i scientists gza geoenvironmental, inc. engfnttrs and
TRANSCRIPT
Jlf-3317 GZA GeoEnvironmental Inc
380 Harvey Road Manchester New Hampshire 03103-3347 603-623-3600 FAX 603-624-9463 wwwgzacom
Engfnttrs and
Scientists IVIAEMAIL
March 9 2012 File No 040029307 _QO
Ms Nancy Lesieur Industrial Pretreatment Coordinator Winnipesaukee River Basin Program Wastewater Treatment Plant Water Division New Hampshire Department ofEnvironmental Services 528 River Street Franklin New Hampshire 03235
Re Wastewater Discharge Monitoring Report Treated Wastewater Merrimack Station Public Service ofNew Hampshire Bow New Hampshire
Dear Ms Lesieur
On behalfof Public Service ofNew Hampshire (PSNH) GZA GeoEnvironmental Inc is pleased to submit the attached Analytical Data Report for sampling conducted on February 9 2012 in accordance with Special Agreement - PSNH and WRBP Wastewater Treatment Plant which requires that Any testing results on the proposed discharge after start up at your facility will need to be forwarded to us for our review and tiles
ANALYTICAL DISCUSSION
Flue Gas Desulfurization (FGD) wastewater requires specialized analytical techniques to overcome matrix interference for certain analysis oftrace metals To assist you in evaluating this issue further we offer an excerpt below from the United States Environmental Protection Agency (EPA) web site and a link to their draft Standard Operating Procedure (SOP) for trace metals analysis ofFGD wastewater that contains further guidance
LABORATORY ANALYSIS OF FGD WASTEWATER
Wastewater from FGD systems can contain constituents known to cause matrix interferences EPA has observed that during inductively coupled plasma - mass spectrometry (ICP-MS) analysis of FGD wastewater certain elements commonly present in the wastewater may cause polyatomic interferences that bias the detection andor quantization of certain elements of interest These potential interferences may become significant when measuring trace elements at concentrations in the low parts-per-billion range
As part of a recent sampling effort for the steam electric power generating effluent guidelines rulemalcing EPA developed an SOP that was used in conjunction with EPA Method 2008 to conduct ICP-MS analyses of FGD wastewater The SOP describes critical technical and quality assurance procedures that were implemented to mitigate anticipated interferences and generate reliable data for FGD wastewater
Copyright~ 2012 GZA GeoEnvironmental Inc
M Equal Oppc1unity Erqloya- MFNR
Winnipesaukee River Basin Program Wastewater Treatment Plant File No 04002930700
March 9 2012 Page2
EPA regulations at 40 CFR 1366 already allow the analytical community flexibility to modify approved methods to lower the costs of measurements overcome matrix interferences or
otherwise improve the analysis The draft SOP developed for FGD wastewater takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (ie a synthetic FGD wastewater matrix) EPAs draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater either for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOP For further information see
Standard Operating Procedure Inductively Coupled Plas~aMass Spectrometry for Trace Element Analysis in Flue Gas Desulfurization Wastewaters (30 pp 174K) httpwater epagovlscitechwastetechguideuploadlsteam _draft_soppdf EPA May 2011
Considering that specialized analytical techniques are necessary to overcome matrix interference for certain analysis of trace metals in FDG wastewater we recommend any analysis on FGD wastewater be conducted in accordance with the EPA draft SOP for trace metals analysis ofFGD wastewater
Should you have any questions concerning this report please do not hesitate to contact me at (603) 232-8744
Very truly yours
GZA GEOENVIRONMENTAL INC
(iZraquootJQ ~ Ronald A Breton P E Principal
RABtmd P04Jobamp0029300s04002930700Wor1clSMlPLING AND REPORTINGIREPORTSfranklinREPORlIFINAL 040029307 fflnklin DATA RPT 030812docx
Attachment Analytical Data Report
ANALYTICAL DATAREPORT
--~1AA_____________e_a_s_t_e_r_n_a_n_a_ly_t_i_c_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report
Eastern Analytical Inc ID 107558
Client Identification Wastewater Analysis - Weekly
Date Received 292012
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QNQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters
The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
z2ftzDate of pages (excluding cover letter)
middot 1 lllailahsc1111
SAMPLE CONDITIONS PAGE EAi ID 107558
~ Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis - Weekly
Temperature upon receipt (degC 20 Received on ice or cold packs (YesNo) y Acceptable temperature range (C) 0-6
Date Date Sample Dry
Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10755801 Effluent Field Blank 2912 2912 aqueous Adheres lo Sample Acceptance Policy
10755802 Treat Tank Effluent 2912 2912 aqueous Adheres lo Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint lgnitlbility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an bullas received basis All results contained in this report relate only to the above listed samples References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweaiJabscom Phone (603) 228-0525 1
LABORATORY REPORT EAi ID 107558
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis - Weekly
middot-middot-middot--------shySample ID Treat Tank Effluent
Lab Sample ID 10755802
Matrix aqueous
Date Sampled 29112 Analysis
Date Received 2912 Units Date Time Method Analyst
pH 72 SU 20912 1056 4500H+B CJJ
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAi ID 107558
Client GZA GeoEnvlronmental Inc NH)
Client Designation Wastewater Analysis - Weekly
Parameter Name Blank LCS LCSD Date of
Units Analysis Limits RPO Method
pH 60 (101 ooR) 60 (101 R) (0 RPD) SU 2912 595 - 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page I Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweaifabscom Phone (603) 228-0525 3
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
GLOBAL SC IENCES Fx 206-622-6870
27 February 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
4
FRONTIER~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID LabID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 10-Feb-I2 0925
Treat Tank Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its entirety
Page I o23 Final Report m1nnM
5 Liz Siska Project Manager
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2of23 Final Report 6 nn1nfll1
Liz Siska Project Manager
I
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The sampl~ were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 lE
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure ofaccuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPO) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and defmitions section ofthe following report middot
Chain or Custody Record amp Laboratory Analysis Request - tla WI 981092-0Z~shyPir Water Sediments Plant and Animal Tissue 07558 205-622-amp0
W6middot622-6100Hydroa1rbon Bo Other Samples ~NT~ w1r1lMJ9nii1~StQ11 ( J 0 ti A l Si C I f N t ( i
i C-3oY~ 2
--3
_ 6
l ~ 8
9
- -~~ 1middot
12
12 -02 - 0
I
- shy - middoti middot-middot- f
- 1- middot-middot bull middot 1
httpbullww FrontlcrGScon
Sanpk Dbullsoosal Uy gg vau d~lar Chat you aqrce with FGS turr~ rgtltJ COldbullt10lt1 1(11 thtl O Return l~hi11png lcfS moy gtPll11middotl Vo ~uthorlze lGS to 1)111orm the spedllcd a-lyscs I Q Strd~rltl OisPOsal bull JO Days 111_ bull~l)Ort D Rct for __ wee~~ _itcr 1lJgtObullt (storage r~s m~y ~pply) USt(raquoJl(l( AgtPOVhl - -bull bullbull bull - _-0DlC bull
1
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
CHAIN OF CUSTODY FORMS
Page3of23 Finalampportnn1nn1
7 Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBA L SCIENCES
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsentirety
Liz Siska Project Manager
middot1 414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 04 40 microgL I F20213l 2Bl80I6 021712 EPA2008 Mod u Arsenic ND 005 015 microgL 1 F20213l 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0004 0020 microgL F202215 2B2l010 022112 EPA 2008 Mod u Chromium ND 0009 OiO microgL F202131 2Bl8016 021712 EPA2008Mod u Copper ND 001 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod QM-12 U
Lead ND 0004 0040 microgL l F202131 2Bl8016 021712 EPA2008 Mod u Manganese ND 0007 010 microgL 1 F20213I 2Bl8016 021712 EPA 2008 Mod u Mercury ND 008 -050 ngL F202196 2B17024 021712 EPA 1631E u Molybdenum ND 0006 006 microgL F202131 2BJ8016 021712 EPA 2008 Mod u Nickel ND 0008 010 microgL l F202I3l 2B18016 021712 EPA 2008 Mod u Seleniwn ND 019 060 microgL 1 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U
Silver ND 0006 0020 microgL I F202149 2B15001 021412 EPA 2008 Mod QM-12 U
Zinc ND 002 020 microgL l F202215 2B21010 022112 EPA 2008 Mod u
Page 4 o23 Final Report 8 1nn11n
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Treat Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Alwninwn ND 222 200 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Arsenic ND 255 750 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0208 100 microgL 50 F202215 2B21010 022112 EPA 2008 Mod u Chromium ND 045 500 microgL 50 F202131 2Bl8016 021712 EPA2008 Mod u Copper ND 050 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U Lead ND 0195 200 microgL 50 F202131 2Bl80I6 021712 EPA 2008 Mod u Manganese 1730 037 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Mercury 209 017 101 ngL 2 F202196 2BI7024 021712 EPA 1631E Molybdenum 110 030 300 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Nickel 126 040 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Selenium 822 969 300 microgL 50 F202131 2B24005 022312 EPA 2008 Mod Silver ND 0300 100 microgL 50 F202149 2Bl5001 021412 EPA 2008 Mod QM-12 U Zinc ND 082 100 microgL 50 F202215 2B2I010 022112 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced i11 its entirety
Page 5 o23 Final Report 9 nn11n1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
bull ~ Fx 206-622-6870 GLOBAL SCIENCE S
MATRIX DUPLICATESTRIPLICATES
SOURCE 1202140-02RE1
Batch F202196 Sequence 2BI7024
Preparation BrCl Oxidation Lab Number F202196-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes
Mercury 2434 2257 101 752 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to lhe samples analyzed in accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6 o23 Final Report 10 mn1nn1
Liz Siska Project Manager
Frontier Global Sciences Inc The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must b reproducd In Its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 2Bl~Q16
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2021 31-MSMSDI
Aoalyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(pgL)
MS
Recovery Recovery
Method Limits Notes
Aluminum 484 15150 1999 100 70 - 130 EPA 2008 Mod
Chromium 107 70700 866 107 70- 130 EPA2008 Mod
Manganese 1735 60600 1712 -373 70 bull 130 EPA 2008 Mod QM-02 Nickel 1262 40400 1766 125 70 - 130 EPA 2008 Mod
Copper 083 40400 507 105 70 - 130 EPA 2008 Mod
Zinc 232 10100 8169 786 70 - 130 EPA 2008 Mod QM-07 Arsenic 561 15150 2194 108 70 - 130 EPA 2008 Mod
Selenium 9717 30300 1230 852 70 bull 130 EPA2008 Mod Molybdenum 110l 20200 1115 719 70 bull 130 EPA 2008 Mod
Lead ND 15150 1567 103 70 bull 130 EPA2008 Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15150 2032 102 164 70- 130 20 EPA 2008 Mod Chromium 70700 856 106 115 70 bull 130 20 EPA 2008 Mod Manganese 60600 1727 -131 0852 70 - 130 20 EPA 2008 Mod QM-02 Nickel 40400 1618 88l 876 70 - 130 20 EPA 2008 Mod Copper 40400 484 993 459 70 - 130 20 EPA 2008 Mod Zinc 10100 1688 144 131 70 - 130 20 EPA 2008 Mod QM-07
QR-08 Arsenic 15150 2485 127 124 70 - 130 20 EPA 2008 Mod Selenium 30300 1351 125 938 70- 130 20 EPA2008 Mod Molybdenum 20200 1125 119 0846 70- 130 20 EPA 2008 Mod Lead 15150 1468 969 656 70 - 130 20 EPA 2008 Mod
Page 7of23 Final Rtport 11 nnn rr
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F20213l Sequence 2BI8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-MSMSD2
Aoalyte
Sample Cqocentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 484 10100 10380 102 70 - 130 EPA 2008 Mod AS
Chromium 107 10100 1060 105 70 - 130 EPA 2008 Mod AS
Manganese 1735 10100 2770 102 70 - 130 EPA 2008 Mod AS
Nickel 1262 12625 1303 102 70 - 130 EPA 2008 Mod AS
Copper 083 12625 1253 992 70 - 130 EPA 2008 Mod AS
Zinc 232 25250 2530 100 70 - 130 EPA 2008 Mod AS
Arsenic 561 10100 1073 106 70 - 130 EPA 2008 Mod AS
Selenium 9717 10100 1127 102 70- 130 EPA2008 Mod AS
Molybdenum 1101 50500 6305 103 70 - 130 EPA 2008 Mod AS
Lead ND 25250 2514 995 70 - 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(JtgL)
MSO
Recovery
Oo
RPO Recovery
Limits RPO Limit Method Notes
Aluminwn 10100 10120 998 252 70 - 130 20 EPA 2008 Mod AS
Chromium 10100 1050 104 0947 70- 130 20 EPA 2008 Mod AS
Manganese 10100 2755 101 0548 70 - 130 20 EPA 2008 Mod AS
Nickel 12625 1302 102 0101 70 - 130 20 EPA 2008 Mod AS
Copper 12625 1258 996 0384 70- 130 20 EPA 2008 Mod AS
Zinc 25250 25ll 993 0770 70- 130 20 EPA 2008 Mod AS
Arsenic 10100 1092 108 173 70- 130 20 EPA 2008 Mod AS
Selenium 10100 1169 106 369 70 - 130 20 EPA2008Mod AS
Molybdenum 50500 6168 100 218 70 - 130 20 EPA 2008 Mod AS
Lead 25250 2499 990 0581 70- 130 20 EPA 2008 Mod AS
Page8of23 Final Report 12 nn7nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
Winnipesaukee River Basin Program Wastewater Treatment Plant File No 04002930700
March 9 2012 Page2
EPA regulations at 40 CFR 1366 already allow the analytical community flexibility to modify approved methods to lower the costs of measurements overcome matrix interferences or
otherwise improve the analysis The draft SOP developed for FGD wastewater takes a proactive approach toward looking for and taking steps to mitigate matrix interferences including using specialized interference check solutions (ie a synthetic FGD wastewater matrix) EPAs draft SOP is being made available to laboratories contemplating ICP-MS analysis of FGD wastewater either for adoption as currently written or to serve as a framework for developing their own laboratory-specific SOP For further information see
Standard Operating Procedure Inductively Coupled Plas~aMass Spectrometry for Trace Element Analysis in Flue Gas Desulfurization Wastewaters (30 pp 174K) httpwater epagovlscitechwastetechguideuploadlsteam _draft_soppdf EPA May 2011
Considering that specialized analytical techniques are necessary to overcome matrix interference for certain analysis of trace metals in FDG wastewater we recommend any analysis on FGD wastewater be conducted in accordance with the EPA draft SOP for trace metals analysis ofFGD wastewater
Should you have any questions concerning this report please do not hesitate to contact me at (603) 232-8744
Very truly yours
GZA GEOENVIRONMENTAL INC
(iZraquootJQ ~ Ronald A Breton P E Principal
RABtmd P04Jobamp0029300s04002930700Wor1clSMlPLING AND REPORTINGIREPORTSfranklinREPORlIFINAL 040029307 fflnklin DATA RPT 030812docx
Attachment Analytical Data Report
ANALYTICAL DATAREPORT
--~1AA_____________e_a_s_t_e_r_n_a_n_a_ly_t_i_c_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report
Eastern Analytical Inc ID 107558
Client Identification Wastewater Analysis - Weekly
Date Received 292012
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QNQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters
The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
z2ftzDate of pages (excluding cover letter)
middot 1 lllailahsc1111
SAMPLE CONDITIONS PAGE EAi ID 107558
~ Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis - Weekly
Temperature upon receipt (degC 20 Received on ice or cold packs (YesNo) y Acceptable temperature range (C) 0-6
Date Date Sample Dry
Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10755801 Effluent Field Blank 2912 2912 aqueous Adheres lo Sample Acceptance Policy
10755802 Treat Tank Effluent 2912 2912 aqueous Adheres lo Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint lgnitlbility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an bullas received basis All results contained in this report relate only to the above listed samples References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweaiJabscom Phone (603) 228-0525 1
LABORATORY REPORT EAi ID 107558
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis - Weekly
middot-middot-middot--------shySample ID Treat Tank Effluent
Lab Sample ID 10755802
Matrix aqueous
Date Sampled 29112 Analysis
Date Received 2912 Units Date Time Method Analyst
pH 72 SU 20912 1056 4500H+B CJJ
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAi ID 107558
Client GZA GeoEnvlronmental Inc NH)
Client Designation Wastewater Analysis - Weekly
Parameter Name Blank LCS LCSD Date of
Units Analysis Limits RPO Method
pH 60 (101 ooR) 60 (101 R) (0 RPD) SU 2912 595 - 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page I Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweaifabscom Phone (603) 228-0525 3
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
GLOBAL SC IENCES Fx 206-622-6870
27 February 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
4
FRONTIER~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID LabID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 10-Feb-I2 0925
Treat Tank Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its entirety
Page I o23 Final Report m1nnM
5 Liz Siska Project Manager
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2of23 Final Report 6 nn1nfll1
Liz Siska Project Manager
I
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The sampl~ were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 lE
