hach ² your partner for water and wastewater analysis - your partne… · information software...
TRANSCRIPT
HACH – YOUR PARTNER FOR WATER
AND WASTEWATER ANALYSIS
Yogananda Maspolim, PhD, BSc
Sales Engineer, Hach
CONTENT
• Hach as part of Danaher Water Quality Platform.
• Hach plays the leading role in water analysis globally.
• Reliable, easy-to-use water analysis solutions.
• How can Hach help in environmental wastewater application?
• COD analysis – how to choose the right instrument?
HACH IS PART OF DANAHER,
CONSISTING OF FIVE STRATEGIC PLATFORMS
3
MARKET REACH
4
• Wastewater Treatment Municipal/ Industry
• Municipal Drinking Water
• Chemical Industry
• Power & Utilities
• Food & Beverage
• Engineers & Consultants
• Labs
• Life Science
• Landfill
• Pulp & Paper
• Electroplating
• Biogas
• Electronics
• Fish Farming
Real-world experience within
each vertical market
DANAHER WATER QUALITY PLATFORM
SOLUTIONS AT EVERY STAGE
5
HACH - THE GLOBAL LEADER IN WATER ANALYSIS
6
COMPANY PROFILE
• 80+ years of pioneering new techniques
for water analysis
• Developed more EPA approved methods
than anyone else
• Expertise in drinking water, municipal &
industrial wastewater, beverage and
power
• 3900 employees worldwide
• Manufacturing & engineering locations in
USA, Germany, France , Switzerland and
China
• Direct sales & service in more than 40
countries
• The largest direct sales force in the
industry
• Complimented by representatives or
distributors in an additional 50
countries
Ensuring water quality for people around the world
GLOBAL FOOTPRINT
7
Sao Paulo, Brazil
Regional Headquarters
Loveland, CO, USA
Regional Headquarters
Production Facility and
Research & Development
Düsseldorf, Germany
Regional Headquarters and
Research & Development Berlin, Germany
Production Facility
Grant Pass, Oregon, USA
Research & Development Shanghai, China
Research & Development
Production Facility
Ames, Iowa, USA
Production Facility
Expanding through growth and acquisitions
Geneva, Switzerland
Research & Development
Production Facility
Lyon, France
Production Facility
PT. DHH TRADING INDONESIA
Jakarta
Surabaya
Medan
Legend
Head Office
Business Development Team
Balikpapan
Pekanbaru
Cilegon
• PT DHH TRADING INDONESIA – Est March 2019
• Head office at WTC , Sudirman
• 15 Associates – Business Dev , Service , HR
• 3 Authorized distributors
HACH COMPANY
• Founded in 1947 in Ames, Iowa
• Hach Headquarters moved to Loveland, CO in 1978
• Purchased by Danaher in 1999
• Merged with Dr. Bruno Lange – Berlin
• Hach keeps growing…
HACH KEEPS GROWING…
10
1998
1999 2001
2002
2003
2005
1997
1996
2007
2008 2000
2009
Dr. Bruno Lange founded his company
in 1933 in Berlin, Germany
Clifford and Kathryn Hach started
in 1942 in Ames, Iowa
2010
2011
2012
2013
2014 +
Environment analysis is a long-standing commitment for us
2017
HACH PROVIDES RELIABLE, EASY-TO-USE SOLUTION
11
1954: Hach introduced the DC-DR
photometer to feature
precalibrated water tests.
2012: Hach launched DR6000 UV-VIS
spectrophotometer with 250
preprogrammed water tests.
• Hach preprogrammed water testing methods for
portable and laboratory application.
• TNTplus vial for fast, reliable measurement.
https://www.youtube.com/watch?v=j9A40Y8_XJU
• Low-maintenance, robust analyzer designed for harsh
sample and environmental condition.
