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    FLARE GASRECOVERY SYSTEMS

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    LIquidLIquidRIngRIng COmpressorCOmpressorStandard SystemStandard System

    GASESGASES

    AcidAcid GasesGases OthersOthers

    H2SH2S NOXNOX CO2CO2 H2 H2 COSCOS CondensableCondensable HCHC mixturesmixtures

    etc.etc.

    APPLICATIONAPPLICATION..

    PROCESSPROCESS RECOVERYRECOVERY

    Topping FlareTopping FlareGasGas FCC Off GasFCC Off Gas VacuumVacuum Steamer Off GasSteamer Off Gas CokingCoking Flash GasFlash Gas

    VisbreakingVisbreaking VOCVOC etc. etc. etc. etc.

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    WHY INSTALL

    A FLARE GASRECOVERY SYSTEM?

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    THE ENVIRONMENTTHE ENVIRONMENT

    Removal of three types of pollution:

    Atmospheric (smoke, SO2, NOx, etc.)

    Light

    Noise

    NB: In many parts of the world continuous flaring is not permitted.

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    THE ECONOMIC ARGUMENTTHE ECONOMIC ARGUMENT

    Consider a typical plant with continuous flaring of 1 ton/h:

    Value of flared gas: 8000 x 1 x $150 = US$ 1,200,000 per year

    First Year Operational Costs (Electricity & Water): = US$ 150,000 (approx)

    Total installed cost of flare gas recovery system: = US$ 700,000 (approx)

    Payback achieved in 8.5 months!

    Subsequent yearly operational savings = US$ 1.050,000!

    For larger systems the payback is shortened!

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    TYPICAL FLARE GAS

    RECOVERY SYSTEM& COMPONENTS

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    FGRS COMPONENTSFGRS COMPONENTS

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    TYPICALTYPICAL FLARE GASFLARE GASRECOVERY SYSTEMRECOVERY SYSTEM

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    THECOMPRESSOR

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    TYPES OF COMPRESSORTYPES OF COMPRESSORGenerally three types of compressor have been used for flare

    gas recovery systems:

    Reciprocating, screw and liquid ring

    Reciprocating and screw type compressors are more efficient

    but they are also more expensive, require more maintenance

    and downtime, result in compressed gases being at high

    temperature and are not tolerant to condensates being present

    in the gas.

    For flare gas recovery liquid ring compressors have many

    advantages.

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    ADVANTAGESADVANTAGESOFOF

    LIQUID RING COMPRESSORSLIQUID RING COMPRESSORS

    Liquid ring compressors are generally the best to use for flare

    gas recovery systems for the following reasons:

    Able to handle gases containing condensates

    Able to handle gases containing particulates

    Able to handle wet gases

    Able to handle toxic, flammable and corrosive gases

    Works without lubricants

    Gas temperature rise is low - 10OC

    Because of liquid ring, compressors are inherently safe

    System tolerates sudden gas and condensate surges

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    DESIGN BASISDESIGN BASIS

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    TYPICAL LIQUID RING VACUUM PUMPTYPICAL LIQUID RING VACUUM PUMP

    Radial Forces

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    THE GARO DESIGNTHE GARO DESIGN

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    THE GARO DESIGNTHE GARO DESIGN

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    GARO is the preferred supplier of liquid ring compressors due to many

    technical advantages.

    Double lobe casing to balance radial pressures acting on overhung

    impeller with a single mechanical seal.

    Noise is dictated by the electric motor

    Reduced vibration levels give bearingsa longer life

    Potential leakage point with

    atmosphere reduced to one mechanicalseal

    The mechanical seal is the onlycomponent subject to wear and is easilyreplaced.

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    FRONT PULL OUTFRONT PULL OUT

    Fast access to compressor

    internals without putting the

    machine in vertical position.