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure ofaccuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPO) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and defmitions section ofthe following report middot
Chain or Custody Record amp Laboratory Analysis Request - tla WI 981092-0Z~shyPir Water Sediments Plant and Animal Tissue 07558 205-622-amp0
W6middot622-6100Hydroa1rbon Bo Other Samples ~NT~ w1r1lMJ9nii1~StQ11 ( J 0 ti A l Si C I f N t ( i
i C-3oY~ 2
--3
_ 6
l ~ 8
9
- -~~ 1middot
12
12 -02 - 0
I
- shy - middoti middot-middot- f
- 1- middot-middot bull middot 1
httpbullww FrontlcrGScon
Sanpk Dbullsoosal Uy gg vau d~lar Chat you aqrce with FGS turr~ rgtltJ COldbullt10lt1 1(11 thtl O Return l~hi11png lcfS moy gtPll11middotl Vo ~uthorlze lGS to 1)111orm the spedllcd a-lyscs I Q Strd~rltl OisPOsal bull JO Days 111_ bull~l)Ort D Rct for __ wee~~ _itcr 1lJgtObullt (storage r~s m~y ~pply) USt(raquoJl(l( AgtPOVhl - -bull bullbull bull - _-0DlC bull
1
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
CHAIN OF CUSTODY FORMS
Page3of23 Finalampportnn1nn1
7 Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBA L SCIENCES
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsentirety
Liz Siska Project Manager
middot1 414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 04 40 microgL I F20213l 2Bl80I6 021712 EPA2008 Mod u Arsenic ND 005 015 microgL 1 F20213l 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0004 0020 microgL F202215 2B2l010 022112 EPA 2008 Mod u Chromium ND 0009 OiO microgL F202131 2Bl8016 021712 EPA2008Mod u Copper ND 001 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod QM-12 U
Lead ND 0004 0040 microgL l F202131 2Bl8016 021712 EPA2008 Mod u Manganese ND 0007 010 microgL 1 F20213I 2Bl8016 021712 EPA 2008 Mod u Mercury ND 008 -050 ngL F202196 2B17024 021712 EPA 1631E u Molybdenum ND 0006 006 microgL F202131 2BJ8016 021712 EPA 2008 Mod u Nickel ND 0008 010 microgL l F202I3l 2B18016 021712 EPA 2008 Mod u Seleniwn ND 019 060 microgL 1 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U
Silver ND 0006 0020 microgL I F202149 2B15001 021412 EPA 2008 Mod QM-12 U
Zinc ND 002 020 microgL l F202215 2B21010 022112 EPA 2008 Mod u
Page 4 o23 Final Report 8 1nn11n
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Treat Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Alwninwn ND 222 200 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Arsenic ND 255 750 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0208 100 microgL 50 F202215 2B21010 022112 EPA 2008 Mod u Chromium ND 045 500 microgL 50 F202131 2Bl8016 021712 EPA2008 Mod u Copper ND 050 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U Lead ND 0195 200 microgL 50 F202131 2Bl80I6 021712 EPA 2008 Mod u Manganese 1730 037 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Mercury 209 017 101 ngL 2 F202196 2BI7024 021712 EPA 1631E Molybdenum 110 030 300 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Nickel 126 040 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Selenium 822 969 300 microgL 50 F202131 2B24005 022312 EPA 2008 Mod Silver ND 0300 100 microgL 50 F202149 2Bl5001 021412 EPA 2008 Mod QM-12 U Zinc ND 082 100 microgL 50 F202215 2B2I010 022112 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced i11 its entirety
Page 5 o23 Final Report 9 nn11n1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
bull ~ Fx 206-622-6870 GLOBAL SCIENCE S
MATRIX DUPLICATESTRIPLICATES
SOURCE 1202140-02RE1
Batch F202196 Sequence 2BI7024
Preparation BrCl Oxidation Lab Number F202196-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes
Mercury 2434 2257 101 752 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to lhe samples analyzed in accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6 o23 Final Report 10 mn1nn1
Liz Siska Project Manager
Frontier Global Sciences Inc The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must b reproducd In Its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 2Bl~Q16
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2021 31-MSMSDI
Aoalyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(pgL)
MS
Recovery Recovery
Method Limits Notes
Aluminum 484 15150 1999 100 70 - 130 EPA 2008 Mod
Chromium 107 70700 866 107 70- 130 EPA2008 Mod
Manganese 1735 60600 1712 -373 70 bull 130 EPA 2008 Mod QM-02 Nickel 1262 40400 1766 125 70 - 130 EPA 2008 Mod
Copper 083 40400 507 105 70 - 130 EPA 2008 Mod
Zinc 232 10100 8169 786 70 - 130 EPA 2008 Mod QM-07 Arsenic 561 15150 2194 108 70 - 130 EPA 2008 Mod
Selenium 9717 30300 1230 852 70 bull 130 EPA2008 Mod Molybdenum 110l 20200 1115 719 70 bull 130 EPA 2008 Mod
Lead ND 15150 1567 103 70 bull 130 EPA2008 Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15150 2032 102 164 70- 130 20 EPA 2008 Mod Chromium 70700 856 106 115 70 bull 130 20 EPA 2008 Mod Manganese 60600 1727 -131 0852 70 - 130 20 EPA 2008 Mod QM-02 Nickel 40400 1618 88l 876 70 - 130 20 EPA 2008 Mod Copper 40400 484 993 459 70 - 130 20 EPA 2008 Mod Zinc 10100 1688 144 131 70 - 130 20 EPA 2008 Mod QM-07
QR-08 Arsenic 15150 2485 127 124 70 - 130 20 EPA 2008 Mod Selenium 30300 1351 125 938 70- 130 20 EPA2008 Mod Molybdenum 20200 1125 119 0846 70- 130 20 EPA 2008 Mod Lead 15150 1468 969 656 70 - 130 20 EPA 2008 Mod
Page 7of23 Final Rtport 11 nnn rr
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F20213l Sequence 2BI8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-MSMSD2
Aoalyte
Sample Cqocentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 484 10100 10380 102 70 - 130 EPA 2008 Mod AS
Chromium 107 10100 1060 105 70 - 130 EPA 2008 Mod AS
Manganese 1735 10100 2770 102 70 - 130 EPA 2008 Mod AS
Nickel 1262 12625 1303 102 70 - 130 EPA 2008 Mod AS
Copper 083 12625 1253 992 70 - 130 EPA 2008 Mod AS
Zinc 232 25250 2530 100 70 - 130 EPA 2008 Mod AS
Arsenic 561 10100 1073 106 70 - 130 EPA 2008 Mod AS
Selenium 9717 10100 1127 102 70- 130 EPA2008 Mod AS
Molybdenum 1101 50500 6305 103 70 - 130 EPA 2008 Mod AS
Lead ND 25250 2514 995 70 - 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(JtgL)
MSO
Recovery
Oo
RPO Recovery
Limits RPO Limit Method Notes
Aluminwn 10100 10120 998 252 70 - 130 20 EPA 2008 Mod AS
Chromium 10100 1050 104 0947 70- 130 20 EPA 2008 Mod AS
Manganese 10100 2755 101 0548 70 - 130 20 EPA 2008 Mod AS
Nickel 12625 1302 102 0101 70 - 130 20 EPA 2008 Mod AS
Copper 12625 1258 996 0384 70- 130 20 EPA 2008 Mod AS
Zinc 25250 25ll 993 0770 70- 130 20 EPA 2008 Mod AS
Arsenic 10100 1092 108 173 70- 130 20 EPA 2008 Mod AS
Selenium 10100 1169 106 369 70 - 130 20 EPA2008Mod AS
Molybdenum 50500 6168 100 218 70 - 130 20 EPA 2008 Mod AS
Lead 25250 2499 990 0581 70- 130 20 EPA 2008 Mod AS
Page8of23 Final Report 12 nn7nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
ANALYTICAL DATAREPORT
--~1AA_____________e_a_s_t_e_r_n_a_n_a_ly_t_i_c_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report
Eastern Analytical Inc ID 107558
Client Identification Wastewater Analysis - Weekly
Date Received 292012
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QNQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters
The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
z2ftzDate of pages (excluding cover letter)
middot 1 lllailahsc1111
SAMPLE CONDITIONS PAGE EAi ID 107558
~ Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis - Weekly
Temperature upon receipt (degC 20 Received on ice or cold packs (YesNo) y Acceptable temperature range (C) 0-6
Date Date Sample Dry
Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10755801 Effluent Field Blank 2912 2912 aqueous Adheres lo Sample Acceptance Policy
10755802 Treat Tank Effluent 2912 2912 aqueous Adheres lo Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint lgnitlbility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an bullas received basis All results contained in this report relate only to the above listed samples References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweaiJabscom Phone (603) 228-0525 1
LABORATORY REPORT EAi ID 107558
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis - Weekly
middot-middot-middot--------shySample ID Treat Tank Effluent
Lab Sample ID 10755802
Matrix aqueous
Date Sampled 29112 Analysis
Date Received 2912 Units Date Time Method Analyst
pH 72 SU 20912 1056 4500H+B CJJ
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAi ID 107558
Client GZA GeoEnvlronmental Inc NH)
Client Designation Wastewater Analysis - Weekly
Parameter Name Blank LCS LCSD Date of
Units Analysis Limits RPO Method
pH 60 (101 ooR) 60 (101 R) (0 RPD) SU 2912 595 - 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page I Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweaifabscom Phone (603) 228-0525 3
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
GLOBAL SC IENCES Fx 206-622-6870
27 February 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
4
FRONTIER~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID LabID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 10-Feb-I2 0925
Treat Tank Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its entirety
Page I o23 Final Report m1nnM
5 Liz Siska Project Manager
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2of23 Final Report 6 nn1nfll1
Liz Siska Project Manager
I
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The sampl~ were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 lE
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure ofaccuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPO) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and defmitions section ofthe following report middot
Chain or Custody Record amp Laboratory Analysis Request - tla WI 981092-0Z~shyPir Water Sediments Plant and Animal Tissue 07558 205-622-amp0
W6middot622-6100Hydroa1rbon Bo Other Samples ~NT~ w1r1lMJ9nii1~StQ11 ( J 0 ti A l Si C I f N t ( i
i C-3oY~ 2
--3
_ 6
l ~ 8
9
- -~~ 1middot
12
12 -02 - 0
I
- shy - middoti middot-middot- f
- 1- middot-middot bull middot 1
httpbullww FrontlcrGScon
Sanpk Dbullsoosal Uy gg vau d~lar Chat you aqrce with FGS turr~ rgtltJ COldbullt10lt1 1(11 thtl O Return l~hi11png lcfS moy gtPll11middotl Vo ~uthorlze lGS to 1)111orm the spedllcd a-lyscs I Q Strd~rltl OisPOsal bull JO Days 111_ bull~l)Ort D Rct for __ wee~~ _itcr 1lJgtObullt (storage r~s m~y ~pply) USt(raquoJl(l( AgtPOVhl - -bull bullbull bull - _-0DlC bull
1
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
CHAIN OF CUSTODY FORMS
Page3of23 Finalampportnn1nn1
7 Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBA L SCIENCES
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsentirety
Liz Siska Project Manager
middot1 414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 04 40 microgL I F20213l 2Bl80I6 021712 EPA2008 Mod u Arsenic ND 005 015 microgL 1 F20213l 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0004 0020 microgL F202215 2B2l010 022112 EPA 2008 Mod u Chromium ND 0009 OiO microgL F202131 2Bl8016 021712 EPA2008Mod u Copper ND 001 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod QM-12 U
Lead ND 0004 0040 microgL l F202131 2Bl8016 021712 EPA2008 Mod u Manganese ND 0007 010 microgL 1 F20213I 2Bl8016 021712 EPA 2008 Mod u Mercury ND 008 -050 ngL F202196 2B17024 021712 EPA 1631E u Molybdenum ND 0006 006 microgL F202131 2BJ8016 021712 EPA 2008 Mod u Nickel ND 0008 010 microgL l F202I3l 2B18016 021712 EPA 2008 Mod u Seleniwn ND 019 060 microgL 1 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U
Silver ND 0006 0020 microgL I F202149 2B15001 021412 EPA 2008 Mod QM-12 U
Zinc ND 002 020 microgL l F202215 2B21010 022112 EPA 2008 Mod u
Page 4 o23 Final Report 8 1nn11n
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Treat Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Alwninwn ND 222 200 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Arsenic ND 255 750 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0208 100 microgL 50 F202215 2B21010 022112 EPA 2008 Mod u Chromium ND 045 500 microgL 50 F202131 2Bl8016 021712 EPA2008 Mod u Copper ND 050 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U Lead ND 0195 200 microgL 50 F202131 2Bl80I6 021712 EPA 2008 Mod u Manganese 1730 037 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Mercury 209 017 101 ngL 2 F202196 2BI7024 021712 EPA 1631E Molybdenum 110 030 300 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Nickel 126 040 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Selenium 822 969 300 microgL 50 F202131 2B24005 022312 EPA 2008 Mod Silver ND 0300 100 microgL 50 F202149 2Bl5001 021412 EPA 2008 Mod QM-12 U Zinc ND 082 100 microgL 50 F202215 2B2I010 022112 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced i11 its entirety
Page 5 o23 Final Report 9 nn11n1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
bull ~ Fx 206-622-6870 GLOBAL SCIENCE S
MATRIX DUPLICATESTRIPLICATES
SOURCE 1202140-02RE1
Batch F202196 Sequence 2BI7024
Preparation BrCl Oxidation Lab Number F202196-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes
Mercury 2434 2257 101 752 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to lhe samples analyzed in accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6 o23 Final Report 10 mn1nn1
Liz Siska Project Manager
Frontier Global Sciences Inc The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must b reproducd In Its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 2Bl~Q16
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2021 31-MSMSDI
Aoalyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(pgL)
MS
Recovery Recovery
Method Limits Notes
Aluminum 484 15150 1999 100 70 - 130 EPA 2008 Mod
Chromium 107 70700 866 107 70- 130 EPA2008 Mod
Manganese 1735 60600 1712 -373 70 bull 130 EPA 2008 Mod QM-02 Nickel 1262 40400 1766 125 70 - 130 EPA 2008 Mod
Copper 083 40400 507 105 70 - 130 EPA 2008 Mod
Zinc 232 10100 8169 786 70 - 130 EPA 2008 Mod QM-07 Arsenic 561 15150 2194 108 70 - 130 EPA 2008 Mod
Selenium 9717 30300 1230 852 70 bull 130 EPA2008 Mod Molybdenum 110l 20200 1115 719 70 bull 130 EPA 2008 Mod
Lead ND 15150 1567 103 70 bull 130 EPA2008 Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15150 2032 102 164 70- 130 20 EPA 2008 Mod Chromium 70700 856 106 115 70 bull 130 20 EPA 2008 Mod Manganese 60600 1727 -131 0852 70 - 130 20 EPA 2008 Mod QM-02 Nickel 40400 1618 88l 876 70 - 130 20 EPA 2008 Mod Copper 40400 484 993 459 70 - 130 20 EPA 2008 Mod Zinc 10100 1688 144 131 70 - 130 20 EPA 2008 Mod QM-07
QR-08 Arsenic 15150 2485 127 124 70 - 130 20 EPA 2008 Mod Selenium 30300 1351 125 938 70- 130 20 EPA2008 Mod Molybdenum 20200 1125 119 0846 70- 130 20 EPA 2008 Mod Lead 15150 1468 969 656 70 - 130 20 EPA 2008 Mod
Page 7of23 Final Rtport 11 nnn rr
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F20213l Sequence 2BI8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-MSMSD2
Aoalyte
Sample Cqocentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 484 10100 10380 102 70 - 130 EPA 2008 Mod AS
Chromium 107 10100 1060 105 70 - 130 EPA 2008 Mod AS
Manganese 1735 10100 2770 102 70 - 130 EPA 2008 Mod AS
Nickel 1262 12625 1303 102 70 - 130 EPA 2008 Mod AS
Copper 083 12625 1253 992 70 - 130 EPA 2008 Mod AS
Zinc 232 25250 2530 100 70 - 130 EPA 2008 Mod AS
Arsenic 561 10100 1073 106 70 - 130 EPA 2008 Mod AS
Selenium 9717 10100 1127 102 70- 130 EPA2008 Mod AS
Molybdenum 1101 50500 6305 103 70 - 130 EPA 2008 Mod AS
Lead ND 25250 2514 995 70 - 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(JtgL)
MSO
Recovery
Oo
RPO Recovery
Limits RPO Limit Method Notes
Aluminwn 10100 10120 998 252 70 - 130 20 EPA 2008 Mod AS
Chromium 10100 1050 104 0947 70- 130 20 EPA 2008 Mod AS
Manganese 10100 2755 101 0548 70 - 130 20 EPA 2008 Mod AS
Nickel 12625 1302 102 0101 70 - 130 20 EPA 2008 Mod AS
Copper 12625 1258 996 0384 70- 130 20 EPA 2008 Mod AS
Zinc 25250 25ll 993 0770 70- 130 20 EPA 2008 Mod AS
Arsenic 10100 1092 108 173 70- 130 20 EPA 2008 Mod AS
Selenium 10100 1169 106 369 70 - 130 20 EPA2008Mod AS
Molybdenum 50500 6168 100 218 70 - 130 20 EPA 2008 Mod AS
Lead 25250 2499 990 0581 70- 130 20 EPA 2008 Mod AS
Page8of23 Final Report 12 nn7nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
--~1AA_____________e_a_s_t_e_r_n_a_n_a_ly_t_i_c_a_l__
Paul Pepler
GZA GeoEnvironmental Inc (NH)
380 Harvey Road
Manchester NH 03103
Subject Laboratory Report
Eastern Analytical Inc ID 107558
Client Identification Wastewater Analysis - Weekly
Date Received 292012
Dear Mr Pepler
Enclosed please find the laboratory report for the above identified project All analyses were performed in accordance with our QNQC Program Unless otherwise stated holding times preservation techniques container types and sample conditions adhered to EPA Protocol Samples which were collected by Eastern Analytical Inc (EAi) were collected in accordance with approved EPA procedures Eastern Analytical Inc certifies that the enclosed test results meet all requirements of NELAP and other applicable state certifications Please refer to our website at wwweailabscom for a copy of our NELAP certificate and accredited parameters
The following standard abbreviations and conventions apply to all EAi reports Solid samples are reported on a dry weight basis unless otherwise noted lt less than followed by the reporting limit gt greater than followed by the reporting limit R Recovery
Eastern Analytical Inc maintains certification in the following states Connecticut (PH-0492) Maine (NH005) Massachusetts (M-NH005) New HampshireNELAP (1012) Rhode Island (269) and Vermont (VT1012)
The following information is contained within this report Sample Conditions summary Analytical ResultsData Quality Control data (if requested) and copies of the Chain of Custody This report may not be reproduced except in full without the the written approval of the laboratory
