hydrogen and fuel cell energy - engineers australia · 2015 system targets energy storage...
TRANSCRIPT
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Presentation to Engineers Australia
Thursday, 24 May, 2007
Mineral Springs Room, RSL - Mittagong
HYDROGEN AND FUEL CELL ENERGY
Southern Highlands and Tablelands Regional Group
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AUSTRALIAN DEMONSTRATED RESOURCES
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AUSTRALIA – POWER NETWORKS
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AUSTRALIA – ENERGY PRODUCTION BY FUEL
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ENERGY CONSUMPTION, BY INDUSTRY
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ENERGY CONSUMPTION, BY INDUSTRY
Other
2%
Transport
23%Electricity
30%
Manufacturin
g
23%
Mining
6% Agriculture
2%
Residential
8%
Commercial
5%
Construction
1%
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PEAK OIL
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DRIVERS FOR CLEAN FUELS AND ENERGY SYSTEMS
1. Energy security
2. Environment quality
4. Reliability
Greenhouse emissions
Urban Air Quality
3. Energy efficiency
5. Safety
6. Potential for reduced costs
Noise
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LIFE CYCLE ANALYSIS (LCA)
CONSIDERS ALL STEPS ACROSS THE ENTIRE ENERGY SUPPLY CHAIN
BASED ON AN ENERGY (GJ), EMISSIONS (Mt) OR COST ($) BASIS
EXPLORATION
EXTRACTION
PRODUCTION
DISTRIBUTION
WASTE MANAGEMENT
END-USE
STORAGE
SOCIETAL COSTS
AIR, WATER, LAND HEALTH, VISIBILITY
RESOURCES
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LCA: LDV CO2-e EMISSIONS (kg/km)
Family-sized vehicle (European Drive Cycle) – CSIRO LCA study, 2004
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LCA: LDV CO2-e EMISSIONS (kg/km)
Family-sized vehicle (European Drive Cycle) – CSIRO LCA study, 2004
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LCA: LDV PM10 EMISSIONS (mg/km)
Family-sized vehicle (European Drive Cycle) - – CSIRO LCA study, 2004
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LCA: LDV GHG EMISSIONS
Vehicle: GOLF III, 150,000 km
life, FC 12.3 km/L
Source: Kuhndt and
Bilitewski, 1999
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GOVERNMENT REPORT: NATIONAL HYDROGEN STUDY (DITR, 2003)
„Australia recognises the potential of hydrogen to
contribute to a more environmentally friendly and
sustainable energy mix and will continue to play an
active role in the national and international
development of hydrogen and related enabling
technologies. In doing so, Australia will focus on
areas where it has scientific, technical or other
advantages.‟
The Hon.
Ian Macfarlane,
Federal Minister for
Industry, Tourism
and Resources
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INTERNATIONAL PROGRAMS
International Partnership for the Hydrogen Economy
International Energy Agency
Hydrogen Implementing Agreement
APEC Energy Working Group
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AUSTRALIAN HYDROGEN ACTIVITY REPORT (4 July, 2005)
“involving at least 36 different organisations”
“120 hydrogen energy research projects underway”
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AUSTRALIAN H&FC ACTIVITY
CFCL
Universities:
National Hydrogen
Materials Alliance
CUTE Bus
Trial
CBOM
Antarctic Division
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HYDROGEN ENERGY INFRASTRUCTURE
End-use
Renewables
Biological
Pipelines Transport and
distribution
Transport: land, sea and air
Fossil fuels
Land and tanker transport
Refuelling/Terminals/
Bulk storage
Power:Industrial, commercial, residential
Storage
Nuclear
Production
, portable
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HYDROGEN CAPTIVE MARKETS
GLASS
Polishing
FOOD
Fat & Oils
GLASS
Float Glass
GLASS
Optical Fiber
FOOD
Starch
CHEMICALS
Specialty
ELECTRONICSSPACE
HEAT TREATMENT
LABORATORY
REFINING
CHEMICALS
Basics
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HYDROGEN MERCHANT MARKETS
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UPTAKE OF ALTERNATIVE FUELS 2010
from CSIRO “The heat is on – the future of energy in Australia”, 2006
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UPTAKE OF ALTERNATIVE FUELS 2050
