fallout remover (industrial strength) - car kem · section 6 - accidental release measures wear...

of 7Fallout Remover (Industrial Strength)

SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS

3.1 SubstancesNot applicable

3.2 MixturesChemical characterization (preparation)

2.2 Label Elements

Hazard Symbol(s):

Acute Toxicity, Oral - Category 5 [H303]

2.1 Classification of substance or mixture

Classification (Regulation (EC) No 1272/2008)

Labeling (Regulation (EC) No 1272/2008)

Skin Corrosion - Category 1C [H314]

Product definition: Mixture

% by Weight CAS Number EC Number EC ClassificationIngredient Index Number<15 Ethanedioic Acid 144-62-7 205-634-3 607-006-00-8 Xn, R21/22

SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION

Product Name: Fallout Remover (Industrial Strength)

+1-407-323-5626; +1-800-423-3168 (toll free)

General Use:

SECTION 2 - HAZARDS IDENTIFICATION

Car Kem Products, Inc.Manufacturer/Distributor

4275 St. Johns ParkwaySanford, FL 32771 USA

Used for the removal of acid rain deposits, hard water spots, dried soap, rail rust, etc.

Synonyms: Aqueous acidic mixtureProduct Codes(s): FO-1, FO-5, FO-55

1.2 Relevant identified uses of the substance or mixture and uses advised against

1.1 Product identifier

1.3 Details of the supplier and of the safety data sheet

1.4 Emergency telephone number: +1-800-424-9300 CHEMTREC

REACH Registration Number: No data available at this time.

Specializing in Professional

Uses advised against: None known

Automotive/Marine Appearance andReconditioning Products

CAR KEM PRODUCTS, INC.

GHS05

SAFETY DATA SHEETFallout Remover

(Industrial Strength)

<6 2-Butoxyethanol 111-76-2 203-905-0 603-014-00-0 Xn, R22<4 Nonylphenol, Ethoxylate 265-200-49016-45-9 ------------ ------------

Signal Word:Hazard Statement(s):

[Prevention]

[Response]

Precautionary Statements:

Danger

P264 - Wash hands and other skin areas exposed to material thoroughly after handling.P280 - Wear protective gloves, protective clothing eye protection and face protection.

[Disposal] P501 - Dispose of contents in accordance with national and local regulations.

P312 - Call a POISON CENTER or doctor if you feel unwell.

H303 - May be harmful if swallowed

P260 - Do not breathe mist or spray.

P301 + P330 + P331 + P310 - IF SWALLOWED: Rinse mouth. Do not induce vomiting. Immediately call a

P303 + P361 + P353 - IF ON SKIN: Remove immediately all contaminated clothing. Rinse skin with water or shower.

P304 + 340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing.

[Storage] P405 - Store locked up.

H314 - Causes severe skin burns and eye damage

P321 - Specific treatment: Refer to Section 4 of this SDS. Contact a POISON CENTER or doctor.

POISON CENTER or doctor.

SECTION 6 - ACCIDENTAL RELEASE MEASURES

Wear appropriate protective clothing designated in Section 8. Ventilate the area.

5.3 Advice for firefightersFull protective equipment including self-contained breathing apparatus should be used. Water may be used to cool closed containers to preventpressure build-up and possible autoignition or explosion when exposed to extreme heat. If possible, firefighters should control runoff water toprevent environmental contamination.

SECTION 5 - FIRE FIGHTING MEASURES

Suitable methods of extinction: Use extinguishing media suitable for surrounding fire.

5.2 Special hazards arising from the substance or mixture

5.1 Extinguishable media

Unsuitable methods of extinction: None known

6.1 Personal precautions, protective equipment and emergency procedures

6.2 Environmental precautions

6.3 Methods and materials for containment and cleaning up

6.4 Reference to other sections

Avoid dispersal of spilled material or run-off and prevent contact with soil and entry into drains, sewers or waterways.

For indications about waste treatment, see Section 13.

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SECTION 7 - HANDLING AND STORAGE

decomposition products may cause a health hazard. Symptoms may not be immediately apparent or may be delayed. Obtain medical attention.Closed containers may explode due to the build-up of pressure when exposed to extreme heat. During emergency conditions overexposure to

SECTION 4 - FIRST AID MEASURES


4.2 Most important symptoms and effects, both acute and delayed

Eyes:

Ingestion:

Causes severe skin irritation and burns. Symptoms include redness, itching, discomfort and scaling, drying and cracking of skin.Skin:

Potential health symptoms and effectsCauses severe eye irritation and burns. Mist or spray can cause severe eye irritation and burns. Symptoms include redness, itching, pain,

Inhalation: Inhalation of mist or spray may cause irritation of the upper respiratory tract with headache, runny nose, coughing and nausea.