If you have any questions regarding the results contained within please feel free to directly contact me or the chemist(s) who performed the testing in question Unless otherwise requested we will dispose of the sample(s) 30 days from the sample receipt date
We appreciate this opportunity to be of service and look forward to your continued patronage
Sincerely
z2ftzDate of pages (excluding cover letter)
middot 1 lllailahsc1111
SAMPLE CONDITIONS PAGE EAi ID 107558
~ Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis - Weekly
Temperature upon receipt (degC 20 Received on ice or cold packs (YesNo) y Acceptable temperature range (C) 0-6
Date Date Sample Dry
Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10755801 Effluent Field Blank 2912 2912 aqueous Adheres lo Sample Acceptance Policy
10755802 Treat Tank Effluent 2912 2912 aqueous Adheres lo Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint lgnitlbility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an bullas received basis All results contained in this report relate only to the above listed samples References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweaiJabscom Phone (603) 228-0525 1
LABORATORY REPORT EAi ID 107558
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis - Weekly
middot-middot-middot--------shySample ID Treat Tank Effluent
Lab Sample ID 10755802
Matrix aqueous
Date Sampled 29112 Analysis
Date Received 2912 Units Date Time Method Analyst
pH 72 SU 20912 1056 4500H+B CJJ
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAi ID 107558
Client GZA GeoEnvlronmental Inc NH)
Client Designation Wastewater Analysis - Weekly
Parameter Name Blank LCS LCSD Date of
Units Analysis Limits RPO Method
pH 60 (101 ooR) 60 (101 R) (0 RPD) SU 2912 595 - 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page I Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweaifabscom Phone (603) 228-0525 3
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
GLOBAL SC IENCES Fx 206-622-6870
27 February 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
4
FRONTIER~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID LabID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 10-Feb-I2 0925
Treat Tank Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its entirety
Page I o23 Final Report m1nnM
5 Liz Siska Project Manager
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2of23 Final Report 6 nn1nfll1
Liz Siska Project Manager
I
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The sampl~ were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 lE
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure ofaccuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPO) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and defmitions section ofthe following report middot
Chain or Custody Record amp Laboratory Analysis Request - tla WI 981092-0Z~shyPir Water Sediments Plant and Animal Tissue 07558 205-622-amp0
W6middot622-6100Hydroa1rbon Bo Other Samples ~NT~ w1r1lMJ9nii1~StQ11 ( J 0 ti A l Si C I f N t ( i
i C-3oY~ 2
--3
_ 6
l ~ 8
9
- -~~ 1middot
12
12 -02 - 0
I
- shy - middoti middot-middot- f
- 1- middot-middot bull middot 1
httpbullww FrontlcrGScon
Sanpk Dbullsoosal Uy gg vau d~lar Chat you aqrce with FGS turr~ rgtltJ COldbullt10lt1 1(11 thtl O Return l~hi11png lcfS moy gtPll11middotl Vo ~uthorlze lGS to 1)111orm the spedllcd a-lyscs I Q Strd~rltl OisPOsal bull JO Days 111_ bull~l)Ort D Rct for __ wee~~ _itcr 1lJgtObullt (storage r~s m~y ~pply) USt(raquoJl(l( AgtPOVhl - -bull bullbull bull - _-0DlC bull
1
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
CHAIN OF CUSTODY FORMS
Page3of23 Finalampportnn1nn1
7 Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBA L SCIENCES
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsentirety
Liz Siska Project Manager
middot1 414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 04 40 microgL I F20213l 2Bl80I6 021712 EPA2008 Mod u Arsenic ND 005 015 microgL 1 F20213l 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0004 0020 microgL F202215 2B2l010 022112 EPA 2008 Mod u Chromium ND 0009 OiO microgL F202131 2Bl8016 021712 EPA2008Mod u Copper ND 001 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod QM-12 U
Lead ND 0004 0040 microgL l F202131 2Bl8016 021712 EPA2008 Mod u Manganese ND 0007 010 microgL 1 F20213I 2Bl8016 021712 EPA 2008 Mod u Mercury ND 008 -050 ngL F202196 2B17024 021712 EPA 1631E u Molybdenum ND 0006 006 microgL F202131 2BJ8016 021712 EPA 2008 Mod u Nickel ND 0008 010 microgL l F202I3l 2B18016 021712 EPA 2008 Mod u Seleniwn ND 019 060 microgL 1 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U
Silver ND 0006 0020 microgL I F202149 2B15001 021412 EPA 2008 Mod QM-12 U
Zinc ND 002 020 microgL l F202215 2B21010 022112 EPA 2008 Mod u
Page 4 o23 Final Report 8 1nn11n
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Treat Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Alwninwn ND 222 200 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Arsenic ND 255 750 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0208 100 microgL 50 F202215 2B21010 022112 EPA 2008 Mod u Chromium ND 045 500 microgL 50 F202131 2Bl8016 021712 EPA2008 Mod u Copper ND 050 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U Lead ND 0195 200 microgL 50 F202131 2Bl80I6 021712 EPA 2008 Mod u Manganese 1730 037 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Mercury 209 017 101 ngL 2 F202196 2BI7024 021712 EPA 1631E Molybdenum 110 030 300 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Nickel 126 040 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Selenium 822 969 300 microgL 50 F202131 2B24005 022312 EPA 2008 Mod Silver ND 0300 100 microgL 50 F202149 2Bl5001 021412 EPA 2008 Mod QM-12 U Zinc ND 082 100 microgL 50 F202215 2B2I010 022112 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced i11 its entirety
Page 5 o23 Final Report 9 nn11n1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
bull ~ Fx 206-622-6870 GLOBAL SCIENCE S
MATRIX DUPLICATESTRIPLICATES
SOURCE 1202140-02RE1
Batch F202196 Sequence 2BI7024
Preparation BrCl Oxidation Lab Number F202196-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes
Mercury 2434 2257 101 752 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to lhe samples analyzed in accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6 o23 Final Report 10 mn1nn1
Liz Siska Project Manager
Frontier Global Sciences Inc The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must b reproducd In Its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 2Bl~Q16
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2021 31-MSMSDI
Aoalyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(pgL)
MS
Recovery Recovery
Method Limits Notes
Aluminum 484 15150 1999 100 70 - 130 EPA 2008 Mod
Chromium 107 70700 866 107 70- 130 EPA2008 Mod
Manganese 1735 60600 1712 -373 70 bull 130 EPA 2008 Mod QM-02 Nickel 1262 40400 1766 125 70 - 130 EPA 2008 Mod
Copper 083 40400 507 105 70 - 130 EPA 2008 Mod
Zinc 232 10100 8169 786 70 - 130 EPA 2008 Mod QM-07 Arsenic 561 15150 2194 108 70 - 130 EPA 2008 Mod
Selenium 9717 30300 1230 852 70 bull 130 EPA2008 Mod Molybdenum 110l 20200 1115 719 70 bull 130 EPA 2008 Mod
Lead ND 15150 1567 103 70 bull 130 EPA2008 Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15150 2032 102 164 70- 130 20 EPA 2008 Mod Chromium 70700 856 106 115 70 bull 130 20 EPA 2008 Mod Manganese 60600 1727 -131 0852 70 - 130 20 EPA 2008 Mod QM-02 Nickel 40400 1618 88l 876 70 - 130 20 EPA 2008 Mod Copper 40400 484 993 459 70 - 130 20 EPA 2008 Mod Zinc 10100 1688 144 131 70 - 130 20 EPA 2008 Mod QM-07
QR-08 Arsenic 15150 2485 127 124 70 - 130 20 EPA 2008 Mod Selenium 30300 1351 125 938 70- 130 20 EPA2008 Mod Molybdenum 20200 1125 119 0846 70- 130 20 EPA 2008 Mod Lead 15150 1468 969 656 70 - 130 20 EPA 2008 Mod
Page 7of23 Final Rtport 11 nnn rr
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F20213l Sequence 2BI8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-MSMSD2
Aoalyte
Sample Cqocentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 484 10100 10380 102 70 - 130 EPA 2008 Mod AS
Chromium 107 10100 1060 105 70 - 130 EPA 2008 Mod AS
Manganese 1735 10100 2770 102 70 - 130 EPA 2008 Mod AS
Nickel 1262 12625 1303 102 70 - 130 EPA 2008 Mod AS
Copper 083 12625 1253 992 70 - 130 EPA 2008 Mod AS
Zinc 232 25250 2530 100 70 - 130 EPA 2008 Mod AS
Arsenic 561 10100 1073 106 70 - 130 EPA 2008 Mod AS
Selenium 9717 10100 1127 102 70- 130 EPA2008 Mod AS
Molybdenum 1101 50500 6305 103 70 - 130 EPA 2008 Mod AS
Lead ND 25250 2514 995 70 - 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(JtgL)
MSO
Recovery
Oo
RPO Recovery
Limits RPO Limit Method Notes
Aluminwn 10100 10120 998 252 70 - 130 20 EPA 2008 Mod AS
Chromium 10100 1050 104 0947 70- 130 20 EPA 2008 Mod AS
Manganese 10100 2755 101 0548 70 - 130 20 EPA 2008 Mod AS
Nickel 12625 1302 102 0101 70 - 130 20 EPA 2008 Mod AS
Copper 12625 1258 996 0384 70- 130 20 EPA 2008 Mod AS
Zinc 25250 25ll 993 0770 70- 130 20 EPA 2008 Mod AS
Arsenic 10100 1092 108 173 70- 130 20 EPA 2008 Mod AS
Selenium 10100 1169 106 369 70 - 130 20 EPA2008Mod AS
Molybdenum 50500 6168 100 218 70 - 130 20 EPA 2008 Mod AS
Lead 25250 2499 990 0581 70- 130 20 EPA 2008 Mod AS
Page8of23 Final Report 12 nn7nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
SAMPLE CONDITIONS PAGE EAi ID 107558
~ Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis - Weekly
Temperature upon receipt (degC 20 Received on ice or cold packs (YesNo) y Acceptable temperature range (C) 0-6
Date Date Sample Dry
Lab ID Sample ID Received Sampled Matrix Weight ExceptionsComments (other than thermal preservation)
10755801 Effluent Field Blank 2912 2912 aqueous Adheres lo Sample Acceptance Policy
10755802 Treat Tank Effluent 2912 2912 aqueous Adheres lo Sample Acceptance Policy
Samples were properly preserved and the pH measured when applicable unless otherwise noted Analysis ofsolids for pH Flashpoint lgnitlbility Paint Filter Corrosivity Conductivity and Specific Gravity are reported on an bullas received basis All results contained in this report relate only to the above listed samples References include 1) EPA 6004-79-020 1983 2) Standard Methods for Examination of Water and Wastewater lnorganics 19th Edition 1995 Microbiology 20th Edition 1998 3) Test Methods for Evaluating Solid Waste SW 846 3rd Edition including updates VA and VB 4) Hach Water Analysis Handbook 2nd edition 1992
eastern analytical inc wwweaiJabscom Phone (603) 228-0525 1
LABORATORY REPORT EAi ID 107558
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis - Weekly
middot-middot-middot--------shySample ID Treat Tank Effluent
Lab Sample ID 10755802
Matrix aqueous
Date Sampled 29112 Analysis
Date Received 2912 Units Date Time Method Analyst
pH 72 SU 20912 1056 4500H+B CJJ
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAi ID 107558
Client GZA GeoEnvlronmental Inc NH)
Client Designation Wastewater Analysis - Weekly
Parameter Name Blank LCS LCSD Date of
Units Analysis Limits RPO Method
pH 60 (101 ooR) 60 (101 R) (0 RPD) SU 2912 595 - 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page I Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweaifabscom Phone (603) 228-0525 3
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
GLOBAL SC IENCES Fx 206-622-6870
27 February 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
4
FRONTIER~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID LabID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 10-Feb-I2 0925
Treat Tank Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its entirety
Page I o23 Final Report m1nnM
5 Liz Siska Project Manager
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2of23 Final Report 6 nn1nfll1
Liz Siska Project Manager
I
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The sampl~ were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 lE
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure ofaccuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPO) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and defmitions section ofthe following report middot
Chain or Custody Record amp Laboratory Analysis Request - tla WI 981092-0Z~shyPir Water Sediments Plant and Animal Tissue 07558 205-622-amp0
W6middot622-6100Hydroa1rbon Bo Other Samples ~NT~ w1r1lMJ9nii1~StQ11 ( J 0 ti A l Si C I f N t ( i
i C-3oY~ 2
--3
_ 6
l ~ 8
9
- -~~ 1middot
12
12 -02 - 0
I
- shy - middoti middot-middot- f
- 1- middot-middot bull middot 1
httpbullww FrontlcrGScon
Sanpk Dbullsoosal Uy gg vau d~lar Chat you aqrce with FGS turr~ rgtltJ COldbullt10lt1 1(11 thtl O Return l~hi11png lcfS moy gtPll11middotl Vo ~uthorlze lGS to 1)111orm the spedllcd a-lyscs I Q Strd~rltl OisPOsal bull JO Days 111_ bull~l)Ort D Rct for __ wee~~ _itcr 1lJgtObullt (storage r~s m~y ~pply) USt(raquoJl(l( AgtPOVhl - -bull bullbull bull - _-0DlC bull
1
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
CHAIN OF CUSTODY FORMS
Page3of23 Finalampportnn1nn1
7 Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBA L SCIENCES
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsentirety
Liz Siska Project Manager
middot1 414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 04 40 microgL I F20213l 2Bl80I6 021712 EPA2008 Mod u Arsenic ND 005 015 microgL 1 F20213l 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0004 0020 microgL F202215 2B2l010 022112 EPA 2008 Mod u Chromium ND 0009 OiO microgL F202131 2Bl8016 021712 EPA2008Mod u Copper ND 001 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod QM-12 U
Lead ND 0004 0040 microgL l F202131 2Bl8016 021712 EPA2008 Mod u Manganese ND 0007 010 microgL 1 F20213I 2Bl8016 021712 EPA 2008 Mod u Mercury ND 008 -050 ngL F202196 2B17024 021712 EPA 1631E u Molybdenum ND 0006 006 microgL F202131 2BJ8016 021712 EPA 2008 Mod u Nickel ND 0008 010 microgL l F202I3l 2B18016 021712 EPA 2008 Mod u Seleniwn ND 019 060 microgL 1 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U
Silver ND 0006 0020 microgL I F202149 2B15001 021412 EPA 2008 Mod QM-12 U
Zinc ND 002 020 microgL l F202215 2B21010 022112 EPA 2008 Mod u
Page 4 o23 Final Report 8 1nn11n
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Treat Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Alwninwn ND 222 200 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Arsenic ND 255 750 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0208 100 microgL 50 F202215 2B21010 022112 EPA 2008 Mod u Chromium ND 045 500 microgL 50 F202131 2Bl8016 021712 EPA2008 Mod u Copper ND 050 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U Lead ND 0195 200 microgL 50 F202131 2Bl80I6 021712 EPA 2008 Mod u Manganese 1730 037 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Mercury 209 017 101 ngL 2 F202196 2BI7024 021712 EPA 1631E Molybdenum 110 030 300 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Nickel 126 040 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Selenium 822 969 300 microgL 50 F202131 2B24005 022312 EPA 2008 Mod Silver ND 0300 100 microgL 50 F202149 2Bl5001 021412 EPA 2008 Mod QM-12 U Zinc ND 082 100 microgL 50 F202215 2B2I010 022112 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced i11 its entirety
Page 5 o23 Final Report 9 nn11n1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
bull ~ Fx 206-622-6870 GLOBAL SCIENCE S
MATRIX DUPLICATESTRIPLICATES
SOURCE 1202140-02RE1
Batch F202196 Sequence 2BI7024
Preparation BrCl Oxidation Lab Number F202196-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes
Mercury 2434 2257 101 752 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to lhe samples analyzed in accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6 o23 Final Report 10 mn1nn1
Liz Siska Project Manager
Frontier Global Sciences Inc The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must b reproducd In Its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 2Bl~Q16
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2021 31-MSMSDI
Aoalyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(pgL)
MS
Recovery Recovery
Method Limits Notes
Aluminum 484 15150 1999 100 70 - 130 EPA 2008 Mod
Chromium 107 70700 866 107 70- 130 EPA2008 Mod
Manganese 1735 60600 1712 -373 70 bull 130 EPA 2008 Mod QM-02 Nickel 1262 40400 1766 125 70 - 130 EPA 2008 Mod
Copper 083 40400 507 105 70 - 130 EPA 2008 Mod
Zinc 232 10100 8169 786 70 - 130 EPA 2008 Mod QM-07 Arsenic 561 15150 2194 108 70 - 130 EPA 2008 Mod
Selenium 9717 30300 1230 852 70 bull 130 EPA2008 Mod Molybdenum 110l 20200 1115 719 70 bull 130 EPA 2008 Mod
Lead ND 15150 1567 103 70 bull 130 EPA2008 Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15150 2032 102 164 70- 130 20 EPA 2008 Mod Chromium 70700 856 106 115 70 bull 130 20 EPA 2008 Mod Manganese 60600 1727 -131 0852 70 - 130 20 EPA 2008 Mod QM-02 Nickel 40400 1618 88l 876 70 - 130 20 EPA 2008 Mod Copper 40400 484 993 459 70 - 130 20 EPA 2008 Mod Zinc 10100 1688 144 131 70 - 130 20 EPA 2008 Mod QM-07
QR-08 Arsenic 15150 2485 127 124 70 - 130 20 EPA 2008 Mod Selenium 30300 1351 125 938 70- 130 20 EPA2008 Mod Molybdenum 20200 1125 119 0846 70- 130 20 EPA 2008 Mod Lead 15150 1468 969 656 70 - 130 20 EPA 2008 Mod
Page 7of23 Final Rtport 11 nnn rr
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F20213l Sequence 2BI8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-MSMSD2
Aoalyte
Sample Cqocentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 484 10100 10380 102 70 - 130 EPA 2008 Mod AS
Chromium 107 10100 1060 105 70 - 130 EPA 2008 Mod AS
Manganese 1735 10100 2770 102 70 - 130 EPA 2008 Mod AS
Nickel 1262 12625 1303 102 70 - 130 EPA 2008 Mod AS
Copper 083 12625 1253 992 70 - 130 EPA 2008 Mod AS
Zinc 232 25250 2530 100 70 - 130 EPA 2008 Mod AS
