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    DET NORSKE VERITAS

    Report on

    QRA for POL IRDs/ depots

    BHARATPUR

    For

    Hindusthan Petroleum Corporation Limited

    Mumbai 400 001Maharashtra, India

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    QRA for POL IRD/depot

    MANAGING RISKBharatpur

    QRA for POL IRDs/ depots

    Bharatpur

    DET NORKSE VERITAS AS

    EMGGEN CHAMBERS,

    10C.S.TROAD,VIDHYANAGARI,

    SANTACRUZ (E),KALINA

    MUMBAI 400098

    TEL:+912226676400

    FAX: +912226653380

    http://www.dnv.com

    For:

    Hindusthan Petroleum Corporation LimitedGresham Assurance Building, Sir P.M. Road,

    Post Box No. 198, Fort,

    Mumbai 400 001

    Maharashtra, India

    Account Ref.:

    K Somashekhar Rao, Sr. Manager HSE-O&D

    [email protected]

    Date of First Issue: 2013-05-29 Project No. PP046380

    Report No.: 12QR1P2-27 Organisation Unit: Maritime & Oil and Gas, India

    Revision No.: 02 Subject Group: SHE

    Summary:

    DNV conducted Quantitative Risk Assessment (QRA) for HPCL POL IRDs/ depots. This QRA Study aimsto identify Individual and Societal Risk associated with the Bharatpur location. This report presents the

    DNVs findings and conclusion from the study.

    Prepared by:Vishalakshi Daine

    ConsultantSignature

    Verified byAnil Bhat Avvari

    ConsultantSignature

    Approved by:

    Salian Varadaraja

    Project Sponsor Signature

    No distribution without permission from the client or responsibleorganisational unit (however, free distribution for internal use

    within DNV after 3 years)Indexing Terms

    No distribution without permission from the client or responsible

    organisational unitKeyWords

    QRA

    Strictly confidentialServiceArea

    SHE Risk Management

    Unrestricted distributionMarket

    Segment

    Oil & Gas

    Rev. No. / Date: Reason for Issue: Prepared by: Verified by Approved by:

    02/30-07-2013 Draft report issued to HPCL

    for comments

    VDAI AVAB VASAL

    All rights reserved. This publication or parts thereof may not be reproduced or transmitted in any form or

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    Executive Summary

    Det Norske Veritas (DNV) conducted a Quantitative Risk Assessment (QRA) study

    covering the entire HPCL POL IRDs/ depots. The presentation of results is in line with

    UK HSE guidelines. This report presents the DNVs study findings and conclusion from

    the study for the Bharatpur.

    The overall objective of the QRA study is to quantify the level of individual fatality risks

    associated with the Bharatpur; and to demonstrate that the level of risks is in compliance

    with the UK HSE guidelines

    Based on the QRA study for the Bharatpur, the following conclusions and

    recommendations can be drawn:

    Area under Study Major HazardRecommended Control

    /Mitigation

    Tank Farm

    Pool fire and Tank fire are

    major events in the Tankfarm area, leading to the

    escalation of the fire fromone tank to the another

    Ensure availability ofwater spray system in thetank farm area for

    protecting the tank from

    the external fire

    Ensure regularmaintenance procedure to

    reduce likelihood of failureof the valves, flanges and

    pipes

    Pump House Area

    Release of pressurizedinventories from the pump

    house may cause severe

    damage in the Depotpremises

    Consider providing HC

    detectors in Pump house

    area

    Gantry Operations

    Fire due to Leak during TT

    loading operations. Major

    events of pool fire due toleak or spillage, flash fire

    are observed Hazardous

    As the gantry area is ahigh risk

    and high consequencezone, ensure minimum

    activity of trucks andpersonnel in this area.

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    Area under Study Major HazardRecommended Control

    /Mitigation

    gantry and TT crew.

    Consider provision of HCdetectors for early

    detection of

    hazardous leaks.

    Ensure training, SOP,emergency procedures

    established andimplemented for all

    personnel at gantry.

    Ensure PPE usage by all

    personnel.

    Ensure that the loaded

    trucks spend minimumtime near the gantry after

    the loading operations

    Office Building

    Fire radiation due to leak

    from the loaded tanker

    trucks.

    Ensure that the loadedtrucks spend minimum

    time near the gantry after

    the loading operations

    Even though the Individual and societal risk levels of the Bharatpur has been found to be

    in ALARP region in assessing with HSE UK risk criteria, In order to maintain the level of

    risk at this level, cost effective risk mitigation measures should be implemented to

    mitigate the risks to a level that is As Low As Reasonably Practicable (ALARP).

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    GLOSSARY

    ALARP: As Low As Reasonable Practical

    HSE : Health Safety Environment

    IR : Individual Risk

    JF : Jet Fire

    kW/m2 : Kilo Watt per Square Metre, a measure of heat flux or radiant heat

    LFL : Lower Flammable LimitLOC : Loss of containment

    LSIR : Location Specific Individual Fatality Risk per year

    P&ID : Piping and Instrumentation Diagram

    PLL : Potential Loss of Life

    QRA : Quantitative Risk Assessment

    UFL : Upper Flammable Limit

    UK HSE: UK Health and safety Executive

    VCE : Vapour Cloud Explosion

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    TABLE OF CONTENTS

    Executive Summary .......................................................................................................... III

    1

    INTRODUCTION .......................................................................................................... 1

    1.1 Background ............................................................................................................ 1

    1.2 Objectives ............................................................................................................... 1

    1.3

    Scope of Study ........................................................................................................ 1

    1.4 Report Structure ...................................................................................................... 2

    1.5 Facility Description................................................................................................. 3

    1.6 Input Data ............................................................................................................... 5

    1.6.1 Material Inventory ................... ......................................................................... 5

    1.6.2 Process Conditions ........................................................................................... 5

    1.6.3 Material Composition ....................................................................................... 5

    1.6.4

    Weather ............................................................................................................ 5

    1.6.5 Ignition Sources................................................................................................ 5

    1.6.6 Population ........................................................................................................ 5

    2

    RISK ASSESSMENT CRITERIA ................................................................................ 6

    2.1 UK HSE criteria ...................................................................................................... 6

    2.2 Individual Risk Criteria ........................................................................................... 7

    2.3 Societal Risk Criteria .............................................................................................. 8

    3

    RISK RESULTS ............................................................................................................ 9

    3.1 Individual Risk ....................................................................................................... 9

    3.2 Societal Risk ......................................................................................................... 11

    3.2.1 FN Curve ........................................................................................................ 11

    4

    CONCLUSIONS AND RECOMMENDATIONS ....................................................... 13

    5

    REFERENCES ............................................................................................................ 15

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    List of Tables

    Table 2-1: Societal Risk Criteria Onsite ............................................................................................................... 8

    Table 3-1: LSIR ....................................................................................................................................................... 9

    List of Figures

    Figure 1-1: Bharatpur Layout ............. ............ .............. ............. .............. ............ ............. .............. .............. .......... 3Figure 1-2: Bharatpur Layout .................................................................................................................................. 4

    Figure 2-1: ALARP Principle .................................................................................................................................. 6

    Figure 2-2: FN Curve and Criterion Line ................................................................................................................ 7

    Figure 3-1: Individual Risk Contours for Bharatpur ............................................................................................. 10

    Figure 3-2: FN Curve Onsite ................................................................................................................................. 11

    Figure 3-3: FN Curve Offsite ................................................................................................................................ 12

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    1

    INTRODUCTION

    1.1 Background

    Det Norske Veritas (DNV) conducted a Quantitative Risk Assessment (QRA) study

    covering the entire HPCL POL IRDs/ depots. The presentation of results is in line with

    UK HSE guidelines. This report presents the DNVs study findings and conclusion from

    the study for the Bharatpur.

    1.2 Objectives

    The overall objective of the QRA study is to

    - Quantify the level of individual fatality risks associated with the Bharatpur; and

    - Demonstrate that the level of risks is in compliance with the UK HSE guidelines

    1.3 Scope of Study

    DNV has performed the work in accordance to the UK HSE guidelines. Following are the

    important aspects of this study:

    - Verify the individual and societal risk levels in accordance with UK HSE criteria

    - Tabulation of the consequences in terms of:

    Distances to radiation levels, Lower Flammability Limit (LFL) and

    explosion overpressure for different weather classes according to specific

    criteria classes.