.

If product mist or spray causes respiratory irritation or distress, move the exposed person to fresh air immediately. If breathing is

tight fitting clothing such as a collar, tie, belt or waistband. If symptoms persist, seek medical attention immediately. difficult or irregular, administer oxygen; if respiratory arrest occurs, start artificial respiration by trained personnel. Get medical attention. Loosen

Inhalation:4.1 Description of first aid measures

Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting, abdominal pain and diarrhea. Ethanedioic Acid can

Ingestion: Rinse mouth with water if victim is conscious. Remove dentures, if present. If victim is conscious and alert, give 2 - 3 cupfuls of milk orwater to drink. Do not induce vomiting unless directed to do so by medical personnel. Do not leave victim unattended. To prevent aspiration ofswallowed product, lay victim on one side with the head lower than the waist. If vomiting occurs and the victim is conscious, give water to further dilute material. Never give anything by mouth to an unconscious person. Immediately call a POISON CENTER or doctor.

Pre-existing disorders of the skin and respiratory system may be aggravated by exposure to this product. Chronic skin exposure may Chronic:

Eyes: Immediately flush eyes with large amounts of water for 15 minutes, occasionally lifting upper and lower lids. Remove contact lenses, if .present and easy to do, after the first 2 minutes and continue rinsing. Obtain immediate medical attention, preferably from an ophthalmologist.

Skin: Flush skin with large amounts of water while removing contaminated clothing. Wash affected area with soap and water. Wash contaminated clothing and shoes thoroughly before reuse. Seek prompt medical attention if irritation persists or if you feel unwell.

sweep up product and place into approved container for proper disposal. Clean contaminated area using a detergent/soap solution or anotherbiodegradable cleaner and water. Do not rinse spilled product down the drain.

Cover drains and contain spill. Cover with a large quantity of inert absorbent. Do not use combustible materials such as saw dust. Shovel or

7.1 Precautions for safe handlingAvoid contact with eyes, skin and clothing. Wear all appropriate personal protective equipment specified in Section 8. If normal use presents arespiratory hazard, use only adequate ventilation or wear an appropriate respirator.

Fallout Remover (Industrial Strength)

There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classifiedas hazardous to the health or the environment and hence require reporting in this section.

swelling and tearing. May cause conjunctivitis and corneal injury.

be toxic when ingested due to its acidic and chelating properties. Ulcerations of the mouth, bloody vomitus and rapid appearance of shock, convulsions, twitching, tetany and cardiovascular collapse may occur.

spray may cause ulceration of the mucous membranes, weight loss, weakness and inflammation of the respiratory system. Ingestion of Ethanedioic Acid solutions can cause the formation of calcium oxalate, which may precipitate in the kidney tubules and the brain. Hypocalcemia may also occur. Repeated and prolonged exposure to mist or spray may produce chronic eye irritation. 2-Butoxyethanol is a known animal carcinogen. Refer to Section 11.2.

result in tissue destruction, dermatitis and lesions characterized by cracking of the skin and slow healing ulcers. Chronic inhalation of mist or

4.3 Indication of any immediate medical attention and special treatment neededAdvice to Doctor and Hospital PersonnelTreat supportively and symptomatically. Intravenous administration of calcium gluconate or calcium chloride may be required if hypocalcemia orhypocalcemic tetany occurs.

Environmental exposure controls: Do not empty into drains.

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

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9.2 Other dataNo data available

9.1 Information on basic physical and chemical propertiesAppearance Clear, green liquidOdor AcidicOdor Threshold Not determinedMolecular Weight Not applicableChemical Formula Not applicablepHFreezing/Melting PointInitial Boiling Point

<0 °C (<32 °F)100 °C (212 °F)

Evaporation Rate <1 (Ethyl Ether = 1)Flammability (solid, gas) Not applicableFlash Point Non-flammableAutoignition Temperature Not applicableDecomposition Temperature Not determinedLower Explosive Limit (LEL) Not applicableUpper Explosive Limit (UEL) Not applicableVapor Pressure Not determinedVapor Density >1 (Air = 1)Specific GravityViscosity Not determinedSolubility in Water CompletePartition Coefficient: n-octanol/water Not determined Volatiles by Volume @ 70 ºF

1.00

>80%

1.8 - 2.2

Engineering Measures: Technical measures and appropriate working operations should be given priority over the use of personal protective 8.2 Exposure controls

equipment. Use adequate ventilation. Local exhaust is preferable. Refer to Section 7.1.

