f3 mindmap

12
What is Chemistry ? Chem Is Try An experiment based subject Observation 5 senses Vision Appearance Colour Transparency State / Form Size speed of reaction density solubility Hear hissing/pop Smell pleasant/sweet/pungent/irritating Taste Never try this in the school laboratory Touch hot/cold/vibrating hardness Use of instrument / chemical e.g. pH meter e.g. voltmeter e.g. pH paper Proper record keeping Common vocabulary colourless vs coloured transparent vs opaque vs cloudy bubbles evolving (effervescence) vigorous hissing sound powdered vs granulated sticky As detail as possible Analysis and report writing Laboratory Safety Discipline in the laboratory Briefing of experiment Distribution of chemicals Communication in laboratory Cleaning up The side bench Your own bench Exercising of common sense Personal protection laboratory gown safety spectacles / googles gloves wash hands Understand the nature of hazard Heat burn Chemical burn Minor Cut Hazard warning labels Proper experimental technique Technique Matches Test tube Smelling Sink No direct disposal No solid waste No organic waste Appropriate amount of chemical Other apparatus A science Scientific method Observation from nature from experiment Law (Rule/pattern) Hypothesis (proposed explanation) Make related prediction To be tested Theory (well-tested hypothesis) May not be the truth Give rise to technology Change the society Try to explain everything Something changed the world Material Science Petrochemical industry Fuel Raw materials for other industry Synthetic material plastic fibre metal and alloy glass paint and coating Agriculture Fertilizer Insecticide Feed the world population of 6 billion Food industry Food additives Biochemistry Medicine Drug Anesthetic Antiseptic Social Hygiene 1:99 Understanding of disease Alchemy Making of gold Making of potion/medicine Making different material Extraction of metal Treatment of metal Father of Chemistry (Robert Boyle (1627-91) Study of Change (of substances) Definition of matter occupies space has mass relationship between matter and substance Physical change of matter No new substance is formed e.g. evaporation of water Chemical change of matter New substance is formed e.g. electrolysis of water Study of Composition Structure Properties Physical Properties Appearance Odour Taste Melting,Boiling and Sublimation point Hardness Density Ductility and Malleability Electrical conductivity Thermal conductivity Chemical Properties Readiness of reaction Speed of reaction Outcome of reaction 1. What is Chemistry .mmap - 20/5/2005 -

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Page 1: F3 Mindmap

Wha

t is

Che

mis

try

?

Chem

Is T

ry

An e

xper

imen

t ba

sed

subj

ect

Obs

erva

tion

5 se

nses

Visi

on

Appe

aran

ce

Colo

ur

Tran

spar

ency

Stat

e /

Form

Size

spee

d of

rea

ctio

n

dens

ity

solu

bilit

y

Hea

rhi

ssin

g/po

p

Smel

lpl

easa

nt/s

wee

t/pu

ngen

t/ir

rita

ting

Tast

e

Nev

er t

ry t

his

in t

he s

choo

lla

bora

tory

Touc

hho

t/co

ld/v

ibra

ting

hard

ness

Use

of

inst

rum

ent

/ ch

emic

al

e.g.

pH

met

er

e.g.

vol

tmet

er

e.g.

pH

pap

er

Prop

er r

ecor

d ke

epin

gCo

mm

on v

ocab

ular

y

colo

urle

ss v

s co

lour

ed

tran

spar

ent

vs o

paqu

e vs

clou

dy

bubb

les

evol

ving

(eff

erve

scen

ce)

vigo

rous

hiss

ing

soun

d

pow

dere

d vs

gra

nula

ted

stic

ky

As d

etai

l as

poss

ible

Anal

ysis

and

rep

ort

wri

ting

Labo

rato

ry S

afet

y

Dis

cipl

ine

in t

he la

bora

tory

Brie

fing

of

expe

rim

ent

Dis

trib

utio

n of

chem

ical

s

Com

mun

icat

ion

in la

bora

tory

Clea

ning

up

The

side

ben

ch

Your

ow

n be

nch

Exer

cisi

ng o

f co

mm

on s

ense

Pers

onal

pro

tect

ion

labo

rato

ry g

own

safe

ty s

pect

acle

s /

goog

les

glov

es

was

h ha

nds

Und

erst

and

the

natu

re o

fha

zard

Hea

t bu

rn

Chem

ical

bur

n

Min

or C

ut

Haz

ard

war

ning

labe

ls

Prop

er e

xper

imen

tal t

echn

ique

Tech

niqu

e

Mat

ches

Test

tub

e

Smel

ling

Sink

No

dire

ct d

ispo

sal

No

solid

was

te

No

orga

nic

was

te

Appr

opri

ate

amou

nt o

fch

emic

al

Oth

er a

ppar

atus

A sc

ienc

eSc

ient

ific

met

hod

Obs

erva

tion

from

nat

ure

from

exp

erim

ent

Law

(Ru

le/p

atte

rn)

Hyp

othe

sis

(pro

pose

dex

plan

atio

n)M

ake

rela

ted

pred

icti

on

To b

e te

sted

Theo

ry (

wel

l-te

sted

hypo

thes

is)

May

not

be

the

trut

h

Giv

e ri

se t

o te

chno

logy

Chan

ge t

he s

ocie

ty

Try

to e

xpla

in e

very

thin

g

Som

ethi

ng c

hang

ed t

hew

orld

Mat

eria

l Sci

ence

Petr

oche

mic

al in

dust

ryFu

el

Raw

mat

eria

ls f

or o

ther

indu

stry

Synt

heti

c m

ater

ial

plas

tic

fibr

e

met

al a

nd a

lloy

glas

s

pain

t an

d co

atin

g

Agri

cult

ure

Fert

ilize

r

Inse

ctic

ide

Feed

the

wor

ld p

opul

atio

n of

6bi

llion

Food

indu

stry

Food

add

itiv

es

Bioc

hem

istr

y

Med

icin

e

Dru

g

Anes

thet

ic

Anti

sept

ic Soci

al H

ygie

ne1:

99

Und

erst

andi

ng o

f di

seas

e

Alc

hem

y

Mak

ing

of g

old

Mak

ing

of p

otio

n/m

edic

ine

Mak

ing

diff

eren

t m

ater

ial

Extr

acti

on o

f m

etal

Trea

tmen

t of

met

al

Fath

er o

f Ch

emis

try

(Rob

ert

Boyl

e (1

627-

91)

Stud

y of

Cha

nge

(of

subs

tanc

es)

Def

init

ion

of m

atte

r

occu

pies

spa

ce

has

mas

s

rela

tion

ship

bet

wee

n m

atte

ran

d su

bsta

nce

Phys

ical

cha

nge

of m

atte

rN

o ne

w s

ubst

ance

is f

orm

ed

e.g.

eva

pora

tion

of

wat

er

Chem

ical

cha

nge

of m

atte

rN

ew s

ubst

ance

is f

orm

ed

e.g.

ele

ctro

lysi

s of

wat

er

Stud

y of

Com

posi

tion

Stru

ctur

e

Prop

erti

es

Phys

ical

Pro

pert

ies

Appe

aran

ce

Odo

ur

Tast

e

Mel

ting

,Boi

ling

and

Subl

imat

ion

poin

t

Har

dnes

s

Den

sity

Duc

tilit

y an

d M

alle

abili

ty

Elec

tric

al c

ondu

ctiv

ity

Ther

mal

con

duct

ivit

y

Chem

ical

Pro

pert

ies

Read

ines

s of

rea

ctio

n

Spee

d of

rea

ctio

n

Out

com

e of

rea

ctio

n

1. W

hat i

s C

hem

istry

.mm

ap -

20/5

/200

5 -

Page 2: F3 Mindmap

Fund

amen

tals

of

chem

istr

yPart

icle

the

ory

ofm

atte

r

Theo

ry

All m

atte

rs a

re m

ade

up o

fti

ny p

arti

cles

.

