カーボンナノ材料 - sigma-aldrich · inkjet printable 808288-5ml graphene ink 7 wt. % solids...
TRANSCRIPT
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グラフェン・酸化グラフェン・還元型酸化グラフェン
グラフェンペーパー
製品名 応用 製品番号
Graphene paper, size 11.5 in. × 23.5 in., thickness 50 μm This is a thin, flexible and lightweight sheet product built on graphene
nanoplatelets. It is a more effective solution than aluminum and copper
foils for a wide variety of applications to optimize thermal conductivity,
thermal spreading, electrical properties, and corrosion resistance.
900449-1EA
Graphene paper, size 11.5 in. × 23.5 in., thickness 120 µm 900451-1EA
Graphene paper, size 11.5 in. × 23.5 in., thickness 240 μm 900452-1EA
グラフェンインク・分散液
製品名 溶媒 粘性 グラフェンサイズ 用途、ほか 製品番号
Graphene dispersion, with ethyl cellulose 1 cyclohexanone and
terpineol 8-15 mPa.s (30 °C) ≤3 μm inkjet printable 793663-5ML
Graphene dispersion, with ethyl cellulose 1 terpineol
0.75-3 Pa.s (25 °C)
(shear viscosity at
100 s-1, 25 °C)
≤3 μm gravure printable 796115-10ML
Graphene dispersion, with ethyl cellulose 1 terpineol
5-50 Pa.s (25 °C)
(shear viscosity at 10
s-1)
≤3 μm screen printable 798983-10ML
Graphene ink ~0.1 wt. % solids in
water 1 cP (100 s-1)
80-500 nm
(exfoliated
graphene flakes)
Inkjet printable 808288-5ML
Graphene ink 7 wt. % solids in
water 570 cP (100 s-1)
500-1500 nm
(exfoliated
graphene flakes)
flexo/gravure/screen
printable 805556-10ML
Graphene ink 10 wt. % solids in
water 350 cP (100 s-1)
500-1500 nm
(exfoliated
graphene flakes)
screen printable 808261-10ML
3D Printing Graphene Ink 2 - 25-45 Pa.s (20 °C) 1-20 μm (length
and width)
Direct syringe extrusion,
Dip-coating, Spin-coating,
Casting
808156-5ML
Graphene ink photonically annealable 3 - 2-4 mPa.s (20-30 °C)
(10-1000 s-1) ≤3 μm
spin-coating, spray-
coating 900960-10ML
Graphene ink photonically annealable -
7-14 mPa.s (25 °C)
(shear viscosity at 10
s-1)
≤3 μm inkjet printing 900695-5ML
Graphene dispersion, 0.2 mg/mL in DMF 4 DMF - Sheet size by
AFM: 5-10 μm. sheet resistance 2 kΩ/sq 900448-50ML
Graphene dispersion, 1 mg/mL in DMF 4 DMF - Sheet size by
AFM: 10 μm.
sheet resistance 4.8
kΩ/sq 900450-5ML
Graphene dispersion, 10 mg/mL, dispersion
in NMP NMP - - - 803839-5ML
Graphene/PEDOT:PSS hybrid ink dispersion
in DMF 5 DMF -
Sheet size by
AFM: 10 μm 0.2 mg/mL (PEDOT:PSS) 900442-50ML
Graphene dispersion, 0.5-1.0 mg/mL in
water, with non-ionic surfactant 6 Water - ≤500 nm - 900696-10ML
1. “Inkjet Printing of High Conductivity, Flexible Graphene Patterns”, Ethan B. Secor, Pradyumna L. Prabhumirashi, Kanan Puntambekar, Michael L. Geier, and Mark
C. Hersam, The Journal of Physical Chemistry Letters 2013 4 (8), 1347-1351. DOI: 10.1021/jz400644c
2. (a)“Three-Dimensional Printing of High-Content Graphene Scaffolds for Electronic and Biomedical Applications”, Adam E. Jakus, Ethan B. Secor, Alexandra L.
Rutz, Sumanas W. Jordan, Mark C. Hersam, and Ramille N. Shah, ACS Nano 2015 9 (4), 4636-4648. DOI: 10.1021/acsnano.5b01179. (b)Webinar: 3D 印刷可能
なハイドロゲルおよび粒子を用いた生体材料インクプラットフォーム
3. “Rapid and Versatile Photonic Annealing of Graphene Inks for Flexible Printed Electronics.” Secor, E. B., Ahn, B. Y., Gao, T. Z., Lewis, J. A. and Hersam, M. C.,
Adv. Mater. 2015 27: 6683-6688. DOI: 10.1002/adma.201502866
4. “Exfoliation of Graphite into Graphene in Aqueous Solutions of Inorganic Salts”, Khaled Parvez, Zhong-Shuai Wu, Rongjin Li, Xianjie Liu, Robert Graf, Xinliang
Feng, and Klaus Müllen, J. Am. Chem. Soc. 2014 136 (16), 6083-6091. DOI: 10.1021/ja5017156
5. “Transparent Conductive Electrodes from Graphene/PEDOT:PSS Hybrid Inks for Ultrathin Organic Photodetectors.”, Liu, Z. , Parvez, K. , Li, R. , Dong, R. ,
Feng, X. and Müllen, K., Adv. Mater. 2015 27: 669-675. DOI: 10.1002/adma.201403826
6. “High-Concentration Aqueous Dispersions of Graphene Using Nonionic, Biocompatible Block Copolymers”, Jung-Woo T. Seo, Alexander A. Green, Alexander L.
