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LEGENDS Burlington, MA USA Case Name: DFP FINAL.HSC Unit Set: Field Date/Time: Wed Mar 21 00:56:33 2012 Material Stream: 1 Fluid Package: Basis-1 Property Package: UNIQUAC - Ideal CONDITIONS Vapour / Phase Fraction Temperature: (F) Pressure: (psia) Molar Flow (lbmole/hr) Mass Flow (lb/hr) Std Ideal Liq Vol Flow (barrel/day) Molar Enthalpy (Btu/lbmole) Molar Entropy (Btu/lbmole-F) Heat Flow (Btu/hr) Liq Vol Flow @Std Cond (barrel/day) Overall 0.0000 23.00 * 14.50 * 2205 * 7.046e+004 6431 -1.060e+005 -83.37 -2.338e+008 6456 * Liquid Phase 1.0000 23.00 14.50 2205 7.046e+004 6431 -1.060e+005 -83.37 -2.338e+008 6456 PROPERTIES Molecular Weight Molar Density Mass Density Act. Volume Flow Mass Enthalpy Mass Entropy Heat Capacity Mass Heat Capacity Lower Heating Value Mass Lower Heating Value Phase Fraction [Vol. Basis] Phase Fraction [Mass Basis] Partial Pressure of CO2 Cost Based on Flow Act. Gas Flow Avg. Liq. Density Specific Heat Std. Gas Flow Std. Ideal Liq. Mass Density Act. Liq. Flow Z Factor Watson K User Property Partial Pressure of H2S Cp/(Cp - R) Cp/Cv Heat of Vap. Kinematic Viscosity Liq. Mass Density (Std. Cond) Liq. Vol. Flow (Std. Cond) Liquid Fraction Molar Volume Mass Heat of Vap. Phase Fraction [Molar Basis] Surface Tension Thermal Conductivity Viscosity Cv (Semi-Ideal) Mass Cv (Semi-Ideal) Cv Mass Cv Cv (Ent. Method) Mass Cv (Ent. Method) Cp/Cv (Ent. Method) (lbmole/ft3) (lb/ft3) (barrel/day) (Btu/lb) (Btu/lb-F) (Btu/lbmole-F) (Btu/lb-F) (Btu/lbmole) (Btu/lb) (psia) (Cost/s) (ACFM) (lbmole/ft3) (Btu/lbmole-F) (MMSCFD) (lb/ft3) (USGPM) (psia) (Btu/lbmole) (cSt) (lb/ft3) (barrel/day) (ft3/lbmole) (Btu/lb) (dyne/cm) (Btu/hr-ft-F) (cP) (Btu/lbmole-F) (Btu/lb-F) (Btu/lbmole-F) (Btu/lb-F) (Btu/lbmole-F) (Btu/lb-F) Overall 31.96 1.501 47.97 6278 -3318 -2.609 22.55 0.7056 2.816e+005 8810 2.122e-314 0.0000 0.0000 1.465 22.55 20.04 46.83 183.1 1.865e-003 11.26 0.0000 1.097 1.235 1.646e+004 0.5151 46.65 6456 1.000 0.6662 515.1 0.0000 44.50 0.1664 0.3958 20.56 0.6435 18.26 0.5715 3601 112.7 6.262e-003 Liquid Phase 31.96 1.501 47.97 6278 -3318 -2.609 22.55 0.7056 2.816e+005 8810 1.000 1.000 0.0000 1.465 22.55 20.04 46.83 183.1 1.865e-003 11.26 1.097 1.235 0.5151 46.65 6456 1.000 0.6662 1.0000 44.50 0.1664 0.3958 20.56 0.6435 18.26 0.5715 3601 112.7 6.262e-003 Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 1 of 76 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 * Specified by user. Licensed to: LEGENDS

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Page 1: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 1Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Vapour / Phase FractionTemperature: (F)Pressure: (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)Liq Vol Flow @Std Cond (barrel/day)

Overall0.000023.00 *

14.50 *

2205 *

7.046e+0046431

-1.060e+005-83.37

-2.338e+0086456 *

Liquid Phase1.000023.0014.502205

7.046e+0046431

-1.060e+005-83.37

-2.338e+0086456

PROPERTIES

Molecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

Overall31.961.50147.976278

-3318-2.60922.55

0.70562.816e+005

8810

2.122e-3140.00000.0000

1.46522.5520.0446.83183.1

1.865e-00311.26

0.00001.0971.235

1.646e+0040.515146.6564561.000

0.6662515.1

0.000044.50

0.16640.395820.56

0.643518.26

0.57153601112.7

6.262e-003

Liquid Phase31.961.50147.976278

-3318-2.60922.55

0.70562.816e+005

88101.0001.000

0.0000

1.46522.5520.0446.83183.1

1.865e-00311.26

1.0971.235

0.515146.6564561.000

0.6662

1.000044.50

0.16640.395820.56

0.643518.26

0.57153601112.7

6.262e-003

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 1 of 76

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Page 2: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 1 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

PROPERTIES

Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(psia)(psia)

(barrel/day)

Overall78.4349.226456

-2.312

Liquid Phase78.4349.226456

-2.312

COMPOSITION

Overall Phase Vapour Fraction 0.0000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

429.9034 *

6.5239 *

874.3342 *

893.8386 *

MOLE FRACTION

0.1950 *

0.0030 *

0.3966 *

0.4054 *

MASS FLOW (lb/hr)

13774.9217 *

300.5544 *

40279.7014 *

16102.5914 *

MASS FRACTION

0.1955 *

0.0043 *

0.5717 *

0.2285 *

LIQUID VOLUMEFLOW (barrel/day)

1185.3515 *

25.8547 *

4114.6604 *

1104.8151 *

LIQUID VOLUMEFRACTION

0.1843 *

0.0040 *

0.6398 *

0.1718 *

Total 2204.6000 1.0000 70457.7689 1.0000 6430.6817 1.0000

Liquid Phase Phase Fraction 1.000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

429.90346.5239

874.3342893.8386

MOLE FRACTION

0.19500.00300.39660.4054

MASS FLOW (lb/hr)

13774.9217300.5544

40279.701416102.5914

MASS FRACTION

0.19550.00430.57170.2285

LIQUID VOLUMEFLOW (barrel/day)

1185.351525.8547

4114.66041104.8151

LIQUID VOLUMEFRACTION

0.18430.00400.63980.1718

Total 2204.6000 1.0000 70457.7689 1.0000 6430.6817 1.0000

K VALUE

COMPONENTSMethanol

EthanoldiM-Ether

H2O

MIXED0.00000.00000.00000.0000

LIGHT0.00000.00000.00000.0000

HEAVY

UNIT OPERATIONS

FEED TOPump: P-100

PRODUCT FROM LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Active): 14.50 psia *

Flow Specification (Active) Molar: 2205 lbmole/hr * Mass: 7.046e+004 lb/hr Std Ideal Liq Volume:6431 barrel/day

User Variables

NOTES

Description

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 2 of 76

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Page 3: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 2Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Vapour / Phase FractionTemperature: (F)Pressure: (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)Liq Vol Flow @Std Cond (barrel/day)

Overall0.000023.87152.32205

7.046e+0046431

-1.060e+005-80.54

-2.337e+0086456 *

Liquid Phase1.000023.87152.32205

7.046e+0046431

-1.060e+005-80.54

-2.337e+0086456

PROPERTIES

Molecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

Overall31.961.50247.996275

-3317-2.52022.56

0.70592.816e+005

8810

2.122e-3140.00000.0000

1.46522.5620.0446.83183.0

1.954e-00211.26

0.00001.0971.233

1.426e+0040.511746.6564561.000

0.6659446.3

0.000044.43

0.16640.393420.58

0.643818.30

0.5727384.712.04

5.864e-002

Liquid Phase31.961.50247.996275

-3317-2.52022.56

0.70592.816e+005

88101.0001.000

0.0000

1.46522.5620.0446.83183.0

1.954e-00211.26

1.0971.233

0.511746.6564561.000

0.6659

1.000044.43

0.16640.393420.58

0.643818.30

0.5727384.712.04

5.864e-002

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 3 of 76

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Page 4: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 2 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

PROPERTIES

Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(psia)(psia)

(barrel/day)

Overall78.4349.226456

-2.328

Liquid Phase78.4349.226456

-2.328

COMPOSITION

Overall Phase Vapour Fraction 0.0000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

429.90346.5239

874.3342893.8386

MOLE FRACTION

0.19500.00300.39660.4054

MASS FLOW (lb/hr)

13774.9217300.5544

40279.701416102.5914

MASS FRACTION

0.19550.00430.57170.2285

LIQUID VOLUMEFLOW (barrel/day)

1185.351525.8547

4114.66041104.8151

LIQUID VOLUMEFRACTION

0.18430.00400.63980.1718

Total 2204.6000 1.0000 70457.7689 1.0000 6430.6817 1.0000

Liquid Phase Phase Fraction 1.000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

429.90346.5239

874.3342893.8386

MOLE FRACTION

0.19500.00300.39660.4054

MASS FLOW (lb/hr)

13774.9217300.5544

40279.701416102.5914

MASS FRACTION

0.19550.00430.57170.2285

LIQUID VOLUMEFLOW (barrel/day)

1185.351525.8547

4114.66041104.8151

LIQUID VOLUMEFRACTION

0.18430.00400.63980.1718

Total 2204.6000 1.0000 70457.7689 1.0000 6430.6817 1.0000

K VALUE

COMPONENTSMethanol

EthanoldiM-Ether

H2O

MIXED0.00000.00000.00000.0000

LIGHT0.00000.00000.00000.0000

HEAVY

UNIT OPERATIONS

FEED TOMixer: MIX-100

PRODUCT FROMPump: P-100

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive) 152.3 psiaFlow Specification (Inactive) Molar: 2205 lbmole/hr Mass: 7.046e+004 lb/hr Std Ideal Liq Volume:6431 barrel/day

User Variables

NOTES

Description

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 4 of 76

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Page 5: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 3Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Vapour / Phase FractionTemperature: (F)Pressure: (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)Liq Vol Flow @Std Cond (barrel/day)

Overall0.000025.98152.32260

7.228e+0046587

-1.059e+005-78.13

-2.395e+0086612 *

Liquid Phase1.000025.98152.32260

7.228e+0046587

-1.059e+005-78.13

-2.395e+0086612

PROPERTIES

Molecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

Overall31.981.50147.996438

-3313-2.44322.71

0.71012.817e+005

8808

2.122e-3140.00000.0000

1.46722.7120.5546.90187.8

1.947e-00211.25

0.00001.0961.233

1.424e+0040.514246.7366121.000

0.6663445.2

0.000043.98

0.16480.395320.72

0.648018.42

0.5760393.912.32

5.765e-002

Liquid Phase31.981.50147.996438

-3313-2.44322.71

0.71012.817e+005

88081.0001.000

0.0000

1.46722.7120.5546.90187.8

1.947e-00211.25

1.0961.233

0.514246.7366121.000

0.6663

1.000043.98

0.16480.395320.72

0.648018.42

0.5760393.912.32

5.765e-002

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 5 of 76

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Page 6: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 3 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

PROPERTIES

Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(psia)(psia)

(barrel/day)

Overall75.0747.836612

-2.314

Liquid Phase75.0747.836612

-2.314

COMPOSITION

Overall Phase Vapour Fraction 0.0000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

482.97149.0619

874.3540894.0539

MOLE FRACTION

0.21370.00400.38680.3955

MASS FLOW (lb/hr)

15475.3228417.4806

40280.614016106.4702

MASS FRACTION

0.21410.00580.55730.2228

LIQUID VOLUMEFLOW (barrel/day)

1331.673435.9131

4114.75371105.0812

LIQUID VOLUMEFRACTION

0.20220.00550.62460.1678

Total 2260.4412 1.0000 72279.8876 1.0000 6587.4213 1.0000

Liquid Phase Phase Fraction 1.000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

482.97149.0619

874.3540894.0539

MOLE FRACTION

0.21370.00400.38680.3955

MASS FLOW (lb/hr)

15475.3228417.4806

40280.614016106.4702

MASS FRACTION

0.21410.00580.55730.2228

LIQUID VOLUMEFLOW (barrel/day)

1331.673435.9131

4114.75371105.0812

LIQUID VOLUMEFRACTION

0.20220.00550.62460.1678

Total 2260.4412 1.0000 72279.8876 1.0000 6587.4213 1.0000

K VALUE

COMPONENTSMethanol

EthanoldiM-Ether

H2O

MIXED0.00000.00000.00000.0000

LIGHT0.00000.00000.00000.0000

HEAVY

UNIT OPERATIONS

FEED TOHeater: E-100

PRODUCT FROMMixer: MIX-100

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive) 152.3 psiaFlow Specification (Inactive) Molar: 2260 lbmole/hr Mass: 7.228e+004 lb/hr Std Ideal Liq Volume:6587 barrel/day

User Variables

NOTES

Description

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 6 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 4Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Vapour / Phase FractionTemperature: (F)Pressure: (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)Liq Vol Flow @Std Cond (barrel/day)

Overall0.0406192.2 *

152.32260

7.228e+0046587

-1.016e+00526.93

-2.296e+0086612 *

Vapour Phase0.0406192.2152.391.784070411.2

-7.858e+00445.00

-7.212e+006441.1

Liquid Phase0.9594192.2152.32169

6.821e+0046176

-1.025e+00526.17

-2.224e+0086185

PROPERTIES

Molecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

Overall31.98

0.386112.35

2.502e+004-3176

0.842226.74

0.83622.817e+005

88086.243e-0025.631e-002

0.00000.0000

1.46726.7420.5546.90204.3

11.25

0.00001.0801.005

1.424e+004

46.736612

0.95942.590445.2

0.040630.60

24.750.774126.60

0.8320

Vapour Phase44.34

2.177e-0020.9654

1.802e+004-17721.01517.24

0.38895.354e+0051.207e+0046.243e-0025.631e-002

0.000070.26

0.954017.24

0.834342.30

1.00011.37

1.1301.130

0.697939.44441.1

0.000045.94

0.0406

1.297e-0021.079e-002

15.260.344115.26

0.3441

Liquid Phase31.451.32441.637004

-32600.831927.14

0.86292.709e+005

86140.93760.9437

0.0000

1.50127.1419.7147.21204.3

1.645e-00211.24

1.0791.079

0.207647.1561851.000

0.7555

0.959430.60

0.15260.138425.15

0.799725.15

0.7997

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 7 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 4 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

PROPERTIES

Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(psia)(psia)

(barrel/day)

Overall75.0747.836626

Vapour Phase113.5110.1441.1

Liquid Phase72.4545.306185

COMPOSITION

Overall Phase Vapour Fraction 0.0406

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

482.97149.0619

874.3540894.0539

MOLE FRACTION

0.21370.00400.38680.3955

MASS FLOW (lb/hr)

15475.3228417.4806

40280.614016106.4702

MASS FRACTION

0.21410.00580.55730.2228

LIQUID VOLUMEFLOW (barrel/day)

1331.673435.9131

4114.75371105.0812

LIQUID VOLUMEFRACTION

0.20220.00550.62460.1678

Total 2260.4412 1.0000 72279.8876 1.0000 6587.4213 1.0000

Vapour Phase Phase Fraction 4.060e-002

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

4.82050.0667

83.65743.2319

MOLE FRACTION

0.05250.00070.91150.0352

MASS FLOW (lb/hr)

154.45953.0743

3854.014558.2234

MASS FRACTION

0.03800.00080.94700.0143

LIQUID VOLUMEFLOW (barrel/day)

13.29150.2645

393.69613.9948

LIQUID VOLUMEFRACTION

0.03230.00060.95730.0097

Total 91.7766 1.0000 4069.7718 1.0000 411.2468 1.0000

Liquid Phase Phase Fraction 0.9594

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

478.15098.9952

790.6965890.8219

MOLE FRACTION

0.22050.00410.36460.4108

MASS FLOW (lb/hr)

15320.8632414.4063

36426.599516048.2468

MASS FRACTION

0.22460.00610.53400.2353

LIQUID VOLUMEFLOW (barrel/day)

