fcc
TRANSCRIPT
Fluid Catalytic CrackingFluid Catalytic Cracking(FCC)(FCC)
Quak Foo, LeeQuak Foo, LeeChemical and Biological Chemical and Biological
EngineeringEngineeringThe University of British ColumbiaThe University of British Columbia
OutlineOutline What is FCC?What is FCC? Why use circulating Fluidized Bed Why use circulating Fluidized Bed
Reactor in FCC?Reactor in FCC? Operating CharacteristicsOperating Characteristics Description of the ProcessDescription of the Process Heat BalanceHeat Balance Pressure BalancePressure Balance ConclusionsConclusions
What is FCC?What is FCC? Primary conversion process in petroleum Primary conversion process in petroleum
refinery.refinery. The unit which utilizes a micro-The unit which utilizes a micro-
spherodial catalyst (zeolitic catalyst) spherodial catalyst (zeolitic catalyst) which fluidizes when properly aerated.which fluidizes when properly aerated.
The purpose is to convert high-boiling The purpose is to convert high-boiling petroleum fractions (gas oil) to high-petroleum fractions (gas oil) to high-value, high-octane gasoline and heating value, high-octane gasoline and heating oil.oil.
Why use Circulating Why use Circulating Fluidized Bed in FCC?Fluidized Bed in FCC?
Compared with Fixed Bed, Fluidized BedCompared with Fixed Bed, Fluidized Bed CFB – fast fluidization regimeCFB – fast fluidization regime CFB good for catalyst size < 0.2 mmCFB good for catalyst size < 0.2 mm Excellent in:Excellent in:
– Gas-solid effective contactGas-solid effective contact– Catalyst effectivenessCatalyst effectiveness– Catalyst internal temperature controlCatalyst internal temperature control– Catalyst regenerationCatalyst regeneration
Operating CharacteristicsOperating Characteristics
Particle Diameter = 150 Particle Diameter = 150 mm Geldart Classification = AGeldart Classification = A Temperature = 650 Temperature = 650 00CC Pressure = 100 kPaPressure = 100 kPa Superficial gas velocity = 10 m/sSuperficial gas velocity = 10 m/s Bed depth = 0.85 mBed depth = 0.85 m Fresh feed flow rate = 300,000 kg/hrFresh feed flow rate = 300,000 kg/hr Catalyst to oil ratio = 4.8Catalyst to oil ratio = 4.8
FCC Reactor-RegeneratorFCC Reactor-Regenerator
Description of the ProcessDescription of the Process ReactorReactor RiserRiser CyclonesCyclones StripperStripper RegeneratorRegenerator Standpipe and Slide ValveStandpipe and Slide Valve
Reactor PerformanceReactor Performance
Feed oil enters the riser near the base Feed oil enters the riser near the base Contacts the incoming regenerated catalystContacts the incoming regenerated catalyst Cracking reactions occur in the vapor Cracking reactions occur in the vapor
phase phase Expanded volume of vapors lift the catalyst Expanded volume of vapors lift the catalyst
and vaporized oil risesand vaporized oil rises Fast reaction, few seconds of contact timeFast reaction, few seconds of contact time
RiserRiser DimensionsDimensions
– Diameter: 1.2 m (4 ft)Diameter: 1.2 m (4 ft)– Height : 36.6 m (120 ft)Height : 36.6 m (120 ft)
Plug flow with minimum back-mixingPlug flow with minimum back-mixing Steam is used to atomize the feedSteam is used to atomize the feed
– Increases the availability of feedIncreases the availability of feed Outlet vapor velocity: 18 m/s (60 ft/sec)Outlet vapor velocity: 18 m/s (60 ft/sec) Hydrocarbon residence time: 2 secondsHydrocarbon residence time: 2 seconds
CyclonesCyclones Located at the end of riser to separate Located at the end of riser to separate
the bulk of the catalyst from the vaporthe bulk of the catalyst from the vapor Use a deflector device to turn catalyst Use a deflector device to turn catalyst
direction downwarddirection downward Two-stage cyclonesTwo-stage cyclones
– To separate the remaining of the catalyst To separate the remaining of the catalyst Return the catalyst to the stripper Return the catalyst to the stripper
through the diplegsthrough the diplegs The product vapors exit the cyclones The product vapors exit the cyclones
and flow to the main fractionator columnand flow to the main fractionator column
CyclonesCyclones
Riser
Stripping Bed
Stripping SectionStripping Section The spent catalysts falls into the stripperThe spent catalysts falls into the stripper Valuable hydrocarbons are absorbed Valuable hydrocarbons are absorbed
within the catalyst bedwithin the catalyst bed Stripping steam, at a rate of 4 kg per Stripping steam, at a rate of 4 kg per
1000 kg of circulating catalyst, is used to 1000 kg of circulating catalyst, is used to strip the hydrocarbons from the catalyststrip the hydrocarbons from the catalyst