Individual protection measures: Wear protective clothing to prevent repeated or prolonged contact with product. Protective clothing needs to be

Other protective equipment:

selected specifically for the workplace, depending on concentrations and quantities of hazardous substances handled. The chemical resistanceof the protective equipment should be enquired at the representative supplier.

clothing. Preventive skin protection is recommended. Wash hands thoroughly after use, before eating, drinking or using the lavatory. Facilities storing or using this material should be equipped with an eyewash station and safety shower. Change contaminated

Wear protective goggles or safety glasses with unperforated side shields during use. Refer to 29 CFR 1910.133, ANSI Z87.1or European Standard EN 166.

Eye/face protection:

Hygiene measures:

Hand Protection: Wear rubber gloves or gloves recommended by glove supplier for protection against materials in Section 3. Gloves should beimpermeable to chemicals and oil. Breakthrough time of selected gloves must be greater than the intended use period.

Protective clothing. Protective boots, if the situation requires.


Respiratory Protection:assessment shows air-purifying respirators are appropriate use a full-faced respirator with multi-purpose combination (US) or type ABEK

None required with normal use. Always use an approved respirator when vapor/aerosols are generated. Where risk

(EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied airrespirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Control parametersACGIH TLVOSHA PEL - TWACAS Number Ingredient NIOSH

111-76-2 2-Butoxyethanol 50 ppm; 240 mg/m3 700 ppm50 ppm TWA; 100 mg/m3 ceiling (aerosol only)

144-62-7 1 mg/m3 1 mg/m3 TWA;1 mg/m3 TWA; 2 mg/m3, STEL


Ethanedioic Acid

500 mg/m3 IDHL

Apart from the uses mentioned in Section 1.2, no other specific uses are stipulated.7.3 Specific end uses

7.2 Conditions for safe storage, including any incompatibilitiesStore in a dry, cool and well-ventilated area, away from incompatible materials, food and drink. Keep from freezing. Transfer only to approvedcontainers having correct labeling. Protect containers against physical damage. Keep containers tightly closed when not in use. Containers thathave been opened must be carefully resealed and kept upright to prevent leakage. Do not reuse empty containers as they may retain product residues. Ventilate closed areas. Do not take internally. Keep out of reach of children.

Advice on protection against fire and explosionNone known

SECTION 12 - ECOLOGICAL INFORMATION

Aspiration hazardNo data available

Handle in accordance with good industrial hygiene and safety practice.

12.1 Toxicity

11.2 Further information

Product is biodegradable.12.2 Persistence and degradability

12.3 Bioaccumulation potential

12.4 Mobility

12.5 Results of PBT and vPvB assessmentNo data available

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Chronic Effects:Carcinogen - Confirmed animal carcinogen with unknown relevance to humans. Not listed as a carcinogen by NTP or OSHA.

2-Butoxyethanol (CAS #111-76-2): IARC, Group 3 carcinogen - Not classifiable as to its carcinogenicity to humans. ACGIH, A3

developmental or fertility effects.

Product contains 2-Butoxyethanol, which is harmful to algae or higher aquatic plants.

Expected to have low acute inhalation toxicity.Acute inhalation toxicity

No data availableMutagenicity

No data availableSpecific organ toxicity - single exposure

Expected to have low acute dermal toxicity.Acute dermal toxicity

No data availableSensitization

Eye irritationCauses severe skin irritation and burns.

Causes severe eye irritation, burns and possible eye damage.

Skin irritation

Genotoxicity in vitroNo data available

No data availableSpecific organ toxicity - repeated exposure


Ethanedioic Acid is slightly toxic to aquatic organisms on an acute basis. Large discharges to the environment may decrease the pH of aquatic systems to a pH <2, which may be fatal to aquatic life and soil micro-organisms.

SECTION 11 - TOXICOLOGICAL INFORMATION

Acute Oral ToxicityLD50, rat: 3,534 mg.kg (calculated)

11.1 Information on toxicological effects

Thermal decomposition products include oxides of carbon, formic acid.

10.5 Incompatible materials

10.6 Hazardous decomposition products

Strong oxidizing agents, strong alkalis, bases, hypochlorite, chlorides


Nonylphenol is a toxic breakdown product of nonylphenol, ethoxylates.

No data is available regarding the mutagenicity or teratogenicity of this product, nor is there any available data that indicates that it causes adverse

SECTION 10 - STABILITY AND REACTIVITY

Stable under recommended storage conditions.