1318.382035.6486

3721.05761101.0864

LIQUID VOLUMEFRACTION

0.21350.00580.60250.1783

Total 2168.6645 1.0000 68210.1158 1.0000 6176.1746 1.0000

K VALUE

COMPONENTSMethanol

EthanoldiM-Ether

H2O

MIXED0.23820.17532.500

8.573e-002

LIGHT0.23820.17532.500

8.573e-002

HEAVY

UNIT OPERATIONS

FEED TOEquilibrium Reactor: ERV-100

PRODUCT FROMHeater: E-100

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive) 152.3 psiaFlow Specification (Inactive) Molar: 2260 lbmole/hr Mass: 7.228e+004 lb/hr Std Ideal Liq Volume:6587 barrel/day

User Variables

NOTESHyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 8 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 4 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

NOTES

Description

Material Stream: 5Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Vapour / Phase FractionTemperature: (F)Pressure: (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)Liq Vol Flow @Std Cond (barrel/day)

Overall1.0000248.0 *

152.31218

4.963e+0044915

-8.105e+00444.88

-9.870e+0075177 *

Vapour Phase1.0000248.0152.31218

4.963e+0044915

-8.105e+00444.88

-9.870e+0075177

Aqueous Phase0.0000248.0152.3

0.00000.00000.0000

-1.144e+00513.25

0.00000.0000

PROPERTIES

Molecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal Conductivity

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

Overall40.75

2.005e-0020.8173

2.596e+005-19891.10117.07

0.41904.623e+0051.134e+004

4.941e-3240.00000.0000

10121.05917.0711.0743.16

0.0000

11.37

0.00001.1321.132

1.161e+0040.887140.985177

0.000049.87284.9

1.0000

1.477e-002

Vapour Phase40.75

2.005e-0020.8173

2.596e+005-19891.10117.07

0.41904.623e+0051.134e+004

1.0001.000

0.000010121.05917.0711.0743.16

1.00011.37

1.1321.132

0.887140.985177

0.000049.87

1.0000

1.477e-002

Aqueous Phase21.722.33550.73

0.0000-5265

0.610023.711.091

7.476e+0043442

0.0000

0.0000

2.54323.71

0.000055.24

0.00008.588e-003

11.25

1.0911.180

0.196656.82

0.00001.000

0.4282

0.000046.98

0.3081

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 9 of 76

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Page 10: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 5 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

PROPERTIES

ViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

Overall1.161e-002

15.090.370215.09

0.3702

113.194.985177

Vapour Phase1.161e-002

15.090.370215.09

0.3702

113.194.985177

Aqueous Phase0.159821.72

0.999920.09

0.9248

77.1422.60

0.0000

COMPOSITION

Overall Phase Vapour Fraction 1.0000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

54.06624.9657

955.0940203.6813

MOLE FRACTION

0.04440.00410.78430.1673

MASS FLOW (lb/hr)

1732.3851228.7692

44000.22353669.3391

MASS FRACTION

0.03490.00460.88660.0739

LIQUID VOLUMEFLOW (barrel/day)

149.074219.6795

4494.7200251.7571

LIQUID VOLUMEFRACTION

0.03030.00400.91440.0512

Total 1217.8072 1.0000 49630.7168 1.0000 4915.2307 1.0000

Vapour Phase Phase Fraction 1.000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

54.06624.9657

955.0940203.6813

MOLE FRACTION

0.04440.00410.78430.1673

MASS FLOW (lb/hr)

1732.3851228.7692

44000.22353669.3391

MASS FRACTION

0.03490.00460.88660.0739

LIQUID VOLUMEFLOW (barrel/day)

149.074219.6795

4494.7200251.7571

LIQUID VOLUMEFRACTION

0.03030.00400.91440.0512

Total 1217.8072 1.0000 49630.7168 1.0000 4915.2307 1.0000

Aqueous Phase Phase Fraction 0.0000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

0.00000.00000.00000.0000

MOLE FRACTION

0.05040.00390.10310.8426

MASS FLOW (lb/hr)

0.00000.00000.00000.0000

MASS FRACTION

0.07430.00830.21860.6988

LIQUID VOLUMEFLOW (barrel/day)

0.00000.00000.00000.0000

LIQUID VOLUMEFRACTION

0.08260.00930.28850.6196

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000

K VALUE

COMPONENTSMethanol

EthanoldiM-Ether

H2O

MIXED0.88121.0387.610

0.1985

LIGHT HEAVY0.88121.0387.610

0.1985

UNIT OPERATIONS

FEED TOValve: VLV-100

PRODUCT FROMEquilibrium Reactor: ERV-100

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 10 of 76

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Page 11: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 5 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive) 152.3 psiaFlow Specification (Inactive) Molar: 1218 lbmole/hr Mass: 4.963e+004 lb/hr Std Ideal Liq Volume:4915 barrel/day

User Variables

NOTES

Description

Material Stream: 6Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Vapour / Phase FractionTemperature: (F)Pressure: (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)Liq Vol Flow @Std Cond (barrel/day)

Overall1.0000247.9145.0 *

12184.963e+004

4915-8.105e+004

44.98-9.870e+007

5177 *

Vapour Phase1.0000247.9145.01218

4.963e+0044915

-8.105e+00444.98

-9.870e+0075177

PROPERTIES

Molecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/Cv

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

Overall40.75

1.910e-0020.7784

2.725e+005-19891.10417.06

0.41864.623e+0051.134e+004

4.941e-3240.00000.0000

10631.05917.0611.0743.16

1.00011.37

0.00001.1321.132

Vapour Phase40.75

1.910e-0020.7784

2.725e+005-19891.10417.06

0.41864.623e+0051.134e+004

1.0001.000

0.000010631.05917.0611.0743.16

1.00011.37

1.1321.132

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 11 of 76

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Page 12: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 6 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

PROPERTIES

Heat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

Overall1.166e+004

0.929740.985177

0.000052.35286.2

1.0000

1.474e-0021.159e-002

15.070.369815.07

0.3698

113.194.985177

Vapour Phase

0.929740.985177

0.000052.35

1.0000

1.474e-0021.159e-002

15.070.369815.07

0.3698

113.194.985177

COMPOSITION

Overall Phase Vapour Fraction 1.0000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

54.06624.9657

955.0940203.6813

MOLE FRACTION

0.04440.00410.78430.1673

MASS FLOW (lb/hr)

1732.3851228.7692

44000.22353669.3391

MASS FRACTION

0.03490.00460.88660.0739

LIQUID VOLUMEFLOW (barrel/day)

149.074219.6795

4494.7200251.7571

LIQUID VOLUMEFRACTION

0.03030.00400.91440.0512

Total 1217.8072 1.0000 49630.7168 1.0000 4915.2307 1.0000

Vapour Phase Phase Fraction 1.000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

54.06624.9657

955.0940203.6813

MOLE FRACTION

0.04440.00410.78430.1673

MASS FLOW (lb/hr)

1732.3851228.7692

44000.22353669.3391

MASS FRACTION

0.03490.00460.88660.0739

LIQUID VOLUMEFLOW (barrel/day)

149.074219.6795

4494.7200251.7571

LIQUID VOLUMEFRACTION

0.03030.00400.91440.0512

Total 1217.8072 1.0000 49630.7168 1.0000 4915.2307 1.0000

K VALUE

COMPONENTSMethanol

EthanoldiM-Ether

H2O

MIXED LIGHT HEAVY

UNIT OPERATIONS

FEED TOCooler: E-101

PRODUCT FROMValve: VLV-100

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 12 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 6 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

PROCESS UTILITY

DYNAMICS

Pressure Specification (Active): 145.0 psia *

Flow Specification (Inactive) Molar: 1218 lbmole/hr Mass: 4.963e+004 lb/hr Std Ideal Liq Volume:4915 barrel/day

User Variables

NOTES

Description

Material Stream: 7Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Vapour / Phase FractionTemperature: (F)Pressure: (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)Liq Vol Flow @Std Cond (barrel/day)

Overall0.7672192.2 *

145.0 *

12184.963e+004

4915-8.516e+004

39.62-1.037e+008

5177 *

Vapour Phase0.7672192.2145.0934.3

4.146e+0044194

-7.871e+00445.01

-7.354e+0074505

Aqueous Phase0.2328192.2145.0283.58171721.0

-1.064e+00521.87

-3.018e+007713.6

PROPERTIES

Molecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/Cv

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

Overall40.75

2.691e-0021.097

1.934e+005-2090

0.972219.13

0.46944.623e+0051.134e+004

0.85330.83540.00000.0000

1.05919.1311.0743.1623.28

11.37

0.00001.1161.087

Vapour Phase44.37

2.073e-0020.9200

1.926e+005-17741.01417.30

0.38985.362e+0051.208e+004

0.85330.8354

0.0000751.1

0.952217.308.49342.25

1.00011.38

1.1301.130

Aqueous Phase28.821.51843.75798.3-3693

0.759025.17

0.87322.185e+005

75790.14670.1646

0.0000

1.68125.172.57748.4423.28

1.366e-00211.30

1.0861.236

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 13 of 76

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Page 14: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 7 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

PROPERTIES

Heat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

Overall1.166e+004

40.985177

0.232837.16286.2

0.767237.52

17.140.420717.60

0.4318

113.194.985218

Vapour Phase

0.737339.344505

0.000048.23

0.7672

1.299e-0021.087e-002

15.310.345115.31

0.3451

116.7111.54505

Aqueous Phase

0.212148.95713.61.000

0.6588

0.232837.52

0.19640.148623.18

0.804320.36

0.7063

88.1343.43713.6

COMPOSITION

Overall Phase Vapour Fraction 0.7672

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

54.06624.9657

955.0940203.6813

MOLE FRACTION

0.04440.00410.78430.1673

MASS FLOW (lb/hr)

1732.3851228.7692

44000.22353669.3391

MASS FRACTION

0.03490.00460.88660.0739

LIQUID VOLUMEFLOW (barrel/day)

149.074219.6795

4494.7200251.7571

LIQUID VOLUMEFRACTION

0.03030.00400.91440.0512

Total 1217.8072 1.0000 49630.7168 1.0000 4915.2307 1.0000

Vapour Phase Phase Fraction 0.7672

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

25.17922.0829

863.214743.8352

MOLE FRACTION

0.02690.00220.92390.0469

MASS FLOW (lb/hr)

806.790895.9600

39767.4388789.6953

MASS FRACTION

0.01950.00230.95920.0190

LIQUID VOLUMEFLOW (barrel/day)

69.42558.2548

4062.331754.1818

LIQUID VOLUMEFRACTION

0.01660.00200.96860.0129

Total 934.3121 1.0000 41459.8850 1.0000 4194.1938 1.0000

Aqueous Phase Phase Fraction 0.2328

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

28.88702.8828

91.8792159.8461

MOLE FRACTION

0.10190.01020.32410.5638

MASS FLOW (lb/hr)

925.5943132.8092

4232.78472879.6437

MASS FRACTION

0.11330.01630.51800.3524

LIQUID VOLUMEFLOW (barrel/day)

79.648711.4247

432.3883197.5753

LIQUID VOLUMEFRACTION

0.11050.01580.59970.2740

Total 283.4951 1.0000 8170.8318 1.0000 721.0369 1.0000

K VALUE

COMPONENTSMethanol

EthanoldiM-Ether

MIXED0.26450.21922.851

LIGHT HEAVY0.26450.21922.851

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 14 of 76

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Page 15: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 7 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

K VALUE

COMPONENTSH2O

MIXED8.321e-002

LIGHT HEAVY8.321e-002

UNIT OPERATIONS

FEED TODistillation: T-100

PRODUCT FROMCooler: E-101

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Active): 145.0 psia *

Flow Specification (Inactive) Molar: 1218 lbmole/hr Mass: 4.963e+004 lb/hr Std Ideal Liq Volume:4915 barrel/day

User Variables

NOTES

Description

Material Stream: 8Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Vapour / Phase FractionTemperature: (F)Pressure: (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)Liq Vol Flow @Std Cond (barrel/day)

Overall0.0000110.0139.0956.0

4.403e+0044497

-8.662e+00437.85

-8.281e+0074878 *

Liquid Phase1.0000110.0139.0956.0

4.403e+0044497

-8.662e+00437.85

-8.281e+0074878

PROPERTIES

Molecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas Flow

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

Overall46.06

0.779935.925240

-18810.821928.21

0.61265.708e+0051.239e+004

2.122e-3140.00000.0000

Liquid Phase46.06

0.779935.925240

-18810.821928.21

0.61265.708e+0051.239e+004

1.0001.000

0.0000

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 15 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 8 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

PROPERTIES

Avg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

Overall0.908728.218.69041.85152.8

2.915e-00211.38

0.00001.0761.0767981

0.131238.5848781.0001.282173.3

0.00009.257

7.011e-0027.548e-002

26.230.569526.23

0.5695

120.4120.74878

Liquid Phase0.908728.218.69041.85152.8

2.915e-00211.38

1.0761.076

0.131238.5848781.0001.282

1.00009.257

7.011e-0027.548e-002

26.230.569526.23

0.5695

120.4120.74878

COMPOSITION

Overall Phase Vapour Fraction 0.0000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

0.93850.0100

955.07410.0075

MOLE FRACTION

0.00100.00000.99900.0000

MASS FLOW (lb/hr)

30.07220.4627

43999.31070.1346

MASS FRACTION

0.00070.00000.99930.0000

LIQUID VOLUMEFLOW (barrel/day)

2.58780.0398

4494.62670.0092

LIQUID VOLUMEFRACTION

0.00060.00000.99940.0000

Total 956.0302 1.0000 44029.9802 1.0000 4497.2635 1.0000

Liquid Phase Phase Fraction 1.000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

0.93850.0100

955.07410.0075

MOLE FRACTION

0.00100.00000.99900.0000

MASS FLOW (lb/hr)

30.07220.4627

43999.31070.1346

MASS FRACTION

0.00070.00000.99930.0000

LIQUID VOLUMEFLOW (barrel/day)

2.58780.0398

4494.62670.0092

LIQUID VOLUMEFRACTION

0.00060.00000.99940.0000

Total 956.0302 1.0000 44029.9802 1.0000 4497.2635 1.0000

K VALUE

COMPONENTSMethanol

MIXED0.0000

LIGHT0.0000

HEAVY

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 16 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 8 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

K VALUE

COMPONENTSEthanol

diM-EtherH2O

MIXED0.00000.00000.0000

LIGHT0.00000.00000.0000

HEAVY

UNIT OPERATIONS

FEED TOValve: VLV-102

PRODUCT FROMDistillation: T-100

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive) 139.0 psiaFlow Specification (Inactive) Molar: 956.0 lbmole/hr Mass: 4.403e+004 lb/hr Std Ideal Liq Volume:4497 barrel/day

User Variables

NOTES

Description

Material Stream: 9Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Vapour / Phase FractionTemperature: (F)Pressure: (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)Liq Vol Flow @Std Cond (barrel/day)

Overall0.0000320.5159.0261.85601418.0

-1.133e+00515.54

-2.966e+007410.3 *

Aqueous Phase1.0000320.5159.0261.85601418.0

-1.133e+00515.54

-2.966e+007410.3

PROPERTIES

Molecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)

Overall21.402.33249.89479.9-5296

0.726222.691.061

6.577e+0043074

0.00000.0000

Aqueous Phase21.402.33249.89479.9-5296

0.726222.691.061

6.577e+00430741.0001.000

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 17 of 76

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Page 18: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 9 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

PROPERTIES

Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

Overall0.0000

2.67722.692.38057.2814.00

8.144e-00310.64

0.00001.0961.213

1.539e+0040.168258.35410.31.000

0.4288719.1

0.000038.26

0.28990.134420.70

0.967718.70

0.8741

4.4812.329410.3

Aqueous Phase0.0000

2.67722.692.38057.2814.00

8.144e-00310.64

1.0961.213

0.168258.35410.31.000

0.4288

1.000038.26

0.28990.134420.70

0.967718.70

0.8741

4.4812.329410.3

COMPOSITION

Overall Phase Vapour Fraction 0.0000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

53.12774.95570.0198

203.6738

MOLE FRACTION

0.20300.01890.00010.7780

MASS FLOW (lb/hr)

1702.3129228.3065

0.91283669.2044

MASS FRACTION

0.30390.04080.00020.6551

LIQUID VOLUMEFLOW (barrel/day)

