gas chr omatography - axial scientific · gas chr omatography popular gc packed columns........

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Gas Chr Gas Chr omatogr omatogr aph aph y y Popular GC Packed Columns .............................................................................. 122-123 CTR Columns ........................................................................................................... 124 Pretested GC Packings ...................................................................................... 125-126 Custom Packed Columns .......................................................................................... 127 Custom Coated Packings ................................................................................... 128-129 Stationary Phases ............................................................................................ 128-129 Deactiglas Glass Columns ................................................................................ 130-133 GC Supports ..................................................................................................... 134-136 Molecular Sieves ..................................................................................................... 137 Carbograph Packings ............................................................................................. 138 Graphpac Packings ................................................................................................ 139 Silica Based Packings and Alltech Porous Polymers .................................................. 140 Tenax ® Porous Polymers .......................................................................................... 141 HayeSep ® Porous Polymers ...................................................................................... 142 Porapak ® and Chromosorb ® Porous Polymers ............................................................. 143 GC Packed Columns Applications ...................................................................... 144-152

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Page 1: Gas Chr omatography - Axial Scientific · Gas Chr omatography Popular GC Packed Columns..... 122-123 CTR Columns

Gas Chr

Gas Chromatogr

omatograph

aphy

yPopular GC Packed Columns .............................................................................. 122-123

CTR Columns ........................................................................................................... 124

Pretested GC Packings ...................................................................................... 125-126

Custom Packed Columns .......................................................................................... 127

Custom Coated Packings ................................................................................... 128-129

Stationary Phases ............................................................................................ 128-129

Deactiglas™ Glass Columns ................................................................................ 130-133

GC Supports ..................................................................................................... 134-136

Molecular Sieves ..................................................................................................... 137

Carbograph™ Packings ............................................................................................. 138

Graphpac™ Packings ................................................................................................ 139

Silica Based Packings and Alltech Porous Polymers .................................................. 140

Tenax® Porous Polymers .......................................................................................... 141

HayeSep® Porous Polymers ...................................................................................... 142

Porapak® and Chromosorb® Porous Polymers............................................................. 143

GC Packed Columns Applications ...................................................................... 144-152

Page 2: Gas Chr omatography - Axial Scientific · Gas Chr omatography Popular GC Packed Columns..... 122-123 CTR Columns

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gcgc

Contact your Alltech office or distributor for current or local prices.© Copyright 2003 Alltech Associates, Inc.

Popular GC Packed Columns• QC Chromatogram of Packing Included

• Preconditioned Packing

These columns are all 6' x 1/8" OD premium grade, precleanedstainless steel (unless otherwise indicated). Each column is madewith preconditioned, pretested packing and comes complete withfittings, column tags, conditioning instructions and packingquality control chromatogram. To order, use the catalog numbershown below and specify the instrument for which it should becoiled. If no coiling instructions are provided, we will supply in anominal 6" coil.

Popular GC Packed Columns

Popular Packed GC Columns1. All columns are 6' x 1/8" stainless steel unless otherwise

specified.

2. All columns are made with pre-conditioned, pretestedpackings.

3. All columns are configured to fit your GC. Please don’t forgetto include coiling instructions when ordering.

iPlease inquire about a custom packed column if you donot see your column listed here.

Popular GC Packed ColumnsPACKING DESCRIPTION DIMENSIONS* PART NO. PRICE

Alumina F-1, 60/80 5' x 1/8" SS 5664PC1% AT™-1000 on Carbograph 1, 60/80 144041% AT™-1000 on Carbograph 1, 60/80 24' x 1/8"SS 1446810% AT™-1000 on Chromosorb W-AW, 80/100 12001PC0.10% AT™-1000 on Graphpac-GC, 80/100 8542PC10% Carbowax® 1500 on Chromosorb T, 40/60 144796.6% Carbowax® 20M on Carbograph 1 AW, 80/100 10' x 1/8" SS 144735.0% Carbowax® 20M on Chromosorb W-HP, 80/100 1448210% Carbowax® 20M on Chromosorb W-AW, 80/100 12005PC10% Carbowax® 20M on Chromosorb W-HP, 80/100 12106PC6.6% Carbowax® 20M on Graphpac GB, 80/120 10' x 1/8" SS 144720.20% Carbowax® 1500 on Graphpac-GC, 80/100 8546PCCarbosphere®, 60/80 5680PCCarbosphere®, 80/100 10' x 1/8" SS 56821PCCarbosphere®, 80/100 15' x 1/16" SS 56825PCCarbosphere®, 80/100 5682PCChemipack C18, 80/100 2768PCChromosorb® 101, 80/100 2406PCChromosorb® 102, 80/100 2409PCChromosorb® 107, 80/100 2424PCChromosorb® 107, 80/100 9783Chromosorb® 750, 80/100 4' x 1/8" SS 1448030% DC-200 (500cstks) on Chromosorb® P-AW, 60/80 1448130% DC-200 (500cstks) on Chromosorb® P-AW, 60/80 30' x 1/8" SS 12713PC10% FFAP on Chromosorb® W-AW, 80/100 8434PCGas Chrom® 220, 80/100 2484PCGas Chrom® 254, 80/100 2486PCGas Chom® MP-1, 100/120 30' x 1/8" SS 4945PCHayeSep® A, 80/100 14484HayeSep® A, 120/140 40' x 1/8" SS 28211HayeSep® B, 80/100 14485HayeSep® D, 80/100 14487HayeSep® D, 100/120 3' x 1/8" SS 14486HayeSep® D, 100/120 20' x 1/8" Ni 27082PCHayeSep® D, 100/120 30' x 1/8" SS 27083PCHayeSep® D, 100/120 10' x 1/8" SS 28301PCHayeSep® DB, 100/120 30' x 1/8" SS 2836PCHayeSep® Dip, 100/120 9' x 1/8" SS 2833PCHayeSep® N, 80/100 14488HayeSep® Q, 60/80 14490HayeSep® Q, 80/100 28010PCHayeSep® Q, 80/100 2801PCHayeSep® Q, 100/120 14489HayeSep® P, 60/80 8' x 1/8" SS 2803PCHayeSep® P, 80/100 2804PCHayeSep® R, 80/100 2807PCHayeSep® S, 100/120 2811PCHayeSep® T, 60/80 3' x 1/8" SS 14491HayeSep® T, 80/100 2813PCHayeSep® T, 100/120 5' x 1/8" SS 2814PC*6' x 1/8" stainless steel unless otherwise specified.

Page 3: Gas Chr omatography - Axial Scientific · Gas Chr omatography Popular GC Packed Columns..... 122-123 CTR Columns

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Contact your Alltech office or distributor for current or local prices. © Copyright 2003 Alltech Associates, Inc.

Popular GC Packed Columns

Popular GC Packed Columns **PACKING DESCRIPTION DIMENSIONS* PART NO. PRICE

5% Krytox® 143 AC on Graphpac, GB 60/80 10' x 1/8" SS 85222Molecular Sieve 5A (Washed), 60/80 14494Molecular Sieve 5A (Washed), 80/100 5605PCMolecular Sieve 5A (Washed), 80/100 10' x 1/8" SS 14495Molecular Sieve 13X (Washed), 60/80 5' x 1/8" SS 57730PCMolecular Sieve 13X (Washed), 80/100 3' x 1/8" SS 14492Molecular Sieve 13X (Washed), 80/100 5773PCMolecular Sieve 13X (Washed), 80/100 10' x 1/8" SS 144933% OV-1 on Chromosorb W-HP, 80/100 12716PC10% OV™-101 on Chromosorb P-AW, 80/100 4' x 1/8" SS 1447710% OV™-101 on Chromosorb P-AW, 80/100 1447820% OV™-101 on Chromosorb P-AW, 80/100 144693% OV™-101 on Chromosorb W-HP, 80/100 12019PC3% OV™-101 on Chromosorb W-HP, 100/120 12700PC20% OV™-101 on Chromosorb W-HP, 80/100 1447010% OV™-101 on Chromosorb W-HP, 80/100 12703PC3% OV™-17 on Chromosorb W-HP, 100/120 12017PC3% OV™-17 on Chromosorb W-HP, 80/100 12719PC0.19% Picric Acid on Graphpac-GC, 80/100 7' x 1/8" SS 85501PCPorapak® N, 80/100 3' x 1/8" SS 14497Porapak® N, 80/100 2716PCPorapak® N, 80/100 12' x 1/8" SS 14498Porapak® N, 100/120 3' x 1/8" SS 14496Porapak® P, 80/100 14499Porapak® PS, 80/100 10' x 1/8" SS 14506Porapak® PS, 100/120 3' x 1/8" SS 14500Porapak® Q, 50/80 4' x 1/8" SS 14508Porapak® Q, 50/80 2700PCPorapak® Q, 80/100 3' x 1/8" SS 14519Porapak® Q, 80/100 12' x 1/8" SS 27012PCPorapak® Q, 80/100 2701PCPorapak® Q, 100/120 2702PCPorapak® QS, 80/100 2719PCPorapak® R, 80/100 2707PCPorapak® S, 50/80 7' x 1/8" SS 2709PCPorapak® S, 80/100 2710PCPorapak® T, 80/100 2713PC5% SE-30 on Chromosorb® W-HP, 80/100 12025PC10% SE-30 on Chromosorb® W-HP, 80/100 12423PCSilica Gel Grade 12, 60/80 8' x 1/8" SS 14523Silica Gel Grade 12, 60/80 18' x 1/8" SS 5651PCSilica Gel Grade 12, 80/100 8' x 1/8" SS 1453010% Silar® 10C on Chromosorb® W-HP, 100/120 12430PC20% Squalene on Chromosorb® P-AW, 80/100 3' x 1/8" SS 1447115% Squalene on Chromosorb® P-AW-DMCS, 80/100 8' x 1/8" SS 5327PCSulfur Gas Column 36' x 1/8" TFE 9779Super Q, 80/100 2735PC18" of Super Q, 80/100 30" x 1/8" TFE 9781Tenax® TA, 60/80 4' x 1/8" SS 14538Tenax® TA, 60/80 4900PCTenax® TA, 80/100 4901PCTenax® GR, 60/80 4937PCUnibeads® 1S, 60/80 2752PCUnibeads® 2S, 60/80 2760PCUnibeads® 3S, 60/80 14541Unibeads® 3S, 80/100 14542VZN-1 , 60/80 23' x 1/8" SS 84623PC10% Silicone UCW-98 on Chromosorb® W-HP, 80/100 8493PC1% TCEP on Carbograph® 1, 80/120 4' x 1/8" SS 14474*6' x 1/8" stainless steel unless otherwise specified.**To order, use the catalog number shown and specify the instrument for which it should be coiled.

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Contact your Alltech office or distributor for current or local prices.© Copyright 2003 Alltech Associates, Inc.

CTR Columns

CTR Columns — For Gas Analysis• CTR Columns Permit the Simultaneous Use of Two Different

Packings for Your Analysis

• CRT I is Ideal for Separating O2, N2, CH4, CO, CO2 at AmbientConditions

• CRT III is Ideal for Argon Analysis in the Presence of O2

• Useful Where Two Separate Chromatographic Runs are Requiredto Analyze One Sample

• Individually Tested

“CTR” is Alltech’s designation for a series of concentric columnswhich offer many advantages for certain types of difficultanalyses. A CTR column is essentially a column within a column.This permits you to use two different packings for the analysis ofyour sample. The diagram below shows the construction of theCTR column.

Cut-Away View of CTR Column

3980

CTR I - Oxygen, Nitrogen, Methane, CarbonMonoxide and Carbon Dioxide

Until the CTR, no single column operating at room temperaturehas been designed to permit, in one analysis, the separation ofoxygen, nitrogen, methane, carbon monoxide and carbon dioxide.Usually this analysis is accomplished by either making twoseparate runs on the sample of interest or employing a switchingvalve and polarity change during the analysis. The reason for thisdifficulty is that carbon dioxide is irreversibly absorbed on themolecular sieve which must be used to obtain the oxygen/nitrogen split. In addition, porous polymers and silica gel, whichare widely used to separate carbon dioxide from otherconstituents, do not separate carbon monoxide from thecomposite air peak at room temperature.

With Alltech’s CTR columns, this type of analysis can beroutinely handled in a one-step operation. The developmentpermits you to analyze oxygen, nitrogen, methane, carbonmonoxide and carbon dioxide under isothermal conditions, atroom temperature, and in less than 10 minutes. A quick method!

Calibration Gas for CTR I Column – This special mixture isuseful for calibrating Part No. 8700 CTR I columns. It containsapproximately 15% CO2 + 7% CO + 7% O2 + 4.5% CH4 with thebalance N2. It is supplied in a 4L push button can with a needleapplicator.

1. Air and Carbon Monoxide(Inner Column)

2. Methane (Inner Column)3. Carbon Dioxide (Inner Column)4. Oxygen (Outer Column)5. Nitrogen (Outer Column)6. Methane (Outer Column)7. Carbon Monoxide

(Outer Column)

Column: CTR I (Part No. 8700)Outer Column: 6ft x 1/4" Packed with Activated Molecular SieveInner Column: 6ft x 1/8" Packed with Porous Polymer MixtureTemp: AmbientFlowrate: Helium, 65mL/minDetector: TCD

CTR I - Air, CO, CH4, CO2, O2, N2

Column: CTR III, 6ft x 1/4" SS (Part No. 8725)Outer Column: 6ft x 1/4" Packed with Activated Molecular SieveInner Column: 6ft x 1/8" Packed with Molecular Sieve &

Oxy AdsorbentTemp: AmbientFlowrate: Helium, 70mL/minDetector: TCD

1. Argon (Inner Column)2. Nitrogen (Inner Column)3. Oxygen + Argon

(Outer Column)4. Nitrogen (Outer Column)

CTR III - Argon In Air

CTR ColumnsDESCRIPTION TEMP. LIMITS PART NO. PRICE

CTR I Column 275°C* 8700Calibration Gas for CTR I — 9799CTR III Argon Analysis Column 275°C* 8725

Additional FittingsTube End Connector, 1/4" to 1/8" Tube — 14169

*Condition this column at 250°C for a minimum of 12 hours.

1 2 3

4

5

6 7

0 1 2 3 4 5 6 7 8 9 Min.