Arsenic 561 10100 1073 106 70 - 130 EPA 2008 Mod AS
Selenium 9717 10100 1127 102 70- 130 EPA2008 Mod AS
Molybdenum 1101 50500 6305 103 70 - 130 EPA 2008 Mod AS
Lead ND 25250 2514 995 70 - 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(JtgL)
MSO
Recovery
Oo
RPO Recovery
Limits RPO Limit Method Notes
Aluminwn 10100 10120 998 252 70 - 130 20 EPA 2008 Mod AS
Chromium 10100 1050 104 0947 70- 130 20 EPA 2008 Mod AS
Manganese 10100 2755 101 0548 70 - 130 20 EPA 2008 Mod AS
Nickel 12625 1302 102 0101 70 - 130 20 EPA 2008 Mod AS
Copper 12625 1258 996 0384 70- 130 20 EPA 2008 Mod AS
Zinc 25250 25ll 993 0770 70- 130 20 EPA 2008 Mod AS
Arsenic 10100 1092 108 173 70- 130 20 EPA 2008 Mod AS
Selenium 10100 1169 106 369 70 - 130 20 EPA2008Mod AS
Molybdenum 50500 6168 100 218 70 - 130 20 EPA 2008 Mod AS
Lead 25250 2499 990 0581 70- 130 20 EPA 2008 Mod AS
Page8of23 Final Report 12 nn7nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
LABORATORY REPORT EAi ID 107558
Client GZA GeoEnvironmental Inc (NH)
Client Designation Wastewater Analysis - Weekly
middot-middot-middot--------shySample ID Treat Tank Effluent
Lab Sample ID 10755802
Matrix aqueous
Date Sampled 29112 Analysis
Date Received 2912 Units Date Time Method Analyst
pH 72 SU 20912 1056 4500H+B CJJ
eastern analytical inc wwweailabscom Phone (603) 228-0525 2
QC REPORT EAi ID 107558
Client GZA GeoEnvlronmental Inc NH)
Client Designation Wastewater Analysis - Weekly
Parameter Name Blank LCS LCSD Date of
Units Analysis Limits RPO Method
pH 60 (101 ooR) 60 (101 R) (0 RPD) SU 2912 595 - 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page I Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweaifabscom Phone (603) 228-0525 3
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
GLOBAL SC IENCES Fx 206-622-6870
27 February 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
4
FRONTIER~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID LabID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 10-Feb-I2 0925
Treat Tank Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its entirety
Page I o23 Final Report m1nnM
5 Liz Siska Project Manager
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2of23 Final Report 6 nn1nfll1
Liz Siska Project Manager
I
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The sampl~ were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 lE
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure ofaccuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPO) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and defmitions section ofthe following report middot
Chain or Custody Record amp Laboratory Analysis Request - tla WI 981092-0Z~shyPir Water Sediments Plant and Animal Tissue 07558 205-622-amp0
W6middot622-6100Hydroa1rbon Bo Other Samples ~NT~ w1r1lMJ9nii1~StQ11 ( J 0 ti A l Si C I f N t ( i
i C-3oY~ 2
--3
_ 6
l ~ 8
9
- -~~ 1middot
12
12 -02 - 0
I
- shy - middoti middot-middot- f
- 1- middot-middot bull middot 1
httpbullww FrontlcrGScon
Sanpk Dbullsoosal Uy gg vau d~lar Chat you aqrce with FGS turr~ rgtltJ COldbullt10lt1 1(11 thtl O Return l~hi11png lcfS moy gtPll11middotl Vo ~uthorlze lGS to 1)111orm the spedllcd a-lyscs I Q Strd~rltl OisPOsal bull JO Days 111_ bull~l)Ort D Rct for __ wee~~ _itcr 1lJgtObullt (storage r~s m~y ~pply) USt(raquoJl(l( AgtPOVhl - -bull bullbull bull - _-0DlC bull
1
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
CHAIN OF CUSTODY FORMS
Page3of23 Finalampportnn1nn1
7 Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBA L SCIENCES
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsentirety
Liz Siska Project Manager
middot1 414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 04 40 microgL I F20213l 2Bl80I6 021712 EPA2008 Mod u Arsenic ND 005 015 microgL 1 F20213l 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0004 0020 microgL F202215 2B2l010 022112 EPA 2008 Mod u Chromium ND 0009 OiO microgL F202131 2Bl8016 021712 EPA2008Mod u Copper ND 001 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod QM-12 U
Lead ND 0004 0040 microgL l F202131 2Bl8016 021712 EPA2008 Mod u Manganese ND 0007 010 microgL 1 F20213I 2Bl8016 021712 EPA 2008 Mod u Mercury ND 008 -050 ngL F202196 2B17024 021712 EPA 1631E u Molybdenum ND 0006 006 microgL F202131 2BJ8016 021712 EPA 2008 Mod u Nickel ND 0008 010 microgL l F202I3l 2B18016 021712 EPA 2008 Mod u Seleniwn ND 019 060 microgL 1 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U
Silver ND 0006 0020 microgL I F202149 2B15001 021412 EPA 2008 Mod QM-12 U
Zinc ND 002 020 microgL l F202215 2B21010 022112 EPA 2008 Mod u
Page 4 o23 Final Report 8 1nn11n
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Treat Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Alwninwn ND 222 200 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Arsenic ND 255 750 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0208 100 microgL 50 F202215 2B21010 022112 EPA 2008 Mod u Chromium ND 045 500 microgL 50 F202131 2Bl8016 021712 EPA2008 Mod u Copper ND 050 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U Lead ND 0195 200 microgL 50 F202131 2Bl80I6 021712 EPA 2008 Mod u Manganese 1730 037 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Mercury 209 017 101 ngL 2 F202196 2BI7024 021712 EPA 1631E Molybdenum 110 030 300 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Nickel 126 040 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Selenium 822 969 300 microgL 50 F202131 2B24005 022312 EPA 2008 Mod Silver ND 0300 100 microgL 50 F202149 2Bl5001 021412 EPA 2008 Mod QM-12 U Zinc ND 082 100 microgL 50 F202215 2B2I010 022112 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced i11 its entirety
Page 5 o23 Final Report 9 nn11n1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
bull ~ Fx 206-622-6870 GLOBAL SCIENCE S
MATRIX DUPLICATESTRIPLICATES
SOURCE 1202140-02RE1
Batch F202196 Sequence 2BI7024
Preparation BrCl Oxidation Lab Number F202196-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes
Mercury 2434 2257 101 752 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to lhe samples analyzed in accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6 o23 Final Report 10 mn1nn1
Liz Siska Project Manager
Frontier Global Sciences Inc The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must b reproducd In Its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 2Bl~Q16
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2021 31-MSMSDI
Aoalyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(pgL)
MS
Recovery Recovery
Method Limits Notes
Aluminum 484 15150 1999 100 70 - 130 EPA 2008 Mod
Chromium 107 70700 866 107 70- 130 EPA2008 Mod
Manganese 1735 60600 1712 -373 70 bull 130 EPA 2008 Mod QM-02 Nickel 1262 40400 1766 125 70 - 130 EPA 2008 Mod
Copper 083 40400 507 105 70 - 130 EPA 2008 Mod
Zinc 232 10100 8169 786 70 - 130 EPA 2008 Mod QM-07 Arsenic 561 15150 2194 108 70 - 130 EPA 2008 Mod
Selenium 9717 30300 1230 852 70 bull 130 EPA2008 Mod Molybdenum 110l 20200 1115 719 70 bull 130 EPA 2008 Mod
Lead ND 15150 1567 103 70 bull 130 EPA2008 Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15150 2032 102 164 70- 130 20 EPA 2008 Mod Chromium 70700 856 106 115 70 bull 130 20 EPA 2008 Mod Manganese 60600 1727 -131 0852 70 - 130 20 EPA 2008 Mod QM-02 Nickel 40400 1618 88l 876 70 - 130 20 EPA 2008 Mod Copper 40400 484 993 459 70 - 130 20 EPA 2008 Mod Zinc 10100 1688 144 131 70 - 130 20 EPA 2008 Mod QM-07
QR-08 Arsenic 15150 2485 127 124 70 - 130 20 EPA 2008 Mod Selenium 30300 1351 125 938 70- 130 20 EPA2008 Mod Molybdenum 20200 1125 119 0846 70- 130 20 EPA 2008 Mod Lead 15150 1468 969 656 70 - 130 20 EPA 2008 Mod
Page 7of23 Final Rtport 11 nnn rr
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F20213l Sequence 2BI8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-MSMSD2
Aoalyte
Sample Cqocentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 484 10100 10380 102 70 - 130 EPA 2008 Mod AS
Chromium 107 10100 1060 105 70 - 130 EPA 2008 Mod AS
Manganese 1735 10100 2770 102 70 - 130 EPA 2008 Mod AS
Nickel 1262 12625 1303 102 70 - 130 EPA 2008 Mod AS
Copper 083 12625 1253 992 70 - 130 EPA 2008 Mod AS
Zinc 232 25250 2530 100 70 - 130 EPA 2008 Mod AS
Arsenic 561 10100 1073 106 70 - 130 EPA 2008 Mod AS
Selenium 9717 10100 1127 102 70- 130 EPA2008 Mod AS
Molybdenum 1101 50500 6305 103 70 - 130 EPA 2008 Mod AS
Lead ND 25250 2514 995 70 - 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(JtgL)
MSO
Recovery
Oo
RPO Recovery
Limits RPO Limit Method Notes
Aluminwn 10100 10120 998 252 70 - 130 20 EPA 2008 Mod AS
Chromium 10100 1050 104 0947 70- 130 20 EPA 2008 Mod AS
Manganese 10100 2755 101 0548 70 - 130 20 EPA 2008 Mod AS
Nickel 12625 1302 102 0101 70 - 130 20 EPA 2008 Mod AS
Copper 12625 1258 996 0384 70- 130 20 EPA 2008 Mod AS
Zinc 25250 25ll 993 0770 70- 130 20 EPA 2008 Mod AS
Arsenic 10100 1092 108 173 70- 130 20 EPA 2008 Mod AS
Selenium 10100 1169 106 369 70 - 130 20 EPA2008Mod AS
Molybdenum 50500 6168 100 218 70 - 130 20 EPA 2008 Mod AS
Lead 25250 2499 990 0581 70- 130 20 EPA 2008 Mod AS
Page8of23 Final Report 12 nn7nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
QC REPORT EAi ID 107558
Client GZA GeoEnvlronmental Inc NH)
Client Designation Wastewater Analysis - Weekly
Parameter Name Blank LCS LCSD Date of
Units Analysis Limits RPO Method
pH 60 (101 ooR) 60 (101 R) (0 RPD) SU 2912 595 - 607 10 4500H+B
Samples were analyzed within holding times unless noted on the sample results page Instrumentation was calibrated in accordance with the method requirements The method blanks were free of contamination at the reporting limits The associated matrix spikes andor Laboratory Control Samples met the above stated criteria Exceptions to the above statements are flagged or noted above or on the QC Narrative page I Flagged analyte recoveries deviated from the QNQC limits
eastern analytical inc wwweaifabscom Phone (603) 228-0525 3
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
GLOBAL SC IENCES Fx 206-622-6870
27 February 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
4
FRONTIER~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID LabID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 10-Feb-I2 0925
Treat Tank Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its entirety
Page I o23 Final Report m1nnM
5 Liz Siska Project Manager
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2of23 Final Report 6 nn1nfll1
Liz Siska Project Manager
I
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The sampl~ were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 lE
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure ofaccuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPO) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and defmitions section ofthe following report middot
Chain or Custody Record amp Laboratory Analysis Request - tla WI 981092-0Z~shyPir Water Sediments Plant and Animal Tissue 07558 205-622-amp0
W6middot622-6100Hydroa1rbon Bo Other Samples ~NT~ w1r1lMJ9nii1~StQ11 ( J 0 ti A l Si C I f N t ( i
i C-3oY~ 2
--3
_ 6
l ~ 8
9
- -~~ 1middot
12
12 -02 - 0
I
- shy - middoti middot-middot- f
- 1- middot-middot bull middot 1
httpbullww FrontlcrGScon
Sanpk Dbullsoosal Uy gg vau d~lar Chat you aqrce with FGS turr~ rgtltJ COldbullt10lt1 1(11 thtl O Return l~hi11png lcfS moy gtPll11middotl Vo ~uthorlze lGS to 1)111orm the spedllcd a-lyscs I Q Strd~rltl OisPOsal bull JO Days 111_ bull~l)Ort D Rct for __ wee~~ _itcr 1lJgtObullt (storage r~s m~y ~pply) USt(raquoJl(l( AgtPOVhl - -bull bullbull bull - _-0DlC bull
1
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
CHAIN OF CUSTODY FORMS
Page3of23 Finalampportnn1nn1
7 Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBA L SCIENCES
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsentirety
Liz Siska Project Manager
middot1 414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 04 40 microgL I F20213l 2Bl80I6 021712 EPA2008 Mod u Arsenic ND 005 015 microgL 1 F20213l 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0004 0020 microgL F202215 2B2l010 022112 EPA 2008 Mod u Chromium ND 0009 OiO microgL F202131 2Bl8016 021712 EPA2008Mod u Copper ND 001 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod QM-12 U
Lead ND 0004 0040 microgL l F202131 2Bl8016 021712 EPA2008 Mod u Manganese ND 0007 010 microgL 1 F20213I 2Bl8016 021712 EPA 2008 Mod u Mercury ND 008 -050 ngL F202196 2B17024 021712 EPA 1631E u Molybdenum ND 0006 006 microgL F202131 2BJ8016 021712 EPA 2008 Mod u Nickel ND 0008 010 microgL l F202I3l 2B18016 021712 EPA 2008 Mod u Seleniwn ND 019 060 microgL 1 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U
Silver ND 0006 0020 microgL I F202149 2B15001 021412 EPA 2008 Mod QM-12 U
Zinc ND 002 020 microgL l F202215 2B21010 022112 EPA 2008 Mod u
Page 4 o23 Final Report 8 1nn11n
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Treat Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Alwninwn ND 222 200 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Arsenic ND 255 750 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0208 100 microgL 50 F202215 2B21010 022112 EPA 2008 Mod u Chromium ND 045 500 microgL 50 F202131 2Bl8016 021712 EPA2008 Mod u Copper ND 050 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U Lead ND 0195 200 microgL 50 F202131 2Bl80I6 021712 EPA 2008 Mod u Manganese 1730 037 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Mercury 209 017 101 ngL 2 F202196 2BI7024 021712 EPA 1631E Molybdenum 110 030 300 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Nickel 126 040 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Selenium 822 969 300 microgL 50 F202131 2B24005 022312 EPA 2008 Mod Silver ND 0300 100 microgL 50 F202149 2Bl5001 021412 EPA 2008 Mod QM-12 U Zinc ND 082 100 microgL 50 F202215 2B2I010 022112 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced i11 its entirety
Page 5 o23 Final Report 9 nn11n1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
bull ~ Fx 206-622-6870 GLOBAL SCIENCE S
MATRIX DUPLICATESTRIPLICATES
SOURCE 1202140-02RE1
Batch F202196 Sequence 2BI7024
Preparation BrCl Oxidation Lab Number F202196-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes
Mercury 2434 2257 101 752 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to lhe samples analyzed in accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6 o23 Final Report 10 mn1nn1
Liz Siska Project Manager
Frontier Global Sciences Inc The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must b reproducd In Its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 2Bl~Q16
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2021 31-MSMSDI
Aoalyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(pgL)
MS
Recovery Recovery
Method Limits Notes
Aluminum 484 15150 1999 100 70 - 130 EPA 2008 Mod
Chromium 107 70700 866 107 70- 130 EPA2008 Mod
Manganese 1735 60600 1712 -373 70 bull 130 EPA 2008 Mod QM-02 Nickel 1262 40400 1766 125 70 - 130 EPA 2008 Mod
Copper 083 40400 507 105 70 - 130 EPA 2008 Mod
Zinc 232 10100 8169 786 70 - 130 EPA 2008 Mod QM-07 Arsenic 561 15150 2194 108 70 - 130 EPA 2008 Mod
Selenium 9717 30300 1230 852 70 bull 130 EPA2008 Mod Molybdenum 110l 20200 1115 719 70 bull 130 EPA 2008 Mod
Lead ND 15150 1567 103 70 bull 130 EPA2008 Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15150 2032 102 164 70- 130 20 EPA 2008 Mod Chromium 70700 856 106 115 70 bull 130 20 EPA 2008 Mod Manganese 60600 1727 -131 0852 70 - 130 20 EPA 2008 Mod QM-02 Nickel 40400 1618 88l 876 70 - 130 20 EPA 2008 Mod Copper 40400 484 993 459 70 - 130 20 EPA 2008 Mod Zinc 10100 1688 144 131 70 - 130 20 EPA 2008 Mod QM-07
QR-08 Arsenic 15150 2485 127 124 70 - 130 20 EPA 2008 Mod Selenium 30300 1351 125 938 70- 130 20 EPA2008 Mod Molybdenum 20200 1125 119 0846 70- 130 20 EPA 2008 Mod Lead 15150 1468 969 656 70 - 130 20 EPA 2008 Mod
Page 7of23 Final Rtport 11 nnn rr
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F20213l Sequence 2BI8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-MSMSD2
Aoalyte
Sample Cqocentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 484 10100 10380 102 70 - 130 EPA 2008 Mod AS
Chromium 107 10100 1060 105 70 - 130 EPA 2008 Mod AS
Manganese 1735 10100 2770 102 70 - 130 EPA 2008 Mod AS
Nickel 1262 12625 1303 102 70 - 130 EPA 2008 Mod AS
Copper 083 12625 1253 992 70 - 130 EPA 2008 Mod AS
Zinc 232 25250 2530 100 70 - 130 EPA 2008 Mod AS
Arsenic 561 10100 1073 106 70 - 130 EPA 2008 Mod AS
Selenium 9717 10100 1127 102 70- 130 EPA2008 Mod AS
Molybdenum 1101 50500 6305 103 70 - 130 EPA 2008 Mod AS
Lead ND 25250 2514 995 70 - 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(JtgL)
MSO
Recovery
Oo
RPO Recovery
Limits RPO Limit Method Notes
Aluminwn 10100 10120 998 252 70 - 130 20 EPA 2008 Mod AS
Chromium 10100 1050 104 0947 70- 130 20 EPA 2008 Mod AS
Manganese 10100 2755 101 0548 70 - 130 20 EPA 2008 Mod AS
Nickel 12625 1302 102 0101 70 - 130 20 EPA 2008 Mod AS
Copper 12625 1258 996 0384 70- 130 20 EPA 2008 Mod AS
Zinc 25250 25ll 993 0770 70- 130 20 EPA 2008 Mod AS
Arsenic 10100 1092 108 173 70- 130 20 EPA 2008 Mod AS
Selenium 10100 1169 106 369 70 - 130 20 EPA2008Mod AS
Molybdenum 50500 6168 100 218 70 - 130 20 EPA 2008 Mod AS
Lead 25250 2499 990 0581 70- 130 20 EPA 2008 Mod AS
Page8of23 Final Report 12 nn7nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
GLOBAL SC IENCES Fx 206-622-6870
27 February 2012
JeffGagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
Ifyou have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
4
FRONTIER~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID LabID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 10-Feb-I2 0925
Treat Tank Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its entirety
Page I o23 Final Report m1nnM
