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TITLE AND SaJEMIL 5. FUNDING NUIMERS

1- 184 CRDONRESERCHCONFERENCE ON HIGH TEMPERATURE CHEM STRY

AUTHOR(S 6110F

2306/A2'

_ Karl E. Spear _ _ _ _

FEW, ,IN ORGANIZATION NAME(S) AND ADORESS4ES) I. PERFORMING NIZATION(\J PEPORT NIUMIGordon Research Center 'University of Rhode Island 0 .~ 9-~L

I Kingston RI 02881

( ~ SFONSORIG/MWONITDRING AGENCY NAMI(S) AND AORSS(IES) 10. SPONSORING/ MONITORING-AFOSR , rjui.AGENCY REPORT NUWERBLDG 410 L) I1BAFB DC 20332-6448 EL C EAFOSR-84-02 17

12a. DISTRUON/AVAILAU.JY STATEMENT tZALb OISTUIUTIO4 CODE

19 (Cotinue, re ,erse :frecessary aid i dentify by block number)rhe Gordon Research Conference on High Temperature Chemistr \as been held biennially since1 6NAs such, it is the only regularly scheduled international meeting where the inter-disciplinary group comprising high temperature science can interact and d*scuss forefrontissues of the day. Gordon Conference surveys of part participants have indicated thisconference to be extremely helpful in the generation of new research ideas and contacts.The mix of foreign, local* academic, industrial and government participants is also arecognized hallmark of such meetings.

The 1984 Conference had 17 invited talks in* the areps of:*Cluster For-mation and Properties'*Chemlistry of Inorganic Species in Flames'*Gas-Solid Processes: Basic Surface Chemistry.SGas-Solid Processes: Laser Vaporization

14. SUJECT TPANS. NUMBER OF PAGES14. UIJ CT T RMS23

IL PRICE CODE

17- SECURITY CLASSIFICATION 16. SECURITY CLASSIFICATION 12. SECURITY CLASSIFICATION 20_. UMTATION OF ABSTRACTOf REPORT OF THS PAGE Of AgSTRACT

unclassified unclassified IIINSN 7S40-01-2SO.S-55.

.. 4tsnd^ ofrm 298 (690104 Draft)-~~~ (M~ ANSI Sid W 3.1

* ~as-olic r._zesses: Vanor Transport .JA i* Gas-Solid Processes: Vaporization* Systematic Errors in High Temp. Equilibrium :leasurements* Modeling Condensed Phase Behavior

in Addition to these formal lectures and discussions, two invited Poster Sessionspertaining to Recent Advances in High Temperature Chamistry were held. Thirty-nine pos.,paper were presented, and piovided a forum for in-depth discussions of other activereseai h topics in the field. A conference program and a list of invited posterpapers are attachments A and B respectively.

The co ference had a total attendance of 106: 20 from outside the United States, 25 fromU.S. i- duatries, 21 from U.S. government laboratories, and 40 from U.S. universities. Th,last g oup included 10 'young' scientists (graduate students and postdoctoral associates)Attaci ent C is a complete registration list.

In acc rdance with Gordon Conference policy, no printed abstracts or papers were producedor dis ributed. The minutes of the conference business meeting, as prepared by theconference secretary, Dr. Clifford E. Myers, are appended as attachment D.

Aoession For#TIS MRU&I

DTIC TABUnannounced

Justifioatiom

By

~-Distribution/%~Availability Ce~s

7Avail and/or

.list Special

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5as-Sc~ii P c ces: acrz:nI : r., 2 1"Se Sc17 r ,7 r_ s:

* Systematic rrors en 77p. Equ i IJr i _6.asur-ets* Modeling Condensed Phase Behavior

in Addition to these formal lectures and discussions, two invited Poster Sessionspertaining to Recent Advances in High Temperature Chemistry were held. Thirty-nine pos-.papers were presented, and provided a forum for in-depth discussions o" other activeresearch topics in the field. A conference program and a list of invited posterpapers are attachments A and B respectively.

The conference had a total attendance of 106: 20 from outside the United States, 25 fromU.S. industries, 21 from U.S. go7ernment laboratories, and 40 from U.S. universities. ThElast group included 10 'young' scientists (graduate students and postdoctoral associates).Attacnent C is a complete registration list.

In accordance with Gordon Conference policy, no printed abstracts or papers were producedor distributed. The minutes of the conference business meeting, as prepared by theconference secretary, Dr. Clifford E. Myers, are appended as attachment D.

Aooession For

NTIS GRA&IDTIC TAB QUnnmounoad tJutitifleotlor

By-

' A lvalab l7ty CodsAvail1 and/or

halt Speelal

Final Report to

Joseph W. Hager, Captain USAFProject Manager for Grant

Air Force Office of Scientific ResearchAir Force Systems Command, USAF

Bolling AFB, D.C. 20332

Grant No. AFOSR-84-0217

1984 GORDON RESEARCH CONFERENCEON

HIGH TEMPERATURE CHEMISTRY

23-27 July 1984

Brewster AcademyWolfebnro, New Hampshire

Karl E. Spear Alexander M. Ckuickshank

Conference Chairman Director, Gordon Research Conf.Materials Research Laboratory Gordon Research CenterThe Pennsylvania State Univ. University of Rhode IslandUniversity Park, PA 16802 Kingston, RI 02881

3 December 1984

Final Report toAir Force Office of Scientific Research

For Partial Support Through Grant No. AFOSR-84-0217of the

1984 GORDON RESEARCH CONFERENCE ON HIGH TEMPERATURE CHEMISTRY23-27 July 1984, Brewster Academy, Wolfeboro, New Hampshire

Conference Chairman Vice-ChairmanKarl E. Spear Donald L. HildenbrandMaterials Research Lab. SRI InternationalThe Pennsylvania State Univ. 333 Ravenswood Ave.University Park, PA 16802 Menlo Park, CA 94025

Background and Nature of Conference

The Gordon Research Conference on High Temperature Chemistry has been

held biennially since 1960. As such, it is the only regularly scheduled

international meeting where the interdisciplinary group comprising high

temperature science can interact and discuss forefront issues of the day.

