nitrobenzene(2i)
![Page 33: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/33.jpg)
New Journal of Chemistry
16) 1-(methylsulfonyl)-4-nitrobenzene(3i)
![Page 34: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/34.jpg)
New Journal of Chemistry
1H-NMR
1) (methylsulfinyl)benzene (2a)
![Page 35: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/35.jpg)
New Journal of Chemistry
2) (methylsulfonyl)benzene (3a
![Page 36: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/36.jpg)
New Journal of Chemistry
3) Sulfinyldibenzene (2b)
![Page 37: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/37.jpg)
New Journal of Chemistry
4) 2-(benzylsulfinyl)acetic acid(2c)
![Page 38: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/38.jpg)
New Journal of Chemistry
5) 2-(benzylsulfonyl)acetic acid (3c)
![Page 39: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/39.jpg)
New Journal of Chemistry
6) Ethyl 2-benzylsulfonyl)acetate(3d)
![Page 40: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/40.jpg)
New Journal of Chemistry
7) 2-(benzylsulfinyl) ethanol (2e)
![Page 41: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/41.jpg)
New Journal of Chemistry
8) 2-(benzylsulfonyl) ethanol (3e)
![Page 42: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/42.jpg)
New Journal of Chemistry
9) 10-butyl-10H-phenothiazine 5-oxide (2f)
![Page 43: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/43.jpg)
New Journal of Chemistry
10) 10-butyl-10H-phenothiazine 5,5-dioxide (3f)
![Page 44: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/44.jpg)
New Journal of Chemistry
11) 10-hexyl-10H-phenothiazine-3-carbaldehyde 5-oxide(2g)
![Page 45: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/45.jpg)
New Journal of Chemistry
12) 10-hexyl-10H-phenothiazine-3-carbaldehyde 5, 5-dioxide (3g)
![Page 46: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/46.jpg)
New Journal of Chemistry
13) 1-methoxy-4-(methylsulfinyl)benzene (2h)
![Page 47: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/47.jpg)
New Journal of Chemistry
14) 1-methoxy-4-(methylsulfonyl)benzene (3h)
![Page 48: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/48.jpg)
New Journal of Chemistry
15) 1-(methylsulfinyl)-4-nitrobenzene(2i
![Page 49: Eknath M. Gayakwad, Vilas V. Patil and Ganapati S ... · New Journal of Chemistry Nonanebis(peroxoic acid) mediated efficient and selective oxidation of sulfide Eknath M. Gayakwad,](https://reader036.vdocuments.net/reader036/viewer/2022063004/5f83b068df117973eb5bc6c5/html5/thumbnails/49.jpg)
New Journal of Chemistry
16) 1-(methylsulfonyl)-4-nitrobenzene(3i)