Easy-to-use TNTplus vial chemistry
Total Organic Carbon online analyzer
with advanced oxidation technology
for dirty sample
HACH SERVICES AND ASSISTANCE
12
On-Site • Trainings, seminars,
workshops
• Symposia
• Customer Advisory Board
• Exhibitions
Device • On-site
• Service hotline
• Device instruction
• Installation
• Service contracts
Quality and security • Standard solutions
• Test equipment
• Proficiency test
• Essential documentation
• Hazard information
Information • Hotlines
• Website
• E-shop
• Order tracking
• Configurators
• Newsletters
• Practice reports
Environmental • Minimal chemical use
• Free redemption of used
reagents
• Detailed product labeling
• Profesional recycling
• Collection, treatment and
proper disposal
Consulting • Expert advice
• Detailed needs analysis
• Knowledge of regional
needs
• Solutions to meet the
requirements
• Results to ensure quality
and save time
All services from a single source
• Product or application support: https://support.hach.com/app/home
• Laboratory Hach standard testing methods: https://www.hach.com/wah
COMPLETE RANGE OF APPLICATION &
SOLUTIONS
13
LABORATORY/FIELD
Meters
Titrators
Reagents
Photometer
Visual Tests
Information Software
Services
- O2, pH, Conductivity
- Turbidity
- Microbiology
- Nutrients
- COD, TOC, AOX, BOD
- Chlorine
- Metals
- Silica
- etc.
PROCESS/ONLINE
Controllers
Probes
Analysers
Reagents
Installation/Supplies
Real Time Control Units
Services
- O2, pH, Conductivity
- Turbidity
- Sludge, Solids
- Nutrients
- TOC, SAC
- Chlorine, Ozone
- Flow, Level, Pressure
- Chloramine
- Streaming Current
SAMPLERS AUTOMIZATION
Pressure/Vacuum
Peristaltic
- Portable
- Stationary
- Real Time Process Control (RTC)
- Prognosys for equipment diagnostic
- Lab-Robot
What we offer What we measure What we offer What we measure
TOWARDS THE FUTURE – CLAROS SOFTWARE
14
https://support.hach.com/app/answers/answer_v
iew/a_id/1019995/loc/en_US
https://support.hach.com/app/answers/answer
_view/a_id/1009280
15
Budgets
• Tight budgets and high expectations for effluent
quality
Regulations / Compliance
• Mandated permits sets standards for effluent
• Increasingly restricting the amount of pollutants that
can be discharged.
Growth / Construction
• Population growth
• Plant expansion projects
• Advanced treatment processes
Aging Systems
• Collection systems and plant processes
• Equipment
• Plant operators
CHALLENGES IN WASTEWATER MANAGEMENT TO GO FROM THIS . . .
TO THIS . . .
• Online Instrumentation
– Process Control and Early Warning
• Sampling and Flow equipment
• Laboratory Equipment
– Verification of Online Instruments
– Regulation / Compliance
• Plant Efficiency and Savings
– Aeration – Controlling Blowers with dissolved oxygen monitoring
– Nutrient removal –Monitoring nutrient concentration, aeration,
polymer usage
– Effluent discharge- Samplers, TOC, pH, Nitrogen components
– Regulations / Compliance – Permit violations are expensive
https://youtu.be/GeWf7KZInI0
HOW CAN HACH HELP IN WASTEWATER APPLICATION?
HOW CAN HACH HELP IN WASTEWATER APPLICATION?
17
• Example is oleochemical industry for fatty acids and fatty alcohol (Permen-
LH-5-2014).
Parameter Kadar paling
tinggi
Hach laboratory
method
APHA
standard
method
Hach Online
analyzer option
BOD 125 mg/L Hach method 8043,
10360
Yes Yes
COD 250 mg/L Hach method 8000 Yes Yes
TSS 150 mg/L Hach method 8158,
8164
Yes Yes
Minyak dan lemak 15 mg/L Hach method 10056 Yes Yes
Fosfat 5 mg/L Hach method 8048 Yes Yes
Amonia (NH3N) 10 mg/L Hach method 8038 Yes Yes
pH 6 - 9 Hach method 8156 Yes Yes
18
Effluent Quality Monitoring System (A Case Study)
19
• Industrialization led to growth of production facilities, resulting in water
pollution in receiving water bodies.
