Upload File

enantioselective total synthesis of (s)-nakinadine b

  • Home
  • Documents
  • Enantioselective total Synthesis of (S)-Nakinadine B
15
Electronic Supplementary Information for Enantioselective total Synthesis of (S)-Nakinadine B Yuvraj Garg and Satyendra Kumar Pandey* School of Chemistry and Biochemistry, Thapar University, Patiala 147001, India *Corresponding Author: Telephone number: +91-175-239-3832, Fax No. +91-175-236-4498 E-mail address: [email protected] Table of contents General Experimental 1. 1 H and 13 C spectra for compound 11 S2-S3 2. 1 H and 13 C spectra for compound 13 S4-S5 3. 1 H and 13 C spectra for compound 14 S6-S7 4. 1 H and 13 C spectra for compound 15 S8-S9 5. 1 H and 13 C spectra for compound 16 S10-S11 6. 1 H and 13 C spectra for compound 17 S12-S13 7. 1 H and 13 C spectra for compound 3 S14-S15 S1 Electronic Supplementary Material (ESI) for RSC Advances. This journal is © The Royal Society of Chemistry 2016

Upload: others

Post on 16-Apr-2022

3 views

Category:

Documents


0 download

Report

TRANSCRIPT

Page 1: Enantioselective total Synthesis of (S)-Nakinadine B

Electronic Supplementary Information for

Enantioselective total Synthesis of (S)-Nakinadine B

Yuvraj Garg and Satyendra Kumar Pandey*

School of Chemistry and Biochemistry, Thapar University, Patiala 147001, India

*Corresponding Author: Telephone number: +91-175-239-3832, Fax No. +91-175-236-4498

E-mail address: [email protected]

Table of contents

General Experimental

1. 1H and 13C spectra for compound 11 S2-S3

2. 1H and 13C spectra for compound 13 S4-S5

3. 1H and 13C spectra for compound 14 S6-S7

4. 1H and 13C spectra for compound 15 S8-S9

5. 1H and 13C spectra for compound 16 S10-S11

6. 1H and 13C spectra for compound 17 S12-S13

7. 1H and 13C spectra for compound 3 S14-S15

S1

Electronic Supplementary Material (ESI) for RSC Advances.This journal is © The Royal Society of Chemistry 2016

mailto:[email protected]
Page 2: Enantioselective total Synthesis of (S)-Nakinadine B

1H NMR (400 MHz, CDCl3/TMS)

NO2

OH

11

S2

Page 3: Enantioselective total Synthesis of (S)-Nakinadine B

13C NMR (100 MHz, CDCl3)

NO2

O H

11

S3

Page 4: Enantioselective total Synthesis of (S)-Nakinadine B

1H NMR (400 MHz, CDCl3/TMS)

NO2

OTBS

13

S4

Page 5: Enantioselective total Synthesis of (S)-Nakinadine B

13C NMR (100 MHz, CDCl3)

NO2

OTBS

13

S5

Page 6: Enantioselective total Synthesis of (S)-Nakinadine B

1H NMR (400 MHz, CDCl3/TMS)

N

O

14

S6

Page 7: Enantioselective total Synthesis of (S)-Nakinadine B

13C NMR (100 MHz, CDCl3)

N

O

14

S7

Page 8: Enantioselective total Synthesis of (S)-Nakinadine B

1H NMR (400 MHz, CDCl3/TMS)

BocN

OTBS

15

12

N

S8

Page 9: Enantioselective total Synthesis of (S)-Nakinadine B

13C NMR (100 MHz, CDCl3)

BocN

OTBS

15

12

N

S9

Page 10: Enantioselective total Synthesis of (S)-Nakinadine B

1H NMR (400 MHz, CDCl3/TMS)

16

BocN

OH

N

12

S10

Page 11: Enantioselective total Synthesis of (S)-Nakinadine B

13C NMR (100 MHz, CDCl3)

16

BocN

OH

N

12

S11

Page 12: Enantioselective total Synthesis of (S)-Nakinadine B

1H NMR (400 MHz, CDCl3/TMS)

17

BocN

OH

HO

N

12

S12

Page 13: Enantioselective total Synthesis of (S)-Nakinadine B

13C NMR (100 MHz, CDCl3)

17

BocN

OH

HO

N

12

S13

Page 14: Enantioselective total Synthesis of (S)-Nakinadine B

1H NMR (400 MHz, CDCl3/TMS)

HN

O HO

nakinadine B 3 N

12

S14

Page 15: Enantioselective total Synthesis of (S)-Nakinadine B

13C NMR (100 MHz, CDCl3)

HN

O HO

nakinadine B 3 N

12

S15


ENANTIOSELECTIVE SYNTHESIS OF BIOACTIVE …ncl.csircentral.net/473/1/th1556.pdf1 enantioselective synthesis of bioactive molecules using asymmetric oxidations and synthetic methodologies

Enantioselective Synthesis of ( )- Jiadifenin, a Potent

Enantioselective total synthesis of callipeltoside A: two ...evans.rc.fas.harvard.edu/pdf/evans325.pdf · The enantioselective total synthesis of callipeltoside A is described.

