Carbohydrate Research Vol. 391, 2014

Contents

FULL PAPERS

Synthesis

Linear synthesis and conformational analysis of the pentasaccharide repeating unit of the cell wall O-antigen ofEscherichia coli O13

pp 9–15

Abhishek Santra, Anshupriya Si, Rajiv Kumar Kar, Anirban Bhunia*, Anup Kumar Misra*

O

OR3

R5R6

R7R8

R3'R4'

R5'

O

OR5R6

R7R8

R3'R4'

R5'

R3

Flavonols R3:OHFlavones R3:H

Flavanols R3: OHFlavanones R3: H

O

O R4'

R7

R5

OH

OH

HO

OHOH

OOH

HO

Chalcone

Stilbene

Isoflavonoids

YjiC

UDP-α-D-glucose UDPFlavonolsFlavonesFlavanols

ChalconeStilbeneIsoflavonoids

Flavanones Glucosides

6-Triazolyl-6-deoxy-b-cyclodextrin derivatives: synthesis, cellular toxicity, and phase-solubility study pp 22–28

Hoa Thi Le, Hyun Mi Jeon, Choon Woo Lim*, Tae Woo Kim*

Selective 4,6-O-benzylidene formation of methyl a-DD-mannopyranoside using 2,6-dimethylbenzaldehyde pp 31–36

Louis J. Liotta*, Jennifer F. Chalmers, Jessica N. Falco Marshall, Timothy E. Ferreira, Hannah E. Mullen, Nicholas J. Pace

iii

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Carbohydrate Research

journal homepage: www.elsevier .com/locate /carres

Synthesis of Calocybe indica var. APK2 polysaccharide repeating unit pp 43–47

Lei Zhang, Xiangming Zhu*

O

OMPOHO

OHOH

OOH

O

OHOH

OH

OO

OHOH

O

OHO

OHOH

HOO

OHHO

Synthesis of a-DD-glucosyl substituted methyl glycosides of 3-deoxy-a-DD-manno- and DD-glycero-a-DD-talo-oct-2-ulosonicacid (Kdo/Ko) corresponding to inner core fragments of Acinetobacter lipopolysaccharide

pp 66–81

Barbara Pokorny, Sven Müller-Loennies, Paul Kosma*

OHO

HOHO

OHO

OMe

O

CO2-Na+

OH/OP(=O)(OH)2

OHOH

H/OH

An improved synthesis of 3,6-anhydro-DD-glucal and a study of its unusual chemical reactivity pp 106–111

Vikram Basava, Sergiu M. Gorun, Cecilia H. Marzabadi*

OTsO

HOHO

O

O

OHH

6eq LiAlH4 / THF

75oC overnight

1 2

Biochemistry and Enzymes

Selective detection of epimeric pentose saccharides at physiological pH using a fluorescent receptor pp 61–65

Matthew I. Gibson, João Neres, Elizabeth Fullam*

iv Contents / Carbohydrate Research 391 (2014) iii–vii

Production of rhamnolipid surfactant and its application in bioscouring of cotton fabric pp 97–105

Zulfiqar Ali Raza*, Aisha Rehman, Muhammad Tahir Hussain, Rashid Masood, Anwar ul Haq, Muhammad Tahir Saddique,Amjed Javid, Niaz Ahmad

Characterization, Naturalproducts

Inhibitory effect and mode of action of chitosan solution against rice bacterial brown stripe pathogen Acidovorax avenaesubsp. avenae RS-1

pp 48–54

Chunlan Yang, Bin Li*, Mengyu Ge, Kaile Zhou, Yanli Wang, Ju Luo,Muhammad Ibrahim, Guanlin Xie, Guochang Sun*

Polysaccharides

Binding assay between murine Dectin-1 and b-glucan/DNA complex with quartz-crystal microbalance pp 1–8

Shinichi Mochizuki, Hiromi Morishita, Yoshiyuki Adachi, Yoshiki Yamaguchi, Kazuo Sakurai*

SPGdA(S)

SPG/dA(S)

dAGG

F (H

z)

Time (s)

-500

-400

-300

-200

-100

00 500 1000 1500

SPG/dA(S)

dA(S)