• Regulatory guidelines were set up in most polluting industrial categories
to monitor pollutants discharge (e.g. distillery, F&B, textile,
chemical/petrochemical, tannery, pulp & paper, metal processing,
slaughterhouse, etc.).
• Key parameters identified: COD, BOD, pH, TSS, flow, and selectively other
parameters (e.g. nickel, arsenic, chromium, etc.).
• Real-time data of key parameters are captured, recorded and transmitted
to regulatory body-controlled data servers.
EFFLUENT QUALITY MONITORING SYSTEM (A CASE
STUDY)
20
Running Header
An example of effluent quality monitoring system for an industrial plant (COD, TSS, pH, DO).
ALL
INDUSTRY
EXCEPT
(REFINERY &
PAPER)
ONLINE EFFLUENT DISCHARGE
MONITORING WITH DATA TRANSMISSION
PRODUCT SCHEMATICS I
ONLINE EFFLUENT DISCHARGE
MONITORING WITH DATA TRANSMISSION
REFINERY &
PAPER
INDUSTRY
ONLINE EFFLUENT DISCHARGE
MONITORING WITH DATA TRANSMISSION
PRODUCT SCHEMATICS II
ONLINE EFFLUENT DISCHARGE
MONITORING WITH DATA TRANSMISSION
• Data can be accessed anytime.
DATA LOGGER – SUTRON X-LINK 500
ONLINE DATA TRANSMISSION &
VISUALIZATION
HACH ONLINE CHEMICAL OXYGEN DEMAND (COD) –CHOOSING THE RIGHT INSTRUMENT
26
COD –
EZ7000 COD
Total Organic Carbon (TOC) –
BioTector
Spectral Absorption
Coefficient (SAC) – UVAS
sc
Robust analyzer for most
and difficult samples.
BioTector provides
optional VOC analysis.
Provides the same
analytical method as
laboratory dichromate
analysis.
"Probe analyzer type
which is “reagentless”.
Biochemical Oxygen Demand: BOD is the amount of oxygen used during the
biological breakdown of organic material i.e. the quantity of oxygen removed from rivers and water ways etc. BOD is considered an indirect measure of the organic
content of a sample.
BOD measurement is a 5 or 7 day laboratory process.
Chemical Oxygen Demand: COD is the equivalent amount of oxygen needed to breakdown organic matter using strong oxidizing agents. It is an approximation of
BOD.
COD measurement is a 2 hours laboratory process.
Total Organic Carbon: TOC is the entire quantity of organic carbon that exists in a measured sample. TOC is used as a measure of the amount of organic pollution in a
water sample.
TOC measurement is a 7 minute online process.
SAC254 or UV254: Spectral absorbance coefficient (SAC) at 254 nm wavelength or UV254 is indicator of dissolved organic substance in a water sample. Measurement is
due to double-bonds of organic compounds absorbing UV light.
SAC254 measurement is a 1 minute online process.
www.biotector.com
ORGANICS: COD-BOD-TOC-SAC254 RELATIONSHIP
ORGANICS: COD-BOD-TOC RELATIONSHIP
UV Absorption DOES NOT directly measure: • TOC
• COD
• or BOD
Inorganic ions such as Nitrate (NO3) and Nitrite (NO2) also absorb UV light
(false positives).
Particulate organic solids and many common organics (non-double-bonds)
are not detected (false negatives). Example: Alcohols, Sugars, Organic acids, solvents such as Acetone and
Hexane.
All UV lamps diminish in intensity over time.
