first application of a new process for producing linear alpha-olefins

1
of detergent enzymes in the 1970s to reduce heavy phosphates use in what was the first major effort to lessen the environmental impact of laundry. It is encouraging to see a new emphasis on low-temperature laundry with its energy-saving benefits, but for the full environmental picture it’s important to consider water use as well as that of energy and chemicals. Over the coming years, global water supply will become an increasing problem. Reducing water consumption by domestic laundry not only conserves water resources but can also reduce detergent use and, within limits, improve detergent performance. In the US, recent figures from the Energy Dept show that water use per load is virtually unchanged from 20 years ago at about 150 litres (40-45 gal). In mid- 1980s Europe, typical washwater loads were around 120 litres but today’s energy-efficient front-loading machines achieve 50-60 litres – ‘every little helps’. Reducing energy use for domestic laundry is good, but to truly minimize its environmental impact what we now need is for detergent manufacturers to work with washing machine producers, and with legislators, to encourage reduced water consumption. Caroline Edser RAW MATERIALS Alpha-olefins First application of a new process for producing linear alpha-olefins Linear alpha-olefins (LAOs) have many applications as intermediates in the chemical industry, particularly as a base stock for plastics and detergents. Linde, in cooperation with Sabic of Saudi Arabia, has developed a new technology for selective catalytic synthesis of LAOs from ethylene. The alpha-SABLIN technology can be used to produce a wide range (short to long chains) of highly pure LAOs with high selectivity and under moderate operating conditions. The product distribution can be changed easily by varying the reaction conditions and adjusting the homogeneous catalyst system. The technology has been tested successfully over several years in a pilot plant at the Sabic Research and Technology Center in Riyadh, Saudi Arabia. The first commercial plant is being built by Linde for Jubail United Petrochemical Co in Al-Jubail, Saudi Arabia. Commercial production will begin in 2006. Linde Technology, Dec 2004, 38-45 (Linde AG, Abraham-Lincoln-Strasse 21, 65189 Wiesbaden, Germany. Tel: +49 0611 770 0. Fax: +49 0611 770 269. Website: http://www.linde.com) Profile of linear alpha-olefins in the US Four plants produce linear alpha- olefins in the US. Total US capacity is 5220 M lbs/y. Demand was 3130 M lbs in 2003, 3200 M lbs in 2004, and is forecast at 3465 M lbs for 2008. Demand growth was 1.5%/y between 1999 and 2004, and is forecast at 2%/y through 2008. Main uses are in the manufacture of polyethylene co- monomer 42%, detergent alcohols 17% and polyalpha-olefins 12%. Chemical Market Reporter, 21 Feb 2005 (Website: http://www.chemicalmarketreporter.com) Oleochemicals Ultrapar to invest US$94 M in new Oxiteno fatty alcohols plant As reported in the March issue, Brazil’s Ultrapar is planning to construct a plant for fatty alcohols production, with co-production of fatty acids (C8 to C18) and glycerine, in the petrochemical complex of Camaçari, in the state of Bahia. The company, through its chemicals arm Oxiteno, will invest approximately US$94 M in the construction during the next two years. Fatty alcohol production capacity will be approximately 80,000 tonnes/y, with lauryl alcohol the major product. The main raw materials to be used are of natural origin, such as palm kernel and coconut vegetable oils, which can be sourced within the state. The plant will be a pioneer unit in Latin America for the production of fatty alcohols. These materials are currently imported, with 2004 South American imports amounting to about 50,000 tonnes. Brazil is responsible for around 90% of this consumption and Oxiteno is the country’s largest consumer of fatty alcohols. Oxiteno estimates it will use some 30% of the alcohol output to make its surfactants product lines for personal care, household cleaning, agrochemicals, textile and other applications. Besides adding value to this existing product line, the new plant is expected to generate additional net sales of US$80 M/y when running at full capacity. Press release from: Oxiteno, Sao Paulo, Brazil. Website: http://www.oxiteno.com.br (16 Feb 2005) & BNAmericas Oil & Gas News, 17 Feb 2005, (Business News Americas Ltda, website: http://www.Bnamericas.com) Kulim aims for even balance in operations Kulim (M) Bhd is in the process of balancing its upstream and downstream operations and has allotted two years to achieve this purpose. At present, 65% of Kulim’s operations are upstream operations against 35% downstream. Once the operations are even, the company’s income will be stabilized. With both the operations strengthened, it believes it can become one of the leading plantation companies in the region. Kulim plans to expand its downstream activities, especially the manufacture of oleochemicals and related by-products. It has invested around Ringgit 150 M for expansion of oleochemical operations, which includes a third plant that would be ready in 2005. Kulim subsidiary Natoleo Chemical Sdn Bhd in Pasir Gudang currently produces fatty acids, glycerine and esters for food, beverage, beauty and healthcare products. Kulim plans to continue to expand its plantation areas in other countries with lower labour cost and cheaper land prices. The company already has palm oil estates in Indonesia and Papua New Guinea, and will shortly set up one in the Solomon Islands. The Star, 9 Feb 2005 (Website: http://www.thestar.com.my) Malaysian palm oil output For the year 2004 to 2005, Malaysian palm oil production is forecast (by the US Department of Agriculture) to grow to 14.5 M tonnes (+1.1 M 2 APRIL 2005 FOCUS ON SURFACTANTS

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of detergent enzymes in the 1970s toreduce heavy phosphates use in whatwas the first major effort to lessen theenvironmental impact of laundry.