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    1.4

    Report Structure

    This report presents:

    Section 1 Introduction

    This section provides a general introduction of the project, the main

    objectives of the QRA study, the scope of study, and the structure of this

    report.

    Section 2 Risk Assessment Criteria

    This action outlines the risk criteria applied in this QRA study.

    Section 3 Risk Results

    This section provides the risk results due to process hazard

    Section 4 Conclusions and Recommendation

    This section outlines the overall conclusions of the study and provides the

    recommendation to be implemented in order to ensure ALARP

    performance in the operation.

    Section 5 Reference

    This section details the reference used in this QRA.

    Annexe 1 QRA Methodology

    This appendix explains the QRA methodology applied in this QRA.

    Annexe 2 Assumptions Register

    The assumptions presented are applied in the modelling and preparation

    of the reports/technical notes.

    Annexe 3 Failure case and frequency analysis

    This appendix defines the failure cases selected for analysis, as well asthe corresponding frequencies.

    Annexe 4 Consequence Analysis

    This appendix presents outcome of an event in terms of toxic, fire and

    explosion.

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    Report No.: 12QR1P2-27

    Rev 02, 30thJuly, 2013

    Page 3

    1.5 Facility Description

    The Bharatpur layout is shown in the figure below.

    Figure 1-1: Bharatpur Layout

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    Rev 02, 30thJuly, 2013

    Page 4

    Figure 1-2: Bharatpur Layout

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    1.6 Input Data

    1.6.1

    Material Inventory

    Material required for the QRA study is taken from the Mass and Energy balance sheet

    provided by the client. The static and dynamic inventory is calculated based on the flow

    rate and equipment dimension provided by the client. The inventory details with respect

    to vessel and pipelines is given at Annexe 3 - Failure case and frequency analysis.

    1.6.2 Process Conditions

    The process conditions like temperature and pressure required for the QRA study is taken

    from the Mass and Energy balance sheet and Process flow diagram provided by the client.

    The details are placed in a table at Annexe 3 - Failure case and frequency analysis.

    1.6.3

    Material Composition

    Material required for the QRA study is taken from the Mass and Energy balance sheet

    provided by the client for most of the cases. If the data is not available suitable

    representative material is considered as per DNV Technical note 13 and international

    standard. This is explained in Assumption Register (Annexe 2) in detail.

    1.6.4

    Weather

    Meteorological data are required at two stages of the QRA. First, various parts of the

    consequence modelling require specification of wind speed and atmospheric stability.

    Second, the impact (risk) calculations require wind-rose frequencies for each combination

    of wind speed and stability class used.

    1.6.5 Ignition Sources

    In order to calculate the risk from flammable materials, information on the ignition

    sources (which are present in the area over which a flammable cloud may drift) is

    required.

    1.6.6

    Population

    All the population details are provided to the study and the presence factor is explained with

    respect to the unit is given in details in Assumption Register (Annexe 2).

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    2

    RISK ASSESSMENT CRITERIA

    In order to determine acceptability, the risk results are assessed against a set of risk

    criteria as per UK HSE criteria.

    2.1 UK HSE criteria

    Following points details the UK HSE guidelines:

    - An individual risk below 1 x 10-6 fatalities per year is considered as acceptable for

    both plant workers and public. An individual risk above 1 x 10-4

    fatalities per year for

    public is considered as unacceptable and an individual risk above 1 x 10-3

    fatalities

    per year for workers is considered unacceptable. Between these limits the risk is

    considered as ALARP (As Low as Reasonably Practicable). An indication of this is

    shown in the below figure

    Figure 2-1: ALARP Principle

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    Often casualties are defined in a risk assessment as fatal injuries, in which case N is

    the number of people that could be killed by the incidents.

    Figure 2-2: FN Curve and Criterion Line

    2.2 Individual Risk Criteria

    The UK HSE Individual Risk Criteria was considered to assess the risk for HPCL POL

    IRDs/ depots. Individual risk above 10-3 per annum for any person shall be considered

    intolerable and fundamental risk reduction improvements are required.

    Risk criteria for Individual Risk for on-site are as follows:

    - Individual risk levels above 1 x 10-3per yearwill be considered unacceptable and

    will be reduced, irrespective of cost

    - Individual risk levels below 1 x 10-6per yearwill be broadly acceptable

    - Risk levels between 1 x 10-3 and 1 x 10-6per year will be reduced to levels as low as

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    2.3

    Societal Risk Criteria

    When considering the risk associated with a major hazard facility, the risk to an

    individual is not always an adequate measure of total risks; the number of the individuals

    at risk is also important. Catastrophic incidents with the potential multiple fatalities have

    a little influence on the level of risk but have a disproportionate effect on the response of

    society and impact of company reputation.

    The concept of societal risk is much more than that for individual risk. A number offactors are involved which make it difficult to determine single value criteria for

    application to a number of different situations. These factors include;

    - The hazard, the consequential risks and the consequential benefits

    - The nature of assessment

    - Factors of importance to the company, government, regulators and authorities, public

    attitudes and perception and aversion to major accidentSocietal risk is the relationship between frequency of an event and the number of people

    affected. Societal risk from a major hazard facility can thus be expressed as the

    relationship between the number of potential fatalities N following a major accident and

    frequency F at which N fatalities are predicated to occur. The relationship between F and

    N, and the corresponding relationship involving F, the cumulative frequency of events

    causing N or more fatalities, are usually presented graphically on log-log axis.

    DNV has used following societal risk criteria. Societal risk should not be confused as

    being the risk to society or the risk as being perceived by society. The word societal is

    merely used to indicate a group of people and societal risk refers to the frequency of

    multiple fatality incidents, which includes workers and the public. Societal risk is usually

    represented by an FN (Frequency Number of Fatality) curve.

    Table 2-1: Societal Risk Criteria Onsite

    Maximum Tolerable

    Intercept With N=1

    Negligible

    Intercept With N=1

    10-2

    10-4

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    3

    RISK RESULTS

    3.1

    Individual Risk

    Location specific individual risk (LSIR) is used to indicate the risk at a particular

    location. It is the risk for a hypothetical individual who is positioned there for 24 hours

    per day, 365 days per year. It is a standard output from a QRA. In onshore studies, the

    geographical variation of LSIR may be represented by iso-risk contour plots and used for

    land-use planning. In offshore studies, an LSIR value is normally computed for each

    separate module on the installation. Since in reality people do not remain continually at

    one location, this is not a realistic risk measure.

    Table 2.1 presents the LSIR

    Table 3-1: LSIR

    S.No Location LSIR Remarks

    1 D.G Control room 5.62E-07 Acceptable

    2 Gantry 7.38E-07 Acceptable

    3 Office Building 3.60E-06 Acceptable

    4 Workers change room 3.34E-06 Acceptable

    Table 3-2: Major Risk Contributors to office building

    S.No Location Risk/yr %

    1 Large Leak from MS Tanker 8.42E-07 23.40

    2 Large Leak from SKO Tanker 7.22E-07 20.08

    3 Large Leak from HSD Tanker 6.25E-07 17.39

    4 Medium leak from MS Tanker 3.91E-07 10.88

    5 Medium leak from SKO Tanker 2.97E-07 8.27

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    Report No.: 12QR1P2-27

    Rev 02, 30thJuly, 2013

    Page 10

    Figure 3-1: Individual Risk Contours for Bharatpur

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    3.2

    Societal Risk

    3.2.1 FN Curve

    FN curve defines the societal risk. It represents the relationship between the frequency

    and the number of people suffering a given level of harm from the realisation of specified

    hazards. It is usually taken to refer to the risk of death and usually, expressed as a risk per

    year.