0 2 4 6 8 10 12 Min.

1

2 3 4

1059

1060Inner 1/8" OD Tube ContainingColumn Packing A

Outer 1/4" OD Tube ContainingColumn Packing B

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Contact your Alltech office or distributor for current or local prices. © Copyright 2003 Alltech Associates, Inc.

Pretested GC Packings

Stainless Steel FittingsPART NO. PRICE

C-14010N

NIOSH Solvents1. Carbon Disulfide2. Acetone3. Carbon Tetrachloride4. 1,1,1-Trichloroethane5. Methyl Ethyl Ketone6. Methylene Chloride7. Benzene8. Trichloroethylene9. Chloroform

10. Tetrachloroethylene11. Toluene12. p-Dioxane + Ethylene dichloride13. p-Xylene14. m-Xylene15. o-Xylene16. 1,1,2-Trichloroethane

1177

Column: 20ft x 1/8" OD, SSPacking: 10% AT™-1000 on Chromosorb® W-AW, 80/100Temp: 60°C (2 min hold) to 160°C at 5°C/minuteFlowrate: Nitrogen, 30mL/minDetector: FID

Columns Packed in AT™-Steel*PACKING DESCRIPTION PART NO. PRICE

10% AT™-1000 on Chromosorb® W-AW, 80/100 800976.6% Carbowax® 20M on Carbograph™ 1 AW, 80/120 80093HayeSep® Q, 80/100 8009110% OV™-101 on Chromosorb® W-HP, 80/100 80095Porapak® N, 80/100 80099* All AT-Steel columns are 6' x 1/8".

AT™-Steel – Available in Packed Columns• Combines the Strength of Stainless Steel with the Inertness of

Deactivated Fused Silica.

0 4 8 12 16 20 Min.

1

2 34

6

89 10

11 1213 14

15

16

5

7

Stainless Steel Fittings*

Columns are supplied with brass nuts and Vespel®/Graphiteferrules. Stainless steel nuts, Vespel® or Graphite ferrules are alsoavailable.

*Column fittings not supplied with 5mm OD columns.

Alltech Pretested GC Packings

Pretested packings are guaranteed and supplied with a testchromatogram. Preconditioning service is available for 20g or 25gof packing. The packing is heated at 25°C below the uppertemperature limit for 3 hours with a flow of oxygen-free nitrogen.

Preconditioning ServicesDESCRIPTION PART NO. PRICE

Packing Preconditioning Service C-14000(per 20-25 grams). Specify StandardPacking Part Number.

Pretested GC PackingsPACKING DESCRIPTION TEMPERATURE LIMITS QTY PART NO. PRICE

Alumina F-1, 60/80 300°C 100g 56641% AT™-1000 on Carbograph 1, 60/80 250°C 15g 173310% AT™-1000 on Chromosorb W-AW, 80/100 250°C 20G 120010.10% AT™-1000 on Graphpac GC, 80/100 225°C 15g 854210% Carbowax® 1500 on Chromosorb T, 40/60 175°C 20g 161466.6% Carbowax® 20M on Carbograph 1-AW, 80/120 660/225°C 15g 17315.0% Carbowax® 20M on Chromosorb W-HP, 80/100 660/225°C 20g 161475.0% Carbowax® 20M on Chromosorb T, 40/60 660/225°C 25g 841610.0% Carbowax® 20M on Chromosorb W-AW, 80/100 660/225°C 20g 1200510.0% Carbowax® 20M on Chromosorb W-HP, 80/100 660/225°C 20g 121064% Carbowax® 20M + 0.8% KOH on Graphpac GB, 60/80 220°C 15g 85196.6% Carbowax® 20m on Graphpac GB, 80/120 175°C 15g 161480.2% Carbowax® 1500 on Graphpac GC, 80/100 175°C 15g 8546Carbosphere®, 60/80 400°C 5g 5680Carbosphere®, 80/100 400°C 5g 5682Chemipack C18, 80/100 320°C 15mL 2768Chromosorb® 101, 80/100 275/325°C 25g 16149Chromosorb® 102, 80/100 250/300°C 25g 16150Chromosorb® 107, 80/100 250/275°C 25g 16151Chromosorb® 750, 80/100 250/275°C 25g 1615230% DC-200 (500 cstk) on Chromosorb® P-AW, 60/80 0/200°C 25g 1271310% FFAP on Chromosorb® W-AW, 80/100 50/250°C 25g 843428% AT-223 + 4% KOH on Gas Chrom® R, 80/100 200°C 25g 49259Gas Chrom® 220, 80/100 250°C 25g 2484Gas Chrom® 254, 80/100 275°C 25g 2486Gas Chrom® MP-1, 100/120 50/250°C 25g 16153HaySep® A, 80/100 165°C 15g 16154HaySep® A, 120/140 165°C 15g 16155HaySep® B, 80/100 190°C 15g 16156HaySep® D, 80/100 290°C 15g 16157

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Contact your Alltech office or distributor for current or local prices.© Copyright 2003 Alltech Associates, Inc.

Pretested GC Packings

Pretested GC PackingsPACKING DESCRIPTION TEMPERATURE LIMITS QTY PART NO. PRICE

HayeSep® D, 100/120 290°C 15g 16166HayeSep® DB, 100/120 290°C 15g 16169HayeSep® Dip, 100/120 290°C 15g 16170HayeSep® N, 80/100 165°C 15g 16172HayeSep® Q, 60/80 275°C 15g 16196HayeSep® Q, 80/100 275°C 15g 16197HayeSep® Q, 100/120 275°C 15g 16198HayeSep® P, 60/80 250°C 15g 16199HayeSep® P, 80/100 250°C 15g 16210HayeSep® R, 80/100 250°C 15g 16211HayeSep® S, 100/120 250°C 15g 16212HayeSep® T, 60/80 165°C 15g 16213HayeSep® T, 80/100 165°C 15g 16214HayeSep® T, 100/120 165°C 15g 162155% Krytox® 143AC on Graphpac® GB, 60/80 175°C 15g 8522Molecular Sieve 5A (washed), 60/80 350°C 50g 5604Molecular Sieve 5A (washed), 80/100 350°C 50g 5605Molecular Sieve 13X (washed), 60/80 350°C 50g 57730Molecular Sieve 13X (washed), 80/100 350°C 50g 577323% OV™-1 on Chromosorb® W-HP, 80/100 100/350°C 20g 1271610% OV™-101 on Chromosorb® P-AW, 80/100 100/350°C 20g 1621620% OV™-101 on Chromosorb® P-AW, 80/100 350°C 20g 162173% OV™-101 on Chromosorb® W-HP, 80/100 350°C 20g 120193% OV™-101 on Chromosorb® W-HP, 100/120 350°C 20g 1270020% OV™-101 on Chromosorb® P-AW, 80/100 350°C 20g 1621810% OV™-101 on Chromosorb® W-HP, 80/100 350°C 20g 127033% OV™-17 on Chromosorb® W-HP, 100/120 350°C 20g 120173% OV™-17 on Chromosorb® W-HP, 80/100 350°C 20g 127190.19% Picric Acid on Graphac® GC, 80/100 120°C 15g 8550Porapak® N, 80/100 190°C 15g 16219Porapak® N, 100/120 190°C 15g 16220Porapak® P, 80/100 250°C 15g 16221Porapak® PS, 80/100 250°C 15g 16223Porapak® PS, 100/120 250°C 15g 16224Porapak® Q. 50/80 250°C 15g 16225Porapak® Q, 80/100 250°C 15g 16226Porapak® Q, 100/120 250°C 15g 16228Porapak® QS, 80/100 250°C 15g 16229Porapak® R, 80/100 250°C 15g 16230Porapak® S, 50/80 250°C 15g 16231Porapak® S, 80/100 250°C 15g 16232Porapak® T, 80/100 190°C 15g 16233Silica Gel Grade 12, 60/80 350°C 100g 5651Silica Gel Grade 12, 80/100 350°C 100g 565320% Squalane on Chromosorb® P-AW, 80/100 140°C 20g 1623515% Squalane on Chromosorb® P-AW-DCMS, 80/100 140°C 20g 16236Super Q, 80/100 250°C 10g 2735Tenax® TA, 60/80 350°C 10g 04916Tenax® TA, 80/100 350°C 10g 04917Tenax® GR, 60/80 350°C 10g 4937Unibeads® 1S, 60/80 200°C 25g 2752Unibeads® 2S, 60/80 200°C 25g 2760Unibeads® 3S, 60/80 200°C 25g 2764Unibeads® 3S, 80/100 200°C 25g 2766VZN-1, 60/80 50°C 10g 84621% TCEP on Carbograph® 1, 80/120 180°C 15g 16270

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Contact your Alltech office or distributor for current or local prices. © Copyright 2003 Alltech Associates, Inc.

Custom Packed Columns

Custom Packed Metal and Teflon® Columns

Before ordering a custom packed GC column, consult the list ofstocked packed columns to see if the column you need is there.

Each column comes complete with brass nuts and brassferrules. For assistance or a quote, please contact AlltechTechnical Support.

Custom Packed ColumnsDESCRIPTION PART NO. PRICE

Custom Packed Columns C-5000(Specify all information from Table 1)

Empty Metal ColumnsEmpty Column with Fittings and Ferrules C-5100

Additional Charges (per Column)Preconditioned Column C-14005Stainless Steel Fittings C-14010NDual and Triple Coated Packings C-14020

Figure 7 Figure 9Figure 8

Figure 6

Figure 3Figure 1 Figure 2

Figure 4 Figure 5

A

B

C

D

2483 2484 2485

2486 2487 2488

2489 2490 2491

A

B

C

D

A

B

C

D

A

B

C

D

E

F

A

B

C

D

E

A

B

C

D

A

B

C

D

E

F

A

B

C D

A

BX

Coiling Schematics

Certain expensive stationary phases and packings may requirea surcharge. Be sure to state coiling instructions.

Table 1 – Custom Metal and Teflon Columns - Ordering Information

1) Column Length: ft/m (circle one)

2) Column ID: in/mm (circle one)

3) Column OD: in/mm (circle one)

4) Tubing Material: (circle one)Stainless Steel AT-Steel Nickel Teflon

TFE-Coated SS Aluminum Copper

5) Liquid Phase A: % Loading:Liquid Phase B*: % Loading:Liquid Phase C*: % Loading:

6) Solid Support: Mesh Size:

7) Instrument Make and Model:

8) Configuration Number: (see coiling schematics)

9) Dimensions: A= ______ in/mm (circle one)

B= ______ in/mm (circle one)

C= ______ in/mm (circle one)

D= ______ in/mm (circle one)

E= ______ in/mm (circle one)

F= ______ in/mm (circle one)

X= ______ in/mm (circle one)

10) Mirror Image:Please check if a mirror image is required.

11) Injection Port Design: (circle one)on-column not on-column

12) Special Instructions: (please be specific)

13) Stainless Steel Fittings:Please check if stainless steel fittings are required(PN: C-14010N).

14) Preconditioning:Please check if column preconditioning is required(PN: C-14005).

* An additional charge applies to dual and triple coated packings(Part No. C-14020).

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Contact your Alltech office or distributor for current or local prices.© Copyright 2003 Alltech Associates, Inc.

Custom Coated Packings

Before ordering a custom coated packing, please check the list ofstock packings. You may find the packing you need in stock andat a savings. When ordering a Custom Packing, be sure to specifiy:1. % Loading; 2. Stationary Phase; 3. Solid Support; 4. MeshRange; 5. Quantity Desired.

Additional Charges for Custom Coated PackingsDESCRIPTION PART NO. PRICE

Multiple Stationary Phases (per phase) C-2000Expensive Stationary Phases: Add the costof the stationary phase used to base price

Acetone Washing C-2700

Base Price for Custom Coated Packings20 GRAMS 50 GRAMS 100 GRAMS

PACKING DESCRIPTION PART NO. PRICE PART NO. PRICE PART NO. PRICE

Chromosorb® G, W (HP) C-3004 C-3036 C-3068Chromosorb® G, W, or P (NAW, AW, DMCS) C-3006 C-3038 C-3070Chromosorb® T C-3008 C-3040 C-3072Chromosorb® 101-108 C-2031 C-2032 — —Chromosorb® 750 C-3012 C-3044 C-3076Gas Chrom® S C-3018 C-3050 C-3082Gas Chrom® R C-3020 C-3052 C-3084Gas Chrom® 220, 254 C-3022 C-3054 C-3086Graphpac™ GC & GB (15 grams), Carbograph™ C-2200 — — — —Porapak® C-2041 C-2042 — —Tenax® or HayeSep® (15 grams) C-3028 — — — —

Custom Coated Packings & GC Stationary Phases

GC Stationary PhasesGC Stationary Phases

TEMP. LIMITS MCRENOLDS NUMBERS USPDESCRIPTION SOLVENT °C X' Y' Z' U' S' CODE QTY PART NO. PRICE

Apiezon® L C 50/300 32 22 15 32 42 — 25g 5017bis-(2-Ethoxyethyl) Adipate (BEEA) C 150 — — — — — — 25g 5046Carbowax® 400 C 20/100 333 653 405 — — G20 100g 5051Carbowax® 20M C 60/225 322 536 368 572 510 G16 10g 5264DC-200, 350cstk (Methyl) C 20/250 16 57 45 66 43 — 100g 5251Dexsil® 300GC C 50/400 47 80 103 148 96 G33 1g 5092FFAP C 50/250 340 580 397 602 627 G35 20g 5156Hi-Eff®-1BP (Diethyleneglycol Succinate)[1] C 20/200 499 751 593 840 860 G4 25g 09505Igepal® CO-630 M 30/200 192 381 253 382 344 — 50g 5175OV™-1 (Methyl Gum) C 100/350 16 55 44 65 42 G2 10g 5293OV™-17 (50% Phenyl) A 20/350 119 158 162 243 202 G3 20g 5301OV™-101 (Methyl Fluid) C 20/350 17 57 45 67 43 G1 20g 5309OV™-275 (Dicyanoallyl) C 250+ 629 872 763 1106 849 — 5g 5314QF-1 (50% Trifluoropropyl) EA 20/250 144 233 355 463 305 — 25g 5269SE-30 (Methyl Gum) C 75/300 15 53 44 64 41 — 100g 5271Sebaconitrile C 150 — — — — — — 20g 5244Silar® 5CP (50% Cyanopropyl Phenyl Silicone)[2] C 50/250 319 495 446 637 531 G7 10g 5246Silar® 9CP (90% Cyanopropyl Phenyl Silicone) C 50/250 489 725 631 913 778 G8 5g 08269Silar® 10C (100% Cyanopropyl Silicone)[3] C 50/250 523 757 659 942 801 G5 5g 5250Tetrahydroxyethylethylene Diamine (THEED) M 125 463 942 626 801 893 — 25g 5347[1] U.S. Patent #3,239,997, [2] U.S. Patent #3,960,521; [3] U.S.Patent #4,063,911C=Chloroform; M=Methanol; MC=Methylene Chloride; W=Water; EA=Ethyl Acetate; A=Acetone; T=Toluene