Evid

ence

s

Dif

fusi

on

Uni

que

crys

tal s

hape

sM

akin

g of

cry

stal

Evap

orat

ion

of s

atur

ated

solu

tion

Brow

nian

mov

emen

t

Kine

tic

theo

ry o

f m

atte

rTh

eory

All m

atte

rs a

re m

ade

up o

fti

ny p

arti

cles

wit

h sp

aces

amon

g th

e pa

rtic

les.

Part

icle

s ar

e in

con

stan

tra

ndom

mot

ion

K.E.

of

the

part

icle

s in

crea

sew

ith

incr

easi

ng t

empe

ratu

re

Able

to

expl

ain

The

exis

tenc

e of

3 p

hysi

cal

stat

es

The

chan

ge in

phy

sica

l sta

tes

Exis

tenc

e of

Ele

men

ts

Def

init

ion

A pu

re s

ubst

ance

tha

t ca

nnot

be b

roke

n do

wn

into

any

thin

gsi

mpl

er b

y ch

emic

al m

etho

ds.

e.g.

hyd

roge

n

Nat

ural

ly o

ccur

ring

ele

men

ts

92 o

nly

e.g.

hyd

roge

n,ox

ygen

, so

dium

Arti

fici

al e

lem

ents

By 3

Feb

200

4, 2

5 ne

wel

emen

ts w

ere

mad

e by

the

scie

ntis

t. E

lem

ent

117

is s

till

not

disc

over

ed.

Rela

tive

abu

ndan

t

49.9

% O

xyge

n

26.0

% Si

licon

7.3%

Alu

min

ium

4.1%

Iron

Exis

tenc

e of

Com

poun

ds

Def

init

ion

A pu

re s

ubst

ance

mad

e up

of

two

or m

ore

elem

ents

chem

ical

ly c

ombi

ned

toge

ther

.

e.g.

com

mon

sal

t -

sodi

um c

hlor

ide

Impo

rtan

t te

rms

Reac

tion

, re

acta

nt,

prod

uct

Form

atio

n of

com

poun

ds f

rom

elem

ents

Dec

ompo

siti

on o

f co

mpo

unds

to e

lem

ents

Exis

tenc

e of

Mix

ture

Anyt

hing

tha

t is

impu

re.

i.e.

Two

or m

ore

pure

sub

stan

ces

mix

ed b

ut n

ot c

hem

ical

lyco

mbi

ned

toge

ther

e.g.

sal

t so

luti

on

Dif

fere

nce

betw

een

Mix

ture

and

Com

poun

d

Sepa

rati

on o

f M

ixtu

re

e.g.

eva

pora

tion

of

salt

sol

utio

n

2. F

unda

men

tals

of c

hem

istry

.mm

ap -

19/5

/200

5 -

Page 3: F3 Mindmap

Atm

osph

ereTh

e ou

term

ost

laye

r of

ear

th

Intr

oduc

tion

to

ear

th

Plac

e w

here

we

live

Sour

ce o

f m

ater

ial /

res

ourc

es

Ove

rvie

w45

00 m

illio

n ye

ars

old

1280

0 km

in d

iam

eter

Laye

red

stru

ctur

eof

ear

th

Atm

osph

ere

80 k

m t

hick

held

to

eart

h by

gra

vity

Oce

anco

ver

70%

of e

arth

cru

st

max

10.

9 km

Crus

t5-

70 k

m

Man

tle

thic

k liq

uid

/ se

mi s

olid

roc

k

Out

er c

ore

dens

e liq

uid

iron

the

flow

of

iron

crea

tes

a m

agne

tic

fuild

Inne

r Co

rede

nse

solid

iron

Com

posi

tion

A m

ixtu

re o

f di

ffer

ent

gase

s

78.0

84 %

nit

roge

n

20.9

47%

oxyg

en

0.93

4% a

rgon

0.03

3% c

arbo

n di

oxid

e

18.2

ppm

/ 0

.001

82 %

Ne

5.2

ppm

/ 0

.000

52%

He

Oth

ers

: kr

yton

, su

lphu

r di

oxid

e,

Met

hane

, H

ydro

gen,

din

itro

gen

oxid

e,xe

non,

ozo

ne,

nitr

ogen

dio

xide

,io

dine

, ca

rbon

mon

oxid

e, a

mm

onia

Sepa

rati

on o

f di

ffer

ent

com

pone

nts

Frac

tion

al d

isti

llati

on o

f liq

uid

air

Dif

fere

nt c

ompo

nent

s ha

vedi

ffer

ent

boili

ng p

oint

s

Prop

erti

es o

f ox

ygen

Phys

ical

- c

olou

rles

s, o

dorl

ess,

slig

htly

den

ser

than

air

,sl

ight

ly s

olub

le

Chem

ical

- r

eact

ive,

sup

port

burn

ing,

for

m o

xide

s w

ith

othe

r el

emen

ts

Test

for

oxy

gen

Perc

enta

ge -

Pas

sing

air

fro

than

d ba

ck o

ver

heat

ed c

oppe

r

Pres

ence

- R

elig

ht g

low

ing

splin

t

Use

of

Gas

es

Oxy

gen

Filli

ng o

xyge

n ta

nk f

orbr

eath

ing

Fuel

in r

ocke

ts a

nd s

pace

shut

tles

For

wel

ding

and

cut

ting

met

al

Nit

roge

n

Food

pac

kagi

ng

As r

efri

gera

nt t

o pr

ovid

e a

very

low

tem

p. e

.g.

sper

mba

nk

Mak

ing

amm

onia

- r

awm

ater

ial f

or m

akin

g fe

rtili

zer,

nitr

ic a

cid

etc.