    The following figure presents the onsite societal risk FN Curve for Bharatpur. The blueline represents the upper limit of risk and the green line represents the lower level of

    risk. The region between this two represents the risk in the ALARP (AS LOW AS

    REASONABLY PRACTICABLE) region. The region beyond the blue line indicates the

    unacceptable region and the region below blue line represents the broadly acceptable

    region. The red line represents the level of societal risk that has been realised around

    Bharatpur.

    Figure 3-2: FN Curve Onsite

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    -

    Compared to the UK HSE risk criteria, the FN Curve shows that societal risk is withinthe Acceptable region and does not exceed the unacceptable criteria.

    FN Curve Offsite

    No Risk curve found for offsite population

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    4

    CONCLUSIONS AND RECOMMENDATIONS

    Area under Study Major HazardRecommended Control

    /Mitigation

    Tank Farm

    Pool fire and Tank fire are

    major events in the Tank

    farm area, leading to the

    escalation of the fire fromone tank to the another

    Consider providing waterspray system in the tank

    farm area for protectingthe tank from the external

    fire

    Ensure regularmaintenance procedure to

    reduce likelihood of failureof the valves, flanges and

    pipes

    Pump House Area

    Release of pressurizedinventories from the pump

    house may cause severe

    damage in the Depot

    premises

    Consider providing HCdetectors in Pump house

    area

    Dyke should be provided

    to the pumps to limit poolformation of the release

    inventory

    Gantry Operations

    Fire due to Leak during TTloading operations. Major

    events of pool fire due to

    leak or spillage, flash fireare observed. Hazardous

    radiation levels of 12.5kw/m2 and 37.5 kW/m2 are

    observed close to gantry.

    As the gantry area is ahigh riskand high consequencezone, ensure minimum

    activity of trucks andpersonnel in this area.

    Ensure emergency escape

    routeis provided and informedto all

    gantry and TT crew.

    Consider provision of HC

    detectors for early

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    Area under Study Major Hazard Recommended Control/Mitigation

    Ensure training, SOP,emergency procedures

    established and

    implemented for allpersonnel at gantry.

    Ensure PPE usage by allpersonnel.

    Ensure that the loadedtrucks spend minimum

    time near the gantry afterthe loading operations

    Office Building

    Fire radiation due to leak

    from the loaded tanker

    trucks.

    Ensure that the loadedtrucks spend minimum

    time near the gantry after

    the loading operations

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    5

    REFERENCES

    - Methods for the calculation of physical effects due to releases of hazardous

    materials (liquids and gases) TNO Yellow Book, CPR 14E, 2005

    - A Flack / B Bain / T Lindberg / J R Spouge Process Equipment Failure

    Frequencies Rev. 04, October 2009 for Process Pipes, Pumps, Atmospheric

    Storage Tank

    - CCPS, Guidelines for Consequence Analysis of Chemical Releases, American

    Institute of Chemical Engineers, 1999.

    - Lees, F. P., Loss Prevention in the Process Industries, Butterworth-Heinemann,

    1996

    - Oil Industry Safety Directorate (OISD), First Edition, August 2007.

    - Robin Pitblado, Andreas Flack, Phil Crosthwaite, David Worthington,

    Consequence Handbook, Report no.:70037714, August 2008

    - TNO, Guidelines for Quantitative Risk Assessment, The Purple Book, 2009

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    Det Norske Veritas:

    Det Norske Veritas (DNV) is a leading, independent provider of services for managing risk witha global presence and a network of 300 offices in 100 different countries. DNVs objective is tosafeguard life, property and the environment.

    DNV assists its customers in managing risk by providing three categories of service:classification, certification and consultancy. Since establishment as an independent foundationin 1864, DNV has become an internationally recognised provider of technical and managerialconsultancy services and one of the worlds leading classification societies. This meanscontinuously developing new approaches to health, safety, quality and environmental

    management, so businesses can run smoothly in a world full of surprises.

    Global impact for a safe and sustainable future:

    Learn more on www.dnv.com

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    Annexe 1

    QRA Methodology

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    Table of Contents

    1 QRA METHODOLOGY ............................................................................................... 1

    1.1 Introduction to Risk Assessment ............................................................................. 1

    1.2 What is QRA? ......................................................................................................... 2

    1.3 Key Components in QRA ....................................................................................... 2

    2 QRA APPROACH ......................................................................................................... 5

    2.1.1 Hazard Identification ........................................................................................ 5

    2.2 Consequence Modelling/Phast Software ................................................................. 6

    2.3 Frequency Analysis................................................................................................. 7

    2.4 Risk Calculation/PHASTRISK Software ................................................................. 7

    2.4.1 Built-In Event Trees ......................................................................................... 7

    2.4.2 Atmospheric Condition ................................................................................... 10

    2.4.3 Risk Presentation: .................... ....................................................................... 10

    3 QRA SOFTWARE TOOL ........................................................................................... 12

    D N V

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    List of TablesTable 2-1: Explosion Overpressure Effects ............................................................................................................. 6Table 2-2: Effects of Thermal Radiation ................................................................................................................. 7Table 3-1 PHAST RISK Default Vulnerability Parameters .................................................................................. 17

    List of Figures

    Figure 1-1: QRA methodology ................................................................................................................................ 3Figure 1-2: ALARP Principle .................................................................................................................................. 4Figure 2-1 : Event Tree 1 Continuous Vapour Release ........................................................................................ 8Figure 2-2: Event Tree 2 Continuous Release with Rainout ................................................................................ 8Figure 2-3: Event Tree 3 Instantaneous Vapour Release...................................................................................... 9Figure 2-4: Event Tree 4 Instantaneous Release with Rainout ............................................................................. 9

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    1

    QRA METHODOLOGY1.1 Introduction to Risk Assessment

    This section is presented to assist the reader who is not familiar with the terms used in

    this document and for those who are familiar to confirm DNV understanding of the terms

    and their application in the context of this document. An oil & gas facility has the

    potential to cause harm such as:

    - Sickness, injury or death of workers and people in the surrounding community- Damage to property and investments

    - Degradation of the physical and biological environment

    - Interruption to production and disruption of business

    A state or condition having the potential to cause a deviation from uniform or intended

    behaviour which, in turn, may result in damage to property, people or environment, is

    known as hazard. Thus a scraper trap is a hazard because it has the potential to cause a

    fire; processes such gas compression is a hazardous activity because it has the potential to

    cause fires and explosions. The word hazard does not express a view on the magnitude

    of the consequences or how likely it is that the harm will actually occur. A major

    hazard is associated with Loss of Containment and has the potential to cause significant

    damage or multiple fatalities. Again, the term does not imply that such events are likely.

    Incidents are the actual realization of a hazard, i.e. an event or chain of events, which has

    caused or could have caused personal injury, damage to property or environment. Theyare sudden unintended departures from normal conditions in which some degree of harm

    is caused. They range from minor incidents such as a small gas leak to major accidents

    such as Flixborough, Mexico City, Bhopal, Pasadena, Texas City, etc. Sometimes, the

    more neutral term event is used in place of the more colloquial term incident. For

    flammable incidents, ignition has to take place for a hazard to be realized.

    Risk is the combination of the likelihood and the consequences of such incidents. More

    scientifically, it is defined as the likelihood of a hazard occurrence resulting in an

    undesirable event. The likelihood may be expressed either as a frequency (i.e. the rate of

    events per unit time) or a probability (i.e. the chance of the event occurring in specified

    circumstances). The consequence is defined as an event or chain of events that result from

    the release of a hazard The impact or effect is the degree of harm caused by the event

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    1.2

    What is QRA?Quantitative risk assessment (QRA) is a means of making a systematic analysis of the

    risks from hazardous activities, and forming a rational evaluation of their significance, in

    order to provide input to a decision-making process.

    QRA is sometimes called probabilistic risk assessment term originally used in the

    nuclear industry. The term Quantified Risk Assessment is synonymous with QRA as

    used here. The term quantitative risk analysis is widely used, but strictly this refers to

    the purely numerical analysis of risks without any evaluation of their significance.

    QRA is probably the most sophisticated technique available to engineers to predict the

    risks of accidents and give guidance on appropriate means of minimizing them.

