glass and ceramic composites for high technology applications … poster prague.pdf · glass and...

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Glass and Ceramic Composites for High Technology Applications (GlaCERCo) Marie Curie Initial Training Network (ITN) www.glacerco.eu 5 Academic Partners, 5 Companies, 17 Early Stage Researchers, 6 Experienced Researchers GlaCERCo-ITN objectives to develop advanced knowledge of glass based materials and to establish innovative, cost-competitive and environmentally acceptable materials and processing technologies. To offer multidisciplinary training in the field of high-tech glasses and composites, in close contact with companies and universities. To strengthen and structure initial training of early stage and experienced researchers (ESRs/ERs) in materials science at a European level. To attract students to scientific careers. To provide trained researchers with the necessary skills to work in industry. To improve career prospects. GlaCERCo training-through-research New high-tech glass-based materials (glasses, glass-ceramics, glass and glass-ceramic composites and fibres) are themselves an emerging supra-disciplinary field: expertise of these new materials brings competitiveness in strategic fields, such as medicine (bioactive glasses as bone replacement and drug delivery systems), telecommunications (glass devices for broad- band applications), photonics (glass based photonic sensors), clean energy (Solid Oxide Fuel Cells glass sealants, thermoelectric materials), waste management (vitrification and reuse of wastes), oil & gas and petrochemical industries (glass reinforced polymer pipes). GlaCERCo partners [scientists in charge] Politecnico di Torino (IT) Project coordinator: Prof. Monica Ferraris [email protected] University of Erlangen-Nuremberg (DE) Prof. Aldo R. Boccaccini [email protected] CNRS - University of Rennes 1 (FR) Dr. Catherine Boussard [email protected] University degli Studi di Padova (IT) Dr. Enrico Bernardo [email protected] Institute of Physics of Materials (CZ) Prof. Ivo Dlouhy [email protected] Element Materials Technology Hitchin Ltd (GB) Dr. Rod Martin [email protected] Colorobbia Italia SpA (IT) Dr. Giovanni Baldi [email protected] Nanoforce Technology Ltd (GB) Prof. Mike Reece [email protected] nLight Corporation (FI) Dr. Laetitia Petit [email protected] Nuova Ompi s.r.l. (IT) Dr. Fabiano Nicoletti [email protected] The research leading to these results has received funding from the European Union’s Seventh Framework Programme managed by REA-Research Executive Agency http://ec.europa.eu/research/rea and it participates in a Marie Curie Action (GlaCERCo GA 264526). Vitrification and reuse of waste Vitrification and reuse of several types of waste (e.g. municipal waste incinerator bottom ash, biomass ash, air pollution control residues, etc. and combination of them) and investigation of the reuse of the so obtained glasses and glass- ceramics as raw material for the manufacturing of building materials. GlaCERCo ESRs developed new porous glass- ceramic insulation materials from waste with properties comparable to commercial products, with novel processes (Patent application, 2013). The obtainment of foams or lightweight tiles was accompanied by the stabilization of pollutants. Design, synthesis and characterisation of advanced composites Composite materials are fast becoming a material of choice for several industrial applications (such as gas & oil petrochemical industry, armour applications, etc.) because of their excellent resistance to aggressive chemicals, their low specific weight and stiffness and potential lower cost. GlaCERCo ESRs/ERs are developing and characterising new advanced composites with improved mechanical and corrosion resistance properties. Smart coatings and numerical modelling of through thickness degradation of glass fibre reinforced composite in ultra-hostile environment are under development. The reinforcements studied include glass fibres, carbon nanotubes, boron nitride nanotubes and graphene. BN Nano-Tubes bridging in borosilicate glass with 5% BNNT Al 2 O 3 - 5vol% graphene sample showing graphene pull out. Special glasses for photonic devices and thermoelectric applications. The material preparation routes include conventional glass preparation by a melt- quenching technique, but also advanced glass processing: glass drawing by rod-in-tube or capillary methods, direct laser writing of waveguides on glass, elaboration of amorphous thin films by magnetron RF sputtering of glassy targets. Borosilicate glasses for 1.5 µm lasers with improved emission properties and reduced power losses have been developed by GlaCERCo ESRs. Easy-to-draw new telluride glass fibres presenting low attenuation factors at 10 µm for optical sensing were fabricated. Stable telluride glass for thermoelectric applications exhibiting a low resistivity and a high stability were obtained. New glasses suitable for medical applications Development of glass-based biomaterials for drug release (mesoporous bioactive glasses, microcellular ceramics, composite coatings) and bone substitution (i.e. glass and glass-ceramic macroporous scaffolds, fibre reinforced composite scaffolds) and arthoprosthesis (i.e. bioactive glasses and composites). The innovative glass, glass-ceramic and composite coatings and scaffolds developed by the GlaCERCo researchers show improved mechanical properties and bioactivity with very good prospects for their further exploitation. Joining and coating of different materials Self-healing, multi-layered coatings and innovative joining materials are designed for specific applications (e.g. nuclear applications, bioactive scaffolds and implants, solid oxide fuel cells, petrochemical industry). The coating and joining materials are prepared and applied by slurry methods, colloidal processing including electrophoretic deposition of nanoparticles, sputtering or Spark Plasma Sintering. Customised mechanical tests for joined structures are under development. Shear strength evaluation: torsion test. Crofer22APU/ sealant/Crofer22APU Politecnico di Torino & University of Padova NANOFORCE COLOROBBIA ELEMENT ELEMENT CNRS – Univ. of Rennes 1 IPM NANOFORCE POLITO Politecnico di Torino Politecnico di Torino SiC SiC Politecnico di Torino Politecnico di Torino NANOFORCE Politecnico di Torino CNRS ELEMENT Politecnico di Torino University of Padova WP1 WP2 WP4 WP5 WP3 Glass and glass-ceramic foams from recycled glass & Fe-rich glass or Fe-rich metallurgical slag WP leader: University of Padova (E. Bernardo) WP leader: Institute of Physics and Materials (I. Dlouhy) WP leader: Univ. of Erlangen-Nuremberg (A.R. Boccaccini) WP leader: CNRS - Univ. of Rennes 1 (C. Boussard) WP leader: Politecnico di Torino (M. Salvo, M. Ferraris) [email protected]