Antaris, and Mark C. Hersam, The Journal of Physical Chemistry Letters 2011 2 (9), 1004-1008. DOI: 10.1021/jz2003556
カーボンナノ材料
材料科学関連製品の製品情報は下記 Webサイトまで
http://www.aldrich.com/ms-jp
(詳細な成分情報などはWeb サイトをご確認ください)
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グラフェン ナノプレートレット
製品名 組成、他 製品番号
Graphene nanoplatelets, 5 μm particle size, surface area 50-80 m2/g Residual acid content: <0.5 wt%
Composition oxygen content, <1%
Thickness 15 nm , average
900409-250G
Graphene nanoplatelets, 15 μm particle size, surface area 50-80 m2/g 900410-250G
Graphene nanoplatelets, 25 μm particle size, surface area 50-80 m2/g 900411-250G
Graphene nanoplatelets, 5 μm particle size, surface area 120-150 m2/g Residual acid content: < 0.5 wt%
Composition oxygen content, <1%
Thickness 6-8 nm , average
900412-250G
Graphene nanoplatelets, 15 μm particle size, surface area 120-150 m2/g 900420-250G
Graphene nanoplatelets, 25 μm particle size, surface area 120-150 m2/g 900413-100G
Graphene nanoplatelets, surface area 300 m2/g Thickness a few nm
Particle size <2 μm
900394-250G
Graphene nanoplatelets, surface area 500 m2/g 900439-250G
Graphene nanoplatelets, surface area 750 m2/g 900407-250G
Graphene nanoplatelets, 1 mg/mL, dispersion in H2O Highly conductive few layer graphene platelets.
Sheet Resistantce: 10 (+/-5) ohm/sq for a 25 μm film
799092-50ML
Graphene nanoplatelets, powder 799084-500MG
Graphene nanoplatelets, powder, hydrocarbon functionalized,
hydrophobic
Carbon >85 wt. %
Oxygen >3 wt. %
Dispersibility: dichloromethane, N-methyl-2-
pyrrolidone, and other non-polar solvents
Lipophilic hydrocarbon functionalization on graphene
nanoplatelets.
806633-25G
Graphene nanoplatelets, powder, hydrophobic
Carbon >95 wt. %
Oxygen <2 wt. %
Gaphene nanoplatelets with large lateral dimension (>
25 micron) Highly hydrophobic. It has been used with
success as electrical conductive additive in powder
coating formulation among other properties.
806668-25G
Graphene nanoplatelets, powder, oxidized
Carbon >95 wt. %
Oxygen >1 wt. %
It is slightly oxidized (content of oxygen around 2%)
yielding to a superior dispersion behavior in different
solvent/matrix. It has been used with success as anti-
corrosion additive in powder coating formulation among
other properties.
806641-25G
Graphene nanoplatelets, powder, polycarboxylate functionalized, hydrophilic
Carbon >70 wt. %
Oxygen >10 wt. %
Polycarboxylate chemically modified graphite
nanoplatelets. High stability in aqueous medium.
806625-25G
グラフェンナノリボン
製品名 サイズ、他 製品番号
Graphene nanoribbons Produced by unzipping multi-walled carbon nanotubes by potassium
intercalation. L × W: 2-15 μm × 40-250 nm
797774-500MG
Graphene nanoribbons, alkyl functionalized 797766-500MG
詳細はこちら→ 【レビュー】グラフェンナノリボン:その合成と応用
酸化グラフェン
製品名 用途、他 製品番号
Graphene oxide, 2 mg/mL, dispersion in H2O
• Chloride free (purified by dialysis)
• Monolayer sheet
• Mean sheet diameter: 22 μm, 90% below 50 μm by laser
diffraction
763705-25ML
763705-100ML
Graphene oxide, 4 mg/mL, dispersion in H2O monolayer content (measured in 0.5mg/mL): >95% 777676-50ML
777676-200ML
Graphene oxide, paste, non-exfoliated
Graphene oxide paste can make storage and transportation of large
quantities in a safe manner. Graphene oxide solutions of desired
concentration or graphene oxide paper or sheet can be made from
graphene oxide paste.
900704-25G
900704-100G
Graphene oxide, film (4cm (diameter) x 12-15mm
(thickness), non-conductive) Novel graphene oxide membranes for ionic and molecular sieving. 798991-1EA
Graphene oxide nanocolloids, 2 mg/mL, dispersion in H2O Single-layer graphene oxide sheets down to a few nanometers in
lateral width
795534-50ML
795534-200ML
Graphene oxide, 15-20 sheets, 4-10% edge-oxidized, 1
mg/mL, dispersion in H2O Oxygen (Dry Basis): < 11 %
794341-50ML
794341-200ML
Graphene oxide, 15-20 sheets, 4-10% edge-oxidized,
powder 796034-1G
Graphene oxide, alkylamine functionalized, 2.0 mg/mL,
dispersion (in toluene)
The excellent solubility /dispersibility of alkylamine-functionalized
graphene oxides (FGOs) in low-polar solvents. 809055-50ML
Graphene oxide, ammonia functionalized, 1 mg/mL,
dispersion in H2O Nitrogen: 3 - 6 %
791520-25ML
791520-100ML
Graphene oxide, pH stabilized, dispersion in 0.05 M HEPES
buffer, pH 7.5 -
901940-25ML NEW!
