enantioselective synthesis of homoallylic alcohols via a chiral in(iii)-pybox complex

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2005 Enantioselective syntheses O 0031 Enantioselective Synthesis of Homoallylic Alcohols via a Chiral In(III)-PYBOX Complex. — A novel chiral indium(III)-PYBOX complex is an efficient catalyst for the enantioselective allylation of aldehydes (I) and (IV). The catalyst could be easily recovered and reused without loss of enantioselectivity. — (LU, J.; HONG, M.-L.; JI, S.-J.; LOH*, T.-P.; Chem. Commun. (Cambridge) 2005, 8, 1010-1012; Dep. Chem., Natl. Univ. Singapore, Singapore 117543, Singapore; Eng.) — R. Staver 27- 032

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Page 1: Enantioselective Synthesis of Homoallylic Alcohols via a Chiral In(III)-PYBOX Complex

2005

Enantioselective synthesesO 0031 Enantioselective Synthesis of Homoallylic Alcohols via a Chiral In(III)-PYBOX

Complex. — A novel chiral indium(III)-PYBOX complex is an efficient catalyst for the enantioselective allylation of aldehydes (I) and (IV). The catalyst could be easily recovered and reused without loss of enantioselectivity. — (LU, J.; HONG, M.-L.; JI, S.-J.; LOH*, T.-P.; Chem. Commun. (Cambridge) 2005, 8, 1010-1012; Dep. Chem., Natl. Univ. Singapore, Singapore 117543, Singapore; Eng.) — R. Staver

27- 032