This is just a partial listing of stationary phases available.Please inquire if you have special requirements.i

Stationary Phase Guidelines for Custom Coated GC Packings and Columns% LOAD % LOAD % LOAD

STATIONARY PHASE SUPPORTED MATERIAL STATIONARY PHASE SUPPORTED MATERIAL STATIONARY PHASE SUPPORTED MATERIAL

8% Max. Carbopack 25% Max. Chromosorb A 5% Max. Chromosorb G

30% Max. Chromosorb P's 12% Max. Chromosorb T 15% Max. Chromosorb W's

2% Max. Chromosorb 101-108 12% Max. Chromosorb 750 15% Max. Gas Chrom S, A, P, Z, & Q

30% Max. Gas Chrom R's 2% Max. Gas Chrom 220 & 254 0.5% Max. Glass Beads

8% Max. Graphpack 2% Max. HaySep's 2% Max. Porapacks

15% Max. SUPELCOPORT 2% Max. Super Q 2% Max. Tenax

12% Max. T-Port-F

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Custom Coated Packings & GC Stationary Phases

OEM Chromatography Solutions to Compliment Your Product Offering -

With Over 30 years Experience, Trust Alltech With Your OEM Needs• ISO Certified - We adhere to Strict Manufacturing Guidelines

• Our Manufacturing Capabilities - Packed & Capillary Columns

• Proprietary Technology and Custom Options - Personalized Labeling, Packaging and Support Materials

Contact our OEM Sales Manager at: 800-255-8324 for additional information on OEM manufacturing of Packed and Capillary GC columns tomeet your needs.

AT™-1000Apiezon® HApiezon® JApiezon® KApiezon® N

BBBTBentone 34BHXBTBMBTBMEA

Carbowax® 540Carbowax® 600Carbowax® 1000Carbowax® 1450Carbowax® 20M-TPACastorwaxCS-10

N,N-bis-(2-Cyanoethyl) formamide (BCEF)

DC-200 (500cstk)DC-410DC-550DC-702Di-n-butyl MaleateDidecyl PhthalateDi(2-ethylhexyl) SebacateDi(2-ethylhexyl) PhthalateDiglycerolDiisodecyl PhthalateDimethyl SulfolaneDinonyl Phthalate

ECNSS-MEGSS-XEthofat 60-25bis-(2-Ethoxyethyl) Sebacate (BEES)

Glycerin

Halocarbon 25-55 GreaseHalocarbon Oil 14-25HexadecanolHi-Eff™ 1AP

(Diethyleneglycol Adipate)Hi-Eff™ 2AP

(Ethyleneglycol Adipate)Hi-Eff™ 2BP

(Ethyleneglycol Succinate)Hi-Eff™ 3BP

(Neopentylglycol Succinate)Hi-Eff™ 3CP

(Neopentyl Glycol Sebacate)Hi Eff™ 8AP

(Cyclohexanedimethanol Adipate)Hi-Eff™ 10BP

(Phenyldiethanolamine Succinate)

Igepal® CO-880Igepal® CO-990

Kel-F® Oil No. 3Kel-F® Oil No. 10Kel-F® WaxKrytox 143AD

LAC 3-R-728LAC 4-R-886LAC 5-R-737Lexan (Polycarbonate Resin)

Neopentyl Glycol Succinate

Octyldecyl AdipateOV®-3OV®-7OV®-17 VinylOV®-22OV®-25OV®-73OV®-105OV®-202

OV®-210OV®-215OV®-225OV®-330OV®-351

Poly-A® 103Poly-A® 135Poly-I® 110Poly-S® 176Polyox 600MPolyvinylpyrrolidone

Reoplex 400

SE-52SE-54SF-96SorbitolSPAN 80SqualaneSUPEROX® 4SUPEROX® 20M

TCEPETCEPb,b-ThiodipropionitrileTriton® X-100Triton® X-305TWEEN 80

UC L-45UCON 50-HB-280-XUCON 75-H-90,000UCON LB-135UCON LB-1715UCON LB-550XUCON LB-1800-XUC W-98

Versamide® 900Versilube F-50

Additional Stationary Phases for Custom Packings and ColumnsStationary Phases

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Deactiglas® Glass Columns

Special Services for Glass ColumnsDESCRIPTION PART NO. PRICE

Stainless Steel Fittings (Per Column) C-14010NPreconditioned Packing (Per Column) C-14005

Key to Configurations for Glass Columns

0043

Deactiglas® Glass Columns• Silane Treated for Inertness

• Precision Bore Glass for Reproducibility

• Brass Fittings and Vespel/Graphite Ferrules Included• Available Packed or Empty

A1 (Arm 1)

A2 (Arm 2)

A1 (Arm 1)

A2 (Arm 2)

A1 (Arm 1)

A2 (Arm 2)

S (Span)

S (Span)

S (Span)

2513

Deactiglas® Glass GC ColumnsCHROMATOGRAPH CONFIGURATION LENGTH ID PACKED PART NO. PRICE EMPTY PART NO. PRICE

Hewlett Packard 5830, 5840, 59853ft 2mm 131122 1311216ft 2mm C6067 60676ft 4mm C6076 6076

3ft 2mm C6564 65646ft 2mm C6568 65686ft 4mm C6572 6572

6ft 2mm C6055 60556ft 4mm C6061 6061

6ft 2mm C6578 65786ft 4mm C6580 6580

On-Column InjectionA1 - 10.72" (272mm)A2 - 7.18" (182mm)S = 6" (152mm)

Not On-Column InjectionA1 - 8.95" (227mm)A2 - 9.25" (235mm)S = 6" (152mm)

4691

2514

On-Column InjectionA1 - 10.72" (272mm)A2 - 7.18" (182mm)S = 9" (229mm)

Not On-Column InjectionA1 - 8.95" (227mm)A2 - 9.25" (235mm)S = 9" (229mm)

4695

Alltech GC Columns are fabricated from precision-bore (2mm±0.05mm or 4mm ±0.1mm ID) glass. All columns are 1/4" ODunless otherwise specified. Columns longer than 2 meters mayhave joints. Several additional services such as stainless steelfittings and preconditioning of the packing are available. Certainexpensive stationary phases and packings may require asurcharge.

Due to space limitations we are not able to list all of thedifferent manufacturers columns in our catalog. However, they arestill available and can be specified at time of order placement. Ifyou do not see your instrument on the following pages, please callCustomer Service.

The following list of instuments can be accommodated: Fisher,Antek, Beckman, Bendix, Carlo Erba/Fisons, Dani, DuPont,Finnigan, Fisher Victoreen, Fisons, Gow Mac, Hewlett Packard,HNU, IBM, Intersmat, Microtek, Packard, Perkin Elmer, Pye-Unicam, Shimadzu, Spectra-Physics, Tremetrics, Tracor, andVarian.

5290

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2530

For explanation of A1, A2, and S, refer to key on Page 130.i

Perkin Elmer 115, 300, 900, 910, 990, F30, 2000, 2100, 3920, Sigma Series2ft 2mm 132442 1324413ft 2mm 131432 1314313ft 4mm 131442 1314411m 2mm C6437 64374ft 2mm C6148 61484ft 4mm C6150 61506ft 2mm C6152 61526ft 4mm C6154 61542m 2mm C6439 64392m 4mm C6441 64418ft 2mm C6443 6443

2.4m 2mm C6446 644610ft 2mm C6105 610510ft 4mm 131492 13149112ft 2mm C6448 6448

3ft 2mm C6451 64511m 2mm C6453 64536ft 2mm C6149 61496ft 4mm C6151 61512m 2mm C6455 64552m 4mm C6458 6458

2.4m 2mm C6462 646210ft 2mm C6106 61062531

Not On-Column InjectionA1 = 9" (229mm)A2 = 9" (229mm)S = 8.75" (222mm)

On-Column InjectionA1 = 12.62" (321mm)A2 = 7.09" (180mm)S = 8.75" (222mm)

2515

Deactiglas® Glass GC Columns (continued)CHROMATOGRAPH CONFIGURATION LENGTH ID PACKED PART NO. PRICE EMPTY PART NO. PRICE

Hewlett Packard 5880, 5890, 5987, 6890*3ft 2mm 130962 1309613ft 4mm 130972 1309714ft 2mm C6082 60824ft 4mm C6085 60856ft 2mm C6087 60876ft 4mm C6089 60892m 2mm C6336 63362m 4mm C6343 63438ft 2mm C6347 6347

1.8m 3mm C6346 634610ft 2mm C6091 609110ft 4mm 131552 131551

6ft 2mm C6368 63686ft 4mm C6391 63912m 2mm C6393 63932m 4mm C6396 63968ft 2mm C6413 6413

1.8m 3mm C6346 634610ft 2mm C6431 643110ft 4mm C6435 6435

3ft 2mm C6427 64273ft 4mm C6433 64334ft 2mm C6436 64364ft 4mm C6440 64406ft 2mm C6442 64426ft 4mm C6445 64452m 2mm C6447 64472m 4mm C6449 64498ft 2mm C6452 6452

2.4m 2mm C6454 645410ft 2mm C6456 645610ft 4mm C6460 6460

Configuration AOn-Column InjectionA1 = 11.02" (280mm)A2 = 9.05" (230mm)S = 9" (229mm)FID

Configuration BOn-Column InjectionA1 = 11.02" (280mm)A2 = 7.09" (180mm)S = 9" (229mm)TCD

Configuration CNot On-Column InjectionA1 & A2 = 9.05" (230mm)S = 9" (229mm)All DetectorsUse with Liner orDisposable Insert

4692

4693

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Deactiglas® Glass Columns

2538

2543

Shimadzu 4BF, 4BM, 4CM, 4MG, 6A, 6AM, 7AG (No Fittings Included)1.7m 3mm C6509 65092m 2mm* C6349 63492m 3mm C6485 64852m 4mm* C6359 6359

2.5m 3mm C6515 6515

Shimadzu 8A, RIA, GC-8A8IF (No Fittings Included)1m 3mm C6489 6489

1.5m 2.6mm C6598 65981.5m 3mm C6658 66582m 2mm* C6281 628112m 2.6mm C6673 66732m 3mm C6493 64932m 4mm* C6334 6334

Shimadzu 7A, 9A, 12A, 14A, 14B, 15A, 16A (No Fittings Included)1m 2.6mm C6487 64871m 3mm C6497 6497

1.7m 2.6mm C6491 64911.7m 3mm C6495 64952m 2mm* C6337 63372m 2.6mm C6498 64982m 3mm C6499 64992m 4mm* C6367 6367

2.4m 2.6mm C6501 65012.4m 3mm C6505 6505

2539

2537

A1 = 9" (229mm)A2 = 9" (229mm)S = 6" (152mm)5mm OD Tubing

A1 = 10.69" (272mm)A2 = 12.81" (327mm)S = 1.57" (40mm)5mm OD Tubing

For explanation of A1, A2, and S, refer to Page 130.i

2534A

2534B

Perkin Elmer 8300, 8400, 8700 Series, 9000 Series, Autosystem3ft 2mm C6464 64641m 2mm C6466 64666ft 2mm C6479 64796ft 4mm C6482 64822m 2mm C6468 64682m 4mm C6584 6584

2.4m 2mm C6471 6471

3ft 2mm C6474 64741m 2mm C6477 64774ft 2mm C6243 62434ft 4mm C6245 62456ft 2mm C6247 62476ft 4mm C6249 62492m 2mm C6484 6484

Not On-Column Injection

A1 = 6.75" (171mm)A2 = 6.75" (171mm)S = 6.5" (165mm)

On-Column InjectionA1 = 12" (305mm)A2 = 6.75" (171mm)S = 6.5" (165mm)

Deactiglas® Glass GC Columns (continued)CHROMATOGRAPH CONFIGURATION LENGTH ID PACKED PART NO. PRICE EMPTY PART NO. PRICE

A1 = 13.2" (335mm)A2 = 11.1" (282mm)S = 1.57" (40mm)5mm OD Tubing

Tremetrics (Tracor) 540, 560, 565, 570, 5853ft 2mm C6537 65371m 2mm C6541 65414ft 2mm C6109 61094ft 4mm C6111 61116ft 2mm C6113 61136ft 4mm C6115 61152m 2mm C6543 65432m 4mm C6545 65458ft 2mm C6547 6547

2.4m 2mm C6551 655110ft 2mm C6556 6556

A1 = 8" (203mm)A2 = 8" (203mm)S = 6" (152mm)

* 1/4" OD Column tapered to 5mm OD x 2.6mm ID ends.

