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<ul><li><p>AGRICULTURE HOME ECONOM ICS 4-H DEVELOPM E NT</p><p>U N I V E R S I T Y O F K E N T U C K Y C O L L E G E O F A G R I C U L T U R E</p><p>C O O P E R A T I V E E X T E N S I O N S E R V I C E</p><p>FOR-58</p><p>OSHA Hazard Communication Standard:OSHA Hazard Communication Standard:OSHA Hazard Communication Standard:OSHA Hazard Communication Standard:OSHA Hazard Communication Standard:EmploEmploEmploEmploEmployyyyyeeeeeeeeees Right to Knos Right to Knos Right to Knos Right to Knos Right to Knowwwww</p><p>James E. Reeb, Extension Specialist, Department of Forestry</p><p>he Hazard Communications Standard is designed to inform and train employees in the proper recognition,use, and handling of hazardous chemicals and products.Written by the Occupational Safety and HealthAdministration (OSHA), it is also known asEmployees Right to Know. It covers both physicalhazards, such as flammability, and health hazards, suchas irritation, lung damage or cancer. The substancescovered under this standard include many that are usedat a typical logging site and in a typical wood productsmill.</p><p>Mandatory compliance began in 1988. In order tocomply, a company must prepare a written hazardcommunication plan, maintain a current inventory ofhazardous chemicals or products at the workplace, andlabel containers of hazardous chemicals or products.Material Safety Data Sheets (MSDSs) must be readilyaccessible to employees at each work site and duringeach work shift. The regulations apply to any chemicalthat is known to be present in the workplace and that anemployee may be exposed to under normal conditions ofuse or in a foreseeable emergency.</p><p>TTTTThe MSDS - Manhe MSDS - Manhe MSDS - Manhe MSDS - Manhe MSDS - Manufufufufufacturacturacturacturacturer'ser'ser'ser'ser'sResponsibilityResponsibilityResponsibilityResponsibilityResponsibility</p><p>The MSDS is a source of detailed information on achemical or product and provides information of thehazards associated with that chemical or product.Chemical manufacturers, importers, and distributors ofhazardous chemicals are required to provide theappropriate labels on their products. Manufacturers anddistributors of these products must also furnishcustomers with MSDSs, at the time of the initialshipment or when information on the MSDS changes,for each hazardous substance or product. Therefore, themanufacturer, and not the user, is responsible fordeveloping an MSDS for any product containing ahazardous chemical.</p><p>The employer who uses these hazardous substances orproducts is responsible for maintaining current MSDSs andhaving them readily accessible to employees. The MSDSs</p><p>must be located close to the employees and must beavailable during each workshift.</p><p>Information on an MSDSInformation on an MSDSInformation on an MSDSInformation on an MSDSInformation on an MSDSA sample MSDS for unleaded gasoline has been</p><p>provided as an example (see Figure 1). However, thereis no set format for producing MSDSs as long as certaininformation is provided. In some instances, this hascaused confusion, and as a result, a set format forproducing MSDSs has been suggested.</p><p>The Chemical Manufacturers Association (CMA) andthe American National Standards Institute (ANSI) spentthe last four years developing a standard for improving thepreparation of MSDSs. The OSHA CommunicationStandards allow MSDSs to be presented in any format aslong as the following minimal information requirementsare met:</p><p>11111) Chemicals name22222) Chemical Abstracts Service Registry Number33333) Hazardous physical and chemical characteristics44444) Any known acute or chronic health effects.