    Nevertheless, while it uses scientific methods and verifiable data, QRA is a rather

    immature and highly judgmental technique, and its results have a large degree of

    uncertainty. Despite this, many branches of engineering have found that QRA can give

    useful guidance. However, QRA should not be the only input to decision-making aboutsafety, as other techniques based on experience and judgment may be appropriate as well.

    1.3 Key Components in QRA

    The study is based on the premises of a traditional Quantitative Risk Assessment. The key

    components of QRA are explained below, and illustrated in Figure 1-1.

    The first stage in a QRA is defined as system definition where the potential hazardsassociated with a facility or activities are to be analyzed. The scope of work for a QRA

    should be to define the boundaries for the study, identifying which activities are to be

    included and which are excluded, and which phases of the facilitys life are to be

    assessed. The hazard identification consists of a qualitative review of possible accidents

    that may occur, based on previous accident experience or judgment where necessary.

    There are several formal techniques for this, which are useful in their own right to give a

    qualitative appreciation of the range and magnitude of hazards and indicate appropriatemitigation measures. This qualitative evaluation is described in this guide as hazard

    assessment.

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    In a QRA, hazard identification uses similar techniques, but has a more precise purpose defining the boundaries of a study in terms of materials to be modelled, release conditions

    to be modelled, impact criteria to be used, and identifying and selecting a list of failure

    cases that will fully capture the hazard potential of the facilities to be studied. Failure

    cases are usually derived by breaking the process system down into a larger number of

    sub- systems, where failure of any component in the sub-system would cause similar

    consequences. In pipeline case, this can be performed by breaking the line into sections

    depending on availability of isolation valves along the line.

    Figure 1-1:QRA methodology

    O th t ti l h d h b id tifi d th f l i ti t h

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    In parallel with the frequency analysis, consequence modelling evaluates the resulting

    effects if the accidents occur, and their impact on people, equipment and structures, the

    environment or business, depending on the defined scope of the QRA study. Estimation

    of the consequences of each possible event often requires some form of computer

    modelling. Consequence analysis requires the modelling of a number of distinctive

    phases, i.e. discharge, dispersion, fires and explosions (for flammable materials).

    Closely liaised with the consequence assessment is the impact assessment, i.e. how does

    the fire, explosion or toxic cloud affect human beings. When the frequencies and

    consequences / impact of each modelled event have been estimated, they can be

    combined to produce risk results. Various forms of risk presentation may be used,

    commonly grouped as follows:

    - Individual risk - the risk experienced by an individual person

    - Group/Societal risk - the risk experienced by a group of people exposed to the

    hazard

    The next stage is to introduce criteria, which are yardsticks to indicate whether the risks

    are acceptable, or to make some other judgment about their significance. Risk assessment

    is the process of comparing the level of risk against a set of criteria as well as the

    identification of major risk contributors. The purpose of risk assessment is to develop

    mitigation measures for unacceptable generators of risk, as well as to reduce the overall

    level of risk to As Low as Reasonably Practical (Figure 1-2).

    Figure 1-2: ALARP Principle

    High Risk

    ALARP

    Region

    Unacceptable

    Region

    Given immediate

    attention and a response

    developed commensurate

    with the scale of the threat

    Broadly acceptableonly if risk reduction

    is impracticable or if

    its cost is grossly

    disproportionate to

    the improvement

    gained

    High Risk

    ALARP

    Region

    Unacceptable

    Region

    Given immediate

    attention and a response

    developed commensurate

    with the scale of the threat

    Broadly acceptableonly if risk reduction

    is impracticable or if

    its cost is grossly

    disproportionate to

    the improvement

    gained

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    2

    QRA APPROACH2.1.1 Hazard Identification

    Hazard identification is the structured study of a plant in order to produce a list of

    foreseeable, potentially hazardous releases. In a plant, there is a wide range of substances

    that, if released, could cause injury or fatality. The hazards applicable for the plant have

    been identified through:

    - Knowledge transfer from other risk assessments for boosting station plants carried

    out by DNV within the applicable confidentiality constraints

    - Site specific parameters

    - The selection of appropriate hazards considered a range of issues, including:

    Nature of potential hazards

    Position of plant in relation to the surrounding community

    Complexity of the process

    DNV has concentrated on the flammable hazards.

    A list of the main process streams is defined from the Process Flow Schemes (PFS). Of

    these, some were considered to be non-hazardous (e.g., water streams) or only likely to

    give a local hazard (e.g., small pool fires), and were not analyzed further. The streams

    identified to be hazardous were further analyzed in the QRA.

    The range of possible releases for a given stream covers a wide spectrum, from a pinholeleak up to a catastrophic rupture (of a vessel) or full bore rupture (of a pipe). It is both

    time-consuming and unnecessary to consider every part of the range; instead, a finite

    number of failure cases are generated to characterize each unit. The number of specific

    cases and the distribution of the cases in terms of the size which are analyzed

    quantitatively take into account the potential consequences and the format of the

    frequency data that are being used.

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    2.2

    Consequence Modelling/Phast SoftwareThe consequence analysis is performed using DNV proprietary software PHAST. PHAST

    is a consequence and impact assessment module integrated within DNV risk calculation

    software PHASTRisk. PHAST calculates wide range of possible consequences from the

    LOC events, including:

    - Jet Fire, causing thermal radiation impact

    - Pool Fire, causing thermal radiation impact

    - Flash Fire, causing thermal radiation impact within the flammable cloud envelope

    - Explosion, causing overpressure impact

    Various factors affecting the extent of consequence are also considered within the

    PHAST model which includes:

    - Atmospheric conditions, including solar radiation flux, ambient temperature,humidity and wind speed/direction as well as weather stability

    - Release location- Release orientation

    Detailed findings of the consequence analysis for selected failure cases are presented in

    Section 6. The qualitative levels of explosion and heat radiation effects are described in

    Table 2-1 and

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    Table 2-2 respectively are used to assess the likelihood of harm to people or thelikelihood of further loss of containment and / escalation as per DNV Technical note.

    Table 2-1: Explosion Overpressure Effects

    Overpressure (bar) Effects Within Zone

    0.02 10% window glass broken

    0.05 Window glass damage causing injury0.1 Repairable damage to buildings and house facades

    0.2 Structural damage to buildings

    0.35 Heavy damage to buildings and process equipment

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    Table 2-2: Effects of Thermal Radiation

    Radiation Intensity

    (kW/m2) Observed Effect

    37.5 Sufficient to cause damage to process equipment

    25Minimum energy required to ignite wood at indefinitely long

    exposures (non piloted)

    12.5Minimum energy required for piloted ignition of wood,

    melting plastic tubing

    9.5Pain threshold reached after 8 sec, second degree burns after

    20 sec

    4

    Sufficient to cause pain to personnel if unable to reach cover

    within 20 s, however blistering of the skin (second degree

    burns) is likely; 0% lethality

    1.6 Will cause no discomfort for long exposure

    2.3

    Frequency Analysis

    The failure frequencies for the scenarios developed are obtained from DNVs Technical

    Notes (TN 14).

    2.4 Risk Calculation/PHASTRISK Software

    As mentioned earlier, DNV proprietary software PHASTRisk is used for the main risk

    calculation in the study. PHASTRisk combines consequence results from the PHAST

    module with a range of risk-related information in order to produce risk results.

    2.4.1

    Built-In Event Trees

    PHASTRisk has 4 built-in consequence outcome event trees, i.e. continuous vapour

    release, continuous release with rain-out1, instantaneous vapour release,

    release with rain-out. These event trees are presented in

    to

    . It is noted that No Ignition event leads to No Effect for flammable-only material

    release.

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    Figure 2-1 : Event Tree 1 Continuous Vapour Release

    Figure 2-2: Event Tree 2 Continuous Release with Rainout

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    Figure 2-3: Event Tree 3 Instantaneous Vapour Release

    Figure 2-4: Event Tree 4 Instantaneous Release with Rainout

    PHAST RISK also accounts for a short duration continuous release an event where a

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    Further, in the event of an instantaneous vapour release, PHASTRisk models the event as

    a pure fireball, in which the thermal radiation impact defines the level of human fatality,

    discounting the overpressure wave which may accompany the event.