Gordon Conference surveys of part participants have indicated this

conference to be extremely helpful in the generation of new research ideas

and contacts. The mix of foreign, local, academic, industrial and

government participants is also a recognized hallmark of such meetings.

The 1984 Conference had 17 invited talks in the areas of:

* Cluster Formation and Properties* Chemistry of Inorganic Species in Flames* Gas-Solid Processes: Basic Surface Chemistry

* Gas-Solid Processes: Laser Vaporization* Gas-Solid Processes: Vapor Transport* Gas-Solid Processes: Vaporization

* Systematic Errors in High Temp. Equilibrium Measurements* Modeling Condensed Phase Behavior

In addition to these formal lectures and discussions, two invited

Poster Sessions pertaining to Recent Advances in High Temperature Chemistry

were held. Thirty-nine poster papers were presented, and provided a forum

for in-depth discussions of other active research topics in the field. A

conference program and a list of invited poster papers are attachments A

and B respectively.

The conference had a total attendance of 106: 20 from outside the

tnited States, 25 from U.S. industries, 21 from U.S. government

laboratories, and 40 from U.S. universities. The last group included 10

'young' scientists (graduate students and postdoctoral associates).

Attachment C is a complete registration list.

In accordance with Gordon Conference policy, no printed abstracts or

papers were produced or distributed. The minutes of the conference

business meeting, as prepared by the conference secretary, Dr. Clifford E.

Myers, are appended as attachment D.

Finances

A total of 112,000. was available for disbursement by the conference

chairman. Of this amount, 47,500. was orovided by the Gordon Research

Conference, 31,500. was provided by the General Electric Company, and

13,000. was provided by the Air Force Office of Scientific Research. These

funds were used to offset the fixed conference fee of $235. and/or travel

expenses of key participants -- primarily speakers and discussion leaders.

A complete record of the disbursement is on file with the conference

chairman and with the Gordon Research Conference Offices.

Acknowledgment and Comments

Partial support of this conference by AFOSR is greatfuliy

acknowledged. A number of key participants would not have been able to

attend if partial support of their expenses had not been possible. The

1984 Conference was considered to be a great success by the participants,

and helped to stimulate many new ideas in basic research areas pertinent to

AFOSR. Our understanding of the high temperature behavior of materials is

critical for processing and fabrication as well as for the final

technological uses. Mechanical failure of structural metals, ceramics, and

composites is often preceded by chemical interactions (corrosion) at high

temperatures. The coupling of the chemical, thermodynamic, kinetic, and

mass transport properties of materials is the key to understanding high

temperature processing and behavior. The assessment and availability of

reliable data for use in these analyses is critical. These are but a 'ew

of the areas which were examined from a basic viewpoint at the 1984

Conference. We are confident that the free exchange of forefront

information, which was so evident at this conference, will be beneficial to

existing and future AFOSR supported programs.

ATTACHMENT A

Gordon Research Conference onHIGH TEMPERATURE CHEMISTRY

Brewster Academy, Wolfeboro, NH23-27 July 1984

Chairman: Karl E. Spear Vice-Chairman: Donald L Hildenbrand

MON. 9:00 A.M. INTRODUCTORY REMARKS/WELCOME

I. CLUSTER FORMATION AND PROPERTIES

#1 - Discussion Leader: W. Weltner (Univ. Florida)Speaker: A.W. Castleman (Penn State Univ.)Title: CLUSTERS: FORMATION, REACTION AND PROPERTIES

#2 Discussion Leader: J. Gole (Georgia Tech.)Speaker: E. Schumacher (Univ. Berne)Title: HIGH TEMPERATURE CHEMISTRY AND PROPERTIES OF CLUSTERS

MON. 7:30 P.M.II. CHEMISTRY OF INORGANIC SPECIES _N FLAMES

- Discussion Leader: C. Kolb (Aerodyne Res. Inc.)Speaker: C. Alkemade (Univ. Utrecht)Title: CHEMISTRY AND SPECTROSCOPY OF METALS IN FLAMES AND SHOCK WAVES

#4 - Discussion Leader: M. Drake (Gen. Elec., Schenectady)Speaker: P. Schenck (Nat. Bur. Stand.)Title: OPTOGALVANIC SPECTROSCOPY OF HIGH TEMPERATURE SPECIES IN FLAMES

TUES. 8:55 A.M. - GROUP CONFERENCE PICTURE

III. GAS-SOLID PROCESSES: BASIC SURFACE CHEMISTRY

#5 - Discussion Leader: R. Schoonmaker (Oberlin College)Speaker: J. Tully (Bell Labs)Title: MOLECULAR DYNAMICS AT SURFACES

#6 - Discussion Leader: M. Friscn (IBM, Yorktown Heights)Speaker: R. Hall (Exxon, Clinton NJ)Title: KINETICS OF SURFACE REACTIONS UTILIZING LASER EXCITATION UF THE