</p><p>This unstructured format has created problems foremergency response personnel who did not know wherecertain information might be located on the MSDS. Thestandard being developed by the CMA for certification byANSI provides a logical and internally consistent structure forMSDSs. If the standard is followed, users of the data sheetswill always be able to find the information they need in thesame place on every sheet. The proposed MSDS structure isdetermined by a sequence of four questions with correspond-ing sections.</p><p>The proposed format is:</p><p>11111) What is the material, and what do I need to knowimmediately in an emergency?Section 1. Chemical Product and Company IdentificationSection 2. Composition and Information on IngredientsSection 3. Hazards Identification</p><p>22222) What should I do if a hazardous situation occurs?Section 4. First-Aid MeasuresSection 5. Fire-Fighting MeasuresSection 6. Accidental Release Measures</p><p>33333) How can I prevent hazardous situations from occur-</p><p>T</p></li><li><p>ring?Section 7. Handling and StorageSection 8. Exposure Controls - Personal ProtectionSection 9. Physical and Chemical PropertiesSection 10. Stability and Reactivity44444) Is there any other useful information about this</p><p>material?Section 11. Toxicological InformationSection 12. Ecological InformationSection 13. Disposal ConsiderationsSection 14. Transport InformationSection 15. Regulatory InformationSection 16. Other InformationHowever, there is no set standard for preparing</p><p>MSDSs yet.</p><p>Preparing and Implementing aPreparing and Implementing aPreparing and Implementing aPreparing and Implementing aPreparing and Implementing aHazard Communication ProgramHazard Communication ProgramHazard Communication ProgramHazard Communication ProgramHazard Communication Program</p><p>The MSDSs can form the basis of a companysHazard Communication Program. All workplaces whereemployees are exposed to hazardous chemicals must havea written plan that describes how the standard will beimplemented in that facility. Employers must establish atraining and information program for employees in theirwork area at the time of initial assignment and whenever anew hazard is introduced into their work area. Outsidecontractors who work at the facility must also be informedof hazardous chemicals or products. The written plan mustdescribe how a contractor will be provided with copies ofMSDSs, what precautionary measures the contractor needsto take for himself or his employees during normaloperations or foreseeable emergencies, and how thecontractor will be notified of the labeling system in use.</p><p>InformationInformationInformationInformationInformationAt a minimum, the discussion topics for employees</p><p>must include the following:</p><p>11111) The location of the Hazard CommunicationStandard and the requirements of the standard.</p><p>22222) The components of the companys program.33333) Operations in work areas where exposure to</p><p>hazardous chemicals or products may occur.44444) The location of hazardous chemicals and the</p><p>required MSDS forms.55555) The names and phone numbers of contact persons.66666) Emergency procedures.77777) Inventory list of hazardous chemicals and products.</p><p>TrainingTrainingTrainingTrainingTrainingThe employee training plan must consist of the</p><p>following elements:11111) How the hazard communication program is</p><p>implemented in that workplace, how to read and interpretinformation on labels and the MSDSs, and how employeescan obtain and use the available hazard information.</p><p>22222) The hazards of the chemicals in the work area. Thehazards may be discussed by individual chemical or byhazard categories such as flammability.</p><p>33333) Measures employees can take to protect themselvesfrom the hazards.</p><p>44444) Specific procedures that the employer has put intoeffect to provide protection, such as engineering controls,work practices, and the use of personal protective equipment.</p><p>55555) Methods and observations, such as visual appear-ance or smell, that workers can use to detect the presenceof a hazardous chemical to which they may be exposed.