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1 ZEECO, INC. ZEECO, INC. 2010 ZEECO, INC. ZEECO, INC. Emissions Testing of Sonic Velocity Flares

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Page 1: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC. ZEECO, INC.

2010 ZEECO, INC. ZEECO, INC.

Emissions Testing of Sonic Velocity Flares

Page 2: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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2010 ZEECO, INC. ZEECO, INC.

Flare Product DivisionJohn Ehlig

ZEECO, INC.

Multipoint Ground Flare History

Developed Early 1970’s

Zeeco founder was one of the original inventors and listed on Original Patent

Original Installation In 1972

Many Improvements over past 43 years in Burner technology

Basic Overall Concept Today is Same as Original

Page 3: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

Original Multipoint Flare Drawings

ZEECO, INC.

Burner Development in Past Years

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Page 4: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

Use Jet action of gas to entrain air for smokeless burning

Smokeless Burning over Wide pressure ranges

Low Radiation

Stable Operation at Sonic Velocity

Multiple burners for unobstructed air access

Wind is less of a factor due to significant momentum

Common Burner Characteristics

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ZEECO, INC.

Variable Arm Area

Investment Cast

Pressure Tested at Factory

310 SS Cast Material

Inherently Stable on Wide Range of Gases

Modern Sonic Velocity Burners

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Page 5: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

Many small burners – each able to pull in air

Staging system to Ensure Operation in Optimum Pressure Band – leading to smokeless operation

Burners in Service are Proportional to Gas Flow

Typically Used for High Pressure, Heavy Hydrocarbon Service

Allows for Controlled Flame Length from Burners

Common MPGF Design Concept

ZEECO, INC.

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Page 6: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

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ZEECO, INC.

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Page 7: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

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ZEECO, INC.

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Page 8: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

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ZEECO, INC.

Typical Staging Curve

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Page 9: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

Typical Installations

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ZEECO, INC.

Typical Installations

Page 10: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

1983 CMA Testing

Air assisted flare

Un-assisted flare

Steam assisted flare

Extractive Sampling

EPA Involvement

Basis for Current Flare Regulations, 40 CFR 60.18

ZEECO, INC.

1983 CMA Testing

Subsequent to all of the CMA sponsored testing of flare systems, there was a separate test using the same equipment on a pressure assisted flare tip.

Results of that test were submitted to the EPA.

Results showed very high destruction efficiency.

No specific conclusion, but the concept of if a stable flame exist, high CE exists.

Page 11: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

1983 CMA TEST DATA ON PRESSURE ASSISTED TIP TESTING, CRUDE PROPYLENE FIRING

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ZEECO, INC.

1986 EER Testing for EPA

Further EPA sponsored testing on different type of flare tips.

Testing was intended to analyze further gas mixtures, alternative gas types, etc.

3 inch nominal flare tip size for most tests.

Also, testing was performed on Pressure Assisted commercially available high velocity flare tips, Commercial tips “E” and “F”.

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Page 12: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

1986 EER TESTING ON PRESSURE ASSISTED FLARE TIPS, PROPANE IN NITROGEN

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ZEECO, INC.

Testing by DOW for Two Installations

Sonic velocity multipoint ground flares

Two different applications, 2007 and 2014

Nominal 4 inch spider type sonic burners.

General Test results presents at AFRC Meetings.

Page 13: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

DOW PRESSURE ASSISTED TIP TESTING, AFRC PRESENTATION, 2007, PROPYLENE / N2 MIX.

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ZEECO, INC.

DOW PRESSURE ASSISTED TIP TESTING, AFRC PRESENTATION, 2014.

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Page 14: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

Sonic Flare Full Scale Testing for Smokeless / Flame Length / Cross Lighting

Xylene Testing Ethylene Testing28

ZEECO, INC.

Multipoint Flare Burner Testing

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Page 15: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

Sonic Flare Testing at Zeeco for DRE

Natural Gas

Propylene

Propane

Inert / H2 Mixtures

Consistently over 99.5% DE

Summer 2013, Fall 2013, Fall 2014, Spring 2015

ZEECO, INC.

Testing Methods Used

Extractive Sampling

Sample Hood with Venturi Suction

Same Design and TCEQ / TU Tests 2010

Temperature and FLIR Camera for Positioning

PFTIR Analysis

Providence FEMS Optical Efficiency Monitor Device

Wind and weather monitoring

Page 16: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

Multipoint Sonic Flare Testing at Zeeco

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ZEECO, INC.