146.486419.63970.0932

251.7478

LIQUID VOLUMEFRACTION

0.35050.04700.00020.6023

Total 261.7770 1.0000 5600.7367 1.0000 417.9672 1.0000

Aqueous Phase Phase Fraction 1.000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

53.12774.95570.0198

203.6738

MOLE FRACTION

0.20300.01890.00010.7780

MASS FLOW (lb/hr)

1702.3129228.3065

0.91283669.2044

MASS FRACTION

0.30390.04080.00020.6551

LIQUID VOLUMEFLOW (barrel/day)

146.486419.63970.0932

251.7478

LIQUID VOLUMEFRACTION

0.35050.04700.00020.6023

Total 261.7770 1.0000 5600.7367 1.0000 417.9672 1.0000

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 18 of 76

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Page 19: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 9 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

K VALUE

COMPONENTSMethanol

EthanoldiM-Ether

H2O

MIXED0.00000.00000.00000.0000

LIGHT HEAVY0.00000.00000.00000.0000

UNIT OPERATIONS

FEED TOValve: VLV-101

PRODUCT FROMDistillation: T-100

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive) 159.0 psiaFlow Specification (Inactive) Molar: 261.8 lbmole/hr Mass: 5601 lb/hr Std Ideal Liq Volume:418.0 barrel/day

User Variables

NOTES

Description

Material Stream: 10Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Vapour / Phase FractionTemperature: (F)Pressure: (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)Liq Vol Flow @Std Cond (barrel/day)

Overall0.275593.091.450 *

261.85601418.0

-1.133e+00514.39

-2.966e+007410.3 *

Vapour Phase0.275593.091.45072.111872150.3

-9.519e+00443.17

-6.864e+006148.3

Aqueous Phase0.724593.091.450189.73729267.7

-1.202e+0053.443

-2.280e+007262.7

PROPERTIES

Molecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

Overall21.40

8.875e-0041.899e-0021.261e+006

-52960.672416.65

0.77806.577e+004

30740.35950.3343

Vapour Phase25.96

2.445e-0046.348e-0031.261e+006

-36661.6639.641

0.37131.547e+005

59570.35950.3343

Aqueous Phase19.663.03859.73266.9-6115

0.175219.31

0.98223.198e+004

16270.64050.6657

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 10 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

PROPERTIES

Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

Overall0.00000.0000

2.67716.652.38057.287.783

10.64

0.00001.1351.034

1.854e+004

58.35410.3

0.72451127866.8

0.275565.90

14.660.685216.10

0.7524

4.4812.329411.0

Vapour Phase

0.000049152.0519.641

0.655553.26

1.00010.64

1.2591.259

65.6053.97148.3

0.00004090

0.2755

9.102e-0036.670e-003

7.6550.29487.655

0.2948

4.4883.249148.3

Aqueous Phase

0.0000

3.02919.311.72459.547.783

8.048e-00510.64

1.1151.164

0.766960.66262.71.000

0.3291

0.724565.90

0.32130.733717.32

0.881216.59

0.8438

4.4701.775262.7

-0.8995

COMPOSITION

Overall Phase Vapour Fraction 0.2755

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

53.12774.95570.0198

203.6738

MOLE FRACTION

0.20300.01890.00010.7780

MASS FLOW (lb/hr)

1702.3129228.3065

0.91283669.2044

MASS FRACTION

0.30390.04080.00020.6551

LIQUID VOLUMEFLOW (barrel/day)

146.486419.63970.0932

251.7478

LIQUID VOLUMEFRACTION

0.35050.04700.00020.6023

Total 261.7770 1.0000 5600.7367 1.0000 417.9672 1.0000

Vapour Phase Phase Fraction 0.2755

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

34.24103.29110.0195

34.5561

MOLE FRACTION

0.47490.04560.00030.4792

MASS FLOW (lb/hr)

1097.1474151.6208

0.8995622.5315

MASS FRACTION

0.58600.08100.00050.3325

LIQUID VOLUMEFLOW (barrel/day)

94.411113.04290.0919

42.7125

LIQUID VOLUMEFRACTION

0.62830.08680.00060.2843

Total 72.1077 1.0000 1872.1992 1.0000 150.2584 1.0000

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 10 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

COMPOSITION

Aqueous Phase Phase Fraction 0.7245

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

18.88671.66460.0003

169.1177

MOLE FRACTION

0.09960.00880.00000.8916

MASS FLOW (lb/hr)

605.165676.68570.0133

3046.6729

MASS FRACTION

0.16230.02060.00000.8171

LIQUID VOLUMEFLOW (barrel/day)

52.07546.59680.0014

209.0353

LIQUID VOLUMEFRACTION

0.19450.02460.00000.7808

Total 189.6693 1.0000 3728.5375 1.0000 267.7088 1.0000

K VALUE

COMPONENTSMethanol

EthanoldiM-Ether

H2O

MIXED4.7695.201177.7

0.5375

LIGHT HEAVY4.7695.201177.7

0.5375

UNIT OPERATIONS

FEED TODistillation: T-101

PRODUCT FROMValve: VLV-101

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Active): 1.450 psia *

Flow Specification (Inactive) Molar: 261.8 lbmole/hr Mass: 5601 lb/hr Std Ideal Liq Volume:418.0 barrel/day

User Variables

NOTES

Description

Material Stream: 11Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Vapour / Phase FractionTemperature: (F)Pressure: (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)Liq Vol Flow @Std Cond (barrel/day)

Overall0.000092.713.75555.801820156.6

-1.033e+00510.15

-5.765e+006156.2 *

Liquid Phase1.000092.713.75555.801820156.6

-1.033e+00510.15

-5.765e+006156.2

PROPERTIES

Molecular WeightOverall

32.62Liquid Phase

32.62

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 11 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

PROPERTIES

Molar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

Overall1.49048.61160.1-3167

0.311228.15

0.86302.849e+005

8734

2.122e-3140.00000.0000

1.52328.15

0.507249.694.669

4.251e-00410.63

0.00001.0761.339

1.624e+0040.641149.83156.21.000

0.6711497.9

0.000028.05

0.10170.499226.17

0.802121.02

0.6444

4.570156.2

-1.755

Liquid Phase1.49048.61160.1-3167

0.311228.15

0.86302.849e+005

87341.0001.000

0.0000

1.52328.15

0.507249.694.669

4.251e-00410.63

1.0761.339

0.641149.83156.21.000

0.6711

1.000028.05

0.10170.499226.17

0.802121.02

0.6444

4.570156.2

-1.755

COMPOSITION

Overall Phase Vapour Fraction 0.0000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

53.06622.50360.01980.2086

MOLE FRACTION

0.95100.04490.00040.0037

MASS FLOW (lb/hr)

1700.3431115.3383

0.91283.7578

MASS FRACTION

0.93410.06340.00050.0021

LIQUID VOLUMEFLOW (barrel/day)

146.31699.92180.09320.2578

LIQUID VOLUMEFRACTION

0.93440.06340.00060.0016

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Page 23: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 11 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

COMPOSITION

Overall Phase (continued) Vapour Fraction 0.0000

Total 55.7982 1.0000 1820.3521 1.0000 156.5898 1.0000

Liquid Phase Phase Fraction 1.000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

53.06622.50360.01980.2086

MOLE FRACTION

0.95100.04490.00040.0037

MASS FLOW (lb/hr)

1700.3431115.3383

0.91283.7578

MASS FRACTION

0.93410.06340.00050.0021

LIQUID VOLUMEFLOW (barrel/day)

146.31699.92180.09320.2578

LIQUID VOLUMEFRACTION

0.93440.06340.00060.0016

Total 55.7982 1.0000 1820.3521 1.0000 156.5898 1.0000

K VALUE

COMPONENTSMethanol

EthanoldiM-Ether

H2O

MIXED0.00000.00000.00000.0000

LIGHT0.00000.00000.00000.0000

HEAVY

UNIT OPERATIONS

FEED TOPump: P-101

PRODUCT FROMDistillation: T-101

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive) 3.755 psiaFlow Specification (Inactive) Molar: 55.80 lbmole/hr Mass: 1820 lb/hr Std Ideal Liq Volume:156.6 barrel/day

User Variables

NOTES

Description

Material Stream: 12Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Vapour / Phase FractionTemperature: (F)Pressure: (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)Liq Vol Flow @Std Cond (barrel/day)

Overall0.000093.58152.3 *

55.801820156.6

-1.033e+00517.57

-5.763e+006156.2 *

Liquid Phase1.000093.58152.355.801820156.6

-1.033e+00517.57

-5.763e+006156.2

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Page 24: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 12 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

PROPERTIES

Molecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

Overall32.621.49048.62160.0-3166

0.538528.17

0.86332.849e+005

8734

2.122e-3140.00000.0000

1.52328.17

0.507249.694.668

1.721e-00210.63

0.00001.0761.337

1.275e+0040.637149.83156.21.000

0.6710390.9

0.000027.97

0.10160.496226.18

0.802521.07

0.6457

4.570156.2

-1.766

Liquid Phase32.621.49048.62160.0-3166

0.538528.17

0.86332.849e+005

87341.0001.000

0.0000

1.52328.17

0.507249.694.668

1.721e-00210.63

1.0761.337

0.637149.83156.21.000

0.6710

1.000027.97

0.10160.496226.18

0.802521.07

0.6457

4.570156.2

-1.766

COMPOSITION

Overall Phase Vapour Fraction 0.0000

COMPONENTS

MethanolEthanoldiM-Ether

MOLAR FLOW (lbmole/hr)

53.06622.50360.0198

MOLE FRACTION

0.95100.04490.0004

MASS FLOW (lb/hr)

1700.3431115.3383

0.9128

MASS FRACTION

0.93410.06340.0005

LIQUID VOLUMEFLOW (barrel/day)

146.31699.92180.0932

LIQUID VOLUMEFRACTION

0.93440.06340.0006

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 12 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

COMPOSITION

Overall Phase (continued) Vapour Fraction 0.0000

COMPONENTS

H2O

MOLAR FLOW (lbmole/hr)

0.2086

MOLE FRACTION

0.0037

MASS FLOW (lb/hr)

3.7578

MASS FRACTION

0.0021

LIQUID VOLUMEFLOW (barrel/day)

0.2578

LIQUID VOLUMEFRACTION

0.0016Total 55.7982 1.0000 1820.3521 1.0000 156.5898 1.0000

Liquid Phase Phase Fraction 1.000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

53.06622.50360.01980.2086

MOLE FRACTION

0.95100.04490.00040.0037

MASS FLOW (lb/hr)

1700.3431115.3383

0.91283.7578

MASS FRACTION

0.93410.06340.00050.0021

LIQUID VOLUMEFLOW (barrel/day)

146.31699.92180.09320.2578

LIQUID VOLUMEFRACTION

0.93440.06340.00060.0016

Total 55.7982 1.0000 1820.3521 1.0000 156.5898 1.0000

K VALUE

COMPONENTSMethanol

EthanoldiM-Ether

H2O

MIXED0.00000.00000.00000.0000

LIGHT0.00000.00000.00000.0000

HEAVY

UNIT OPERATIONS

FEED TORecycle: RCY-1

PRODUCT FROMPump: P-101

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Active): 152.3 psia *

Flow Specification (Inactive) Molar: 55.80 lbmole/hr Mass: 1820 lb/hr Std Ideal Liq Volume:156.6 barrel/day

User Variables

NOTES

Description

Material Stream: 13Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Vapour / Phase FractionTemperature: (F)Pressure: (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)

Overall0.000093.60 *

152.3 *

55.84 *

1822156.7

-1.033e+00517.57

Liquid Phase1.000093.60152.355.841822156.7

-1.033e+00517.57

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 13 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Heat Flow (Btu/hr)Liq Vol Flow @Std Cond (barrel/day)

Overall-5.768e+006

156.3 *

Liquid Phase-5.768e+006

156.3

PROPERTIES

Molecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

Overall32.631.49048.62160.2-3166

0.538428.17

0.86332.851e+005

8736

2.122e-3140.00000.0000

1.52328.17

0.507649.694.672

1.721e-00210.63

0.00001.0761.337

1.276e+0040.637349.83156.31.000

0.6711390.9

0.000027.97

0.10160.496326.18

0.802421.08

0.6459

4.562156.3

-1.766

Liquid Phase32.631.49048.62160.2-3166

0.538428.17

0.86332.851e+005

87361.0001.000

0.0000

1.52328.17

0.507649.694.672

1.721e-00210.63

1.0761.337

0.637349.83156.31.000

0.6711

1.000027.97

0.10160.496326.18

0.802421.08

0.6459

4.562156.3

-1.766

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 26 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: 13 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

COMPOSITION

Overall Phase Vapour Fraction 0.0000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

53.0680 *

2.5380 *

0.0198 *

0.2153 *

MOLE FRACTION

0.9503 *

0.0455 *

0.0004 *

0.0039 *

MASS FLOW (lb/hr)

1700.4011 *

116.9262 *

0.9126 *

3.8788 *

MASS FRACTION

0.9332 *

0.0642 *

0.0005 *

0.0021 *

LIQUID VOLUMEFLOW (barrel/day)

146.3219 *

10.0584 *

0.0932 *

0.2661 *

LIQUID VOLUMEFRACTION

0.9335 *

0.0642 *

0.0006 *

0.0017 *

Total 55.8412 1.0000 1822.1187 1.0000 156.7396 1.0000

Liquid Phase Phase Fraction 1.000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

53.06802.53800.01980.2153

MOLE FRACTION

0.95030.04550.00040.0039

MASS FLOW (lb/hr)

1700.4011116.9262

0.91263.8788

MASS FRACTION

0.93320.06420.00050.0021

LIQUID VOLUMEFLOW (barrel/day)

146.321910.05840.09320.2661

LIQUID VOLUMEFRACTION

0.93350.06420.00060.0017

Total 55.8412 1.0000 1822.1187 1.0000 156.7396 1.0000

K VALUE

COMPONENTSMethanol

EthanoldiM-Ether

H2O

MIXED0.00000.00000.00000.0000

LIGHT0.00000.00000.00000.0000

HEAVY

UNIT OPERATIONS

FEED TOMixer: MIX-100

PRODUCT FROMRecycle: RCY-1

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive) 152.3 psia *

Flow Specification (Inactive) Molar: 55.84 lbmole/hr * Mass: 1822 lb/hr Std Ideal Liq Volume:156.7 barrel/day

User Variables

NOTES

Description

Material Stream: AGUAFluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Vapour / Phase FractionTemperature: (F)Pressure: (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)

Overall0.0000203.013.76206.03780

Aqueous Phase1.0000203.013.76206.03780

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 27 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: AGUA (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)Liq Vol Flow @Std Cond (barrel/day)

Overall261.4

-1.201e+0055.664

-2.475e+007256.0 *

Aqueous Phase261.4

-1.201e+0055.664

-2.475e+007256.0

PROPERTIES

Molecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

Overall18.353.22459.17273.1-6546

0.308618.31

0.99796405349.0

0.00000.00000.0000

3.36918.311.87261.837.965

6.000e-00410.76

0.00001.1221.182

1.759e+0040.316063.12256.01.000

0.3102958.6

0.000059.02

0.38700.299616.33

0.889715.49

0.8442

1.102256.0

-2.518

Aqueous Phase18.353.22459.17273.1-6546

0.308618.31

0.99796405349.01.0001.000

0.0000

3.36918.311.87261.837.965

6.000e-00410.76

1.1221.182

0.316063.12256.01.000

0.3102

1.000059.02

0.38700.299616.33

0.889715.49

0.8442

1.102256.0

-2.518

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 28 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: AGUA (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

COMPOSITION

Overall Phase Vapour Fraction 0.0000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

0.06152.45210.0000

203.4652

MOLE FRACTION

0.00030.01190.00000.9878

MASS FLOW (lb/hr)

1.9696112.9681

0.00003665.4467

MASS FRACTION

0.00050.02990.00000.9696

LIQUID VOLUMEFLOW (barrel/day)

0.16959.71790.0000

251.4900

LIQUID VOLUMEFRACTION

0.00060.03720.00000.9622

Total 205.9788 1.0000 3780.3844 1.0000 261.3774 1.0000

Aqueous Phase Phase Fraction 1.000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

