gasification of woody biomass at the pilot-scale...overview of usda-forest service gasification...

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Gasification of Woody Biomass at the Pilot-Scale Thomas Elder Leslie H. Groom USDA-Forest Service Southern Research Station

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Page 1: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Gasification of Woody Biomass at the Pilot-Scale

Thomas ElderLeslie H. Groom

USDA-Forest ServiceSouthern Research Station

Page 2: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Gasifier work

• 25 kW downdraft gasifierwas acquired from Community Power Corporation

• Located at the Winn District Ranger Station on the Kistachie National Forest

• July 2008-Delivery

• October 2008-Comissioning

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 3: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Cooperative Projects

• The system is an integrated– Gasifier

– Spark ignited engine

– Electrical generator rated at 25 kW

• National Forest System – Functional Energy

• Southern Research Station – Feedstock Effect

• Forest Health Protection – Demonstration Projects

• Unique location

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 4: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Overview of USDA-Forest Service Gasification Project

• Located at Winn Ranger District Office

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 5: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Overview of USDA-Forest Service Gasification Project

• Feedstock (to date) has been southern pine and mixed hardwood chips

• Chips are loaded into two drying bins that hold ~500 pounds of dry chips each

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 6: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Overview of USDA-Forest Service Gasification Project

• The chips are sorted to size

• An auger transports the chips into the gasifier

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 7: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Overview of USDA-Forest Service Gasification Project

• The reaction is initiated with a resistance heater

• The gasifier is open to the atmosphere

• It has several heated zones with temperatures in the range of 600-900°C

• At these temperatures, and in an oxygen starved environment, the wood is converted into producer gas

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 8: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Gasifier dimensions and zones

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 9: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Overview of USDA-Forest Service Gasification Project

Frontiers in Biorefining, St. Simons Island, October 22, 2010

• Grate at the bottom of the gasifier

Page 10: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Overview of USDA-Forest Service Gasification Project

• The gas is exits the gasifier at ~ 500°C and is cooled in a tube and shell heat exchanger to ~110°C

• The heat exchanger requires periodic maintainence

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 11: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Overview of USDA-Forest Service Gasification Project

• Next the gas is filtered to remove particulates

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 12: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Overview of USDA-Forest Service Gasification Project

• The composition is monitored in real-time with an infrared gas analyzer

– O2

– CO

– CO2

– CH4

– H2

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 13: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Overview of USDA-Forest Service Gasification Project

• The cleaned and cooled gas goes to a conventional, spark-ignited, internal combustion engine

• The engine runs only on the producer gas

• This powers a generator capable of producing 25kW of electricity

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 14: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Overview of USDA-Forest Service Gasification Project

• The electricity generated is adequate to power the Winn Ranger District Office building, with the excess returned to the utility grid.

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 15: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Control Panel (one of them,anyway)

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 16: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Initial Research Runs

• Feedstock– Pine chips (MC ~12%)– Mixed hardwood chips (~50% oak, 25% elm, hickory, 25% sweetgum, maple, beech) (MC~13%)

• Flowrate– 70 scmh (heat exchanger issues)– 62 scmh– 55 scmh– 40 scmh (char, pressure issues)

• Typical run– ~5 hours total– ~1 hour from cold start to operating temperatures– ~ 1 hour at operating temperature to stabilize– Report data for last 3 hours of the run

• Results– Temperature profiles– Gas composition/efficiency

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 17: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Wood consumption

• Hourly consumption increases with gas flow rate

• Hardwood consumption is higher than pine

Frontiers in Biorefining, St. Simons Island, October 22, 2010

15

17

19

21

23

25

27

29

31

33

40 50 60 70

Kgh

-1

Flow rate (Nm3h-1)

feedstock consumption

pine

hardwood

Page 18: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Results-temperature profiles

0

100

200

300

400

500

600

700

800

900

1000

0 1 2 3 4 5 6

tem

pe

ratu

re (

°C)

run time (hours)

Hardwoods 40 scmh

level 1

level 2

level 3

level 4

level 5

grate

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 19: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Results-gas composition

0

5

10

15

20

25

0 1 2 3 4 5 6

gas

com

po

siti

on

(%

)

run time (hours)

hardwoods 40 scmh

CO

CO2

"CH4"

H2

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 20: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Results: Flow rate/feedstockTemperatures at Level 1

300

350

400

450

500

550

600

650

700

40 45 50 55 60 65 70

°C

flow rate (Nm3h-1)

level 1

pine

hardwood

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 21: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Results: Flow rate/feedstockTemperatures at Level 2

720

740

760

780

800

820

840

860

40 45 50 55 60 65 70

°C

Flow rate (Nm3h-1)

level 2

pine

hardwood

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 22: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Results: Flow rate/feedstockTemperatures at Level 3