901940-100ML NEW!
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ドープグラフェン他
製品名 アプリケーション例 製品番号
Graphene, alkylamine functionalized
• Polymer filler to improve thermal, electrical and mechanical
properties.
• Rubber filler to improve mechanical and gas barrier properties.
• Hydrophobic surface.
• Lubrication.
900551-250MG
Graphene, silane modified
• Polymer filler to improve thermal, electrical and mechanical
properties.
• Rubber filler to improve mechanical and gas barrier properties.
• Super hydrophobic surface.
900552-250MG
Nitrogen-doped graphene (high electrochemical activity)
High electrochemical activity towards oxygen reduction in alkali
medium providing an affordable industrial alternative to currently
used noble metal-based catalysts (i.e. Pt, Pd).
900416-500MG
Nitrogen-doped graphene (Nitrogen, 2.0-4.0%, >500 m2/g (BET))
• Electro catalyst.
• Field-effect transistors.
• Sensors.
• Lithium ion batteries.
• Supercapacitors. 900527-250MG
Nitrogen/Phosphorus co-doped graphene
• Electro catalyst.
• Field-effect transistors.
• Sensors.
• Lithium ion batteries.
• Supercapacitors.
900531-250MG
Nitrogen/Sulfur co-doped graphene 900530-250MG
Phosphorus-doped graphene 900529-250MG
Sulfur-doped graphene 900528-250MG
Boron-doped graphene 900526-250MG
Boron/Nitrogen co-doped graphene 900535-250MG
Graphene, powder, electrical conductivity >103 S/m • Anti-corrosion coatings.
• Anti-static packaging-cement.
• Composites electronics 900561-500MG
ナノコンポジット, 10 mg/mL, dispersion in acetone
製品名 Loading Density by TEM
Particle size アプリケーション例 製品番号
Pd/graphene 10%-50% (Pd nanocrystal)
5-50 nm (Pd nanocrystal)
• Perfect for transmission electron microscopy imaging standard.
• A catalytic material to be used in fuel cells, CH4 gas sensor.
803707-5ML
Pd/reduced graphene oxide 803790-5ML
Pt/graphene 5%-30% (Pt nanocrystal)
2-5 nm (Pt nanocrystal)
• Supercapacitor electrode materials.
• Filling materials for heating conduction.
• Photocatalysis.
803693-5ML
Pt/reduced graphene oxide 803782-5ML
PtCo/graphene 10%-50% (PtCo nanocrystal)
2-5 nm (PtCo nanocrystal) Efficient electrocatalyst material for fuel cells including
methanol oxidation, proton exchange membrane.
803766-5ML
PtCo/reduced graphene oxide 803901-5ML
PtPd/graphene 10%-50% (PtPd nanocrystal)
5-50 nm (PtPd nanocrystal)
803758-5ML
PtPd/reduced graphene oxide 803820-5ML
Fe3O4/graphene 30%-70% (Fe3O4 nanocrystal)
5-25 nm (Fe3O4 nanocrystal)
• Electromagnetic wave absorption materials.
• Electro-magnetic device.
• Anode material for lithium-ion batteries.
803715-5ML
Fe3O4/reduced graphene oxide 803804-5ML
Mn3O4/graphene 30%-70% (Mn3O4 nanocrystal)
5-25 nm (Mn3O4 nanocrystal)
High capacity anode material for supercapacitors and lithium
ion batteries.
803723-5ML
Mn3O4/reduced graphene oxide 803812-5ML
TiO2/graphene 30%-70% (TiO2 nanocrystal)
10-40 nm (TiO2 nanocrystal)
• Photocatalyst
• Dye sensitized solar cells
805351-5ML
TiO2/reduced graphene oxide 805343-5ML
単層グラフェン膜 by CVD
製品名 Substrate 製品番号
Monolayer graphene film, 1 cm x 1 cm on copper foil Cu Foil thickness: 25 μm 773697-4EA
Monolayer graphene film, 1 in x 1 in on copper foil Cu Foil thickness: 18 μm
799009-1EA
Monolayer graphene film, 4 in diameter on copper foil 900415-1EA
Monolayer graphene film 1 in x 1 in on copper foil, with PMMA coating Cu Foil thickness: 18 μm
PMMA Coating: <100 nm
900445-1EA
Monolayer graphene film 1 cm x 1 cm on copper foil, with PMMA coating 900443-4EA
Monolayer graphene film, 1 cm x 1 cm on quartz Quartz substrate thickness: 525 μm 773719-4EA
Monolayer graphene film, 1 cm x 1 cm on SiO2/Si substrate SiO2/Si substrate thickness: 525 μm 773700-4EA
