hydrodeoxygenation on transition metal phosphides

École polytechnique fédérale de Lausanne (EPFL) Valais/Wallis Institute of Chemical Sciences and Engineering (ISIC) Basic Science Faculty (SB) Energypolis, Rue de l’Industrie 17, CH-1950 Sion, Switzerland ENERGYPOLIS SEMINAR 05. 04. 2016, 14:00 - 15:00, ENERGYPOLIS Sion, 4 th floor, Seminar room Hydrodeoxygenation on transition metal phosphides Xiaoyang Huang, Marco Peroni, Oliver Y. Gutiérrez, Johannes A. Lercher Technische Universität München, Department of Chemistry and Catalysis Research Center, Lichtenbergstraße 4, 85748 Garching, Germany Transition metal phosphides are an interesting option as catalyst for hydrodefunctionalization of biomass derived molecules, intrinsically more active than sulfides and more poison tolerant than most base or noble metals [1] . As newer synthesis methods have replaced the old high temperature routes, a wider variety of catalytic materials has become available [2] . In order to explore catalytic properties beyond the frequently tested NiP, a series of phosphide materials (W, Mo, and Ni) was prepared by a novel route based on the addition of citric acid in the synthesis and explored with respect to the hydrodeoxygenation of palmitic acid as a model compound for algae based feedstocks. References: [1] Prins, R., Bussell, M. E., Catal. Lett. 142, 1413 (2012). [2] Soled, S., Miseo, S., Baumgartner J., Guzman, J. “Can Ni Phosphides Become Viable Hydroprocessing Catalysts?” paper presented at the 23rd North American Meeting of the North American Catalysis Society (NAM), Kentucky, USA, 2013. CV: Xiaoyang Huang Born 28/04/1990. 06/2013: Bachelor Degree in Environmental Engineering, Zhejiang University, China. 04/2015: Joint Master Degree in Industrial Chemistry, National University of Singapore & Technical University of Munich. 05/2015-10/2015: Employed as a research assistant in the Department of Chemistry and Catalysis Research Center, Technical University of Munich. 11/2015-: Research work in Cardiff University, UK, in the research field of Hydroxymethylfurfural oxidation on gold nanoparticles.

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Page 1: Hydrodeoxygenation on transition metal phosphides

ÉcolepolytechniquefédéraledeLausanne(EPFL)Valais/WallisInstituteofChemicalSciencesandEngineering(ISIC)BasicScienceFaculty(SB)Energypolis,Ruedel’Industrie17,CH-1950Sion,Switzerland

ENERGYPOLISSEMINAR05.04.2016,14:00-15:00,ENERGYPOLISSion,4thfloor,Seminarroom

Hydrodeoxygenationontransitionmetalphosphides

XiaoyangHuang,MarcoPeroni,OliverY.Gutiérrez,JohannesA.Lercher

TechnischeUniversitätMünchen,DepartmentofChemistryandCatalysisResearchCenter,Lichtenbergstraße4,85748Garching,Germany

Transition metal phosphides are an interesting option as catalyst for hydrodefunctionalization ofbiomassderivedmolecules, intrinsicallymoreactivethansulfidesandmorepoisontolerantthanmostbaseornoblemetals[1].Asnewersynthesismethodshavereplacedtheoldhightemperatureroutes,awider variety of catalytic materials has become available [2]. In order to explore catalytic propertiesbeyondthefrequentlytestedNiP,aseriesofphosphidematerials (W,Mo,andNi)waspreparedbyanovel route based on the addition of citric acid in the synthesis and explored with respect to thehydrodeoxygenationofpalmiticacidasamodelcompoundforalgaebasedfeedstocks. References:[1]Prins,R.,Bussell,M.E.,Catal.Lett.142,1413(2012).[2]Soled,S.,Miseo,S.,BaumgartnerJ.,Guzman,J.“CanNiPhosphidesBecomeViableHydroprocessingCatalysts?”paperpresentedatthe23rdNorthAmericanMeetingoftheNorthAmericanCatalysisSociety(NAM),Kentucky,USA,2013.

CV:XiaoyangHuangBorn28/04/1990.06/2013:BachelorDegreeinEnvironmentalEngineering,ZhejiangUniversity, China. 04/2015: Joint Master Degree in Industrial Chemistry, NationalUniversity of Singapore & Technical University of Munich. 05/2015-10/2015:Employed as a research assistant in the Department of Chemistry and CatalysisResearchCenter,TechnicalUniversityofMunich.11/2015-:ResearchworkinCardiffUniversity, UK, in the research field of Hydroxymethylfurfural oxidation on goldnanoparticles.

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