820

830

840

850

860

870

880

890

900

910

920

40 45 50 55 60 65 70

°C

flow rate(Nm3h-1)

level 3

pine

hardwood

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 23: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Results: Flow rate/feedstockTemperatures at Level 4

820

830

840

850

860

870

880

890

900

910

40 45 50 55 60 65 70

°C

Flow rate (Nm3h-1)

level 4

pine

hardwood

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 24: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Results: Flow rate/feedstockTemperatures at Level 5

835

840

845

850

855

860

865

870

875

880

885

40 45 50 55 60 65 70

°C

Flow rate (Nm3h-1)

level 5

pine

hardwood

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 25: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Results: Flow rate/feedstockTemperatures at grate

600

620

640

660

680

700

720

740

40 45 50 55 60 65 70

°C

Flow rate (Nm3h-1)

grate

pine

harwood

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 26: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Results-Temperatures

• Temperatures for hardwoods are generally lower than for softwoods

• Temperature may increase slightly with flow rate

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 27: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Frontiers in Biorefining, St. Simons Island, October 22, 2010

19

19.5

20

20.5

21

21.5

22

22.5

23

0 1 2 3

CO

%

time (hours)

pine

hardwoods

10.5

11

11.5

12

12.5

13

13.5

14

0 1 2 3

CO

2 %

time (hours)

pine

hardwoods

2.5

3

3.5

4

4.5

5

5.5

6

0 1 2 3

CH

4%

time (hours)

pine

hardwoods

17.5

18

18.5

19

19.5

20

20.5

0 1 2 3

H2

%

time (hours)

pine

hardwoods

Page 28: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Results: Flow rate/feedstockCO %

20

20.2

20.4

20.6

20.8

21

21.2

21.4

40 45 50 55 60 65 70

% v

/v

Flow rate (Nm3h-1)

CO

pine

hardwood

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 29: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Results: Flow rate/feedstockCO2 %

11.6

11.8

12

12.2

12.4

12.6

12.8

13

13.2

40 45 50 55 60 65 70

% v

/v

Flow rate (Nm3h-1)

CO2

pine

hardwood

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 30: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Results: Flow rate/feedstockCH4 %

3

3.2

3.4

3.6

3.8

4

4.2

40 45 50 55 60 65 70

% v

/v

Flow rate (Nm3h-1)

CH4

pine

hardwood

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 31: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Results: Flow rate/feedstockH2 %

Frontiers in Biorefining, St. Simons Island, October 22, 2010

18.4

18.5

18.6

18.7

18.8

18.9

19

19.1

19.2

19.3

19.4

40 45 50 55 60 65 70

% v

/v

Flow rate (Nm3h-1)

H2

pine

hardwood

Page 32: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Energy content

5.75

5.8

5.85

5.9

5.95

6

6.05

6.1

40 45 50 55 60 65 70

MJm

-3

Flow rate (Nm3h-1)

Energy content

pine

hardwood

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 33: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Efficiency

0.68

0.69

0.7

0.71

0.72

0.73

0.74

0.75

0.76

0.77

40 45 50 55 60 65 70

Flow rate (Nm3h-1)

efficiency

pine

hardwood

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 34: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Gas composition and quality

• Composition varies over a fairly small range• Hardwoods generally produce less CO, more CO2

and H2

• H2 inversely related to temperature at level 5• “Methane” decreases with flow rate for

softwoods, levels off for hardwoods• Gas quality (as measured by heat of combustion)

– Decreases with flow rate for softwoods, levels off for hardwoods

• Efficiency increases with flow rate

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 35: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Next Studies-Feedstocks

• FACE sites

– Chips from Rhinelander have begun to arrive

• Impact of silviculture

– SRS-University of Arkansas-Monticello

• High Extractive Slash Pine

Frontiers in Biorefining, St. Simons Island, October 22, 2010

Page 36: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

CO

55 SCMH

feedstock

pine hardwoods poplar clean pine whole tree pine

% C

O

16

18

20

22

24

26

Page 37: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

CO2

55 SCMH

feedstock

pine hardwoods poplar clean pine whole tree pine

% C

O2

8

9

10

11

12

13

14

Page 38: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

CH4

55 SCMH

feedstock

pine hardwoods poplar clean pine whole tree pine

% C

H4

2.0

2.5

3.0

3.5

4.0

4.5

5.0

5.5

Page 39: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

H2

55 SCMH

feedstock

pine hardwoods poplar clean pine whole tree pine

% H

2

15

16

17

18

19

20

Page 40: Gasification of Woody Biomass at the Pilot-Scale...Overview of USDA-Forest Service Gasification Project •Feedstock (to date) has been southern pine and mixed hardwood chips •Chips

Next Studies-Processes

• GTL

– FT(?)

– Mixed alcohols?

– DME

• CHP

Frontiers in Biorefining, St. Simons Island, October 22, 2010