    Lower power consumption

    DISTRIBUTION CONEDISTRIBUTION CONE

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    CONE & IMPELLER ALIGNMENTCONE & IMPELLER ALIGNMENT

    Easy checking of internalclearances without any need toopen the machine (two spannersand a dial gauge are all thatsrequired)

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    The GARO machines are customengineered to meet process

    requirements. Dimensional changes to

    internal components alter the

    machines operational capability.

    Each size of compressor can be

    adjusted to vary pressures, flow rates

    and power consumption within a range.This optimizes performance in relation

    to the required conditions of service.

    Post supply process changes can oftenbe accommodated without the need to

    replace the machine.

    Casing

    Impeller

    Cone

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    CROSS SECTIONCROSS SECTION

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    TYPICAL LIQUID RING COMPRESSORTYPICAL LIQUID RING COMPRESSOR

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    MAINTENANCE

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    EASY MAINTENANCEEASY MAINTENANCE

    OVERHUNG IMPELLEROVERHUNG IMPELLER

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    EASY MAINTENANCEEASY MAINTENANCE

    OVERHUNG IMPELLEROVERHUNG IMPELLER

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    OVERHUNG IMPELLEROVERHUNG IMPELLER

    EASY MAINTENANCEEASY MAINTENANCE

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    BETWEEN BEARINGS DESIGNBETWEEN BEARINGS DESIGN

    TRADITIONAL DESIGNTRADITIONAL DESIGN

    Liquid ring compressor AM 850 maintenance costs

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    T he table underneath show s the realm aintenance costs of a single stage G aro's co m pressor A M 850 operating

    D ate C ause Shut dow n in T otal costs in U SD ,

    hours incl. labor costs**

    1 7 .0 8 .89 S ulphur rem o val* fro m filter 1 1 8

    1 4 .0 9 .89 S ulphur rem o val* fro m filter 1 3 8

    18.10.89 Sulphur rem oval* fro m filter, pipe and 1 2 3 0 0

    valve upstream filter.

    0 7 .1 1 .89 N ew filter installed* 4 8 * * * 4 .9 0 0

    1 9 9 0 - - -

    0 3 .0 6 .91 M ech. seal rings 8 1 .3 3 01 6 .1 0 .91 S et o f bearings 1 2 * * * 1 .5 4 3

    0 5 .0 5 .9 2 M ech. seal gaskests 8 1 7 0

    1 6 .1 1 .9 2 N ew filter cartridge 4 9 1 3

    1 9 9 3 - - -

    2 6 .0 1 .9 4 C o m plete m ech. seal 1 2 * * * 2 .1 4 8

    0 9 .0 2 .9 5 R ing + gaskets o f m ech. seal 8 1 .4 5 0

    2 1 .0 2 .9 5 R efitting due to w ro ng assem bly 4 1 9 02 0 .0 8 .9 5 S et o f bearings 1 2 * * * 1 .6 8 0

    1 9 9 6 - - -

    1 2 .0 2 .9 7 M ech. seal 8 3 .2 8 5

    2 6 .0 5 .9 7 N ew filter cartridge 4 1 .3 6 1

    1 9 9 8 - - -

    T otal U SD 19.326

    *In 1989 the refinery plant started refining crude oil w ith high sulphur content w hich led to frequent filters

    clogging: in N ovem ber 1989 the filter w as rep laced by a self cleaning type.

    **1 U S D = 1 ,071 2 E U R O

    ***D uring general plant shutdow n.

    at a refinery p lant in S annazzaro de B urgund i, P avia -Italy- from 1989 up to 1998.

    (C o st calcu latio n m eth o d : fro m 17.08.89 u n til 31.12.98 = 112 m o n th s. 19.326/ 112 x12= 2.070 U S D p er y ear.)