    Various probability factors which will determine the route of event within the event trees

    are also determined in the PHASTRisk model. These include:

    Immediate Ignition:This is directly specified and will be different depending on the size

    of the release.

    Delayed ignition:This is a calculated value within PHASTRisk, unique to each release

    case and release direction. The calculation is based on the strength, location and presence

    factor of all ignition sources specified, and the extent and duration of dispersing

    flammable vapour clouds being exposed to those sources. Delayed ignition sources can be

    modelled as point sources (e.g. ground flares), line sources (roads, power lines) or area

    sources (e.g. to cater for background sources posed by a variety of human activity).

    Fireball / flash fire / explosion probability in the event of immediate ignition ofinstantaneous release. This is directly specified in PHASTRisk. Flash fire/explosion

    probability in the event of delayed ignition. This is also directly specified in PHASTRisk.

    Entire Complex has been considered as Ignition source with ignition probability 0.09 and

    operating probability 1 as per DNV Technical Note.

    2.4.2

    Atmospheric Condition

    Variation in wind direction defines the apparent orientation of consequences. PHASTRiskaccounts for the different wind directions from the wind distribution probability input and

    combine the values into the risk calculation. Atmospheric conditions, which include

    temperature and humidity, are also addressed.

    2.4.3

    Risk Presentation:

    Risk would be presented in terms of Individual and Societal (group).

    Individual Risk per Annum (IRPA) is the annual frequency that any individual in aspecific worker group becomes a fatality. Individual risk criteria are intended to ensure

    that individual workers are not exposed to excessive risk levels on an installation. They

    are largely independent of the number of workers exposed, and hence in principle may be

    applied to different situations

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    separate module on the installation. Since in reality people do not remain continually at

    one location, this is not a realistic risk measure.

    IRPA = LSIR x presence factor

    Risk is defined as the product of the consequences (here measured as harm to people) and

    the likelihood of occurrence (i.e. an expected rate of occurrence per year). Societal (or

    group) risk measures the risk of an operation to the company, the industry or a

    community. There are several ways of presenting societal risk, but the measure, which is

    found to be most useful for offshore installations, is the Potential Loss of Life (PLL).

    PLL is defined as the long term average number of fatalities per year due to a specific

    cause and can be expressed mathematically as:

    PLL = f . N

    Where:

    = sum for all outcomes

    f = frequency of an outcome (per year)

    N = number of fatalities caused by the outcome

    Potential Loss of Life (PLL) is the measure of the average number of statistical fatalities

    that may be expected within a given time period. "PLL per year" is another term for

    annual fatality rate. Potential loss of life (PLL) is a societal or group risk measure and istypically used in cost benefit analysis for assessing remedial measures, or for comparing

    alternatives during the design stages of any project. There is no acceptance criterion for

    PLL.

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    3

    QRA SOFTWARE TOOLThe basis for this QRA study is DNVs proprietary risk modelling software, PHAST

    RISK software version 6.7.

    The PHAST RISK software has been in existence since the 1970s, and has been under

    continual development and improvement ever since, which is managed by DNVs

    London-based software development division.

    An electronic database of approximately 1400 materials is available to the PHAST RISK

    software, with the material properties regularly reviewed and if required re-adjusted,

    based on the latest available data. The PHAST RISK consequence modelling results (for

    each material) are regularly reviewed and where required re-calibrated, based on the latest

    available accident and test data.

    The PHATS RISK software will calculate dispersion and consequence modelling resultsfor all specified weather classes and wind speeds with the failure case specified release

    frequency data, specified weather class, wind speed, wind directional probability data,

    specified immediate ignition probability data, software calculated delayed ignition

    probability data, built-in event tree alternate consequence outcome branch probability

    data, fatal impact probability data for each alternate consequence outcome (e.g. jet fire,

    flash fire, explosion), based on the specified consequence impact criteria levels, and

    specified population data by location, to produce individual and societal risk results, as

    required.

    This PHAST RISK modelling software requires the following inputs to be able to

    produce risk results:

    - Import an electronic map of the study area, on which individual fatality risk

    contour results may be produced.

    - The electronic map may be programmed in PHAST RISK to:

    - Superimpose all on-site and off-site populations within the study area by

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    Delayed ignition sources may be specified as point sources (e.g. flares, fired

    heaters, diesel-generators, and transformers), area sources (e.g. welding work

    shops) or line sources (e.g. roads, railway lines, and overhead power lines). Each

    ignition source carries additional specification in terms of presence factor and

    ignition source strength (probability of ignition per unit time, when in contact with

    a flammable vapour cloud between LFL and UFL). The actual delayed ignition

    probability of any release is calculated by PHAST RISK, based on the dispersion

    modelling results and event duration.

    The immediate ignition probability associated with each flammable failure case is

    a risk analyst programmed value, based on historical ignition data, which varies

    with leak size and release phase (Gas / Liquid / 2-Phase) (the larger the leak

    vapour flow rate, the higher the ignition probability, typically varying from 1% to

    30%, unless above auto ignition, then 100%).

    Prepare and import weather class, wind speed and wind direction probability data

    for the study area. Normally separate day / night, weather class, wind speed, wind

    directional probability files are entered into PHAST RISK, most often broken

    down into 16 wind directions.

    Enter all identified failure cases, which are defined in terms of: Location, Material

    released, Quantity released (or release duration), Temperature, Pressure, Leak

    size, Leak direction (e.g. horizontal, vertical), Leak elevation, Leak frequency and

    Immediate ignition probability.

    Each failure case calculation in PHAST RISK starts with discharge modelling.

    Based on release duration and release phase (gas, liquid, 2-phase), PHAST RISK

    directs the dispersion and consequence calculations to one of 4 alternate, built-in

    consequence outcome event trees (continuous vapour release, continuous releasewith rain-out, instantaneous vapour release, instantaneous release with rain-out),

    where each event tree branch probability carries default values, which may be re-

    programmed by the risk analyst.

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    So far the calculations performed in PHAST RISK only relate to the alternate

    consequence outcomes and the consequence hazard ranges, for each specified

    failure case. To produce risk results, PHAST RISK will perform impact frequency

    calculations, using the failure case specified leak frequency as starting point.

    Frequency aspects of the risk calculations relate to the:

    Risk analyst defined failure case leak frequency.

    Weather class, wind speed and wind directional probability, for each of the 16

    wind directions.

    Specified immediate ignition probability and PHAST RISK calculated delayed

    ignition probability. The delayed ignition probability calculation is based on the

    strength and location of all specified ignition sources and the failure case

    dispersion hazard range, combined with vapour cloud persistence (duration).

    PHAST RISK selected event tree and branch probabilities, for each alternate

    consequence out come.

    Fatal Impact probability for each alternate consequence outcome. This is based on

    the PHAST RISK calculated magnitude of each consequence and the PHAST

    RISK default impact probability criteria or risk analyst specified impact criteria

    for that type of consequence.

    Location and number of people (or equipment) within hazard area for societal risk

    results, with separate calculations for day and night, indoors and outdoors.

    PHAST RISK performs its individual and societal risk calculations based on a 200

    x 200 grids (40,000 points), with the grid point spacing automatically varied,

    based on the consequence hazard range results.

    For each release case, PHAST RISK takes the failure case release frequency as

    initial input, multiplies this by the first weather class / wind speed probability, for

    the first of 16 wind directions.

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    These 2 results are multiplied by the first of the event tree consequence branch

    probabilities, relating to immediate or delayed ignition branch path.

    PHAST RISK takes the calculated consequence hazard range and verifies which

    grid points are within the consequence hazard area. For each grid point within

    range PHAST RISK then calculates the magnitude of the consequence at each grid

    point (e.g. explosion overpressure at a particular grid point may be 3psi).

    The calculated consequence magnitude at each grid point is then compared to thePHAST RISK programmed impact criteria level, and the likelihood of fatality or

    damage calculated, based on the impact probability criteria specified in PHAST

    RISK, for the type of consequence and the magnitude of the consequence.