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Page 1: Glass and Ceramic Composites for High Technology Applications … poster Prague.pdf · Glass and Ceramic Composites for High Technology Applications (Gla CERCo) Marie Curie Initial

Glass and Ceramic Composites for High

Technology Applications (GlaCERCo)

Marie Curie Initial Training Network (ITN)www.glacerco.eu

5 Academic Partners, 5 Companies,

17 Early Stage Researchers, 6 Experienced Researchers

GlaCERCo-ITN objectives• to develop advanced knowledge of glass

based materials and to establish innovative,cost-competitive and environmentally

acceptable materials and processing

technologies.

• To offer multidisciplinary training in the field of

high-tech glasses and composites, in close

contact with companies and universities.

• To strengthen and structure initial training of

early stage and experienced researchers

(ESRs/ERs) in materials science at a European

level.

• To attract students to scientific careers.

• To provide trained researchers with the

necessary skills to work in industry.

• To improve career prospects.

GlaCERCo training-through-research

New high-tech glass-based materials (glasses,

glass-ceramics, glass and glass-ceramic

composites and fibres) are themselves an

emerging supra-disciplinary field: expertise of

these new materials brings competitiveness in

strategic fields, such as

medicine (bioactive glasses as bone

replacement and drug delivery systems),telecommunications (glass devices for broad-

band applications),

photonics (glass based photonic sensors),

clean energy (Solid Oxide Fuel Cells glass

sealants, thermoelectric materials),

waste management (vitrification and reuse of

wastes),

oil & gas and petrochemical industries (glassreinforced polymer pipes).

GlaCERCo partners [scientists in charge]

Politecnico di Torino (IT)

Project coordinator: Prof. Monica Ferraris [email protected]

University of Erlangen-Nuremberg (DE)

Prof. Aldo R. Boccaccini [email protected]

CNRS - University of Rennes 1 (FR)

Dr. Catherine Boussard [email protected]

University degli Studi di Padova (IT)

Dr. Enrico Bernardo [email protected]

Institute of Physics of Materials (CZ)

Prof. Ivo Dlouhy [email protected]

Element Materials Technology Hitchin Ltd (GB)

Dr. Rod Martin [email protected]

Colorobbia Italia SpA (IT)

Dr. Giovanni Baldi [email protected]

Nanoforce Technology Ltd (GB)

Prof. Mike Reece [email protected]

nLight Corporation (FI)

Dr. Laetitia Petit [email protected]

Nuova Ompi s.r.l. (IT)

Dr. Fabiano Nicoletti [email protected]

The research leading to these results has received funding from the European

Union’s Seventh Framework Programme managed by REA-Research

Executive Agency http://ec.europa.eu/research/rea and it participates in a

Marie Curie Action (GlaCERCo GA 264526).