    U S D 2.070A verage annual cost:

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    FLARE SAFETY

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    P1 = 0.03 bar g

    1000 m3/h

    0 am3/h

    1 0 0 0

    m

    3 / h

    P2= 0.02 bar g

    P3 = 0.01 bar g

    P T

    1000 m3/h

    1000 m3/h

    NO BY- PASS REQUIRED

    Pilots Only

    NORMAL OPERATIONNORMAL OPERATION

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    P1 = 0.02 bar g

    800 m3/h

    0 am3/h

    8 0 0 m3

    /h

    P2= 0.016 bar g

    P3 = 0.01 bar g

    P T

    1000

    m3/h

    800 m3/h

    BY- PASS OPEN

    Pilots Only

    200 m3/h

    REDUCED GAS FLOWREDUCED GAS FLOW

    NO GAS FLOWNO GAS FLOW

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    P1 = 0,01 bar g

    No gas = 0 m3/h

    0 am3/h

    0 m3 /h

    P2= 0,01 bar g

    P3 = 0,01 bar g

    P T

    1000 m3/h

    0 m3/h

    100% BY- PASS OPEN

    Pilots Only

    1000 m3/h

    PSL

    Shut-down of compressor

    NO GAS FLOWNO GAS FLOW

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    CAPACITIES

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    Vol. capacity ^ P 5 ^ P 7 Mod. Flow power cons.

    in Tonnes / h bar abs bar abs Garo in m 3/h in kW

    Approx. operating conditions

    0,4 - 0,8 x AM 400 400 - 800 88

    x AB 600 " 107 1200 - 1800 RPM 71 k W - 143 k W Inle t Pr es s. 1 bar abs

    0,8 - 1,1 x AM 800 800 - 1100 140 Inlet Tem p. 20 -40 Cx AB 850 " 170 1300 - 1600 RPM 143 kW - 197 kW

    Cooling water 30 - 35 C

    1,1 - 1,4 x AM 1100 1100 - 1400 185

    x AB 1100 " 280 1100 - 1400 RPM 197 kW - 251 kW Frequency 50 Hz

    1,4 - 2,0 x AM 1500 1400 - 2000 251 Mol. Weight 15-45 Kg/kmol.

    x AB 1500 " 305 900 - 1200 RPM 251 kW - 359 kW

    2,5 - 3,0 x AM 2500 2500 - 3200 444

    x C 250-6,3 X/SP " 538 800 - 980 RPM 420 kW - 568 kW

    *** 4,0 - 5,0 AM/AB 5000 4000-7500 660 - 1200 RPM 430 - 620 Kw *** Double support compressor

    System Single or duoble stage Garo compressor ( mech.seals, flushing system, couplings, baseframe )

    Garo basic scope of supply as per enclosed annexe 1

    Execution: All parts in carbon steel.

    Compressor in 316 and other parts in carbon steel ( for H2S )

    Other materials required ( S.S., Duplex etc. )

    NOTES 1) Garo AB 600-850-1500 can reach 14 bar abs

    2) Different eccentricity of the impeller and cone can change performances for each GARO COMPRESSOR TYPE

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    AM=Single Stage AB=Double stage

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    PLOT SIZE

    PLOT SIZE

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    PLOT SIZEPLOT SIZE

    TWO COMPRESSOR SYSTEMTWO COMPRESSOR SYSTEM G AG A

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    TWO COMPRESSOR SYSTEMTWO COMPRESSOR SYSTEMG.A.G.A.

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    REFERENCESFLARE GAS RECOVERY

    REFERENCE LIST FOR FLARE GAS &REFERENCE LIST FOR FLARE GAS &

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    REFERENCE LIST FOR FLARE GAS &REFERENCE LIST FOR FLARE GAS &

    HYDROCARBONS RECOVERYHYDROCARBONS RECOVERY SYSTEMSSYSTEMS

    1986/1992 AGIP PETROLI, SANNAZZARO DE BURGONDI REFINERY (PV) - ITALYThree liquid ring compressors type AM 850 each handling 850 m^3/h of flare gas from 1 to 4 bar abs

    1996 ISAB PRIOLO, COOGENERATION PLANT ERG PETROLI, PRIOLO (SR) - ITALYOne liquid ring compressor type AB 1500 handling 1400 m^3/h of flare gas from 1 to 7 bar abs