The catalyst level provides the pressure The catalyst level provides the pressure head which allows the catalyst to flow head which allows the catalyst to flow into the regeneratorinto the regenerator
Inside Stripping SectionInside Stripping Section
Steam
Reactor Stripper
Catalyst Level
Reactor Riser
RegeneratorRegenerator Two functions:Two functions:
– Restores catalyst activity Restores catalyst activity – Supplies heat to crack the feedSupplies heat to crack the feed
Air is the source of oxygen for the combustion Air is the source of oxygen for the combustion of cokeof coke
The air blower with 1m/s (3 ft/s) air velocity to The air blower with 1m/s (3 ft/s) air velocity to maintain the catalyst bed in a fluidized statemaintain the catalyst bed in a fluidized state
14 kPa (2 psi) pressure drop in air distributors 14 kPa (2 psi) pressure drop in air distributors to ensure positive air flow through all nozzlesto ensure positive air flow through all nozzles
Inside RegeneratorInside Regenerator
Catalyst (low carbon)
Catalyst (high carbon)
High Oxygen
Low Oxygen
Dense Phase Bed
Cat
alys
t
A
ir
Standpipe & Slide ValveStandpipe & Slide Valve Standpipe provides the necessary Standpipe provides the necessary
pressure head needed to circulate the pressure head needed to circulate the catalyst around the unitcatalyst around the unit
The catalyst density in standpipe is 642 The catalyst density in standpipe is 642 kg/mkg/m33 (40 lbs/ft (40 lbs/ft33))
Slide valve is used to regulate the flow Slide valve is used to regulate the flow rate of the regenerated catalyst to the rate of the regenerated catalyst to the riserriser
Slide valve function is to supply enough Slide valve function is to supply enough catalyst to heat the feed and achieve the catalyst to heat the feed and achieve the desired reactor temperaturedesired reactor temperature
Heat BalanceHeat Balance A catalyst cracker continually adjusts A catalyst cracker continually adjusts
itself to stay in heat balance.itself to stay in heat balance. The reactor and regenerator heat The reactor and regenerator heat
flows must be equal.flows must be equal. Heat balance performed around Heat balance performed around
– the reactorthe reactor– the stripper-regeneratorthe stripper-regenerator
Use to calculate catalyst circulation rate and Use to calculate catalyst circulation rate and catalyst-to-oil ratiocatalyst-to-oil ratio
– overall heat balanceoverall heat balance
Heat BalanceHeat Balance The unit produces and burns enough coke to provide The unit produces and burns enough coke to provide
energy to:energy to:– Increase the temperature of the fresh feed, recycle, and Increase the temperature of the fresh feed, recycle, and
atomizing steam from their preheated states to the reactor atomizing steam from their preheated states to the reactor temperature.temperature.
– Provide the endothermic heat of cracking.Provide the endothermic heat of cracking.– Increase the temperature of the combustion air from the Increase the temperature of the combustion air from the
blower discharge temperature to the regenerator flue gas blower discharge temperature to the regenerator flue gas temperature.temperature.
– Make up for heat losses from the reactor and regenerator Make up for heat losses from the reactor and regenerator to surroundings.to surroundings.
– Provide for heat sinks, such as stripping steam and Provide for heat sinks, such as stripping steam and catalyst cooling.catalyst cooling.
FCC Heat BalanceFCC Heat BalanceRegenerator Reactor
Spent CatalystFlue gas
Heat losses
Regeneration Air Feed Preheater
Recycle
Fresh Feed
Products
Heat LossesHeat of Coke Combustion
Heat of Reaction
Regenerated Catalyst
FCC Heat BalanceFCC Heat BalanceRegenerator Reactor
Spent CatalystFlue gas
Heat losses
Regeneration Air Feed Preheater
Recycle
Fresh Feed
Products
Heat LossesHeat of Coke Combustion
Heat of Reaction
Regenerated Catalyst
Heat Balance Heat Balance Around Stripper-Around Stripper-
RegeneratorRegenerator Heat to raise air from the blower discharge Heat to raise air from the blower discharge
temperature to the regenerator dense temperature to the regenerator dense phase temperature. (108 phase temperature. (108 10 1066 Btu/hr) Btu/hr)
Heat to desorb the coke from the spent Heat to desorb the coke from the spent catalyst. (39.5 catalyst. (39.5 10 1066 Btu/hr) Btu/hr)
