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Getting the most out of malt! Aaron MacLeod Maritime Craft Malt Workshop November 30 2018

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Page 1: Getting the most out of malt! - Atlantic Grains Councilatlanticgrainscouncil.ca/wp/wp-content/uploads/2017/03/... · 2018-12-17 · Nitrosamines NDMA in barley malt at levels greater

Getting the most out of malt!

Aaron MacLeodMaritime Craft Malt WorkshopNovember 30 2018

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Our Mission

▪ Support growth and innovation in craft food and beverage production through quality testing, technical support, & education.

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Investment

▪ The Center was awarded a total of $1,125,000 in start-up funding from federal, state, and private sources

▪ Empire State Development

▪ USDA Rural Business Development

▪ Appalachian Regional Commission

▪ George Alden Trust

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Grain Quality Testing

Barley Selection Package (Moisture,

Protein, Plump, Kernel Weight,

Germination Energy, RVA, & DON)

$75

Moisture & Protein $15

Starch $25

Germination (4mL, 8mL & Capacity) $20

DON (ELISA) $35

RVA (for pre-harvest germination) $25

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Malt Quality Testing

Full Malt Analysis – (Moisture, Assortment,

Friability, Fine Extract, Coarse Extract, F/C

Difference, β-glucan, FAN, soluble protein, S/T, DP,

α-amylase, color, filtration time, clarity)

$150

Basic Malt Analysis – (Moisture, Fine Extract,

β-glucan, FAN, DP, α-amylase, color, filtration time,

clarity)

$75

Enzymes Only (Diastatic Power & α-amylase) $50

Specialty Malt Analysis – (Moisture, Extract,

Color)$25

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Safety Testing

DON $35

Aflatoxin $35

Ochratoxin $30

Total Aerobic Count $30

Yeast & Mold Count $30

EColi $30

Nitrosamines (NDMA) $250

Glycosidic Nitrile $225

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Beer Quality Testing

Alcohol (ABV) $15

Bitterness (IBU) $20

Free Amino Nitrogen (FAN) $20

Beer QC (ABV, SG, RE, OE, RDF, IBU,

Color, pH)$50

Minerals (Ca, Mg, & Zn) $225

Beer Spoiler Alert™ $75

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Micro and Pilot Scale Malting

▪ Micromalting assessment

▪ Variety & Agronomy Trials

▪ Cornell

▪ Penn State

▪ Virginia Tech

▪ UD Davis

▪ Oregon State University

▪ Washington State University

▪ AAFC

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Using Third Party Labs

▪ Outsourcing some analysis can fill gaps in your quality assurance program by providing analysis that requires equipment you don’t have or validation that your own analysis makes sense.

▪ Third party analysis can be used for:

▪ Identify high quality raw materials

▪ Feedback for process optimization

▪ Characterizing finished products

▪ Monitoring process variation

▪ Validation of in house test methods

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Malting barley quality selection criteria

Characteristic SpecificationProtein content 9–12% dry matter

Plumpness >85% (over 6/64”)

Varietal purity >98%Germination Energy >95%Rapid Visco Analyzer >120 stirring number

DON <1.0ppm

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Moisture

▪ Barley moisture < 13.5% to ensure good storability

▪ High moisture encourages microbial growth and germination loss

▪ Exercise caution when drying barley grain as it can destroy germination (max 100°F)

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Grain Moisture

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0

10

20

30

40

50

60

70

80

90

100

32 41 50 59 68 77 86

Ma

xim

um

Nu

mb

er

of W

ee

ks

Storage Temperature (°F)

10%

12%

14%

16%

18%

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Protein

▪ Related to growing environment, agronomic practice, and genetics

▪ High protein limits extract potential

▪ Low protein limits enzymes

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Nitrogen Management

Nitrogen

Yie

ld

Gra

in P

rote

in

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Protein%

FRI%

EX%

SP%

S/T%

BGppm

DP°L

9.1 95 82.3 4.3 44.6 45 116

9.6 91 81.5 4.3 43.0 78 128

10.5 86 81.1 4.4 42.0 114 132

12.2 76 80.0 4.5 37.1 150 152

13.0 67 79.4 4.6 36.4 270 160

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Germination

▪ Will the barley germinate now?- Germinative energy

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Vitality versus Vigor

Variety 24h 48 h 72h 3 Day

Endeavor 70 27 1 98

Puffin 9 32 57 98

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Germination

▪ Will the barley germinate now?- Germinative energy

▪ Is it dead or just dormant?- Germinative capacity

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Dormancy

▪ Dormancy is characterized by the absence of germination in the presence of favorable conditions

▪ Subsides after a period of grain storage

▪ Varies by variety

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Germination & Dormancy - 20174

mL

Ge

rmin

ati

on

% (

at

ha

rve

st)