Carb

on d

ioxi

de

Dry

ice

Fuzz

y so

ft d

rink

Fire

ext

ingu

ishe

rs

Nob

le g

ases

Hel

ium

- f

illin

g ai

r sh

ip a

ndba

lloon

(lig

ht a

ndno

n-fl

amm

able

)

Neo

n -

Use

d in

neo

n lig

ht

Argo

n -

Filli

ng li

ght

bulb

Cha

pter

3 -

The

atm

osph

ere

Page 4: F3 Mindmap

Oce

ans

Intr

oduc

tion

70%

of e

arth

cru

st c

over

ed b

yw

ater

(oc

ean

and

sea)

Sea

wat

er c

onta

ins

diff

eren

tsa

lts

sodi

um c

hlor

ide

68%

(com

mon

sal

t)

mag

nesi

um c

hlor

ide

15%

sodi

um s

ulph

ate

11%

calc

ium

chl

orid

e 3%

othe

r sa

lts

3%

Extr

acti

on o

f co

mm

onsa

lt f

rom

sea

wat

er

Evap

orat

ion

by s

un

by d

irec

t he

atin

g or

indi

rect

heat

ing

wit

h st

eam

bat

h

Filt

rati

on a

nd

crys

talli

zati

on b

y ev

apor

atio

n or

co

olin

g

Rem

ovin

g th

e in

solu

ble

impu

riti

es (

resi

due)

Mak

ing

a sa

tura

ted

solu

tion

Slow

er t

he

crys

talli

zati

on p

roce

ss,

bigg

er t

he c

ryst

al

Isol

atio

n of

pur

e w

ater

from

sea

wat

erD

isti

llati

on

Labo

rato

ry s

etup

(w

itho

utw

ater

con

dens

er)

Labo

rato

ry s

etup

(w

ith

wat

erco

nden

ser

usin

g Q

uick

fit

appa

ratu

s)

Des

alti

ng p

lant

- d

isti

llati

on in

larg

e sc

ale

Test

for

dif

fere

ntco

mpo

siti

ons

in s

ea w

ater

Sodi

um io

nFl

ame

test

Plat

inum

wir

e, c

once

ntra

ted

hydr

ochl

oric

aci

d, b

unse

nbu

rner So

dium

ion

give

s br

illia

ntgo

lden

yel

low

fla

me

Can

be u

sed

to t

est

for

othe

r m

etal

:po

tass

ium

- l

ilac

calc

ium

- b

rick

red

copp

er -

blu

ish

gree

n

Chlo

ride

ion

Silv

er n

itra

te s

olut

ion

+ di

lute

nit

ric

acid

Whi

te p

reci

pita

te

Wat

er

anhy

drou

s co

pper

(II)

sulp

hate

pow

der

turn

s fr

om w

hite

to

blue

anhy

drou

s co

balt

(II)

chlo

ride

pap

ertu

rns

from

blu

e to

pin

k

Elec

trol

ysis

of

brin

e(P

ure

conc

entr

ated

sodi

um c

hlor

ide

solu

tion

) -

Chlo

r-al

kali

indu

stry

Hyd

roge

nga

s

Mak

ing

hydr

ochl

oric

aci

d,m

arga

rine

, am

mon

ia,

rock

etfu

el

Chl

orin

ega

s

Mak

ing

hydr

ochl

oric

aci

d, P

VCpl

asti

c, c

hlor

ine

blea

ch,

solv

ent.

Ste

riliz

ing

wat

er

Sodi

umhy

drox

ide

solu

tion

Mak

ing

soap

and

pap

er.

Extr

acti

ng a

lum

iniu

m.

Trea

ting

acid

was

te

4. O

cean

s.m

map

- 10

/11/

2004

-

Page 5: F3 Mindmap

Rock

s an

d M

iner

als

Wea

ther

ing

and

Eros

ion

Wea

ther

ing

Slow

pro

cess

of

brea

king

up

ofex

pose

d ro

ck in

to s

mal

ler

piec

e

Phys

ical

wea

ther

ing

Tem

p. c

hang

e

Irre

gula

r co

ntra

ctio

n an

dex

pans

ion

of d

iffe

rent

min

eral

s

Fros

t ac

tion

Wat

er f

reez

es in

cra

cks

inro

cks

and

expa

nds

Abra

sion

Cons

tant

abr

asio

n of

win

d,st

ream

s an

d w

ave

Che

mic

alw

eath

erin

g

Atta

ck b

y ac

id r

ain

(lim

esto

ne,

chal

k,m

arbl

e)

carb

on d

ioxi

de +

wat

er

= ca

rbon

ic a

cid

calc

ium

car

bona

te (

inso

lubl

e) +

car

boni

c ac

id=

calc

ium

hyd

roge

ncar

bona

te (

solu

ble)

calc

ium

car

bona

te (

inso

lubl

e) +

str

ong

acid

= ca

lciu

m s

alt

+ ca

rbon

dio

xide

+ w

ater

effe

rves

cenc

eob

serv

ed

Atta

ck b

y ox

ygen

Iron

con

tain

ing

rock

will

cor

rode

and

form

red

iron

oxi

des

Che

mic

alpr

oper

ties

of c

alci

umca

rbon

ate

Hea

t ca

lciu

m c

arbo

nate

(lim

esto

ne)

stro

ngly

gi

ves

calc

ium

oxi

de (

quic

klim

e) a

nd c

arbo

n di

oxid

e

Add

a lit

tle

wat

er t

o ca

lciu

m o

xide

(qu

ickl

ime)

turn

s it

to

calc

ium

hyd

roxi

de (

slak

ed li

me)

+ h

eat

Dis

solv

eca

lciu

mhy

drox

ide

(sla

ked

lime)

ina

lot

of w

ater

to

giv

e ca

lciu

mhy

drox

ide

solu

tion

/su

spen

sion

(lim

ewat

er)

Use

of

lim

ewat

erto

tes

tfo

rca

rbon

diox

ide

calc

ium

hyd

roxi

de (

solu

ble)

+ca

rbon

dio

xide

= c

alci

umca

rbon

ate

(ins

olub

le)

+ w

ater

Test

for

cal

cium

ion

(Fla

me

test

) -

bric

k re

d fl

ame

Test

for

car

bona

te i

on -

add

hyd

roch

lori

c ac

id a

nd

allo

w t

he g

as e

volv

ed t

o pa

ss t

hrou

gh li

mew

ater

Eros

ion

Slow

pro

cess

of

wea

ther

ing

ofro

ck a

nd t

rans

port

ing

away

from

the

ori

gina

l pla

ceM

iner

al

a na

tura

l sol

id w

ith

defi

nite

crys

talli

ne s

truc

ture

and

chem

ical

com

posi

tion

The

arra

ngem

ent

of p

arti

cles

are

regu

lar

e.g.

gra

phit

e, a

lum

iniu

mox

ide,

sod

ium

chl

orid

e

Use

of

min

eral

s

grap

hite

- p

enci

l lea

d

rock

sal

t -

cook

ing

jade

- j

ewel

lery

mar

ble

- bu

ildin

g m

ater

ial

gold

- j

ewel

lery

Met

al i

s us

uall

y ex

trac

ted

from

ore

Ore

- a

min

eral

fro

m w

hich

aco

nsti

tuen

t ca

n be

pro

fita

bly

extr

acte

d

Extr

acti

on p

roce

ss -

min

ing,

conc

entr

atin

g or

e, e

xtra

ctio

nof

met

al,

puri

fyin

g im

pure

met

al

Extr

acti

on o

f ir

onfr

om h

aem

atit

e (m

ainl

y ir

on(I

II) o

xide

)

Hea

ting

haem

atit

ew

ith

carb

on

Extr

acti

on o

f al

umin

ium

fro

m

baux

ite

(mai

nly

alum

iniu

m o

xide

)

Elec

trol

ysis

of m

olte

nba

uxit

e

The

reso

urce

is li

mit

ed

Rock

a so

lid m

ass

of a

min

eral

or

am

ixtu

re o

f m

iner

als

Thre

e m

ain

type

s of

roc

k

Sedi

men

tary

Form

ed b

y se

dim

enta

tion

of

min

eral

s, r

emai

ns o

f pl

ant

and

anim

als

and/

or o

ther

prec

ipit

ates

e.g.