    This calculation is repeated for each event tree alternate consequence outcome at

    each grid point, for that weather class / wind speed and wind direction, and the

    result added to the previous risk level, at each grid point.

    The above calculations are then repeated for each of the 16 wind directions,

    cumulatively adding to the risk level at each grid point.

    The above calculations are repeated for all day / night weather classes, wind

    speeds and wind directions, cumulatively adding these risk results at each grid

    point.

    Once all risk calculations at these grid points have been completed for the first

    failure case, the next failure case will be calculated, again adding all results

    cumulatively at each grid point. This is repeated until all failure cases have been

    calculated, while PHAST RISK also tracks the risk contribution made by each

    failure case at each grid point.

    Once completed, PHAST RISK produces individual risk contour results by

    linking points of equal risk, based on the pre-specified levels of individual fatality

    risk (or equipment damage) to be plotted, and using linear interpolation between

    relevant grid points. The risk contour results are super imposed on the electronic

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    The above discussion demonstrates that the meteorological data, ignition data and

    population data entered into the PHAST RISK software are critical to the risk

    results.

    Note that with default settings the risk modelling within PHAST RISK aims to

    produce conservative offsite fatality risk results. This is in line with the intention

    of performing a QRA as per the Guidelines for QRA Study (Revision April

    2008) for a purpose of land-use planning. This is achieved by the build-in but

    programmable parameter settings, which include:

    Indoor & outdoor people fatality impact criteria levels, for each alternate

    consequence outcome.For flammable releases the alternate consequences would

    be spill fires, fire balls, jet fires, flash fires and vapour cloud explosions (VCEs),

    each with predefined values for the impact levels that will affect people. For jet

    fires, pool fires and fire balls the varying percentage fatalities (with distance) is

    calculated based on the Eisenberg Probit equation. For flash fires the LFL

    envelope is used and for VCE overpressure two impact criteria levels are used, 1.5

    psi (0.1 barg) and 5 psi (0.34 barg).

    For jet fires, pool fires and fire balls the varying percentage fatalities (with

    distance) is calculated based on the Eisenberg Probit equation. For flash fires the

    LFL envelope is used and for VCE overpressure two impact criteria levels are

    used, 0.5(0.034) psi, 1.0 psi (0.068 barg) and 5 psi (0.34 barg).

    4 built-in event trees (Continuous No Rain Out; Continuous With Rain Out;

    Instantaneous No Rain Out; Instantaneous With Rain Out) that are automatically

    selected based on the type of material and the release conditions. Each event-tree

    assigns a split between alternate consequence outcomes (spill fires, fire balls, jet

    fires, flash fires, VCEs and no hazard), based on the immediate ignition, delayed

    ignition and no ignition probabilities.

    People vulnerability criteria, which pre-determines the fraction of fatalities

    resulting indoor & outdoor from being exposed to specific consequence outcomes

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    Table 3-1 PHAST RISK Default Vulnerability Parameters

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    Annexe 2

    Assumption Register

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    Table of Contents

    1 RISK CALCULATION TOOL ..................................................................................... 1

    2 METEOROLOGICAL DATA ...................................................................................... 2

    2.1 Day Weather Class.................................................................................................. 2

    2.2 Night Weather Class ............................................................................................... 2

    3 IGNITION ...................................................................................................................... 4

    3.1.1 Identification of Ignition Sources ...................................................................... 5

    4 POPULATION ............................................................................................................... 5

    5 MATERIAL COMPOSITION ...................................................................................... 5

    6

    IMPACT CRITERIA..................................................................................................... 6

    6.1 Jet fire, pool fire and fireball ................................................................................... 6

    6.2 Flash fire ................................................................................................................. 6

    6.3 Explosion ................................................................................................................ 6

    7

    RELEASE SIZES........................................................................................................... 7

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    1 RISK CALCULATION TOOL

    The risk analysis within this study is conducted using DNV Softwares Phast Risk

    program Version 6.7, which is an industry standard method for carrying out QRA of

    onshore process and pipelines (chemical and petrochemical) facilities.

    - Phast Risk allows efficient identification of major risk contributors, so that time

    and effort can then be directed to mitigating these highest risk activities.

    - Phast Risk analyses complex consequences from accident scenarios, taking

    account of local population, land usage and weather conditions, to quantify the

    risk associated with the release of hazardous materials.

    - Phast Risk incorporates the industry standard consequence modeling of Phast.

    Phast Risk is intended as a set of models for risk analysts to enable them to provide

    timely, accurate and appropriate advice on safety related issues. It models all stages of a

    release from outflow through a hole or from a pipe end, through atmospheric dispersion,

    rain-out and re-evaporation of liquid, to thermal radiation from fires, explosion

    overpressures and toxic lethality. PhastRisk combines recognized and validated models

    for the various physical phenomena, automatically selecting the appropriate model

    depending on the circumstances of the release. It provides an experienced risk analystwith a tool that allows them to focus their attention and experience on the real problem

    areas rather than the administration of large quantities of data.

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    2 METEOROLOGICAL DATA

    Data on the wind speed and stability category have been obtained from the client and this

    will be used for this particular QRA study. There are two different weather classes for

    Day and Night which are listed below:

    2.1 Day Weather Class

    - D11 : D stability (neutral) and 11 m/s wind speed.

    - B2 : B stability (Unstable) and 2 m/s wind speed.

    2.2 Night Weather Class

    - D11 : D stability (neutral) and 11 m/s wind speed.

    - F3 : F stability (very stable) and 3 m/s wind speed.

    This distribution is combined with the wind rose information to generate likelihood for

    the wind to be from a particular direction and of a specified speed and stability.

    Table 2-1: Wind Speed Distribution (Day)

    Wind Direction

    Weather Categories

    3B 5D

    N 0.042958904 0.00460274

    NE 0.042958904 0.00460274

    E 0.104328767 0.011178082SE 0.024547945 0.002630137

    S 0.006136986 0.000657534

    SW 0.018410959 0.001972603

    W 0.085917808 0.009205479

    NW 0.110465753 0.011835616

    Calm 0.177972603 0.019068493

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    Table 2-2: Wind Speed Distribution (Night)

    Wind Direction

    Weather Categories

    3B 5D

    N 0.060931507 0.005041096

    NE 0.038082192 0.003150685

    E 0.060931507 0.005041096

    SE 0.038082192 0.003150685

    S 0.022849315 0.001890411

    SW 0.060931507 0.005041096

    W 0.167561644 0.013863014

    NW 0.190410959 0.015753425

    Calm 0.121863014 0.010082192

    Referring to the same study, the following meteorological parameters will be applied:

    An average ambient condition as follow is used in the study:

    - Atmospheric temperature : 15-25C

    - Surface temperature : 15-25C

    - Humidity : 70%

    - Solar radiation flux : 0.5kw/m2for day and 0kw/m2for night

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    3 IGNITION

    In order to calculate the risk from flammable materials, information on the ignition

    sources (which are present in the area over which a flammable cloud may drift) is

    required. For each ignition source considered, the following factors need to be specified:

    - Presence Factor

    - This is the probability that an ignition source is active at a particular location.

    - Ignition Factor

    - This defines the strength of an ignition source. It is derived from the probability

    that a source will ignite a cloud if the cloud is present over the source for a

    particular length of time.

    - Location

    The location of each ignition source must be specified on the site layout. This allows the

    position of the source relative to the location of each release to be calculated. The resultsof the dispersion calculations for each flammable release are then used to determine the

    size and mass of the cloud when it reaches the source of ignition.

    If these factors are known for each source of ignition considered, then the probability of a

    flammable cloud being ignited as it moves downwind over the sources can be calculated.

    The data is entered into the risk quantification software, namely PHAST RISK, for eachsource (as that used for population data). The PHAST RISK software then calculates

    equivalent combined ignition factors and presence factors for all sources based on its

    location on the map.

    Ignition sources in a QRA study may be of 3 types:

    Point sources Known specific sources such as flares, workshops, etc.

    Line sources Roads, railways, electrical transmission lines.

    Area sourcesPopulation, industrial sites where location of specific ignition

    sources is unknown.