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Deactiglas® Glass Columns

2549

Deactiglas® Glass GC Columns (continued)CHROMATOGRAPH CONFIGURATION LENGTH ID PACKED PART NO. PRICE EMPTY PART NO. PRICE

Varian 3300, 34003ft 2mm C6558 65584ft 2mm C6261 62614ft 4mm C6263 62636ft 2mm C6265 62656ft 4mm C6283 62832m 2mm C6340 63402m 4mm C6342 6342

Varian 3300, 3400,3600, 3700, 4400, 4600, 6000 Vista Series3ft 2mm 131662 1316613ft 4mm 131672 1316711m 2mm C6306 63061m 4mm C6308 63084ft 2mm C6189 61894ft 4mm C6190 61906ft 2mm C6191 61916ft 4mm C6192 61922m 2mm C6310 63102m 4mm C6312 6312

2.4m 2mm C6560 656010ft 2mm C6197 619710ft 4mm 131692 1316914m 2mm C6314 63144m 4mm C6316 6316

Varian Universal Columns 3300, 3400, 3600, 3700, 4400, 4600, 6000 Vista Series3ft 2mm C6562 65626ft 2mm C6206 62066ft 4mm C6208 62082m 2mm C6356 63562m 4mm C6358 63584m 2mm C6360 63604m 4mm C6366 6366

A1 = 9.5" (241mm)A2 = 2.25" (57mm)S = N/AFID, TCD, ECD

0050C

0050A

Injector B to Detector BA1 = 9.5" (241mm)A2 = 8.1" (206mm)S = 6.82" (173mm)FID

Injector A to Detector AA1 = 9.5" (241mm)A2 = 8.1" (206mm)S = 5.5" (140mm)FID

For explanation of A1, A2, and S, refer to key on Page 130.i

Universal Glass Column Adaptors are available for the Varian3000 and Varian 3700/VISTA Series. Please contact CustomerService for part numbers and prices.

Adaptor KitDESCRIPTION PART NO. PRICE

Universal Adaptor Kit 6210

Hi-EFF® Pre-Columns• Extend Column Life

• Reduce Sample Clean-up

• Perform Reaction Chromatography• Perform Subtraction Chromatography

To order a Hi-EFF® Pre-Column, state catalog number and, ifpacked, describe the packing (% load, phase, support and mesh).Glass and glass-lined SS and columns are deactivated at no charge.

Hi-EFF® Pre-ColumnsPACKED EMPTY

DESCRIPTION LENGTH QTY PART NO. PRICE PART NO. PRICE

1/8" SS 6" 6 5900 59101/4" Glass with Guide 6" 6 5902 59121/8" Glass-Lined SS 6" 3 5904 59141/8" Bottom-Drilled SS Union — Ea — — 59201/4" Bottom-Drilled SS Union — Ea — — 5921

Deactiglas® Column Inlet Liners• Prolong the Life of Your Glass Columns

• Silane-Treated for Inertness

• Available for 2mm or 4mm ID Columns• Inserts Directly Into The End of Your Column

Deactiglas® Column Inlet LinersDESCRIPTION QTY PART NO. PRICE

For 2mm ID Columns 10 6301For 2mm ID Columns 50 6302For 4mm ID Columns 10 6303For 4mm ID Columns 50 6304Glass Wool Inserter/Remover 2 6292

Column PackingDeactiglas®

Column

Inlet Liner

2mm ID Column

4mm ID ColumnGlass Wool

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GC Supports

Chromosorb® T

Chromosorb® T is a support materialmade from Teflon® 6. It provides a highlyinert surface and is useful for theanalysis of polar compounds such aswater, hydrazine, sulfur dioxide, etc.Temperature affects the physicalproperties of Chromosorb® T.It melts at 327°C, starts to decompose at290°C, and fuses together underprolonged use at 250°C. The free falldensity is 0.42g/cc. The surface area is 7-8m2/g and maximumloading capacity is 12%. When packing, we recommend chillingthe material to below 19°C. This helps make the material harderand reduces static electricity which interferes with the successfulpacking of the column.

T-Port-F

T-Port-F is a screened tetrafluoroethylenesupport useful for analysis of very polarcompounds. It has a density of about0.5g/cc with a maximum temperature limit of150°C.

T-Port-FDESCRIPTION QTY PART NO. PRICE

30/60 50g 244760/80 50g 244880/100 50g 2449

Glass Beads

These glass beads can be loaded with up to 0.5wt. % before becoming tacky. Two types areavailable: untreated (regular) ordimethyldichlorosilane (DMCS)-treated. TheDMCS-treated glass beads are also useful forpacking injection port liners or delay columns.

Glass BeadsDESCRIPTION QTY PART NO. PRICE

Regular, 60/80 mesh 125g 5420Regular, 80/100 mesh 125g 5422Regular, 100/120 mesh 125g 5424DMCS Treated, 60/80 mesh 125g 5426DMCS Treated, 80/100 mesh 125g 5428DMCS Treated, 100/120 mesh 125g 5430

Chromosorb® TDESCRIPTION QTY PART NO. PRICE

30/60 225g 2437140/60 225g 24381

Gas Chrom® S

Gas Chrom® S is white diatomaceousearth that is screened and water washedto neutrality. It has no additionalchemical treatment and is often used asa filtering agent or trapping material.

Gas Chrom® R

Gas Chrom® R is red diatomaceousearth that is screened and waterwashed to neutrality.

Gas Chrom®

DESCRIPTION QTY PART NO. PRICE

Gas Chrom® S80/100 100g 03010

Gas Chrom® R45/60 100g 495660/80 100g 496680/100 100g 4976

5294

5295

5293

U.S. Standard Mesh Size Conversion TableMESH SIZE MICROMETERS INCHES

20 850 0.0331

30 600 0.0234

40 425 0.0165

50 300 0.0117

60 250 0.0098

70 212 0.0083

80 180 0.0070

100 150 0.0059

120 125 0.0049

140 106 0.0041

170 90 0.0035

200 75 0.0029

230 63 0.0025

270 53 0.0021

325 45 0.0017

400 38 0.0015

5292

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GC Supports

Chromosorb® W SeriesDESCRIPTION QTY PART NO. PRICE

Chromosorb® W-NAW30/60 150g 2333145/60 150g 2334160/80 150g 2335180/100 150g 23361100/120 150g 23371120/140 150g 23381

Chromosorb® W-AW30/60 150g 2345145/60 150g 2346160/80 150g 2347180/100 150g 23481100/120 150g 23491

Chromosorb® W-AW-DMCS45/60 150g 2358160/80 150g 2359180/100 150g 23601100/120 150g 23611

Chromosorb® W-HP60/80 150g 2440180/100 150g 23651100/120 150g 23661120/140 150g 24421

Chromosorb® Diatomite Supports

There are four basic Chromosorb® diatomite basedgrades. These are Chromosorb® A, G, P and W,available in both untreated and in treated forms,as well as in a choice of various mesh ranges.

Chromosorb® A SeriesDESCRIPTION QTY PART NO. PRICE

Chromosorb® A-NAW20/30 454g 243145/60 454g 243260/80 454g 2433

Chromosorb® G SeriesDESCRIPTION QTY PART NO. PRICE

Chromosorb® G-NAW45/60 225g 2372160/80 225g 2373180/100 225g 23741100/120 225g 23751120/140 225g 23761

Chromosorb® G-AW45/60 225g 2382160/80 225g 2383180/100 225g 23841100/120 225g 23851

Chromosorb® G-AW-DMCS45/60 225g 2392160/80 225g 2393180/100 225g 23941100/120 225g 23951120/140 225g 23961

Chromosorb® G-HP60/80 225g 239680/100 225g 2397100/120 225g 2398120/140 225g 2444

Chromosorb® P SeriesDESCRIPTION QTY PART NO. PRICE

Chromosorb® P-NAW30/60 454g 230445/60 454g 230560/80 454g 230680/100 454g 2307100/120 454g 2308

Chromosorb® P-AW30/60 454g 231445/60 454g 231560/80 454g 231680/100 454g 2317100/120 454g 2318

Chromosorb® P-AW-DMCS45/60 454g 232360/80 454g 232480/100 454g 2325100/120 454g 2326

Chromosorb® Treatment SpecificationsABBREVIATION TREATMENTS

NAW Untreated (non-acid washed)

AW Acid washed (HCL is used)

DMCS Dimethyldichlorosilane (silanized)

HP High performance QC'd (acid washed, silanized,flux-calcined)

Chromosorb® SpecificationsRECOMMENDED

CHROMOSORB® SURFACE PACKED LIQUID PHASE

SERIES TYPE AREA DENSITY LOAD

A Flux-calcined 2.7m2/g 0.48gm/cc 25%

G Flux-calcined 0.5m2/g 0.58gm/cc 5%

P Calcined 4.0m2/g 0.47gm/cc 30%

W Flux-calcined 1.0m2/g 0.24gm/cc 15%

750 Flux-calcined 0.75m2/g 0.40gm/cc 12%

Chromosorb® 750

Chromosorb® 750 is the most inert and highlyefficient support material in the series. Thissupport material is acid-washed, DMCStreated, and carefully screened. Three meshranges are available: 60/80, 80/100 and100/120. The support is designed specificallyfor biomedical and pesticide analyses.

Chromosorb® 750DESCRIPTION QTY PART NO. PRICE

60/80 100g 239980/100 100g 2400100/120 100g 2401

5301

5303

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GC Supports

Silica Gel

Silica Gel is commonly used for the analysis offixed gases and light hydrocarbons. It is alsouseful for dehydration of gases and liquids.Silica Gel also strongly adsorbs hydrogen-bonding compounds.

Grade 42 Indicating Silica Gel changesfrom blue to pink as it becomes saturatedwith water. It conforms to MIL-D-3716 Type IVGrade H. It will adsorb water up to about 40% by weight. Themaximum temperature limit is 350°C.

Activated Alumina

Activated alumina is useful for the analysis oflight hydrocarbons. Unsaturated hydrocarbonsare retained longer than saturated ones. Theydry and “sweeten” liquid or gas streams. GradeF-6 is an indicating alumina which turns fromblue to pink upon adsorption of water. Themaximum temperature limit is 300°C.

Chemipack® C18

Chemipack® C18 is a chemically bonded GCpacking. Because it is bonded, it has highthermal stability, zero bleed and stabilityto water. These properties make it idealfor GC/MS or high sensitivity GC with anydetector. Chemipack® C18 is made bysilicon-bonding technology, not esterbonding. The monolayer produced yields ahighly efficient packing. The functional group bonded to the silicais octadecyl.

Chemipack®

DESCRIPTION MAX. TEMP. PART NO. PRICE

Chemipack® C18, 80/100, 15mL 320°C 2768

Stock Packed Column6ft x 1/8" SS packed with Chemipack® 2768PC

C18, 80/100

Silica Gel100 GRAMS 1KG

GRADE AND MESH PART NO. PRICE PART NO. PRICE

Grade 1240/60 5650 0553260/80 5651 0553380/100 5653 05534100/120 5655 05535

Grade 1535/60 5648 05545

Indicating Silica Gel, Grade 426/16 05559 05560

Stock Packed Column18ft x 1/8" SS packed with Silica Gel, 60/80 5651PC

Activated AluminaGRADE AND MESH QTY PART NO. PRICE

Grade F-140/60 100g 566260/80 100g 566480/100 100g 5666100/120 100g 5668

Grade F-68/14 100g 05561

Stock Packed Column5ft x 1/8" SS packed with Alumina F-1, 60/80 5664PC

Carbosphere™

DESCRIPTION QTY PART NO. PRICE

Carbosphere™

60/80 Mesh 5g 568080/100 Mesh 5g 5682

Stocked Packed Columns6ft x 1/8" SS Column Packed with Ea 5680PC

Carbosphere™, 60/806ft x 1/8" SS Column Packed with Ea 5682PC

Carbosphere™, 80/10010ft x 1/8" SS Column Packed with Ea 56821PC

Carbosphere™, 80/10015ft x 1/16" SS Column Packed with Ea 56825PC

Carbosphere™, 80/100

Carbosphere™ Carbon Molecular Sieve

Carbosphere™ exhibits properties similar tomolecular sieves due to small pore sizes in theangstrom range. It has a surface area of about1000m2/g with a pore size of about 13Å.Carbosphere™ separates oxygen, nitrogen, methane,carbon monoxide and carbon dioxide in the samerun. It also separates air, carbon dioxide and theC1-C2 hydrocarbons. At ambient temperatures,hydrogen will elute before oxygen.

Carbosphere™ resolves trace amounts ofmethane and acetylene in ethylene and even traceamounts of methane, acetylene and ethylene in ethane. Thecarbon molecular sieves also separate oxides of nitrogen andsulfur. Because Carbosphere™ is very nonretentive for water, rapidseparations of organics, such as formaldehyde and methanol inwater are possible.

Being a fairly hard dense bead, Carbosphere™ lacks electricityand packs easily into columns. Carbosphere™ can be affected bycontaminants in the air and in carrier gases and is best storedunder nitrogen or argon.

It is important to remove every trace of oxygen from thecarrier gas used on Carbosphere™ columns. This is essential if youare doing trace analysis or using temperatures above 200°C.Alltech’s Oxy-Trap™ and Indicating Oxy-Trap™ are ideal for removalof oxygen from carrier gas.

5299

5298

5297

5296

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Contact your Alltech office or distributor for current or local prices. © Copyright 2003 Alltech Associates, Inc.

Molecular Sieves

Molecular Sieves• For Drying Applications

Molecular sieves are synthetic alkali metal alumino-silicates with various cations. They are primarilyused for the separation of fixed gases and drying ofliquid or gas streams. Molecules are adsorbedprimarily because their molecular diameter matches the porediameter of the molecular sieve. They can be reactivated by heatingat 250°C for 12 hours; 300°C for 4 hours; or 350°C for 2 hours.

Molecular Sieves100 GRAMS 1KG

GRADE AND MESH PART NO. PRICE PART NO. PRICE

Molecular Sieve 3A1/8" Pellets 05252 052531/16" Pellets 05254 0525540/60 05306 0529560/80 05307 0529880/100 05308 05301100/120 05309 05304

Molecular Sieve 4A8/12 Beads 05256 052571/8" Pellets 05258 052591/16" Pellets 05260 0526140/60 5620 0534560/80 5622 0534880/100 5624 05351100/120 5625 05355

Molecular Sieve 5A1/8" Pellets 05264 052651/16" Pellets 5633 0526740/60 5626 0532760/80 5628 0533080/100 5630 05333100/120 5632 05336

Molecular Sieve 13X8/12 Beads 05268 052691/8" Pellets 05270 052711/16" Pellets 05272 0527340/60 5634 0549360/80 5636 0549680/100 5638 05499100/120 5640 05502

Washed Molecular Sieves• For Chromatography Applications

The usual gas chromatographic grades of molecularsieves have a fine dust adhering to each particlewhich cannot be removed simply by carefulsieving. This dust is responsible for poorerseparations and higher pressure drops thanmolecular sieves which are essentially dust-free.