lim

esto

ne,

chal

k, s

ands

tone

Igne

ous

Form

ed b

y ha

rden

ing

ofm

olte

n ro

ck

e.g.

gra

nite

, ba

salt M

etam

orph

ic

Form

ed f

rom

sed

imen

tary

or

igne

ous

rock

und

er h

eat

and/

or p

ress

ure

e.g.

mar

ble,

sla

te

Lim

esto

ne,

chal

k an

d m

arbl

e(2

sed

imen

tary

roc

ks a

nd 1

met

amor

phic

roc

k)

All c

onta

in c

alci

te (

calc

ium

car

bona

te)

Ori

gin

limes

tone

and

cha

lk -

fro

m t

here

mai

ns o

f se

a sh

ells

mar

ble

- fr

om r

ecry

stal

lizat

ion

of li

mes

tone

und

er h

eat

and

pres

sure

Use

s

Lim

esto

ne -

bui

ldin

g m

ater

ial,

mak

ing

cem

ent,

gla

ss,

stee

l,pa

per,

neu

tral

izin

g ac

id

Chal

k -

build

ing

mat

eria

l

Mar

ble

- bu

ildin

g m

ater

ial,

mar

king

sta

tue

and

mon

umen

t

5. R

ocks

and

min

eral

s.m

map

- 25

/11/

2004

-

Page 6: F3 Mindmap

Ato

mic

stru

ctur

eElem

ent

Def

init

ion

- Su

bsta

nce

that

can

not

be b

roke

n do

wn

into

any

thin

gsi

mpl

er b

y ch

emic

al m

etho

d (e

.g.

by h

eati

ng /

ele

ctro

lysi

s)

Clas

sifi

cati

on

by p

hysi

cal s

tate

solid

liqui

d

gas

by m

etal

licpr

oper

ties

met

al

Silv

ery

whi

te(e

xcep

t Au

(go

lden

yel

low

) an

dCu

(re

ddis

h br

own)

Mal

leab

le a

nd d

ucti

le

Goo

d co

nduc

tor

of h

eat

and

elec

tric

ity

non-

met

al

Vari

ousl

y co

lour

ed

Brit

tle

Usu

ally

poo

r co

nduc

tor

of e

lect

rici

ty a

nd h

eat

sem

i-m

etal

/m

etal

loid

Test

for

met

allic

pro

pert

ies

Chem

ical

Sym

bols

Atom

s

Def

init

ion

- Sm

alle

st p

art

of a

n el

emen

t st

illpo

sses

ses

the

prop

erti

es o

f th

e el

emen

t.

0.03

nm

- 0

.30

nm ;

1 m

= 1

,000

,000

,000

nm

ON

E el

emen

t is

com

pris

ed o

fon

ly O

NE

kind

of

atom

s.

Chem

ical

Sym

bols

for

the

ele

men

ts c

anal

so b

e us

ed a

s th

e At

omic

Sym

bol.

Mas

s of

ato

ms

Isot

opes

Atom

s of

the

sam

e el

emen

t w

ith

diff

eren

t m

ass

/ m

ass

no.

/ no

. of

neu

tron

Hav

ing

the

sam

e ch

emic

al p

rope

rtie

s bu

t sl

ight

lydi

ffer

ent

phys

ical

pro

pert

ies

Carb

on-1

2 sc

ale

a C-

12 is

otop

e is

def

ined

as

havi

ngex

actl

y 12

uni

ts o

f m

ass

(Rel

ativ

e) Is

otop

ic m

ass

Mas

s of

a p

arti

cula

r is

otop

eba

sed

on C

-12

scal

e

Isot

opic

mas

s ≈

mas

s no

. (n

ot e

qual

)

(Rel

ativ

e) a

tom

ic m

ass

Rela

tive

abu

ndan

ceof

dif

fere

nt is

otop

es

Wei

ghte

d av

erag

e of

isot

opic

mas

ses

Elec

tron

ic

conf

igur

atio

nof

ato

ms

by n

umbe

ring

by e

lect

ron

diag

ram

elec

tron

ic a

rran

gem

ent

of t

he f

irst

20

elem

ents

Stab

ility

and

ele

ctro

nic

conf

igur

atio

n of

nob

le g

ases

dupl

et o

r oc

tet

Stru

ctur

eof

ato

ms

Dif

fere

nt m

odel

s

Dal

ton'

s m

odel

Atom

s ar

e in

divi

sibl

e sp

here

s

Thom

son'

s m

odel

Rais

in p

uddi

ng m

odel

-el

ectr

ons

on a

pos

itiv

e pu

ddin

g

Ruth

erfo

rd's

mod

elN

ucle

us +

ele

ctro

ns

Bohr

's m

odel

Nuc

leus

+ e

lect

rons

orbi

ting

aro

und

Orb

ital

mod

el

Loca

tion

of

elec

tron

s ca

n on

lybe

des

crib

ed b

y pr

obab

ility

Fund

amen

tal

suba

tom

icpa

rtic

les

- Al

l at

oms

are

mad

e up

of

thes

e.

Prot

onPo

siti

ve p

arti

cle

at n

ucle

us

Neu

tron

Elec

tric

ally

neu

tral

par

ticl

eat

nuc

leus

wit

h th

e sa

me

mas

s as

pro

ton

Elec

tron

Neg

ativ

e pa

rtic

le w

ith

virt

ually

no

mas

s, t

hesa

me

amou

nt o

f ch

arge

as p

roto

n, o

rbit

ing

arou

nd n

ucle

us

In a

n el

ectr

ical

ly n

eutr

al a

tom

, #

of p

= #

of

n

Atom

ic n

o. (

Z)no

. of

pro

ton

uniq

ue t

o in

divi

dual

ele

men

t

Mas

s no

. (A

)no

. of

pro

ton

+ no

. of

neu

tron Fu

ll at

omic

sym

bol

wit

h m

ass

no.

wit

h or

wit

hout

ato

mic

no.

over

all a

ll ch

arge

s

tota

l no.

of

p -

tota

l no.

of e

lect

ron

no.

of s

peci

es

6. A

tom

ic s

truct

ure.

mm

ap -

21/1

/200

5 -

Page 7: F3 Mindmap

The

Peri

odic

Tab

le

Dev

elop

men

t of

Per

iodi

cTa

ble

Prop

erti

es o

f va

riou

s el

emen

ts a

re c

ompa

red

Elem

ents

wit

h si

mila

r ch

emic

al p

rope

rtie

s ar

e gr

oupe

d to

geth

er in

gro

ups

e.g.

sod

ium

, po

tass

ium

e.g.

chl

orin

e, b

rom

ine,

iodi

ne

Elem

ents

are

arr

ange

d in

asc

endi

ngor

der

of a

tom

ic n

o. (

not

mas

s)

Elem

ents

sho

ws

peri

odic

vari

atio

n of

pro

pert

ies

e.g.

non

-met

al,

met

al,

sem

i-m

etal

, no

n-m

etal

,m

etal

, se

mi-

met

al,

non-

met

al,

met

al..

.

e.g.

gas

, so

lid,

gas,

sol

id,

gas,

sol

id,

gas,

sol

id..

.