Vitrification and reuse of waste

Vitrification and reuse of several types of waste(e.g. municipal waste incinerator bottom ash,

biomass ash, air pollution control residues, etc.

and combination of them) and investigation of

the reuse of the so obtained glasses and glass-

ceramics as raw material for the manufacturing

of building materials.

GlaCERCo ESRs developed new porous glass-ceramic insulation materials from waste with

properties comparable to commercial products,

with novel processes (Patent application, 2013).

The obtainment of foams or lightweight tiles was

accompanied by the stabilization of pollutants.

Design, synthesis and

characterisation of advanced composites

Composite materials are fast becoming amaterial of choice for several industrial

applications (such as gas & oil petrochemical

industry, armour applications, etc.) because of

their excellent resistance to aggressive

chemicals, their low specific weight and stiffness

and potential lower cost. GlaCERCo ESRs/ERs are

developing and characterising new advanced

composites with improved mechanical andcorrosion resistance properties. Smart coatings

and numerical modelling of through thickness

degradation of glass fibre reinforced composite

in ultra-hostile environment are under

development.

The reinforcements studied include glass fibres,carbon nanotubes, boron nitride nanotubes and

graphene.

BN Nano-Tubes bridging in

borosilicate glass with 5% BNNT

Al2O3- 5vol% graphenesample showing graphene

pull out.

Special glasses for photonic

devices and thermoelectric applications.

The material preparation routes include

conventional glass preparation by a melt-

quenching technique, but also advanced glass

processing: glass drawing by rod-in-tube or

capillary methods, direct laser writing of

waveguides on glass, elaboration of amorphousthin films by magnetron RF sputtering of glassy

targets.

Borosilicate glasses for 1.5 µm lasers with

improved emission properties and reduced

power losses have been developed by

GlaCERCo ESRs.

Easy-to-draw new telluride glass fibres presenting

low attenuation factors at 10 µm for optical

sensing were fabricated.

Stable telluride glass for thermoelectric

applications exhibiting a low resistivity and a high

stability were obtained.

New glasses suitable for

medical applications

Development of glass-based biomaterials for

drug release (mesoporous bioactive glasses,

microcellular ceramics, composite coatings) and

bone substitution (i.e. glass and glass-ceramic

macroporous scaffolds, fibre reinforced

composite scaffolds) and arthoprosthesis (i.e.bioactive glasses and composites). The

innovative glass, glass-ceramic and compositecoatings and scaffolds developed by the

GlaCERCo researchers show improved

mechanical properties and bioactivity with very

good prospects for their further exploitation.

Joining and coating of different

materials

Self-healing, multi-layered coatings and

innovative joining materials are designed for

specific applications (e.g. nuclear applications,bioactive scaffolds and implants, solid oxide fuel

cells, petrochemical industry). The coating and

joining materials are prepared and applied by

slurry methods, colloidal processing including

electrophoretic deposition of nanoparticles,

sputtering or Spark Plasma Sintering. Customised

mechanical tests for joined structures are under

development.

Shear strength

evaluation: torsion test.

Crofer22APU/

sealant/Crofer22APU

Politecnico di Torino

& University of Padova

NANOFORCE COLOROBBIA

ELEMENT

ELEMENT

CNRS – Univ. of Rennes 1

IPM

NANOFORCE

POLITO

Politecnico di Torino

Politecnico di Torino

SiC

SiC

Politecnico di Torino

Politecnico di Torino

NANOFORCE

Politecnico di Torino

CNRS

ELEMENT

Politecnico di Torino

University of Padova

WP1

WP2

WP4

WP5

WP3

Glass and glass-ceramic foams from recycled glass

& Fe-rich glass or Fe-rich metallurgical slag

WP leader: University of Padova (E. Bernardo)

WP leader: Institute of Physics and Materials (I. Dlouhy)

WP leader: Univ. of Erlangen-Nuremberg (A.R. Boccaccini)

WP leader: CNRS - Univ. of Rennes 1 (C. Boussard)

WP leader: Politecnico di Torino (M. Salvo, M. Ferraris)

[email protected]