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    3.1.1 Identification of Ignition Sources

    The ignition sources identified for the proposed expansion project are near-by Industrial

    plants and onsite ignition sources like hot machinery surfaces, electrical sources. No

    specific field survey is performed for the neighbouring industrial plants in this risk study;

    however, generally a process petro-chemical plant has various types of ignition sources

    on-site, e.g. hot work, hot surface, flare, turbine, compressor and vehicles movement etc.

    In summary, the ignition sources considered in this QRA study are listed below:

    - It is assumed that stringent ignition control is maintained, as is the standard

    prevailing in the HPCL Bharatpur

    - Entire Complex has been considered as Ignition source with ignition probability

    0.9 and operating probability 0.1 as per DNV Technical Note.

    4 POPULATION

    A representative estimate of the exposed populations is sufficient to determine the

    acceptability of societal risks by determining the order of magnitude of potential fatalities

    within a population group.

    The basis of the population assigned to the facility will be based on the data given by

    HPCL Bharatpur. Further analysis of the population will be conducted in order to define

    various factors associated with the population presence, e.g. day/night variation, fraction

    of time spent indoor etc.

    5 MATERIAL COMPOSITION

    The material composition used for the study is provided by HPCL Bharatpur.

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    6

    IMPACT CRITERIAThe following impact criteria are used.

    6.1 Jet fire, pool fire and fireball

    Two sets of criteria are used to determine impact from combination of these events. Areas

    exposed to radiation levels of 37.5 kW/m2are assumed to give 100% fatality level. The

    fatality levels in areas exposed to lower radiation levels are determined using the

    following Probit function.

    Pr = -36.38 + 2.56 ln(I1.333 . t)

    Where:

    Pr : Probit

    I : thermal radiation level in W/m2

    t : exposure duration in second

    The maximum exposure duration for these events is set to 20 seconds.This is assumed as the time that someone will remain within the

    radiation envelope before attempting to escape.

    6.2

    Flash fire

    The area within the LFL envelope of flammable vapor cloud is used as single value

    criteria and it is assumed that this area gives 100% fatality level.

    6.3 Explosion

    The study applies the TNT Correlation Model which utilizes two fixed coefficients to

    establish ranges to specified damage levels (these coefficients are 0.03 for heavy damage

    to buildings and 0.06 for repairable damage to buildings). These damage levels are not

    explicitly associated with overpressure levels but are generally considered to be

    equivalent to 0.3 and 0.1 bar for heavy and repairable damage, respectively. The damage

    levels are used as single criteria to establish the human fatality rate.

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    7 RELEASE SIZES

    The following representative leak sizes have been applied:

    Release Sizes:

    - Small release through 5 mm equivalent hole,representative of 3 to 10 mm hole

    sizes.

    - Medium release through 25 mm hole, representative of 10 to 50 mm hole sizes.

    - Large release through 100 mm hole, representative of 50 to 100 mm hole sizes.

    - Catastrophic Rupture at vessel diameter/ Full bore release at pipeline diameter,

    representative of releases larger than 150mm.

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    Annexe 3

    Frequency Analysis

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    N G NG S

    Table of Contents

    1 HAZARD IDENTIFICATION ...................................................................................... 3

    1.1 Failure case scenarios .................... ......................................................................... 3

    1.2 Continuous Releases ............................................................................................... 5

    1.3 Instantaneous Releases ................... ......................................................................... 5

    1.4 Events which could lead to a Release .................... ......................................... ......... 5

    1.5 Failure Cases ............................................................................... ........................... 6

    1.6 Release duration ..................................................................................................... 8

    2 FREQUENCY DISCUSSION ....................................................................................... 8

    List of TablesTable 1-1 : Failure case scenarios ............ .............. ............. ............ .............. ............. ............ .............. .............. ...... 3

    Table 1-2 : List of Failure Cases ............................................................................................................................. 6

    Table 2-1 : Failure frequencies of the identified scenarios ...................................................................................... 9

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    1

    HAZARD IDENTIFICATION

    1.1

    Failure case scenarios

    Following scenarios have been identified for the Bharatpur

    Table 1-1 : Failure case scenarios

    Sr. No Failure Case MaterialHandled Temp Pressure

    1 TK-1 HSD ambient atmospheric

    2 TK-2 HSD ambient atmospheric

    3 TK-3 SKO ambient atmospheric

    4 TK-4 SKO ambient atmospheric

    5 TK-5 MS ambient atmospheric

    6 TK-6 MS ambient atmospheric7 TK-7/UG MS ambient atmospheric

    8 TK-8/UG MS ambient atmospheric

    9 TK-9/UG HSD ambient atmospheric

    10 TK-10 WATER ambient atmospheric

    11 TK-11 WATER ambient atmospheric

    12 TK-12 HSD ambient atmospheric

    13 TK-13 HSD ambient atmospheric14 TK-14 MS ambient atmospheric

    15 TK-15 MS ambient atmospheric

    16 TK-16 MS ambient atmospheric

    17 TK-17 HSD ambient atmospheric

    18 TK-18 HSD ambient atmospheric

    19 HSD Pump_2400 LPM HSD ambient 2.5bar

    20 SKD Pump_1200 LPM SKO ambient 2.5bar21 MS Pump 2400 LPM MS ambient 2.5bar

    22 Receipt Pipeline to Tank MS MS ambient 2.5bar

    23 Receipt Pipeline to Tank HSD HSD ambient 2.5bar

    24 Receipt Pipeline to Tank SKO SKO ambient 2 5bar

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    Sr. No Failure CaseMaterialHandled Temp Pressure

    28

    PL from pump house to

    gantry_MS MS ambient 2.5bar

    29

    PL from pump house to

    gantry_SKO SKO ambient 2.5bar

    30

    PLfrom pump house to

    gantry_HSD HSD ambient 2.5bar

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    1.2 Continuous Releases

    If ignited immediately, a continuous release will form a jet fire. If ignition is delayed, a

    flammable cloud would be formed and drifted with the wind. In such situation, if the

    cloud is ignited (after some delays), a flash fire or Vapour Cloud Explosion (VCE) may

    result, depending upon the degree of congestion within area and energy strength of the

    ignition source.

    1.3

    Instantaneous Releases

    An instantaneous release would result from catastrophic rupture of a storage vessel (such

    as the storage cylinders, the trailers etc.) or reactors. If ignition is immediate, a fireball

    may be formed depending on the nature of the material. If ignition occurs after some

    delay similar to continuous release, a flash fire or VCE may be the consequence.

    1.4 Events which could lead to a Release

    Releases can be caused by:

    - Impact event;

    - Natural event (e.g. tide, waves, tsunamis, strong winds);

    - Failure or leak from other equipment, pipe-work or fittings;

    - Internal explosion in ship;

    - Incorrect operation;

    - Release occasioned from other operations or maintenance;

    - Vandalism/sabotage

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    1.5 Failure Cases

    The failure cases with the hole sizes considered for each of the release is as follows

    Table 1-2 : List of Failure CasesSr. No Failure Case Hole Size (mm)

    Small Medium Large Cata/ FBR

    Tank

    Fire

    1 TK-1 5mm NA 100 mm

    catastrophic

    Rupture

    Tank

    Fire

    2 TK-2 5mm NA 100 mm

    catastrophic

    Rupture

    Tank

    Fire

    3 TK-3 5mm NA 100 mm

    catastrophic

    Rupture

    Tank

    Fire

    4 TK-4 5mm NA 100 mmcatastrophic

    RuptureTankFire

    5 TK-5 5mm NA 100 mm

    catastrophic

    Rupture

    Tank

    Fire

    6 TK-6 5mm NA 100 mm

    catastrophic

    Rupture

    Tank

    Fire

    7 TK-7/UG 5mm NA NA

    catastrophic

    Rupture NA

    8 TK-8/UG 5mm NA NA

    catastrophic

    Rupture NA

    9 TK-9/UG 5mm NA NA

    catastrophic

    Rupture NA

    10 TK-10 5mm NA 100 mm

    catastrophic

    Rupture

    Tank

    Fire

    11 TK-11 5mm NA 100 mm

    catastrophic

    Rupture

    Tank

    Fire

    12 TK-12 5mm NA 100 mm

    catastrophic

    Rupture

    Tank

    Fire

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    Sr. No Failure Case Hole Size (mm)