Monolayer graphene film, 1 in. x 1 in. on PET film PET film thickness: 0.188 mm
745863-1EA
745863-5EA
Monolayer graphene film, 2 in. x 2 in. on PET film 745871-1EA
Suspended monolayer graphene on TEM grid substrate (Quantifoil gold)
Type: QUANTIFOIL R 2/4
Hole Size: 2 micrometers
Space between holes: 4
micrometers
Diameter: 3 mm
Coating: Au coated 798177-1PK
還元型酸化グラフェン
製品名 組成 表面積、他 製品番号
Reduced graphene oxide Carbon: >75%
Nitrogen: <5%
BET surf. Area: 103 m2/g
Conductivity: 7111 S/m (pressed pallet)
805424-500MG
805424-1G
Reduced graphene oxide Carbon: 95 wt. %
Nitrogen: >5 wt. %
BET surf. Area: 450 m2/g
Conductivity: 600 S/m (20 nm film thickness)
777684-250MG
777684-500MG
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Reduced graphene oxide, amine functionalized Carbon: >65 wt. %
Nitrogen: >5 wt. % 805432-500MG
Reduced graphene oxide, octadecylamine functionalized Carbon: >78 wt. %
Nitrogen: >3 wt. % Surface group: -NH(CH2)17CH3 805084-500MG
Reduced graphene oxide, piperazine functionalized Carbon: >65 wt. %
Nitrogen: >5 wt. % Surface group: piperazine 805440-500MG
Reduced graphene oxide, tetraethylene pentamine
functionalized
Carbon: >65 wt. %
Nitrogen: >8 wt. % Surface group: -N(CH2CH2NHCH2CH2NH2)2 806579-500MG
Reduced graphene oxide, stabilized with poly(sodium 4-
styrenesulfonate), 10 mg/mL, dispersion in H2O -
Non-covalent functionalization with PSS
molecules prevents rGO from aggregation. 900197-100ML
単層カーボンナノチューブ ※供給元資料よりの参考情報。製品規格は Web サイトにてご確認ください。
Carbon nanotube, single-walled(Signis ®
CG-100)
Carbon nanotube, single-walled(Signis ®
CG-200)
Carbon nanotube, single-walled(Signis
® CG 300)
704113-250MG, 1G 724777-250MG, 1G 775533-250MG, 1G
Economical Single-Wall CNT
Carbon Purity: ≥ 90 wt% (TGA)
CNT Purity: ≥ 89 wt% (TGA)
Average Diameter: 0.82 nm (NIRF)
Median Length: 1 micron (AFM)
Specific Surface Area: ≥ 700 m2/g (BET)
Moisture Content: ≤ 5 wt% (TGA)
G/D Ratio: ≥ 15 (Raman, 633 nm)
Large Diameter Single-Wall CNT
Carbon Purity: ≥ 90 wt% (TGA)
CNT Purity: ≥ 89 wt% (TGA)
Average Diameter: 1.3 nm (NIRF)
Median Length: 1 micron (AFM)
Specific Surface Area: ≥ 700 m2/g (BET)
Moisture Content: ≤ 5 wt% (TGA)
G/D Ratio: ≥ 15 (Raman, 633 nm)
Conductive Single-Wall CNT
Carbon Purity: ≥ 95 wt% (TGA)
CNT Purity: ≥ 94 wt% (TGA)
Average Diameter: 0.84 nm (NIRF)
Median Length: 1 micron (AFM)
Specific Surface Area: ≥ 700 m2/g (BET)
Moisture Content: ≤ 5 wt% (TGA)
G/D Ratio: ≥ 15 (Raman, 633 nm)
Sheet Resistance: ≤600 Ω/□ @ 85% VLT
(TCF)
Carbon nanotube, single-walled,(6,5)
chirality(Signis ® SG-65i)
Carbon nanotube, single-walled,(6,5)
chirality(Signis® SG-65)
Carbon nanotube, single-walled,(7,6)
chirality(Signis ® SG-76)
773735-250MG, 1G 704148-250MG, 1G 704121-250MG, 1G
Semiconducting Single-Wall CNT Enriched in
Chirality (6,5)
Carbon Purity: ≥ 95 wt% (TGA)
CNT Purity: ≥ 94 wt% (TGA)
Semiconducting CNT Content: 95% (Opt. Abs.)
(6,5) CNT Content: ≥ 40% (NIRF)
Average Diameter: 0.78 nm (NIRF)
Median Length: 1 micron (AFM)
Specific Surface Area: ≥ 700 m2/g (BET)
Moisture Content: ≤ 5 wt% (TGA)
G/D Ratio: ≥ 20 (Raman, 633 nm)
組成: >90%(carbon)、≥77%(carbon as
SWCNT, T1%)
長さ: ≥700 nm
直径: 0.7 - 0.9 nm(光吸収スペクトルお
よび AFM にて確認)
Single-Wall CNT Enriched in Chirality (7,6)
Carbon Purity: ≥ 90 wt% (TGA)
CNT Purity: ≥ 89 wt% (TGA)
Average Diameter: 0.83 nm (NIRF)
Median Length: 1 micron (AFM)
Specific Surface Area: ≥ 700 m2/g (BET)
Moisture Content: ≤ 5 wt% (TGA)
Carbon nanotube, single-walled
(NANOCYL™ NC1100)
Carbon nanotube, single-walled
(Tuball)
Carbon nanotube, single-walled Low
metal content (Tuball) NEW!
