fuel utilization in flexible industrial gas turbines larfeldt ffw kaust 2016...the airflow including...
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Thuwal, 8th of March 2016
Fuel Utilization in Flexible Industrial Gas TurbinesJenny Larfeldt
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Introduction to industrial gas turbines
Compressor
Stationary gas turbines are continuously flowed through fixed-drive machines withhigh power densities, meaning that they deliver a large amount of energy in relationto their size and weight.The combustion process takes place at a pressure generated by the compressor andthe airflow including the products of combustion (and excess air) is then delivered tothe turbine which drives the compressor as well as generating power to thegenerator or other external equipment depending on application.
Combustor
Turbine
20 bar693K
SGT-800 50MWel
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Gas Turbine Fuel Flexibility forEnvironmental Protection and Plant Profitability
About 140 billion cubicmeters of associated gas areestimated as flared or ventedannually. This is equivalent toalmost a third of the EU’s gasconsumption. Reducing CO2emissions from flaring wouldequal taking 70 million carsoff the road.
Use “waste” gas streams inchemical plants for increasedprofitability. For instanceethane, propane andhydrogen rich gases.
Improve availability byavoiding complex andexpensive fuel treatmentequipment.
Intermittent production ofpower from growing shareof renewables leads tostoring demands.Converting wind power toH2 (P2G) and potentiallyback to power or feed H2directly in natural gas grid.
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0
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Wo
bbe
Inde
x[M
J/N
m3]
Lower Heating Value [MJ/kg]
Industrial gas turbine gaseous fuel map
Fuel testing NG with;1. Nitrogen 50 vol%2. Pentane 23 vol%3. Ethane 100 vol%4. Hydrogen 20 - 40 vol%
1
2 3
4
Heavyhydrocarbons
High H2
Standard range NG WI: 42 to 53 MJ/nm3
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The key performance of an industrial gas turbinecombustor
- High-combustion efficiency (i.e. the fuel should be completely burned so that allits chemical energy is liberated as heat).
- Low pressure loss.- An outlet temperature distribution (pattern factor) that is tailored to maximize
the lives of the turbine blades and nozzle guide vanes.- Low emissions of smoke and gaseous pollutant species- Freedom from pressure pulsations and other manifestations of combustion-
induced instability- Wide stability limits (i.e., the flame should stay alight at pressures and air/fuel
ratios corresponding to the whole gas turbine operating range).- Fuel flexibility.- Design for minimum cost and ease of manufacturing.- Size and shape compatible with engine envelope.- Maintainability.- Durability.- Reliable and smooth ignition at the ambient conditions of relevance for an
industrial gas turbine.Lefebvre and Ballal, “Gas turbine Combustion – Alternative Fuels and Emissions”, 2010.
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The key performance of an industrial gas turbinecombustor
- High-combustion efficiency (i.e. the fuel should be completely burned so that allits chemical energy is liberated as heat).
- Low pressure loss.- An outlet temperature distribution (pattern factor) that is tailored to maximize
the lives of the turbine blades and nozzle guide vanes.- Low emissions of smoke and gaseous pollutant species- Freedom from pressure pulsations and other manifestations of combustion-
induced instability- Wide stability limits (i.e., the flame should stay alight at pressures and
air/fuel ratios corresponding to the whole gas turbine operating range).- Fuel flexibility.- Design for minimum cost and ease of manufacturing.- Size and shape compatible with engine envelope.- Maintainability.- Durability.- Reliable and smooth ignition at the ambient conditions of relevance for an
industrial gas turbine.Lefebvre and Ballal, “Gas turbine Combustion – Alternative Fuels and Emissions”, 2010.
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Combustion in Industrial Gas Turbines 1(3)SGT-800 30 DLE burners in an annular combustor
20 barl 2693K
SGT-800 50MWel
Main gasFilm air holes
Partly premixed pilot gas
Compressor air Burner outlet
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Combustion in Industrial Gas Turbines 2(3)Emissions versus load
0
50
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-5.0 0.0 5.0 10.0 15.0 20.0 25.0 30.0
Load (MW)
CO
UH
Cpp
mat
15%
O2
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NO
Xpp
mat
15%
O2
PFR
%
Below 50% load Full load
SGT-700
CO ppmvd@15UHC ppmvd@15NOx ppmvd@15PFR gas incl purge to oil %
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Combustion in Industrial Gas Turbines 3(3)Emissions versus combustion induced instabilities
Flow andmixture
perturbations
Heat releaseoscillations
Acousticoscillations
Dampingsoftwall
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0
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0 10 20 30 40 50 60 70 80 90
Wo
bbe
Inde
x[M
J/N
m3]
Lower Heating Value [MJ/kg]
Industrial gas turbine gaseous fuel map
Fuel testing NG with;1. Nitrogen 50 vol%2. Pentane 23 vol%3. Ethane 100 vol%4. Hydrogen 20 - 40 vol%
1
2 3
4
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Challenges with high hydrogen fuels:- Flashback due to flame speed
2014-08-02 Author / DepartmentPage 11
0vol% H2 30vol% H2
60vol% H2 100vol% H2
Flame position at various hydrogen content in natural gas atatmospheric combustion conditions
Test with singleburner feed showspotential up to40 vol-% H2 intoday standardDLE burner.