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Dormancy Break

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Germination

▪ Will the barley germinate now?- Germinative energy

▪ Is it dead or just dormant?- Germinative capacity

▪ Special care required for steeping?- Water sensitivity

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Water Sensitivity

▪ the failure of seed to germinate in excess moisture

▪ Special case of dormancy, but may not improve on storage

▪ Steeping process parameters must be adjusted to overcome water sensitivity

▪ Shorter wet immersions

▪ Longer air rests

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Water Sensitivity - 20178

mL

Ge

rmin

ati

on

%

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Water Sensivity

Day 1 Day 2 Day 3 Total

4 mL 47 51 2 100

8 mL 95 3 0 98

4 mL 33 91 3 97

8 mL 31 22 8 61

Barley A

Barley B

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Multi Step Immersion Steeping

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Germination

▪ Will the barley germinate now?- Germinative energy

▪ Is it dead or just dormant?- Germinative capacity

▪ Special care required for steeping?- Water sensitivity

▪ Long term storability of the barley?- sprouting/pre-germination

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Pre-Harvest Sprouting

▪ Caused by excessive moisture prior to harvest

▪ Can be visually detected at only at severe levels

▪ Pre-germination (early signs) can not be visually seen, but can be measured using Falling Number or Rapid Visco Anaysis(RVA)

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Risk of loss of germination on storage

▪ RVA > 120

▪ Barley is sound, high probability that germination will be retained on long term storage

▪ 50 < RVA < 120

▪ Barley is moderately pre-germinated, medium risk of germination loss on storage. Risk can be reduced if storage conditions are cool and dry

▪ RVA < 50

▪ Barley is severely pre-germinated, should be malted as soon as possible.

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Germination Loss

Storage Time

Ger

min

atio

n E

ner

gy

sound

moderatelypre-germinated

Severelypre-germinated

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Germination loss during storage

At Harvest July/Aug December

Moisture%

GerminationEnergy %

RVAGermination

Energy %

Scala 13.2 99 65 93

Synergy 13.3 98 75 98

Synergy 14.1 97 55 91

Scala 15.3 97 50 73

Conlon 15.3 94 30 73

Newdale 16.1 98 20 48

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Fusarium & DON

▪ Mycotoxin produced by fusarium mold

▪ Can survive the brewing process

▪ Fusarium is implicated in gushing and PYF

▪ Maltsters reject >1.0 ppm

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Fusarium and malting

▪ Highly infected barley can produce additional DON during malting

▪ Fusarium growth and DON production more likely after harvest then after long term storage

▪ Fusarium viability declines during storage

▪ The mold produces enzymes which cause damage to the protein structures

▪ Excessive soluble protein, FAN

▪ Elevated wort color

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Solutions - Grower

▪ Variety choice

▪ Look for varieties with resistance

▪ Rotation

▪ Do not follow corn or small grains

▪ Fungicide & Timing

▪ Tillage

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Solutions - Maltster

▪ Screen barley and malt for DON

▪ Have a “do not accept level” for incoming barley

▪ Cleaning

▪ DON is difficult to clean out of barley

▪ Small reductions in damaged kernels might be possible

▪ Storage

▪ Fusarium losses viability and is less likely to grow

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Solutions - Maltster

▪ Malting Practice

▪ Increased overflow in steep may help to rinse surface contamination

▪ Chemical Control (e.g. bleach, ozone)

▪ Research is inconclusive on safety or effectiveness

▪ Microbiological Control

▪ Adjusting steep water pH (alkaline or acidify)

▪ Protective cultures (lactic acid bacteria or geotricum yeast)

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Best practices to maintain high quality

▪ Harvest malting barley in a timely manner, ideally in good conditions when both grain and straw are mature.

▪ Dry grain gently (<100°F) to < 13.5% moisture

▪ Obtain an accurate/representative sample for testing

▪ Handle harvested grain gently to avoid breakage and hull abrasion

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Keys to success

▪ Know your market

▪ Discuss variety choice, quality specifications, & price with maltster in advance

▪ Plan for alternative markets if quality isn’t met

▪ Know your product

▪ Send a representative sample for testing

▪ Monitor quality during storage

▪ Keep a representative sample

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What Is Quality?

▪ Fitness for use

▪ functional characteristics

▪ Meets customer expectations

▪ Free from defects

▪ Preforms well in the brewery

▪ Safe

▪ Brand Values

▪ the art of malting

▪ Distinctive, innovative, local, sustainable, flavorful

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Understanding Malt Analysis

▪ What do we use it for?

▪ Process quality control

▪ Comparing different malts

▪ Predicting brewingperformance

▪ specifications

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What do brewers need?

▪ High BrewhouseYield

▪ high extract

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Endosperm Modification

▪ Barley genetics

▪ Kernel hydration

▪ Germination moisture/temperature/time

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Ease of modification

Bet

a-G

luca

n(m

g/L

)

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What do brewers need?