755710-250MG, 1G 805033-25G 901634-25G
製法 CVD 法
炭素純度 >70% (TGA)
不純物 金属酸化物・カーボンシェル:
<30% (TGA), アモルファルカー
ボン: NA (HRTEM)
平均直径×長さ 2 nm (HRTEM, Raman) × several
μm (TEM)
表面積 >1000 m2/g (BET)
組成: ≥85 % (carbon), >70%
(carbon as SWNT)
平均直径×長さ 1.8 nm (1.3-2.3 nm) ×>5 μm
(AFM)
表面積 ~520 m2/g (BET)
Used as additives
組成 ≥93% (carbon as SWNT by TEM,
TGA)
>99% (carbon content, EDX, TGA)
長さ >5 μm , By AFM
直径 1.2-2.0 nm , By Optical absorption
不純物 <1% Metal impurities (TGA, By EDX)
Low-iron, purified SWCNT powder especially for use
in energy applications
Carbon nanotube, single-walled
(ZEONANO)
900711-5G
製法 Super-growth (SG) method
組成: ≥98 % carbon basis
Ash: < 1%
平均直径×長さ 3-5 nm ×>300-500 μm (in
forest)
表面積 800-1000 m2/g (BET)
Application
• Electrode in power storage devices.
• Additives in structural materials.
• Flexible electronic materials.
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Signis is a registered trademark of Chasm Advanced Materials, Inc. CoMoCAT is a trademark of Chasm Advanced Materials, Inc. NANOCYL is a trademarks of Nanocyl, Inc.
Nanointegris社製単層カーボンナノチューブ (詳しくは Web サイト(www.aldrich.com/nano-jp)をご覧ください)
IsoNanotubes-M™ (750530-
1MG)
IsoNanotubes-S™ (750522-
1MG)
PureTubes™ (750492-100MG)
SuperPureTubes™ (750514-25MG)
ナノチューブタイプ Arc discharge or Plasma Torch
チューブ直径 1.2 - 1.7 nm
チューブ平均直径 1.4 nm
チューブ長さ 0.3 – 5 µm
チューブ平均長さ 1 micron
炭素系不純物 < 5% by mass
残留触媒 ~1% by mass ~1% by mass < 3.5% by mass (750492)
< 1% by mass (750514)
半導体性 CNT 含有量 2 % 98% 70 %
金属性 CNT 含有量 98% 2 % 30 %
価格 ¥107,000 ¥70,200 ¥49,700 (750492)
¥46,000 (750514)
IsoNanotubes, PureTubes and SuperPureTubes are trademarks of NanoIntegris, Inc.
透明導電性 CNT インク CoMoCAT®カーボンナノチューブを含む導電性インクには、コーティングの種類ごとに 3 つのタイプがあります。耐久性と環境安定性の必要な用途で、優れた透明
導電性を示すコーティングが可能です。
製品名 用途 製品番号
SWCNT, conductive aqueous ink, 0.2 mg/mL (Signis® AC100) Spray Coating 791490-25ML
791490-100ML
SWCNT conductive aqueous ink, 1.00 mg/mL (Signis® AC200) Meyer-Rod/Slot-Die Coating 791504-25ML
791504-100ML
SWCNT solvent-based conductive ink, 1 mg/mL (Signis® VC101 ink) Screen Printing 792462-25ML
792462-100ML
※詳細な物性やコーティング条件は、供給元 Chasm Advanced Materials 社の Web サイト(www.chasmtek.com)をご覧ください。
カーボンナノホーン Web サイト(www.aldrich.com/nano-jp)にて、レビュー「カーボンナノホーン:大量製造技術、材料特性、応用展開」を公開中です。
製品名 物性 製品番号・価格
Carbon nanohorns, as-grown
(CNH, CNHs)
assay:90% (TGA) impurities:0% metallic, 10% graphite, amorphous
diameter:2-5 nm (TEM)
surface area:spec. surface area 400 m2/g (BET)
804118-250MG
Carbon nanohorns, oxidized
(CNHox, Holey Carbon
Nanohorns)
assay:90% (TGA) impurities:0% Metallic compound, 10% graphite;
amorphous
diameter:2-5 nm (TEM)
surface area:spec. surface area 1300-1400 m2/g (BET method)
804126-250MG
ポリジアセチレンナノチューブ(PDNT) ポリジアセチレンナノチューブ(PDNT:Polydiacetylene Nanotube)は、共役 2 重、3 重結合の架橋構造から構成される自己組織化ジアセチレンナノチューブで
す。PDNT は、均一な構造をもち、固体もしくは溶液内において応答性の高いクロミック特性を示すことで知られています。Web サイト(www.aldrich.com/nano-
jp)にて、レビューを公開中です。
性質
• 内径と外径が非常に均一な高純度ナノチューブ
• ポリマー内のπ電子による電気伝導性
• 熱およびメカノクロミズム
期待される応用例
• バイオセンサ
• 色の変化を利用した圧力センサ
• 酵素担体
• ナノエレクトロニクス、Lab-on-a-chip デバイス
• Langmuir-Blodgett 膜
• MEMS、メンブレンフィルタ、ガス分離
Poly(N-[2-(ethylamino)ethyl]-10,12-pentacosadiyneamide hydrogen bromide) nanotube
O.D. × I.D. × L 100 nm × 30 nm × 1,000 nm 773484-250MG
Poly(N-[2-(propylamino)ethyl]-10,12-pentacosadiyneamide hydrogen bromide) nanotube
O.D. × I.D. × L 110 nm × 40 nm × 1,000 nm 773492-250MG
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修飾済み単層カーボンナノチューブ