0.06152.45210.0000

203.4652

MOLE FRACTION

0.00030.01190.00000.9878

MASS FLOW (lb/hr)

1.9696112.9681

0.00003665.4467

MASS FRACTION

0.00050.02990.00000.9696

LIQUID VOLUMEFLOW (barrel/day)

0.16959.71790.0000

251.4900

LIQUID VOLUMEFRACTION

0.00060.03720.00000.9622

Total 205.9788 1.0000 3780.3844 1.0000 261.3774 1.0000

K VALUE

COMPONENTSMethanol

EthanoldiM-Ether

H2O

MIXED0.00000.0000

0.0000

LIGHT HEAVY0.00000.0000

0.0000

UNIT OPERATIONS

FEED TO PRODUCT FROMDistillation: T-101

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive) 13.76 psiaFlow Specification (Inactive) Molar: 206.0 lbmole/hr Mass: 3780 lb/hr Std Ideal Liq Volume:261.4 barrel/day

User Variables

NOTES

Description

Material Stream: DMEFluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Vapour / Phase FractionTemperature: (F)Pressure: (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)

Overall0.0133106.2131.7956.0

4.403e+004

Vapour Phase0.0133106.2131.712.75587.2

Liquid Phase0.9867106.2131.7943.3

4.344e+004

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 29 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: DME (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)Liq Vol Flow @Std Cond (barrel/day)

Overall4497

-8.662e+00437.54

-8.281e+0074878 *

Vapour Phase59.98

-7.872e+00442.87

-1.003e+00665.07

Liquid Phase4437

-8.672e+00437.47

-8.181e+0074813

PROPERTIES

Molecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

Overall46.06

0.534124.607651

-18810.815127.86

0.60505.708e+0051.239e+0041.334e-0021.334e-002

0.00000.0000

0.908727.868.69041.85149.9

11.38

0.00001.0771.0078026

38.584878

0.98671.872174.3

0.01339.542

25.880.561927.66

0.6006

120.4120.74878

Vapour Phase46.07

2.169e-0020.9995

2511-1709

0.930716.27

0.35335.711e+0051.240e+0041.334e-0021.334e-002

0.00009.792

0.908316.27

0.115941.85

1.00011.38

1.1391.139

0.594438.5765.07

0.000046.09

0.0133

1.046e-0029.516e-003

14.290.310214.29

0.3102

120.665.07

Liquid Phase46.05

0.784536.135140

-18830.813528.02

0.60845.708e+0051.239e+004

0.98670.9867

0.0000

0.908728.028.57441.85149.9

2.765e-00211.38

1.0761.076

0.133038.5848131.0001.275

0.98679.542

7.093e-0027.696e-002

26.030.565326.03

0.5653

120.4120.74813

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 30 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: DME (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

COMPOSITION

Overall Phase Vapour Fraction 0.0133

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

0.93850.0100

955.07410.0075

MOLE FRACTION

0.00100.00000.99900.0000

MASS FLOW (lb/hr)

30.07220.4627

43999.31070.1346

MASS FRACTION

0.00070.00000.99930.0000

LIQUID VOLUMEFLOW (barrel/day)

2.58780.0398

4494.62670.0092

LIQUID VOLUMEFRACTION

0.00060.00000.99940.0000

Total 956.0302 1.0000 44029.9802 1.0000 4497.2635 1.0000

Vapour Phase Phase Fraction 1.333e-002

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

0.00040.0000

12.74520.0000

MOLE FRACTION

0.00000.00001.00000.0000

MASS FLOW (lb/hr)

0.01390.0001

587.15650.0000

MASS FRACTION

0.00000.00001.00000.0000

LIQUID VOLUMEFLOW (barrel/day)

0.00120.0000

59.97930.0000

LIQUID VOLUMEFRACTION

0.00000.00001.00000.0000

Total 12.7456 1.0000 587.1706 1.0000 59.9805 1.0000

Liquid Phase Phase Fraction 0.9867

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

0.93820.0100

942.32890.0075

MOLE FRACTION

0.00100.00000.99900.0000

MASS FLOW (lb/hr)

30.06160.4626

43412.14930.1346

MASS FRACTION

0.00070.00000.99930.0000

LIQUID VOLUMEFLOW (barrel/day)

2.58680.0398

4434.64690.0092

LIQUID VOLUMEFRACTION

0.00060.00000.99940.0000

Total 943.2846 1.0000 43442.8081 1.0000 4437.2828 1.0000

K VALUE

COMPONENTSMethanol

EthanoldiM-Ether

H2O

MIXED3.431e-0021.988e-002

1.0011.237e-002

LIGHT3.431e-0021.988e-002

1.0011.237e-002

HEAVY

UNIT OPERATIONS

FEED TO PRODUCT FROMValve: VLV-102

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive) 131.7 psiaFlow Specification (Inactive) Molar: 956.0 lbmole/hr Mass: 4.403e+004 lb/hr Std Ideal Liq Volume:4497 barrel/day

User Variables

NOTES

Description

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 31 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: P-RFluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Vapour / Phase FractionTemperature: (F)Pressure: (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)Liq Vol Flow @Std Cond (barrel/day)

Overall0.0000248.0152.31043

2.265e+0041753

-1.144e+00513.25

-1.193e+0081704 *

Vapour Phase0.0000248.0152.3

0.00000.00000.0000

-8.105e+00444.88

0.00000.0000

Aqueous Phase1.0000248.0152.31043

2.265e+0041753

-1.144e+00513.25

-1.193e+0081704

PROPERTIES

Molecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

Overall21.722.33550.731909

-52650.610023.711.091

7.476e+0043442

4.941e-3240.00000.0000

2.54323.719.47855.2455.67

11.25

0.00001.0911.180

1.637e+0040.196656.8217041.000

0.4282753.4

0.000046.98

0.30810.159821.72

0.999920.09

0.9248

Vapour Phase40.75

2.005e-0020.81730.0000-19891.10117.07

0.41904.623e+0051.134e+004

0.0000

0.0000

1.05917.07

0.000043.16

1.00011.37

1.1321.132

0.887140.98

0.00000.000049.87

0.0000

1.477e-0021.161e-002

15.090.370215.09

0.3702

Aqueous Phase21.722.33550.731909

-52650.610023.711.091

7.476e+00434421.0001.000

0.0000

2.54323.719.47855.2455.67

8.588e-00311.25

1.0911.180

0.196656.8217041.000

0.4282

1.000046.98

0.30810.159821.72

0.999920.09

0.9248

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 32 of 76

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Page 33: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: P-R (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

PROPERTIES

Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(psia)(psia)

(barrel/day)

Overall77.1422.601704

Vapour Phase113.194.98

0.0000

Aqueous Phase77.1422.601704

COMPOSITION

Overall Phase Vapour Fraction 0.0000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

52.52874.0962

107.4486878.5611

MOLE FRACTION

0.05040.00390.10310.8426

MASS FLOW (lb/hr)

1683.1186188.7114

4950.049115827.3669

MASS FRACTION

0.07430.00830.21860.6988

LIQUID VOLUMEFLOW (barrel/day)

144.834716.2336

505.65841085.9316

LIQUID VOLUMEFRACTION

0.08260.00930.28850.6196

Total 1042.6346 1.0000 22649.2460 1.0000 1752.6584 1.0000

Vapour Phase Phase Fraction 0.0000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

0.00000.00000.00000.0000

MOLE FRACTION

0.04440.00410.78430.1673

MASS FLOW (lb/hr)

0.00000.00000.00000.0000

MASS FRACTION

0.03490.00460.88660.0739

LIQUID VOLUMEFLOW (barrel/day)

0.00000.00000.00000.0000

LIQUID VOLUMEFRACTION

0.03030.00400.91440.0512

Total 0.0000 1.0000 0.0000 1.0000 0.0000 1.0000

Aqueous Phase Phase Fraction 1.000

COMPONENTS

MethanolEthanoldiM-EtherH2O

MOLAR FLOW (lbmole/hr)

52.52874.0962

107.4486878.5611

MOLE FRACTION

0.05040.00390.10310.8426

MASS FLOW (lb/hr)

1683.1186188.7114

4950.049115827.3669

MASS FRACTION

0.07430.00830.21860.6988

LIQUID VOLUMEFLOW (barrel/day)

144.834716.2336

505.65841085.9316

LIQUID VOLUMEFRACTION

0.08260.00930.28850.6196

Total 1042.6346 1.0000 22649.2460 1.0000 1752.6584 1.0000

K VALUE

COMPONENTSMethanol

EthanoldiM-Ether

H2O

MIXED0.88121.0387.610

0.1985

LIGHT HEAVY0.88121.0387.610

0.1985

UNIT OPERATIONS

FEED TO PRODUCT FROMEquilibrium Reactor: ERV-100

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive) 152.3 psiaFlow Specification (Inactive) Molar: 1043 lbmole/hr Mass: 2.265e+004 lb/hr Std Ideal Liq Volume:1753 barrel/day

User Variables

NOTESHyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 33 of 76

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Page 34: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Material Stream: P-R (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

NOTES

Description

Energy Stream: Q1Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Duty Type: Direct Q Duty Calculation Operation: E-100Duty SP: 9.883e+006 Btu/hr Minimum Available Duty: Maximum Available Duty:

COMPOSITION

( Not a material stream - No compositions exist )

UNIT OPERATIONS

FEED TOHeater: E-100

PRODUCT FROM LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive)Flow Specification (Inactive) Molar: Mass: Std Ideal Liq Volume:

User Variables

NOTES

Description

Energy Stream: Q2Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Duty Type: Direct Q Duty Calculation Operation: ERV-100Duty SP: 1.163e+007 Btu/hr Minimum Available Duty: Maximum Available Duty:

COMPOSITION

( Not a material stream - No compositions exist )

UNIT OPERATIONS

FEED TOEquilibrium Reactor: ERV-100

PRODUCT FROM LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive)

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 34 of 76

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Page 35: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Energy Stream: Q2 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

DYNAMICS

Flow Specification (Inactive) Molar: Mass: Std Ideal Liq Volume:

User Variables

NOTES

Description

Energy Stream: Q3Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Duty Type: Direct Q Duty Calculation Operation: E-101Duty SP: 5.013e+006 Btu/hr Minimum Available Duty: Maximum Available Duty:

COMPOSITION

( Not a material stream - No compositions exist )

UNIT OPERATIONS

FEED TO PRODUCT FROMCooler: E-101

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive)Flow Specification (Inactive) Molar: Mass: Std Ideal Liq Volume:

User Variables

NOTES

Description

Energy Stream: Q4Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Duty Type: Direct Q Duty Calculation Operation: Condenser @COL1Duty SP: 6.041e+007 Btu/hr Minimum Available Duty: Maximum Available Duty:

COMPOSITION

( Not a material stream - No compositions exist )

UNIT OPERATIONS

FEED TO PRODUCT FROMDistillation: T-100

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 35 of 76

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Page 36: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Energy Stream: Q4 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive)Flow Specification (Inactive) Molar: Mass: Std Ideal Liq Volume:

User Variables

NOTES

Description

Energy Stream: Q5Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Duty Type: Direct Q Duty Calculation Operation: Reboiler @COL1Duty SP: 5.166e+007 Btu/hr Minimum Available Duty: Maximum Available Duty:

COMPOSITION

( Not a material stream - No compositions exist )

UNIT OPERATIONS

FEED TODistillation: T-100

PRODUCT FROM LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive)Flow Specification (Inactive) Molar: Mass: Std Ideal Liq Volume:

User Variables

NOTES

Description

Energy Stream: Q6Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Duty Type: Direct Q Duty Calculation Operation: Condenser @COL2Duty SP: 3.402e+013 Btu/hr Minimum Available Duty: Maximum Available Duty:

COMPOSITION

( Not a material stream - No compositions exist )

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 36 of 76

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Page 37: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Energy Stream: Q6 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

UNIT OPERATIONS

FEED TO PRODUCT FROMDistillation: T-101

LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive)Flow Specification (Inactive) Molar: Mass: Std Ideal Liq Volume:

User Variables

NOTES

Description

Energy Stream: Q7Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Duty Type: Direct Q Duty Calculation Operation: Reboiler @COL2Duty SP: 3.402e+013 Btu/hr Minimum Available Duty: Maximum Available Duty:

COMPOSITION

( Not a material stream - No compositions exist )

UNIT OPERATIONS

FEED TODistillation: T-101

PRODUCT FROM LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive)Flow Specification (Inactive) Molar: Mass: Std Ideal Liq Volume:

User Variables

NOTES

Description

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 37 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Energy Stream: Q-100Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Duty Type: Direct Q Duty Calculation Operation: P-101Duty SP: 1372 Btu/hr Minimum Available Duty: Maximum Available Duty:

COMPOSITION

( Not a material stream - No compositions exist )

UNIT OPERATIONS

FEED TOPump: P-101

PRODUCT FROM LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive)Flow Specification (Inactive) Molar: Mass: Std Ideal Liq Volume:

User Variables

NOTES

Description

Energy Stream: W1Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

CONDITIONS

Duty Type: Direct Q Duty Calculation Operation: P-100Duty SP: 4.993e+004 Btu/hr Minimum Available Duty: Maximum Available Duty:

COMPOSITION

( Not a material stream - No compositions exist )

UNIT OPERATIONS

FEED TOPump: P-100

PRODUCT FROM LOGICAL CONNECTION

UTILITIES

( No utilities reference this stream )

PROCESS UTILITY

DYNAMICS

Pressure Specification (Inactive)Flow Specification (Inactive) Molar: Mass: Std Ideal Liq Volume:

User Variables

NOTES

Description

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 38 of 76

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Page 39: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Energy Stream: W1 (continued)Fluid Package: Basis-1

Property Package: UNIQUAC - Ideal

Recycle: RCY-1

CONNECTIONS

Inlet Stream

Stream Name From Unit Operation

12 P-101Pump

Outlet Stream

Stream Name To Unit Operation

13 MIX-100Mixer

TOLERANCE

Vapour Fraction: 10.00 * Temperature: 10.00 * Pressure: 10.00 *

Flow: 10.00 * Enthalpy: 10.00 * Composition: 10.00 *

NUMERICAL

Acceleration Type: Wegstein Iteration Type: NestedMaximum Iterations: 10 * Iteration Count: 0 *

Wegstein Count: 3 * Q Minimum: -20.00 * Q Maximum: 0.0000 *

Iteration History

Iteration0 *

VariableConverged

Outlet Value Inlet Value

User Variables

CONDITIONS

NameVapourTemperature (F)Pressure (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)

120.0000

93.5826152.2896 *

55.79821820.3521156.5898

-1.033e+00517.57

-5.7633e+06

130.0000

93.5961 *

152.2896 *

55.8412 *

1822.1187156.7396

-1.033e+00517.57

-5.7684e+06

PROPERTIES

NameMolecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. Density

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)

1232.621.49048.62160.0-3166

0.538528.17

0.86332.849e+005

8734

2.122e-3140.00000.0000

1.523

1332.631.49048.62160.2-3166

0.538428.17

0.86332.851e+005

8736

2.122e-3140.00000.0000

1.523

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 39 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Recycle: RCY-1 (continued)

PROPERTIES

NameSpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(Btu/lbmole-F)(MMSCFD)

(lb/ft3)(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

1228.17

0.507249.694.668

1.721e-00210.63

0.00001.0761.337

1.275e+0040.637149.83156.21.000

0.6710390.9

0.000027.97

0.10160.496226.18

0.802521.07

0.6457

4.570156.2

-1.766

1328.17

0.507649.694.672

1.721e-00210.63

0.00001.0761.337

1.276e+0040.637349.83156.31.000

0.6711390.9

0.000027.97

0.10160.496326.18

0.802421.08

0.6459

4.562156.3

-1.766

Heater: E-100

CONNECTIONS

Inlet Stream

STREAM NAME FROM UNIT OPERATION

3 MIX-100Mixer

Outlet Stream

STREAM NAME TO UNIT OPERATION

4 ERV-100Equilibrium Reactor

Energy Stream

STREAM NAME FROM UNIT OPERATION

Q1

PARAMETERS

Pressure Drop: 0.0000 psi * Duty: 9.883e+006 Btu/hr Volume: 3.531 ft3Function: Not Selected Zones: 1

User Variables

RATING

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Page 41: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Heater: E-100 (continued)