▪ High BrewhouseYield

▪ high extract

▪ Efficient conversion

▪ Adequate alpha amylase

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α-amylase

▪ Important enzyme for rapid degradation of starch during mashing

▪ Is produced during malting process

▪ Promotes fast “wort conversion”

▪ Influenced by variety and malting conditions

▪ Specifications:

▪ Moderate: 40 - 55 D.U.

▪ High: 55 - 70 D.U.

▪ Very High: >70 D.U (distillers)

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Action of α-amylase

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Steep 1 2 3 4 5

a-A

myla

se A

ctivity

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What do brewers need?

▪ High BrewhouseYield

▪ high extract

▪ Efficient conversion

▪ Adequate alpha amylase

▪ Good wort separation

▪ low β-glucan, good hull retention

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1.35

1.40

1.45

1.50

1.55

1.60

1.65

1.70

0 100 200 300 400 500 600

beta-glucan (mg/L)

wo

rt v

isco

sity

(cP

)

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What do brewers need?

▪ High BrewhouseYield

▪ high extract

▪ Efficient conversion

▪ Adequate alpha amylase

▪ Good wort separation

▪ low β-glucan, good hull retention

▪ Fermentability

▪ adequate DP, adequate FAN

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Diastatic Power

▪ Represents total activity of starch degrading enzymes

▪ Primarily related to β-amylase activity which produces fermentable sugars

▪ Influenced by variety and protein content

▪ Specification ranges:

▪ High > 150 °L

▪ Moderate 100-150°L

▪ Low < 100°L

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Action of β-amylase

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Impact of mash temps on enzymes

110 120 130 140 150 160

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Malt Sensory – ASBC Hot Steep

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Developing flavor in pale malt

▪ Use higher protein barley

▪ Promote modification

▪ Higher steep out moisture

▪ Extend germination time

▪ Higher cure temp (195 vs 185°F)

▪ Raise temperature (130 - 150°F) at higher moisture

▪ Increasing color will reduce DP

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Nitrosamines

▪ NDMA in barley malt at levels greater than 10 ppb is considered avoidable contamination under section 406 of the Federal Food, Drug, and Cosmetic Act.

▪ The action level of 10 ppb NDMA in barley malt applies to all barley malt produced after October 1, 1980

▪ Actionable if a composite of 10 subsamples of finished product barley malt contains greater than 10 ppb NDMA

▪ Action levels represent limits at or above which FDA can take legal action to remove products from the market.

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Nitrosamines

▪ Risk Factors

▪ Direct fire kilning

▪ Industrial emissions

▪ Mitigation

▪ Indirect fire kilns

▪ Low NOx burners

▪ Burn sulfer in the kiln

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Glycosidic Nitrile

▪ Risk Factors

▪ Barley genetics

▪ All malt spirit production

▪ Copper in descending vapor phase

▪ Mitigation

▪ Non-GN producing or Low GN varieties

▪ Malting conditions (low temp, low moisture, short germination)

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Malt Quality

Characteristic

Adjunct

Brewing

All Malt

Brewing

Total protein (%) >11.5% <11.5%

Soluble/Total protein (%.) 40-47% 38-45%

Extract (%) >80.0% >81.0%

Diastatic power (oL) >150 100 -120

Free Amino Nitrogen 180 - 220 120 - 180

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Spring 2-Row Spring 6-Row Winter 2-Row

Protein, % 11.8 12.7 9.5

Extract, % 80.0 79.0 82.0

β-glucan, % 120 260 70

FAN, mg/L 200 230 150

Diastatic Power, °L 130 140 110

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CrispMarrisOtter

SimpsonsGoldenPromise

WeyermanPaleAle

Rahr2-Row

Moisture, % 3.1 4.4 4.8 4.8

Extract, % 81.8 81.2 81.0 81.8

Protein, % 9.4 9.6 11.0 11.6

Friability, % 94.3 94.5 87.2 85.6

Color, °L 4.3 3.2 3.95 2.2

Kolbach, S/T % 47.1 46.7 39.5 43.0

FAN 154 192 148 187

β-glucan. % 212 64 114 118

Diastatic Power, °L 75 100 105 140

α-amylase, DU 40.0 53.2 59.5 63.0

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Beyond the numbers…

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Growth in Craft Beer Market Share

Source: Brewer’s Association

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Projected malt usage

Source: Brewer’s Association

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North American Craft Maltsters Guild

▪ Craft Malt is made using a majority (greater than 50% by weight) of locally grown grains

▪ Craft Malthouse producing minimum 5 metric tons & maximum 10,000 metric tons product/year

▪ Ownership by non-craft malt company does not exceed 24%

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Find a craft malthouse near you!

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February 2-3 . 2019

Bozeman, Montana

www.craftmalting.com

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▪ “If you want something different, then it isn’t going to be the same”

-Jason Sahler, Strong Rope Brewery