Single-walled carbon nanotubes, octadecylamine
functionalized 1)
Single-walled carbon nanotubes, polyaminobenzene sulfonic
acid functionalized 2)
652482-100MG 639230-100MG
炭素含有量 80 – 90 % (carbon basis)
ODA 含有量 30 – 40 wt.%
金属含有量 2 - 6 %
直径(Bundle) 2 – 10 nm
長さ 0.5 – 2 µm, bundles
溶解性
THF, 1,2-Dichlorobenzene, CS2 : ≧1 mg/ml
ベンゼン、トルエン、クロロホルム、ジクロロメタンにも溶解
炭素含有量 75 – 85 % (carbon basis)
金属含有量 4 %
ポリマー含有量 65 % (PABS, typical)
ポリマー平均分子量 Mw 400 – 600 g/mol (PABS)
直径(Bundle) 4 – 5 nm
長さ 500 – 1000 nm
溶解性 c) H2O: 5.0 mg/ml, DMF: 0.1 mg/ml,
Ethanol: 0.05 mg/ml
Single-walled carbon nanotubes, poly(ethylene glycol)
functionalized 2) Carbon nanotube, single-walled, amide functionalized
652474-100MG 685380-100MG
炭素含有量 > 80 % (carbon basis)
金属含有量 4 - 5 %
ポリマー含有量 80 wt.%
ポリマー平均分子量
Mw ~600 g/mol (PEG)
直径(Bundle) 4 – 5 nm
長さ 500 – 600 nm, bundles
溶解性 H2O: 5.0 mg/ml
炭素含有量 > 90 % (carbon basis)
アミド含有量 per 4 atom% (amide groups)
金属含有量 5 - 8 %
直径(Bundle) 4 – 6 nm
長さ 0.7 – 1.0 µm, bundles
溶解性
DMF, acetone, alcohols:
0.5 - 1.0 mg/mL (with sonication)
Single-walled carbon nanotubes, carboxylic acid functionalized
652490-250MG, 1G
As-produced nanotubes are purified with nitric acid and left
in a highly functionalized form. This material contains
carboxylic acid functionality along the length of the
nanotube which can be derivatized with a variety of
functional groups.(2) The carboxylic acid groups are located
at the edge and defect sites on the side walls. The SWNTs
material is produced by electric arc discharge technique.(4),(5)
The type of Carboxylic group is ”-COOH”.
炭素含有量 > 90 % (carbon basis)
カルボン酸含有量 1.0 - 3.0 atom% carboxylic acid
金属含有量 5 - 8 %
直径(Bundle) 4 – 5 nm
長さ 0.5 – 1.5 µm, bundles
溶解性 DMF = 1.0 mg/ml, H2O = 0.1 mg/ml
各 SWCNT の平均直径は 1.4 nm ± 0.1 nm。炭素含有量は「Nano. Lett., 2003, 3(3), 309」の方法で測定。アーク放電法で作製された SWCNT を使用。
1) Niyogi, S. et al. Accts. Chem. Res. 2002, 35, 1105. 2) Zhao, B. et al. Adv. Funct. Mater. 2004, 14(1), 71., Zhao, B. et al. J. Am. Chem. Soc. 2005, 127, 8197.
3) Solubilities determined by NIR absorbance. 4) Journet, C. et al., Nature 1997, 388, 756. 5) Itkis, M.E. et al. J. Phys. Chem. B 2004, 108, 12770.
Nanocyl社製 2層カーボンナノチューブ
NANOCYLTM NC2150, Short Double-Wall
製品番号、価格 755141-1G
製法 CVD 法
炭素純度 >90% (TGA)
不純物 金属酸化物:<10% (TGA)
カーボンシェル・アモルファルカーボン: TBD (HRTEM)
平均直径×長さ 3.5 nm (HRTEM) × several μm (TEM/SEM)
※供給元資料よりの参考情報
多層カーボンナノチューブ
Carbon nanotube, few-walled
(Signis® FW100) Carbon nanotube, multi-walled
Carbon nanotube, multi-walled,
thin(NANOCYLTM NC-3100)
900788-250MG, 1G 698849-1G 755133-5G
組成: > ≥94% (carbon as CNT by TGA)
Median number of walles: 2 to 3 (TEM)
G/D ratio: ≥10 (Raman)
直径×長さ: 2.5-3 nm × 2-6 μm
BET 表面積: >700 m2/g (BET)
製法: CoMoCAT™ synthesis process
組成: >98% carbon content (trace metal basis)
外径×長さ:
6 - 13 nm × 2.5 - 20 μm (約7 ~ 13層)
BET 表面積 約 220 m2/g (SSA)
製法: CVD 法 (塩酸処理済み)
組成: >95% carbon content (TGA)
直径×長さ: 9.5 nm × 1.5 μm (TEM)
金属酸化物: < 5% (TGA)
製法: CVD 法
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Carbon nanotube, multi-walled,
short, thin(NANOCYLTM NC-3150)
Carbon nanotube, multi-walled,
thin, carboxylic acid functionalized Carbon nanotube, multi-walled
755117-1G 755125-1G 659258-2G, 10G
組成: >95% carbon content (TGA)
直径×長さ: 9.5 nm × 1 μm (TEM)
金属酸化物: < 5% (TGA)
製法: CVD 法
組成: >8% carboxylic acid functionalized
直径×長さ:
9.5 nm × 1.5 μm (TEM)
製法: CVD 法
Product of Nanocyl, Inc
組成: >90% carbon content、≤0.1 % (Fe)