NOZZLE PARAMETERS

Base Elevation Relative to Ground Level 0.0000 ft *

Diameter (ft)Elevation (Base) (ft)Elevation (Ground) (ft)

30.16400.00000.0000

40.16400.00000.0000

CONDITIONS

NameVapourTemperature (F)Pressure (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)

30.0000

25.9755152.2896

2260.441272279.88766587.4213

-1.059e+005-78.13

-2.3947e+08

40.0406

192.2000 *

152.28962260.4412

72279.88766587.4213

-1.016e+00526.93

-2.2959e+08

Q1

9.8829e+06

PROPERTIES

NameMolecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

331.981.50147.996438

-3313-2.44322.71

0.71012.817e+005

8808

2.122e-3140.00000.0000

1.46722.7120.5546.90187.8

1.947e-00211.25

0.00001.0961.233

1.424e+0040.514246.7366121.000

0.6663445.2

0.000043.98

0.16480.395320.72

431.98

0.386112.35

2.502e+004-3176

0.842226.74

0.83622.817e+005

88086.243e-0025.631e-002

0.00000.0000

1.46726.7420.5546.90204.3

11.25

0.00001.0801.005

1.424e+004

46.736612

0.95942.590445.2

0.040630.60

24.75

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Page 42: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

20.00 40.00 60.00 80.00 100.0 120.0 140.0 160.0 180.0 200.0

Temperature (F)

147.0

148.0

149.0

150.0

151.0

152.0

153.0

154.0

155.0

156.0

157.0

Pre

ssur

e (p

sia)

Heater: E-100 (continued)

PROPERTIES

NameMass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

30.648018.42

0.5760393.912.32

5.765e-00275.0747.836612

-2.314

40.774126.60

0.8320

75.0747.836626

PERFORMANCE PROFILES

Zone

Inlet0

Pressure (psia)

152.29152.29

Temperature (F)

25.98192.20

Vapour Fraction

0.00000.0406

Enthalpy (Btu/lbmole)

-105940.60-101568.53

PERFORMANCE PLOT

PERFORMANCE TABLE

Overall Phase

Temperature (F)

25.98192.20

Pressure (psia)

152.29152.29

Heat Flow (Btu/hr)

0.009882901.31

Enthalpy (Btu/lbmole)

-105940.60-101568.53

Vapour Fraction

0.00000.0406

Vapour Phase

Mass Flow (lb/hr)

4069.77

Molecular Weight

44.34

Density (lb/ft3)

0.97

Mass Specific Heat (Btu/lb-F)

0.39

Viscosity (cP)

0.01

Thermal Conductivity (Btu/hr-ft-F)

0.01

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 42 of 76

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Page 43: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Heater: E-100 (continued)

PERFORMANCE TABLE

Light Liquid Phase

Mass Flow (lb/hr)

72279.8968210.12

Density (lb/ft3)

47.9941.63

Mass Specific Heat (Btu/lb-F)

0.710.86

Viscosity (cP)

0.14

Thermal Conductivity (Btu/hr-ft-F)

0.15

Surface Tension (dyne/cm)

43.9830.60

Heavy Liquid Phase

Mass Flow (lb/hr)

Density (lb/ft3)

Mass Specific Heat (Btu/lb-F)

Viscosity (cP)

Thermal Conductivity (Btu/hr-ft-F)

Surface Tension (dyne/cm)

DYNAMICS

Model Details: Supplied Duty

ZoneVolume (ft3)Duty (Btu/hr)

1 *

3.531 *

9.883e+006

Delta P (psi)Overall K (lb/hr/sqrt(psia-lb/ft3))

0.0000 *

8.341e-002 *

Holdup Details

Phase

VapourLiquid

Aqueous

Accumulation (lbmole/hr)

0.00000.00000.0000

Moles (lbmole)

0.00000.00000.0000

Volume (ft3)

0.00000.00000.0000

Total 0.0000 0.0000 0.0000

Individual Zone Holdups: Zone 0

Delta P Specs and Duties

Zone

0 *

dP Value (psi)

0.0000 *

dP Option

not specified

Duty (Btu/hr)

3.658e+006 *

Zone Conductance Specifications

Zone

0 *

k (lb/hr/sqrt(psia-lb/ft3))

8.341e-002

Specification

Disabled

NOTES

Cooler: E-101

CONNECTIONS

Inlet Stream

STREAM NAME FROM UNIT OPERATION

6 VLV-100Valve

Outlet Stream

STREAM NAME TO UNIT OPERATION

7 T-100Distillation

Energy Stream

STREAM NAME TO UNIT OPERATION

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 43 of 76

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Page 44: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Cooler: E-101 (continued)

CONNECTIONS

Q3

PARAMETERS

Pressure Drop: 0.0000 psi Duty: 5.013e+006 Btu/hr Volume: 3.531 ft3Function: Not Selected Zones: 1

User Variables

NOZZLE PARAMETERS

Base Elevation Relative to Ground Level 0.0000 ft *

Diameter (ft)Elevation (Base) (ft)Elevation (Ground) (ft)

60.16400.00000.0000

70.16400.00000.0000

CONDITIONS

NameVapourTemperature (F)Pressure (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)

61.0000

247.9137145.0377 *

1217.807249630.71684915.2307

-8.105e+00444.98

-9.8701e+07

70.7672

192.2000 *

145.0377 *

1217.807249630.71684915.2307

-8.516e+00439.62

-1.0371e+08

Q3

5.0133e+06

PROPERTIES

NameMolecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)

640.75

1.910e-0020.7784

2.725e+005-19891.10417.06

0.41864.623e+0051.134e+004

4.941e-3240.00000.0000

10631.05917.0611.0743.16

1.00011.37

0.00001.1321.132

1.166e+0040.929740.98

740.75

2.691e-0021.097

1.934e+005-2090

0.972219.13

0.46944.623e+0051.134e+004

0.85330.83540.00000.0000

1.05919.1311.0743.1623.28

11.37

0.00001.1161.087

1.166e+004

40.98

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 44 of 76

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Page 45: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

190.0 200.0 210.0 220.0 230.0 240.0 250.0

Temperature (F)

140.0

141.0

142.0

143.0

144.0

145.0

146.0

147.0

148.0

149.0

150.0

Pre

ssur

e (p

sia)

Cooler: E-101 (continued)

PROPERTIES

NameLiq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

65177

0.000052.35286.2

1.0000

1.474e-0021.159e-002

15.070.369815.07

0.3698

113.194.985177

75177

0.232837.16286.2

0.767237.52

17.140.420717.60

0.4318

113.194.985218

PERFORMANCE PROFILES

Zone

Inlet0

Pressure (psia)

145.04145.04

Temperature (F)

247.91192.20

Vapour Fraction

1.00000.7672

Enthalpy (Btu/lbmole)

-81047.22-85163.82

PERFORMANCE PLOT

PERFORMANCE TABLE

Overall Phase

Temperature (F)

247.91

Pressure (psia)

145.04

Heat Flow (Btu/hr)

0.00

Enthalpy (Btu/lbmole)

-81047.22

Vapour Fraction

1.0000

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Page 46: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Cooler: E-101 (continued)

PERFORMANCE TABLE

Overall Phase

Temperature (F)

192.20

Pressure (psia)

145.04

Heat Flow (Btu/hr)

-5013275.30

Enthalpy (Btu/lbmole)

-85163.82

Vapour Fraction

0.7672

Vapour Phase

Mass Flow (lb/hr)

49630.7241459.89

Molecular Weight

40.7544.37

Density (lb/ft3)

0.780.92

Mass Specific Heat (Btu/lb-F)

0.420.39

Viscosity (cP)

0.01

Thermal Conductivity (Btu/hr-ft-F)

0.01

Light Liquid Phase

Mass Flow (lb/hr)

Density (lb/ft3)

Mass Specific Heat (Btu/lb-F)

Viscosity (cP)

Thermal Conductivity (Btu/hr-ft-F)

Surface Tension (dyne/cm)

Heavy Liquid Phase

Mass Flow (lb/hr)

8170.83

Density (lb/ft3)

43.75

Mass Specific Heat (Btu/lb-F)

0.87

Viscosity (cP)

0.15

Thermal Conductivity (Btu/hr-ft-F)

0.20

Surface Tension (dyne/cm)

37.52

DYNAMICS

Model Details: Supplied Duty

ZoneVolume (ft3)Duty (Btu/hr)

1 *

3.531 *

5.013e+006

Delta P (psi)Overall K (lb/hr/sqrt(psia-lb/ft3))

0.00008.341e-002 *

Holdup Details

Phase

VapourLiquid

Aqueous

Accumulation (lbmole/hr)

0.00000.00000.0000

Moles (lbmole)

0.00000.00000.0000

Volume (ft3)

0.00000.00000.0000

Total 0.0000 0.0000 0.0000

Individual Zone Holdups: Zone 0

Delta P Specs and Duties

Zone

0 *

dP Value (psi)

0.0000 *

dP Option

not specified

Duty (Btu/hr)

-6.196e+006 *

Zone Conductance Specifications

Zone

0 *

k (lb/hr/sqrt(psia-lb/ft3))

8.341e-002

Specification

Disabled

NOTES

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Page 47: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Equilibrium Reactor: ERV-100

CONNECTIONS

Inlet Stream Connections

Stream Name From Unit Operation4 E-100Heater

Outlet Stream Connections

Stream Name To Unit Operation5 Valve: VLV-100

P-R

Energy Stream Connections

Stream Name From Unit OperationQ2

PARAMETERS

Physical Parameters Optional Heat Transfer: Heating

Delta P Vessel Volume Duty Energy Stream0.0000 psi 1.163e+007 Btu/hr Q2

User Variables

REACTION DETAILS

ComponentMethanoldiM-Ether

H2O

Molecular Weight32.0446.0718.02

Stoichiometric Coefficient-2 *

1 *

1 *

REACTION RESULTS FOR : Set-1

Extents

Rxn-2

Act. % Conv.77.93

Base Comp.Methanol

Eqm Constant66.55

Rxn Extent (lbmole/hr)188.2

Balance

MethanolEthanol

diM-EtherH2O

Total Inflow (lbmole/hr)

483.09.062874.4894.1

Total Rxn (lbmole/hr)

-376.4-1.721e-015

188.2188.2

Total Outflow (lbmole/hr)

106.69.06210631082

RATING

Sizing

Cylinder Vertical Reactor has a Boot: NoVolume Diameter Height

Nozzles

Base Elevation Relative to Ground Level 0.0000 ft * Diameter Height

Diameter (ft)Elevation (Base) (ft)Elevation (Ground) (ft)Elevation (% of Height) (%)

40.16400.00000.0000

50.16400.00000.0000

P-R0.16400.00000.0000

PROPERTIES

NameMolecular Weight

431.98

P-R21.72

540.75

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Page 48: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Equilibrium Reactor: ERV-100 (continued)

PROPERTIES

NameMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

40.386112.35

2.502e+004-3176

0.842226.74

0.83622.817e+005

88086.243e-0025.631e-002

0.00000.0000

1.46726.7420.5546.90204.3

11.25

0.00001.0801.005

1.424e+004

46.736612

0.95942.590445.2

0.040630.60

24.750.774126.60

0.8320

75.0747.836626

P-R2.33550.731909

-52650.610023.711.091

7.476e+0043442

4.941e-3240.00000.0000

2.54323.719.47855.2455.67

11.25

0.00001.0911.180

1.637e+0040.196656.8217041.000

0.4282753.4

0.000046.98

0.30810.159821.72

0.999920.09

0.9248

77.1422.601704

52.005e-002

0.81732.596e+005

-19891.10117.07

0.41904.623e+0051.134e+004

4.941e-3240.00000.0000

10121.05917.0711.0743.16

0.0000

11.37

0.00001.1321.132

1.161e+0040.887140.985177

0.000049.87284.9

1.0000

1.477e-0021.161e-002

15.090.370215.09

0.3702

113.194.985177

DYNAMICS

Vessel Parameters: Initialize from Product

Vessel Volume (ft3)Vessel Diameter (ft)Vessel Height (ft)Liquid Level Percent (%) 50.00

Level CalculatorFraction CalculatorFeed Delta P (psi)Vessel Pressure (psia)

Vertical cylinderUse levels and nozzles

0.0000152.3

Holdup: Vessel Levels

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Page 49: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Equilibrium Reactor: ERV-100 (continued)Phase

VapourLiquid

Aqueous

Level (ft)

Percent (%)

Volume (ft3)

0.00000.00000.0000

Holdup: Details

Phase

VapourLiquid

Aqueous

Accumulation (lbmole/hr)

0.00000.00000.0000

Moles (lbmole)

0.0000 *

0.0000 *

0.0000 *

Volume (ft3)

0.00000.00000.0000

Total 0.0000 0.0000 0.0000

Duty Valve Source : Direct_Q

SP (Btu/hr)

Min. Available (Btu/hr)

Max. Available (Btu/hr)

1.163e+007

Liquid Heater Height as % of Vessel Volume

Top of Heater : 5.00 % Bottom of Heater : 0.00 %

Heat Flow into the PFR: Heating

NOTES

Mixer: MIX-100

CONNECTIONS

Inlet Stream

STREAM NAME FROM UNIT OPERATION

132

RCY-1

P-100

Recycle

Pump

Outlet Stream

STREAM NAME TO UNIT OPERATION

3 E-100Heater

PARAMETERS

User Variables

NOZZLE PARAMETERS

Base Elevation Relative to Ground Level 0.0000 ft *

Diameter (ft)Elevation (Base) (ft)Elevation (Ground) (ft)

130.16400.00000.0000

20.16400.00000.0000

30.16400.00000.0000

CONDITIONS

NameVapourTemperature (F)Pressure (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)

130.0000

93.5961 *

152.2896 *

55.8412 *

1822.1187156.7396

20.0000

23.8698152.2896

2204.600070457.76896430.6817

30.0000

25.9755152.2896

2260.441272279.88766587.4213

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 49 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Mixer: MIX-100 (continued)

CONDITIONS

Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)

-1.033e+00517.57

-5.7684e+06

-1.060e+005-80.54

-2.3371e+08

-1.059e+005-78.13

-2.3947e+08

PROPERTIES

NameMolecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

1332.631.49048.62160.2-3166

0.538428.17

0.86332.851e+005

8736

2.122e-3140.00000.0000

1.52328.17

0.507649.694.672

1.721e-00210.63

0.00001.0761.337

1.276e+0040.637349.83156.31.000

0.6711390.9

0.000027.97

0.10160.496326.18

0.802421.08

0.6459

4.562156.3

-1.766

231.961.50247.996275

-3317-2.52022.56

0.70592.816e+005

8810

2.122e-3140.00000.0000

1.46522.5620.0446.83183.0

1.954e-00211.26

0.00001.0971.233

1.426e+0040.511746.6564561.000

0.6659446.3

0.000044.43

0.16640.393420.58

0.643818.30

0.5727384.712.04

5.864e-00278.4349.226456

-2.328

331.981.50147.996438

-3313-2.44322.71

0.71012.817e+005

8808

2.122e-3140.00000.0000

1.46722.7120.5546.90187.8

1.947e-00211.25

0.00001.0961.233

1.424e+0040.514246.7366121.000

0.6663445.2

0.000043.98

0.16480.395320.72

0.648018.42

0.5760393.912.32

5.765e-00275.0747.836612

-2.314

DYNAMICS

Pressure Specification: Set Outlet to Lowest Inlet

Holdup DetailsHyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 50 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Mixer: MIX-100 (continued)Holdup Details

Phase

VapourLiquid

Aqueous

Accumulation (lbmole/hr)

0.00000.00000.0000

Moles (lbmole)

0.0000 *

0.0000 *

0.0000 *

Volume (ft3)

0.00000.00000.0000

Total 0.0000 0.0000 0.0000

NOTES

Pump: P-100

CONNECTIONS

Inlet Stream

Stream Name From Unit Operation

1

Outlet Stream

Stream Name To Unit Operation

2 MIX-100Mixer

Energy Stream

Stream Name From Unit Operation

W1

PARAMETERS

Adiabatic Efficiency (%): 75.00 Delta P: 137.8 psi * Duty: 19.62 hp

CURVES

Delta P: 137.8 psi * Duty: 19.62 hpCoefficient A: 0.0000 * Coefficient B: 0.0000 * Coefficient C: 0.0000 *