Test Area Video

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Page 17: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

Details for Recent Sonic Testing

Flare Gas Fuel TypeFlare Gas Lower Heating Value

(Btu/SCF)Max Allowable Exit Velocity per 40

CFR 60.18 Regulation (ft/s)Flare Gas Exit Velocity in Zeeco Test

Facility (ft/s)

Destruction Efficiency % from Extractive Sampling of Zeeco

FlaresCombustion Efficiency % from Extractive Sampling

Combustion Efficiency % from IMACC PFTIR Measurement

Operating Pressure (psig)

Propane 2316 400 800 99.99 99.99 99.6 16

54mol% Propane/46mol% N2 1251 400 903 99.99 99.99 99.9 10.3

Propylene 2183 400 823 99.99 99.96 99.6 16.9

Tulsa Natural Gas 937 400 1378 99.99 99.99 99.5 15

Propane 2316 400 820 99.99 99.99 15.1

55mol% Propane/ 45mol% N2 1274 400 913 99.99 99.99 10.2

Propylene 2183 400 859 99.99 99.99 15.4

Tulsa Natural Gas 937 400 1403 99.99 99.98 15.3

TNG 937 1443 99.997 99.9955 20

TNG 937 1440 99.9949 99.9943 20

87TNG/13N2 800 1411 99.9988 99.9976 20

65TNG/35N2 600 1323 99.9983 99.9971 20

76TNG/24N2 700 1387 99.9972 99.9887 20

54TNG/46N2 500 1307 99.9964 99.9882 20

30TNG/70H2 465 2500 99.9985 99.9964 20

30TNG/70H2 465 2450 99.9951 99.9923 20

30TNG/70H2 465 2495 99.9941 99.9925 20

Propane 2316 840 99.9977 99.9947 20

Propylene 2183 870 99.9991 99.9968 20

63Propylene/37N2 1375 954 99.9992 99.9971 20

37Propylene/63N2 808 1030 99.9979 99.9957 20

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ZEECO, INC.

Destruction Efficiency, Sonic Velocity

95.0

96.0

97.0

98.0

99.0

100.0

101.0

0 100 200 300 400 500 600 700 800 900 1000 1100 1200 1300 1400 1500 1600 1700 1800 1900 2000 2100 2200 2300 2400 2500

Des

truct

ion

Effic

ienc

y (%

)

Flare Gas Exit Velocity (ft/s)

Destruction Efficiency versus Flare Gas Exit Velocity

Assumed Destruction Efficiency per 40 CFR 60.18

Measured Destruction Efficiency from Extractive Sampling

Maximum Allowable Exit Velocity per 40 CFR 60.18

Page 18: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

Combustion Efficiency, Sonic Velocity

95.0

96.0

97.0

98.0

99.0

100.0

101.0

0 100 200 300 400 500 600 700 800 900 1000 1100 1200 1300 1400 1500

Com

bust

ion

Effic

ienc

y (%

)

Flare Gas Exit Velocity (ft/s)

Combustion Efficiency versus Flare Gas Exit Velocity

Maximum Allowable Exit Velocity per 40 CFR 60.18

Measured Combustion Efficiency from Extractive Sampling

Measured Combustion Efficiency from IMACC PFTIR technology

ZEECO, INC.

PFTIR versus Extractive Sampling Data

CE/DRE Testing Points - IMACC Testing Air Hygiene Data

Test Date Start TimeTest Facility Notation -

Test Point # Flare Fuel Actual Fuel Rate lb/hIMAAC Notation - Test

Point # IMACC CE% DRE % CE%

11/11/2014 9:25:00 AM 11A MPGF Propane 5159 15 99.6 99.99 99.99

11/11/2014 9:35:00 AM 13A MPGF Propane/ N2 2474/1347 16 99.9 99.99 99.99

11/11/2014 8:57:00 AM 12A MPGF Propylene 5053 17 99.6 99.99 99.96

11/11/2014 9:57:00 AM 14A MPGF Tulsa NG 3300 18 99.5 99.99 99.99

Page 19: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

Past Zeeco Sonic Testing Results

ZEECO, INC.

CFD Analysis

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Page 20: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

CFD Analysis

ZEECO, INC.

CFD Analysis

Page 21: Emissions Testing of Sonic Velocity Flarescontent.4cmarketplace.com/presentations/EmissionsTestingofSonic... · ZEECO, INC. Sonic Flare Testing at Zeeco for DRE Natural Gas Propylene

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ZEECO, INC.

General Benefits for MPGF High Destruction Efficiencies

Maximum Smokeless Capacity Possible

Low Utility Usage and Cost

Minimizes Impact to your Neighbors

Radiation Fence

Smoke Production

Easy Access for Maintenance

Small Plot Space

2010 ZEECO, INC. ZEECO, INC.

Questions?