SAC254 – DIRECT UV ABSORPTION ISSUES
Method Interferences Oxidation Potential
(volts)
Accuracy /
Reproducibility
Response
Time
Hazardous Waste
Generated
BOD5 Nitrite, Sulfide,
Chlorides, Iron,
Acids
N/A
Biological
± 15% 5 Days No
CODcr Nitrite, Sulfide,
Chlorides, Iron,
Acids
1.33 ± 8% 2 Hours Yes
(Chromium, Acids,
Mercury, Silver)
CODmn Nitrite, Sulfide,
Chlorides, Ammonia*, Iron,
Acids
1.49 Unknown
Typically oxidizes <80% of organic
compounds
1 Hour Yes
(Mercury, Acids,
Silver)
TOC Inorganic Carbon 2.8
(Hydroxyl Radical)
± 2% <7 Minutes No
Source: Instrumentation Testing Association (ITA) www.instrument.org
www.biotector.com
COMPARISON OF BOD, COD, TOC MEASUREMENT
PRINCIPLE
LOW-MAINTENANCE, ROBUST TOC ANALYZER DESIGNED FOR
HARSH SAMPLE AND ENVIRONMENTAL CONDITION.
• Superior reliability – Typically 99.7% uptime
• High dependability – Patented Two-Stage Advanced
Oxidation (TSAO) technology handles even the most
challenging applications involving fats, oils, greases,
salts, sludge, and particulates
• Intelligent design – Self-cleaning technology and
oversized tubing eliminates filtration and prevents
clogging and sample contamination
• Minimal maintenance – No calibration or service
required between 6-month service intervals
• Low cost of ownership – Provides a quick pay back
with cost savings in customers’ chemical dosing, waste reduction and optimized processes
CONSIDERATIONS OF SITE SAMPLING CONDITIONS
HACH ONLINE CHEMICAL OXYGEN DEMAND (COD) –CHOOSING THE RIGHT INSTRUMENT
33
• It is important to know which measurement principle is suitable for the
sample.
• It is important to consider site sampling condition to choose suitable
analyzer.
• Interferences, accuracy, sampling cycle required for process control
automation and disposal of hazardous reagents are some other factors
that also need to be considered.
THANK YOU FOR YOUR ATTENTION
34
HACH – YOUR PARTNER FOR WATER
AND WASTEWATER ANALYSIS
Contacts:
Yoga [email protected]
Diana [email protected]
BACK UP CLAROS SLIDES
36
CLAROS OVERVIEW
37
https://support.hach.com/app/answers/answer_v
iew/a_id/1019995/loc/en_US
https://support.hach.com/app/answers/answer
_view/a_id/1009280
• Prognosys is designed to give you the information they need
to react to instrument changes
before it becomes an emergency.
• Prognosys displays two indictors that portray the condition
and maintenance needs of Hach instruments
PROGNOSYS
Measurement Indicator Service Indicator
Instrument Warning
Instrument Error
sc1000 operation with Prognosys
PROGNOSYS
Normal Operation
When Prognosys is yellow, there is a
window of opportunity for Hach
customers to be proactive instead of
reactive. It is ideal for those who value
preventative maintenance.
WATER INFORMATION MANAGEMENT SYSTEM
40
WHAT IS RTC?
41
RTC Industrial PC
RTC Proprietary Control Algorithm
Instruments and sensors
Plant information
Control setpoints:
• DO setpoint
• Polymer feed rate
• Chemical feed rate
RTC is an industrial computer running proprietary
algorithms that outputs a setpoint to control customer
processes
HOW DOES THIS INTEGRATE WITH CUSTOMER SYSTEMS?
42
In advanced plants seeking to optimize processes the RTC can be used to
provide a setpoint for control of aeration, or for polymer and chemical dosing
PLC
RTC Industrial PC
43
CASE STUDY: RTC-P
OUTCOME: 50% of reduction in coagulant dosing and compliance to
phosphorous control
44
CASE STUDY: RTC-N
OUTCOME: 15% reduction in energy usage.
RTC
45
CLAROS OVERVIEW
46