SURFACE

1I

1984 Gordon Research Conf. - High Temperature Chemistry - page2

TUES. 7:30 P.M.IV. GAS-SOLID PROCESSES: LASER VAPORIZATION* *** ** **** ** ***** *** ****** ****** ****** *** **

#7 - Discussion Leader: R. Hauge (Rice Univ.)Speaker: D. Olander (Univ. Calif., Berezley)Title: TRANSIENT VAPORIZATION OF REFRACTORY SOLIDS BY LASER PUL3E

HEATING

#8 - Session Leader: D. Hildenbrand (Stanford Res. Internat.)Invited Poster Session: RECENT ADVANCES IN HIGH TEMPERATURE CHEISTRY

WED. 9:00 A.M.V. GAS-SOLID PROCESSES: VAPOR TRANSPORT

#9 - Discussion Leader: J. Leitnaker (Oak Ridge Gas. Dif. Plant)Speaker: H. Wiedemeier (Rensselaer Polytecti. Ins.)Title: VAPOR TRANSPORT PROCESSES UNDER MICRO-GRAVITY CONDITIONS:

THERMODYNAMIC, MASS TRANSFER, AND MORPHOLOGY ASFECTS

#10 - Discussion Leader: F. Kohl (NASA Lewis Res. Labs.)Speaker: D. Rosner (Yale Univ.)Title: CVD CONSEQUENCES OF VAPOR PHASE BOUNDARY LAYER PHENOMENA IN

NON-ISOTHERMAL SYSTEMS

#11 - Discussion Leader: K.D. Carlson (Argonne Nat. Lab.)Speaker: E. Zubler (Gen. Elec., Cleveland)Title: CHEMICAL TRANSPORT PROCESSES IN LAMPS

WED. 7:70 P.M.VI. GAS-SOLID PROCESSES: VAPORIZATION

#12 - Discussicn Leader: G. Rosenblatt (Los Alamos Nat. Lab.)Speakers: D. Hildenbrand (Stantoro Res. Inter ,t.)

J. Drowart (Vrije Univ. Brussels)J. Hastie (Nat. Bur. Stand.)

Topic: COMFLEX PROBLEMS IN THE INTERPRETATION OF MASS SPECTROMETRICDATA OF A COMPLICATED CHEMICAL SYSTEM: EXAMFLE SYSTEM OF As-O

#13 - Session Leader: D. Hildenbrand (Stanford Res. Internat.)Invited Poster Session: RECENT ADVANCES IN HIGH TEMPERATURE CHEMISTRY

1984 Gordon Research Conf. - High Temperature Chemistry - page 7

THURS. 9:00 A.M.(cont.) VI. GAC-SOLID PROCESSES: VAPORIZATION

#14 - Discussion Leader: K. Komarek (Univ. Vienna)Speaker: Z. Munir: (Univ. Calif., Davis)Title: INFLUENCE OF AN ELECTRIC FIELD ON EVAPORATION KINETICS

#15 - Discussion Leader: L. Brewer (Univ. Calif., Berkeley)Speaker: D. Peterson (Los Alamos Nat. Lao.)Title: ACTINIDE VAPORIZATION AND BONDING CORRELATIONS

End of Morning Session - CONFERENCE BUSINESS MEETING

THURS. 8:00 P.M.VII. SPECIAL EVENING LECTURE* *** ** * **** ***** *** ****** ***

#16 - Disc. Leader & Intro.: P. Gilles (Univ. Kansas)

Speaker: Leo Brewer (Univ. Calif., Berheley)Topic: SERIOUS SYSTEMATIC ERRORS IN HIGH TEMPERATURE EQUILIBRiUmi

MEASUREMENTS

FRI. 8:45 A.M.VIII. MODELING CONDENSED PHASE BEHAVIOR

********** ***** ** **** **** ** *** ****

#17 - Discussion Leader: M. Blander (Argonne Nat. Lab.,Speaker: M. Rand (AERE Harwell, UK)Title: HIGH TEMPERATURE THERMOCHEMISTRY OF CONDENSED PHASE EJUILIERIA

#18 - Discussion Leader: M.L. Saboungi (Argonn- Nat. Lab.Speaker: A. Pelton (Univ. Montreal)Title: MODELING PHASE EQUILIBRIA IN OXIDE AND SALT SYSTEMS

#19 - Discussion Leader: P. Potter (AERE Harwell, UK)Speaker: Y.A. Chang (Univ. Wisconsin)Title: THERMODYNAMIC MODELING AND PHASE DIAGRAM CALCULATION/FREDICTION

OF BINARY AND HIGHER ORDER SYSTEMS

ADJOURN 12:00 noon

1984 Gordon Research Conf. - High Temperature Chemistry - page 4

OTHER ITEMS

Sunday - aning: Reception(*): 6-7 P.M.Dinner: 7 P.M.Reception(*): after dinner

Thursday Evening: Reception(*): before conference banquet

(*) Beer, wine and snacks are the compliments of Aerodyne ResearchInc., Billerica, MA

Monday Morning: Get aquainted coffee for conference guestsHostess: Marilyn Myers

Monday Afternoon: Open meeeing Qf the NAS/NRC Committee on HighTemperature Science & TechnologyChairman: Gerd Rosenblatt

Nominating Committee Chairman: Paul Gilles

Recommendations Committee Chairman: Paul Nordine

Conference Secretary: Cliff Myers

The 1984 Gordon Research Conference on High Temperature Chemistry issupported in part by the:

(a) Directorate of Electronic and Material Sciences of the Air FcorceOffice of Scientific Research,

(b) Research & Development Center of the General Electric Compn'y.