    1997 AGIP PETROLI, GELA REFINERY (CL) - ITALYFour liquid ring compressors type AB 2500 (former C250-X/SP) each handling 2700 m^3/h of flare gas

    from 1 to 6,5 bar abs

    1997 AGIP PETROLI, TARANTO REFINERY - ITALYOne liquid ring compressor type AM 2500 handling 2700 m^3/h of flare gas from 1 to 3,8 bar abs

    1997 SARAS, SARROCH REFINERY (CA) - ITALYTwo liquid ring compressors type AB 850 each handling 900 m^3/h of flare gas from 1 to 7 bar abs

    1998 ITALIA ENERGIA E SERVIZI (I.E.S.), MANTOVA REFINERY - ITALYOne liquid ring compressor type AB 850 handling 900 m^3/h of flare gas from 1 to 7 bar abs

    1999 ERG PETROLI, PRIOLO GARGALLO REFINERY, PRIOLO (SR) - ITALYOne liquid ring compressor type AM 1500 handling 1600 m^3/h of flare gas from 1 to 4 bar abs

    2000 SHELL, DOCK SUD, AVELLANEDA - ARGENTINATwo liquid ring compressors type AB 850 IX each handling 600 m^3/h of flare gas from 1 to 8 bar abs

    2000 SNP PETROM BRANCH PETROBRAZI BRAZI PRAHOVA ROMANIA

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    2000 SNP PETROM BRANCH PETROBRAZI, BRAZI PRAHOVA - ROMANIAOne liquid ring compressor type AM 2500 handling 2800 m^3/h of flare gas from 1,05 to 4,05 bar abs

    2001 LION OIL, EL DORADO, ARKANSAS - U.S.A.Seven liquid ring compressors type AB 1100 each handling 1200 m^3/h of flare gas from 1,05 to 7,5 bar abs

    2001 ADCO, SAHIL - UNITED ARAB EMIRATESOne liquid ring compressor type AB 850 IX handling 450 m^3/h of flare gas from 1 to 6,5 bar abs

    2001 REPSOL YPF, ESCOMBRERAS, CARTAGENA - SPAIN

    One liquid ring compressor type AB 850 handling 950 m^3/h of flare gas from 1,05 to 7,5 bar abs

    2001 CONOCO REEFINERY, PONCA CITY, OKLAHOMA U.S.A.Three liquid ring compressor type AB 1500 handling 1820 m^3/h of flare gas from 1,08 to 6,85 bar abs

    2001 R.A.M. RAFFINERIA DI MILAZZO (ME) - ITALYOne liquid ring compressor type AB 2500 (former C250-X/SP) handling 2300 m^3/h of flare gas from

    1 to 7,85 bar abs

    2001 REPSOL YPF PETRONOR, REF. DE SOMORROSTRO, BILBAO SPAINOne liquid ring compressor type AB 850 handling 900 m^3/h of flare gas from 1 to 8 bar abs

    2001 STATOIL, MONGSTAD REFINERY - NORWAYTwo liquid ring compressors type AB 2500 (former C250-X/SP) each handling 2600 m^3/h of flare gas

    from 1 to 5 bar abs

    2001 BP OIL, CASTELLON - SPAINOne liquid ring compressor type AB 1500 handling 1450 m^3/h of flare gas from 1 to 7, 5 bar abs(from different flare)

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    2002 SHELL OIL CO. PORT ARTHUR, TX - U.S.A.Four liquid ring compressors type AB 1500 each handling 1500 m^3/h of flare gas from 1 to 8 bar abs

    2002 SHELL OIL CO. NORCO, LA - U.S.A.Three liquid ring compressors type AB 1500 each handling 1500 m^3/h of flare gas from 1 to 8 bar abs

    2002 SHELL OIL CO. CONVENT, LA - U.S.A.

    Four liquid ring compressors type AB 1500 each handling 1500 m^3/h of flare gas from 1 to 8 bar abs