Stru

ctur

e of

a m

oder

npe

riod

ic t

able

Elem

ents

wit

h th

e sa

me

no.

of o

ccup

ied

elec

tron

shel

ls a

re a

rran

ged

in r

ows

calle

d pe

riod

Peri

od n

o. =

no.

of

occu

pied

ele

ctro

n sh

ells

Elem

ents

wit

h si

mila

r ch

emic

alpr

oper

ties

are

arr

ange

d in

vert

ical

col

umn

calle

d gr

oups

Gro

up n

o. =

no.

of

oute

rmos

t el

ectr

on

Som

e sp

ecia

l gro

ups

Gro

up I

- al

kali

met

als

soft

, ca

n be

cut

by

a kn

ife

silv

ery

reac

tive

reac

t w

ith

wat

er t

o gi

ve a

nal

kain

e so

luti

on

Gro

up II

- a

lkal

ine

eart

h m

etal

sle

ss r

eact

ive

than

alk

ali m

etal

Gro

up V

II -

halo

gens

pois

onou

s

reac

tive

reac

t w

ith

sodi

um s

ulph

ite

solu

tion

to

give

col

ourl

ess

prod

ucts

Gro

up 0

- n

oble

gas

esco

lour

less

gas

very

sta

ble

Gro

up t

rend

met

al

reac

tivi

ties

incr

ease

s do

wn

agr

oup

Met

al a

tom

lose

s el

ectr

on m

ore

read

ily d

own

a gr

oup

Attr

acti

on b

etw

een

the

oute

rmos

t el

ectr

on a

nd t

henu

cleu

s ge

ts le

ss a

s th

e si

ze o

f th

e at

om g

ets

bigg

er

non-

met

al

reac

tivi

ties

dec

reas

e do

wn

agr

oup

Non

-met

al a

tom

gai

ns e

lect

ron

less

rea

dily

dow

n a

grou

p

Attr

acti

on b

etw

een

the

inco

min

g el

ectr

on a

nd t

he n

ucle

usge

ts le

ss a

s th

e si

ze o

f th

e at

om g

ets

bigg

er'

Gro

upin

g in

blo

cks

40 m

etal

s in

the

mid

dle

of t

he t

able

are

cal

led

tran

siti

on m

etal

s

28 m

etal

s in

the

a s

epar

ate

bloc

k at

the

bot

tom

are

cal

led

rare

ear

th m

etal

s /

elem

ents

All o

ther

ele

men

ts o

n th

e 2

side

s ar

e ca

lled

mai

n gr

oup

elem

ents

7. T

he P

erio

dic

Tabl

e.m

map

- 21

/1/2

005

-

Page 8: F3 Mindmap

Ioni

c bo

ndin

g

Cond

ucti

vity

of

com

poun

ds in

liqu

id o

raq

ueou

s st

ate

Elec

trol

yte

a co

mpo

und

whi

ch c

ondu

cts

atliq

uid

or a

queo

us s

tate

onl

y

usua

lly c

ompr

ised

of

met

alan

d no

n-m

etal

cons

ists

of

part

icle

s ca

lled

ions

ion

: an

ele

ctri

cally

cha

rged

atom

(si

mpl

e io

n) o

r gr

oup

ofat

oms

(pol

yato

mic

ion)

non-

elec

trol

yte

a co

mpo

und

whi

ch d

oes

not

cond

uct

at li

quid

or

aque

ous

stat

e

com

pris

ed o

f no

n-m

etal

s on

ly

cons

ists

of

part

icle

s ca

lled

mol

ecul

e

mol

ecul

e :

the

smal

lest

par

ticl

eth

at c

an e

xist

on

its

own

(ele

ctri

cally

unc

harg

ed)

Evid

ence

of

pres

ence

of

ions

Elec

trol

ysis

of

elec

trol

yte

Elec

trol

ysis

of

mol

ten

elec

trol

yte

e.g.

mol

ten

lead

(II)

brom

ide

Som

e te

rms

cati

on :

pos

itiv

e io

n

anio

n :

nega

tive

ion

cath

ode

: th

e el

ectr

ode

whi

ch t

heca

tion

(+v

e io

n) m

oves

tow

ards

to

anod

e :

the

elec

trod

e w

hich

the

anio

n (-

ve io

n) m

oves

tow

ards

to

posi

tive

ele

ctro

de :

the

elec

trod

e co

nnec

ting

to

the

posi

tive

ter

min

al o

f th

e ba

tter

y

nega

tive

ele

ctro

de :

the

ele

ctro

deco

nnec

ting

to

the

nega

tive

term

inal

of

the

batt

ery

com

pris

ed o

f m

obile

ions

Cond

ucti

ng o

f el

ectr

icit

y

mig

rati

on o

f th

e m

obile

ions

inth

e el

ectr

olyt

e

mig

rati

on o

f el

ectr

ons

in t

heco

nduc

ting

wir

e

Dec

ompo

siti

on o

fth

e el

ectr

olyt

e

disc

harg

e of

cat

ions

at t

he c

atho

de

e.g.

for

mat

ion

ofm

olte

n le

ad a

t ca

thod

e

disc

harg

e of

ani

ons

at t

he a

node

e.g.

for

mat

ion

ofbr

omin

e va

pour

at

anod

e

Elec

trol

ysis

of

aque

ous

elec

trol

yte

e.g.

copp

er(I

I)ch

lori

de s

olut

ion

com

pris

ed o

f m

obile

ions

sur

roun

ded

by w

ater

mol

ecul

es

Cond

ucti

ng o

f el

ectr

icit

ym

igra

tion

of

the

mob

ile io

ns in

wat

er

mig

rati

on o

f el

ectr

ons

in t

heco

nduc

ting

wir

e

Dec

ompo

siti

on o

fth

e el

ectr

olyt

e

disc

harg

e of

cat

ions

at t

he c

atho

de

e.g.

for

mat

ion

ofco

pper

met

al a

tca

thod

e

disc

harg

e of

ani

ons

at t

he a

node

e.g.

for

mat

ion

ofch

lori

ne g

as a

t an

ode

Colo

ur o

f io

nsus

ually

con

tain

ing

tran

siti

on m

etal

Mig

rati

on o

f io

nsm

igra

tion

of

ions

in g

el

mig

rati

on o

f io

ns o

n a

piec

e of

filt

er p

aper

moi

sten

ed w

ith

an a

queo

us e

lect

roly

te

Form

atio

n of

ioni

c bo

nd

tran

sfer

ring

of

elec

tron

fro

mm

etal

ato

ms

to n

on-m

etal

ato

ms

repr

esen

ted

by e

lect

ron

dot

and

cros

s di

agra

m (

elec

tron

dia

gram

)