DISTRIBUTION OF SPEAKERS AND DISCUSSION LEADERS

(19b4 Gordon Research Conference - High Temperature Che_ t -

University (USA)

Speakers Discussion Leaders

L. Brewer (U. Cal.-Berkeley) P. Gilles (Univ. Kansas,

A.W. Castleman (Penn State) J. Gole (Georgia Tech)Y.A. Chang (Univ. Wisconsin) R. Hauge (Rice Univ.,Z. Munir (U.Cal.-Davis) R. Schoonmaker !Oberlin

D. Olander (U.Cal.-Berkeley) W. Weltner (Univ. Florida;

D. Rosner (Yale Univ.)H. Wiedemeier (RPI)

National/Industrial Laboratories (USA)

Speakers Discussion Leaders

R. Hall (Exxon, Clinton, NJ) M. Blander (Argonne)

J . Hastie (NBS) K.D. Carlson (Argonne)

D. Hildenbrand (Stanford R.I.) M. Drake (GE Schenectady)

D. Peterson (Los Alamos) M. Frisch (IBM Yktwn Hts)

P. Schenck (NBS) C. Kolb (Aerodyne)J. Tully (Bell Labs) F. Kohl (NASA Lewis)

E. Zubler (GE Lighting Div.) J. Leitnaker (O.R. Gas. Diff.G. Rosenblatt (Los Alamos;

M. Saboungi (Argonne)

Foreign

Speakers Discussion Leaders

C. Alkemade (Univ. Utrecht) K. Komarei (Univ. Vienna,j. Drowart (Vrije Univ. Brussels) F. Potter (AERE HarwellA. Felton (Univ. Montreal)M. Rand fAERE Harwell)

E. Schumacher (Univ. Berne)

ATTACHMENT B

TUESDAY POSTERS

R. H. HaugeMass Spectrometric and Matrix Isolation Studies of Laser VaporizedApterials

Dr. J. M. DykePhotoelectron Spectroscopy of High Temperature Molecules and otherRelative Species

I. R. BeattieUC14 /ThCl4 ; Polyatomics in a Seeded Nozzle Beam Experiment

Dr. Manfred M. .appesSpectroscopy of Mixed Metal Clusters

Timothy D. RussellVapor Phase UV Absorption Spectra of the CdI 2 /Scl 3NaI System

John W. HastieLaser Vaporization Mass Spectrometry of Graphite and BN

Richard J. Mawhorter, Jr.Molecules at High Temperature as Studied by High PrecisionElectron Diffraction

Charles E. KolbGas Phase Reaction Kinetics of Alkali Oxides and Alkali Hydroxides

Richard SchoonmakerStructure, Binding Energy, and Barrier to Diffusiou for Alkali

Halide Molecules Adsorbed on Alkali Halide (100) Surfaces

Michael C. DrakeLaser Measurements of Superequilibrium Radical Concentrations inTurbulent Combustion

P. A. MontaioX-ray Absorption Studies of FeCI4 and FeBr 2 Molecules Isolated inSolid Argon

Prof. Dr. T. TorringElectronic Structure of Alkaline Earth Monohalides Determined byCombined LASER- and MW-Spectroscopy

K. HilpertMass Spectrometric Study of Metal Iodide Vapors and Clusters

Prof. Dr. K. H. WeilMolecules and Clusters in the Equilibrium Vapour OverAlkali/Antimony Systems

Milton BlanderThe Prediction of Entropies and Free Energy Functions of VaporMolecules and Liquids

Istvan Hargittai/O. Dorofeeva, J. Tremmel, and M. HargittaiFirst Row Transition Metal Dihalides: Linear and Bent

M.-L. Saboungi/J. Ellefson/W. FreylandThermodynamic Properties of a Liquid Semi-Conductor: The Na-SbSystem

Paul Nordine/Robert SchissmanEnthalpy of Boron Sublimation

R. D. Brittain/ K. H. Lau/R. H. LamoreauxActivity of Arsenic in Molten Copper

Kirk Veirs and Gerd M. RosenblattRaman Scattering from Molecular Hydrogen

2

WEDNESDAY POSTERS

Theodore M. BesmannModeling of Chemical Thermodynamic Behavior in the Fluorite-

Structure Phases UO2*x, PuO 2 _x, and Ul.zPUzO2_x

E. David CaterElectron Beam and Thermal Decomposition of Dolomite, CaMg(C03 )2 -

a TEM Study

J. S. OgdenThe Characterization of Molecular As 4010- As409 , As408 , and As407by Matrix Isolation I.R. Spectroscopy

0. J. KleppaHeats of Formation of Diborides of First Row Transition Metals byHigh Temperature Calorimetry

L. N. YannopoulosHigh Temperature Metal Oxide Semiconductor Gas Sensors

Bret HalpernHigh Temperature Oxidation of Carbon on Metals: Infrared Emissionand Modulated Fast Flow Thermionic Emission