5 Liz Siska Project Manager
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2of23 Final Report 6 nn1nfll1
Liz Siska Project Manager
I
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The sampl~ were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 lE
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure ofaccuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPO) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and defmitions section ofthe following report middot
Chain or Custody Record amp Laboratory Analysis Request - tla WI 981092-0Z~shyPir Water Sediments Plant and Animal Tissue 07558 205-622-amp0
W6middot622-6100Hydroa1rbon Bo Other Samples ~NT~ w1r1lMJ9nii1~StQ11 ( J 0 ti A l Si C I f N t ( i
i C-3oY~ 2
--3
_ 6
l ~ 8
9
- -~~ 1middot
12
12 -02 - 0
I
- shy - middoti middot-middot- f
- 1- middot-middot bull middot 1
httpbullww FrontlcrGScon
Sanpk Dbullsoosal Uy gg vau d~lar Chat you aqrce with FGS turr~ rgtltJ COldbullt10lt1 1(11 thtl O Return l~hi11png lcfS moy gtPll11middotl Vo ~uthorlze lGS to 1)111orm the spedllcd a-lyscs I Q Strd~rltl OisPOsal bull JO Days 111_ bull~l)Ort D Rct for __ wee~~ _itcr 1lJgtObullt (storage r~s m~y ~pply) USt(raquoJl(l( AgtPOVhl - -bull bullbull bull - _-0DlC bull
1
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
CHAIN OF CUSTODY FORMS
Page3of23 Finalampportnn1nn1
7 Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBA L SCIENCES
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsentirety
Liz Siska Project Manager
middot1 414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 04 40 microgL I F20213l 2Bl80I6 021712 EPA2008 Mod u Arsenic ND 005 015 microgL 1 F20213l 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0004 0020 microgL F202215 2B2l010 022112 EPA 2008 Mod u Chromium ND 0009 OiO microgL F202131 2Bl8016 021712 EPA2008Mod u Copper ND 001 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod QM-12 U
Lead ND 0004 0040 microgL l F202131 2Bl8016 021712 EPA2008 Mod u Manganese ND 0007 010 microgL 1 F20213I 2Bl8016 021712 EPA 2008 Mod u Mercury ND 008 -050 ngL F202196 2B17024 021712 EPA 1631E u Molybdenum ND 0006 006 microgL F202131 2BJ8016 021712 EPA 2008 Mod u Nickel ND 0008 010 microgL l F202I3l 2B18016 021712 EPA 2008 Mod u Seleniwn ND 019 060 microgL 1 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U
Silver ND 0006 0020 microgL I F202149 2B15001 021412 EPA 2008 Mod QM-12 U
Zinc ND 002 020 microgL l F202215 2B21010 022112 EPA 2008 Mod u
Page 4 o23 Final Report 8 1nn11n
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Treat Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Alwninwn ND 222 200 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Arsenic ND 255 750 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0208 100 microgL 50 F202215 2B21010 022112 EPA 2008 Mod u Chromium ND 045 500 microgL 50 F202131 2Bl8016 021712 EPA2008 Mod u Copper ND 050 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U Lead ND 0195 200 microgL 50 F202131 2Bl80I6 021712 EPA 2008 Mod u Manganese 1730 037 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Mercury 209 017 101 ngL 2 F202196 2BI7024 021712 EPA 1631E Molybdenum 110 030 300 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Nickel 126 040 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Selenium 822 969 300 microgL 50 F202131 2B24005 022312 EPA 2008 Mod Silver ND 0300 100 microgL 50 F202149 2Bl5001 021412 EPA 2008 Mod QM-12 U Zinc ND 082 100 microgL 50 F202215 2B2I010 022112 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced i11 its entirety
Page 5 o23 Final Report 9 nn11n1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
bull ~ Fx 206-622-6870 GLOBAL SCIENCE S
MATRIX DUPLICATESTRIPLICATES
SOURCE 1202140-02RE1
Batch F202196 Sequence 2BI7024
Preparation BrCl Oxidation Lab Number F202196-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes
Mercury 2434 2257 101 752 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to lhe samples analyzed in accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6 o23 Final Report 10 mn1nn1
Liz Siska Project Manager
Frontier Global Sciences Inc The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must b reproducd In Its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 2Bl~Q16
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2021 31-MSMSDI
Aoalyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(pgL)
MS
Recovery Recovery
Method Limits Notes
Aluminum 484 15150 1999 100 70 - 130 EPA 2008 Mod
Chromium 107 70700 866 107 70- 130 EPA2008 Mod
Manganese 1735 60600 1712 -373 70 bull 130 EPA 2008 Mod QM-02 Nickel 1262 40400 1766 125 70 - 130 EPA 2008 Mod
Copper 083 40400 507 105 70 - 130 EPA 2008 Mod
Zinc 232 10100 8169 786 70 - 130 EPA 2008 Mod QM-07 Arsenic 561 15150 2194 108 70 - 130 EPA 2008 Mod
Selenium 9717 30300 1230 852 70 bull 130 EPA2008 Mod Molybdenum 110l 20200 1115 719 70 bull 130 EPA 2008 Mod
Lead ND 15150 1567 103 70 bull 130 EPA2008 Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15150 2032 102 164 70- 130 20 EPA 2008 Mod Chromium 70700 856 106 115 70 bull 130 20 EPA 2008 Mod Manganese 60600 1727 -131 0852 70 - 130 20 EPA 2008 Mod QM-02 Nickel 40400 1618 88l 876 70 - 130 20 EPA 2008 Mod Copper 40400 484 993 459 70 - 130 20 EPA 2008 Mod Zinc 10100 1688 144 131 70 - 130 20 EPA 2008 Mod QM-07
QR-08 Arsenic 15150 2485 127 124 70 - 130 20 EPA 2008 Mod Selenium 30300 1351 125 938 70- 130 20 EPA2008 Mod Molybdenum 20200 1125 119 0846 70- 130 20 EPA 2008 Mod Lead 15150 1468 969 656 70 - 130 20 EPA 2008 Mod
Page 7of23 Final Rtport 11 nnn rr
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F20213l Sequence 2BI8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-MSMSD2
Aoalyte
Sample Cqocentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 484 10100 10380 102 70 - 130 EPA 2008 Mod AS
Chromium 107 10100 1060 105 70 - 130 EPA 2008 Mod AS
Manganese 1735 10100 2770 102 70 - 130 EPA 2008 Mod AS
Nickel 1262 12625 1303 102 70 - 130 EPA 2008 Mod AS
Copper 083 12625 1253 992 70 - 130 EPA 2008 Mod AS
Zinc 232 25250 2530 100 70 - 130 EPA 2008 Mod AS
Arsenic 561 10100 1073 106 70 - 130 EPA 2008 Mod AS
Selenium 9717 10100 1127 102 70- 130 EPA2008 Mod AS
Molybdenum 1101 50500 6305 103 70 - 130 EPA 2008 Mod AS
Lead ND 25250 2514 995 70 - 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(JtgL)
MSO
Recovery
Oo
RPO Recovery
Limits RPO Limit Method Notes
Aluminwn 10100 10120 998 252 70 - 130 20 EPA 2008 Mod AS
Chromium 10100 1050 104 0947 70- 130 20 EPA 2008 Mod AS
Manganese 10100 2755 101 0548 70 - 130 20 EPA 2008 Mod AS
Nickel 12625 1302 102 0101 70 - 130 20 EPA 2008 Mod AS
Copper 12625 1258 996 0384 70- 130 20 EPA 2008 Mod AS
Zinc 25250 25ll 993 0770 70- 130 20 EPA 2008 Mod AS
Arsenic 10100 1092 108 173 70- 130 20 EPA 2008 Mod AS
Selenium 10100 1169 106 369 70 - 130 20 EPA2008Mod AS
Molybdenum 50500 6168 100 218 70 - 130 20 EPA 2008 Mod AS
Lead 25250 2499 990 0581 70- 130 20 EPA 2008 Mod AS
Page8of23 Final Report 12 nn7nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
FRONTIER~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc SDG
Client Eastern Analytical Inc Project Merrimack Station 2008
Sample ID LabID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 10-Feb-I2 0925
Treat Tank Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced In Its entirety
Page I o23 Final Report m1nnM
5 Liz Siska Project Manager
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2of23 Final Report 6 nn1nfll1
Liz Siska Project Manager
I
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The sampl~ were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 lE
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure ofaccuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPO) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and defmitions section ofthe following report middot
Chain or Custody Record amp Laboratory Analysis Request - tla WI 981092-0Z~shyPir Water Sediments Plant and Animal Tissue 07558 205-622-amp0
W6middot622-6100Hydroa1rbon Bo Other Samples ~NT~ w1r1lMJ9nii1~StQ11 ( J 0 ti A l Si C I f N t ( i
i C-3oY~ 2
--3
_ 6
l ~ 8
9
- -~~ 1middot
12
12 -02 - 0
I
- shy - middoti middot-middot- f
- 1- middot-middot bull middot 1
httpbullww FrontlcrGScon
Sanpk Dbullsoosal Uy gg vau d~lar Chat you aqrce with FGS turr~ rgtltJ COldbullt10lt1 1(11 thtl O Return l~hi11png lcfS moy gtPll11middotl Vo ~uthorlze lGS to 1)111orm the spedllcd a-lyscs I Q Strd~rltl OisPOsal bull JO Days 111_ bull~l)Ort D Rct for __ wee~~ _itcr 1lJgtObullt (storage r~s m~y ~pply) USt(raquoJl(l( AgtPOVhl - -bull bullbull bull - _-0DlC bull
1
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
CHAIN OF CUSTODY FORMS
Page3of23 Finalampportnn1nn1
7 Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBA L SCIENCES
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsentirety
Liz Siska Project Manager
middot1 414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 04 40 microgL I F20213l 2Bl80I6 021712 EPA2008 Mod u Arsenic ND 005 015 microgL 1 F20213l 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0004 0020 microgL F202215 2B2l010 022112 EPA 2008 Mod u Chromium ND 0009 OiO microgL F202131 2Bl8016 021712 EPA2008Mod u Copper ND 001 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod QM-12 U
Lead ND 0004 0040 microgL l F202131 2Bl8016 021712 EPA2008 Mod u Manganese ND 0007 010 microgL 1 F20213I 2Bl8016 021712 EPA 2008 Mod u Mercury ND 008 -050 ngL F202196 2B17024 021712 EPA 1631E u Molybdenum ND 0006 006 microgL F202131 2BJ8016 021712 EPA 2008 Mod u Nickel ND 0008 010 microgL l F202I3l 2B18016 021712 EPA 2008 Mod u Seleniwn ND 019 060 microgL 1 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U
Silver ND 0006 0020 microgL I F202149 2B15001 021412 EPA 2008 Mod QM-12 U
Zinc ND 002 020 microgL l F202215 2B21010 022112 EPA 2008 Mod u
Page 4 o23 Final Report 8 1nn11n
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Treat Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Alwninwn ND 222 200 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Arsenic ND 255 750 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0208 100 microgL 50 F202215 2B21010 022112 EPA 2008 Mod u Chromium ND 045 500 microgL 50 F202131 2Bl8016 021712 EPA2008 Mod u Copper ND 050 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U Lead ND 0195 200 microgL 50 F202131 2Bl80I6 021712 EPA 2008 Mod u Manganese 1730 037 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Mercury 209 017 101 ngL 2 F202196 2BI7024 021712 EPA 1631E Molybdenum 110 030 300 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Nickel 126 040 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Selenium 822 969 300 microgL 50 F202131 2B24005 022312 EPA 2008 Mod Silver ND 0300 100 microgL 50 F202149 2Bl5001 021412 EPA 2008 Mod QM-12 U Zinc ND 082 100 microgL 50 F202215 2B2I010 022112 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced i11 its entirety
Page 5 o23 Final Report 9 nn11n1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
bull ~ Fx 206-622-6870 GLOBAL SCIENCE S
MATRIX DUPLICATESTRIPLICATES
SOURCE 1202140-02RE1
Batch F202196 Sequence 2BI7024
Preparation BrCl Oxidation Lab Number F202196-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes
Mercury 2434 2257 101 752 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to lhe samples analyzed in accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6 o23 Final Report 10 mn1nn1
Liz Siska Project Manager
Frontier Global Sciences Inc The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must b reproducd In Its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 2Bl~Q16
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2021 31-MSMSDI
Aoalyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(pgL)
MS
Recovery Recovery
Method Limits Notes
Aluminum 484 15150 1999 100 70 - 130 EPA 2008 Mod
Chromium 107 70700 866 107 70- 130 EPA2008 Mod
Manganese 1735 60600 1712 -373 70 bull 130 EPA 2008 Mod QM-02 Nickel 1262 40400 1766 125 70 - 130 EPA 2008 Mod
Copper 083 40400 507 105 70 - 130 EPA 2008 Mod
Zinc 232 10100 8169 786 70 - 130 EPA 2008 Mod QM-07 Arsenic 561 15150 2194 108 70 - 130 EPA 2008 Mod
Selenium 9717 30300 1230 852 70 bull 130 EPA2008 Mod Molybdenum 110l 20200 1115 719 70 bull 130 EPA 2008 Mod
Lead ND 15150 1567 103 70 bull 130 EPA2008 Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15150 2032 102 164 70- 130 20 EPA 2008 Mod Chromium 70700 856 106 115 70 bull 130 20 EPA 2008 Mod Manganese 60600 1727 -131 0852 70 - 130 20 EPA 2008 Mod QM-02 Nickel 40400 1618 88l 876 70 - 130 20 EPA 2008 Mod Copper 40400 484 993 459 70 - 130 20 EPA 2008 Mod Zinc 10100 1688 144 131 70 - 130 20 EPA 2008 Mod QM-07
QR-08 Arsenic 15150 2485 127 124 70 - 130 20 EPA 2008 Mod Selenium 30300 1351 125 938 70- 130 20 EPA2008 Mod Molybdenum 20200 1125 119 0846 70- 130 20 EPA 2008 Mod Lead 15150 1468 969 656 70 - 130 20 EPA 2008 Mod
Page 7of23 Final Rtport 11 nnn rr
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F20213l Sequence 2BI8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-MSMSD2
Aoalyte
Sample Cqocentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 484 10100 10380 102 70 - 130 EPA 2008 Mod AS
Chromium 107 10100 1060 105 70 - 130 EPA 2008 Mod AS
Manganese 1735 10100 2770 102 70 - 130 EPA 2008 Mod AS
Nickel 1262 12625 1303 102 70 - 130 EPA 2008 Mod AS
Copper 083 12625 1253 992 70 - 130 EPA 2008 Mod AS
Zinc 232 25250 2530 100 70 - 130 EPA 2008 Mod AS
Arsenic 561 10100 1073 106 70 - 130 EPA 2008 Mod AS
Selenium 9717 10100 1127 102 70- 130 EPA2008 Mod AS
Molybdenum 1101 50500 6305 103 70 - 130 EPA 2008 Mod AS
Lead ND 25250 2514 995 70 - 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(JtgL)
MSO
Recovery
Oo
RPO Recovery
Limits RPO Limit Method Notes
Aluminwn 10100 10120 998 252 70 - 130 20 EPA 2008 Mod AS
Chromium 10100 1050 104 0947 70- 130 20 EPA 2008 Mod AS
Manganese 10100 2755 101 0548 70 - 130 20 EPA 2008 Mod AS
Nickel 12625 1302 102 0101 70 - 130 20 EPA 2008 Mod AS
Copper 12625 1258 996 0384 70- 130 20 EPA 2008 Mod AS
Zinc 25250 25ll 993 0770 70- 130 20 EPA 2008 Mod AS
Arsenic 10100 1092 108 173 70- 130 20 EPA 2008 Mod AS
Selenium 10100 1169 106 369 70 - 130 20 EPA2008Mod AS
Molybdenum 50500 6168 100 218 70 - 130 20 EPA 2008 Mod AS
Lead 25250 2499 990 0581 70- 130 20 EPA 2008 Mod AS
Page8of23 Final Report 12 nn7nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 2of23 Final Report 6 nn1nfll1
Liz Siska Project Manager
I
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The sampl~ were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 200 8 (modified)
Samples were prepared and analyzed for total mercury in accordance with EPA Method 163 lE
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure ofaccuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RPO) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and defmitions section ofthe following report middot
Chain or Custody Record amp Laboratory Analysis Request - tla WI 981092-0Z~shyPir Water Sediments Plant and Animal Tissue 07558 205-622-amp0
W6middot622-6100Hydroa1rbon Bo Other Samples ~NT~ w1r1lMJ9nii1~StQ11 ( J 0 ti A l Si C I f N t ( i
i C-3oY~ 2
--3
_ 6
l ~ 8
9
- -~~ 1middot
12
12 -02 - 0
I
- shy - middoti middot-middot- f
- 1- middot-middot bull middot 1
httpbullww FrontlcrGScon
Sanpk Dbullsoosal Uy gg vau d~lar Chat you aqrce with FGS turr~ rgtltJ COldbullt10lt1 1(11 thtl O Return l~hi11png lcfS moy gtPll11middotl Vo ~uthorlze lGS to 1)111orm the spedllcd a-lyscs I Q Strd~rltl OisPOsal bull JO Days 111_ bull~l)Ort D Rct for __ wee~~ _itcr 1lJgtObullt (storage r~s m~y ~pply) USt(raquoJl(l( AgtPOVhl - -bull bullbull bull - _-0DlC bull
1
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
CHAIN OF CUSTODY FORMS
Page3of23 Finalampportnn1nn1
7 Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBA L SCIENCES
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsentirety
Liz Siska Project Manager
middot1 414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 04 40 microgL I F20213l 2Bl80I6 021712 EPA2008 Mod u Arsenic ND 005 015 microgL 1 F20213l 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0004 0020 microgL F202215 2B2l010 022112 EPA 2008 Mod u Chromium ND 0009 OiO microgL F202131 2Bl8016 021712 EPA2008Mod u Copper ND 001 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod QM-12 U
Lead ND 0004 0040 microgL l F202131 2Bl8016 021712 EPA2008 Mod u Manganese ND 0007 010 microgL 1 F20213I 2Bl8016 021712 EPA 2008 Mod u Mercury ND 008 -050 ngL F202196 2B17024 021712 EPA 1631E u Molybdenum ND 0006 006 microgL F202131 2BJ8016 021712 EPA 2008 Mod u Nickel ND 0008 010 microgL l F202I3l 2B18016 021712 EPA 2008 Mod u Seleniwn ND 019 060 microgL 1 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U
Silver ND 0006 0020 microgL I F202149 2B15001 021412 EPA 2008 Mod QM-12 U
Zinc ND 002 020 microgL l F202215 2B21010 022112 EPA 2008 Mod u
Page 4 o23 Final Report 8 1nn11n
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Treat Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Alwninwn ND 222 200 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Arsenic ND 255 750 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0208 100 microgL 50 F202215 2B21010 022112 EPA 2008 Mod u Chromium ND 045 500 microgL 50 F202131 2Bl8016 021712 EPA2008 Mod u Copper ND 050 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U Lead ND 0195 200 microgL 50 F202131 2Bl80I6 021712 EPA 2008 Mod u Manganese 1730 037 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Mercury 209 017 101 ngL 2 F202196 2BI7024 021712 EPA 1631E Molybdenum 110 030 300 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Nickel 126 040 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Selenium 822 969 300 microgL 50 F202131 2B24005 022312 EPA 2008 Mod Silver ND 0300 100 microgL 50 F202149 2Bl5001 021412 EPA 2008 Mod QM-12 U Zinc ND 082 100 microgL 50 F202215 2B2I010 022112 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced i11 its entirety