Siemens releasedcapability for SGT-800 is today30 vol-% H2.
4
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Ignition delay for straight chained hydrocarbons at 500 °C
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10000
100000
0 1 2 3 4 5 6 7 8
# of carbons
igni
tion
dela
y(m
s)
p = 27 bar; phi = 2.5p = 27 bar; phi = 0.5p = 1 bar; phi = 2.5p = 1 bar; phi = 0.5
Challenges with higher hydrocarbons in fuels:- Flashback due to auto ignition delay time
Page 12
Average residencetime in burner mixingtube ~3-5 ms
2 3
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Challenges with higher hydrocarbons in fuels:- SGT-700 our fleet leader at PDH plant in China
C3H
8
C2H
6
C6+
H2
Power output during 150 days continuous operation
2 3
SGT-700 in mechanical drive
• >5000 OH since start-up 2014
• Propane as fuel during plant start-up
• Waste process gas with variablecomposition during normal operation
• Ethane, propane, but also methane,butanes, alkenes, hydrogen, etc
• NOx emissions below 15 ppm
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Challenges with higher hydrocarbons in fuels:- PDH plant in China fuel detail
Component (mol %)
HydrogenH2 Nitrogen N2
MethaneCH4
EthaneC2H6
EthyleneC2H4
PropaneC3H8
PropyleneC3H6
ButanesC4H10
ButenesC4H8
PentanesC5H12
PentenesC5H10 Others*
Day -21 - - 0,1 0,6 - 99,2 - 0,1 - - - -Day -9 5,7 0,2 21,3 13,3 0,7 57,6 0,8 1,1 0,0 0,0 - -Day 9 - - 0,0 0,9 - 79,9 0,0 18,9 0,2 0,0 0,1 0,1Day 13 - 0,4 0,0 0,9 - 90,5 0,0 6,1 0,3 0,0 0,1 1,7Day 14 - 0,1 - 0,6 - 65,6 0,0 13,8 1,0 0,3 0,2 18,4Day 15 - - 0,0 1,0 - 93,7 0,0 4,9 0,2 0,0 0,1 -Day 15 - 0,1 0,0 0,4 - 62,3 0,0 15,3 1,1 0,3 0,2 20,3Day 34 - - 8,6 56,6 2,6 13,5 0,0 10,7 0,6 0,1 0,1 7,3Day 38 - 0,4 1,3 50,3 1,6 23,3 0,0 20,9 1,1 0,1 0,1 1,0Day 44 - 0,1 12,9 67,0 3,8 13,8 0,0 1,8 0,2 0,0 0,0 0,5Day 49 - 0,0 0,8 16,8 0,5 37,9 1,1 23,3 2,9 0,4 0,6 15,8Day 52 - 0,1 10,7 65,8 3,4 14,9 0,0 3,9 0,4 0,0 0,0 0,8Day 155 9,5 0,0 18,6 51,7 5,7 14,4 0,0 0,1 0,0 - - 0,0Day 157 0,1 0,0 1,5 32,7 1,4 58,9 0,0 3,8 0,2 0,0 0,0 0,4Day 162 4,3 0,2 13,8 56,3 3,5 19,9 0,0 1,1 0,1 0,0 0,0 0,6Day 165 0,6 0,0 16,5 66,7 4,0 11,1 0,0 0,5 0,0 0,0 0,0 0,5Day 173 0,3 0,1 12,1 48,7 2,4 34,3 0,0 1,7 0,1 0,2 0,0 0,2
* C6+, Dienes, Propyne, Acetylene, etc
Commissioning period
2 3
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Challenges with high inert fuels:- LBO … and do not forget the auxiliary system!
Main control valve
Pilot control valve
Fired duty 120 MWth (~50 MWel in SGT-800)Std NG 2,5 kg/sGorzow gas 5,4 kg/s
1
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Extended use of alternative fuels- Margin to LBO and FB
High availability and reliability- Flame position and temperaturedistribution
Reduced emissions- Fuel and species distribution
Higher efficiency- Flame stability and flame interactions
Future needs and challenges for fuel flexibleindustrial gas turbines
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SGT-800 ITM process integration 1(2)DOE DE-FC26-98FT40343 Turbo machinery
2014-08-01Page 17
Membrane
G
Fuel
Oxygen
c3 c5 c8
c6
Fuel
c1
c4
c7
c9
c10
System boundary
Steam Cycle
Stack
s1
s2
s3
s4s5
s6
s8
c2s7
s10
Air
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SGT-800 ITM process integration 2(2)DOE DE-FC26-98FT40343 Turbo machinery
2014-08-01Page 18
FROMITM
FROMITM
TOITM
TOITM
From SGT-800compressor
To SGT-800turbine
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Thank you for your attention
Jenny Larfeldt, PhDCombustor Development
Gas Turbine R&D
Industrial Gas Turbines
SE-612 83 Finspong
Sweden
Phone: +46 [0] 122 827 89
E-mail:[email protected]