Prof. Dr. Kurt L. KomarekThermodynamics of the Non-Stoichiometry Phase P'-PdMn

Dr. Emanuel KaldisThermodynamic Properties of Mixed-Valent SmSe

H. SpychigerHeats of Formation, Non-Stoichiometric and Phase Diagram of theSemarium Sulfides

M. TellefsenPhase Diagrams of the Ce-H2 and La-H 2 Systems

J. E. BennettSolid-Solid Reactions Between Alkali Metal Sulfates and Graphite

S. LinMaterial Degradation under Pulsed High Temperature and HighPressure

Robert F. DavisFree Energy Minimization and Phase Equilibria in the Ti-C-N-Cl-HSystem

1

Nathan S. JacobsonHot Corrosion of SiC Ceramics

Don OlanderRelease of Volatile Fission Products (Xe, I, Te, and Cd) from U0 2

P. G. WahlbeckValidity of the Ruff-MKW Method for Determinations of VaporPressures, Gaseous Viscosities, and Gaseous Diffusion Coefficients

Jimmie G. EdwardsRecent Chemical and Thermodynamic Findings in the Systems: In-Se,Ga-Se, In-Te, Ga2S-In2S, Pb-Al, and Others

Malcolm W. ChaseThermodynamic Properties of the Alkaline Earth Metals

Atilla M. OnerHigh Temperature Chemistry of Fluorine/Metal Interactions

2

ATTACIMENT C

GORDON RESEARCH CONFERENCES

HIGH TEMPERATURE CHEMISTRY

JULY 22-27, 1984Brester Academy, Wolfeboro, New Hampshire

Karl E. Spear, ChairmanDonald L. Hildenbrand, Vice-Chairman

REGISTRATION LIST

Alkemade, Cornelis Estabrook 15 Blander, Milton Non-ResidentState University of Utrecht Argonne Nat'l Lab. Skellinger,Fysisch Lab., Princetonplein 9700 S. Cass Ave Wolfeboro, NHUtrecht The Netherlands 3584 CC Argonne, IL 60439

Alkemade, Paul Sargent 210 Bonnell, David Non-Resident(Guest of Cornelis Alkemade) Nat'l Bureau of Standards Lake Motel

A331/223 - Division 420Bamberger, Carlos Estabrook 8 Baithersburg, MD 20899Oak Ridge Nat'l Lab.P.O. Box X, Chemistry Div. Brewer, Leo Brown 8Oak Ridge, TN Univ. of California

Dept. of Chem.Beattie, Ian Sargent 110 Berkeley, CA 94720Southampton UniversityUK Brittain, Robert D. Sargent 102

SRI InternationalBeaver, Kenneth Non-Resident 333 Ravenswood Ave.Kennametal Inc. Menlo Park, CA 94025P.O. Box 30700Raleigh, NC 27622 Carlson, K. Douglas Estabrook 5

Argonne Nat'l Lab.Bennett, J. Edward Sargent 103 Chem Div.Arkansas State University Argonne, IL 60439Chemistry Dept.State University, AR 72467 Carlsson, Jan-Otto Estabrook 4

Uppsala UniversityBesmann, Theodore Sargent B-8 Dept. of Chem.Oak Ridge Nat'l Lab. Solid State Chem. Group, S-75121P.O. Box X, Bldg 4501 Uppsala, SwedenOak Ridge, TN 37831

Casleton, Kent Sargent B-IBlackburn, Paul Brown 1 US Dept. of Energy/METCArgonne Nat'l Lab. P.O. Box 8809700 S. Cass Ave. Chem Dept. Morgantown, WV 26505Argonne, IL 60439

Castleman, A.W. Non-ResidentBlackburn, Joy Brown 1 Pennsylvania State Univ.(Guest of Paul Blackburn) Dept. of Chem., 152 Davey Lab.

University Park, PA 16802Blackburn, Amy Brown 2(Guest of Paul Blackburn) Cater, David Estabrook 7

Univ. of Iowa Dept. of Chem.Iowa City, IA 52242

Registration List - High Temperature Chemistry July 22-27, 1984 Page 2

Chang, Y.A. Sargent 103 Fredin, Leif Sargent 104Univ. of Wisconsin W.M. Rice UniversityDept. of Metallurgical & P.O. Box 1892/ ChemistryMineral Engrg. Houston, TX 772511509 University Ave.Madison, WI 53706 Frisch, Margaret A. Chamberlain 1

IBM ResearchChase, Malcolm Bearce 4 P.O. Box 218The Dow Chemical Co. Yorktown Heights, NY 105981707 Bldg. Thermal Lab.Midland, Michigan 48640 Gelb, Alan Sargent B-9

Physical Sciences Inc.

Davis, Robert Estabrook 7 P.O. Box 3100, Research ParkNorth Carolina State Univ. Andover, MA 01810229 Riddick Lab., Dept. of Mat. Eng.Raleigh, NC 27695 Gilles, Paul Sargent 202

Univ. of KansasDestry, Jack Sargent 201 Dept. of Chem.Physics Dept. Univ. de Montreal Lawrence, KS 66045P.O. Box 6128, Sta. AMontreal, P.Q. Conada Gilles, Helen Sargent 202

(Guest of Paul Gilles)Destry, Mildred Sargent 201(Guest of Jack Destry) Gokoglu, Suleyman Estabrook 6

Analex Co./Nasa Lewis Res. Ct.