Page 5 o23 Final Report 9 nn11n1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
bull ~ Fx 206-622-6870 GLOBAL SCIENCE S
MATRIX DUPLICATESTRIPLICATES
SOURCE 1202140-02RE1
Batch F202196 Sequence 2BI7024
Preparation BrCl Oxidation Lab Number F202196-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes
Mercury 2434 2257 101 752 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to lhe samples analyzed in accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6 o23 Final Report 10 mn1nn1
Liz Siska Project Manager
Frontier Global Sciences Inc The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must b reproducd In Its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 2Bl~Q16
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2021 31-MSMSDI
Aoalyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(pgL)
MS
Recovery Recovery
Method Limits Notes
Aluminum 484 15150 1999 100 70 - 130 EPA 2008 Mod
Chromium 107 70700 866 107 70- 130 EPA2008 Mod
Manganese 1735 60600 1712 -373 70 bull 130 EPA 2008 Mod QM-02 Nickel 1262 40400 1766 125 70 - 130 EPA 2008 Mod
Copper 083 40400 507 105 70 - 130 EPA 2008 Mod
Zinc 232 10100 8169 786 70 - 130 EPA 2008 Mod QM-07 Arsenic 561 15150 2194 108 70 - 130 EPA 2008 Mod
Selenium 9717 30300 1230 852 70 bull 130 EPA2008 Mod Molybdenum 110l 20200 1115 719 70 bull 130 EPA 2008 Mod
Lead ND 15150 1567 103 70 bull 130 EPA2008 Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15150 2032 102 164 70- 130 20 EPA 2008 Mod Chromium 70700 856 106 115 70 bull 130 20 EPA 2008 Mod Manganese 60600 1727 -131 0852 70 - 130 20 EPA 2008 Mod QM-02 Nickel 40400 1618 88l 876 70 - 130 20 EPA 2008 Mod Copper 40400 484 993 459 70 - 130 20 EPA 2008 Mod Zinc 10100 1688 144 131 70 - 130 20 EPA 2008 Mod QM-07
QR-08 Arsenic 15150 2485 127 124 70 - 130 20 EPA 2008 Mod Selenium 30300 1351 125 938 70- 130 20 EPA2008 Mod Molybdenum 20200 1125 119 0846 70- 130 20 EPA 2008 Mod Lead 15150 1468 969 656 70 - 130 20 EPA 2008 Mod
Page 7of23 Final Rtport 11 nnn rr
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F20213l Sequence 2BI8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-MSMSD2
Aoalyte
Sample Cqocentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 484 10100 10380 102 70 - 130 EPA 2008 Mod AS
Chromium 107 10100 1060 105 70 - 130 EPA 2008 Mod AS
Manganese 1735 10100 2770 102 70 - 130 EPA 2008 Mod AS
Nickel 1262 12625 1303 102 70 - 130 EPA 2008 Mod AS
Copper 083 12625 1253 992 70 - 130 EPA 2008 Mod AS
Zinc 232 25250 2530 100 70 - 130 EPA 2008 Mod AS
Arsenic 561 10100 1073 106 70 - 130 EPA 2008 Mod AS
Selenium 9717 10100 1127 102 70- 130 EPA2008 Mod AS
Molybdenum 1101 50500 6305 103 70 - 130 EPA 2008 Mod AS
Lead ND 25250 2514 995 70 - 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(JtgL)
MSO
Recovery
Oo
RPO Recovery
Limits RPO Limit Method Notes
Aluminwn 10100 10120 998 252 70 - 130 20 EPA 2008 Mod AS
Chromium 10100 1050 104 0947 70- 130 20 EPA 2008 Mod AS
Manganese 10100 2755 101 0548 70 - 130 20 EPA 2008 Mod AS
Nickel 12625 1302 102 0101 70 - 130 20 EPA 2008 Mod AS
Copper 12625 1258 996 0384 70- 130 20 EPA 2008 Mod AS
Zinc 25250 25ll 993 0770 70- 130 20 EPA 2008 Mod AS
Arsenic 10100 1092 108 173 70- 130 20 EPA 2008 Mod AS
Selenium 10100 1169 106 369 70 - 130 20 EPA2008Mod AS
Molybdenum 50500 6168 100 218 70 - 130 20 EPA 2008 Mod AS
Lead 25250 2499 990 0581 70- 130 20 EPA 2008 Mod AS
Page8of23 Final Report 12 nn7nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
Chain or Custody Record amp Laboratory Analysis Request - tla WI 981092-0Z~shyPir Water Sediments Plant and Animal Tissue 07558 205-622-amp0
W6middot622-6100Hydroa1rbon Bo Other Samples ~NT~ w1r1lMJ9nii1~StQ11 ( J 0 ti A l Si C I f N t ( i
i C-3oY~ 2
--3
_ 6
l ~ 8
9
- -~~ 1middot
12
12 -02 - 0
I
- shy - middoti middot-middot- f
- 1- middot-middot bull middot 1
httpbullww FrontlcrGScon
Sanpk Dbullsoosal Uy gg vau d~lar Chat you aqrce with FGS turr~ rgtltJ COldbullt10lt1 1(11 thtl O Return l~hi11png lcfS moy gtPll11middotl Vo ~uthorlze lGS to 1)111orm the spedllcd a-lyscs I Q Strd~rltl OisPOsal bull JO Days 111_ bull~l)Ort D Rct for __ wee~~ _itcr 1lJgtObullt (storage r~s m~y ~pply) USt(raquoJl(l( AgtPOVhl - -bull bullbull bull - _-0DlC bull
1
The results in this report only apply to the samples analyzed in accordance with theFrontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
CHAIN OF CUSTODY FORMS
Page3of23 Finalampportnn1nn1
7 Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBA L SCIENCES
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsentirety
Liz Siska Project Manager
middot1 414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 04 40 microgL I F20213l 2Bl80I6 021712 EPA2008 Mod u Arsenic ND 005 015 microgL 1 F20213l 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0004 0020 microgL F202215 2B2l010 022112 EPA 2008 Mod u Chromium ND 0009 OiO microgL F202131 2Bl8016 021712 EPA2008Mod u Copper ND 001 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod QM-12 U
Lead ND 0004 0040 microgL l F202131 2Bl8016 021712 EPA2008 Mod u Manganese ND 0007 010 microgL 1 F20213I 2Bl8016 021712 EPA 2008 Mod u Mercury ND 008 -050 ngL F202196 2B17024 021712 EPA 1631E u Molybdenum ND 0006 006 microgL F202131 2BJ8016 021712 EPA 2008 Mod u Nickel ND 0008 010 microgL l F202I3l 2B18016 021712 EPA 2008 Mod u Seleniwn ND 019 060 microgL 1 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U
Silver ND 0006 0020 microgL I F202149 2B15001 021412 EPA 2008 Mod QM-12 U
Zinc ND 002 020 microgL l F202215 2B21010 022112 EPA 2008 Mod u
Page 4 o23 Final Report 8 1nn11n
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Treat Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Alwninwn ND 222 200 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Arsenic ND 255 750 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0208 100 microgL 50 F202215 2B21010 022112 EPA 2008 Mod u Chromium ND 045 500 microgL 50 F202131 2Bl8016 021712 EPA2008 Mod u Copper ND 050 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U Lead ND 0195 200 microgL 50 F202131 2Bl80I6 021712 EPA 2008 Mod u Manganese 1730 037 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Mercury 209 017 101 ngL 2 F202196 2BI7024 021712 EPA 1631E Molybdenum 110 030 300 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Nickel 126 040 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Selenium 822 969 300 microgL 50 F202131 2B24005 022312 EPA 2008 Mod Silver ND 0300 100 microgL 50 F202149 2Bl5001 021412 EPA 2008 Mod QM-12 U Zinc ND 082 100 microgL 50 F202215 2B2I010 022112 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced i11 its entirety
Page 5 o23 Final Report 9 nn11n1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
bull ~ Fx 206-622-6870 GLOBAL SCIENCE S
MATRIX DUPLICATESTRIPLICATES
SOURCE 1202140-02RE1
Batch F202196 Sequence 2BI7024
Preparation BrCl Oxidation Lab Number F202196-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes
Mercury 2434 2257 101 752 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to lhe samples analyzed in accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6 o23 Final Report 10 mn1nn1
Liz Siska Project Manager
Frontier Global Sciences Inc The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must b reproducd In Its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 2Bl~Q16
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2021 31-MSMSDI
Aoalyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(pgL)
MS
Recovery Recovery
Method Limits Notes
Aluminum 484 15150 1999 100 70 - 130 EPA 2008 Mod
Chromium 107 70700 866 107 70- 130 EPA2008 Mod
Manganese 1735 60600 1712 -373 70 bull 130 EPA 2008 Mod QM-02 Nickel 1262 40400 1766 125 70 - 130 EPA 2008 Mod
Copper 083 40400 507 105 70 - 130 EPA 2008 Mod
Zinc 232 10100 8169 786 70 - 130 EPA 2008 Mod QM-07 Arsenic 561 15150 2194 108 70 - 130 EPA 2008 Mod
Selenium 9717 30300 1230 852 70 bull 130 EPA2008 Mod Molybdenum 110l 20200 1115 719 70 bull 130 EPA 2008 Mod
Lead ND 15150 1567 103 70 bull 130 EPA2008 Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15150 2032 102 164 70- 130 20 EPA 2008 Mod Chromium 70700 856 106 115 70 bull 130 20 EPA 2008 Mod Manganese 60600 1727 -131 0852 70 - 130 20 EPA 2008 Mod QM-02 Nickel 40400 1618 88l 876 70 - 130 20 EPA 2008 Mod Copper 40400 484 993 459 70 - 130 20 EPA 2008 Mod Zinc 10100 1688 144 131 70 - 130 20 EPA 2008 Mod QM-07
QR-08 Arsenic 15150 2485 127 124 70 - 130 20 EPA 2008 Mod Selenium 30300 1351 125 938 70- 130 20 EPA2008 Mod Molybdenum 20200 1125 119 0846 70- 130 20 EPA 2008 Mod Lead 15150 1468 969 656 70 - 130 20 EPA 2008 Mod
Page 7of23 Final Rtport 11 nnn rr
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F20213l Sequence 2BI8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-MSMSD2
Aoalyte
Sample Cqocentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 484 10100 10380 102 70 - 130 EPA 2008 Mod AS
Chromium 107 10100 1060 105 70 - 130 EPA 2008 Mod AS
Manganese 1735 10100 2770 102 70 - 130 EPA 2008 Mod AS
Nickel 1262 12625 1303 102 70 - 130 EPA 2008 Mod AS
Copper 083 12625 1253 992 70 - 130 EPA 2008 Mod AS
Zinc 232 25250 2530 100 70 - 130 EPA 2008 Mod AS
Arsenic 561 10100 1073 106 70 - 130 EPA 2008 Mod AS
Selenium 9717 10100 1127 102 70- 130 EPA2008 Mod AS
Molybdenum 1101 50500 6305 103 70 - 130 EPA 2008 Mod AS
Lead ND 25250 2514 995 70 - 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(JtgL)
MSO
Recovery
Oo
RPO Recovery
Limits RPO Limit Method Notes
Aluminwn 10100 10120 998 252 70 - 130 20 EPA 2008 Mod AS
Chromium 10100 1050 104 0947 70- 130 20 EPA 2008 Mod AS
Manganese 10100 2755 101 0548 70 - 130 20 EPA 2008 Mod AS
Nickel 12625 1302 102 0101 70 - 130 20 EPA 2008 Mod AS
Copper 12625 1258 996 0384 70- 130 20 EPA 2008 Mod AS
Zinc 25250 25ll 993 0770 70- 130 20 EPA 2008 Mod AS
Arsenic 10100 1092 108 173 70- 130 20 EPA 2008 Mod AS
Selenium 10100 1169 106 369 70 - 130 20 EPA2008Mod AS
Molybdenum 50500 6168 100 218 70 - 130 20 EPA 2008 Mod AS
Lead 25250 2499 990 0581 70- 130 20 EPA 2008 Mod AS
Page8of23 Final Report 12 nn7nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsentirety
Liz Siska Project Manager
middot1 414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Aluminum ND 04 40 microgL I F20213l 2Bl80I6 021712 EPA2008 Mod u Arsenic ND 005 015 microgL 1 F20213l 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0004 0020 microgL F202215 2B2l010 022112 EPA 2008 Mod u Chromium ND 0009 OiO microgL F202131 2Bl8016 021712 EPA2008Mod u Copper ND 001 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod QM-12 U
Lead ND 0004 0040 microgL l F202131 2Bl8016 021712 EPA2008 Mod u Manganese ND 0007 010 microgL 1 F20213I 2Bl8016 021712 EPA 2008 Mod u Mercury ND 008 -050 ngL F202196 2B17024 021712 EPA 1631E u Molybdenum ND 0006 006 microgL F202131 2BJ8016 021712 EPA 2008 Mod u Nickel ND 0008 010 microgL l F202I3l 2B18016 021712 EPA 2008 Mod u Seleniwn ND 019 060 microgL 1 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U
Silver ND 0006 0020 microgL I F202149 2B15001 021412 EPA 2008 Mod QM-12 U
Zinc ND 002 020 microgL l F202215 2B21010 022112 EPA 2008 Mod u
Page 4 o23 Final Report 8 1nn11n
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Treat Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Alwninwn ND 222 200 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Arsenic ND 255 750 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0208 100 microgL 50 F202215 2B21010 022112 EPA 2008 Mod u Chromium ND 045 500 microgL 50 F202131 2Bl8016 021712 EPA2008 Mod u Copper ND 050 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U Lead ND 0195 200 microgL 50 F202131 2Bl80I6 021712 EPA 2008 Mod u Manganese 1730 037 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Mercury 209 017 101 ngL 2 F202196 2BI7024 021712 EPA 1631E Molybdenum 110 030 300 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Nickel 126 040 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Selenium 822 969 300 microgL 50 F202131 2B24005 022312 EPA 2008 Mod Silver ND 0300 100 microgL 50 F202149 2Bl5001 021412 EPA 2008 Mod QM-12 U Zinc ND 082 100 microgL 50 F202215 2B2I010 022112 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced i11 its entirety
Page 5 o23 Final Report 9 nn11n1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
bull ~ Fx 206-622-6870 GLOBAL SCIENCE S
MATRIX DUPLICATESTRIPLICATES
SOURCE 1202140-02RE1
Batch F202196 Sequence 2BI7024
Preparation BrCl Oxidation Lab Number F202196-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes
Mercury 2434 2257 101 752 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to lhe samples analyzed in accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6 o23 Final Report 10 mn1nn1
Liz Siska Project Manager
Frontier Global Sciences Inc The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must b reproducd In Its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 2Bl~Q16
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2021 31-MSMSDI
Aoalyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(pgL)
MS
Recovery Recovery
Method Limits Notes
Aluminum 484 15150 1999 100 70 - 130 EPA 2008 Mod
Chromium 107 70700 866 107 70- 130 EPA2008 Mod
Manganese 1735 60600 1712 -373 70 bull 130 EPA 2008 Mod QM-02 Nickel 1262 40400 1766 125 70 - 130 EPA 2008 Mod
Copper 083 40400 507 105 70 - 130 EPA 2008 Mod
Zinc 232 10100 8169 786 70 - 130 EPA 2008 Mod QM-07 Arsenic 561 15150 2194 108 70 - 130 EPA 2008 Mod
Selenium 9717 30300 1230 852 70 bull 130 EPA2008 Mod Molybdenum 110l 20200 1115 719 70 bull 130 EPA 2008 Mod
Lead ND 15150 1567 103 70 bull 130 EPA2008 Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15150 2032 102 164 70- 130 20 EPA 2008 Mod Chromium 70700 856 106 115 70 bull 130 20 EPA 2008 Mod Manganese 60600 1727 -131 0852 70 - 130 20 EPA 2008 Mod QM-02 Nickel 40400 1618 88l 876 70 - 130 20 EPA 2008 Mod Copper 40400 484 993 459 70 - 130 20 EPA 2008 Mod Zinc 10100 1688 144 131 70 - 130 20 EPA 2008 Mod QM-07
QR-08 Arsenic 15150 2485 127 124 70 - 130 20 EPA 2008 Mod Selenium 30300 1351 125 938 70- 130 20 EPA2008 Mod Molybdenum 20200 1125 119 0846 70- 130 20 EPA 2008 Mod Lead 15150 1468 969 656 70 - 130 20 EPA 2008 Mod
Page 7of23 Final Rtport 11 nnn rr
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F20213l Sequence 2BI8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-MSMSD2
Aoalyte
Sample Cqocentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 484 10100 10380 102 70 - 130 EPA 2008 Mod AS
Chromium 107 10100 1060 105 70 - 130 EPA 2008 Mod AS
Manganese 1735 10100 2770 102 70 - 130 EPA 2008 Mod AS
Nickel 1262 12625 1303 102 70 - 130 EPA 2008 Mod AS
Copper 083 12625 1253 992 70 - 130 EPA 2008 Mod AS
Zinc 232 25250 2530 100 70 - 130 EPA 2008 Mod AS
Arsenic 561 10100 1073 106 70 - 130 EPA 2008 Mod AS
Selenium 9717 10100 1127 102 70- 130 EPA2008 Mod AS
Molybdenum 1101 50500 6305 103 70 - 130 EPA 2008 Mod AS
Lead ND 25250 2514 995 70 - 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(JtgL)
MSO
Recovery
Oo
RPO Recovery
Limits RPO Limit Method Notes
Aluminwn 10100 10120 998 252 70 - 130 20 EPA 2008 Mod AS
Chromium 10100 1050 104 0947 70- 130 20 EPA 2008 Mod AS
Manganese 10100 2755 101 0548 70 - 130 20 EPA 2008 Mod AS
Nickel 12625 1302 102 0101 70 - 130 20 EPA 2008 Mod AS
Copper 12625 1258 996 0384 70- 130 20 EPA 2008 Mod AS
Zinc 25250 25ll 993 0770 70- 130 20 EPA 2008 Mod AS
Arsenic 10100 1092 108 173 70- 130 20 EPA 2008 Mod AS
Selenium 10100 1169 106 369 70 - 130 20 EPA2008Mod AS
Molybdenum 50500 6168 100 218 70 - 130 20 EPA 2008 Mod AS
Lead 25250 2499 990 0581 70- 130 20 EPA 2008 Mod AS
Page8of23 Final Report 12 nn7nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Treat Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Alwninwn ND 222 200 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Arsenic ND 255 750 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod u Cadmium ND 0208 100 microgL 50 F202215 2B21010 022112 EPA 2008 Mod u Chromium ND 045 500 microgL 50 F202131 2Bl8016 021712 EPA2008 Mod u Copper ND 050 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod QM-12 U Lead ND 0195 200 microgL 50 F202131 2Bl80I6 021712 EPA 2008 Mod u Manganese 1730 037 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Mercury 209 017 101 ngL 2 F202196 2BI7024 021712 EPA 1631E Molybdenum 110 030 300 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Nickel 126 040 500 microgL 50 F202131 2Bl8016 021712 EPA 2008 Mod Selenium 822 969 300 microgL 50 F202131 2B24005 022312 EPA 2008 Mod Silver ND 0300 100 microgL 50 F202149 2Bl5001 021412 EPA 2008 Mod QM-12 U Zinc ND 082 100 microgL 50 F202215 2B2I010 022112 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced i11 its entirety
Page 5 o23 Final Report 9 nn11n1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
bull ~ Fx 206-622-6870 GLOBAL SCIENCE S
MATRIX DUPLICATESTRIPLICATES
SOURCE 1202140-02RE1
Batch F202196 Sequence 2BI7024
Preparation BrCl Oxidation Lab Number F202196-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes
Mercury 2434 2257 101 752 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to lhe samples analyzed in accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6 o23 Final Report 10 mn1nn1
Liz Siska Project Manager
Frontier Global Sciences Inc The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must b reproducd In Its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 2Bl~Q16
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2021 31-MSMSDI
Aoalyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(pgL)