10.1 ReactivityNo special reactivity has been reported.

10.2 Chemical stability

Hazardous polymerization will not occur.

Extreme temperatures. Contact with incompatible materials.10.4 Conditions to avoid

None known10.3 Possibility of hazardous reactions

Nonylphenol, ethoxylate has the potential to bioaccumulate. n-Octanol/water partition coefficient (log Pow) is ~4.48.

Nonylphenol, ethoxylate absorbs to soil and has low mobility. The remaining components are water soluble and highly mobile in soil.

12.6 Other adverse effectsAdditional ecological information

SECTION 13 - DISPOSAL CONSIDERATIONS

The generation of waste should be avoided or minimized whenever possible. Empty containers or liners may retain some

licensed waste disposal contractor. Disposal of this product, solutions and any by-products should at all times comply with the requirements ofenvironmental protection and waste disposal legislation and any regional local authority requirements. Avoid dispersal of spilt material and runoff

13.1 Waste treatment methods

product residues. This material and its container must be disposed of in a safe way. Dispose of surplus and non-recyclable products via aMethods of disposal:

and contact with soil, waterways, drains and sewers.

Do not allow material to run into surface waters, wastewater or soil.An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.

The classification of this product may meet the criteria for a hazardous waste.Hazardous waste:

SECTION 14 - TRANSPORT INFORMATION

Note: Transportation information provided is for reference only. Customer is urged to consult 49 CFR 100 - 177, IMDG, IATA, EC, United NationsTDG and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes, packaging materialsand methods of shipping.

RID/ADR (Rail Transportation)Proper Shipping Name: Hazard Class: 8

Packing Group: III3265UN/NA:

Corrosive liquid, acidic, organic, n.o.s., (Ethanedioic Acid)

Proper Shipping Name: Corrosive liquid, acidic, organic, n.o.s., (Ethanedioic Acid)Hazard Class: 8


IMO/IMDG (Water Transportation)

EMS Number: F-S, S-B

ICAAO/IATA (Air Transportation)

Proper Shipping Name: Hazard Class: 8


Proper Shipping Name: Hazard Class: 8




Marine Pollutant: No

US DOT (Domestic Ground Transportation)

NAERG: Guide #153Packaging Authorization: Non-Bulk: 49 CFR 173.203; Bulk: 173.241Packaging Exceptions: 49 CFR 173.154

Quantity Limitations: 49 CFR 173.27 and 175.75 - Cargo Aircraft Only: 60 l Passenger Aircraft: 5 l

Nonylphenol, Ethoxylate is a marine pollutant. Product may be harmful to the environment if released in large quantities.

of 7CAR KEM PRODUCTS, INC.Fallout Remover (Industrial Strength)

SARA 313 Information: 2-Butoxyethanol (CAS #111-76-2) is subject to the reporting levels established by Section 313 of the EmergencyPlanning and Community Right-to Know Act of 1986.

Superfund Amendments and Reauthorization Act (SARA)

SARA 302/304 Extremely Hazardous SubstanceNo components of the product exceed the threshold (de minimis) reporting levels established by of these sections of Title III of SARA.

SARA 302/304 Emergency Planning & NotificationNo components of the product exceed the threshold (de minimis) reporting levels established by of these sections of Title III of SARA.

OSHA Process Safety Management Standard: Components of this product are not regulated under OSHA PSM Standard 29 CFR 1910.119.EPA Risk Management Planning Standard: Components of this product are not regulated under EPA RMP Standard (RMP) 40 CFR Part 68.

SARA Section 311/312 Hazard Categories: Acute Health Hazard, Chronic Health Hazard

This product does not contain any chemicals that are listed as Hazardous Air Pollutants (HAPs) designated in CAA Section 112 (b). Clean Air Act (CAA)

This product does not contain any Class 1 Ozone depletors. This product does not contain any Class 2 Ozone depletors.

Comprehensive Response Compensation and Liability Act (CERCLA): This product contains no CERCLA reportable substances:

SECTION 15 - REGULATORY INFORMATION

U. S. Federal Regulations

OSHA Hazard Communication Standard:

15.1 Safety, health and environmental regulations/legislation specific for substance or mixture

This material is classified as hazardous in accordance with OSHA 29 CFR 1910-1200.

TSCA Status: All components of this product are listed on the Toxic Substance Control Act (TSCA) Inventory. Ethanedioic Acid (CAS #144-62-7) is subject to TSCA 12(b) Export Notification.