直径×長さ:
110 – 170 nm × 5 – 9 μm
製法: CVD 法
Carbon nanotube, multi-walled,
flake of bundled CNTs
Carbon nanotube, multi-walled,
vertically aligned on Si substrate
Carbon nanotube, multi-walled,
vertically aligned on Si substrate
901002-1G 901052-1EA 901051-1EA
組成: >95% carbon content
直径(O.D.)×長さ:
10-40 nm × 0.5-1.5 mm
製法: CVD 法
基板: 20 mm x 20 mm Si substrate
Areal density: 1-5 x 109 cm-2
直径×長さ: 10 - 40 nm × 1.0 mm ± 0.1 mm
組成: ≥98% (carbon as CNT)
製法: CVD 法
基板: 20 mm x 20 mm Si substrate
Areal density: 1-5 x 109 cm-2
直径×長さ: 10 - 40 nm × 0.5 mm ± 0.1 mm
組成: ≥98% (carbon as CNT)
製法: CVD 法
Carbon nanotube, multi-walled,
drawable, vertically aligned on Si
substrate
Carbon nanotube, multi-walled,
sheet
Carbon nanotube, multi-walled,
sheet
901046-1EA 901082-1EA 901056-1EA
基板: 10 mm x 20 mm Si substrate
Areal density: 1-5 x 109 cm-2
直径×長さ: 10 - 40 nm × 1.0 mm ± 0.1 mm
組成: ≥98% (carbon as CNT)
製法: CVD 法
組成: >95% carbon content
直径: 10-40 nm (carbon nanotubes)
シート大きさ: 100 mm × 100 mm × 1-5 μm
製法: CVD 法
組成: >95% carbon content
直径: 10-40 nm (carbon nanotubes)
シート大きさ: 50 mm × 50 mm × 1-5 μm
製法: CVD 法
Carbon nanotube, multi-walled
901019-25G
組成: >95% carbon content
直径: 50-90 nm
アスペクト比: >100 , by FE-SEM
製法: CVD 法
Carbon nanochips
別名 Heat treated platelet graphite nanofibers, carbon
nanochip fibers
外観 flakes
サイズ aspect Ratio: 25, average length: 2.5μm, average
width : 100 nm
表面積 40 m2/g
799017-500MG
Application
• Negative electrode for lithium ion secondary batteries.
• Catalyst for ethylene oxidative dehydrogenation.
General description
Carbon nanochips consist of wrapped graphite sheets oriented perpendicular
to the fiber axis. Carbon nanochips are formed when platelet graphene or
graphite nanofibers are heated in argon to about 3000°C, resulting in a
sealing action of some of the edge sites and also removes all traces of
inclusions such as the catalyst that is used to grow the precursor graphite
nanofibers.
フラーレン誘導体
[60]PCBM Bis[60]PCBM, 99.5%(mixture of isomers)
[70]PCBM, 99% PCBB, [60]PCB-C4 , > 97%
(99%: scale-up grade)
684430-1G
(99.5%: research grade)
684449-100MG, 500G
(99.9%: for exploratory work)
684457-100MG
704326-100MG 684465-100MG, 500G 685321-100MG, 1G
-8-
PCBO, [60]PCB-C8 , 99% [60]ThCBM, 99% d5-PCBM, 99% C60 Pyrrolidine tris-acid ethyl ester, 97%
684481-100MG 688215-100MG 684503-100MG 709093-250MG
C60 Pyrrolidine tris-acid, 97% (1,2-Methanofullerene C60)-61-carboxylic acid
N-Methylfulleropyrrolidine, 99%
ICBA
709085-100MG 658847-25MG 668184-100MG (99%) 753955-250MG
(99.9%) 745839-250MG
water, pH >9: soluble
ICMA, 97% Small gap fullerenes1 Small gap fullerene-ethyl nipecotate, ≥95%
Polyhydroxy small gap fullerenes, hydrated
753947-250MG 707503-1G 707473-250MG 707481-100MG
water, pH >9: soluble
C60-SAM, >99% Polyhydroxylated fullerenes, Water soluble (C60(OH)n · mH2O (n>40, m>8))
802832-100MG 793248-100MG
極性溶媒に対して溶解性をもたないフラーレンを水溶性にするため、フラーレン分子表面に多数の水酸基を付与
することにより、優れた水溶解性を実現しています。また、共役結合に由来する抗酸化に加え、水酸基由来の抗酸
化作用を発揮するため、優れた抗酸化作用を示します。これらの特徴を生かし、研磨剤としての利用やライフサイ
エンス分野など幅広い応用が期待されます 2-7。
【特徴】
● 40 個以上の水酸基を持つフラーレン誘導体
● 高い水溶解性(50 mg/mL)
● 水溶液中で単分散
● 優れた抗酸化作用・抗炎症作用
● 抗菌作用など生物学的応用にも期待
1. Diener, M.D. et. al Carbon 49, 37-46, (2011) 2. Kokubo K, et al. Nano Res 4(2), 204-215, (2011) 3. Ken Kokubo et. al ACS Nano, 2(2), 327-333 (2008) 4. Yasukazu Saitoh et. al Journal