MS
Recovery Recovery
Method Limits Notes
Aluminum 484 15150 1999 100 70 - 130 EPA 2008 Mod
Chromium 107 70700 866 107 70- 130 EPA2008 Mod
Manganese 1735 60600 1712 -373 70 bull 130 EPA 2008 Mod QM-02 Nickel 1262 40400 1766 125 70 - 130 EPA 2008 Mod
Copper 083 40400 507 105 70 - 130 EPA 2008 Mod
Zinc 232 10100 8169 786 70 - 130 EPA 2008 Mod QM-07 Arsenic 561 15150 2194 108 70 - 130 EPA 2008 Mod
Selenium 9717 30300 1230 852 70 bull 130 EPA2008 Mod Molybdenum 110l 20200 1115 719 70 bull 130 EPA 2008 Mod
Lead ND 15150 1567 103 70 bull 130 EPA2008 Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15150 2032 102 164 70- 130 20 EPA 2008 Mod Chromium 70700 856 106 115 70 bull 130 20 EPA 2008 Mod Manganese 60600 1727 -131 0852 70 - 130 20 EPA 2008 Mod QM-02 Nickel 40400 1618 88l 876 70 - 130 20 EPA 2008 Mod Copper 40400 484 993 459 70 - 130 20 EPA 2008 Mod Zinc 10100 1688 144 131 70 - 130 20 EPA 2008 Mod QM-07
QR-08 Arsenic 15150 2485 127 124 70 - 130 20 EPA 2008 Mod Selenium 30300 1351 125 938 70- 130 20 EPA2008 Mod Molybdenum 20200 1125 119 0846 70- 130 20 EPA 2008 Mod Lead 15150 1468 969 656 70 - 130 20 EPA 2008 Mod
Page 7of23 Final Rtport 11 nnn rr
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F20213l Sequence 2BI8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-MSMSD2
Aoalyte
Sample Cqocentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 484 10100 10380 102 70 - 130 EPA 2008 Mod AS
Chromium 107 10100 1060 105 70 - 130 EPA 2008 Mod AS
Manganese 1735 10100 2770 102 70 - 130 EPA 2008 Mod AS
Nickel 1262 12625 1303 102 70 - 130 EPA 2008 Mod AS
Copper 083 12625 1253 992 70 - 130 EPA 2008 Mod AS
Zinc 232 25250 2530 100 70 - 130 EPA 2008 Mod AS
Arsenic 561 10100 1073 106 70 - 130 EPA 2008 Mod AS
Selenium 9717 10100 1127 102 70- 130 EPA2008 Mod AS
Molybdenum 1101 50500 6305 103 70 - 130 EPA 2008 Mod AS
Lead ND 25250 2514 995 70 - 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(JtgL)
MSO
Recovery
Oo
RPO Recovery
Limits RPO Limit Method Notes
Aluminwn 10100 10120 998 252 70 - 130 20 EPA 2008 Mod AS
Chromium 10100 1050 104 0947 70- 130 20 EPA 2008 Mod AS
Manganese 10100 2755 101 0548 70 - 130 20 EPA 2008 Mod AS
Nickel 12625 1302 102 0101 70 - 130 20 EPA 2008 Mod AS
Copper 12625 1258 996 0384 70- 130 20 EPA 2008 Mod AS
Zinc 25250 25ll 993 0770 70- 130 20 EPA 2008 Mod AS
Arsenic 10100 1092 108 173 70- 130 20 EPA 2008 Mod AS
Selenium 10100 1169 106 369 70 - 130 20 EPA2008Mod AS
Molybdenum 50500 6168 100 218 70 - 130 20 EPA 2008 Mod AS
Lead 25250 2499 990 0581 70- 130 20 EPA 2008 Mod AS
Page8of23 Final Report 12 nn7nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
bull ~ Fx 206-622-6870 GLOBAL SCIENCE S
MATRIX DUPLICATESTRIPLICATES
SOURCE 1202140-02RE1
Batch F202196 Sequence 2BI7024
Preparation BrCl Oxidation Lab Number F202196-DUPI
Sample Duplicate Concentration Concentration RPD
Analyte ngL ngL MRL RPD Limit Method Notes
Mercury 2434 2257 101 752 24 EPA 1631E
Frontier Global Sciences Inc The results in this report only apply to lhe samples analyzed in accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Page 6 o23 Final Report 10 mn1nn1
Liz Siska Project Manager
Frontier Global Sciences Inc The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must b reproducd In Its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 2Bl~Q16
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2021 31-MSMSDI
Aoalyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(pgL)
MS
Recovery Recovery
Method Limits Notes
Aluminum 484 15150 1999 100 70 - 130 EPA 2008 Mod
Chromium 107 70700 866 107 70- 130 EPA2008 Mod
Manganese 1735 60600 1712 -373 70 bull 130 EPA 2008 Mod QM-02 Nickel 1262 40400 1766 125 70 - 130 EPA 2008 Mod
Copper 083 40400 507 105 70 - 130 EPA 2008 Mod
Zinc 232 10100 8169 786 70 - 130 EPA 2008 Mod QM-07 Arsenic 561 15150 2194 108 70 - 130 EPA 2008 Mod
Selenium 9717 30300 1230 852 70 bull 130 EPA2008 Mod Molybdenum 110l 20200 1115 719 70 bull 130 EPA 2008 Mod
Lead ND 15150 1567 103 70 bull 130 EPA2008 Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15150 2032 102 164 70- 130 20 EPA 2008 Mod Chromium 70700 856 106 115 70 bull 130 20 EPA 2008 Mod Manganese 60600 1727 -131 0852 70 - 130 20 EPA 2008 Mod QM-02 Nickel 40400 1618 88l 876 70 - 130 20 EPA 2008 Mod Copper 40400 484 993 459 70 - 130 20 EPA 2008 Mod Zinc 10100 1688 144 131 70 - 130 20 EPA 2008 Mod QM-07
QR-08 Arsenic 15150 2485 127 124 70 - 130 20 EPA 2008 Mod Selenium 30300 1351 125 938 70- 130 20 EPA2008 Mod Molybdenum 20200 1125 119 0846 70- 130 20 EPA 2008 Mod Lead 15150 1468 969 656 70 - 130 20 EPA 2008 Mod
Page 7of23 Final Rtport 11 nnn rr
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F20213l Sequence 2BI8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-MSMSD2
Aoalyte
Sample Cqocentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 484 10100 10380 102 70 - 130 EPA 2008 Mod AS
Chromium 107 10100 1060 105 70 - 130 EPA 2008 Mod AS
Manganese 1735 10100 2770 102 70 - 130 EPA 2008 Mod AS
Nickel 1262 12625 1303 102 70 - 130 EPA 2008 Mod AS
Copper 083 12625 1253 992 70 - 130 EPA 2008 Mod AS
Zinc 232 25250 2530 100 70 - 130 EPA 2008 Mod AS
Arsenic 561 10100 1073 106 70 - 130 EPA 2008 Mod AS
Selenium 9717 10100 1127 102 70- 130 EPA2008 Mod AS
Molybdenum 1101 50500 6305 103 70 - 130 EPA 2008 Mod AS
Lead ND 25250 2514 995 70 - 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(JtgL)
MSO
Recovery
Oo
RPO Recovery
Limits RPO Limit Method Notes
Aluminwn 10100 10120 998 252 70 - 130 20 EPA 2008 Mod AS
Chromium 10100 1050 104 0947 70- 130 20 EPA 2008 Mod AS
Manganese 10100 2755 101 0548 70 - 130 20 EPA 2008 Mod AS
Nickel 12625 1302 102 0101 70 - 130 20 EPA 2008 Mod AS
Copper 12625 1258 996 0384 70- 130 20 EPA 2008 Mod AS
Zinc 25250 25ll 993 0770 70- 130 20 EPA 2008 Mod AS
Arsenic 10100 1092 108 173 70- 130 20 EPA 2008 Mod AS
Selenium 10100 1169 106 369 70 - 130 20 EPA2008Mod AS
Molybdenum 50500 6168 100 218 70 - 130 20 EPA 2008 Mod AS
Lead 25250 2499 990 0581 70- 130 20 EPA 2008 Mod AS
Page8of23 Final Report 12 nn7nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
Frontier Global Sciences Inc The results In this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must b reproducd In Its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 2Bl~Q16
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2021 31-MSMSDI
Aoalyte
Sample Concentration
(microgL)
Spike Added (microgL)
MS Concentration
(pgL)
MS
Recovery Recovery
Method Limits Notes
Aluminum 484 15150 1999 100 70 - 130 EPA 2008 Mod
Chromium 107 70700 866 107 70- 130 EPA2008 Mod
Manganese 1735 60600 1712 -373 70 bull 130 EPA 2008 Mod QM-02 Nickel 1262 40400 1766 125 70 - 130 EPA 2008 Mod
Copper 083 40400 507 105 70 - 130 EPA 2008 Mod
Zinc 232 10100 8169 786 70 - 130 EPA 2008 Mod QM-07 Arsenic 561 15150 2194 108 70 - 130 EPA 2008 Mod
Selenium 9717 30300 1230 852 70 bull 130 EPA2008 Mod Molybdenum 110l 20200 1115 719 70 bull 130 EPA 2008 Mod
Lead ND 15150 1567 103 70 bull 130 EPA2008 Mod
Analyte
Spike Added (microgL)
MSD Concentration
(microgL)
MSD
Recovery
Oo
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15150 2032 102 164 70- 130 20 EPA 2008 Mod Chromium 70700 856 106 115 70 bull 130 20 EPA 2008 Mod Manganese 60600 1727 -131 0852 70 - 130 20 EPA 2008 Mod QM-02 Nickel 40400 1618 88l 876 70 - 130 20 EPA 2008 Mod Copper 40400 484 993 459 70 - 130 20 EPA 2008 Mod Zinc 10100 1688 144 131 70 - 130 20 EPA 2008 Mod QM-07
QR-08 Arsenic 15150 2485 127 124 70 - 130 20 EPA 2008 Mod Selenium 30300 1351 125 938 70- 130 20 EPA2008 Mod Molybdenum 20200 1125 119 0846 70- 130 20 EPA 2008 Mod Lead 15150 1468 969 656 70 - 130 20 EPA 2008 Mod
Page 7of23 Final Rtport 11 nnn rr
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F20213l Sequence 2BI8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-MSMSD2
Aoalyte
Sample Cqocentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 484 10100 10380 102 70 - 130 EPA 2008 Mod AS
Chromium 107 10100 1060 105 70 - 130 EPA 2008 Mod AS
Manganese 1735 10100 2770 102 70 - 130 EPA 2008 Mod AS
Nickel 1262 12625 1303 102 70 - 130 EPA 2008 Mod AS
Copper 083 12625 1253 992 70 - 130 EPA 2008 Mod AS
Zinc 232 25250 2530 100 70 - 130 EPA 2008 Mod AS
Arsenic 561 10100 1073 106 70 - 130 EPA 2008 Mod AS
Selenium 9717 10100 1127 102 70- 130 EPA2008 Mod AS
Molybdenum 1101 50500 6305 103 70 - 130 EPA 2008 Mod AS
Lead ND 25250 2514 995 70 - 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(JtgL)
MSO
Recovery
Oo
RPO Recovery
Limits RPO Limit Method Notes
Aluminwn 10100 10120 998 252 70 - 130 20 EPA 2008 Mod AS
Chromium 10100 1050 104 0947 70- 130 20 EPA 2008 Mod AS
Manganese 10100 2755 101 0548 70 - 130 20 EPA 2008 Mod AS
Nickel 12625 1302 102 0101 70 - 130 20 EPA 2008 Mod AS
Copper 12625 1258 996 0384 70- 130 20 EPA 2008 Mod AS
Zinc 25250 25ll 993 0770 70- 130 20 EPA 2008 Mod AS
Arsenic 10100 1092 108 173 70- 130 20 EPA 2008 Mod AS
Selenium 10100 1169 106 369 70 - 130 20 EPA2008Mod AS
Molybdenum 50500 6168 100 218 70 - 130 20 EPA 2008 Mod AS
Lead 25250 2499 990 0581 70- 130 20 EPA 2008 Mod AS
Page8of23 Final Report 12 nn7nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F20213l Sequence 2BI8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-MSMSD2
Aoalyte
Sample Cqocentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Aluminum 484 10100 10380 102 70 - 130 EPA 2008 Mod AS
Chromium 107 10100 1060 105 70 - 130 EPA 2008 Mod AS
Manganese 1735 10100 2770 102 70 - 130 EPA 2008 Mod AS
Nickel 1262 12625 1303 102 70 - 130 EPA 2008 Mod AS
Copper 083 12625 1253 992 70 - 130 EPA 2008 Mod AS
Zinc 232 25250 2530 100 70 - 130 EPA 2008 Mod AS
Arsenic 561 10100 1073 106 70 - 130 EPA 2008 Mod AS
Selenium 9717 10100 1127 102 70- 130 EPA2008 Mod AS
Molybdenum 1101 50500 6305 103 70 - 130 EPA 2008 Mod AS
Lead ND 25250 2514 995 70 - 130 EPA 2008 Mod AS
Analyte
Spike Added (microgL)
MSD Concentration
(JtgL)
MSO
Recovery
Oo
RPO Recovery
Limits RPO Limit Method Notes
Aluminwn 10100 10120 998 252 70 - 130 20 EPA 2008 Mod AS
Chromium 10100 1050 104 0947 70- 130 20 EPA 2008 Mod AS
Manganese 10100 2755 101 0548 70 - 130 20 EPA 2008 Mod AS
Nickel 12625 1302 102 0101 70 - 130 20 EPA 2008 Mod AS
Copper 12625 1258 996 0384 70- 130 20 EPA 2008 Mod AS
Zinc 25250 25ll 993 0770 70- 130 20 EPA 2008 Mod AS
Arsenic 10100 1092 108 173 70- 130 20 EPA 2008 Mod AS
Selenium 10100 1169 106 369 70 - 130 20 EPA2008Mod AS
Molybdenum 50500 6168 100 218 70 - 130 20 EPA 2008 Mod AS
Lead 25250 2499 990 0581 70- 130 20 EPA 2008 Mod AS
Page8of23 Final Report 12 nn7nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
CLO BA L SC IE NC ES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149 Sequence 2Bl500I
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-MSMSD1
Sample Spike MS MS Concentration Added Concentration RecoveryAnalyte microgL) (microgL) (microgL) Recovery MethodLimits Notes
Silver ND l5180 1529 101 70- 130 EPA 2008 Mod
Spike MSD MSD Added Concentration Recovery RPD
RPD Limits Limit Analyte microgL) (microgL) Recovery Method Notes
Silver 15180 1577 104 313 70-130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page9of23Final Report 13 mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202149
Preparation Closed Vessel Nitric Oven Digestion
Analyte
Silver
Analyte
Silver
Sample Spike Concentration Addcd
(microgL) (microgL)
ND 50500
MS Concentration
(microgL)
4417
MS
Recovery
875
Recovery Method Limits
70 - 130 EPA 2008 Mod
Notes
AS
Spike MSD Added Concentration (microgL) (microgL)
50500 4381
MSD Oo
RPD Recovery
868 0808
Recovery Limits
70 - 130
RPD Limit Melbod
20 EPA 2008 Mod
Notes
AS
Sequence 2Bl5001
Lab Number F202I49-MSMSD2
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page JOo23 Ftna Report 14 fl71fl1
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA98I09 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202223-02
Batch F202I96 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202 l96-MSMSD1
Analyte
MercUI)
Sample Spike Concentration Added
(ngL) (ngL)
3963 10200
Spike MSD
MS Concentration
(ngL)
1453
MSD
MS
Recovery
104
RecoveryLimits
71 - 125
Method
EPA 1631E
Notes
Added Concentration Recovery RPD Analyte
Mercury
(ngL)
10200
(ngL)
1436
Recovery
102
RPD
l12
Limits
71 - 125
Limit
24
Method
EPA 1631E
Notes
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in Its enJirety
Page 11 o23Final Report 15 fln7nfl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202196 Sequence 2817024
Preparation BrCl Oxidation Lab Number F202196-MSMSD2
Analyte
Sample Concentration
(ogL)
Spike Added ngL)
MS Concentration
(ngL)
MS
Recovery Recovery
Limits Method Notes
Mercwy
Analyte
2434
Spike Added ngL)
71400 9661 101 71- 125 EPA 1631E
MSD Concentration
(ngL)
MSD
RPD Recovery
Recovery Limits
RPD Limit Method Notes
Mercwy 71400 9620 101 0422 71 - 125 24 EPA 1631E
The results in this report only apply to the samples analyzed in accordance wfth the chain of custody document This analytical report must be reproduced in its entirety
Frontier Global Sciences Inc
Page I 2 qf23 Final Report 16n7fl1
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022l5-MSIMSD1
Analyte
Sample Spike Concentration Added
(microgL) (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Method Limits Notes
Zinc ND 10100 965 955 70- 130 EPA 2008 Mod
Cadmium 0216 080800 1142 115 70 - 130 EPA 2008 Mod
Analyte
Spike MSD Added Concentration (microgL) (microgL)
MSD
RPD RecoveryRecovery
Limits RPDLimit Method Notes
Zinc 10100 999 989 347 70 - 130 20 EPA 2008 Mod Cadmium 080800 1189 120 407 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustodydocument 1nisanalytical report must ~ rtproductd In Its entirety
Liz Siska Project Manager Page 13023 Final amppan 17 nn7nn
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed In accordance wfth the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
414 Pontius Ave North
Seattle WA 98109~ Ph 206-622-6960 FRONTR Fx 206-622-6870 GLOBAL SCIENCES
MATRIX SPIKE I MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE1
Batch F202215 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion Lab Number F2022 l 5-MSMSD2
Sample Spike MS MS Concentration Added Concentration Ofo Recovery
Analyte (microgL) (microgL) (microgL) Recovery Method NotesLimits
Zinc ND 25250 2297 910 70 - 130 EPA 2008 Mod AS Cadmium 0216 10100 8731 862 70 - 130 EPA 2008 Mod AS
Spike MSD MSD Added Concentration Oo Recovery RPD
RPD Limits Limit Method Notes(microgL) (microgL) RecoveryAnalyte
Zinc 25250 2300 911 0162 70- 130 20 EPA 2008 Mod AS Cadmium 10100 8953 884 250 70 -130 20 EPA 2008 Mod AS
Page 14 o23 Final Report 18 nn7nt111
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202131 Sequence 2B 18016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSDI
LCS Source Blank SIike
Spike LCS LCS
Analyte
Aluminwn
Added (microgL)
15000
Concentration (microgL)
1459
Recovery
973
RecoveryLimits
85 - 115 E
Method
PA 2008 Mod
Notes
Chromium 70000 694 99l 85 - 115 EPA 2008 Mod Manganese 60000 591 985 85 - 115 EPA 2008 Mod Nickel 40000 419 105 85 - 115 EPA 2008 Mod Copper 40000 440 110 85 - 115 EPA 2008 Mod Zinc 10000 ll13 111 85 - 115 EPA2008 Mod Arsenic 15000 1505 100 85 - 115 EPA 2008 Mod Selenium 30000 3061 102 85 - 115 EPA 2008 Mod Molybdenum 20000 193 966 85 - 115 EPA2008 Mod Lead l5000 l560 104 85 - 115 EPA2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD Oo
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Aluminum 15000 1473 982 0925 85 - 115 20 EPA2008 Mod Chromium
Manganese
Nickel
Copper
Zinc
Arsenic
Selenium
Molybdenum
Lead
70000
60000
40000
40000
10000
15000
30000
20000
15000
694
600
423
443
1092
1483
3203
191
1586
99l
999
106
111
109
989
107
954
106
00117
148
104
0541
197
146
453
117
l66
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 - 115
85 115
85 - 115
20
20
20
20
20
20
middot20
20
20
EPA2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA 2008 Mod
EPA2008 Mod
EPA 2008 Mod
shy
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed i1 accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Sska Project Manager Page 15 o23Final Report 19mn1nn1
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
bull GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202149 Sequence 2Bl5001
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202149-BSBSD1
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS
Recovery Recovery
Limits Method Notes
Silver 15000 1709 114 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Silver 15000 1738 116 l68 85 - 115 20 EPA 2008 Mod QM-12
Frontier Global Sciences Inc The results in this report only apply 10 he samples analyzed in accordance with the chain ofcustody document This analylical report must be reproduced in its entirety
Liz Siska Project Manager Page 16 oj23 Final Report nn1nni
20
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202196 Sequence 2Bl7024
Preparation BrCI Oxidation Lab Number F202196-BSBSD1
LCS Source LCS
Spike LCS LCS Added Concentration Oo Recovery
Analyte (ngL) (ngL) Recovery Limits Method Notes Mercury 15679 1627 bull 104 80 120 EPA 163IE
)
Spike LCSD LCSD Added Concentration Recovery RPD
Analyte ngL) (ngL) Recovery RPD Limits Limit Method Notes Mercury 15679 1620 103 0396 80 - 120 24 EPA 1631E
shy
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page 17 o23 Final Report 21 n1nl
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPD
Batch F202215 Sequence 2B2l0IO
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202215-BSBSDI
LCS Source Blank Spike
Analyte
Spike Added (microgL)
LCS Concentration
(JlgL)
LCS
Recovery Recovery
Limits Method Notes
Zinc 10000 999 999 85 - 115 EPA 2008 Mod
Cadmium 080000 0892 112 85 - 115 EPA 2008 Mod
Analyte
Spike Added (microgL)
LCSD Concentration
(JlgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Zinc 10000 993 993 0528 85 bull 115 20 EPA2008 Mod