Clean Water Act (CWA)

None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.

U.S. State Regulations

California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986

Other U.S. State Inventories

This product contains no chemical(s) known to the State of California to cause cancer or other reproductive harm.

CanadaWHMIS Hazard Symbol and Classification:

Canadian Ingredient Disclosure List (IDL):

European Economic Community

2-Butoxyethanol and Nonylphenol, Ethoxylate are listed on the NPRI.Canadian National Pollutant Release Inventory (NPRI):

1WGK, Germany (Water danger/protection):

Canadian Controlled Products Regulations (CPR):Products Regulations, and the SDS contains all the information required by the Controlled Products Regulations.

This product has been classified in accordance with the hazard criteria of the Controlled

Ethanedioic Acid (CAS #144-62-7) and 2-Butoxyethanol (CAS #111-76-2) are listed on the IDL.

2-Butoxyethanol (CAS #111-76-2) is listed on the following State Hazardous Substance Inventories, Right-to-Know lists and/or Air Quality/Air Pollutants lists: CA, ID, MA, MN, NJ, PA, WA, WI.

Labeling (67/548/EEC or 1999/45/EC)


Ethanedioic Acid (CAS #144-62-7) is listed on the following State Hazardous Substance Inventories, Right-to-Know lists and/or Air Quality/AirPollutants lists: CA, ID, ME, MA, NJ, PA, WA, WI.

None of the chemicals in this product are listed as Hazardous Substances under the CWA.


Risk Phrases: R34 - Causes burns.

Safety Phrases: S1/2 - Keep locked up and out of the reach of children.

S36/37/39 - Wear suitable protective clothing, gloves, eye protection and face protection.

S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S28 - After contact with skin, wash immediately with plenty of water.

S24/25 - Avoid contact with skin and eyes.

C- Corrosive

S27 - Take off immediately all contaminated clothing.

SECTION 16 - OTHER INFORMATION

15.2 Chemical safety assessmentFor this product a chemical safety assessment was not carried out.

Health

Flammability

Instability

Special

2 0

National Fire Protection Association (NFPA)

HMIS & NFPA Hazard Rating Legend

4 = EXTREME

* = Chronic Health Hazard0 = INSIGNIFICANT1 = SLIGHT

2 = MODERATE3 = HIGH

Hazardous Material Information System (HMIS)

Health

Flammability

Physical Hazard

Personal Protection

0

C

00

* 2

Canada: Domestic Substance List (DSL).

Global Chemical Inventory Lists

YesCountry Inventory Name Inventory Listing*

Canada: Non-Domestic Substance List (NDSL). NoEurope: Inventory of New and Existing Chemicals (EINECS)United States: Toxic Substance Control Act (TSCA)Australia: Australian Inventory of Chemical Substances (AICS)New Zealand: New Zealand Inventory of Chemicals (NZIoC)

YesYesYesYes

China: Inventory of Existing Chemical Substances in China (IECSC)Japan: Inventory of Existing and New Chemical Substances (ENCS)Korea: Existing Chemicals List (ECL)Philippines: Philippines Inventory of Chemicals and Chemical Substances (PICCS)

YesYesYesYes

*"Yes" indicates that all components of this product are in compliance with the inventory requirements administered by the governing country.*"No" indicates that one or more components of this product are not on the inventory and are not exempt from listing.

*Full Text of Risk (R) – Phrases Referenced in Section 3.

R21/22 - Harmful in contact with skin and if swallowed.

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Toxic material causing other toxic effectsD2A - Severe eye irritation/burns - Severe skin irritation/burns - E - Corrosive material - necrosis of human skin

of the user to determine the suitability of this information for the adoption of the safety precautions as may be necessary. It is the responsibility of the user to comply with all Federal,

The information herein is given in good faith and is believed to be accurate and correct; however, no warranty, expressed or implied, is made. Car Kem Products, Inc. assumes noresponsibility for personal injury or property damage that may arise from the use of this material since the conditions of handling and use are beyond our control. It is the responsibility

Version 2: Change to GHS SDS formatPreparation date: 22 May 2014

Data Sheets from time to time as new technical information becomes available. The user has the responsibility to contact the company to make sure that the Safety Data Sheet is the latest issue.

State and local laws and regulations regarding use of this product. Vendees or users assume all risks associated with the use of this material. We reserve the right to revise Safety

CAR KEM PRODUCTS, INC.Fallout Remover (Industrial Strength) of 7

fallout remover (industrial strength) - car kem · section 6 - accidental release measures wear...

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