</p><p>Other FOther FOther FOther FOther Forororororms of ms of ms of ms of ms of WWWWWarararararningningningningningPesticides labeled in accordance with the Federal</p><p>Insecticide, Fungicide and Rodenticide Act and regula-tions issued by the Environmental Protection Agencycomply with OSHAs Hazard Communication Standard.The same is true for products labeled in agreement withregulations of the Food and Drug Administration and forconsumer products labeled in accordance with regulationsof the Consumer Product Safety Act.</p><p>OSHA allows some exemptions to its in-plantindividual container labeling requirement. For a group ofstationary containers within a work area that have similarcontents and hazards, employers may post signs thatconvey the hazard information rather than label individualcontainers.</p><p>Employers do not have to label portable containers ofhazardous chemicals or products transferred from theiroriginal containers if used immediately by the employeewho made the transfer. Do not allow any left-over sub-stances to remain in unlabeled containers.</p><p>All labels must be legible at all times. Replacedestroyed or difficult-to-read labels immediately.</p><p>Hazardous CommunicationHazardous CommunicationHazardous CommunicationHazardous CommunicationHazardous CommunicationChecklistChecklistChecklistChecklistChecklist</p><p>This checklist will help maintain compliance with theHazard Communication Standard.</p><p> List all of the hazardous chemicals or products inthe work place.</p><p> Establish a file for information on hazardouschemicals or products.</p><p> Obtain an MSDS for each hazardous chemical orproduct in use or stored on site.</p><p> Develop a system to ensure the labeling of allincoming hazardous chemicals or products.</p><p> Review each MSDS for completeness. Ensure that MSDSs are readily available. Write a Hazard Communication Plan. Develop a method for communicating hazards to</p><p>employees and to others. Inform employees of protective measures for</p><p>hazardous chemicals or products used in the workplace. Alert employees to other appropriate forms of warning.</p><p>2</p></li><li><p>HoHoHoHoHow Can I Obtain MSDSs?w Can I Obtain MSDSs?w Can I Obtain MSDSs?w Can I Obtain MSDSs?w Can I Obtain MSDSs?As an employer, you may have hazardous chemicals</p><p>or products at the job site but not their MSDSs. In thatcase, MSDSs can usually be obtained from the retail orwholesale outlet where you purchased the chemicals. Ifthey are not available, you may obtain them by writingdirectly to the company listed on the package label. Youmay want to use the following as a suggested format whenwriting:</p><p>SugSugSugSugSuggggggested Letter Fested Letter Fested Letter Fested Letter Fested Letter Fororororormamamamamat ft ft ft ft forororororObtaining an MSDSObtaining an MSDSObtaining an MSDSObtaining an MSDSObtaining an MSDS</p><p>(Your Return Address)(Date)</p><p>(Name and Address of Chemical Manufacturer as listed on container label)</p><p>Dear Manufacturer:</p><p>In accordance with requirements of the OSHA Hazard Communication Standard, (your company)maintains Material Safety Data Sheets on all hazardous chemicals used in our operations. Pleaseprovide us with current copies of the Data Sheets for these materials.</p><p>(List chemicals.)</p><p>Sincerely,</p><p>Your Title</p><p>Note: Keep a copy of the letter in your files. This does not take the place of an MSDS but will show an OSHAinspector that you are attempting to comply.