Onl

y an

ove

r-si

mpl

ifie

d ex

plan

atio

n; t

heac

tual

exp

lana

tion

will

be

stud

ied

in F

orm

6

non-

dire

ctio

nal n

atur

e of

ioni

c bo

nd

Elec

tros

tati

c na

ture

of

the

stro

ng a

ttra

ctio

n am

ong

oppo

site

ly c

harg

ed io

ns

trill

ions

and

trill

ions

of

oppo

site

lych

arge

d io

nsjo

inin

g to

geth

er

Gia

nt io

nic

stru

ctur

e

Elec

tric

ally

neu

tral

Form

ula

ofio

nic

com

poun

d

ioni

c fo

rmul

a

show

ing

the

sim

ples

t w

hole

num

ber

rati

o of

ions

pre

sent

empi

rica

l for

mul

a

show

ing

the

sim

ples

t w

hole

num

ber

rati

o of

ato

ms

pres

ent

brac

ket

is u

sed

to e

nclo

seth

ose

poly

atom

ic io

n in

afo

rmul

a if

the

re is

mor

e th

anon

e po

lyat

omic

ion

of t

hesa

me

kind

Ions

Form

atio

n of

ions

met

al a

tom

s te

nd t

o lo

se e

lect

rons

to

get

a fu

lly f

illed

out

erm

ost

shel

l to

for

m c

atio

ns

Onl

y an

ove

r-si

mpl

ifie

d ex

plan

atio

n of

for

mat

ion

of io

ns;

the

actu

al e

xpla

nati

on w

ill b

e st

udie

d in

For

m 6

non-

met

al a

tom

s te

nd t

o ga

in e

lect

rons

to

get

a fu

lly f

illed

out

erm

ost

shel

l to

for

m a

nion

s

Form

ula

and

nam

ing

ofio

ns

Nam

e of

cat

ions

sim

ple

cati

on

Usu

ally

hav

e th

e sa

me

nam

e as

the

ato

m e

.g.

hydr

ogen

ion

For

thos

e at

oms

capa

ble

to f

orm

mul

tipl

e io

ns,

the

char

gew

ill b

e in

dica

ted

by a

rom

an n

umer

al e

.g.

copp

er(I

) io

n,co

pper

(II)

ion

poly

atom

ic c

atio

ne.

g. a

mm

oniu

m io

n

Nam

e of

anio

ns

sim

ple

anio

nen

d w

ith

-ide

e.g.

oxi

de io

n

poly

atom

icio

n

end

wit

h -i

dee.

g. h

ydro

xide

ion end

wit

h -i

te o

r -a

te

oxyg

en c

onta

inin

g po

lyat

omic

ion

-ite

, co

ntai

ns l

ess

oxyg

en

e.g.

sul

phit

e io

n, n

itri

te io

n

-ate

, co

ntai

n m

ore

oxyg

en

e.g.

sul

phat

e io

n, n

itra

te io

n

othe

rpr

efix

es

per-

: e

ven

mor

epe

rman

gana

te io

n

hypo

- :

even

less

hypo

chlo

rite

ion

di-

: tw

odi

chro

mat

e io

n

hydr

ogen

- :

hydr

ogen

ion

hydr

ogen

carb

onat

e io

n

thio

- :

repl

aced

an

Oat

om w

ith

a su

lphu

r at

omth

iosu

lpha

te io

n

Dif

fere

nce

betw

een

atom

and

ion

atom

s an

d io

ns s

how

tot

ally

diff

eren

t pr

oper

ties

e.g.

sod

ium

ver

sus

sodi

um c

hlor

ide

in w

ater

8. Io

nic

bond

ing.

mm

ap -

1/2/

2005

-

Page 9: F3 Mindmap

Cova

lent

bon

ding

Cova

lent

bon

d

Nat

ure

of c

oval

ent

bond

Stro

ng,

elec

tros

tati

c, d

irec

tion

al

Form

ed b

y sh

arin

g of

out

erm

ost

elec

tron

s,

i.e.

co-

mea

ns s

hari

ng,

-val

ent

mea

ns o

uter

mos

t sh

ell e

lect

rons

From

the

ele

ctro

stat

ic a

ttra

ctio

n be

twee

npo

siti

ve n

ucle

us-n

egat

ive

bond

ing

elec

tron

-pos

itiv

e nu

cleu

s

Elec

tron

diag

ram

of

cova

lent

mol

ecul

e

feat

ures

on

the

diag

ram

(fo

r th

eou

term

ost

elec

tron

s on

ly)

bond

ing

elec

tron

s

Each

pai

r is

know

n as

abo

nd p

air

1 bo

nd p

air

= si

ngle

bon

d2

bond

pai

rs =

dou

ble

bond

3 bo

nd p

airs

= t

ripl

e bo

nd

non-

bond

ing

elec

tron

s

Each

pai

r is

kno

wn

as a

lone

pair

Form

atio

n of

cova

lent

bon

d

Two

non-

met

al a

tom

s sh

are

the

oute

rmos

t el

ectr

ons

wit

hea

ch o

ther

to

atta

inco

mpl

etel

y fi

lled

oute

rmos

tsh

ell.

The

atom

s b

ecom

e st

able

.

Shar

ing

of e

ach

elec

tron

virt

ually

giv

esth

e at

om o

nem

ore

elec

tron

.

Gro

up 7

ato

ms

usua

lly s

hare

1 e

lect

ron;

For

m 1

bon

d

Gro

up 6

ato

ms

usua

lly s

hare

2 e

lect

rons

; Fo

rm 2

bon

ds

Gro

up 5

ato

ms

usua

lly s

hare

3 e

lect

rons

; Fo

rm 3

bon

ds

Gro

up 4

ato

ms

usua

lly s

hare

4 e

lect

rons

; Fo

rm 4

bon

ds

Gro

up 1

-3 a

tom

s do

not

for

m c

oval

ent

bond

at

all a

sth

ey a

re m

etal

ato

ms.

Gia

nt C

oval

ent

subs

tanc

e (S

ubst

ance

s in

whi

ch b

illio

ns a

ndbi

llion

s no

n-m

etal

ato

ms

are

join

ed t

oget

her

byco

vale

nt b

ond.

)Ex

ampl

es

Dia

mon

d (a

for

m o

f ca

rbon

elem

ent)

Billi

ons

and

billi

ons

of c

arbo

nat

oms

are

join

ed t

oget

her

tetr

ahed

rally

by

stro

ng C

-Csi

ngle

bon

d

Har

dest

sub

stan

ce in

the

wor

ld.

Silic

on(I

V) o

xide

, al

so k

now

nas

qua

rtz

Silic

on a

tom

s ar

e jo

ined

tetr

ahed

rally

thr

ough

oxy

gen

atom

s by

str

ong

Si-O

sin

gle

bond

Mol

ecul

ar s

ubst

ance

s(S

ubst

ance

s in

whi

chdi

scre

te (

sepa

rate

)m

olec

ules

are

fou

nd.)

Def

init

ion

of m

olec

ule

: th

e sm

alle

stpa

rtic

le t

hat

can

exis

ts o

n it

s ow

n. i.

e.th

e pa

rtic

les

foun

d in

non

-ele

ctro

lyte

Ion

cann

ot e

xist

on

its

own;

Posi

tive

ions

alw

ays

attr

act

nega

tive

ions

Prot

on c

anno

t ex

ist

on it

s ow

n,It

alw

ays

attr

acts

ele

ctro

ns

Met

allic

ato

ms

cann

ot e

xist

on

its

own,

bill

ions

of

met

alat

oms

are

stic

king

tog

ethe

r in

the

smal

lest

pos

sibl

e pi

ece

ofm

etal

.