Devore, Thomas Sargent 104 21000 Brookpark Rd., MS 106-1James Madison Univ. Cleveland, OH 44070Dept. of ChemistryHarrisonburg, VA 22807 Gole, James Sargent 105

Georgia Inst. of TechnologyDrake, Michael Estabrook 6 Physics Dept., 225 North Ave.General Electric Corp. Atlanta, GA 30332Res. & Dev. CenterP.O. Box 8 Hall, Richard Brown 9

Schenectady, NY Exxon Research and Eng. Co.Route 22 East - Clinton Township

Drowart, Jean Sargent B-6 Annandale, NJ 08801

Vrije Univ. BrusselLab. Fysische Chem. Halpern, Bret Kimball 1

Pleinlaan 2, B-1050 Yale UniversityBrussels, Belgium Box 2159 Yale Station

New Haven, CT 06520

Dyke, John Sargent B-3Southampton Univ. Hargittai, Istv~n Estabrook 18

Dept. of Chem. Univ. of ConnecticutSouthampton S09 5NH U.K. Dept. of Physcis

Storrs, CT 06268

Edwards, Jimmie Sargent 110Univ. of Tp;edp Hastie, John Non-Resident

Dept. of Chemistry Nat'l Bureau Standards Lake Motel

Toledo, OH 43606 Washington, D.C. 20234

Ellefson, Julie Chamberlain 2 Hauge, Robert Sargent 105

Bell Lab. nice University600 Mountain Ave 6G-319 Chem. Dept. P.O. Box 1892Murray Hill, NJ 07974 Houston, TX 77251

Registration List - High Temperature Chemistry July 22-27, 1984 Page 3

Hemley, Russell Kimball I Kleinschmidt, Phillip Kimball 39ept. of Chem. Los Alamos Nat'l Lab.Harvard Univ., Chem. Lab. Los Alamos, NM 8754512 Oxford St, Box 328Cambridge, MA 02138 Kleppa, O.J. Bearce 10

University of ChicagoHildenbrand, Donald New Dorm 1 James Franck InstituteSRI International 5640 S. Ellis Ave.333 Ravenswood Ave. Chicago, IL 60637Menlo Park, CA 94025

Kohl, Fred Kimball 6Hilpert, Klaus Estabrook 9 NASA Lewis Research CenterNuclear Research Center(KFA) Juelich 21000 Brookpark Rd. Ms 49-1Institute of Applied Physical Chem. Cleveland, OH 44135Box 1913, 517 Juelich, West Germany

Kolb, Charles E. Sargent 109Jacobson, Nathan Kimball 2 Aerodyne Research, Inc.NASA - Lewis Research Center, 45 Manning Rd.MS 106-1 Billerica, MA 0182121000 Brookpark Rd.Cleveland, OH 44135 Komarek, Kurt Brown 3

Univ. of ViennaJohnson, Ernest Kimball 5 Inst. Inorgan. ChemistryMonsanto Research Corp. Waehringerstr. 42,Mound Rd. A-1090 Vienna, AustriaMiamisburg, OH 45342

Krushwitz, Karen Chamberlain 2Kaldis, Emanuel Estabrook 3 Dept. of Chem.Federal Institute of Technology University of CaliforniaCH - 8903 Zurich, Switzerland Berkeley, CA 94720

Kana'an, Adli Sargent 106 Lamoreaux, Robert New Dorm 1Western Michigan University SRI InternationalDept. of Chem. 333 Ravenswood AveKalamazoo, MI 49008 Menlo Park, CA 94025

Kappes, Manfred Kimball 2 Lau, Kai-Lung Sargent 102Univ. of Bern SRI InternationalInstitute oflnorganic Chem. 333 Ravenswood Ave., AG 223Freiestrasse 3, Ch-3000 Bern 9, Menlo Park, CA 95136Switzerland

Leitnaker, James Bearce 4Kematick, Robert Estabrook 17 Martin MariettaSUNY- Binghamton ORGDP K-1006, MS 271Chem. Dept. Oak Ridge, TN 37830Binghamton, NY 13901 Liao, Pok-Kai Estabrook iKessinger, Glen Sargent 101 Pennsylvania State Univ.Univ. of Kansas 271 Materials Research Lab.Dept. of Chem.-Malott Hall University Park, PA 16802Lawrence, KS 66045

Kizilirmak, Nesligul Sargent 203(Guest of Atilla M. Oner)

Registration List - High Temperature Chemistry July 22-27, 1984 Page 4

Lin, Sin Shong Kimball 7 Myers, Clifford Sargent 206Army Mat. & Mech. Res. Center State Univ. of NY at BinghamtonArsenal St. Dept. of Chem.Watertown, MA 02090 BinghamtoR, NY 13901

Lynch, Denis Sargent 106 Myers, Marilyn Sargent 206General Electric Lamp Group (Guest of Clifford Myers)

incandescent & Specialty Lamp '3437Nela Park, Cleveland, OH 44112 Nordine, Paul Sargent 107

Midwest Research InsituteLynn, Sui-Yuan Sargent 211 425 Volker Blvd.Materials Res. Lab Kansas City, MO 54110Pennsylvania State UniversityUniversity Park, PA 16802 Olander, Donald Brown 4

Univ. of CaliforniaLynn, Mei Sargent 211 Dept. of Nuclear Engineering(Guest of Sui-Yuan Lynn) Berkeley, CA 94720

Margrave, John Sargent 204 Oner, Atilla Sargent 203Rice University Yale UniversityDept. of Chem. Chemical Engineering Dept.Houston, TX 77251 P.O. Box 2159 Yale Station

New Haven, CT 06520Mawhorter, Richard Kimball 3University of Texas at Austin Pelton, Arthur Brown 5Physics Dept. Ecole PolytechniqueAustin, TX 78712 P.O. Box 6079, Station A

