for b.sc chemistry (general), part- i by dr. kakoli banerjee department of chemistry
TRANSCRIPT
RADIOACTIVITY
For B.Sc Chemistry (General), Part- I
By
Dr. Kakoli Banerjee
Department of Chemistry
Aims and Objectives
Definition of Radioactivity Discovery of Radioactivity- The Pioneers Cause of Radioactivity- Nuclear Instability Discussion on the three most important
types of emissions- Effects of α, β and γ rays
Radioactive decay & half-life Nuclear Reactions- Fission & Fusion Where is Radioactivity encountered? Hazards of Radioactivity
Radioactivity- A spontaneous phenomenon
A natural and spontaneous process by which the unstable atoms of an element emit or radiate excess energy in the form of particles or waves
After emission the remaining daughter atom can either be a lower energy form of the same element or a completely different element
The Pioneers Roentgen:
(Discoverer of X-rays 1895)
Becquerel:
(Discoverer of Radioactivity 1896) Rutherford:
(Discoverer Alpha and Beta rays 1897)
The Curies:
(Discoverers of Radium and Polonium 1900-1908)
n/p ratio in stable isotopes
Comparison between types of radiation
Radioactive Kinetics-1st order reaction
Radioactivity or decay rate A is the rate of disintegration of nuclei. Initially (at t = 0), we have No nuclei, and at time t, we have N nuclei. This rate is proportional to N, and the proportional constant is called decay constant .
dNA = – ––––– = N Integration gives
d t
ln N = ln No – t or N = No e – t
Units of Radioactivity
The curie (Ci): The activity of a radioactive substance is said to be one curie if it undergoes 3.7 x 1010 disintegrations per second
1 curie = 3.7 x 1010 disintegrations / second
The rutherford (Rd): The activity of a radioactive substance is said to be one rutherford if it undergoes 106 disintegrations per second
1 rutherford = 106 disintegrations / second
The becquerel (Bq): The activity of a radioactive substance is said to be one becquerel if it undergoes 1 disintegration per second
1 becquerel = 1 disintegration / second
The half-life (t½) of a radioactive substance, is the time required for one half of it to decay
When N = No / 2 , t = t ½ So t ½ = 0.693 /
After 5 lifetimes more than 99% of the initial particles have decayed away!
Packing Fraction & Nuclear Binding Energy Mass Defect, Δm = [ Zmp + (A – Z) mn ] - M
The difference between the rest mass of the nucleus and the sum of the masses of the nucleons composing a nucleus is known as mass defect
Mass defect per nucleon is called Packing Fraction
Binding Energy, B.E = Δm c2
It is the energy required to break up a nucleus into its constituent parts and place them at an infinite distance from one another
Sources of Radioactivity Primordial - from before the creation of the Earth radioisotopes
34 primordial radionuclides represent isotopes of 28 separate elements.-Cadmium,tellurium, neodymium and uranium
Cosmogenic - formed as a result of cosmic ray interactions
tritium, carbon-14 and phosphorus-32
Human produced - enhanced or formed due to human actions (minor amounts compared to natural)
Nuclear reactor - thallium-201 and iridium-192 Radionuclide generators- technetium-99m generator
used in nuclear medicine
Nuclear Fission Vs Fusion
Application & Hazards of Radioactivity
Ionizing radiation can damage living tissue in the human body. It strips away electrons from atoms breaks some chemical bonds.
Uses of Radioactivity Preservation of food grains and seeds
Some of the isotopes are used in the treatment of cancer
Some of the isotopes are used to study the proper functioning of internal organs.
Gamma radiations are used to sterilize the surgical instruments.
Radio phosphorous is used for studying the rate of phosphorous assimilation by the plant.
Radiocarbon Dating