The washed molecular sieves offered here have been carefullycleaned of dust particles by washing with distilled water. Thecleaned product is then activated and sealed in glass jars.Molecular Sieves are typically reactivated at a temperature of300°C for four hours.

Washed Molecular SievesDESCRIPTION QTY PART NO. PRICE

Washed Molecular Sieve 5A40/60 50g 560260/80 50g 560480/100 50g 5605100/120 50g 56066ft x 1/8" SS Packed with 80/100 Ea 5605PC

Washed 5A

Washed Molecular Sieve 13X40/60 50g 5772860/80 50g 5773080/100 50g 57732100/120 50g 577346ft x 1/8" SS Packed with 80/100 Ea 5773PC

Washed 13X5ft x 1/8" SS Packed with 60/80 Ea 57730PC

Washed 13X

Molecular Sieve PropertiesPORE SIZE: 3Å 4Å 5Å 10Å

Cation: Potassium Sodium Calcium Sodium

Water Capacity: 20% 22% 21.6% 28.6%

Molindicator®

DESCRIPTION QTY PART NO. PRICE

Molindicator®, 8/12 mesh 100g 055521000g 05553

Molindicator®

Molindicator® moisture-indicating molecular sieve. Atfull activity, Molindicator® is bright blue in color. Theblue color will turn to buff as water is adsorbed.Molindicator® offers a reliable means of visuallymonitoring the condition of your desiccant.

Molecular Sieve 5A

Column: 6ft x 1/8" OD, SS (Part No. 5605PC)Packing: Molecular Sieve 5A, 80/100 (Part No. 5630)Temp: 80°CFlowrate: Helium, 30mL/minDetector: TCD

Molecular Sieve 13X

1. Hydrogen2. Oxygen3. Nitrogen4. Methane5. Carbon Monoxide

Column: 6ft x 1/8" OD, SS (Part No. 5773PC)Packing: Molecular Sieve 13X, 80/100 (Part No. 5638)Temp: 35°CFlowrate: Helium, 30mL/minDetector: TCD

0

1

23

4 5

1 2 3 4 5 Min.

0

1

2 3

45

1 2 3 4 min.

1. Hydrogen2. Oxygen3. Nitrogen4. Methane5. Carbon Monoxide

2133

2134

5304 5305

5300

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Carbograph Packings

Carbograph™ Graphitized Carbon Blacks• High Speed Analysis

• Optimum Peak Symmetry

• Wide Range of Applications• Extremely Hydrophobic - Ideal for Aqueous

Injections

• Less Expensive than other Equivalents

Carbograph™ packings are graphitized carbonblacks equivalent to the Carbopackpackings. There are three different typesof graphitized carbon blacks (Carbograph™

packings 1 and 2) that differ in specific surface areas (see below).

Unlike diatomites that must have a stationary phase,Carbograph™ packings possess partitioning properties without anysurface modifications. Carbograph™ packings can also be modifiedwith a stationary phase giving them unique selectivities.

Carbograph™ 1

Equivalent to Carbopack™ B. Obtained by graphitization andgranulation from carbon black similar to Vulcan or Spheron. Ithas a surface area of 100m2/g. Carbograph™ 1-TD has a coarsemesh of 20/40 which is suitable for thermal desorption work.

Carbograph™ 1SC

Similar to Carbopack™ BHT. It is a type of Carbograph™ 1 that ismanufactured specifically for the separation of sulfur compoundsSF6, SO2, H2S, COS, mercaptans, and disulfides. It is also suitablefor analysis of sulfurs in oil products.

Carbograph™ 2

Equivalent to Carbopack™ C. Similar to graphitized carbon blackP 33 or Sterling FT. It has a specific surface of 10m2/g. It can beused alone as an uncoated adsorbent packing for the separation ofvolatile organic compounds. Carbograph™ 2-TD has a coarse meshof 20/40 which is suitable for thermal desorption work.

Carbograph™ support materials may be coated with anysingle or a combination of liquid phases for specialapplications. Please call our Customer ServiceDepartment to inquire about custom-made packings.

Carbograph™ PackingsPACKING DESCRIPTION OR APPLICATION MAX. TEMP. MESH QTY PART NO. PRICE

UncoatedCarbograph™ 1-TD For thermal desorption >500°C 20/40 15g 1740Carbograph™ 1 Light hydrocarbons >500°C 60/80 10g 1722Carbograph™ 1 Light hydrocarbons >500°C 80/120 10g 1724Carbograph™ 2-TD For thermal desorption >500°C 20/40 15g 1745Carbograph™ 2 Light hydrocarbons >500°C 60/80 10g 1726Carbograph™ 2 Light hydrocarbons >500°C 80/100 10g 1728Carbograph™ 1-SC Sulfur gases 225°C 40/60 10g 1734

Coated1% AT™-1000 on Carbograph™ 1 Low MW halogenated compounds 225°C 60/80 15g 17330.1% AT™-1000 on Carbograph™ 2 Higher MW halogenated compounds 225°C 80/100 15g 17374% Carbowax® 20M on Carbograph™ 1 DA Low MW acids + lactic acid 200°C 80/120 15g 172710.2% Carbowax® 1500 on Carbograph™ 2 Low MW alcohols and hydrocarbons 175°C 60/80 15g 17250.2% Carbowax® 1500 on Carbograph™ 2 Low MW alcohols and hydrocarbons 175°C 80/100 15g 17205% Carbowax® 20M on Carbograph™ 1 AW Alcoholic beverages 225°C 80/120 15g 17296.6% Carbowax® 20M on Carbograph™ 1 AW Alcoholic beverages 225°C 80/120 15g 17314% Carbowax® 20M + 0.8% KOH on Carbograph™ 1 Aliphatic amines 220°C 60/80 15g 17350.19% Picric Acid on Carbograph™ 2 Rapid separation of C2-C4 hydrocarbons 120°C 80/100 15g 17360.8% THEED on Carbograph™ 2 Ethylene oxide residues 125°C 80/100 15g 1942

Hydrocarbons1862

1

3

2

4

5

6

7 8

9

10

11

0 22 Min.10 202 4 6 8 12 14 16 18

1. Propane2. Propylene3. Isobutane4. 1-Butene5. n-Butane6. Isobutylene7. cis-2-Butene8. trans-2-Butene9. 1,3-Butadiene

10. Isopentane11. n-Pentane

Column: 2m x 2mm ID, GlassPacking: 0.19% Picric acid on Carbograph™ 2, 80/100

(Part No. 1736)Temp: 50°CFlowrate: Nitrogen, 20mL/minDetector: TCD

5306

i

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Contact your Alltech office or distributor for current or local prices. © Copyright 2003 Alltech Associates, Inc.

Graphpac™ Packings

Trihalomethanes

Graphpac™ PackingsPACKING SUGGESTED APPLICATIONS MAX. TEMP. MESH QTY PART NO. PRICE

Graphpac™-GC0.1% Alltech AT™-1000 Halocarbons, Phenols & Solvents 225°C 80/100 15g 85420.2% Carbowax® 1500 Alcohols, Solvents 175°C 60/80 15g 85440.2% Carbowax® 1500 Alcohols, Solvents 175°C 80/100 15g 85460.3% Carbowax® 20M + 0.1% H3PO4 C2-C5 Acids 220°C 60/80 15g 85480.19% Picric Acid C4 Hydrocarbons 120°C 80/100 15g 85500.8% THEED Ethylene Oxide Residues, Glycols 125°C 80/100 15g 8552Uncoated — — 60/80 15g 8536Uncoated — — 80/100 15g 8538Custom – Specify Phase and % Loading — — Specify 15g C-2200

Graphpac™-GB1% Alltech AT™-1000 Halocarbons, Solvents 225°C 60/80 15g 85174% Carbowax® 20M + 0.8% KOH Amines 220°C 60/80 15g 8519Uncoated — — 60/80 15g 8513Uncoated — — 80/120 15g 8515Uncoated, Acid Washed — — 60/80 15g 8533Uncoated, Acid Washed — — 80/120 15g 8535Custom – Specify Phase and % Loading — — Specify 15g C-2200Custom, Acid Washed – Specify Phase — — Specify 15g C-2300 and % Loading

Stock Packed Columns6ft x 1/8" SS packed with 0.1% AT™-1000 on Graphpac™ GC, 80/100 8542PC6ft x 1/8" SS packed with 0.2% Carbowax® 1500 on Graphpac™ GC, 80/100 8546PC10ft x 1/8" SS packed with 5% Krytox® 143C on Graphpac™ GB, 60/80 852227ft x 1/8" SS packed with 0.19% Picric Acid on Graphpac™ GC, 80/100 85501PC

Graphtrap™-GBDESCRIPTION PART NO. PRICE

Graphtrap™-GB, 50g, 20/40 mesh 8537

Graphpac™-GC and Graphpac™-GB• Graphitized Carbon

• Inert, Non-Specific Surface

• Unique Separation Properties• Optimized Phase Loading

• Hydrophobic – Ideal for AqueousInjections

Two types of Graphpacs™ are available, Graphpac™-GC andGraphpac™-GB. Graphpac™-GC has an average surface area of10-13m2/g, while Graphpac™-GB has a larger surface area of100-110m2/g. Both types interact with samples almost completelyby non-specific adsorption. There is no ionic charge associatedwith the surfaces of these materials unlike Tenax® or other porouspolymers. This interaction results in unique separations that arenot achievable with fused silica open tubular (FSOT) capillarycolumns. Alcohols, hydrocarbons, and acids are separated in seriesaccording to carbon number.

Stationary phases can be used to modify the selectivity ofthese carbons. These carbons possess partitioning capabilities asuncoated packings, however when a stationary phase is employedspecific selectivities can be obtained. The uncoated and coatedpackings are listed below. See the packed column applications formore example chromatograms. If you are ordering a packedcolumn for an on-column injection please specify so wecan leave 3inches unpacked in the injection arm of the column.

Graphtrap-GB

This coarse mesh of Graphpac™-GB (20/40 mesh) is useful fortrapping volatile compounds bexcause it has little retention forwater, which minimizes interference during desorption. It can beused with thermal or solvent desorption processes.

Column: 8ft x 1/8”, SS (Part No. C-5000*)Packing: 0.1% Alltech AT™-1000 on Graphpac™-GC, 80/100

(Part No. 8542)Temp: 75°C to 150°C at 10°C/minFlowrate: Nitrogen, 30mL/minDetector: FID at 175°C

0 2 4 6 8 10 12 Min.

12

3

4 1. Chloroform2. Dichlorobromomethane3. Dibromochloromethane4. Bromoform

*Custom columns must specifiy dimensions, packing, and GC.

1186

5307

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Silica Based Packing and Alltech Porous Polymers

Super QDESCRIPTION QTY PART NO. PRICE

Super Q Polymer Packing80/100 10g 2735

Stock Packed Column6ft x 1/8" SS Column Packed Ea 2735PC

with Super Q, 80/10030" x 1/8" TFE packed with 18" Ea 9781

of Super Q, 80/100

Super Q Polymer Packing

Super Q is a modified version of Porapak® Q.It is extensively washed with a selectedprogram of organic solvents and acids andthen conditioned in an oxygen-freeatmosphere. This treatment effectivelyremoves residual monomers andpolymerization catalysts. Thechromatogram below exhibits theversatility and superiority of Super Q.The maximum temperature limit is 250°C.

Gas Chrom® Porous Polymers

Gas Chrom® Porous Polymers are designedespecially for gas chromatography. Because theyare low in residual monomers and contaminants,Gas Chrom® Porous Polymers condition faster andhave lower column bleed. Due to a low affinityfor water, Gas Chrom® Porous Polymers alsodetermine low levels of water in organicsolvents and organics in water.

Gas Chrom® Porous PolymersDESCRIPTION QTY PART NO. PRICE

Gas Chrom® Porous Polymers220, 80/100 25g 2484254, 80/100 25g 2486

Stock Packed Columns6ft x 1/8" SS Column Packed Ea 2484PC

with Gas Chrom® 220, 80/1006ft x 1/8" SS Column Packed Ea 2486PC

with Gas Chrom® 254, 80/100

Unibeads® S Silica Based Packings

The Unibeads® S series consists of sphericalporous silica beads. Unibeads 1S have a pore sizeof 22 angstroms. Unibeads® 2S have a pore sizeof 60 angstroms and Unibeads 3S have a poresize of 100 angstroms. Unibead® 2S arecomparable to Porasil® A and Spherosil® XO-A-400. Unibeads® 3S are similar to Porasil®

B and Spherosil® XO-A-200. The smallerthe pore size, the greater the retentionfor hydrocarbons. Unibeads are also anideal material for making bonded silica GC packings.

Gas Chrom® SpecificationsGAS CHROM® 254 GAS CHROM® 220

Pore Size: 3000nm 10nm

Surface Area: 1000m2/g 450m2/g

Temp. Limits: 275°C-310°C 250°C-300°C

Equivalents: Porapak® P Porapak® QChromosorb® 101 Chromosorb® 102

Unibeads® SDESCRIPTION QTY PART NO. PRICE

Unibeads® Packings1S, 60/80 25g 27521S, 80/100 25g 27582S, 60/80 25g 27602S, 80/100 25g 27623S, 60/80 25g 27643S, 80/100 25g 2766

Stock-Packed Columns6ft x 1/8" SS packed with Ea 2752PC

Unibeads® 1S, 60/806ft x 1/8" SS packed with Ea 2760PC

Unibeads® 2S, 60/80

Alcohols

Column: Silanized Glass, 6ft x 2mm IDPacking: Alltech Super Q, 80/100 (Part No. 2735)Temp: 150°C to 220°C at 5°C/minFlowrate: Nitrogen at 15mL/minDetector: FID

1182

5308

5309

5310

0 2 4 6 8 10 12 14 16 18 20 Min.