    2002 SHELL OIL CO. DEER PARK, TX - U.S.A.Five liquid ring compressors type AB 1500 each handling 1500 m^3/h of flare gas from 1 to 8 bar abs

    2002 CARMEL OLEFINS - ISRAELTwo liquid ring compressorstype AB 600 each handling 570 m^3/h of flare gas from 1,1 to 9 bar abs

    2002 AGIP ECUADOR EPSS VILLANOTwo liquid ring compressors type AB 600 each handling 720 m^3/h of flare gas from 1,2 to 6,5 bar abs

    2002 RELIANCE INDUSTRIES LIMITES INDIAOne liquid ring compressor type AB 1500 handling 3600 m^3/h of flare gas from 1,1 to 8 bar abs

    2003 REPSOL YPF PETROLEO RAFFINERIA DE PUERTOLLANO SPAINTwo compression systems each with four liquid ring compressors type AB 1500 each handling 1650 m^3/h

    of flare gas from 0,95 to 7 bar abs

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    GAS WASHING

    6

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    1

    2 3 4

    5

    6

    1. Sour gas

    2. Regenerated amine

    3. Skimmed hydrocarbons4. Semi-rich amine to be sent to a medium pressure absorber or to regenerator

    5. Regenerated amine to the final clean up column

    6. Sweet gas to fuel gas network

    FLARE GAS RECOVERY INTEGRATEDFLARE GAS RECOVERY INTEGRATED SYSTEMSYSTEM

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    EQUIPPEDEQUIPPEDWITHWITH LIQUIDLIQUIDRINGRING COMPRESSORCOMPRESSOR

    Process water

    M edium pressure absorber

    Slop

    Blow Down

    Fuel gas

    Am ine washing unit

    SW S treatm ent

    Cooling water

    Am ine regeneration unit

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    LIQUID RINGCOMPRESSOR

    APPLICATIONS

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    Main applicationsMain applications Chlorine (wet and dry)

    Vinyl Chloride Monomer

    Ethylene Flare and vent gases (any kind)

    Carbon monoxide / dioxide

    Hydrogen

    Hydrogen sulphide

    Nitrogen oxides

    Hydrochloric acid

    Ethylene dichloride

    Typical Applications

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    A P P LIC A T IO N G A S H A N D LE D S E R V IC E LIQ U ID

    V inyl A cetate E thylene (R ecovery) A cetic A cidP V C V C M (R ecovery) W ater

    P ulp & P aper W et C hlorine W ater

    P ulp & P aper C O 2 (R ecovery) W ater

    C hlorine D ry C hlorine S ulphuric A cid

    S ugar C O 2 W ater

    S ugar C H 4 W ater

    H 2O 2 H 2 (R ecovery) S olvent (U hde)

    H 2O 2 H 2 (R ecovery) W ater

    E D C D ry C hlorine S ulphuric A cid

    E D C E D C (R ecovery) E D C

    E D C V ent G ases (C O 2) C entrifugal

    T iO 2 D ry C hlorine S ulphuric A cid

    V C M V ent G ases (C 2H 4) E D C

    A dipic A cid N O x N itric A cid & w ater

    F ertiliser N O x N itric A cid & w ater

    C aprolactam N O x N itric A cid & w ater

    E xplosives N O x N itric A cid & w ater

    N 2 N O x N itric A cid & w ater

    H C l H C l S ulphuric A cid

    N uclear P ow er H 2S W ater

    O lefins B F 3 (B oron F luoride) X ylols

    P olyolefins O lefins W ater

    E nergy R ecovery (R e finery) B low D ow n G ases W ater/G asoline

    D esalination C O 2 W ater

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    REFERENCESGENERAL APPLICATIONS

    GENERAL REFERENCE LISTGENERAL REFERENCE LIST

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    GENERAL REFERENCE LISTGENERAL REFERENCE LIST

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