Montreal, Quebec, Canada H3C 3A7Montano, Pedro Bearce 11West Virginia University Peterson, Dean New Dorm 2Dept. of Physics Los Alamos Nat'l Lab.P.O. Box 6023 MST-5, MS G730Morgantown, WV 26506-6023 Los Alamos, NM 87545

Munir, Zuhair Estabrook 12 Pfefferle, Lisa Chamberlain 3Univ. of California Yale University, Dept. Chem. Eng.Div. of Materials Science 9 Hillhouse Ave, P.O. Box 2159 YSDavis, CA 95616 New Haven, CT 06520

Murad, Edmond Sargent 205 Plante, Ernest Bearce 2Air Force Geophysics Lab Nat'l Bureau of StandardsHanscom AFB, MA 01731 Rm A331 Bldg. 223

Washinton D.C. 20234Murad, Judith Sargent 205(Guest of Edmond Murad) Potter, Paul Edward Estabrook 17

UKAEA, AERE HarwellMurray, Gary Estabrook 17 Chem. Div., Bldg, 540.1SUNY- Binghamton AERE Harwell, Didcot, OxfordshireBinghamton, NY 13903 OXl ORA U.K.

Reqistration List - High Temperature Chemistry July 22-27, 1984 Page 5

Rand, Malcolm Sargent 204 Sheldon, Robert Bearce 3U.K. Atomic Energy Authority Los Alamos Nat'l Lab.B-552 AERE, Hanwell MST-5, MS G730Didcot, OXI1 ORA, England Los Alamos, NM 87545

Rand, Tonia Sargent 204 Shumaker, Craig Non-Resident(Guest of Malcolm Rand) Standard Oil Co., Research

4440 Warrensville Center Rd.Rosenberger, Franz Sargent 107 Cleveland, OH 44128Dept. of PhysicsUniv. of Utah Sigai, Gary Sargent 207Salt Lake City, UT 84112 GTE Lab., Inc.

40 Sylvan Rd.Rosenblatt, Gerd Kimball 4 Waltham, MA 02254Los Alamos Nat'l Lab.MS J563, Chem. Div. Sigai, June Sargent 207Los Alamos, NM 87545 (Guest of Gary Sigai)

Rosner, Daniel Estabrook 13 Simpson,Marty Sargent 208Yale University Delta ResearchDept. of Chem. Engrg. 1003 W. Ash.Mason Lab, Rm. 319, 9 Hillhouse Ave. Blytheville, AR 72315New Haven, CT 06520

Simpson, Melissa Sargent 208Russell, Timothy Sargent 108 (Guest of Marty Simpson)General Electric Co.Nela Park #1312 Spear, Karl New Dorm 3Cleveland, OH 44112 Pennsylvania State Uiiv.

272 MRL3aLounyi, Marie-Louise Non-Resident University Park, PA 16802Argonne Nat'l Lab9700 S. Cass Ave Speros, Dimitri Sargent 209Argonne, IL 60439 10293 Pruty Rd.

Painesville, OH 44077Schenck, Peter New Dorm 2Nat'l Bureau of Standards Speros, Marinel Sargent 209Bldg 223 Rm A331 (Guest Dimitri Speros)Baithersburg, MD 20899

Spychiger, Herbert Bearce 1Schiffman, Robert Bearce 2 Swiss Fcderal Institute of Tech.Midwest Research Inst. ETH-Houggerberg CH-8093425 Volker Blvd. Zurich SwitzerlandKansas City, MO 64110

Tellefsen, Mark Estabrook 1Schoonmaker, Richard Bearce 3 ETH - Zuerich, Lab. of Solid State PhysicsOberlin College ETH-Hoenggerberg, Ch-8093Dept. of Chem. Zuerich, SwitzerlandOberlin, OH 44074

Thomas, Michael Sargent B-3Schumaker, Ernst New Dorm 4 NIMR CSIRUniversity of Bern Meiring Naude Rd. P.O. Box 395Institute for Inorganic Chem. Pretoria, South AfricaFreiestrasse 3, Ch-3000 Bern 9,Switzerland

Registration List - High Temperature Chemistry July 22-27, 1984 Page 6

Topor, Letitia Chamberlain 4 Williamson, Mark Sargent 101University of Chicago Univ. of Kansas5640 S. Ellis Ave. J. Franck Institute Dept. of Chem., Malott HallChicago, IL 60637 Lawrence, .KS 66045

Torring, Thoms Sargent B-2 Yannopoulos, L.N. Estabroot 14Freie Univ. Berlin Westinghouse Res. & Dev. Ctr.Aruimallee 14, Dept. Phys. 1310 Beulah Rd.D-1000 Berlin 33 Pittsburgh, PA 15235

Tully, John Bearce 12 Zubler, Edward Brown 7AT&T Bell Labs. General Electfic Co.600 Mountain Ave. Nela Park #1312Murray Hill, NJ 07974 Cleveland, OH 44112

van Straten, Stella Sargent 210(Guest of Cornelis Alkemade)

van Zee, Richard Sargent 108Chemistry Dept.University of FloridaGainesville, Florida 32611

Wahlback, Phillip Estabrook IDept. of Chem.Wichita State Univw-ityWichita, KS 67208

Weil, Konrad Bearce 8Techn. Hochschule Darmstadt, Inst. fur Phys. Chem.Petersenstrasse 20, D-6100 DarmstadtD-6100 Darmstadt. FRG

Weltner, William Kimball 2AUniversity of FloridaDept. of Chem.Gainesville, FL 32611