1

2

3

4

5

6

7

810

11

9

12

13

8. n-Hexane9. Benzene

10. Methyl Butyl Ketone11. Toluene12. m & p-Xylenes + Ethylbenzene13. o-Xylene

1. Methanol2. Ethanol3. Acetone4. Methylene Chloride5. Ethyl Ether6. Methyl Ethyl Ketone7. Ethly Acetate

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gc gcTenax® Porous Polymers

Tenax®-TA (GC) • Stable Baseline After Conditioning

• Short Retention Times

• Low Affinity for Water

• Maximum Temperature Limit is 350°C

Tenax®-TA is a porous polymer that is based on2,6-Diphenyl-p-phenylene Oxide. Tenax®-TA isa low bleeding material with a very lowlevel of impurities and has replacedTenax®-GC. Tenax®-TA can be used as both acolumn packing material and as a trapping adsorbent for organicvolatile and semi-volatile compounds. Both the EPA and NIOSHspecify the use of Tenax® in their standard methods. Tenax® isparticularly useful for the analysis of high boiling compounds suchas alcohols, polyethylene glycols, diols, phenols, monoamines anddiamines, ethanolamines, aldehydes, ketones and chlorinatedaromatics. We designed a fibrillar material from Tenax® as ahydrophobic disk for SPE of organics in drinking and waste water.

Conditioning

We highly recommend that Tenax®, like all other porouspolymers, be preconditioned before being packed into GCcolumns. This removes most of the shrinkage of the polymer andminimizes the need for further conditioning. Tenax® can beexpected to shrink further in use.

Properties of Tenax®-TASpecific Surface Area: 35m2/g

Pore Volume: 2.4cc/g

Average Pore Size: 200nm

Density: 0.25g/cc

Tenax®-TADESCRIPTION QTY PART NO. PRICE

Tenax®-TA Porous Polymers20/35 10g 0491420/35 100g 04914120/35 500g 04914220/35 1000g 04914335/60 10g 0491535/60 100g 04915135/60 500g 04915235/60 1000g 04915360/80 10g 0491660/80 100g 04916160/80 500g 04916260/80 1000g 04916380/100 10g 0491780/100 100g 04917180/100 500g 04917280/100 1000g 049173

Pretreated Tenax® -TA C-4196 Please CallCleaned by Solvent Extraction

Stocked Packed Columns6ft x 1/8" SS packed with Ea 4900PC Tenax® TA, 60/806ft x 1/8" SS packed with Ea 4901PC Tenax® TA, 80/100

Tenax®-TA Membranes, 47mm 10 4943

Tenax®-GR• Contains 23% Graphitized Carbon

• Superior Properties as Trapping Material

• More Symmetrical Peaks as GC Packing

• Maximum Temperature Limit is 350°C

Tenax®-GR contains 23% graphitized carbon asan integral part of the material. This is notan admixture; the graphitized carbon isco-precipitated with the Tenax® polymer.The resulting material gives higherbreak-through volumes for most materials,yet is less water retentive than Tenax®-TA. This makes it an idealmaterial for the preparation of adsorbent traps. When using thismaterial for packing GC columns, better peak symmetry isobserved. Surface area is 24.1m2/g.

The following table gives the breakthrough volumes for severallow molecular weight compounds both on Tenax®-TA and onTenax®-GR. Because the density of the Tenax®-GR is higher thanTenax®-TA, the data is presented as mL/g of Tenax®-GR and asmL/mL of Tenax®-GR. The bulk density for Tenax®-GR is about0.55g/mL while it is about 0.20g/mL for Tenax®-TA.

Tenax® GRMESH QTY PART NO. PRICE

Tenax®-GR Porous Polymers20/35 10g 493320/35 100g 4933120/35 500g 4933220/35 1000g 4933335/60 10g 493535/60 100g 4935135/60 500g 4935235/60 1000g 4935360/80 10g 493760/80 100g 4937160/80 500g 4937260/80 1000g 4937380/100 10g 493980/100 100g 4939180/100 500g 4939280/100 1000g 49393

Stocked Packed Columns6ft x 1/8" OD SS Column Ea 4937PC Packed with Tenax®-GR, 60/80

Breakthrough Volumes at 20° C TENAX®-TA TENAX®-GR

TEST COMPOUND ML/G ML/ML ML/G ML/ML

Methane 5.7 1.1 2.2 1.2

Ethane 19.7 3.9 14.4 8.0

Bromotrifluoromethane 56.0 11.2 18.2 10.0

Water 55 11 47 26

Methyl Chloride 190 37.9 182 100

Butane 676 135 395 217

Vinyl Chloride 345 69 506 278

Benzene 44,400 8,880 33,800 18,600

1,1,2-Trichloroethane 110,000 21,900 105,000 57,700

5311 5312

For additional information on Tenax products, requestData Sheets 04914 and 4943.i

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HayeSep® Polymers

HayeSep® Porous Polymers• Pre-Purified Porous Polymers for GC

• Less Bleed and Shrinkage than Other PorousPolymers

• Conditioned

HayeSep® manufactures polymers withguaranteed consistent batch to batchperformance, no shrinkage and minimumbleed. These polymers are thoroughlycleaned and conditioned to 200oC (165oCfor N and T) under oxygen-free nitrogen before packaging.

Several HayeSep® polymers were developed to solve specificseparation problems. These include the room temperatureseparation of N2, O2, Ar and CO with HayeSep® A; ppm H2O in thepresence of HCl, Cl2 etc. with HayeSep® R; and many others. TheHayeSep® D series better separates the fixed gases to the C2

hydrocarbons. Small differences in pore sizes between themembers of this series can make dramatic differences in theseparations. Table 1 illustrates this.

HayeSep® Porous PolymersPACKING MAX. TEMP. PART NO. PRICE

HayeSep® Q, 75cc60/80 Mesh 275°C 280080/100 Mesh 275°C 2801100/120 Mesh 275°C 2802

HayeSep® P, 75cc60/80 Mesh 250°C 280380/100 Mesh 250°C 2804100/120 Mesh 250°C 2805

HayeSep® R, 75cc60/80 Mesh 250°C 280680/100 Mesh 250°C 2807100/120 Mesh 250°C 2808

HayeSep® S, 75cc60/80 Mesh 250°C 280980/100 Mesh 250°C 2810100/120 Mesh 250°C 2811

HayeSep® T, 75cc60/80 Mesh 165°C 281280/100 Mesh 165°C 2813100/120 Mesh 165°C 2814

HayeSep® N, 75cc60/80 Mesh 165°C 281580/100 Mesh 165°C 2816100/120 Mesh 165°C 2817

HayeSep® A, 75cc60/80 Mesh 165°C 281880/100 Mesh 165°C 2819100/120 Mesh 165°C 2820120/140 Mesh 165°C 2821

HayeSep® B, 75cc60/80 Mesh 190°C 282280/100 Mesh 190°C 2823100/120 Mesh 190°C 2824

HayeSep® C, 75cc60/80 Mesh 250°C 282580/100 Mesh 250°C 2826100/120 Mesh 250°C 2827

HayeSep® D, 75cc60/80 Mesh 290°C 282880/100 Mesh 290°C 2829100/120 Mesh 290°C 2830

HayeSep® DIP, 75cc60/80 Mesh 290°C 283180/100 Mesh 290°C 2832100/120 Mesh 290°C 2833

HayeSep® DB, 75cc60/80 Mesh 290°C 283480/100 Mesh 290°C 2835100/120 Mesh 290°C 2836

HayeSep® Stock Packed ColumnsPACKING DIMENSIONS PART NO. PRICE

HayeSep® A, 120/140 40ft x 1/8" SS 28211HayeSep® D, 100/120 20ft x 1/8" NI 27082PCHayeSep® D, 100/120 30ft x 1/8" SS 27083PCHayeSep® D, 100/120 10ft x 1/8" SS 28301PCHayeSep® DB, 100/120 30ft x 1/8" SS 2836PCHayeSep® Dip, 100/120 9ft x 1/8" SS 2833PCHayeSep® P, 60/80 8ft x 1/8" SS 2803PCHayeSep® P, 80/100 6ft x 1/8" SS 2804PCHayeSep® Q, 80/100 6ft x 1/8" SS 2801PCHayeSep® Q, 80/100 8ft x 1/8" SS 28010PCHayeSep® R, 80/100 6ft x 1/8" SS 2807PCHayeSep® S, 100/120 6ft x 1/8" SS 2811PCHayeSep® T, 80/100 6ft x 1/8" SS 2813PCHayeSep® T, 100/120 5ft x 1/8" SS 2814PC

Comparison of HayeSep® “D” Formulations†

Table 1 – Retention Time (in minutes)AIR CH4 CO2 C2H2 C2H4 C2H6 H2O

DIP 0.9 1.7 3.1 5.4 5.8 8.3 9.0

D 0.9 1.7 3.1 5.8 6.1 8.4 8.6

DOX 1.0 1.8 3.2 5.9 6.3 8.5 8.3

DB 0.9 1.6 3.1 6.1 6.6 8.7 8.1

†Retention data based on 10ft x 1/8" SS at 45°C, 30mL/min.

HayeSep® Porous Polymer SpecificationsHAYSEP® SURFACE AREA

SERIES POLYMER COMPOSITION (M2/G) POLARITY

Q DVB* 582 Non-polar

P DVB*/Styrene 165 Slightly Polar

R DVB*/N-Vinyl-2-pyrrolidinone 344 Moderately Polar

S DVB*/4-Vinyl-pyridine 583 Moderately Polar

T EGDM** 250 Very Polar

N DVB*/EGDM** 405 Very Polar

A DVB*/EGDM** (high purity) 526 Moderately Polar

B DVB*/Polyethyleneimine 608 Very Polar

C DVB*/Acrylonitrile 442 Moderately Polar

D DVB* (high purity) 795 Non-Polar

* Divinylbenzene. ** Ethyleneglycoldimethacrylate.

5313

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Chromosorb® and Porapak Porous Polymers

Century Series Chromosorb®

Century Series Chromosorb® porouspolymers have a rigid structure anddistinct pore size. They are packed intocolumns in the normal manner and do notrequire a liquid coating. Seven differentChromosorb® polymer materials areavailable. We recommend preconditioningall porous polymers before packingcolumns.

Chromosorb®

DESCRIPTION TEMP. LIMITS PART NO. PRICE

Chromosorb® 101, 50g60/80 275/325°C 240580/100 275/325°C 2406100/120 275/325°C 2407

Chromosorb® 102, 50g60/80 250/300°C 240880/100 250/300°C 2409100/120 250/300°C 2410

Chromosorb® 103, 50g60/80 275/300°C 241180/100 275/300°C 2412100/120 275/300°C 2413

Chromosorb® 105, 50g60/80 250/275°C 241780/100 250/275°C 2418100/120 250/275°C 2419

Chromosorb® 106, 50g60/80 250/275°C 242080/100 250/275°C 2421100/120 250/275°C 2422

Chromosorb® 107, 50g60/80 250/275°C 242380/100 250/275°C 2424100/120 250/275°C 2425

Chromosorb® 108, 50g60/80 250/275°C 242680/100 250/275°C 2427100/120 250/275°C 2428

Preconditioning Service† (per bottle) C-14030†Specify bulk packing Part No. and Preconditioning Service Part No.

Chromosorb® SpecificationsCHROMOSORB® SURFACE

SERIES POLYMER COMPOSITION AREA (M2/G) POLARITY

101 DVB*/Styrene >50 Non-Polar

102 DVB*/Styrene 300-400 Slightly Polar

103 Cross-linked Polystyrene** 15-25 Non-Polar

105 Polyaromatic 600-700 Mod. Polar

106 Cross-linked Polystyrene 700-800 Non-Polar

107 Cross-linked Acrylic Ester 400-500 Polar

108 Cross-linked Acrylic 100-200 Polar

* Divinylbenzene. **The surface is Basic

Porapak® Porous Polymers

Porapak® GC packings are cross-linked polymerswhich may be used directly in GC columnswithout a stationary phase coating. Acetonewashing of Porapaks® has been shown toimprove their performance by removingsurface adsorbed moisture and residualmonomers.

Porapak®

DESCRIPTION TEMP. LIMITS PART NO. PRICE

Porapak® Q, 26g50/80 250°C 270080/100 250°C 2701100/120 250°C 2702

Porapak® P, 20g50/80 250°C 270380/100 250°C 2704100/120 250°C 2705

Porapak® R, 24g50/80 250°C 270680/100 250°C 2707100/120 250°C 2708

Porapak® S, 26g50/80 250°C 270980/100 250°C 2710100/120 250°C 2711

Porapak® T, 31g50/80 190°C 271280/100 190°C 2713100/120 190°C 2714

Porapak® N, 29g50/80 190°C 271580/100 190°C 2716100/120 190°C 2717

Porapak® QS, 26g50/80 250°C 271880/100 250°C 2719100/120 250°C 2720

Porapak® PS, 20g50/80 250°C 272180/100 250°C 2722100/120 250°C 2723

Acetone Washing Service† (per bottle) C-2700†Specify bulk packing Part No. in addition to acetone washing Part No.

Porapak® SpecificationsPORAPAK® SURFACE

SERIES POLYMER COMPOSITION AREA (M2/G) POLARITY

Q DVB*/Ethylvinylbenzene 500-600 Slightly Polar

P DVB*/Styrene 100-200 Non-Polar

R DVB*/Vinyl pyrrolidinone 450-600 Moderately Polar

S DVB*/Vinyl pyridine 300-450 Moderately Polar

T EGDM** 225-350 Polar

N DVB*/Vinyl pyrrolidinone 250-350 Very Polar

* Divinylbenzene, ** Ethyleneglycoldimethacrylate

5314

5315

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GC Packed Columns Applications

C1-C3 Acids (Aqueous)

Free Acids

Column: 6ft x 2mm ID, GlassPacking: HayeSep® R, 80/100 (Part No. 2807)Temp: 220°CFlowrate: Helium, 39.2mL/minDetector: FID

Column: 6ft x 2mm ID, GlassPacking: Porapak® QS, 80/100 (Part No. 2719)Temp: 175°CFlowrate: Helium, 25mL/minDetector: TCD

Low Molecular Weight Acids

Column: 2m x 2mm ID, GlassPacking: 4% Carbowax® 20M on Carbograph™ 1-DA,

80/120 (Part No. 17271)Temp: 180°CFlowrate: Nitrogen, 20mL/minDetector: FID

Applications Page

Acids ............................................................................ 144Alcohols ....................................................................... 145Amines ................................................................... 145-146Carbohydrates ............................................................... 144Flavors/Fragrances ......................................................... 144Environmental Compounds ................................ 146, 148, 149Gases

Ammonia ................................................................... 152Hydrocarbons ........................................... 146,147,148,150Oxides of Nitrogen ................................................ 149-151Oxides of Carbon ................................................... 148-152Sulfur Gases ........................................................ 148, 150Air, Methane, Oxides of Carbon ............................... 149-152Natural Gas ................................................................ 152Miscellaneous Gases .............................................. 150-152

Solvents ....................................................................... 146

1. Acetic Acid2. Propionic Acid3. Isobutyric Acid4. Butyric Acid5. Isovaleric Acid6. Valeric Acid

1. Formic Acid2. Acetic Acid3. Propionic Acid4. Isobutyric Acid5. Butyric Acid6. Isovaleric Acid7. Lactic Acid8. Valeric Acid

1. Water2. Formic Acid3. Acetic Acid4. Propionic Acid

0 5 10 15 Min.