Parameter Preferences Units for Delta P: m Flow Basis ActVolFlow Units for Flow: m3/h

User Variables

RATING

Characteristic Curves

Speed: Flow Head Efficiency (%)

NPSH

NPSH Required NPSH Available Enable NPSH Curves: NoNPSH Curves

Nozzle Paramaters

Base Elevation Relative to Ground Level 0.0000 ft *

Diameter (ft)Elevation (Base) (ft)Elevation (Ground) (ft)

10.16400.00000.0000

20.16400.00000.0000

Inertia

Rotational inertia (lb-ft2) 11.87 Radius of gyration (ft) 0.3281 Mass (lb) 110.2 Friction loss factor (lb-ft2/s) 1.187

Start Up

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 51 of 76

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Page 52: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Pump: P-100 (continued)Design Flow Typical Operating Capacity 1510 barrel/day

CONDITIONS

NameVapourTemperature (F)Pressure (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)

10.0000

23.0000 *

14.5038 *

2204.6000 *

70457.76896430.6817

-1.060e+005-83.37

-2.3376e+08

20.0000

23.8698152.2896

2204.600070457.76896430.6817

-1.060e+005-80.54

-2.3371e+08

W1

4.9931e+04

PROPERTIES

NameMolecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

131.961.50147.976278

-3318-2.60922.55

0.70562.816e+005

8810

2.122e-3140.00000.0000

1.46522.5520.0446.83183.1

1.865e-00311.26

0.00001.0971.235

1.646e+0040.515146.6564561.000

0.6662515.1

0.000044.50

0.16640.395820.56

0.643518.26

0.57153601112.7

6.262e-003

231.961.50247.996275

-3317-2.52022.56

0.70592.816e+005

8810

2.122e-3140.00000.0000

1.46522.5620.0446.83183.0

1.954e-00211.26

0.00001.0971.233

1.426e+0040.511746.6564561.000

0.6659446.3

0.000044.43

0.16640.393420.58

0.643818.30

0.5727384.712.04

5.864e-002

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 52 of 76

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Page 53: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Pump: P-100 (continued)

PROPERTIES

NameReid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(psia)(psia)

(barrel/day)

178.4349.226456

-2.312

278.4349.226456

-2.328

PERFORMANCE

Results

Total HeadTotal Fluid HeadPressure Head 413.6 ft *

Velocity Head -4.865e-003 ft *

Delta P excluding Static Head Results

DYNAMICS

Dynamic Specifications

Head (ft)Fluid Head (lbf-ft/lbm)Adiabatic Efficiency (rpm)Polytropic Efficiency (%)Pressure Increase (psi)

75.00137.8 *

Not ActiveNot ActiveNot Active

ActiveActive

Power (Btu/hr)

Capacity (barrel/day)

Use Characteristic Curves

Pump is Acting as a Turbine

4.993e+004

6431

Not Active

Not Active

Not Active

Holdup Details

Phase

VapourLiquid

Aqueous

Accumulation (lbmole/hr)

0.00000.00000.0000

Moles (lbmole)

0.0000 *

0.0000 *

0.0000 *

Volume (ft3)

0.00000.00000.0000

Total 0.0000 0.0000 0.0000

NOTES

Pump: P-101

CONNECTIONS

Inlet Stream

Stream Name From Unit Operation

11 T-101Distillation

Outlet Stream

Stream Name To Unit Operation

12 RCY-1Recycle

Energy Stream

Stream Name From Unit Operation

Q-100

PARAMETERS

Adiabatic Efficiency (%): 75.00 Delta P: 148.5 psi Duty: 0.5393 hp

CURVES

Delta P: 148.5 psi Duty: 0.5393 hpCoefficient A: 0.0000 * Coefficient B: 0.0000 * Coefficient C: 0.0000 *

Parameter Preferences Units for Delta P: m Flow Basis ActVolFlow Units for Flow: m3/h

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 53 of 76

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Page 54: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Pump: P-101 (continued)

User Variables

RATING

Characteristic Curves

Speed: Flow Head Efficiency (%)

NPSH

NPSH Required NPSH Available Enable NPSH Curves: NoNPSH Curves

Nozzle Paramaters

Base Elevation Relative to Ground Level 0.0000 ft *

Diameter (ft)Elevation (Base) (ft)Elevation (Ground) (ft)

110.16400.00000.0000

120.16400.00000.0000

Inertia

Rotational inertia (lb-ft2) 11.87 Radius of gyration (ft) 0.3281 Mass (lb) 110.2 Friction loss factor (lb-ft2/s) 1.187

Start Up

Design Flow Typical Operating Capacity 1510 barrel/day

CONDITIONS

NameVapourTemperature (F)Pressure (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)

110.0000

92.71013.7550

55.79821820.3521156.5898

-1.033e+00510.15

-5.7647e+06

120.0000

93.5826152.2896 *

55.79821820.3521156.5898

-1.033e+00517.57

-5.7633e+06

Q-100

1.3723e+03

PROPERTIES

NameMolecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass Density

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

1132.621.49048.61160.1-3167

0.311228.15

0.86302.849e+005

8734

2.122e-3140.00000.0000

1.52328.15

0.507249.69

1232.621.49048.62160.0-3166

0.538528.17

0.86332.849e+005

8734

2.122e-3140.00000.0000

1.52328.17

0.507249.69

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Page 55: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Pump: P-101 (continued)

PROPERTIES

NameAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

114.669

4.251e-00410.63

0.00001.0761.339

1.624e+0040.641149.83156.21.000

0.6711497.9

0.000028.05

0.10170.499226.17

0.802121.02

0.6444

4.570156.2

-1.755

124.668

1.721e-00210.63

0.00001.0761.337

1.275e+0040.637149.83156.21.000

0.6710390.9

0.000027.97

0.10160.496226.18

0.802521.07

0.6457

4.570156.2

-1.766

PERFORMANCE

Results

Total HeadTotal Fluid HeadPressure Head 440.0 ft *

Velocity Head -1.155e-006 ft *

Delta P excluding Static Head Results

DYNAMICS

Dynamic Specifications

Head (ft)Fluid Head (lbf-ft/lbm)Adiabatic Efficiency (rpm)Polytropic Efficiency (%)Pressure Increase (psi)

75.00148.5

Not ActiveNot ActiveNot Active

ActiveActive

Power (Btu/hr)

Capacity (barrel/day)

Use Characteristic Curves

Pump is Acting as a Turbine

1372

156.6

Not Active

Not Active

Not Active

Holdup Details

Phase

VapourLiquid

Aqueous

Accumulation (lbmole/hr)

0.00000.00000.0000

Moles (lbmole)

0.0000 *

0.0000 *

0.0000 *

Volume (ft3)

0.00000.00000.0000

Total 0.0000 0.0000 0.0000

NOTES

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 55 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Distillation: T-100

CONNECTIONS

Inlet Stream

STREAM NAME Stage FROM UNIT OPERATION

7Q5

4__Main TSReboiler

E-101Cooler

Outlet Stream

STREAM NAME Stage TO UNIT OPERATION

Q489

CondenserCondenserReboiler

VLV-102VLV-101

ValveValve

MONITOR

Specifications SummarySpecified Value Current Value Wt. Error Wt. Tol. Abs. Tol. Active Estimate Used

Distillate Rate 956.0 lbmole/hr 1.000e-002 2.205 lbmole/hr Off On OffReflux Rate 6614 lbmole/hr 1.000e-002 2.205 lbmole/hr Off On OffBtms Prod Rate 261.8 lbmole/hr 1.000e-002 2.205 lbmole/hr Off On OffComp Fraction 1.000e-003 * 1.000e-003 3.893e-006 1.000e-002 1.000e-003 On On OnComp Fraction - 2 1.000e-003 * 1.000e-003 2.353e-005 1.000e-002 1.000e-003 On On On

SPECS

Column Specification Parameters

Distillate Rate

Fixed / Ranged: Fixed Primary / Alternate: Primary Lower Bound: Upper Bound:Stream: 8 @COL1 Flow Basis: Molar

Reflux Rate

Fixed / Ranged: Fixed Primary / Alternate: Primary Lower Bound: Upper Bound:Stage: Condenser Flow Basis: Molar Liquid Specification: ---

Btms Prod Rate

Fixed / Ranged: Fixed Primary / Alternate: Primary Lower Bound: Upper Bound:Stream: 9 @COL1 Flow Basis: Molar

Comp Fraction

Fixed / Ranged: Fixed Primary / Alternate: Primary Lower Bound: Upper Bound:Stage: Condenser Flow Basis: Mole Fraction Phase: LiquidComponents: Methanol Ethanol H2O

Comp Fraction - 2

Fixed / Ranged: Fixed Primary / Alternate: Primary Lower Bound: Upper Bound:Stage: Reboiler Flow Basis: Mole Fraction Phase: VapourComponents: diM-Ether

SUBCOOLING

Degrees of SubcoolingSubcool to

Condenser

User Variables

PROFILES

General ParametersSub-Flow Sheet: T-100 (COL1) Number of Stages: 7 *

Profile Estimates

Condenser

Temperature (F)

110.0

Net Liquid (lbmole/hr)

6614

Net Vapour (lbmole/hr)

1.279e-018

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Page 57: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Distillation: T-100 (continued)Profile Estimates

1__Main TS2__Main TS3__Main TS4__Main TS5__Main TS6__Main TS7__Main TS

Reboiler

Temperature (F)

111.8139.9216.6258.8282.3291.8302.0320.5

Net Liquid (lbmole/hr)

6086451138924206411240143833261.8

Net Vapour (lbmole/hr)

75707042546748483944385037523571

EFFICIENCIES

Stage EfficienciesStages

Condenser1__Main TS2__Main TS3__Main TS4__Main TS5__Main TS6__Main TS7__Main TSReboiler

Overall Efficiency1.0001.0001.0001.0001.0001.0001.0001.0001.000

Methanol1.0001.0001.0001.0001.0001.0001.0001.0001.000

Ethanol1.0001.0001.0001.0001.0001.0001.0001.0001.000

diM-Ether1.0001.0001.0001.0001.0001.0001.0001.0001.000

H2O1.0001.0001.0001.0001.0001.0001.0001.0001.000

SOLVER

Column Solving Algorithm: HYSIM Inside-OutSolving Options

Maximum Iterations: 10000Equilibrium Error Tolerance: 1.000e-05Heat/Spec Error Tolerance: 5.000e-004Save Solutions as Initial Estimate: OnSuper Critical Handling Model: Simple KTrace Level: LowInit from Ideal K's: Off

Initial Estimate Generator ParametersIterative IEG (Good for Chemicals): Off

Acceleration ParametersAccelerate K Value & H Model Parameters: Off

Damping ParametersAzeotrope Check: OffFixed Damping Factor: 1

SIDE STRIPPERS

SIDE RECTIFIERS

PUMP AROUNDS

VAP BYPASSES

RATING

Tray Sections

Tray SectionTray Diameter (ft)Weir Height (ft)Weir Length (ft)Tray Space (ft)Tray Volume (ft3)Disable Heat Loss CalculationsHeat ModelRating Calculations

Main TS @COL14.9210.1640 *

3.937 *

1.804 *

34.32No

NoneNo

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Distillation: T-100 (continued)Tray Hold Up (ft3) 3.120

Vessels

VesselDiameter (ft)Length (ft)Volume (ft3)OrientationVessel has a BootBoot Diameter (ft)Boot Length (ft)Hold Up (ft3)

Reboiler @COL13.9145.87170.63 *

HorizontalNo

35.31

Condenser @COL13.9145.87170.63 *

HorizontalNo

35.31

Other Equipment In Column Flowsheet

Pressure Profile

Pressure (psia) Pressure Drop (psi)Condenser1__Main TS2__Main TS3__Main TS4__Main TS5__Main TS6__Main TS7__Main TS

Reboiler

139.0 psia *

139.0 psia142.3 psia145.7 psia149.0 psia152.3 psia155.7 psia159.0 psia159.0 psia *

0.0000 psi3.333 psi3.333 psi3.333 psi3.333 psi3.333 psi3.333 psi

0.0000 psi

Pressure Solving Options

Pressure Tolerance 1.000e-004 Pressure Drop Tolerance 1.000e-004 Damping Factor 1.000 Max Press Iterations 100

CONDITIONS

NameVapourTemperature (F)Pressure (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)

70.7672

192.2000 *

145.0377 *

1217.807249630.71684915.2307

-8.516e+00439.62

-1.0371e+08

80.0000

110.0070139.0000956.0302

44029.98024497.2635

-8.662e+00437.85

-8.2809e+07

90.0000

320.5048159.0000261.7770

5600.7367417.9672

-1.133e+00515.54

-2.9664e+07

Q5

5.1655e+07

Q4

6.0414e+07

PROPERTIES

NameMolecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas Flow

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

740.75

2.691e-0021.097

1.934e+005-2090

0.972219.13

0.46944.623e+0051.134e+004

0.85330.83540.00000.0000

846.06

0.779935.925240

-18810.821928.21

0.61265.708e+0051.239e+004

2.122e-3140.00000.0000

921.402.33249.89479.9-5296

0.726222.691.061

6.577e+0043074

0.00000.00000.0000

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Distillation: T-100 (continued)

PROPERTIES

NameAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

71.05919.1311.0743.1623.28

11.37

0.00001.1161.087

1.166e+004

40.985177

0.232837.16286.2

0.767237.52

17.140.420717.60

0.4318

113.194.985218

80.908728.218.69041.85152.8

2.915e-00211.38

0.00001.0761.0767981

0.131238.5848781.0001.282173.3

0.00009.257

7.011e-0027.548e-002

26.230.569526.23

0.5695

120.4120.74878

92.67722.692.38057.2814.00

8.144e-00310.64

0.00001.0961.213

1.539e+0040.168258.35410.31.000

0.4288719.1

0.000038.26

0.28990.134420.70

0.967718.70

0.8741

4.4812.329410.3

SUMMARY

Flow Basis: Molar The composition option is selectedFeed Composition

Flow Rate (kgmole/h)

MethanolEthanol

diM-EtherH2O

71.217807e+03

0.04440.00410.78430.1673

Flow Basis: Molar The composition option is selectedFeed Flows

Flow Rate (kgmole/h)

Methanol (kgmole/h)Ethanol (kgmole/h)

diM-Ether (kgmole/h)H2O (kgmole/h)

71.217807e+03

54.06624.9657

955.0940203.6813

ProductsFlow Basis: Molar The composition option is selected

Product Compositions

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Distillation: T-100 (continued)

SUMMARY

Flow Rate (kgmole/h)

MethanolEthanol

diM-EtherH2O

8956.0302

0.00100.00000.99900.0000

9261.7770

0.20300.01890.00010.7780

Flow Basis: Molar The composition option is selectedProduct Flows

Flow Rate (kgmole/h)

Methanol (kgmole/h)Ethanol (kgmole/h)

diM-Ether (kgmole/h)H2O (kgmole/h)

8956.0302 *

0.9385 *

0.0100 *

955.0741 *

0.0075 *

9261.7770 *

53.1277 *

4.9557 *

0.0198 *

203.6738 *

Flow Basis: Molar The composition option is selectedProduct Recoveries

Flow Rate (kgmole/h)

Methanol (%)Ethanol (%)

diM-Ether (%)H2O (%)

8956.0302

1.73590.202399.99790.0037

9261.7770

98.264199.79770.002199.9963

COLUMN PROFILES

Reflux Ratio: 6.918 Reboil Ratio: 13.64 The Flows Option is Selected Flow Basis: MolarColumn Profiles Flows

Condenser1__Main TS2__Main TS3__Main TS4__Main TS5__Main TS6__Main TS7__Main TS

Reboiler

Temperature (F)110.0111.8139.9216.6258.8282.3291.8302.0320.5

Pressure (psia)139.0139.0142.3145.7149.0152.3155.7159.0159.0

Net Liq (lbmole/hr)66146086451138924206411240143833

Net Vap (lbmole/hr)

75707042546748483944385037523571

Net Feed (lbmole/hr)