White, Philip Estabrook 2GTE Products Corp.Sylvania Lighting Center -100 Endicott St.Danvers, MA 01923

Wiedemeier, Heribert Brown 6Dept. of Chem.Rensselaer Polytechnic InstituteTroy, NY 12181

ATTACENT D

GORDON RESARII CONFEMCE ON HIGH ATTCIIESN Y

Brewster AcademyWolfeboro, NH

July 23-27, 1984

Minutes of the Business Meeting

The business meeting of the conference was called to order by the chairman,Karl Spear, following the morning session on Thursday, July 26, 198A, at 11:45a.m. He reported that there were 106 conferees, 20 from outside the UnitedStates, 25 from U.S. Industries, 21 from U.S. Government Laboratories, and 40from U.S. Universities. The last included 10 'young' scientists (graduatestudents and post-doctoral associates). A complete registration list is

attached.

Following the tradition of the conference, it was moved, seconded and carriedthat Donald Hildenbrand, the 1984 Vice-Chairman, be elected Chairman of the1986 Conference.

The Nominating Committee, which had been named on the first day of theconference and included all former chairman present, consisted of: PaulGilles (1962, Chairman), Leo Brewer (1960), K. D glas Carlson (1972), E.David Cater (1978), John Hastie (1980), Gerd Rosenblatt (1974) and Karl Spear(1984).

The committee's nominees for Vice-Chairman of the 1986 conference wereannounced:

Robert Hauge, Rice UniversityPaul Nordine, Midwest Research Institute

A call was made for nominations from the floor, but there were none. PaulNordine was elected by a secret ballot.

The Chairman called on Paul Nordine for the report of the RecommendationsCommittee. Committee members were:

Paul Nordine, Chairman (Midwest Research Institute)David Bonnell (U.S. National Bureau of Standards)Ian Beattie (University of Southampton, United Kingdom)Franz Rosenberger (University of Utah)

Gary Sigai (GTE Sylvania R and D Labs)Kent Casleton (U.S. Department of Energy, Morgantown)Paul Blackburn (Argonne National Laboratory)Michael Drake (General Electric R and D Labs)

The Committee made the following recommendations:

1. There should be a Gordon Research Conference on HighTemperature Chemistry in 1986 at the same time of year as thepresent Conference or later, and the location of theconference should be Tilton or Brewster (Wolfeboro). A strawvote overwhelmingly favored the Brewster site.

2. The conference meeting room should be equipped with aperiodic chart.

3. With respect to the poster sessions: a) there is a need forimproved spacial arrangements, b) posters need to be upearlier, and c) other times (e.g., 11:30 a.m. -- 12:30 p.m.)should be considered.

4. With respect to program organization: a) the 1984 program isan excellent prototype, b) continuation of the presentpattern of two or three longer lectures with discussionshould be continued for some of the sessions, and c) Some ofthe sessions should have more numerous shorter talks on acommon theme.

5. The topics covered should maintain a balance between activeresearch areas and new directions, concepts, and methods. Inthis connection, a survey of the high temperature communitywould be helpful. A list of suggested topics is attached tothese minutes.

Chairman Spear expressed his appreciation to those whom he had consultedextensively in preparing the program. He then gave over the Chair to the 1986Chairman Elect, Donald Hildenbrand, who expressed appreciation on behalf ofthe conferees to Chairman Spear for his effective planning and smooth runningof the present conference.

The meeting was adjourned at 12:10 p.m.

Respectively submitted,Clifford E. MyersConference SecretaryJuly 26, 1984

1984 RECOIWMDATIONS COKIDTIEE REPORT

Paul Nordine, Chairman

Next ConferenceTime: Same time of year or laterYear: 1986

Location: Tilton or Wolfeboro

Need Periodic Table(make Vice Chairman Responsible)

PostersNeed improved spacePut them up earlierConsider other times for poster session (11:30 a.m. -- 12:30 p.m.?)

Program Organization1984 piogram is an excellent prototypeSome longer lectures, two speakers plus discussion leadersSome, more numerous shorter talks (common theme)

TopicsMaintain balance between active research areas, and new directions,

concepts, methodsSurvey high temperature community

Specific Topics Covering High Temperature and Chemistry

Surfaces

SpectroscopyNew experimentTheoryEffects of temperature change

Chemistry far from equilibriumTurbulent systemsIntense radiation fieldsPlasmasThick shocksVery excited molecules

Extreme conditionsHigh temperatures and pressuresFundamental properties at T 3000K

Phase equilibria and thermodynamicsModelling and measurementsNew techniques

Calorimetry

New techniques for less well understood systemsGlassesSlagsLiquidsetc.

High Temperature Chemistry inThe electronics industryFor energy conversion

1984 Gordon Research Conference on High Temperature Chemistry

Nominating Comittee (Past Chairmen)

Paul Gilles (1962), ChairmanKarl Spear (1984)John Hastie (1980)

Dave Cater (1978)Gerd Rosenblatt (1974)Doug Carlson (1972)Leo Brewer (1960)

Recomendations Comittee S

Paul Nordine, ChairmanDave Bonnell - NBSIan Beattie - University of SouthamptonFranz Rosenberger - University of UtahGary Sigai - GTE Sylvania (*., D Labs)Kent Casleton - DOE MorgantownPaul Blackburn - ANLMike Drake - GE (R and D Labs)

Conference Secretary

Cliff Myers

Hostess for Monday Morning Spouses Coffee

Marilyn Myers