1 2

3

4

5 6

1 23

4

5

6

7

8

0 4 8 12 16 20 Min.

0 2 4 6 Min.

1

2

3

4

1439 1801

1072

TMS SugarsDistilled Lemon Oil

1. α-Pinene2. β-Pinene3. Myrcene4. Limonene5. γ-Terpinene

Column: 6ft x 2mm ID, GlassPacking: 3% OV™-101 on Chromosorb® W-HP, 80/100

(Part No. 12019)Temp: 160°C to 250°C at 10°C/minFlowrate: Nitrogen, 20mL/minDetector: FID

Column: 6ft x 2mm ID, GlassPacking: 10% AT™-1000 on Chromosorb® W-AW, 80/100

(Part No. 12001)Temp: 75°C (4min hold) to 120°C at 5°C/minFlowrate: Nitrogen, 15mL/minDetector: FID

0 2 4 6 8 Min.

12

3

4

5

6

0 2 4 6 8 10 12 Min.

1

3

5

2

4

11181120

1. L-Arabinose2. D-Xylose3. β--Fructose4. α-D-Fructose5. β-D-Glucose6. D-Galactose

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GC Packed Columns Applications

Column: 6ft x 2mm ID, GlassPacking: 0.2 % Carbowax® 1500 on Graphpac™-GC, 80/100

(Part No. 8546)Temp: 80°C to 150°C at 10°C/minFlowrate: Nitrogen, 20mL/minDetector: FID

C1-C5 Alcohols (Programmed)

1083

0 1 2 3 4 5 6 Min.

1

2 34

5

6 78

9 101112

13141516

7. 2-Methyl-1-propanol8. 1-Butanol9. 2-Methyl-2-butanol

10. 2,2-Dimethyl-1-propanol11. 3-Methyl-2-butanol12. 3-Pentanol13. 2-Pentanol14. 2-Methyl-1-butanol15. 3-Methyl-1-butanol16. 1-Pentanol

4. 1-Propanol5. 2-Methyl-2-propanol6. 2-Butanol

C1-C5 Alcohols

1. Methanol2. Ethanol3. 2-Propanol

Column: 6ft x 1/8" OD, SS (Part No. 2486PC)Packing: Gas Chrom® 254, 80/100 (Part No. 2486)Temp: 140°C to 180°C at 5°C/minFlowrate: Nitrogen, 20mL/minDetector: FID

0 2 4 6 8 Min.

1

2

3 45

67 89

1011

12

13

1079

4. 2-Methyl-2-propanol5. 1-Propanol6. 2-Butanol7. 2-Methyl-1-propanol8. 2-Methyl-2-butanol +

1-Butanol9. 2,2-Dimethyl-1-propanol

10. 3-Methyl-2-butanol11. 2-Pentanol + 3-Pentanol12. 3-Methyl-1-butanol +

2-Methyl-1-butanol13. 1-Pentanol

1. Methanol2. Ethanol3. 2-Propanol4. 1-Propanol5. 2-Methyl-2-propanol

C1-C5 Alcohols

Column: 6ft x 2mm ID, GlassPacking: 0.2% Carbowax® 1500 on Carbograph™ 2, 60/80

(Part No. 1725)Temp: 130°CFlowrate: Nitrogen, 20mL/minDetector: FID

12

3

4

5

6

78

9

1011

1213

1415 16

0 2 4 6 8 10 Min.

1815

6. 2-Butanol7. 2-Methyl-1-propanol8. 1-Butanol9. 2-Methyl-2-butanol

10. 2,2-Dimethyl-1-propanol11. 3-Methyl-2-butanol12. 3-Pentanol13. 2-Pentanol14. 2-Methyl-1-butanol15. 3-Methyl-1-butanol16. 1-Pentanol

Column: 4ft x 3mm ID, GlassPacking: Chromosorb® 101, 100/120 (Part No. 2407)Temp: 210°CFlowrate: Helium, 50mL/minDetector: FID

Glycols

1. Ethylene Glycol2. 1,2-Propanediol3. 2,3-Butanediol4. 1,3-Propanediol5. 1,3-Butanediol6. 1,4-Butanediol7. Diethylene Glycol8. Glycerol

0 1 2 3 4 Min.

1

2

3 4

5

6

7

8

1087

Ethylamines

Column: 6ft x 4mm ID, GlassPacking: 28% AT™-223 + 4% KOH on Gas Chrom® R, 80/100

(Part No. 49259)Temp: 130°CFlowrate: Helium, 75mL/minDetector: TCD

1. Ammonia2. Ethylamine3. Ethanol4. Diethylamine5. Triethylamine

1095

0 2 4 6 8 10 Min.

1

2

3

4

5

Butylamines

1. tert-Butylamine2. sec-Butylamine3. iso-Butylamine4. n-Butylamine

Column: 10ft x 1/8", SS (Custom Part No. C-5000*)Packing: 10% AT™-223 + 4% KOH on Gas Chrom® R,

80/100 (Part No. 49269)Temp: 90°CFlowrate: Nitrogen, 20mL/minDetector: FID

1093

0 42 6 10 14 188 12 16 20 Min.

12

3

4

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GC Packed Columns Applications

Aliphatic Amines

Column: 2m x 2mm ID, GlassPacking: 4% Carbowax 20M + 0.8% KOH on Carbograph™ 1,

60/80 (Part No. 1735)Temp: 90°C to 150°C at 4°C/minFlowrate: Nitrogen, 20mL/minDetector: FID

1. Methylamine2. Dimethylamine3. Ethylamine4. Trimethylamine5. Isopropylamine6. n-Propylamine7. t-Butylamine8. Diethylamine9. sec-Butylamine

10. Isobutylamine11. n-Butylamine

* Impurity

18141

2 3

4

56 7

89 10 11

0 2 4 6 8 10 Min.

**

Volatile Organic Compounds

1. Methylene Chloride2. Chloroform3. Carbon Tetrachloride4. 1,2-Dichloropropane5. Benzene6. Toluene7. Chlorobenzene8. Ethylbenzene9. 1,3-Dichlorobenzene

10. 1,2-Dichlorobenzene

1878

1

2

3 4

56

7 8

910

0 4 8 12 16 20 24 28 32 36 40 Min.

1818

Solvents

1. Acetaldehyde2. Methanol3. Ethanol4. Ethyl Acetate5. n-Propanol [propanol]6. Isobutanol7. Pentanol [amyl alcohol]8. Isopentanol [isoamyl alcohol]9. Acetic Acid

1

2

3

4

5

6

7

8

9

0 2 4 6 8 10 12 14 16 18 Min.

Solvents

Column: 6ft x 2mm ID, GlassPacking: 1% AT™-1000 on 60/80 Graphpac GC

(Part No. 8517)Flowrate: Nitrogen, 20mL/minTemp: 80°C to 230°C at 10°C/minDetector: FID

1. Methanol2. Ethanol3. Acetone4. 2-Propanol

1. Pyridine2. 2-Picoline

1107

1180

Pyridines

0 4 8 12 16 20 Min.

1

234

5

67 8

9

10 11

12

3. 2,6-Lupetidine4. 2,6-Lutidine5. 2-Ethylpyridine6. 2,5-Lutidine7. n-Ethylaniline8. 2,4-Dimethylaniline9. Quinoxaline

10. Quinoline11. 2-Benzylpyridine12. 4-Benzylpyridine

9. Benzene10. n-Hexane11. Cyclohexane12. 2-Hexannone13. n-Butyl Acetate14. Toluene15. Butyl Cellosolve®

+ Cellosolve Acetate16. Ethylbenzene17. m-Xylene18. o+p-Xylene19. p-Cymene

5. 1-Propanol6. Methyl Ethyl Ketone7. Ethyl Acetate8. 1-Butanol

0 5 10 15 20 25 Min.

467

10

1617 19

15141312

119

8 181

235

Column: 2m x 2mm ID, GlassPacking: Carbogrpah 1 AW 20, 80/120Temp: 70°C to 170°C at 4°C/minFlowrate: Nitrogen, 20mL/minDetector: FID

Column: 2m x 2mm ID, GlassPacking: 1% AT™-1000 on Carbograph™ 1, 60/80

(Part No. 1733)Temp: 45°C (3min hold) to 230°C at 8°C/minFlowrate: Nitrogen, 20mL/minDetector: FID

Column: 6ft x 1/8", Nickel 200 (Custom Part No. C-5000*)Packing: 10% Apiezon® L + 2% KOH on Chromosorb® W-AW,

80/100Temp: 80°C (4 minutes) to 200°C at 8°C/minFlowrate: Nitrogen, 40mL/minDetector: FID

C1-C5 Hydrocarbons

8. n-Butane9. 1-Butane +

Isobutylene10. trans-2-Butene11. cis-2-Butene12. 1,3-Butadiene13. Isopentane14. 1,2-Butadiene15. n-Pentane16. 1-Butyne

1. Methane2. Ethane + Ethylene3. Propane4. Propylene5. Acetylene6. Isobutane7. Propadiene

0 5 10 15 20 25 30 35 40 Min.

1

2

3 4

5

6

7

8

910

1112

13 14 15 16

Column: 23ft x 1/8" OD, SS (Part No. 84623PC)Packing: VZN-1, 60/80 (Part No. 8462)Temp: 40°CFlowrate: Nitrogen, 20mL/minDetector: FID

1147

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GC Packed Columns Applications

Hydrocarbons

1. Propane2. Propylene3. Isobutane4. 1-Butene

Column: 2m x 2mm ID, GlassPacking: 0.19% Picric acid on Carbograph™ 2, 80/100

(Part No. 1736)Temp: 50°CFlowrate: Nitrogen, 20mL/minDetector: TCD

5. n-Butane6. Isobutylene7. cis-2-Butene8. trans-2-Butene9. 1,3-Butadiene

10. Isopentane11. n-Pentane

1506

1

3

2

4

5

6

789

10

11

0 22 Min.10 202 4 6 8 12 14 16 18

Unibeads

0 2 4 6 8 10 Min.

1

2 4

3

5

6

Column: Stainless Steel, 6ft x 1/8" OD, Unibeads 2S, 60/80Packing:Temp: 70°CFlowrate: Helium, 26mL/minDetector: FID*Custom column. Must specifiy dimensions, packing and GC.

1. Methane2. Ethane

3. Ethylene 4. Propane 5. Isobutane 6. n-Butane & Propylene

1509

0 2 4 6 Min.1 3 5

1

23

4

5

6

7 89

Gases, 1000ppm in Air

Column: 8ft x 1/8" OD, SS (Part No. 5327PC)Packing: 15% Squalane on Chromosorb® P-AW-DMCS, 80/100Temp: 25°CFlowrate: Helium, 20mL/minDetector: FID at 100°C

1. Methane2. Ethane3. Propylene4. Propane5. Isobutane6. 1-Butene7. Butane8. trans-2-Butene9. cis-2-Butene

1703

Hydrocarbons

0 4 8 12 16 Min.

1

23

45

6

1. Air2. Methane3. Ethane4. Carbon Dioxide5. Ethylene6. Propane

Column: 6ft x 1/8" OD, SS (Part No. 2752PC)Packing: Unibeads® 1S, 60/80 (Part No. 2752)Temp: 70°CFlowrate: Helium, 26mL/minDetector: TCD

1506

Column: 7ft x 1/8" OD, SS (Part No. 85501PC)Packing: 0.19% Picric Acid on Graphpac™-GC, 80/100

(Part No. 8550)Temp: 30°CFlowrate: Helium, 40mL/minDetector: FID

C1-C5 Hydrocarbons

0 1 2 3 4 5 6 7 15 16 17 Min.

1 23

4

5

67

8

9

1011

1213

1. Methane2. Ethane + Acetylene3. Propane

4. Propylene5. Propyne6. Isobutane7. 1-Butene8. n-Butane9. Isobutylene

10. cis-2-Butene11. trans-2-Butene12. 1,3-Butadiene13. n-Pentane

1143

C1-C2 Hydrocarbons

0 2 4 6 Min.

1

2

3

4

Column: 6ft x 1/8" OD, SS (Part No. 5682PC)Packing: Carbosphere™, 80/100 (Part No. 5682)Temp: 225°CFlowrate: Nitrogen, 45mL/minDetector: FID

1. Methane (3ppm)2. Acetylene (83ppm)3. Ethylene (39ppm)4. Ethane

1144

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GC Packed Columns Applications

C1-C2 Hydrocarbons

1. Methane (0.1894%)2. Ethane (0.0965%)3. Propane (0.0989%)4. Isobutane (0.1019%)5. Butane (0.1019%)6. n-Pentane (0.2002%)

Paraffin/Aromatic Separation

1 2 3

45

6

0 3 6 9 12 Min.

12

3

4

5

6

78

9

10

11

0 2 4 6 Min.