It is encouraging to see a newemphasis on low-temperature laundrywith its energy-saving benefits, but forthe full environmental picture it’simportant to consider water use aswell as that of energy and chemicals.Over the coming years, global watersupply will become an increasingproblem. Reducing waterconsumption by domestic laundry notonly conserves water resources butcan also reduce detergent use and,within limits, improve detergentperformance. In the US, recentfigures from the Energy Dept showthat water use per load is virtuallyunchanged from 20 years ago atabout 150 litres (40-45 gal). In mid-1980s Europe, typical washwaterloads were around 120 litres buttoday’s energy-efficient front-loadingmachines achieve 50-60 litres –‘every little helps’. Reducing energyuse for domestic laundry is good, butto truly minimize its environmentalimpact what we now need is fordetergent manufacturers to work withwashing machine producers, and withlegislators, to encourage reducedwater consumption.

Caroline Edser

RAWMATERIALS

Alpha-olefins

First application of a new process forproducing linear alpha-olefins

Linear alpha-olefins (LAOs) havemany applications as intermediates inthe chemical industry, particularly asa base stock for plastics anddetergents. Linde, in cooperation withSabic of Saudi Arabia, has developeda new technology for selectivecatalytic synthesis of LAOs fromethylene. The alpha-SABLINtechnology can be used to produce awide range (short to long chains) ofhighly pure LAOs with high selectivityand under moderate operatingconditions. The product distribution

can be changed easily by varying thereaction conditions and adjusting thehomogeneous catalyst system. Thetechnology has been testedsuccessfully over several years in apilot plant at the Sabic Research andTechnology Center in Riyadh, SaudiArabia. The first commercial plant isbeing built by Linde for Jubail UnitedPetrochemical Co in Al-Jubail, SaudiArabia. Commercial production willbegin in 2006.

Linde Technology, Dec 2004, 38-45 (Linde AG,Abraham-Lincoln-Strasse 21, 65189 Wiesbaden,Germany. Tel: +49 0611 770 0. Fax: +49 0611 770269. Website: http://www.linde.com)

Profile of linear alpha-olefins in the US

Four plants produce linear alpha-olefins in the US. Total US capacity is5220 M lbs/y. Demand was 3130 Mlbs in 2003, 3200 M lbs in 2004, andis forecast at 3465 M lbs for 2008.Demand growth was 1.5%/y between1999 and 2004, and is forecast at2%/y through 2008. Main uses are inthe manufacture of polyethylene co-monomer 42%, detergent alcohols17% and polyalpha-olefins 12%.

Chemical Market Reporter, 21 Feb 2005 (Website:http://www.chemicalmarketreporter.com)

Oleochemicals

Ultrapar to invest US$94 M in newOxiteno fatty alcohols plant

As reported in the March issue,Brazil’s Ultrapar is planning toconstruct a plant for fatty alcoholsproduction, with co-production of fattyacids (C8 to C18) and glycerine, inthe petrochemical complex ofCamaçari, in the state of Bahia. Thecompany, through its chemicals armOxiteno, will invest approximatelyUS$94 M in the construction duringthe next two years. Fatty alcoholproduction capacity will beapproximately 80,000 tonnes/y, withlauryl alcohol the major product. Themain raw materials to be used are ofnatural origin, such as palm kerneland coconut vegetable oils, whichcan be sourced within the state. Theplant will be a pioneer unit in LatinAmerica for the production of fattyalcohols. These materials arecurrently imported, with 2004 SouthAmerican imports amounting to about50,000 tonnes. Brazil is responsible

for around 90% of this consumptionand Oxiteno is the country’s largestconsumer of fatty alcohols. Oxitenoestimates it will use some 30% of thealcohol output to make its surfactantsproduct lines for personal care,household cleaning, agrochemicals,textile and other applications. Besidesadding value to this existing productline, the new plant is expected togenerate additional net sales ofUS$80 M/y when running at fullcapacity.

Press release from: Oxiteno, Sao Paulo, Brazil.Website: http://www.oxiteno.com.br (16 Feb 2005) &BNAmericas Oil & Gas News, 17 Feb 2005, (BusinessNews Americas Ltda, website:http://www.Bnamericas.com)

Kulim aims for even balance inoperations

Kulim (M) Bhd is in the process ofbalancing its upstream anddownstream operations and hasallotted two years to achieve thispurpose. At present, 65% of Kulim’soperations are upstream operationsagainst 35% downstream. Once theoperations are even, the company’sincome will be stabilized. With boththe operations strengthened, itbelieves it can become one of theleading plantation companies in theregion. Kulim plans to expand itsdownstream activities, especially themanufacture of oleochemicals andrelated by-products. It has investedaround Ringgit 150 M for expansionof oleochemical operations, whichincludes a third plant that would beready in 2005. Kulim subsidiaryNatoleo Chemical Sdn Bhd in PasirGudang currently produces fattyacids, glycerine and esters for food,beverage, beauty and healthcareproducts. Kulim plans to continue toexpand its plantation areas in othercountries with lower labour cost andcheaper land prices. The companyalready has palm oil estates inIndonesia and Papua New Guinea,and will shortly set up one in theSolomon Islands.

The Star, 9 Feb 2005 (Website:http://www.thestar.com.my)

Malaysian palm oil output

For the year 2004 to 2005, Malaysianpalm oil production is forecast (by theUS Department of Agriculture) togrow to 14.5 M tonnes (+1.1 M

2 APRIL 2005

F O C U S O N S U R F A C T A N T S