1218

Net Draws (lbmole/hr)956.0

261.8Column Profiles Energy

Condenser1__Main TS2__Main TS3__Main TS4__Main TS5__Main TS6__Main TS7__Main TS

Reboiler

Temperature (F)110.0111.8139.9216.6258.8282.3291.8302.0320.5

Liquid Enthalpy (Btu/lbmole)-8.662e+004-8.699e+004-9.113e+004-9.695e+004-9.976e+004-1.017e+005-1.039e+005-1.077e+005-1.133e+005

Vapour Enthalpy (Btu/lbmole)-7.866e+004-7.864e+004-7.836e+004-7.929e+004-8.245e+004-8.576e+004-8.753e+004-8.945e+004-9.279e+004

Heat Loss (Btu/hr)

FEEDS / PRODUCTS

Flow Basis: Molar Stream Type Duty (kJ/h) State Flows (kgmole/h) Enthalpy (kJ/kgmole Temp (C)

CondenserQ48

EnergyDraw

6.041e+007 *

Liquid 956.0 * -8.662e+004 * 110.0 *

1__Main TS2__Main TS

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Distillation: T-100 (continued)

FEEDS / PRODUCTS

3__Main TS4__Main TS 7 Feed Mixed 1218 * -8.516e+004 * 192.2 *

5__Main TS6__Main TS7__Main TS

ReboilerQ59

EnergyDraw

5.166e+007 *

Liquid 261.8 * -1.133e+005 * 320.5 *

SETUP

Sub-FlowsheetFeed Streams

Internal Stream7

Q5

External Stream7

Q5

Transfer BasisP-H Flash

None Req'd

Product StreamsInternal Stream

Q489

External StreamQ489

Transfer BasisNone Req'dP-H FlashP-H Flash

VARIABLES

Column Flowsheet Vars Available as ParametersData Source Variable Component Description

COMPONENT MAPS

Feed StreamsFeed Name

7Q5

In to SubFlowSheet Out of SubFlowSheet

Product StreamProduct Name

Q489

In to SubFlowSheet Out of SubFlowSheet

DYNAMICS

Vessel Dynamic Specifications

VesselDiameter (ft)Height.0 (ft)Volume.0 (ft3)Liquid Volume Percent (%)Level CalculatorFraction CalculatorVessel Delta P (psi)Fixed Vessel P Spec (psia)Fixed P Spec Active

Reboiler @COL13.9145.87170.63 *

50.00Horizontal cylinder

Use levels and nozzles0.0000159.0

Not Active

Condenser @COL13.9145.87170.63 *

50.00Horizontal cylinder

Use levels and nozzles0.0000139.0

Not Active

Other Equipment in Column Flowsheet

Holdup Details

Condenser1__Main TS2__Main TS3__Main TS4__Main TS

Pressure (psia)

0.00000.00000.00000.00000.0000

Volume (ft3)

0.0000 *

0.0000 *

0.0000 *

0.0000 *

0.0000 *

Bulk Liquid Volume (ft3)

0.00000.00000.00000.00000.0000

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Distillation: T-100 (continued)

5__Main TS6__Main TS7__Main TSReboiler

Pressure (psia)

0.00000.00000.00000.0000

Volume (ft3)

0.0000 *

0.0000 *

0.0000 *

0.0000 *

Bulk Liquid Volume (ft3)

0.00000.00000.00000.0000

NOTES

Distillation: T-101

CONNECTIONS

Inlet Stream

STREAM NAME Stage FROM UNIT OPERATION

Q710

Reboiler10__Main TS VLV-101Valve

Outlet Stream

STREAM NAME Stage TO UNIT OPERATION

Q6AGUA11

CondenserReboilerCondenser P-101Pump

MONITOR

Specifications SummarySpecified Value Current Value Wt. Error Wt. Tol. Abs. Tol. Active Estimate Used

Reflux Ratio 3.753e+007 1.000e-002 1.000e-002 Off On OffReflux Rate 2.094e+009 lbmole/hr 1.000e-002 2.205 lbmole/hr Off On OffComp Fraction 1.000e-003 * 3.738e-003 0.4221 1.000e-002 1.000e-003 Off On OffComp Fraction - 2 1.000e-003 * 1.220e-002 0.8845 1.000e-002 1.000e-003 Off On OffComp Recovery - 2 0.0010 * 0.0010 -1.613e-003 1.000e-002 1.000e-003 On On On

SPECS

Column Specification Parameters

Reflux Ratio

Fixed / Ranged: Fixed Primary / Alternate: Primary Lower Bound: Upper Bound:Stage: Condenser Flow Basis: Molar Liquid Specification: ---

Reflux Rate

Fixed / Ranged: Fixed Primary / Alternate: Primary Lower Bound: Upper Bound:Stage: Condenser Flow Basis: Molar Liquid Specification: ---

Comp Fraction

Fixed / Ranged: Fixed Primary / Alternate: Primary Lower Bound: Upper Bound:Stage: Condenser Flow Basis: Mole Fraction Phase: LiquidComponents: H2O

Comp Fraction - 2

Fixed / Ranged: Fixed Primary / Alternate: Primary Lower Bound: Upper Bound:Stage: Reboiler Flow Basis: Mole Fraction Phase: LiquidComponents: Methanol Ethanol diM-Ether

Comp Recovery - 2

Fixed / Ranged: Fixed Primary / Alternate: Primary Lower Bound: Upper Bound:Draw: 11 @COL2 Flow Basis: Molar

Components: H2O

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Distillation: T-101 (continued)Column Specification Parameters

Fixed / Ranged: Primary / Alternate: Lower Bound: Upper Bound:Draw: Flow Basis:

Components:

SUBCOOLING

Degrees of SubcoolingSubcool to

Condenser

User Variables

PROFILES

General ParametersSub-Flow Sheet: T-101 (COL2) Number of Stages: 15 *

Profile Estimates

Condenser1__Main TS2__Main TS3__Main TS4__Main TS5__Main TS6__Main TS7__Main TS8__Main TS9__Main TS

10__Main TS11__Main TS12__Main TS13__Main TS14__Main TS15__Main TS

Reboiler

Temperature (F)

92.7193.96102.6111.9121.1129.5136.6142.5147.5151.7155.5158.9162.2165.7170.4182.8203.0

Net Liquid (lbmole/hr)

2.094e+0092.071e+0092.063e+0092.045e+0092.025e+0092.009e+0091.998e+0091.992e+0091.989e+0091.989e+0091.989e+0091.989e+0091.987e+0091.979e+0091.950e+0091.912e+009

206.0

Net Vapour (lbmole/hr)

6.835e-0062.094e+0092.071e+0092.063e+0092.045e+0092.025e+0092.009e+0091.998e+0091.992e+0091.989e+0091.989e+0091.989e+0091.989e+0091.987e+0091.979e+0091.950e+0091.912e+009

EFFICIENCIES

Stage EfficienciesStages

Condenser1__Main TS2__Main TS3__Main TS4__Main TS5__Main TS6__Main TS7__Main TS8__Main TS9__Main TS10__Main TS11__Main TS12__Main TS13__Main TS14__Main TS15__Main TSReboiler

Overall Efficiency1.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.000

Methanol1.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.000

Ethanol1.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.000

diM-Ether1.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.000

H2O1.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.0001.000

SOLVER

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Distillation: T-101 (continued)Column Solving Algorithm: HYSIM Inside-Out

Solving OptionsMaximum Iterations: 10000Equilibrium Error Tolerance: 1.000e-05Heat/Spec Error Tolerance: 5.000e-004Save Solutions as Initial Estimate: OnSuper Critical Handling Model: Simple KTrace Level: LowInit from Ideal K's: Off

Initial Estimate Generator ParametersIterative IEG (Good for Chemicals): Off

Acceleration ParametersAccelerate K Value & H Model Parameters: Off

Damping ParametersAzeotrope Check: OffFixed Damping Factor: 1

SIDE STRIPPERS

SIDE RECTIFIERS

PUMP AROUNDS

VAP BYPASSES

RATING

Tray Sections

Tray SectionTray Diameter (ft)Weir Height (ft)Weir Length (ft)Tray Space (ft)Tray Volume (ft3)Disable Heat Loss CalculationsHeat ModelRating CalculationsTray Hold Up (ft3)

Main TS @COL24.9210.1640 *

3.937 *

1.804 *

34.32No

NoneNo

3.120

Vessels

VesselDiameter (ft)Length (ft)Volume (ft3)OrientationVessel has a BootBoot Diameter (ft)Boot Length (ft)Hold Up (ft3)

Reboiler @COL23.9145.87170.63 *

HorizontalNo

35.31

Condenser @COL23.9145.87170.63 *

HorizontalNo

35.31

Other Equipment In Column Flowsheet

Pressure Profile

Pressure (psia) Pressure Drop (psi)Condenser1__Main TS2__Main TS3__Main TS4__Main TS5__Main TS6__Main TS7__Main TS

3.755 psia *

3.755 psia4.469 psia5.184 psia5.898 psia6.612 psia7.327 psia8.041 psia

0.0000 psi0.7143 psi0.7143 psi0.7143 psi0.7143 psi0.7143 psi0.7143 psi0.7143 psi

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Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Distillation: T-101 (continued)8__Main TS9__Main TS10__Main TS11__Main TS12__Main TS13__Main TS14__Main TS15__Main TS

Reboiler

8.755 psia9.470 psia10.18 psia10.90 psia11.61 psia12.33 psia13.04 psia13.76 psia13.76 psia *

0.7143 psi0.7143 psi0.7143 psi0.7143 psi0.7143 psi0.7143 psi0.7143 psi

0.0000 psi

Pressure Solving Options

Pressure Tolerance 1.000e-004 Pressure Drop Tolerance 1.000e-004 Damping Factor 1.000 Max Press Iterations 100

CONDITIONS

NameVapourTemperature (F)Pressure (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)

100.2755

93.08521.4504 *

261.77705600.7367417.9672

-1.133e+00514.39

-2.9664e+07

110.0000

92.71013.7550

55.79821820.3521156.5898

-1.033e+00510.15

-5.7647e+06

AGUA0.0000

202.963613.7554

205.97883780.3844261.3774

-1.201e+0055.664

-2.4745e+07

Q7

3.4021e+13

Q6

3.4017e+13

PROPERTIES

NameMolecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

1021.40

8.875e-0041.899e-0021.261e+006

-52960.672416.65

0.77806.577e+004

30740.35950.33430.00000.0000

2.67716.652.38057.287.783

10.64

0.00001.1351.034

1.854e+004

58.35410.3

0.72451127866.8

1132.621.49048.61160.1-3167

0.311228.15

0.86302.849e+005

8734

2.122e-3140.00000.0000

1.52328.15

0.507249.694.669

4.251e-00410.63

0.00001.0761.339

1.624e+0040.641149.83156.21.000

0.6711497.9

AGUA18.353.22459.17273.1-6546

0.308618.31

0.99796405349.0

0.00000.00000.0000

3.36918.311.87261.837.965

6.000e-00410.76

0.00001.1221.182

1.759e+0040.316063.12256.01.000

0.3102958.6

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Distillation: T-101 (continued)

PROPERTIES

NamePhase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

100.275565.90

14.660.685216.10

0.7524

4.4812.329411.0

110.000028.05

0.10170.499226.17

0.802121.02

0.6444

4.570156.2

-1.755

AGUA0.000059.02

0.38700.299616.33

0.889715.49

0.8442

1.102256.0

-2.518

SUMMARY

Flow Basis: Molar The composition option is selectedFeed Composition

Flow Rate (kgmole/h)

MethanolEthanol

diM-EtherH2O

10261.7770

0.20300.01890.00010.7780

Flow Basis: Molar The composition option is selectedFeed Flows

Flow Rate (kgmole/h)

Methanol (kgmole/h)Ethanol (kgmole/h)

diM-Ether (kgmole/h)H2O (kgmole/h)

10261.7770

53.12774.95570.0198

203.6738Products

Flow Basis: Molar The composition option is selectedProduct Compositions

Flow Rate (kgmole/h)

MethanolEthanol

diM-EtherH2O

1155.7982

0.95100.04490.00040.0037

AGUA205.9788

0.00030.01190.00000.9878

Flow Basis: Molar The composition option is selectedProduct Flows

Flow Rate (kgmole/h)

Methanol (kgmole/h)Ethanol (kgmole/h)

diM-Ether (kgmole/h)H2O (kgmole/h)

1155.7982 *

53.0662 *

2.5036 *

0.0198 *

0.2086 *

AGUA205.9788 *

0.0615 *

2.4521 *

0.0000 *

203.4652 *

Flow Basis: Molar The composition option is selectedProduct Recoveries

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 66 of 76

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Distillation: T-101 (continued)

SUMMARY

Flow Rate (kgmole/h)

Methanol (%)Ethanol (%)

diM-Ether (%)H2O (%)

1155.7982

99.884350.519199.99980.1024

AGUA205.9788

0.115749.48090.000099.8976

COLUMN PROFILES

Reflux Ratio: 3.753e+007 Reboil Ratio: 9.283e+006 The Flows Option is Selected Flow Basis: MolarColumn Profiles Flows

Condenser1__Main TS2__Main TS3__Main TS4__Main TS5__Main TS6__Main TS7__Main TS8__Main TS9__Main TS10__Main TS11__Main TS12__Main TS13__Main TS14__Main TS15__Main TS

Reboiler

Temperature (F)92.7193.96102.6111.9121.1129.5136.6142.5147.5151.7155.5158.9162.2165.7170.4182.8203.0

Pressure (psia)3.7553.7554.4695.1845.8986.6127.3278.0418.7559.47010.1810.9011.6112.3313.0413.7613.76

Net Liq (lbmole/hr)2.094e+0092.071e+0092.063e+0092.045e+0092.025e+0092.009e+0091.998e+0091.992e+0091.989e+0091.989e+0091.989e+0091.989e+0091.987e+0091.979e+0091.950e+0091.912e+009

Net Vap (lbmole/hr)

2.094e+0092.071e+0092.063e+0092.045e+0092.025e+0092.009e+0091.998e+0091.992e+0091.989e+0091.989e+0091.989e+0091.989e+0091.987e+0091.979e+0091.950e+0091.912e+009

Net Feed (lbmole/hr)

261.8

Net Draws (lbmole/hr)55.80

206.0Column Profiles Energy

Condenser1__Main TS2__Main TS3__Main TS4__Main TS5__Main TS6__Main TS7__Main TS8__Main TS9__Main TS10__Main TS11__Main TS12__Main TS13__Main TS14__Main TS15__Main TS

Reboiler

Temperature (F)92.7193.96102.6111.9121.1129.5136.6142.5147.5151.7155.5158.9162.2165.7170.4182.8203.0

Liquid Enthalpy (Btu/lbmole)-1.033e+005-1.042e+005-1.056e+005-1.077e+005-1.101e+005-1.122e+005-1.139e+005-1.151e+005-1.159e+005-1.164e+005-1.168e+005-1.171e+005-1.173e+005-1.177e+005-1.185e+005-1.199e+005-1.201e+005

Vapour Enthalpy (Btu/lbmole)-8.667e+004-8.707e+004-8.776e+004-8.911e+004-9.109e+004-9.330e+004-9.530e+004-9.687e+004-9.799e+004-9.877e+004-9.930e+004-9.966e+004-9.994e+004-1.002e+005-1.005e+005-1.010e+005-1.021e+005

Heat Loss (Btu/hr)

FEEDS / PRODUCTS

Flow Basis: Molar Stream Type Duty (kJ/h) State Flows (kgmole/h) Enthalpy (kJ/kgmole Temp (C)

CondenserQ611

EnergyDraw

3.402e+013 *

Liquid 55.80 * -1.033e+005 * 92.71 *

1__Main TS2__Main TS3__Main TS4__Main TS

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Page 68: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Distillation: T-101 (continued)

FEEDS / PRODUCTS

5__Main TS6__Main TS7__Main TS8__Main TS9__Main TS10__Main TS 10 Feed Mixed 261.8 * -1.133e+005 * 93.09 *

11__Main TS12__Main TS13__Main TS14__Main TS15__Main TS

ReboilerQ7AGUA

EnergyDraw

3.402e+013 *

Liquid 206.0 * -1.201e+005 * 203.0 *

SETUP

Sub-FlowsheetFeed Streams

Internal StreamQ710

External StreamQ710

Transfer BasisNone Req'dP-H Flash

Product StreamsInternal Stream

Q6AGUA

11

External StreamQ6

AGUA11

Transfer BasisNone Req'dP-H FlashP-H Flash

VARIABLES

Column Flowsheet Vars Available as ParametersData Source Variable Component Description