Hydrocarbons, Sulfur Gases

Column: 10ft x 1/8" OD, SS (Part No. 28301PC)Packing: HayeSep® D, 100/120 (Part No. 2830)Temp: 120°C to 200°C at 20°C/minFlowrate: Helium, 35mL/minDetector: FID

Column: 10ft x 1/8" OD, SS (Part No. 28301PC)Packing: HayeSep® D, 100/120 (Part No. 2830)Temp: 80°CFlowrate: Helium, 35mL/minDetector: FID

1. Methane (1%)2. Acetylene (1%)3. Ethylene (1%)4. Ethane (1%)

C1-C5 Paraffins

Column: A: 12ft x 1/8" SS (Custom Part No. C-5000*)B: 6ft x 1/8" SS (Custom Part No. C-5000*)

Packing: A: 35% BCEF on Chromosorb® P-AW-DMCS, 80/100B: 10% OV™-101 on Chromosorb® W-HP, 80/100

Temp: 75°C (5 min) to 110°C at 10°C/minFlowrate: Nitrogen, 20mL/minDetector: FID*Custom column. Must specifiy dimensions, packing and GC.

1. Pentane2. Hexane3. Heptane4. Octane

Column: 8ft x 1/8" OD, SS (Part No. 28010PC)Packing: HayeSep® Q, 80/100 (Part No. 2801)Temp: 90°CFlowrate: Helium, 30mL/minDetector: TCD at 120°C

1. Air2. Methane3. Carbon Dioxide4. Ethylene5. Acetylene

6. Ethane7. Hydrogen Sulfide8. Carbonyl Sulfide9. Propylene

10. Propane11. Propadiene

1727

1728

1738

0 4 8 12 16 20 24 Min.

8

7

6

5

3

21

4

1

2 3

4

0 2 4 Min.

5. Nonane6. Decane7. Benzene8. Toluene

1150

C1-C4 Hydrocarbons

Mapp Gas

0 2 4 6 8 Min.

1

23 4

5

67

8

Column: 10ft x 1/8" OD, SS (Custom Part No. C-5000*)Packing: HayeSep® R, 100/120 (Part No. 2808)Temp: 80°CFlowrate: Helium, 30mL/minDetector: TCD*Custom column. Must specifiy dimensions, packing and GC.

1. Air2. Methane3. Carbon Dioxide4. Ethylene5. Ethane6. Acetylene

Column: 5ft x 1/8" OD, SS (Custom Part No. C-5000*)Packing: HayeSep® T, 80/100 (Part No. 2813)Temp: 32°CFlowrate: Helium, 30mL/minDetector: TCD at 180°C*Custom column. Must specifiy dimensions, packing and GC.

1. Air2. Methane3. Carbon Dioxide4. Ethane5. Propylene6. Propane7. Propadiene8. Methyl Acetylene

0 2 4 6 8 Min.

45 6

12

3

1451

2021

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GC Packed Columns Applications

Nitric Oxide

Carbon Dioxide and Nitrous Oxide

Column: 30ft x 1/8" OD, SS (Part No. 2836PC)Packing: HayeSep® DB, 100/120 (Part No. 2836)Temp: 22°CFlowrate: Helium, 30mL/minDetector: TCD at 140°C*Custom column. Must specifiy dimensions, packing and GC.

1. Air2. Carbon Dioxide3. Nitrous Oxide

Column: 8ft x 1/8" OD, SS (Custom Part No. C-5000*)Packing: Chromosorb® 101, 80/100 (Part No. 2406)Temp: 45°CFlowrate: Helium, 35mL/minDetector: TCD*Custom column. Must specifiy dimensions, packing and GC.

0 2 4 6 8 Min.

1

2

31. Nitrogen (Balance)2. Argon3. Nitric Oxide (0.58%)

0 2 Min.

1

2 3

1484

2014

0 2 4 6 8 10 Min.

1

23

45

6 7

Loop Sampling with Backflush of Precolumnto Vent C3’s and C4’s

Column: 15ft x 1/16" OD, SS (Part No. 56825PC)Packing: Carbosphere®, 80/100 (Part No. 5682)Temp: 30°C (3min) to 225°C at 30°C/minFlowrate: Helium, 15mL/minDetector: TCD at ambient

1. Hydrogen (65%)2. Nitrogen (1.03%)3. Carbon Monoxide

(29.92%)4. Methane (1.00%)5. Carbon Dioxide

(2.00%)

1. Nitrogen (Balance)2. Carbon Monoxide (1%)3. Methane (1%)4. Carbon Dioxide (1%)5. Acetylene (1%)6. Ethylene (1%)7. Ethane (1%)

Columns: (1) 30ft x 1/8" OD, SS (Part No. 27083PC),(2) 30ft SS (Part No. 27083PC) for Column Balancing

Packing: (1) HayeSep® D, 100/120(2) HayeSep® D, 100/120

Temp: 35°C (11min) to 175°C at 30°C/minFlowrate: Helium, 19mL/minDetector: TCD at 250°CInjection: 10 Port Valco Valve, 0.5mL Sample LoopNote: Baseline Subtraction

0

1 3

2

4 5

20 Min.2 4 6 8 10 12 14 16 18

Fast Environmental Gas Analysis

1708

1589

2020

Scott Mix 234

Column: 30ft x 1/8" OD, SS (Part No. 2836PC)Packing: HayeSep® DB, 100/120 (Part No. 2836)Temp: 22°CFlowrate: Nitrogen, 30mL/minDetector: TCD

1. Helium (Balance)2. Hydrogen (4%)3. Oxygen (4%)4. Methane (4%)

0

1 2

3

4

2 4 6 8 10 Min.

12

34

56

7

0 11 Min.

Scott Mix 216

1. Nitrogen (Balance)2. Carbon Monoxide (1%)3. Methane (1%)4. Carbon Dioxide (1%)5. Acetylene (1%)6. Ethylene (1%)7. Ethane (1%)

Column: 20ft x 1/8" OD, Nickel (Part No. 27082PC)Packing: HayeSep® D, 100/120 (Part No. 2830)Temp: 40°C (2min) to 110°C at 24°C/minFlowrate: Helium, 30mL/minDetector: TCD at 140°C

1726

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GC Packed Columns Applications

Gases

1. Air, Carbon Monoxide2. Carbon Dioxide3. Water4. Carbonyl Sulfide5. Sulfur Dioxide

Column: 6ft x 2mm ID, GlassPacking: Porapak® Q, 80/100 (Part No. 2701)Temp: 75°CFlowrate: Helium, 20mL/minDetector: TCD

0 2 4 6 Min.

3

45

1 2

1478

0 7 Min.

4

5

1 2 3 Gas Mixture

12

3

456

78 9

10 11

0 2 4 6 8 Min.

Hydrocarbons, Sulfur Gases

1. Air2. Methane3. Carbon Dioxide4. Acetylene5. Ethylene6. Ethane7. Water8. Hydrogen Sulfide9. Carbonyl Sulfide

10. Propylene11. Propane

Column: 9ft x 1/8" OD, SS (Part No. 2833PC)Packing: HayeSep® Dip, 100/120 (Part No. 2833)Temp: 100°CFlowrate: Helium, 30mL/minDetector: TCD

1. Nitrogen (Balance)2. Carbon Dioxide (2%)3. Nitrous Oxide (3%)4. Water (0.5%)5. Hydrogen Sulfide (3%)

Column: 10ft x 1/8" OD, SS (Part No. 28301PC)Packing: HayeSep® D, 100/120 (Part No. 2830)Temp: 80°CFlowrate: Helium, 30mL/minDetector: TCD

1772

1771

*Custom columns must specify dimensions, packing, and GC.

0 5 10 15 20 Min.

8

7

6

53

41

2

Sulfur Gases in Air

Reactive Gas Mixture

1. Hydrogen Sulfide2. Carbonyl Sulfide3. Sulfur Dioxide4. Methyl Mercaptan5. Methyl Sulfide6. Dimethyl Disulfide

0 1 2 3 4 5 6 7 Min.

1

23

4

5

6

Column: 30" x 1/8" OD, Teflon® (Part No. 9781)Packing: 18" Super Q, 80/100 (Part No. 2735)Temp: 30°C (1min hold) to 210°C at 40°C/minFlowrate: Helium, 40mL/minDetector: FPD

1. Air2. Methane3. Carbon Dioxide4. Nitrous Oxide5. Ammonia6. Ethane7. Hydrogen Sulfide8. Carbonyl Sulfide

Column: 8ft x 1/8" OD, SS (Part No. 28010PC)Packing: HayeSep® Q, 80/100 (Part No. 2801)Temp: 50°CFlowrate: Helium, 30mL/minDetector: TCD

1447

1067

Columns: (1) 7ft x 1/8" Porapak® S, 50/80, SS (Part No. 2709PC)(2) 5ft x 1/8" Washed Molecular Sieve 13X, 60/80,SS (Part No. 57730PC)

Temp: 80°CFlowrate: Helium, 35mL/minDetector: TCDConfiguration: Column Sequence Reversal without BackflushInjection: 10 Port Valco Valve with 250µL Sample Loop

Flue Gas Sample

Switch

1

234

5

6

78

0 2 4 6 8 Min.

1. Carbon Doxide2. Hydrogen3. Ethane4. Oxygen5. Nitrogen6. Methane7. Water8. Carbon Monoxide

1756

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GC Packed Columns Applications

Hydrogen/Air

Room Air

0 2 4 6 8 10 12 Min.

1

2 34 1. Argon (Inner Column)

2. Nitrogen (Inner Column)3. Oxygen + Argon

(Outer Column)4. Nitrogen (Outer Column)

Argon in Air

Gas Mixture

0 2 4 Min.

1 2

3

1. Hydrogen2. Nitrogen3. Oxygen4. Argon

Column: 25ft x 1/8" OD, SS (Custom Part No. C-5000*)Packing: HayeSep® D, 100/120 (Part No. 2830)Temp: 25°CFlowrate: Helium, 24mL/minDetector: TCD*Custom column. Must specify dimensions, packing, and GC.

Column: 30ft x 1/8" OD, SS (Part No. 2836PC)Packing: Hayesep® DB, 100/120 (Part No. 2836)Temp: -66°CFlowrate: Helium, 30mL/minDetector: TCD

Column: CTR III, 6ft x 1/4" OD, SS (Part No. 8725)Packing: Inner Column – Molecular Sieve & Oxygen Adsorbent

Outer Column – Molecular SieveTemp: AmbientFlowrate: Helium, 70mL/minDetector: TCD

1. Nitrogen2. Carbon Monoxide3. Methane4. Carbon Dioxide5. Acetylene6. Ethylene7. Water8. Ethane

Column: 30ft x 1/8" OD, SS (Part No. 2836PC)Packing: Hayesep® DB, 100/120 (Part No. 2836)Temp: 120°CFlowrate: Helium, 28mL/minDetector: TCD

1. Nitrogen (78%)2. Oxygen (21%)3. Argon (0.94%)

2460

17061060

1452

Scott Mix 234

Column: 30ft x 1/8" OD, SS (Part No. 2826PC)Packing: HayeSep® DB, 100/120 (Part No. 2836)Temp: 22°CFlowrate: Nitrogen, 30mL/minDetector: TCD

1. Helium2. Hydrogen3. Oxygen4. Methane

2461

Air, CH4, CO2, N2O

1

2

3

4

0 1 2 Min.

Column: 6ft x 1/8"OD, SS (Part No. 5682PC)Packing: Carbosphere™, 80/100 (Part No. 5682)Temp: 200°CFlowrate: Helium, 20mL/minDetector: TCD

1. Air2. Methane3. Carbon Dioxide4. Nitrous Oxide

1712

0 5 10 15 Min.

7

86

5

43

2

1

0 1

1

2

2

3

3

4

4 5 6 Min.

0 1

1

2

2

3

3

4

4

5 6 7 8 9 10 Min.

Page 32: Gas Chr omatography - Axial Scientific · Gas Chr omatography Popular GC Packed Columns..... 122-123 CTR Columns

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GC Packed Columns Applications

Air, CO, CH4, CO2, O2, N2

Column: CTR I, 6ft x 1/4" OD, SS (Part No. 8700)Packing: Inner Column – Porous Polymer Mixture

Outer Column – Molecular SieveTemp: AmbientFlowrate: Helium, 65mL/minDetector: TCD

123

4

5

6 7

0 1 2 3 4 5 6 7 8 9 Min.

1059

1. Air + Carbon Monoxide (Inner Column)2. Methane (Inner Column)3. Carbon Dioxide (Inner Column)4. Oxygen (Outer Column)5. Nitrogen (Outer Column)6. Methane (Outer Column)7. Carbon Monoxide (Outer Column)

Air, CH4, CO

1. Oxygen2. Nitrogen3. Methane4. Carbon Monoxide

Column: 6ft x 1/8" OD, SS (Part No. 5605PC)Packing: Washed Molecular Sieve 5A, 80/100

(Part No. 5605)Temp: 35°CFlowrate: Helium, 30mL/minDetector: TCD

0 5 10 Min.

4

3

1

2

1064

1. Nitrogen2. Oxygen3. Carbon Monoxide4. Methane5. Carbon Dioxide

Column: 20ft x 1/8" OD, Ni (Part No. 27082PC)Packing: HayeSep® D, 100/120 (Part No. 2830)Temp: 25°CFlowrate: Helium, 30mL/minDetector: TCD

0 3 6 9 12 15 18 Min.

4

5

1

32

Permanent Gases

1450

Natural Gas

Ammonia

0 1 2 3 Min.

1

2 3

0 5 10 15 20 Min.

3

671

24

5

1. Air2. Ammonia (35%)3. Water (65%)

Column: 8ft x 1/8" OD, SS (Part No. 2803PC)Packing: HayeSep® P, 60/80 (Part No. 2803)Temp: 80°CFlowrate: Helium, 30mL/minDetector: TCD

1. Nitrogen2. Methane3. Carbon Dioxide4. Ethane5. Propane6. Isobutane7. n-Butane

Column: 30ft x 1/8" OD, SS (Part No. 12713PC)Packing: 30% DC-200 (500cstk) on Chromosorb® P-AW, 60/80

(Part No. 12713)Temp: 40°CFlowrate: Helium, 23mL/minDetector: TCD

1530

1770

Sulfur Compounds

1. Hydrogen Sulfide2. Carbonyl Sulfide3. Sulfur Dioxide4. Methyl Mercaptan

Column: 2m x 2mm ID, GlassPacking: Carbograph™ 1SC, 40/60 (Part No. 1734)Temp: 35°CFlowrate: Nitrogen, 20mL/minDetector: FPD

1800

1

2

3

4

0 1 2 3 Min.