</p><p>3</p></li><li><p>MATERIAL SAFETY DATA SHEETMATERIAL SAFETY DATA SHEETMATERIAL SAFETY DATA SHEETMATERIAL SAFETY DATA SHEETMATERIAL SAFETY DATA SHEET(Training Purposes Only)(Training Purposes Only)(Training Purposes Only)(Training Purposes Only)(Training Purposes Only)</p><p>PRODUCT NAME: JOHN DOE UNLEADED GASOLINEPRODUCT CODE NO: 00600_ Issue Date 8/10/91 PAGE 1 of 5</p><p>MANUFACTURER:MANUFACTURER:MANUFACTURER:MANUFACTURER:MANUFACTURER: Transportation Emergencies:Transportation Emergencies:Transportation Emergencies:Transportation Emergencies:Transportation Emergencies:Call CHEMTREC</p><p>John Does Refining &amp; Marketing Division (800) 424-XXXX Cont. U.S.Morgan Oil Company of California (202) 483-XXXX (Collect)100000 W. 9th Avenue from Alaska &amp; HawaiiMorgantown, California 80017 Health Emergencies:Health Emergencies:Health Emergencies:Health Emergencies:Health Emergencies:</p><p>Call John Does PoisonContact for further information: Information Center (24 hrs.)MSDS Coordinator (213) 977-XXXX (304) 001-XXXX</p><p>PRODUCT IDENTIFICATIONPRODUCT IDENTIFICATIONPRODUCT IDENTIFICATIONPRODUCT IDENTIFICATIONPRODUCT IDENTIFICATION</p><p>Product Name: XXX Unleaded Gasoline</p><p>Synonyms: XXX Unleaded Gasoline</p><p>Generic Name: Unleaded Gasoline</p><p>Chemical Family: Petroleum Hydrocarbon Mixture</p><p>DOT Proper Shipping Name: Gasoline</p><p>ID Number: UN1203</p><p>SECTION I - INGREDIENTSSECTION I - INGREDIENTSSECTION I - INGREDIENTSSECTION I - INGREDIENTSSECTION I - INGREDIENTS TLV UNITSTLV UNITSTLV UNITSTLV UNITSTLV UNITS AGENCYAGENCYAGENCYAGENCYAGENCY TYPETYPETYPETYPETYPE</p><p>Gasoline 300.00 PPM ACGIH Full Term TWA</p><p>Benzene 10.00 PPM OSHA Full Term TWA</p><p>Gasoline is a complex combination of hydrocarbons, including a small quantity of benzene. The identities ofingredi- ents that are trade secrets are excluded from this list.</p><p>SECTION II - EMERGENCY FIRST AID PROCEDURESSECTION II - EMERGENCY FIRST AID PROCEDURESSECTION II - EMERGENCY FIRST AID PROCEDURESSECTION II - EMERGENCY FIRST AID PROCEDURESSECTION II - EMERGENCY FIRST AID PROCEDURES ***EMERGENCY******EMERGENCY******EMERGENCY******EMERGENCY******EMERGENCY***Have physician call John DoesPoison Information Center (24 hrs.) (304) 001-XXXX</p><p>EYE CONTACT:</p><p>For direct contact, flush the affected eye(s) with clean water. If irritation or redness develops, seek medicalattention.</p><p>SKIN CONTACT:</p><p>Wipe material from skin and remove contaminated clothing. Cleanse affected area(s) thoroughly by washing withsoap and water. If irritation or redness develops and persists, seek medical attention.</p><p>INHALATION (Breathing):</p><p>If symptoms of exposure develop (see Section III), move away from source of exposure and into fresh air. If symp-toms persist, seek medical attention. If victim is not breathing or if breathing difficulties develop, artificialrespiration or oxygen should be administered by qualified personnel. Seek immediate medical attention.</p><p>4</p></li><li><p>SECTION II - EMERGENCY AND FIRST AID PROCEDURESSECTION II - EMERGENCY AND FIRST AID PROCEDURESSECTION II - EMERGENCY AND FIRST AID PROCEDURESSECTION II - EMERGENCY AND FIRST AID PROCEDURESSECTION II - EMERGENCY AND FIRST AID PROCEDURES ***EMERGENCY******EMERGENCY******EMERGENCY******EMERGENCY******EMERGENCY*** (cont'd)(cont'd)(cont'd)(cont'd)(cont'd) Have physician call John Does Poison</p><p>Information Center (24 hrs.) (304) 001-XXXX</p><p>INGESTION (Swallowing):</p><p>***ASPIRATION HAZARD: Do not induce vomiting because gasoline can enter lungs and cause severe lungdamage.***If victim is conscious and alert, give 2 to 3 cups of milk or water to drink. Seek medical attention. Tophysician: Emesis or lavage is not recommended for ingestions of minute quantities or tastes of most hydrocarbons.Medical opinion is divided for larger ingestions. Emesis or lavage has been recommended for those petroleum productswhich have a high oral toxicity. Gastric lavage with a cuffed endotracheal tube is recommended by some physicians to preventaspiration.</p><p>SECTION III - POTENTIAL ADVERSE HEALTH EFFECTSSECTION III - POTENTIAL ADVERSE HEALTH EFFECTSSECTION III - POTENTIAL ADVERSE HEALTH EFFECTSSECT...</p></li></ul>

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