Elem

ent

Def

init

ion

of a

tom

icit

y :

Num

ber

of a

tom

s in

a m

olec

ule

of a

n el

emen

t

Exam

ples

mon

oato

mic

(at

omic

ity

= 1)

: H

e, N

e, A

rdi

atom

ic (

atom

icit

y =2

) :

H2,

O2,

N2,

F2,

Cl2

, Br

2, I

2tr

iato

mic

(at

omic

ity

= 3)

: O

3te

traa

tom

ic (

atom

icit

y =

4) :

P4

octa

atom

ic (

atom

icit

y =

8) :

S8

Com

poun

dEx

ampl

es :

wat

er H

2O,

alco

hol C

2H6O

, gl

ucos

e C6

H12

O6

Form

ulae

use

d to

repr

esen

t m

olec

ular

subs

tanc

e

Empi

rica

l for

mul

a

Show

ing

the

sim

ples

t w

hole

num

ber

rati

o of

ato

ms

pres

ent

e.g.

CH

2O f

orgl

ucos

e

Mol

ecul

ar f

orm

ula

Show

ing

the

actu

al n

o. o

fat

oms

pres

ent

in a

mol

ecul

e e.

g. C

6H12

O6

for

gluc

ose

Stru

ctur

al f

orm

ula

Show

ing

the

orde

r of

conn

ecti

on o

f at

oms

in a

mol

ecul

e

Mod

els

used

to

repr

esen

tm

olec

ular

sub

stan

ce

Ball-

and-

stic

k m

odel

Skel

etal

ato

mic

mod

el

Spac

e-fi

lling

mod

el

Inte

rmol

ecul

ar f

orce

s(a

ttra

ctiv

e fo

rces

am

ong

the

mol

ecul

e)

Firs

t di

scov

ered

by

van

der

Waa

ls,

ther

efor

e it

is a

lso

know

n as

van

der

Waa

ls'

forc

es.

Muc

h w

eake

r th

an c

oval

ent

bond

, ab

out

10 t

imes

wea

ker.

The

stre

ngth

is d

epen

ding

on

the

mol

ecul

ar s

ize,

usu

ally

ala

rger

mol

ecul

e w

ill g

ive

ast

rong

van

der

Waa

ls' f

orce

.

9. C

oval

ent b

ondi

ng.m

map

- 12

/4/2

005

-

Page 10: F3 Mindmap

Structure andproperties of

materials

Structure - a description of the arrangement of particles in a substance.

Molecular structure(individual/discretemolecules can be found)

Simple molecular

e.g. H2O, NO2, S8, P4

under 100 atoms fat and oil - marginal cases, with just over 100 atoms

weaker intermolecularforces among molecules

usually gases, liquids or low melting solids

soft and weak

usually insoluble in water (a polarsolvent) but soluble in non-aqueoussolvent (non-polar solvent).

In general, LIKE (solvent)dissolves LIKE (solute)

Macromolecular

e.g. starch, protein, plastic

over thousands of atoms

stronger intermolecular forces as the strength ofvan der Waals' is depending on the molecular size

usually solid at roomtemperature

non-conducting

no delocalized electrons ormobile ions present.

Giant structure (trillionsof atoms/ions are joinedtogether by strong bonds(ionc, covalent ormetallic)

Giant ionic structure

strong ionic bond(non-directional in nature)

high m.p. and b.p.

All are solids at roomtemperature

hard

high density

brittle

slight dislocation bringsions of similar chargetogether repulsion cleaves the crystal

presence of ions

the ions are not free tomove in solid state only conducts in molten or aqueous state

If soluble, only soluble in aqueous solvent

In general, LIKE (solvent)dissolves LIKE (solute)

Giant covalent structure

e.g. diamond (C), quartz (SiO2), graphite (C)

strong covalent bond(directional in nature)

high m.p. and b.p.

All are solids at roomtemperature

hard

high density

usually non-conductor ofelectricity

bonding electrons in most covalentsubstances are not free to move

usually poor conductor ofheat (except diamond)

insoluble in any solvent

intermolecular forces are never strongerthan covalent bond

Special case : Graphite

brittle weak van der Waals' forces between layers

slipperyflat hexagonal layers

weak van der Waals' forces between layers

conducting

presence of delocalized electrons along thehexagonal layers

high melting, even higherthan diamond strong C-C bond, bond order 1.5

lower density thandiamond

large spacebetween layers

weak van der Waals' forcesbetween layers

Giant metallic structure

Electron sea model of metal

A lattice of positive metal ions is immersed in a sea ofdelocalized electrons which are contributed by the metalatoms from their outermost shell.

Metallic bond (non-directionalin nature)

Attraction between the positive ions - delocalized electrons -positive ions

usually very stronge.g. in Fe

high m.p. and b.p.

hard

high density

Except Hg, all metals are solidat room temperature.

Presence of sea of delocalized electronsmalleable and ductile

the metallic bond canreform at new position whenthe position of the ions arebeing shifted.

high conductivity of heat and electricity

Usually soluble in mercury

Mercury alloy is called amalgam. e.g. sodiumamalgam - a mixture of sodium and mercury

In general, LIKE (solvent)dissolves LIKE (solute)