    Small Medium Large Cata/ FBR

    Tank

    Fire

    16 TK-16 5mm NA 100 mm

    catastrophic

    Rupture

    Tank

    Fire

    17 TK-17 5mm NA 100 mm

    catastrophic

    Rupture

    Tank

    Fire

    18 TK-18 5mm NA 100 mm

    catastrophic

    Rupture

    Tank

    Fire

    19 HSD Pump_2400 LPM NA NA NA FBR NA

    20 SKD Pump_1200 LPM NA NA NA FBR NA

    21 MS Pump 2400 LPM NA NA NA FBR NA

    22

    Receipt Pipeline to

    Tank MS 5mm 25mm 100 mm FBR NA

    23

    Receipt Pipeline to

    Tank HSD 5mm 25mm 100 mm FBR NA

    24

    Receipt Pipeline to

    Tank SKO 5mm 25mm 100 mm FBR NA

    25

    pl from tank to pump

    house_MS 5mm 25mm 100 mm FBR NA

    26

    PL from tank to pump

    house_HSD 5mm 25mm 100 mm FBR NA

    27

    PL from tank to pump

    house_SKO 5mm 25mm 100 mm FBR NA

    28

    PL from pump house to

    gantry_MS 5mm 25mm 100 mm FBR NA

    29

    PL from pump house to

    gantry_SKO 5mm 25mm 100 mm FBR NA

    30

    PLfrom pump house to

    gantry_HSD 5mm 25mm 100 mm FBR NA

    NA stands for Not Applicable

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    1.6 Release duration

    Release duration of 600 seconds is chosen for this study. This includes the time to detect,

    isolate and the subsequent blow down (if possible) of the node from which leak occurs.

    After the leak is detected and the section is isolated it is understood that no more

    inventory is entering the section.

    2 FREQUENCY DISCUSSION

    Estimation of the likelihood of occurrence of each of the failure cases modelled has been

    done based on historical failure frequencies of process equipment. The historical failure

    data are based on an extensive research by DNV on several failure frequency databases

    worldwide. DNV has ensured that the most reputable, comprehensive and appropriate

    data are selected for each of the equipment failure frequencies quoted.

    The below Table shows the failure frequencies that are considered for the failure case

    scenarios

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    Report No.: 12QR1P2-27Rev 02, 30thJuly, 2013

    Page 9

    Table 2-1 : Failure frequencies of the identified scenarios

    Case Description Small Medium Large FBR

    Atmospheric Storage tank Failure 2.50E-03 1.00E-04 5.00E-06 2.00E-03

    Underground Tank Failure 3.80E-04 4.30E-05 8.40E-06 1.00E-05

    Pipeline from Tank to Pump House9.00E-07 1.10E-06 2.50E-07 5.60E-08

    Receipt Lines to Tanks9.00E-07 1.10E-06 2.50E-07 5.60E-08

    HSD, SKD, Ethanol, MS pump failure 0 0 0 3.00E-05

    HSD, SKD, MS loading arm Failure 7.80E-03 1.80E-02 7.10E-03 1.40E-03

    HSD,SKD, MS Road Tanker Failure 9.00E-05 9.00E-05 1.00E-05 5.00E-07

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    Annexe 4

    Consequence Analysis

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    Table of Contents

    1 CONSEQUENCE ASSESSMENT ................................................................................ 4

    1.1 Pool Fire ................................................................................................................. 5

    1.2 Jet Fire .................................................................................................................... 6

    1.3 Flash Fire ................................................................................................................ 7

    1.4 Vapour Cloud Explosion (VCE).............................................................................. 8

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    List of Tables

    Table 1-1 : Consequence Results ............. .............. ............. ............ .............. ............. ............ .............. .............. ...... 9

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    1

    CONSEQUENCE ASSESSMENT

    For each defined failure case for the POL Terminal Bharatpur, the consequence

    modelling is carried out to determine the potential effects of releases, the results of which

    are discussed in terms of hazard distances.

    The corresponding consequences in terms of flammable and explosive effects are

    modelled and analysed by using PHAST RISK software version 6.7. The flammable

    consequences that may potentially arise from failure of equipments or lines are:

    - Jet fires;

    - Flash fires;

    - Fireball; and/or

    - Explosions.

    The hazard distances for each event depend on the leak size, operating conditions,

    weather conditions, the release location, the release conditions and the dispersion

    characteristics as calculated by the PHAST RISK software. Each failure case is entered

    into PHAST RISK software, where the corresponding consequences and risk impact are

    calculated, based on built-in programmable event trees.

    The dispersion of gas releases from different hole sizes are modelled using state-of-art

    methods. For flammable and explosive consequence, the effect zones for the various

    possible outcomes of such a release are determined for both early and delayed ignition

    presents the consequence hazard distances for the failure case scenarios identified in the

    POL Terminal Bharatpur.

    Consequence distances for the following weather conditions have been evaluated in the

    tables below,

    - D11 : D stability (neutral) and 11 m/s wind speed.

    - F3 : F stability (very stable) and 3 m/s wind speed.

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    The consequence analysis is performed using DNV proprietary software PHAST. PHASTis a consequence and impact assessment module integrated within DNV risk calculation

    software PHAST Risk. The following descriptions are based on the different hazard types

    modeled, which are jet fires, flash fires, vapor cloud explosions, pool fires.

    1.1

    Pool Fire

    A pool fire in the open air and in an enclosed area may take place when there is anignition of a liquid spill which is released on a horizontal, solid surface in the open air or

    within an enclosure. A liquid pool fire can be either fuel controlled or ventilation

    controlled.

    In general terms, outside pool fires rarely cause fatalities as the time between when the

    fire starts until the time when the fire is fully developed is usually sufficient for people to

    escape. If there are fatalities, these tend to be people caught within the pool itself or laterfire fighting personnel in the event of a boil-over (due to burning oil not thermal

    radiation).

    The extent of the consequence of a Pool fire is represented by the thermal radiation

    envelope. Three levels of radiation are presented in this report, i.e.:

    - 4 kW/m2; this level is sufficient to cause personnel if unable to reach cover

    within 20s; however blistering of the skin (second degree burn) is likely; 0:

    lethality.

    - 12.5 kW/m2; this level will cause extreme pain within 20 seconds and

    movement to a safer place is instinctive. This level indicates around 6% fatality

    for 20 seconds exposure.

    - 37.5 kW/m2; this level of radiation is assumed to give 100% fatality.

    In Case of tanks small, medium leaks are considered from the fittings around the tanks

    like flanges, valves etc, and tank fire and bund fire scenarios are considered as the worst

    i T bl 1 1 b l i i f il i h h

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    1.2

    Jet Fire

    A jet fire may result from ignition of a high-pressure leakage of gas from process plants

    or storage tanks. Jet fires are characterized by a high momentum jet flame that is highly

    turbulent. The flame is lifted above the exit opening from which the gas is discharged

    generally at high pressure. This distance appears because the combustion process can

    only take place when the flow velocity is reduced sufficiently to allow stable combustion.

    Another feature of such fires is the high entrainment of air into the flame plume due tothe highly turbulent flame.

    The extent of the consequence of a Jet fire is represented by the thermal radiation

    envelope. Three levels of radiation are presented in this report, i.e.:

    - 4 kW/m2; this level is sufficient to cause personnel if unable to reach cover

    within 20s; however blistering of the skin (second degree burn) is likely; 0:

    lethality,

    - 12.5 kW/m2; this level will cause extreme pain within 20 seconds and

    movement to a safer place is instinctive. This level indicates around 6% fatality

    for 20 seconds exposure.

    - 37.5 kW/m2; this level of radiation is assumed to give 100% fatality.

    Jet fires are a direct hazard to people and structures caught within the flame envelope or

    exposed to high thermal radiation levels. This scenario is considered for the whole

    boosting station in which material is handled at the significant pressures. Table 1-1below

    summarises representative failure cases with the associated jet fire conse