Structural characterization of an acetylated glucomannan with antiinflammatory activity and gastroprotective propertyfrom Cyrtopodium andersonii

pp 16–21

José P. Parente*, Camila R. Adão, Bernadete P. da Silva, Luzineide W. Tinoco

→4)-2-O-acetyl-β-D-Manp-(1→→4)-β-D-Glcp-(1→→4)-β-D-Manp-(1→

OOH

HOO

HO O

OHHO

O

HO

OO

HOO

HOO

Contents / Carbohydrate Research 391 (2014) iii–vii v

Physical, X-Ray, Chromatography

Supramolecular self-assembled aggregates formed by pentacosa-10,12-diynyl amidomethyl-b-cyclodextrin pp 37–42

Eunae Cho, Hwanhee Kim, Jee Eun Yang, Bong-Hyun Jun, Seung R. Paik, Seunho Jung*

Fast separation and determination of free myo-inositol by hydrophilic liquid chromatography pp 55–60

Jirí Pazourek*

NOTES

Synthesis

Synthesis and X-ray studies of novel 3-C-nitromethyl-hexofuranoses pp 82–88

Maris Turks*, Krista Veze, Gl�ebs Kisel�ovs, Jevgen�ija Mackevica, Jevgen�ija Lugin�ina, Anatoly Mishnev, Dean Markovic

HClO4–silica-catalysed regioselective opening of benzylidene acetals and its application towards regioselective HO-4glycosylation of benzylidene acetals in one-pot

pp 93–96

Saidulu Dara, Varma Saikam, Mahipal Yadav, Parvinder Pal Singh*, Ram A. Vishwakarma*

ORORO

OOBnO

OP

OOOPh

OP

OHOBnO

OP

Regioselectivebenzylidene ring opening

RORORO

OR

(14 examples)(4 examples)

Tandem regioselectivering opening-glycosylation

RO

vi Contents / Carbohydrate Research 391 (2014) iii–vii

Polysaccharides

Structure of the capsular polysaccharide of Acinetobacter baumannii ACICU containing di-N-acetylpseudaminic acid pp 89–92

Sof�ya N. Senchenkova, Alexander S. Shashkov, Mikhail M. Shneider, Nikolay P. Arbatsky, Anastasiya V. Popova,Konstantin A. Miroshnikov, Nikolay V. Volozhantsev, Yuriy A. Knirel*

CH2O

HO

O

CH2O

HO

HNAc

CH2OHO

HO

OO

OH

HO

OHHO2C

AcNH O

CH3 OH

HO

AcNH

O

CORRIGENDA

Corrigendum to ‘‘Non-enveloped virus reduction with quaternized chitosan nanofibers containing graphene’’[Carbohydr. Res. 380 (2013) 137–142]

pp 29

Bingyu Bai, Xue Mi, Xu Xiang, Patricia A. Heiden, Caryn L. Heldt*

Corrigendum to ‘‘Electrochemical characterization of globotriose-containing self-assembled monolayers on nanoporousgold and their binding of soybean agglutinin’’ [Carbohydr. Res. 373 (2013) 9–17]

pp 30

Binod Pandey, Yih Horng Tan, Archana R. Parameswar, Papapida Pornsuriyasak, Alexei V. Demchenko, Keith J. Stine*

*Corresponding authorSupplementary data available via ScienceDirect

COVER

Multi-functionalisation of cyclodextrins (CD) has entered a new era thanks to the regioselective chemistry developed by M. Sollogoub’s group.As illustrated on the cover, many applications can now be reached using CDs with various functions on specific positions. An example offunctionalisation of CDs is given in the first issue of this journal. Image realised by Mickaël Ménand.

Available online at www.sciencedirect.com

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Abstracted/Indexed in: Chem. Abstr.: Curr. Contents: Phys., Chem. & Earth Sci. Life Sci. Current Awareness in Bio. Sci. (CABS).Science Citation Index. Full texts are incorporated in CJELSEVIER, a file in the Chemical Journals Online database whichis availabe on STN� International. Also covered in the abstract and citation database Scopus�. Full text available onScienceDirect�

ISSN 0008-6215

Contents / Carbohydrate Research 391 (2014) iii–vii vii