Enantioselective Total Synthesis of Lyconadins A-E through ...fshan.ciac.jl.cn/wp-content/uploads/sites/14/2020/...Enantioselective Total Synthesis of Lyconadins A-E through A Palladium-Catalyzed

Enantioselective Synthesis of Dideoxy-tetrafluorinated Hexoses252Ejoc... · 2019. 12. 9. · Enantioselective Synthesis of Dideoxy-tetrafluorinated Hexoses Samuel Golten,† Clement

Enantioselective Metathesis Catalysts: Synthesis ...evans.rc.fas.harvard.edu/pdf/smnr_2004-2005_Young_Joseph.pdf · Enantioselective Metathesis Catalysts: Synthesis, Application,

Enantioselective synthesis of heterocyclic compounds mediated by

Enantioselective Total Synthesis of Nigelladine A via Late

Enantioselective Total Synthesis of (+)-Wortmanninccc.chem.pitt.edu/wipf/Current Literature/JohnM_11.pdf · Enantioselective Total Synthesis of (+)-Wortmannin ... •Key features

Enantioselective Synthesis of ( )-Cephalostatin 1chemh215/W10HTML/SSG3/Cephalostatin.pdf · Enantioselective Synthesis of (+)-Cephalostatin 1 Kevin C. Fortner,| Darryl Kato,‡ Yoshiki

Enantioselective, intermolecular [2+2] photocycloaddition ... · Enantioselective, intermolecular [2+2] photocycloaddition reactions of 3-acetoxyquinolone: Total synthesis of (−−−−)-pinolinone

Enantioselective Total Syntheses of (‒) (‒)

Research Paper for enantioselective drug synthesis

Enantioselective Total Synthesis of Cymoside through a

Litterature Meeting Enantioselective Total Synthesis of Avrainvillamide and Stephacidins A and B Aspergillus ochraceus

Catalytic Enantioselective Alkylative …ccc.chem.pitt.edu/wipf/Current Literature/Xueling_2.pdfCatalytic Enantioselective Alkylative Dearomatization-Annulation: Total Synthesis and

The First Enantioselective Synthesis of the Natural ...wiredspace.wits.ac.za/.../10988/1/KathyHadjeGeorgiou_0503329H_MSc… · The First Enantioselective Synthesis of the Natural

Enantioselective synthesis of pyrroloindolines and tryptophan

Enantioselective Total Synthesis of (-) Jiadifenolide

LSD Enantioselective Total Synthesis

Efficient Entry to the Hasubanan Alkaloids: First Enantioselective Total Synthesis of (-)- Hasubanonine, (-)-Runanine, (-)-Delavayine, and (+)-Periglaucine

Enantioselective Synthesis of Dialkylated N …...Enantioselective Synthesis of Dialkylated N-Heterocycles by Palladium-Catalyzed Allylic Alkylation Yoshitaka Numajiri†, Gonzalo

Enantioselective Total Synthesis of (+)-Gliocladin C and (+)-Gliocladine C

Enantioselective Total Synthesis of Ecteinascidin 743 Nan Li

Enantioselective Total Synthesis of Amphidinolide F

Enantioselective synthesis of

Enantioselective total synthesis of ( )-epoxyquinols A and B. …repository.ias.ac.in/28956/1/337.pdf · 2016. 5. 17. · Enantioselective total synthesis of ())-epoxyquinols A and

Enantioselective Total Synthesis of (+)-Psiguadial Bcapricorn.bc.edu/lsy/public_html/files/total-synthesis/2016-12-30... · Enantioselective Total Synthesis of (+)-Psiguadial B Lauren

Enantioselective Synthesis of 3,3 -Dihydropyrryl-spirooxindoles via an Organocatalytic ... · 2012. 6. 11. · 1 Enantioselective Synthesis of 3,3′-Dihydropyrryl-spirooxindoles

Catalytic Enantioselective Total Synthesis of (+) …authors.library.caltech.edu/68874/2/mmc1.pdfCatalytic Enantioselective Total Synthesis of (+)-Eucomic Acid Benzi I. Estipona, Beau

Enantioselective Enzymatic Desymmetrizations in Organic Synthesis

Sorensen’s Enantioselective Total Synthesis of FR182877

Synthesis of (-)-flustramine B: Enantioselective ...€¦ · Synthesis of (-)-flustramine B: Enantioselective organocatalytic Pyrroloindoline Construction Joel F. Austin, Sung-Gon

Enantioselective Synthesis of Cyclopropanone Equivalents

Enantioselective Total Synthesis and Structure Revision of Spirodihydrobenzofuranlactam 1. Total Synthesis of Stachybotrylactam Org. Lett. 2003, 5, 1785