Cadmium 080000 0897 112 0517 85 - 115 20 EPA 2008 Mod
Frontier Global Sciences Inc The resuits in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 18oj23 Final Report 22 n7nl
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960
FRONTIER- Fx 206-622-6870 cioaAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2815001
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202 l 49-BLK 1 Silver -00002 0020 microgL F202149 ~PA 2008 Molt
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in ace-0rdance with the chain ofcustody document This analytical report must be reproductd In Its t nJirety
Liz Siska Project Manager Pagel9of23 Finalampport 23 n1n 1n n1
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
FRONTIE~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument Hg-16 Sequence 2Bl7024
Preparation BrCl Oxidation
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202196-BLK1
F202196-BLK2
F202196-BLK3
F202196-BLK4
Mercury Mercury Mercury Mercury
004
004
005 008
050
050
050
050
ngL
ngL
ngL
ngL
F202196
F202196
F202196
F202196
EPA 1631E
EPA 163IE
EPA 1631E EPA 1631pound
u u u
QB-04 U
Frontier Global Sciences Inc The results In this report only apply to the samples analyzed in accordance with the chain ofcustody docunient Thisanalytical report must be reproduced in its entirety
Liz Siska Project Manager Page 20of23 Final Report mn7nni
24
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
~ GLOBAL SCIENCES
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Aualyte Found MRL Units Batch Method Notes
F202131-BLKI Aluminum 009 40 microgL F202131 PA 2008 Moc u F20213l-BLKI Chromium -002 010 microgL F20213l PA 2008 Moc u F20213l-BLKI Manganese 0004 010 microgL F202I3l ~PA 2008 Moc u F202l3I-BLK1 Nickel 0004 010 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Copper 0005 010 microgL F202131 ~PA 2008 Moc u F202131-BLK1 Zinc 007 020 microgL F202131 PA2008 Moc u F202131-BLK1 Arsenic -0IO 015 microgL F202131 PA 2008 Moc u F202I3l-BLK1 Selenium -006 060 microgL F202131 PA 2008 Moc u F202131-BLK1 Molybdenum 001 006 microgL F202131 PA 2008 Moc u F20213l-BLK1 Lead 0002 0040 microgL F202131 ~PA 2008 Moc u
Frontier Global Sciences Inc [he results in this report only apply to the samples analyzed in accordance with Jhe chain ofcustody document This analytical report must be reproduced In its enlirety
Page 21 o23Final Report 25 l711
Liz Siska Project Manager
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B21010
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202215-BLKI Zinc -003 020 microgL F202215 ~PA 2008 Moc u F202215-BLKI Cadmium -0001 0020 microgL F202215 PA 2008 Moc u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordilnce wj(h the chain ofcustody document This analytical report must be reproduced in its entirery
Page 22of23 Final Report 26Liz Siska Project Manager mn1nn1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPD values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis pennits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than l times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-04 The blank was preserved to 2 BrCl rather than l The contr-ol limit for blanks preserved to greater than l BrCl is the preservation percentage multiplied by the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the charn ifcustody documenl 11rts analytical report must be reproduced In its entirety
Liz Siska Project Manager Page 23023 Final Report 27 nn1nn1
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109~ Pb 206-622-6960
GLOB~L SCIENCES Fx 206-622-6870
27 February 2012
Jeff Gagne
Eastern Analytical Inc
25 Chenell Drive
Concord NH 03301
RE Merrimack Station 2008
Enclosed are the analytical results for samples received by Frontier Global Sciences All quality control measurements are within established control limits and there were no analytical difficulties encountered with the exception of those listed in the case narrative section of this report
If you have any questions concerning this report please feel free to contact me
Sincerely
Liz Siska
Project Manager
28
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
I ~ C LOBAL SC I ENCE S
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 Fx 206-622-6870
ANALYTICAL REPORT FOR SAMPLES
Laboratory Frontier Global Sciences Inc
Client Eastern Analytical Inc
SDG
Project Merrimack Station 2008
Sample ID Lab ID Matrix Date Sampled Date Received
Effluent Field Blank 1202140-01 Water 09-Feb-12 0000 IO-Feb-12 0925
Treat Tanlc Effluent 1202140-02 Water 09-Feb-12 0000 10-Feb-12 0925
Frontier Global Sciences Inc
middotmiddot
Liz Siska Project Manager
The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Page I of12I 202140 Fmal Report B Co V 29 1gt171111
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
CASE NARRATIVE
SAMPLE RECEIPT
Samples were received at Frontier Global Sciences (FGS) on February 10th 2012 The samples were received intact on-ice with temperatures measured at 20 degrees Celsius
SAMPLE PREPARATION AND ANALYSIS
Samples were prepared and analyzed for total metals in accordance with EPA Method 2008 (modified)
ANALYTICAL ISSUES
Liquid spikes were prepared for every preparation as a measure of accuracy All liquid spikes and certified reference material were within the control limits
As an additional measure ofthe accuracy ofthe methods utilized for analysis and to check for matrix interference matrix spikes (MS) and matrix spike duplicates (MSD) were digested and analyzed All ofthe matrix spike recoveries were within the control limits with the exception of any QC flagged and described in the notes and definitions section ofthe following report
A reasonable measure ofthe precision ofthe analytical methods utilized for analysis is the relative percent difference (RJgtD) between matrix spike and matrix spike duplicate recoveries and between laboratory control sample and laboratory control sample duplicate recoveries All of the relative percent differences were within the control limits with the exception ofany QC flagged and described in the notes and definitions section ofthe following report
Frontier Global Sciences Inc The results in this reporJ only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
Page 2 of12 1202140 Final Report B Co V 30 111n1n11n
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
Chain of Custody Record amp Laboritory Analysis Request bullbull - tie WA 9810) _fir Water Sediments Plant and Animal Tissu~ 107558 206-622-60
206-622 680~
Hydrocarbon amp Otlicr S11mpiesFRONTIEK tntsi~fJlnlietGS~ll G I O U A 1 ~CI f fol C ( t P1Q~ _ cf ( j 2 o-t -to l11tp(www F1011tlerGS1ot)1
0)t CltampS__~1microilu _ _ COflUgtltt lbulll shy~ gt _ - shyiAddre~ 1gtc ~ () ~V(_1Lf(lJlpoundJtU-r _ middotmiddot--middot _c~_Y ~middotbull E~~1 ilaquois~kc -rolect NM1a M ~ middot - -- ~bmiddotbull~ Cootr~clPO 2 - c-o ~C()Orr -~eltA ldlt11c5
(OVCl(fl To ~middoto - shy
- middot 1 I 4gtcJc-c ~~r fi1 gt- A e- - j 10~middot v r1J~
~ vor~+ middotir~- s~
gt) 71 6(~ Zu bull
~~ _ _ FG-V e~+-middot
tlt(_ A ~-i~C ft -p---~ Cft4l11 i
z ro - rz trr78 Fl- 1lt1) - R ~ lt- U
Sanbullple Cgt15oosal Sy bullJning yov cJer1ar1 th1 yau agree wkh FGS wm ( cXgtNhtlous nn(I lhatl1a Petun (shippi11g felts m~y aPl)ly) )OU Dutl(izr FGS to pcrlorn he spltoct(red a natyss
o St-~rltl Discosal - JO Days ine bulltl)Ot _ 1 iDc -deg middot middotmiddot r cdeg c ge--recs--middot ______ rcvhl=-=middot middot-===-==a=middot =-middot -_ middot middotamiddot-=-middotmiddot----~tcbull - - --eeks__tc1 tfso_ middot Y3_PPlv) __Cusi=middotoc11lt~gtmiddotPLP middotmiddot- middotmiddotmiddot D - middot
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870FRONTIER
GLOBAL S C IENC E S
CHAIN OF CUSTODY FORMS
shy
Frontier Global Sciences Inc chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager
11e results in tAfs report only apply to the samples analyzed in accordance with the
Page3ofl2 1202140 Final Report B Co V 31 n1n1nn1
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98 l 09 ~ Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
ANALYTICAL RESULTS
Effluent Field Blank
Matrix Water Laboratory ID 1202140-01
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Method Notes
Boron ND 021 300 microgL 1 F202131 2Bl80I6 021712 EPA 2008 Mod QB-02 QM-12 U
Cobalt ND 0007 010 microgL 1 F202131 2B18016 021712 EPA 2008 Mod u Vanadium ND 001 010 microgL F20213I 2Bl8016 021712 EPA 2008 Mod u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance wilh the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 4 o12 J202140 Final Report B Co V nn1nn1
32
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
-ltx) deg(v~ - 414 Pontius Ave North
0 Seattle WA 98109~ v Ph 206-622-6960FRONTIER Fx 206-622-6870 GLOBAL SCIENCES
ANALYTICAL RESULTS
Tr~at Tank Effluent
Matrix Water Laboratory ID 1202140-02
Analyte Result MDL MRL Units Dilution Batch Sequence Analyzed Metliod Notes
Boron 357000 412 6000 microgL 2000 F202131 2B24005 022312 EPA2008 Mod Cobalt ND 034 500 microgL 50 F202I31 2Bl8016 021712 EPA2008Mod u Vanadiwn ND 068 500 microgL 50 F202131 2B18016 021712 EPA2008Mod u
Frontier Global Sciences Inc The results in this report only apply 10 the samples analyzed inaccordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page5 of121202140 Final ReponB Co V 33 nllfll
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131 Sequence 28806
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202l3l-MSMSD1
Analyte
Sample Concentration
(11gL)
Spike Added (microgL)
MS Concentration
(microgL)
MS
Recovery Recovery
Limits Method Notes
Vanadiwn 121 50500 807 136 70 - 130 EPA 2008 Mod QM-07
Cobalt
Analyte
076
Spike Added (microgL)
50500
MSD Concentration
(microgL)
583
MSD
RPD Recovery
106 202
100 70 - 130 EPA 2008 Mod
Recovery Limits
70 - 130
RPD Limit Method
20 EPA 2008 Mod
Notes
QR-08 Vanadium 50500 658
Cobalt 50500 606 105 384 70 - 130 20 EPA 2008 Mod
Frontier Global Sciences Inc The results in this report onlyapply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 6012 1202140 Final Report B Co V 34 mn71nT
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960~ Fx 206-622-6870
GLOBAL SCIENCES
MATRIX SPIKE I MA TRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02
Batch F202131
Preparation Closed Vessel Nitric Oven Digestion
Sequence 2BI80I6
Lab Number F202 l 3 l-MSMSD2
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Method Limits Notes
Vanadium 121 10100 1097 108 70 - 130 EPA2008 Mod AS Cobalt 076 50500
Spike MSD
5174
MSD
102 70- 130 EPA 2008 Mod AS
Added Concentration Recovery RPD Analyte (microgL) (pgL) Recovery RPO Limits Limit Method Notes
Vanadium IO 100 1052 104 420 70 shy 130 20 EPA2008 Mod AS Cobalt 50500 5183 102 0187 70 - 130 20 EPA2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page 7of12 1202140 Final Report B Co V nunnni
35
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206--622-6960~ Fx 206--622-6870
GLOBAL SCIENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F202131 Sequeoce 2B2400S
Preparation Closed Vessel Nitric Oven Digestjon Lab Number F202131-MSMSD5
Analyte
Sample Concentration
(microgL
Spike Added (microgL)
MS Concentration
(pigL)
MS Oo
Recovery Recovery
Method Limits Notes
Boron 356800 75750 356500 -478 70- 130 EPA 2008 Mod QM~o2
Analyte
Spike Added (microgL)
MSD Concentration
(pgL)
MSD
Recovery
RPD
Recovery Limits
RPD Limit Method Notes
Boron 75750 359700 3820 0909 70 - 130 20 EPA 2008 Mod QM-02
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Page8oJI2 1202140 Final Report B Co V 36 )77)1
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
G L OBAL S C IENCES
MATRIX SPIKE MATRIX SPIKE DUPLICATE RECOVERY AND RPD
SOURCE 1202140-02RE2
Batch F20213 l Sequence 2B24005
Preparation Closed Vessel Nitric Oven Digestion Lab Number F20213 l-MSMSD6
Sample Spike MS MS
Analyte Concentration
(microgL) Added (microgL)
Concentration (microgL)
Recovery
Recovery Limits Method Notes
Boron 356800 161600 530100 107 70 - 130 EPA 2008 Mod AS Spike MSD MSD
Added Concentration Recovery RPD
Analyte RPD (microgL) (1igL) Recovery Limits Limit Method Notes
Boron 161600 497000 868 643 70- 130 20 EPA 2008 Mod AS
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance with the chain ofCUJtody document Thir analytical report murt ~ reproduad i11 Its enJirety
Liz Siska Project Manager Page 9o12 1202140 Final Report B Co V 37 mn1nn11
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
LABORATORY CONTROL SAMPLE LABORATORY CONTROL SAMPLE DUPLICATE
RECOVERY AND RPO
Batch F20213 l Sequence 2Bl8016
Preparation Closed Vessel Nitric Oven Digestion Lab Number F202131-BSBSD1
LCS Source Blank ~Iike
Analyte
Spike Added (microgL)
LCS Concentration
(microgL)
LCS Oo
Recovery Recovery
Limits Method Notes
Boron 75000 7623 102 85 - 115 EPA 2008 Mod
Vanadiwn 50000 457 914 85 - 115 EPA 2008 Mod
Cobalt 50000 506 101 85 - 115 EPA2008 Mod
Analyte
Spike Added (pgL)
LCSD Concentration
(microgL)
LCSD
Recovery
RPD Recovery
Limits RPD Limit Method Notes
Boron 75000 7722 103 129 85 - 115 20 EPA 2008 Mod
Vanadium 50000 493 986 759 85 bull 115 20 EPA 2008 Mod
Cobalt 50000 515 103 181 85 - 115 20 EPA2008 Mod
The results In this report only apply to the samples analyzed in accordance with the chain ofcustody document This analytical report must be reproduced in itsemirety
Frontier Global Sciences Inc
Liz Siska Project Manager Page Oof12 J202140 Final Report B Co V 38 rnn1nM
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North
Seattle WA 98109 Ph 206-622-6960 Fx 206-622-6870
GLOBAL SCIENCES
PREPARATION BLANKS
Instrument ICPMS-6 Sequence 2B18016
Preparation Closed Vessel Nitric Oven Digestion
Lab Sample ID Analyte Found MRL Units Batch Method Notes
F202131-BLK1 F202l31-BLK1 F202131-BLK1
Boron Vanadium Cobalt
113 -006
00001
300 010 010
microgL
microgL
microgL
F202131 F202I3l F202131
~PA 2008 Moc ~PA 2008 Moc ~PA 2008 Moc
u u u
Frontier Global Sciences Inc The results in this report only apply to the samples analyzed in accordance 1fith the chain ofcustody document This analytical report must be reproduCd In Its entirety
-~ -~ Page I1 o12 1201140 Final Report B Co V mn11nn
39 Liz Siska Project Manager
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
414 Pontius Ave North Seattle WA98109 Ph 206-622-6960 ~ Fx 206-622-6870
GLOBAL SCIENCES
Notes and Definitions
U Analyte included in the analysis but not detected
QR-08 The RPD value for the MSMSD was outside ofacceptance limits Batch QC acceptable based on matrix duplicate andor LCSLCSD RPO values within control limits
QM-12 Initial or continuing calibration verification andor blank spikeblank spike duplicate recoveries above upper control limits All reported sample concentrations were below the reporting limit
QM-07 The spike recovery was outside control limits for the MS andor MSD The batch was accepted based on LCS and LCSD recoveries withinmiddotcontrol limits and when lnalysis permits acceptable ASASD
QM-02 The MS andor MSD recoveries outside acceptance limits due to spike concentration less than 1 times the sample concentration The batch was accepted based on LCS and LCSD recoveries within control limits and when analysis permits acceptable ASASD
QB-02 The method blank andor initialcontinuing calibration blank contains analyte at a concentration above the MRL However the sample concentrations are less than the MRL
AS This MS andor MSD is an analytical spike andor an analytical spike duplicate
DET Analyte Detected
MDL Minimum Detection Limit
MRL Minimum Reporting Limit
ND Analyte Not Detected at or above the reporting limit
wet Sample results reported on a wet weight basis
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
RSD Relative Standard Deviation
Frontier Global Sciences Inc The results in this report only apply to the samples analyed in accordance with the chain ofcustody document This analytical report must be reproduced in its entirety
Liz Siska Project Manager Pagel2oI2 1202140 Final Report B Co V mn7nni
40
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~
107558-W - eastern analytical inc CHAIN-OF-CUSTODY RECORD shyortprofessonal laboflltory services uLANH
DateTime Composites need start
Sample IDs and stop dateslimes Matrix Parameters and Sample Notes of containers
Effluent Field Blank I -2Iq 1~ AqToUSWLLMetalsSubaqueous [C
e rcomp oltss_ Dissolved Sample Field Filtered L0 Sampler confirms ID and parameters are accurate Circle preservstives HCL HNO HSO NaOH MEOH NaSO(IC
Treat Tank Effluent I t jCf 1il AqToUSWLLMetalsSubpH aqueous ~ orcompOi~6
Dlssolved Sample Field FIitered LD Sampler confirms ID and parameters are accurate Circle preservetvels HCL HNO HSO NaOH MEOH NaSO
Please ensure this auto COC is accurate adheres to permit orsampling requirements for this sampling event and modify as necessary
EAi Project 10 3902
Project Name Wastewater Analysis - Weekly
State NH
Cllent (Pro Mgr) Paul Pepler
Customer GZA GeoEnvironmental Inc (NH)
Address 380 Harvey Road
City Manchester NH 03103
Phone 623-3600 Fax 624-9463 (37)
emailA~cfr~ss pi)upp[ergia~om
Results Needed by Preferred date----shy
Notes about project (ie Special Limits BIiiing info If different )
Subcontract ALL metals to Frontier Global Sciences Metals include Total AsCdCrCuPbHgMoNiSe AgZn Metals analyses require project-specific MSMSD
QC deliverables
DA DA+ ~B DB+ DC OPC
ReportlngOptlons
~HC PONumber 02259252 ~EDD PDF
Quote No 1009476ampI EDD email ampI PDF prellm NO FAX Temperature 2-0 degC D e-mall Login Confirmation
Ice present Yes ~ No CJONO FAX
Sampte19911ected
j)i1 0950 by
~__ elinqulshed by
Relinquished by DateTime Received by
Eastern Analytical Inc 25 Chenet Dr Concord NH 03301 Phone (603)228-0525 1-800-287-0525 Fax (603)228--4591
JO~