ib chemistry on redox, oxidation, reduction and oxidation number

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IB Chemistry on Redox, Oxidation, Reduction and Oxidation number.

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Page 1: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

http://lawrencekok.blogspot.com

Prepared by Lawrence Kok

Video Tutorial on Redox, Oxidation, Reduction and oxidation number.

Page 3: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

Redox (Oxidation and Reduction)

Oxidation – Gain of oxygen ↑

Oxidation – Loss of hydrogen ↓ Reduction – Gain of hydrogen ↑

Reduction – Loss of oxygen ↓

Page 4: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

Oxidation Number / State

• Arbitary /Imaginary charge assign to an element• Imagining electrons shared will move to a more electronegative atom

Page 5: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

Oxidation Number / State

• Arbitary /Imaginary charge assign to an element• Imagining electrons shared will move to a more electronegative atom

Electron moving to CI Electron moving to C Electron moving to CI

Electron moving to O Electron moving to N Electron moving to O

Page 6: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

• Oxidation number for oxygen is usually (-2) BUT will change if attached toa more electronegative atom like Fluorine

Oxidation Number / State

Oxidation number oxygen change from (-2) → (+2)

Page 7: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

• Oxidation number for oxygen is usually (-2) BUT will change if attached toa more electronegative atom like Fluorine

• Oxidation number for Gp 7 (CI, Br, I) is usually (-1) BUT will change if attach toa more electronegative atom like oxygen

Oxidation Number / State

Oxidation number oxygen change from (-2) → (+2)

Oxidation number group 7 change from (-1) → (+1)

Page 8: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

• Oxidation number for oxygen is usually (-2) BUT will change if attached toa more electronegative atom like Fluorine

• Oxidation number for Gp 7 (CI, Br, I) is usually (-1) BUT will change if attach toa more electronegative atom like oxygen

Oxidation Number / State

Oxidation number oxygen change from (-2) → (+2)

Oxidation number group 7 change from (-1) → (+1)

• Oxidation number for an atom or molecule of an element (NOT combined to formcompound) is always = ZERO (O)

Page 9: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

Oxidation Number / State

• Oxidation number for Polyatomic Ions

Sum of oxidation number for polyatomic ion = Charge on the ion

Page 10: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

Oxidation Number / State

• Oxidation number for Polyatomic Ions

Sum of oxidation number for polyatomic ion = Charge on the ion

• Sum of oxidation number of all atoms present is EQUAL to the CHARGE of ion

Page 11: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

Oxidation Number / State• Oxidation number for monoatomic cations

MONOATOMIC ION -- Oxidation Number = Charge on ion

• Oxidation number for cation = Charge on ion

Page 12: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

• Metal with more than > ONE oxidation number, Roman numeral is used

Oxidation Number / State

• Oxidation number for NON-METALS -- Electronegative → (-ve)

• Oxidation number for METALS -- Electropositive → (+ve)

Page 13: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

Oxidation Number / State• Oxidation Number for Ionic Compound

Oxidation number S = +4 Oxidation number S = +6 Oxidation number N = +3 Oxidation number N = +5

Page 14: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

Oxidation Number / State• Oxidation Number for Ionic Compound

Oxidation number S = +4 Oxidation number S = +6 Oxidation number N = +3 Oxidation number N = +5

Oxidation number Mn = +2 Oxidation number Mn = +4 Oxidation number S = +6 Oxidation number Mn = +7

Page 15: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

Oxidation Number / State• Oxidation Number for Ionic Compound

Oxidation number S = +4 Oxidation number S = +6 Oxidation number N = +3 Oxidation number N = +5

Oxidation number Mn = +2 Oxidation number Mn = +4 Oxidation number S = +6 Oxidation number Mn = +7

Oxidation number Cr= +6 Oxidation number Cr = +6 Oxidation number N = +5 Oxidation number C = +4

Page 16: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

Oxidation Number / StateExample: Determine the oxidation number for element below

1) V in V2O5

6) C in C2H3CI35) C in CH3CI4) O in F2O

3) O in CI2O2) Sn in SnCI4

Page 17: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

Oxidation Number / StateExample: Determine the oxidation number for element below

1) V in V2O5

6) C in C2H3CI35) C in CH3CI4) O in F2O

3) O in CI2O2) Sn in SnCI4

Page 18: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

Determine the oxidation number for the underlined elements

1) (SO4)2- 2) (SO3)2- 3) (OCI )- 1 4) (HCO3)-1

5) (MnO4)-1 7) H2 O 2

Oxidation Number / State

6) (F2O )

Page 19: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

Determine the oxidation number for the underlined elements

1) (SO4)2- 2) (SO3)2- 3) (OCI )- 1 4) (HCO3)-1

5) (MnO4)-1 7) H2 O 2

Oxidation Number / State

Oxidation number for oxygen usually (-2) BUT (-1) in peroxide

6) (F2O )

Oxidation number for oxygen usually (-2) BUT (+2) if bond to more electronegative fluorine

Page 20: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

• Charges on Anion and Polyatomic ion

Oxidation Number / State

• Charges on cations and oxidation number

Page 22: IB Chemistry on Redox, Oxidation, Reduction and Oxidation number

Acknowledgements

Thanks to source of pictures and video used in this presentation

Thanks to Creative Commons for excellent contribution on licenseshttp://creativecommons.org/licenses/

Prepared by Lawrence Kok

Check out more video tutorials from my site and hope you enjoy this tutorialhttp://lawrencekok.blogspot.com