from CSIRO “The heat is on – the future of energy in Australia”, 2006
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HYDROGEN SUPPLY
Clean Fuels Project (October 2000)
36,000 scm/hr production capacity
BOC's 2nd largest gas production plant investment in the world @ £65 mill
H2/CO2 POX UnitH2/CO2 POX Unit
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BP/GE “ENERGY” PLANT (475 MWe)
storing some 1.8 million tonnes of CO2 a year in the North Sea Miller oilfield
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“HYDROGEN ENERGY” PROPOSED GASIFICATION PLANT (500 MWe)
A$2 billion (US$1.5 billion) coal-fired power generation project
15 % of the power demand of south west Western Australia
half a million homes
Kwinana, Western Australia
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HYDROGEN PRODUCTION: IGCC EMISSIONS
0.5
1
1.5
2
SCPC1 IGCC2 NGCC1
NOx SO2 PM Hg
~80% 95%+
NOx SO2 PM Hg NOx SO2 PM Hg
~0 ~0 ~0
lb/MWh
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ELECTROLYSIS
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HYDROGEN DISTRIBUTION
MOBILE REFUELLING STATIONS
CONVENTIONAL DISTRIBUTION
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HYDROGEN DISTRIBUTION: REFUELLING
No. Hydrogen Fuel Stations World wide
-
20
40
60
80
100
120
140
160
Pre-1
998
1998
1999
2000
2001
2002
2003
2004
2005
2006
Source: A lexandra B aker, Fuel C ell M arket Survey: A ut omot ive
Hydrogen Inf rast ruct ure, Fuel C ell Today – 2 5 M ay 2 0 0 5
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HYDROGEN DISTRIBUTION: REFUELLING
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HYDROGEN STORAGE
NEW TECHNOLOGY
CONVENTIONAL STORAGE
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VEHICULAR STORAGE
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HYDROGEN STORAGE: TARGETS
USDOE performance targets (transport)
0
1
2
3
4
5
6
7
8
9
10
specific
energy
(kWh/kg)
weight
percent
H2, %
energy
density
(kWh/liter)
system
cost ($/kg
system)
flow rate
(g/sec)
refueling
rate (kg
H2/min)
2007
2010
2015
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HYDROGEN STORAGE: NEW MATERIALS
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HYDROGEN STORAGE: TRENDS
Hydrogen properties of various storage media
CH2 @ 350 bar = 24
kg/m 3 @ 100%
CH2 @ 700 bar = 40
kg/m 3 @ 100%
CH4
C2H6
C3H8
NH3FeTiH1.7
LaNiH6
CaH2
NaH
Mg2NiH4
TiH2
KBH4
MgH2
CH3OH
C2H5OH
C8H8
LH2 = 71 kg/m 3 @ 100%
0
20
40
60
80
100
120
140
160
0 5 10 15 20 25
Hydrogen mass
density (mass %)
Hydrogen
vol. density
(kg H2/m3)
2010 system targets
2015 system targets
Energy storage properties of various fuels
NaBH4LiBH4
Al(BH4)3
LH2 (new)
0
88
176
0 15 30Specific energy
(W-h/kg)
Energy
density
(W-h/L)
2010 system targets
2015 system targets
Propane and
gasoline limits
6,000
3,000
5,000 10,000
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HYDROGEN END-USE: FUEL CELL TYPES
Alkaline
(AFC)
Polymer
Electrolyte
Membrane
(PEMFC)
Direct Methanol
(DMFC)
Polymer
Electrolyte
Membrane
(PEMFC)
Direct
Methanol
(DMFC)
Solid Oxide
(SOFC)
Phosphoric
Acid
(PAFC)
Molten
Carbonate
(MCFC)
TYPES OF
FUEL CELLS
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HYDROGEN END-USE: STATIONARY POWER
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GLOBAL LEADER: CERAMIC FUEL CELLS LTD
World leader in planar SOFC development
Micro CHP (COGEN) units (1-5 kW)
Expanding into European market
Originally based in Melbourne, Australia
have signed product development
agreements with gas water heater
manufacturers in Germany and France
cell/stack plant in Germany supported by the
State of North Rhine Westphalia
advanced ceramic powder plant near
Liverpool, UK
moved from the circular all-ceramic stack with
electrolyte supported cells to a rectangular
metal enclosed array of anode supported cells
that doubles the power density and is more
compact
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SOLID OXIDE FUEL CELL COSTS
The estimated costs were
diesel generator
$800-$1,500/kW
natural gas turbine
< $400/kW
Delphi and GE have made significant advances in the reduction of solid oxide fuel
cell (SOFC) stack costs, surpassing the SECA target for 2006.
$294/kW for a 4.24 kW Delphi system;
$254/kW for a 5.4 kW GE system.
2010 goal: < $400/kW system cost.