COMPONENT MAPS

Feed StreamsFeed Name

Q710

In to SubFlowSheet Out of SubFlowSheet

Product StreamProduct Name

Q6AGUA11

In to SubFlowSheet Out of SubFlowSheet

DYNAMICS

Vessel Dynamic Specifications

VesselDiameter (ft)Height.0 (ft)Volume.0 (ft3)Liquid Volume Percent (%)Level CalculatorFraction CalculatorVessel Delta P (psi)Fixed Vessel P Spec (psia)Fixed P Spec Active

Reboiler @COL23.9145.87170.63 *

50.00Horizontal cylinder

Use levels and nozzles0.000013.76

Not Active

Condenser @COL23.9145.87170.63 *

50.00Horizontal cylinder

Use levels and nozzles0.00003.755

Not Active

Other Equipment in Column Flowsheet

Holdup Details

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Page 69: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Distillation: T-101 (continued)

Condenser1__Main TS2__Main TS3__Main TS4__Main TS5__Main TS6__Main TS7__Main TS8__Main TS9__Main TS10__Main TS11__Main TS12__Main TS13__Main TS14__Main TS15__Main TSReboiler

Pressure (psia)

0.00000.00000.00000.00000.00000.00000.00000.00000.00000.00000.00000.00000.00000.00000.00000.00000.0000

Volume (ft3)

0.0000 *

0.0000 *

0.0000 *

0.0000 *

0.0000 *

0.0000 *

0.0000 *

0.0000 *

0.0000 *

0.0000 *

0.0000 *

0.0000 *

0.0000 *

0.0000 *

0.0000 *

0.0000 *

0.0000 *

Bulk Liquid Volume (ft3)

0.00000.00000.00000.00000.00000.00000.00000.00000.00000.00000.00000.00000.00000.00000.00000.00000.0000

NOTES

Valve: VLV-100

CONNECTIONS

Inlet Stream

STREAM NAME FROM UNIT OPERATION

5 ERV-100Equilibrium Reactor

Outlet Stream

STREAM NAME TO UNIT OPERATION

6 E-101Cooler

PARAMETERS

Physical Properties

Pressure Drop: 7.252 psi

User Variables

RATING

Sizing

Sizing ConditionsInlet Pressure 152.3 psia Molecular Weight 40.75 CurrentValve Opening 50.00 % * Delta P 7.252 psi Flow Rate 4.963e+004 lb/hr

Valve Manufacturer and Valve TypeManufacturer: Universal Gas Sizing Type: ---

Valve Operating Characteristic and Sizing MethodLinear Sizing Method: Cg

C1 25.00 Km 0.9000 Cv 903e+004 USGPM Cg 1.476e+006

Nozzle Parameters

Base Elevation Relative to Ground Level 0.0000 ft *

Diameter (ft)Elevation (Base) (ft)

50.16400.0000

60.16400.0000

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Valve: VLV-100 (continued)Elevation (Ground) (ft)Elevation (% of Height) (%)

0.0000 0.0000

CONDITIONS

NameVapourTemperature (F)Pressure (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)

51.0000

248.0000 *

152.28961217.8072

49630.71684915.2307

-8.105e+00444.88

-9.8701e+07

61.0000

247.9137145.0377 *

1217.807249630.71684915.2307

-8.105e+00444.98

-9.8701e+07

PROPERTIES

NameMolecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

540.75

2.005e-0020.8173

2.596e+005-19891.10117.07

0.41904.623e+0051.134e+004

4.941e-3240.00000.0000

10121.05917.0711.0743.16

0.0000

11.37

0.00001.1321.132

1.161e+0040.887140.985177

0.000049.87284.9

1.0000

1.477e-0021.161e-002

15.090.370215.09

0.3702

640.75

1.910e-0020.7784

2.725e+005-19891.10417.06

0.41864.623e+0051.134e+004

4.941e-3240.00000.0000

10631.05917.0611.0743.16

1.00011.37

0.00001.1321.132

1.166e+0040.929740.985177

0.000052.35286.2

1.0000

1.474e-0021.159e-002

15.070.369815.07

0.3698

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Valve: VLV-100 (continued)

PROPERTIES

NameCp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(psia)(psia)

(barrel/day)

5

113.194.985177

6

113.194.985177

DYNAMICS

Dynamic Specifications

Total Delta P (psi)Pressure Flow Relation

7.252 Not ActiveActive

Dynamic Parameters

Valve Opening (%)Conductance (USGPM)

50.00 *

5.903e+004Mass Flow (lb/hr)Friction Delta P (psi)

4.963e+0047.252

Pipe Model Parameters

MaterialRoughness (ft)Pipe Length (ft)Feed Diameter (ft)

Cast Iron8.497e-004

0.0000 *

0.1640

Darcy Friction FactorPipe k (lb/hr/sqrt(psia-lb/ft3))Velocity (ft/s)Reynolds Number

0.0000 *

798.2 *

1.371e+007 *

Hold-Up Volume: 0.0000 ft3 *

Phase

VapourLiquid

Aqueous

Accumulation (lbmole/hr)

0.00000.00000.0000

Moles (lbmole)

0.0000 *

0.0000 *

0.0000 *

Volume (ft3)

0.00000.00000.0000

Total 0.0000 0.0000 0.0000

Actuator Parameters

Parameters Mode: Instantaneous

Actuator Time Constant (seconds)Valve Stickiness Time Constant (seconds)

1.000 * Actuator Linear Rate 1.000e-002 *

Activator Position

Fail Position: None

Min (%)

Max (%)

Current (%)

Desired (%)

Offset (%)

ValveActuator

0.00 *

0.00 *

100.00 *

100.00 *

50.00 *

50.00 * 50.00 *

0.00 *

Valve: VLV-101

CONNECTIONS

Inlet Stream

STREAM NAME FROM UNIT OPERATION

9 T-100Distillation

Outlet Stream

STREAM NAME TO UNIT OPERATION

10 T-101Distillation

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Page 72: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Valve: VLV-101 (continued)

PARAMETERS

Physical Properties

Pressure Drop: 157.5 psi

User Variables

RATING

Sizing

Sizing ConditionsInlet Pressure 159.0 psia Molecular Weight 21.40 CurrentValve Opening 50.00 % * Delta P 157.5 psi Flow Rate 5601 lb/hr

Valve Manufacturer and Valve TypeManufacturer: Universal Gas Sizing Type: ---

Valve Operating Characteristic and Sizing MethodLinear Sizing Method: Cv (standard) cal/min.sqrt(psi)

C1 25.00 Km 0.9000 Cv Cg

Nozzle Parameters

Base Elevation Relative to Ground Level 0.0000 ft *

Diameter (ft)Elevation (Base) (ft)Elevation (Ground) (ft)Elevation (% of Height) (%)

90.16400.00000.0000

100.16400.00000.0000

CONDITIONS

NameVapourTemperature (F)Pressure (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)

90.0000

320.5048159.0000261.7770

5600.7367417.9672

-1.133e+00515.54

-2.9664e+07

100.2755

93.08521.4504 *

261.77705600.7367417.9672

-1.133e+00514.39

-2.9664e+07

PROPERTIES

NameMolecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas Flow

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)

921.402.33249.89479.9-5296

0.726222.691.061

6.577e+0043074

0.00000.00000.0000

2.67722.692.380

1021.40

8.875e-0041.899e-0021.261e+006

-52960.672416.65

0.77806.577e+004

30740.35950.33430.00000.0000

2.67716.652.380

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LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Valve: VLV-101 (continued)

PROPERTIES

NameStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(lb/ft3)(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

957.2814.00

8.144e-00310.64

0.00001.0961.213

1.539e+0040.168258.35410.31.000

0.4288719.1

0.000038.26

0.28990.134420.70

0.967718.70

0.8741

4.4812.329410.3

1057.287.783

10.64

0.00001.1351.034

1.854e+004

58.35410.3

0.72451127866.8

0.275565.90

14.660.685216.10

0.7524

4.4812.329411.0

DYNAMICS

Dynamic Specifications

Total Delta P (psi)Pressure Flow Relation

157.5 Not ActiveActive

Dynamic Parameters

Valve Opening (%)Conductance (USGPM)

50.00 * Mass Flow (lb/hr)Friction Delta P (psi)

5601157.5

Pipe Model Parameters

MaterialRoughness (ft)Pipe Length (ft)Feed Diameter (ft)

Cast Iron8.497e-004

0.0000 *

0.1640

Darcy Friction FactorPipe k (lb/hr/sqrt(psia-lb/ft3))Velocity (ft/s)Reynolds Number

0.0000 *

1.475 *

1.337e+005 *

Hold-Up Volume: 0.0000 ft3 *

Phase

VapourLiquid

Aqueous

Accumulation (lbmole/hr)

0.00000.00000.0000

Moles (lbmole)

0.0000 *

0.0000 *

0.0000 *

Volume (ft3)

0.00000.00000.0000

Total 0.0000 0.0000 0.0000

Actuator Parameters

Parameters Mode: InstantaneousHyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 73 of 76

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Page 74: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Valve: VLV-101 (continued)Parameters Mode: Instantaneous

Actuator Time Constant (seconds)Valve Stickiness Time Constant (seconds)

1.000 * Actuator Linear Rate 1.000e-002 *

Activator Position

Fail Position: None

Min (%)

Max (%)

Current (%)

Desired (%)

Offset (%)

ValveActuator

0.00 *

0.00 *

100.00 *

100.00 *

50.00 *

50.00 * 50.00 *

0.00 *

Valve: VLV-102

CONNECTIONS

Inlet Stream

STREAM NAME FROM UNIT OPERATION

8 T-100Distillation

Outlet Stream

STREAM NAME TO UNIT OPERATION

DME

PARAMETERS

Physical Properties

Pressure Drop: 7.252 psi *

User Variables

RATING

Sizing

Sizing ConditionsInlet Pressure 139.0 psia Molecular Weight 46.06 CurrentValve Opening 50.00 % * Delta P 7.252 psi * Flow Rate 4.403e+004 lb/hr

Valve Manufacturer and Valve TypeManufacturer: Universal Gas Sizing Type: ---

Valve Operating Characteristic and Sizing MethodLinear Sizing Method: Cv (standard) cal/min.sqrt(psi)

C1 25.00 Km 0.9000 Cv 84.16 USGPM Cg 2104

Nozzle Parameters

Base Elevation Relative to Ground Level 0.0000 ft *

Diameter (ft)Elevation (Base) (ft)Elevation (Ground) (ft)Elevation (% of Height) (%)

80.16400.00000.0000

DME0.16400.00000.0000

CONDITIONS

NameVapourTemperature (F)Pressure (psia)Molar Flow (lbmole/hr)Mass Flow (lb/hr)

80.0000

110.0070139.0000956.0302

44029.9802

DME0.0133

106.2195131.7481956.0302

44029.9802

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Page 75: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Valve: VLV-102 (continued)

CONDITIONS

Std Ideal Liq Vol Flow (barrel/day)Molar Enthalpy (Btu/lbmole)Molar Entropy (Btu/lbmole-F)Heat Flow (Btu/hr)

4497.2635-8.662e+004

37.85-8.2809e+07

4497.2635-8.662e+004

37.54-8.2809e+07

PROPERTIES

NameMolecular WeightMolar DensityMass DensityAct. Volume FlowMass EnthalpyMass EntropyHeat CapacityMass Heat CapacityLower Heating ValueMass Lower Heating ValuePhase Fraction [Vol. Basis]Phase Fraction [Mass Basis]Partial Pressure of CO2Cost Based on FlowAct. Gas FlowAvg. Liq. DensitySpecific HeatStd. Gas FlowStd. Ideal Liq. Mass DensityAct. Liq. FlowZ FactorWatson KUser PropertyPartial Pressure of H2SCp/(Cp - R)Cp/CvHeat of Vap.Kinematic ViscosityLiq. Mass Density (Std. Cond)Liq. Vol. Flow (Std. Cond)Liquid FractionMolar VolumeMass Heat of Vap.Phase Fraction [Molar Basis]Surface TensionThermal ConductivityViscosityCv (Semi-Ideal)Mass Cv (Semi-Ideal)CvMass CvCv (Ent. Method)Mass Cv (Ent. Method)Cp/Cv (Ent. Method)Reid VP at 37.8 CTrue VP at 37.8 CLiq. Vol. Flow - Sum(Std. Cond)Viscosity Index

(lbmole/ft3)(lb/ft3)

(barrel/day)(Btu/lb)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole)

(Btu/lb)

(psia)(Cost/s)(ACFM)

(lbmole/ft3)(Btu/lbmole-F)

(MMSCFD)(lb/ft3)

(USGPM)

(psia)

(Btu/lbmole)(cSt)

(lb/ft3)(barrel/day)

(ft3/lbmole)(Btu/lb)

(dyne/cm)(Btu/hr-ft-F)

(cP)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)(Btu/lbmole-F)

(Btu/lb-F)

(psia)(psia)

(barrel/day)

846.06

0.779935.925240

-18810.821928.21

0.61265.708e+0051.239e+004

2.122e-3140.00000.0000

0.908728.218.69041.85152.8

2.915e-00211.38

0.00001.0761.0767981

0.131238.5848781.0001.282173.3

0.00009.257

7.011e-0027.548e-002

26.230.569526.23

0.5695

120.4120.74878

DME46.06

0.534124.607651

-18810.815127.86

0.60505.708e+0051.239e+0041.334e-0021.334e-002

0.00000.0000

0.908727.868.69041.85149.9

11.38

0.00001.0771.0078026

38.584878

0.98671.872174.3

0.01339.542

25.880.561927.66

0.6006

120.4120.74878

DYNAMICS

Dynamic SpecificationsHyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 75 of 76

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Page 76: Hysys Print

LEGENDSBurlington, MAUSA

Case Name: DFP FINAL.HSC

Unit Set: Field

Date/Time: Wed Mar 21 00:56:33 2012

Valve: VLV-102 (continued)Dynamic Specifications

Total Delta P (psi)Pressure Flow Relation

7.252 * Not ActiveActive

Dynamic Parameters

Valve Opening (%)Conductance (USGPM)

50.00 *

84.16Mass Flow (lb/hr)Friction Delta P (psi)

4.403e+0047.252

Pipe Model Parameters

MaterialRoughness (ft)Pipe Length (ft)Feed Diameter (ft)

Cast Iron8.497e-004

0.0000 *

0.1640

Darcy Friction FactorPipe k (lb/hr/sqrt(psia-lb/ft3))Velocity (ft/s)Reynolds Number

0.0000 *

16.11 *

1.872e+006 *

Hold-Up Volume: 0.0000 ft3 *

Phase

VapourLiquid

Aqueous

Accumulation (lbmole/hr)

0.00000.00000.0000

Moles (lbmole)

0.0000 *

0.0000 *

0.0000 *

Volume (ft3)

0.00000.00000.0000

Total 0.0000 0.0000 0.0000

Actuator Parameters

Parameters Mode: Instantaneous

Actuator Time Constant (seconds)Valve Stickiness Time Constant (seconds)

1.000 * Actuator Linear Rate 1.000e-002 *

Activator Position

Fail Position: None

Min (%)

Max (%)

Current (%)

Desired (%)

Offset (%)

ValveActuator

0.00 *

0.00 *

100.00 *

100.00 *

50.00 *

50.00 * 50.00 *

0.00 *

Equilibrium: Rxn-2

STOICHIOMETRY

ComponentMethanoldiM-Ether

H2O

Molecular Weight32.0446.0718.02

Stoichiometric Coefficient-2 *

1 *

1 *

Balance Error : 0.0000 Reaction Heat (25 C) : -5035 Btu/lbmole

BASIS

Basis PhaseApproach

(F)Min. Temp

(F)Max. Temp

(F)

Activity VapourPhase -459.7 5432

PARAMETERS

Source : Gibbs Free Energy

Hyprotech Ltd. Aspen HYSYS Version 7.1 (23.0.0.7119) Page 76 of 76

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