of Photochemistry and Photobiology B: Biology, 102(1), 69-76 (2011) 5. Eropkin YM, et al. Pharmaceut. Chem. J. 47(2), 87-91, (2013) 6. Hisae Aoshima et. al Biocontrol Science, 14(2),
69-72 (2009) 7. Yasukazu Saitoh et. al Molecular and Cellular Biochemistry, 366(1-2), 191-200 (2012)
炭素系量子ドット Carbon quantum dots, 0.2+% in H2O (λem 450-550 nm) 900414-10ML
Graphene quantum dots, blue luminescent, 1 mg/mL in H2O 900708-50ML
Graphene quantum dots, blue luminescent, powder 900726-50MG
Graphene quantum dots, cyan luminescent, 1 mg/mL in H2O 900707-50ML
Graphene quantum dots, aqua green luminescent, 1 mg/mL in H2O 900712-50ML
Graphene quantum dots, aqua green luminescent, powder 900713-50MG
Graphene quantum dots, >0.005% in H2O 900560-10ML
900708(Graphene quantum dots, blue luminescent)の外観および TEM 像
-9-
蛍光ナノダイヤモンド
蛍光ナノダイヤモンドは、ダイヤモンド中の窒素と格子欠陥が形成する N-V(nitrogen-vacancy) cenrter による高い蛍光特性を有するナノダイヤモンドです。また、
ナノダイヤモンドは高い生体適合性を持ち、低い細胞毒性および遺伝毒性を示すことから、生物医学用イメージングや診断、治療薬としての利用が期待されてい
ます。Web サイト(www.aldrich.com/nano-jp)にて、レビュー「色中心を有する蛍光ナノダイヤモンド粒子:その特性と応用」を公開中です。
製品名 製品番号
Fluorescent nanodiamond, Nitrogen vacancy >300 NV/particle, 70 nm, 1 mg/mL in deionized water 798169-5ML
Fluorescent nanodiamond, Nitrogen vacancy >500 NV/particle, 90 nm, 1 mg/mL in deionized water 798150-5ML
Fluorescent nanodiamond, Nitrogen vacancy >400 NV/particle, 100 nm, 1 mg/mL in deionized water 798142-5ML
Fluorescent nanodiamond, Nitrogen vacancy >800 NV/particle, 100 nm, 1 mg/mL in deionized water 798134-5ML
Fluorescent nanodiamond, Nitrogen vacancy >1200 NV/particle, 120 nm, 1 mg/mL in deionized water 798088-5ML
Fluorescent nanodiamond, Nitrogen vacancy <=4 NV/particle, 35 nm, 1 mg/mL in deionized water, carboxylated 900172-5ML
Fluorescent nanodiamond, Nitrogen vacancy >60 NVN/particle, 70 nm, 1 mg/mL in deionized water 900173-5ML
Fluorescent nanodiamond, Nitrogen vacancy >900 NV/particle, 100 nm, 1 mg/mL in deionized water, hydroxylated 900174-5ML
Fluorescent nanodiamond, nitrogen vacancy ~3 ppm, 140 nm avg. part. size, amine functionalized, powder 901799-5MG NEW!
Fluorescent nanodiamond, nitrogen vacancy ~3 ppm, 140 nm avg. part. size, amine functionalized, PEG 3000 coated, 1
mg/mL in deionized water 901802-5ML NEW!
Fluorescent nanodiamond, nitrogen vacancy ~3 ppm, 140 nm avg. part. size, biotin functionalized, PEG 3000 coated, 1
mg/mL in deionized water 901798-2ML NEW!
Fluorescent nanodiamond, nitrogen vacancy ~3 ppm, 140 nm avg. part. size, carboxylic acid functionalized, PEG 3000
coated, 1 mg/mL in deionized water 901800-5ML NEW!
Fluorescent nanodiamond, nitrogen vacancy ~3 ppm, 140 nm avg. part. size, hydroxyl functionalized, PEG 3000 coated, 1
mg/mL in deionized water 901803-5ML NEW!
Nanodiamonds, 65 nm octadecane functionalized, powder 901770-1G NEW!
Nanodiamonds, 65 nm, dodecane functionalized, powder 901967-1G NEW!
Monodispersed nanodiamond particles, 5 nm, 10 mg/mL in NMP, carboxylated 900177-100ML
Monodispersed nanodiamond particles, 5 nm, 10 mg/mL in polyalphaolefin synthetic base oil, carboxylated 900178-5ML
900178-100ML
Monodispersed nanodiamond particles, 5 nm, 10 mg/mL in DMSO, hydroxylated 900179-5ML
900179-100ML
Monodispersed nanodiamond particles, 5 nm, 10 mg/mL in H2O, carboxylated 900180-5ML
900180-100ML
Monodispersed nanodiamond particles, 5 nm, 10 mg/mL in ethylene glycol, carboxylated 900184-5ML
900184-100ML
Monodispersed nanodiamond particles, 5 nm, 10 mg/mL in DMSO 900185-5ML
900185-100ML
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