April 6, 2007
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MOLTEN CARBONATE FC COSTS
> 300 kW systems
www.fce.com/site/investor/strategy_9_12.html
Fuel Cell Energy (USA)
approx. US$ 3,500/kW for MW scale systems
commercial target: US$ 2,000-3000/kW
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HYDROGEN AND FUEL CELLS FOR TRANSPORT
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TRENDS IN FUELS DEVELOPMENT
TIME
SCALE
STEAM ENGINE: 19th C TECHNOLOGY
COMBUSTION ENGINE: 20th C TECHNOLOGY
FUEL CELL: 21st C TECHNOLOGY
INDUSTRIAL REVOLUTION
INFORMATION AGE
LOW SPECIFIC WEIGHT
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INTERNAL COMBUSTION vs FUEL CELL ELECTRIC
GAS COMBUSTION
LIMITED TO OTTO EFFICIENCY
EMITS SOME TAILPIPE POLLUTANTS
ELECTRIC MOTOR
HIGH EFFICIENCY
NO TAILPIPE POLLUTANTS
SIMPLE DESIGNCOMPLEX BUT FLEXIBLE DESIGN
HUGE ECONOMY OF SCALE DISRUPTIVE TECHNOLOGY
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UPTAKE OF ICE vs HYBRID ELECTRIC-ICE VEHICLES 2050
from CSIRO “The heat is on – the future of energy in Australia”, 2006
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MEMBRANE REACTIONS
O2
2H2O
4H+
4e -
2
H2
O2
H2O
2H2 4H+
4e -
O2
2H2O
4H+
4e -
H+
Transport
AnodeCathode
Polymer
electrolyte Carbon cloth
Pt-cat
Pt-catalyst
Oxidation
Reduction
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FUEL CELL FEATURES
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REVERSIBLE FUEL CELL UNIT
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FUEL CELL KIT COMPONENTS
FUEL CELL KIT COMPONENTS
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• Top speed: 160 km/h
CASE STUDY: THE HONDA - FCX
The Honda Home Energy Station.
• High-efficiency lithium ion battery
• Drive range: up to 570 km (30%)
• Power output: 95 kW, 14kW FC increase
• FC stack: 20% smaller
• FC stack: Horizontal to vertical gas flow• Power plant: 180kg (30%) lighter
• Power plant: 40 % smaller in volume
• Energy efficiency: 60 percent
ie 3 x petrol-engine vehicle
ie 2 x hybrid vehicle
ie 10% higher cf. current FCX
• converts natural gas into hydrogen
• fills the FCX's tank overnight
• provides electricity and hot water to entire house
• “Space-age”, “spacious interior”
Web site: www.world.honda.com/fcx/
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HONDA FCX – RELEVANT CONSIDERATIONS
10. Integration
1. Performance
2. Cost
3. Environment
4. Ergonomics
6. Quality
7. Reliability
8. Safety
9. Design life
5. Aesthetics
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FCX AND MGS – RELEVANT DESIGN CONSIDERATIONS
1. PerformanceSmaller Size - Compact
More power
Increased efficiency
Extended range
Lighter Weight
5. Aesthetics 10. Integration
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PEM FUEL CELL DURABILITY GOALS
2005: 2,100 hr. 2010 Goal: 5,000 hr.
2,000 hours equivalent to 100,000 kilometers under regular driving conditions
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PEM FUEL CELL START UP GOALS
2005: -25°C in 90 s 2010 Goal: -30°C in 30 s
to 50% of rated power
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PEM FUEL CELL VOL. POWER DENSITY GOALS
2005: 1,470 Wnet/L 2010 Goal: 2,500 Wnet/L
2010: US DOE target 2,000 Wnet/L
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PEM FUEL CELL COST GOALS
2005: US$75/kW 2010 Goal: US$30/kW
2005: 10% less than 2004
SPACE PROGRAM
1960s and 1970s
≈$600,000/kW
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HYDROGEN END-USE: MICRO/PORTABLE
• Portable appliances and power tools
• Small personal vehicles
• Consumer electronics (laptops, cell phones)
• Roadway and traffic signage
• Backup power
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TECHNOLOGY TRANSITIONS
In 1954 ….
In 2006 ….
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AUSTRALIAN INSTITUTE OF ENERGY HYDROGEN DIVISION
Objectives:
Web: www.aie.org.au/hydrogen
• To offer a credible source of information & focal point pertaining to H&FC technology
• To promote inter-disciplinary discussion of H&FC technology and research
• To assist in the promotion of Australian H&FC projects and studies
• To demonstrate H&FC technology to the Australian community
• To encourage H&FC studies in educational curricula
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17TH WORLD HYDROGEN ENERGY CONFERENCE, 2008
International Association of
Hydrogen Energy
Dr Andrew Dicks
University of Queensland
WHEC XVII Chairman
Australian Institute of Energy
Brisbane, WHEC Host City
Brisbane Convention and Exhibition Centre,
WHEC Venue