10. Structures and properties.mmap - 5/5/2005 -

Page 11: F3 Mindmap

Occ

urre

nce

and

extr

acti

on o

f m

etal

Prop

erti

es a

ndU

sefu

lnes

s of

met

als

Fact

ors

to b

e co

nsid

ered

: a

vaila

bilit

y, p

rope

rtie

s an

d pr

ices

Iron

Pros

Chea

p, s

tron

g, m

agne

tic

Cons

Hea

vy,

Easi

ly c

orro

ded

Use

sCo

nstr

ucti

on,

Vehi

cle

Copp

er

Pros

Stro

ng,

Exce

llent

con

duct

or o

f he

at a

nd e

lect

rici

ty,

Corr

osio

n re

sist

ant,

duc

tile

, m

alle

able

Cons

Hea

vy,

Expe

nsiv

e co

mpa

ring

wit

h ir

on

Use

sEl

ectr

ical

wir

e, w

ater

pip

e, c

ooki

ng u

tens

il

Alum

iniu

m

Pros

Ligh

t, G

ood

cond

ucto

r of

ele

ctri

city

and

hea

t,no

n-po

ison

ous,

duc

tile

, m

alle

able

Cons

Expe

nsiv

e, N

ot a

s ha

rd a

s ir

on a

nd c

oppe

r, d

iffi

cult

to

sold

er

Use

s

Ove

rhea

d po

wer

cab

le,

airc

raft

, sa

ucep

an,

kitc

hen

foil,

sof

t dr

ink

can,

win

dow

fra

me

Tita

nium

Pros

Ligh

t, S

tron

g, C

orro

sion

to

resi

stan

t

Cons

Very

exp

ensi

ve

Use

sAi

rcra

ft

Gol

d

Pros

Attr

acti

ve a

ppea

ranc

e,

very

mal

leab

le,

Expe

nsiv

e,Re

frac

tive

, Re

sist

ant

to a

bras

ion

Cons

Expe

nsiv

e, T

oo s

oft

Use

sJe

wel

lery

, Co

ins,

Ele

ctri

cal c

onta

cts,

Shi

eld

for

heat

Mer

cury

Pros

Liqu

id a

t ro

om t

empe

ratu

re,

Not

sti

cky,

Exp

and

upon

heat

ing,

Dis

solv

e ot

her

met

al

Cons

Very

poi

sono

us

Use

sTh

erm

omet

er,

dent

al f

illin

g

Silv

er

Pros

Exce

llent

con

duct

or o

f he

at a

nd e

lect

rici

ty,

Corr

osio

nre

sist

ant,

Att

ract

ive

appe

aran

ce,

Shin

y, m

alle

able

and

duct

ile

Cons

Expe

nsiv

e

Use

sEl

ectr

ical

wir

ing,

Jew

elle

ry,

Coin

s

Cons

ervi

ng m

etal

s

Nee

d of

con

serv

atio

n

Met

al a

s a

non-

rene

wab

le r

esou

rce

Recy

clin

g sa

ve e

nerg

y an

d ot

her

reso

urce

s

Recy

clin

g he

lps

to r

educ

e po

lluti

on

Recy

clin

g pr

omot

es p

ublic

aw

aren

ess

of r

esou

rce

scar

city

Way

of

cons

ervi

ng

Reus

e m

etal

art

icle

s

Recy

clin

g us

ed m

etal

s

Repl

acin

g m

etal

s by

oth

er p

rodu

cts

Dis

cove

ry o

fm

etal

s

Ord

er o

f di

scov

ery

Less

rea

ctiv

e m

etal

fir

st,

follo

wed

by

the

mor

e re

acti

ve o

nes.

Som

e un

reac

tive

met

al e

xist

in f

ree

stat

e in

the

ear

th c

rust

. e.

g.Au

, Pt

Fact

ors

affe

ctin

g th

e av

aila

bilit

y of

met

als

Abun

danc

e of

met

als

in e

arth

cru

st

Ease

of

min

ing

of t

he o

re

Ease

of

extr

acti

on o

f m

etal

Extr

acti

on o

fm

etal

s fr

omm

etal

ore

s

Som

e M

etal

Ore

s

Baux

ite

cont

ains

Al2

O3 Co

pper

pyr

ite

cont

ains

CuF

eS2

Hae

mat

ite

cont

ains

Fe2

O3

Gal

ena

cont

ains

PbS

Met

als

in f

ree

stat

ese.

g. A

u, P

t

Extr

acti

on o

f m

etal

sfr

om m

etal

ore

s

By h

eati

ng a

lone

e.g.

Hg,

Ag

By h

eati

ng w

ith

carb

on

Sulp

hide

or

carb

onat

e or

es a

re h

eate

dst

rong

ly in

air

to

conv

ert

to o

xide

fir

st

The

oxid

e of

met

al is

heat

ed w

ith

carb

on t

o ge

tre

duce

d to

met

al

Ope

rati

on o

fbl

ast

furn

ace

e.g.

Zn,

Fe,

Pb,

Cu

By e

lect

roly

sis

of m

olte

n or

e

only

wor

ks in

the

abs

ence

of

wat

er

e.g.

K,

Na,

Ca,

Mg,

Al

Ord

er o

f di

ffic

ulti

es in

extr

acti

on

K, N

a, C

a, M

g, A

l, Z

n, F

e, P

b,Cu

, H

g, A

g, A

u

Exam

ples

of

wor

deq

uati

ons

Gen

eric

Wor

d Eq

uati

on

Spec

ific

Wor

d Eq

uati

on

11. O

ccur

renc

e an

d ex

tract

ion

of m

etal

.mm

ap -

19/5

/200

5 -

Page 12: F3 Mindmap

Reac

tivi

ty o

fm

etal

s

Reac

tivi

ties

of

diff

eren

t m

etal

s

Reac

tivi

ty :

the

read

ines

s to

rea

ctCo

mpa

re t

he t

emp.

nee

ded

to s

tart

the

rea

ctio

nCo

mpa

re t

he r

ate

(spe

ed)

of r

eact

ion

Com

pare

the

am

ount

of

heat

giv

en o

ut in

the

rea

ctio

n

Ord

er o

fre

acti

vity

(rea

ctiv

ity

seri

es)

K, N

a, C

a, M

g, A

l, Z

n, F

e, P

b, C

u, H

g, A

g, A

u

Reac

tion

wit

h ai

rst

orag

e of

met

als

Reac

tion

wit

hw

ater

Reac

tion

wit

h liq

uid

wat

erRe

acti

on w

ith

stea

mRe

acti

on w

ith

dilu

te a

cid

Expl

anat

ion

for

reac

tivi

ty o

fm

etal

s

Met

als

reac

t by

losi

ng e

lect

ron

Read

ines

s to

lose

the

oute

rmos

tel

ectr

ons

Reac

tivi

tyin

crea

ses

dow

n a

grou

p

The

larg

er t

hem

etal

ato

m,

the

wea

ker

the

attr

acti

onbe

twee

n th

eou

term

ost

elec

tron

s an

dth

e nu

cleu

s.

Reac

tivi

tyde

crea

ses

acro

ss a

peri

od

Wit

h th

e sa

me

no.

of e

lect

ron

shel

l, t

he la

rger

no.

of p

roto

ns a

tth

e nu

cleu

sat

trac

ts t

heou

term

ost

elec

tron

s m

ore

stro

ngly

.

App

licat

ion

of reac

tivi

tyse

ries

of

met

als

Extr

acti

onof

met

als

from

the

iror

e

Redu

ctio

n of

met

al o

xide

(Rem

oval

of

oxyg

en f

rom

met

al o

xide

)Ac

tion

of

heat

on

met

al o

xide

sRe

duct

ion

wit

h m

etal

sRe

duct

ion

wit

h ca

rbon

Dis

plac

emen

tre

acti

ons

ofm

etal

inaq

ueou

sso

luti

on

A m

ore

reac

tive

met

al is

cap

able

to

disp

lace

a le

ss r

eact

ive

met

al f

rom

aso

luti

on o

f th

e sa

lt o

f th

e le

ss r

eact

ive

met

al.

Chem

ical

equa

tion

s

Role

of

aneq

uati

on

All e

quat

ions

are

use

d to

rep

rese

nt r

eact

ions

acc

urat

ely.

Lim

itat

ion

of e

quat

ion

Doe

sn't

tell

the

cond

itio

n ne

eded

to

star

t th

e re

acti

onD

oesn

't te

ll ho

w f

ast

and

how

vig

orou

s th

e re

acti

on is

.

Gen

eric

wor

d eq

uati

on

Spec

ific

wor

d eq

uati

on

Unb

alan

ced

equa

tion

Phys

ical

sta

tes

of d

iffe

rent

spe

cies

: (

s),

(l),

(g)

and

(aq

) Bala

nced

equ

atio

n

Stoi

chio

met

ric

coef

fici

ents

No

new

sub

stan

ce s

houl

d be

intr

oduc

ed in

bal

anci

ng a

rea

ctio

n

Ioni

c eq

uati

on

Ioni

c eq

uati

on =

Ba

lanc

ed e

quat

ion

- sp

ecta

tor

ions

Spec

tato

r io

ns :

tho

se io

ns w

hich

are

neit

her

phys

ical

ly n

or c

hem

ical

ly c

hang

ed.

Bala

nced

equ

atio

n

Ioni

c eq

uati

on

Spec

tato

r io

ns

12. R

eact

ivity

of m

etal

s.m

map

- 22

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005

-