Heat to raise the temperature of the Heat to raise the temperature of the stripping steam to the reactor temperature. stripping steam to the reactor temperature. (4.4 (4.4 10 1066 Btu/hr) Btu/hr)
Heat to raise the coke on the catalyst from Heat to raise the coke on the catalyst from the reactor T to the regenerator dense the reactor T to the regenerator dense phase T. (3.7 phase T. (3.7 10 1066 Btu/hr) Btu/hr)
Heat BalanceHeat BalanceAround Stripper-Around Stripper-
RegeneratorRegenerator Heat to raise the coke products from the Heat to raise the coke products from the
regenerator dense temperature to flue regenerator dense temperature to flue gas temperature. (2.17 gas temperature. (2.17 10 1066 Btu/hr) Btu/hr)
Heat to compensate for regenerator heat Heat to compensate for regenerator heat losses. ( 19.3losses. ( 19.3 10 1066 Btu/hr) Btu/hr)
Heat to raise the spent catalyst from the Heat to raise the spent catalyst from the reactor temperature to the regenerator reactor temperature to the regenerator dense phase. (305.5 dense phase. (305.5 10 1066 Btu/hr) Btu/hr)
Reactor Heat BalanceReactor Heat Balance Hot-regenerated catalyst supplies Hot-regenerated catalyst supplies
the bulk of the heat required to the bulk of the heat required to vaporize the liquid feedvaporize the liquid feed
To provide the overall endothermic To provide the overall endothermic heat of crackingheat of cracking
To raise the temperature of To raise the temperature of dispersion steam and inert gases to dispersion steam and inert gases to the reactor temperaturethe reactor temperature
Reactor Heat BalanceReactor Heat Balance Heat into the reactor Heat into the reactor
– Regenerated catalyst = 1186 Regenerated catalyst = 1186 10 1066 Btu/hrBtu/hr
– Fresh feed = 267 Fresh feed = 267 10 1066 Btu/hr Btu/hr– Atomizing steam = 12 Atomizing steam = 12 10 1066 Btu/hr Btu/hr– Heat of absorption = 35 Heat of absorption = 35 10 1066
Btu/hrBtu/hr Total heat in = 1500 Total heat in = 1500 10 1066 Btu/hr Btu/hr
Reactor Heat BalanceReactor Heat Balance Heat out of the reactorHeat out of the reactor
– Spent catalyst = 880 Spent catalyst = 880 10 1066 Btu/hr Btu/hr– To vaporize feed = 513 To vaporize feed = 513 10 1066 Btu/hr Btu/hr– Heat content of steam = 15 Heat content of steam = 15 10 1066
Btu/hrBtu/hr– Loss to surroundings = 6 Loss to surroundings = 6 10 1066 Btu/hr Btu/hr– Heat of reaction = ?Heat of reaction = ?
Total heat out = 1414 Total heat out = 1414 10 1066 Btu/hr Btu/hr + Heat of reaction+ Heat of reaction
Reaction Heat BalanceReaction Heat Balance Calculation of Heat of ReactionCalculation of Heat of Reaction Total heat out = Total heat inTotal heat out = Total heat in Total heat in = 1500 Total heat in = 1500 10 1066 Btu/hr Btu/hr Total heat out = 1414 Total heat out = 1414 10 1066 Btu/hr + Btu/hr +
Heat of reactionHeat of reaction Therefore, Overall Endothermic Heat Therefore, Overall Endothermic Heat
of Reaction = 86 of Reaction = 86 10 1066 Btu/hr Btu/hr
Pressure BalancePressure Balance Deals with the hydraulics of catalyst Deals with the hydraulics of catalyst
circulation in the reactor and circulation in the reactor and regenerator circuit.regenerator circuit.
The incremental capacity come from The incremental capacity come from increased catalyst circulation or from increased catalyst circulation or from altering the differential pressure altering the differential pressure between reactor-regenerator.between reactor-regenerator.
Pressure Balance ResultsPressure Balance Results In spent catalyst standpipe:In spent catalyst standpipe:
– Pressure buildup = 27 kPa (4 psi)Pressure buildup = 27 kPa (4 psi)– Catalyst density = 658 kg/mCatalyst density = 658 kg/m33
– Optimum pressure to circulate more Optimum pressure to circulate more catalystcatalyst
In regenerated catalyst standpipe:In regenerated catalyst standpipe:– Pressure buildup = 55 kPa (8 psi)Pressure buildup = 55 kPa (8 psi)– Catalyst density = 642 kg/mCatalyst density = 642 kg/m33
ConclusionsConclusions Circulating Fluidized Bed is used in Circulating Fluidized Bed is used in
FCC unit.FCC unit. Stripping steam of 4 kg per 1000 kg Stripping steam of 4 kg per 1000 kg
circulating catalyst is required.circulating catalyst is required. Overall endothermic Heat of Overall endothermic Heat of
Reaction is 86 MBtu/hr.Reaction is 86 MBtu/hr. Pressure buildup in spent catalyst Pressure buildup in spent catalyst
standpipe is 27 kPa (4 psi).standpipe is 27 kPa (4 psi). Pressure buildup in regenerated Pressure buildup in regenerated
catalyst standpipe is 55 kPa (8 psi).catalyst standpipe is 55 kPa (8 psi).